FR2225979A5 - Highly explosive composite contg. crosslinked polyurethane binder - and nitro org cpds., with high explosive content - Google Patents
Highly explosive composite contg. crosslinked polyurethane binder - and nitro org cpds., with high explosive contentInfo
- Publication number
- FR2225979A5 FR2225979A5 FR6944792A FR6944792A FR2225979A5 FR 2225979 A5 FR2225979 A5 FR 2225979A5 FR 6944792 A FR6944792 A FR 6944792A FR 6944792 A FR6944792 A FR 6944792A FR 2225979 A5 FR2225979 A5 FR 2225979A5
- Authority
- FR
- France
- Prior art keywords
- explosive
- cpds
- org
- nitro
- compsn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002360 explosive Substances 0.000 title abstract 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 title abstract 4
- 239000011230 binding agent Substances 0.000 title abstract 3
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- 239000004814 polyurethane Substances 0.000 title abstract 2
- 239000002131 composite material Substances 0.000 title 1
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000028 HMX Substances 0.000 abstract 1
- AGUIVNYEYSCPNI-UHFFFAOYSA-N N-methyl-N-picrylnitramine Chemical group [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 229920006037 cross link polymer Polymers 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920003225 polyurethane elastomer Polymers 0.000 abstract 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
- C08G18/6755—Unsaturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0008—Compounding the ingredient
- C06B21/0025—Compounding the ingredient the ingredient being a polymer bonded explosive or thermic component
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
- C08G18/6517—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An explosive compsn. comprises particles of a highly explosive matl. (I) dispersed in >=10%, based on compsn. of a crosslinked polymer (esp. a polyurethane), (I) being pref. nitro or org. nitrate cpds. esp. (I) is octogen (CH2=N-NO2)4, hexogen (CH2=N-NO2)2, pentrite (O2N-O-H2C)4C or tetryl. The compsn. pref. contains =65 wt.% oxidiser, i.e. KClO4 or NH4ClO4. The present compsns. may contain 19-90% explosive and may further be given various shapes while having reduced porosity and consistency ranging from a high hardness to high flexibility. Prior art compsns. contg. metal carboxylate polymer as main binder and polyurethane elastomer as secondary binder contain no more than 80% explosive.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6944792A FR2225979A5 (en) | 1969-12-24 | 1969-12-24 | Highly explosive composite contg. crosslinked polyurethane binder - and nitro org cpds., with high explosive content |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6944792A FR2225979A5 (en) | 1969-12-24 | 1969-12-24 | Highly explosive composite contg. crosslinked polyurethane binder - and nitro org cpds., with high explosive content |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2225979A5 true FR2225979A5 (en) | 1974-11-08 |
Family
ID=9045134
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR6944792A Expired FR2225979A5 (en) | 1969-12-24 | 1969-12-24 | Highly explosive composite contg. crosslinked polyurethane binder - and nitro org cpds., with high explosive content |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2225979A5 (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2294421A1 (en) * | 1974-12-12 | 1976-07-09 | Saint Louis Inst | Thermal effects resisting combustible envelope for propellant charge - consists of plastics foam with secondary explosives |
FR2316203A1 (en) * | 1975-07-02 | 1977-01-28 | Dynamit Nobel Ag | FLEXIBLE EXPLOSIVE BODY MANUFACTURING PROCESS |
FR2432030A1 (en) * | 1978-07-28 | 1980-02-22 | France Etat | High nitro content polyurethane binder for explosives - prepd. from nitrated aromatic poly:ol, aliphatic poly:ol and di:isocyanate |
FR2447358A1 (en) * | 1979-01-24 | 1980-08-22 | Belico Ind Material Brasil | Plastics explosive compsns. - contg. aq. elastomer dispersion as binder, giving improved water resistance and storage (BR 2.5.79) |
EP0036481A2 (en) * | 1980-03-15 | 1981-09-30 | Friedrich-Ulf Deisenroth | Process to prepare polymer-bonded explosives and products obtained according to this process |
FR2577919A1 (en) * | 1985-02-27 | 1986-08-29 | Poudres & Explosifs Ste Nale | METHOD FOR THE NON-SOLVENT MANUFACTURING OF COMPOSITE PYROTECHNIC PRODUCTS WITH THERMOSETTING BINDER AND PRODUCTS THUS OBTAINED, IN PARTICULAR PROPULSIVE COMPOSITE POWDERS |
EP0208665A1 (en) * | 1985-06-20 | 1987-01-14 | Nobel Kemi AB | An explosive charge for the explosive welding of large diameter pipes, and a method for its manufacture |
EP0323828A1 (en) * | 1988-01-05 | 1989-07-12 | ADVANCED EXPLOSIVES GESELLSCHAFT b.R | Explosive for war heads and solid propellants |
FR2640261A1 (en) * | 1979-08-14 | 1990-06-15 | Poudres & Explosifs Ste Nale | Autopyrolysable composition for aerobic propulsion in which the oxidiser is an explosive |
