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ES482760A2 - Catalytic Composite useful for the Oxidation of Mercaptans in Sour Petroleum Distillates - Google Patents

Catalytic Composite useful for the Oxidation of Mercaptans in Sour Petroleum Distillates

Info

Publication number
ES482760A2
ES482760A2 ES482760A ES482760A ES482760A2 ES 482760 A2 ES482760 A2 ES 482760A2 ES 482760 A ES482760 A ES 482760A ES 482760 A ES482760 A ES 482760A ES 482760 A2 ES482760 A2 ES 482760A2
Authority
ES
Spain
Prior art keywords
petroleum distillates
sour petroleum
mercaptans
alkaryl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES482760A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/927,318 external-priority patent/US4206079A/en
Priority claimed from US05/927,317 external-priority patent/US4157312A/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of ES482760A2 publication Critical patent/ES482760A2/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Mercaptan oxidation catalysts for sweetening sour petroleum distillates comprise a metal chelate (e.g. a phthalocyanine) and a quaternary compound of the structural formula < IMAGE > where each R is an alkyl, cycloalkyl, aryl, alkaryl or aralkyl radical containing up to 20 carbon atoms, R<1> is a substantially straight chain alkyl radical containing from 5 to 20 carbon atoms, R2 is aryl, alkaryl or aralkyl, and X<-> is the chloride, bromide, iodide, fluoride, nitrate, nitrite, sulfate, phosphate, acetate, citrate, tartrate or hydroxide anion, impregnated on a solid adsorptive support. The catalytic composites are especially used for trating sour petroleum distillates containing the more difficultly oxidizable mercaptans in the presence of an oxidizing agent and an alkaline reagent (which may be the above quaternary ammonium compound in which X is hydroxide).
ES482760A 1978-07-24 1979-07-23 Catalytic Composite useful for the Oxidation of Mercaptans in Sour Petroleum Distillates Expired ES482760A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/927,318 US4206079A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US05/927,317 US4157312A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate

Publications (1)

Publication Number Publication Date
ES482760A2 true ES482760A2 (en) 1980-07-01

Family

ID=27129942

Family Applications (1)

Application Number Title Priority Date Filing Date
ES482760A Expired ES482760A2 (en) 1978-07-24 1979-07-23 Catalytic Composite useful for the Oxidation of Mercaptans in Sour Petroleum Distillates

Country Status (20)

Country Link
AT (1) AT374818B (en)
AU (1) AU530970B2 (en)
BR (1) BR7904695A (en)
CA (1) CA1124223A (en)
DE (1) DE2927685C2 (en)
DK (1) DK310279A (en)
EG (1) EG14061A (en)
ES (1) ES482760A2 (en)
FR (1) FR2433974A2 (en)
GB (1) GB2027359B (en)
HU (1) HU179813B (en)
IT (1) IT1122275B (en)
MX (1) MX154990A (en)
NL (1) NL7904951A (en)
NO (1) NO160493C (en)
PH (1) PH14933A (en)
RO (1) RO77061A (en)
SE (1) SE436696B (en)
SU (1) SU1095873A3 (en)
YU (1) YU40569B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012202622A1 (en) * 2012-02-21 2013-08-22 Wacker Chemie Ag Catalyst for the carbonylation of carbonylatable compounds in the gas phase
MD4420C1 (en) * 2012-06-26 2017-02-28 Оп "Matricon" Ооо Use of dark heavy oil components as a catalyst in the oxidative purification of hydrocarbonic compositions from hydrogen sulphide and light mercaptans and process for purification of hydrocarbonic compositions

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2988500A (en) * 1959-03-13 1961-06-13 Universal Oil Prod Co Treatment of hydrocarbon distillates
US3164544A (en) * 1963-02-26 1965-01-05 Sun Oil Co Oxidative sweetening with base and quaternary ammonium compound
FR1602191A (en) * 1968-12-31 1970-10-19
US4028269A (en) * 1975-08-21 1977-06-07 Uop Inc. Process for the preparation of a solid bed catalyst system
ZA7740B (en) * 1976-01-14 1977-11-30 Uop Inc Improved process for sweetening sour hydrocarbon distillates
US4070307A (en) * 1976-08-12 1978-01-24 Uop Inc. Method of catalyst manufacture
US4087378A (en) * 1977-01-18 1978-05-02 Uop Inc. Preparation of a supported metal phthalocyanine
US4124494A (en) * 1978-01-11 1978-11-07 Uop Inc. Treating a petroleum distillate with a supported metal phthalocyanine and an alkanolamine hydroxide
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide

Also Published As

Publication number Publication date
EG14061A (en) 1983-03-31
BR7904695A (en) 1980-05-13
DE2927685A1 (en) 1980-02-07
GB2027359A (en) 1980-02-20
RO77061A (en) 1982-03-24
NO160493C (en) 1989-04-26
AU4820279A (en) 1980-01-31
DK310279A (en) 1980-01-25
NO160493B (en) 1989-01-16
MX154990A (en) 1988-01-18
HU179813B (en) 1982-12-28
SU1095873A3 (en) 1984-05-30
NO792430L (en) 1980-01-25
SE7906183L (en) 1980-01-25
ATA501079A (en) 1983-10-15
GB2027359B (en) 1982-10-06
IT1122275B (en) 1986-04-23
FR2433974B2 (en) 1984-08-24
AU530970B2 (en) 1983-08-04
YU40569B (en) 1986-02-28
DE2927685C2 (en) 1987-03-26
NL7904951A (en) 1980-01-28
SE436696B (en) 1985-01-21
YU179179A (en) 1983-02-28
FR2433974A2 (en) 1980-03-21
CA1124223A (en) 1982-05-25
AT374818B (en) 1984-06-12
IT7924574A0 (en) 1979-07-23
PH14933A (en) 1982-01-29

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Legal Events

Date Code Title Description
FD2A Announcement of lapse in spain

Effective date: 20170707