ES8203236A1 - Procedimiento para obtener catalizadores de plata especialmente activados y de duracion prolongada. - Google Patents
Procedimiento para obtener catalizadores de plata especialmente activados y de duracion prolongada.Info
- Publication number
- ES8203236A1 ES8203236A1 ES492730A ES492730A ES8203236A1 ES 8203236 A1 ES8203236 A1 ES 8203236A1 ES 492730 A ES492730 A ES 492730A ES 492730 A ES492730 A ES 492730A ES 8203236 A1 ES8203236 A1 ES 8203236A1
- Authority
- ES
- Spain
- Prior art keywords
- promoter metal
- activity
- metal compounds
- ethylene oxide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052709 silver Inorganic materials 0.000 title abstract 6
- 239000004332 silver Substances 0.000 title abstract 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title abstract 2
- 230000000694 effects Effects 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 150000002736 metal compounds Chemical class 0.000 abstract 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA UTILIZACION DE UN CATALIZADOR DE PLATA EN EL PROCEDO DE OBTENCION DEL OXIDO DE ETILENO, POR OXIDACION DE ETILENO CON OXIGENO. SE COMBINA CON EL CATALIZADOR PORTADOR DE PLATA PROPORCIONES COMPRENDIDAS ENTRE EL 5-15 POR 100 EN VOLUMEN, RESPECTO DEL PRODUCTO FINAL OBTENIDO, DE UN COMPUESTO METALICO PROMOTOR DE SU ACTIVIDAD CATALITICA, EN FORMA DE MATERIAL SOPORTE O BIEN DE UN MATERIAL SOPORTE LIBRE DE PLATA IMPREGANADO EN EL COMPUESTO METALICO PROMOTOR DE DICHA ACTIVIDAD CON UNA ESTRUCTURA CRISTALINA EXTERIORMENTE SIMILAR AL CATALIZADOR DE PLATA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2925625A DE2925625C2 (de) | 1979-06-26 | 1979-06-26 | Verfahren zur Steigerung der Aktivität und zur Verlängerung der Standzeit bei hoher Selektivität von Silber-Träger-Katalysatoren für den Einsatz zur Ethylenoxid-Synthese |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8203236A1 true ES8203236A1 (es) | 1982-04-16 |
ES492730A0 ES492730A0 (es) | 1982-04-16 |
Family
ID=6074117
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES492730A Granted ES492730A0 (es) | 1979-06-26 | 1980-06-25 | Procedimiento para obtener catalizadores de plata especialmente activados y de duracion prolongada. |
Country Status (8)
Country | Link |
---|---|
US (2) | US4310442A (es) |
EP (1) | EP0020962B1 (es) |
JP (1) | JPS567645A (es) |
AT (1) | AT374801B (es) |
AU (1) | AU535445B2 (es) |
CA (1) | CA1137065A (es) |
DE (1) | DE2925625C2 (es) |
ES (1) | ES492730A0 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2916887C2 (de) * | 1979-04-26 | 1981-12-17 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zum Aktivieren oder Reaktivieren von Silber-Träger-Katalysatoren |
US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
US4555501A (en) * | 1984-05-14 | 1985-11-26 | The Halcon Sd Group, Inc. | Process for preparing silver catalysts |
EP0207541B1 (en) * | 1985-06-28 | 1989-10-11 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of a silver-containing catalyst |
JPH084745B2 (ja) * | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
JP2637537B2 (ja) * | 1989-01-24 | 1997-08-06 | 株式会社日本触媒 | エチレンオキシド製造用銀触媒およびその製造方法 |
US5362890A (en) * | 1993-10-04 | 1994-11-08 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US5703254A (en) * | 1996-10-02 | 1997-12-30 | Arco Chemical Technology, L.P. | Propylene oxide process using mixed precious metal catalyst supported on alkaline earth metal carbonate |
RU2242281C1 (ru) * | 2003-07-30 | 2004-12-20 | Общество с ограниченной ответственностью "Томскнефтехим" | Способ регенерации серебряного катализатора получения формальдегида |
TWI341218B (en) | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
ES2990147T3 (es) | 2016-02-18 | 2024-11-29 | Int Flavors & Fragrances Inc | Composición de microcápsulas |
EP3512625B1 (en) | 2016-09-16 | 2023-04-26 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA588750A (en) * | 1959-12-15 | A. Cheney Harry | Catalyst for forming olefin oxides | |
US2799687A (en) * | 1952-12-23 | 1957-07-16 | Merle L Gould | Catalytic oxidation of olefins and contact beds and catalyst therefor |
US3420784A (en) * | 1966-01-13 | 1969-01-07 | Engelhard Ind Inc | Silver and silver-containing copper-cadmium oxide-zinc oxide-barium oxide catalysts |
US4012425A (en) * | 1972-01-07 | 1977-03-15 | Shell Oil Company | Ethylene oxide process |
IT971362B (it) * | 1972-11-30 | 1974-04-30 | Sir Soc Italiana Resine Spa | Procedimento per la produzione dell ossido di etilene mediante ossidazione dell etilene e cata lizzatore relativo |
JPS5136245B2 (es) * | 1973-09-07 | 1976-10-07 | ||
US4130570A (en) * | 1973-10-19 | 1978-12-19 | Boreskov Georgy K | Method of producing ethylene oxide |
US4212772A (en) * | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
GB1594362A (en) * | 1977-05-23 | 1981-07-30 | Ici Ltd | Production of alkylene oxides and catalysts therefor |
DE2751767A1 (de) * | 1977-11-19 | 1979-05-23 | Basf Ag | Verfahren zur herstellung eines aethylenoxidkatalysators |
DE2753359A1 (de) * | 1977-11-30 | 1979-06-07 | Basf Ag | Katalysator zur herstellung von aethylenoxid |
DE2916887C2 (de) * | 1979-04-26 | 1981-12-17 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zum Aktivieren oder Reaktivieren von Silber-Träger-Katalysatoren |
-
1979
- 1979-06-26 DE DE2925625A patent/DE2925625C2/de not_active Expired
-
1980
- 1980-05-08 EP EP80102506A patent/EP0020962B1/de not_active Expired
- 1980-06-24 US US06/162,649 patent/US4310442A/en not_active Expired - Lifetime
- 1980-06-24 JP JP8466380A patent/JPS567645A/ja active Pending
- 1980-06-25 AU AU59595/80A patent/AU535445B2/en not_active Ceased
- 1980-06-25 ES ES492730A patent/ES492730A0/es active Granted
- 1980-06-25 AT AT0332780A patent/AT374801B/de not_active IP Right Cessation
- 1980-06-25 CA CA000354768A patent/CA1137065A/en not_active Expired
-
1981
- 1981-09-18 US US06/303,470 patent/US4409394A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE2925625C2 (de) | 1981-10-01 |
AT374801B (de) | 1984-06-12 |
AU5959580A (en) | 1981-01-08 |
AU535445B2 (en) | 1984-03-22 |
DE2925625B1 (de) | 1980-10-23 |
JPS567645A (en) | 1981-01-26 |
US4310442A (en) | 1982-01-12 |
EP0020962B1 (de) | 1982-12-22 |
ATA332780A (de) | 1983-10-15 |
EP0020962A1 (de) | 1981-01-07 |
CA1137065A (en) | 1982-12-07 |
ES492730A0 (es) | 1982-04-16 |
US4409394A (en) | 1983-10-11 |
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