EP0481838A1 (en) * | 1990-10-17 | 1992-04-22 | Societe Nationale Des Poudres Et Explosifs | Insensitive ammunition containing an explosive multi-compositional charge and process for obtaining a blasting effect in water as well as in air |
US5320043A (en) * | 1990-10-17 | 1994-06-14 | Snpe Inc. | Low-vulnerability explosive munitions element including a multicomposition explosive charge, and method for obtaining a blast and/or bubble effect |
WO2003078356A1 (en) * | 2002-03-11 | 2003-09-25 | Bae Systems Plc | Apparatus for mixing explosive materials and for filling of ordnance |
FR2928917A1 (en) * | 2008-03-21 | 2009-09-25 | Eurenco France Sa | Liquid composition, useful as a precursor for finish coating of pyrotechnic filler, comprises energetic filler in a crosslinkable plastic binder |
FR3090629A1 (en) * | 2018-12-20 | 2020-06-26 | Arianegroup Sas | Process for the preparation of composite pyrotechnic products |
-
1969
- 1969-12-24 FR FR6944792A patent/FR2225979A5/en not_active Expired
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2294421A1 (en) * | 1974-12-12 | 1976-07-09 | Saint Louis Inst | Thermal effects resisting combustible envelope for propellant charge - consists of plastics foam with secondary explosives |
FR2316203A1 (en) * | 1975-07-02 | 1977-01-28 | Dynamit Nobel Ag | FLEXIBLE EXPLOSIVE BODY MANUFACTURING PROCESS |
FR2432030A1 (en) * | 1978-07-28 | 1980-02-22 | France Etat | High nitro content polyurethane binder for explosives - prepd. from nitrated aromatic poly:ol, aliphatic poly:ol and di:isocyanate |
FR2447358A1 (en) * | 1979-01-24 | 1980-08-22 | Belico Ind Material Brasil | Plastics explosive compsns. - contg. aq. elastomer dispersion as binder, giving improved water resistance and storage (BR 2.5.79) |
FR2640261A1 (en) * | 1979-08-14 | 1990-06-15 | Poudres & Explosifs Ste Nale | Autopyrolysable composition for aerobic propulsion in which the oxidiser is an explosive |
EP0036481A2 (en) * | 1980-03-15 | 1981-09-30 | Friedrich-Ulf Deisenroth | Process to prepare polymer-bonded explosives and products obtained according to this process |
EP0036481A3 (en) * | 1980-03-15 | 1981-10-21 | Friedrich-Ulf Deisenroth | Process to prepare polymer-bonded explosives and products obtained according to this process |
FR2577919A1 (en) * | 1985-02-27 | 1986-08-29 | Poudres & Explosifs Ste Nale | METHOD FOR THE NON-SOLVENT MANUFACTURING OF COMPOSITE PYROTECHNIC PRODUCTS WITH THERMOSETTING BINDER AND PRODUCTS THUS OBTAINED, IN PARTICULAR PROPULSIVE COMPOSITE POWDERS |
EP0194180A1 (en) * | 1985-02-27 | 1986-09-10 | Societe Nationale Des Poudres Et Explosifs | Process for the solventless production of pyrotechnical products having a thermosetting binder |
US4657607A (en) * | 1985-02-27 | 1987-04-14 | Societe Nationale Des Poudres Et Explosifs | Process for the solvent-free manufacture of compound pyrotechnic products containing a thermosetting binder and products thus obtained |
EP0208665A1 (en) * | 1985-06-20 | 1987-01-14 | Nobel Kemi AB | An explosive charge for the explosive welding of large diameter pipes, and a method for its manufacture |
EP0323828A1 (en) * | 1988-01-05 | 1989-07-12 | ADVANCED EXPLOSIVES GESELLSCHAFT b.R | Explosive for war heads and solid propellants |
US4874441A (en) * | 1988-01-05 | 1989-10-17 | Advanced Explosives Gesellschaft B.R. | Explosive for warheads and solid rocket propellant |
EP0481838A1 (en) * | 1990-10-17 | 1992-04-22 | Societe Nationale Des Poudres Et Explosifs | Insensitive ammunition containing an explosive multi-compositional charge and process for obtaining a blasting effect in water as well as in air |
FR2668146A1 (en) * | 1990-10-17 | 1992-04-24 | Poudres & Explosifs Ste Nale | LOW VULNERABLE ELEMENT OF EXPLOSIVE MUNICIANS COMPRISING A MULTI-COMPOSITION EXPLOSIVE LOADING AND METHOD OF OBTAINING A BLOWER AND / OR BUBBLE EFFECT. |
US5189247A (en) * | 1990-10-17 | 1993-02-23 | Snpe Inc. | Low-vulnerability explosive munitions element including a multi-composition explosive charge, and method for obtaining a blast and/or bubble effect |
US5320043A (en) * | 1990-10-17 | 1994-06-14 | Snpe Inc. | Low-vulnerability explosive munitions element including a multicomposition explosive charge, and method for obtaining a blast and/or bubble effect |
WO2003078356A1 (en) * | 2002-03-11 | 2003-09-25 | Bae Systems Plc | Apparatus for mixing explosive materials and for filling of ordnance |
US7370565B2 (en) | 2002-03-11 | 2008-05-13 | Bae Systems Plc | Apparatus for mixing explosive materials and for filling of ordnance |
FR2928917A1 (en) * | 2008-03-21 | 2009-09-25 | Eurenco France Sa | Liquid composition, useful as a precursor for finish coating of pyrotechnic filler, comprises energetic filler in a crosslinkable plastic binder |
FR3090629A1 (en) * | 2018-12-20 | 2020-06-26 | Arianegroup Sas | Process for the preparation of composite pyrotechnic products |
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