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FR2347097A1 - Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals - Google Patents

Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals

Info

Publication number
FR2347097A1
FR2347097A1 FR7609832A FR7609832A FR2347097A1 FR 2347097 A1 FR2347097 A1 FR 2347097A1 FR 7609832 A FR7609832 A FR 7609832A FR 7609832 A FR7609832 A FR 7609832A FR 2347097 A1 FR2347097 A1 FR 2347097A1
Authority
FR
France
Prior art keywords
group
esp
hydrocarbon conversion
contg
alumina
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7609832A
Other languages
French (fr)
Other versions
FR2347097B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Francaise de Raffinage SA
Original Assignee
Compagnie Francaise de Raffinage SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Francaise de Raffinage SA filed Critical Compagnie Francaise de Raffinage SA
Priority to FR7609832A priority Critical patent/FR2347097A1/en
Publication of FR2347097A1 publication Critical patent/FR2347097A1/en
Application granted granted Critical
Publication of FR2347097B1 publication Critical patent/FR2347097B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

Hydrocarbon conversion catalysts comprise (a) an Al2O3 support, (b) 0.5-30 wt.% of one or more Group VIII metals and (c) 0.01-5 (pref. 0.1-2) wt.% of Si in combined form. The catalysts are esp. useful for hydrodesulphurising and hydrocracking atmospheric and vacuum gas oils and fuel oils. The Al2O3 pref. has a specific surface of >15 m.2/g., and a pore vol. of >0.1 cm.3/g. The catalysts pref. contain 1-20 (esp. 5-15) wt.% Group VIA metal (esp. Mo and/or W) and 0.5-8 (esp. 1-5) wt.% Group VIII metal (esp. Ni and/or Co).
FR7609832A 1976-04-05 1976-04-05 Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals Granted FR2347097A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7609832A FR2347097A1 (en) 1976-04-05 1976-04-05 Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7609832A FR2347097A1 (en) 1976-04-05 1976-04-05 Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals

Publications (2)

Publication Number Publication Date
FR2347097A1 true FR2347097A1 (en) 1977-11-04
FR2347097B1 FR2347097B1 (en) 1981-06-12

Family

ID=9171395

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7609832A Granted FR2347097A1 (en) 1976-04-05 1976-04-05 Hydrocarbon conversion catalysts based on alumina - contg. silicon and group=VIA or group=VIII metals

Country Status (1)

Country Link
FR (1) FR2347097A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2553430A1 (en) * 1983-10-14 1985-04-19 Shell Int Research PROCESS FOR THE HYDRO-ISOMERIZATION OF PETROLEUM WAXES
FR2553302A1 (en) * 1983-10-14 1985-04-19 Shell Int Research PROCESS FOR THE PREPARATION OF MODIFIED REFRACTORY OXIDES AND THEIR USE IN HYDROCONVERSION PROCESSES
EP0145042A2 (en) * 1983-10-14 1985-06-19 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion processes and modified refractory oxides which can be used in such processes
FR2564006A1 (en) * 1984-05-10 1985-11-15 Inst Francais Du Petrole Supported catalyst, process for its preparation and its application to the hydrocracking of heavy petroleum cuts
EP0180269A2 (en) * 1984-11-02 1986-05-07 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
EP0180799A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Process for the preparation of monocarboxylic-acid anhydrides
EP0180802A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Use of a supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0180801A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0533451A2 (en) * 1991-09-16 1993-03-24 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
EP0848992A1 (en) * 1996-12-17 1998-06-24 Institut Francais Du Petrole Boron and silicon containing catalyst and its application in the hydrotreatment of hydrocarbon feeds

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0145042A3 (en) * 1983-10-14 1987-04-08 Shell Internationale Research Maatschappij B.V. Hydrocarbon conversion processes and modified refractory oxides which can be used in such processes
FR2553302A1 (en) * 1983-10-14 1985-04-19 Shell Int Research PROCESS FOR THE PREPARATION OF MODIFIED REFRACTORY OXIDES AND THEIR USE IN HYDROCONVERSION PROCESSES
EP0145042A2 (en) * 1983-10-14 1985-06-19 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion processes and modified refractory oxides which can be used in such processes
FR2553430A1 (en) * 1983-10-14 1985-04-19 Shell Int Research PROCESS FOR THE HYDRO-ISOMERIZATION OF PETROLEUM WAXES
FR2564006A1 (en) * 1984-05-10 1985-11-15 Inst Francais Du Petrole Supported catalyst, process for its preparation and its application to the hydrocracking of heavy petroleum cuts
EP0180269A3 (en) * 1984-11-02 1987-11-25 Shell Internationale Research Maatschappij B.V. Catalyst preparation
EP0180269A2 (en) * 1984-11-02 1986-05-07 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
EP0180802A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Use of a supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0180801A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0180801A3 (en) * 1984-11-07 1986-07-16 Hoechst Aktiengesellschaft Supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0180802A3 (en) * 1984-11-07 1986-07-16 Hoechst Aktiengesellschaft Supported catalyst for the preparation of monocarboxylic-acid anhydrides
EP0180799A3 (en) * 1984-11-07 1986-07-16 Hoechst Aktiengesellschaft Process for the preparation of monocarboxylic-acid anhydrides
EP0180799A2 (en) * 1984-11-07 1986-05-14 Hoechst Aktiengesellschaft Process for the preparation of monocarboxylic-acid anhydrides
EP0533451A2 (en) * 1991-09-16 1993-03-24 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
EP0533451A3 (en) * 1991-09-16 1993-04-14 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
EP0848992A1 (en) * 1996-12-17 1998-06-24 Institut Francais Du Petrole Boron and silicon containing catalyst and its application in the hydrotreatment of hydrocarbon feeds
US6037300A (en) * 1996-12-17 2000-03-14 Institut Francais Du Petrole Catalyst containing boron and silicon and its use for hydrotreating hydrocarbon feeds

Also Published As

Publication number Publication date
FR2347097B1 (en) 1981-06-12

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