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FR2364879A1 - Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking - Google Patents

Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking

Info

Publication number
FR2364879A1
FR2364879A1 FR7628245A FR7628245A FR2364879A1 FR 2364879 A1 FR2364879 A1 FR 2364879A1 FR 7628245 A FR7628245 A FR 7628245A FR 7628245 A FR7628245 A FR 7628245A FR 2364879 A1 FR2364879 A1 FR 2364879A1
Authority
FR
France
Prior art keywords
hydrogenolysis
feed
prodn
propylene
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7628245A
Other languages
French (fr)
Other versions
FR2364879B1 (en
Inventor
Jean-Pierre Franck
Edouard Freund
Christian Marcilly
Jean Miquel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7628245A priority Critical patent/FR2364879A1/en
Priority to IN1406/CAL/77A priority patent/IN146703B/en
Priority to US05/834,025 priority patent/US4137147A/en
Publication of FR2364879A1 publication Critical patent/FR2364879A1/en
Application granted granted Critical
Publication of FR2364879B1 publication Critical patent/FR2364879B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/42—Hydrogen of special source or of special composition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Prodn. of ethylene and propylene from a hydrocarbon feed boiling at 360 degrees C and contg. C4+ n-and isoparaffins is carried out by first subjecting the feed to hydrogenolysis at a temp. of 300-550 degrees C, a pressure of 10-150 bars, an LHSV of 0.2-5 and an H2/feed vol. ratio of 300-3000 Nl/l, in the presence of a mordenite catalyst contg. 0.01-25 wt. % of >=1 Gp. VIII metal. The hydrogenolysis effluent is then sepd. into an overhead fraction comprising CH4 and opt. H2, a middle fraction comprising C2-3, hydrocarbons, and a bottoms fraction comprising C4+ hydrocarbons. The C2-3, fraction is then subjected to steam cracking at a temp. of 700-850 degrees C, a pressure of 1-1.4 bar and an H2O/hydrocarbon wt. ratio of 0.25-0.4 for a residence time of 0.2-1.2 sec to form C2-3 olefins. The process is highly selective, e.g. givin C2-3 olefin yields of 58-65% based on the wt. of the feed.
FR7628245A 1976-09-16 1976-09-16 Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking Granted FR2364879A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR7628245A FR2364879A1 (en) 1976-09-16 1976-09-16 Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking
IN1406/CAL/77A IN146703B (en) 1976-09-16 1977-09-15
US05/834,025 US4137147A (en) 1976-09-16 1977-09-16 Process for manufacturing olefinic hydrocarbons with respectively two and three carbon atoms per molecule

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7628245A FR2364879A1 (en) 1976-09-16 1976-09-16 Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking

Publications (2)

Publication Number Publication Date
FR2364879A1 true FR2364879A1 (en) 1978-04-14
FR2364879B1 FR2364879B1 (en) 1981-05-22

Family

ID=9177861

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7628245A Granted FR2364879A1 (en) 1976-09-16 1976-09-16 Ethylene and propylene prodn. from higher paraffin cpds. - by hydrogenolysis and steam cracking

Country Status (2)

Country Link
FR (1) FR2364879A1 (en)
IN (1) IN146703B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619757A (en) * 1982-08-31 1986-10-28 Linde Aktiengesellschaft Two stage hydrotreating pretreatment in production of olefins from heavy hydrocarbons
FR2637200A1 (en) * 1988-10-05 1990-04-06 Inst Francais Du Petrole MORDENITE-BASED CATALYST HAVING AT LEAST ONE GROUP VIII METAL AND ITS USE IN ISOMERIZATION OF AN AROMATIC C8 CUT
WO2015000840A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
WO2015000841A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Process for upgrading refinery heavy residues to petrochemicals
WO2015000845A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products
WO2015000844A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
WO2015000843A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Process for the production of light olefins and aromatics from a hydrocarbon feedstock.
WO2018212985A1 (en) * 2017-05-15 2018-11-22 Saudi Arabian Oil Company Method for the conversion of heavy oils to petrochemical products

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619757A (en) * 1982-08-31 1986-10-28 Linde Aktiengesellschaft Two stage hydrotreating pretreatment in production of olefins from heavy hydrocarbons
FR2637200A1 (en) * 1988-10-05 1990-04-06 Inst Francais Du Petrole MORDENITE-BASED CATALYST HAVING AT LEAST ONE GROUP VIII METAL AND ITS USE IN ISOMERIZATION OF AN AROMATIC C8 CUT
EP0363253A1 (en) * 1988-10-05 1990-04-11 Institut Français du Pétrole Mordenite-based catalyst with at least one group VIII metal and its use in the isomerisation of an aromatic C8 fraction
US5077254A (en) * 1988-10-05 1991-12-31 Institut Francais Du Petrole Mordenite-based catalyst containing at least one metal from group viii and its use for isomerizing a c8 aromatic fraction
EA030392B1 (en) * 2013-07-02 2018-07-31 Сауди Бейсик Индастриз Корпорейшн Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products
US10526553B2 (en) 2013-07-02 2020-01-07 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
WO2015000845A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products
WO2015000844A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
WO2015000843A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Process for the production of light olefins and aromatics from a hydrocarbon feedstock.
CN105358660A (en) * 2013-07-02 2016-02-24 沙特基础工业公司 Method for cracking a hydrocarbon feedstock in a steam cracker unit
CN105555925A (en) * 2013-07-02 2016-05-04 沙特基础工业公司 Method for cracking a hydrocarbon feedstock in a steam cracker unit
EA029413B1 (en) * 2013-07-02 2018-03-30 Сауди Бейсик Индастриз Корпорейшн Method for cracking a hydrocarbon feedstock in a steam cracker unit
WO2015000840A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
EA030932B1 (en) * 2013-07-02 2018-10-31 Сауди Бейсик Индастриз Корпорейшн Method for cracking a hydrocarbon feedstock in a steam cracker unit
CN105378037B (en) * 2013-07-02 2018-11-16 沙特基础工业公司 It is the method for petroleum chemicals by refinery's heavy oil residue upgrading
CN110066686B (en) * 2013-07-02 2023-02-17 沙特基础工业公司 Process for cracking hydrocarbon feedstock in steam cracker unit
EA032112B1 (en) * 2013-07-02 2019-04-30 Сауди Бейсик Индастриз Корпорейшн Process for the production of light olefins and aromatics from a hydrocarbon feedstock
CN110066686A (en) * 2013-07-02 2019-07-30 沙特基础工业公司 The method of hydrocarbon raw material is cracked in steam crackers unit
US10465131B2 (en) 2013-07-02 2019-11-05 Saudi Basic Industries Corporation Process for the production of light olefins and aromatics from a hydrocarbon feedstock
US11072750B2 (en) 2013-07-02 2021-07-27 Saudi Basic Industries Corporation Process for upgrading refinery heavy residues to petrochemicals
WO2015000841A1 (en) 2013-07-02 2015-01-08 Saudi Basic Industries Corporation Process for upgrading refinery heavy residues to petrochemicals
US10822558B2 (en) 2013-07-02 2020-11-03 Saudi Basic Industries Corporation Method for cracking a hydrocarbon feedstock in a steam cracker unit
US10899978B2 (en) 2013-07-02 2021-01-26 Saudi Basic Industries Corporation Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products
US11046900B2 (en) 2013-07-02 2021-06-29 Saudi Basic Industries Corporation Process for upgrading refinery heavy residues to petrochemicals
CN110621762A (en) * 2017-05-15 2019-12-27 沙特阿拉伯石油公司 Process for converting heavy oil to petrochemicals
WO2018212985A1 (en) * 2017-05-15 2018-11-22 Saudi Arabian Oil Company Method for the conversion of heavy oils to petrochemical products

Also Published As

Publication number Publication date
FR2364879B1 (en) 1981-05-22
IN146703B (en) 1979-08-18

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