ES482364A1 - Procedimiento para la obtencion de latex de caucho carboxi- lado. - Google Patents
Procedimiento para la obtencion de latex de caucho carboxi- lado.Info
- Publication number
- ES482364A1 ES482364A1 ES482364A ES482364A ES482364A1 ES 482364 A1 ES482364 A1 ES 482364A1 ES 482364 A ES482364 A ES 482364A ES 482364 A ES482364 A ES 482364A ES 482364 A1 ES482364 A1 ES 482364A1
- Authority
- ES
- Spain
- Prior art keywords
- weight
- surface tension
- production
- high surface
- rubber latices
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
Procedimiento para la obtención de látex de caucho carboxilado, esencialmente libre de vetas, con alta tensión superficial, por polimerización de una mezcla de monómeros de 0,5 a 10 partes en peso de uno o varios ácidos mono- o di-carboxílicos alfa, beta-monoetilénicamente insaturados y 90 hasta 99,5 partes en peso de una mezcla de 10 hasta 90 partes en peso de uno o varios dienos conjugados acíclicos, conteniendo de 4 a 9 átomos de carbono, y 10 hasta 90 partes en peso de uno o varios monómeros de arilvinilo conteniendo 8 hasta 12 átomos de carbono y/o (met)acrilonitrilo, ascendiendo la cantidad de (met)acrilonitrilo como máximo a 50 partes en peso, en fase acuosa en presencia de 0 hasta 0,5 partes en peso, calculado sobre el monómero total, de uno o varios emulsionantes hidrosolubles del tipo sulfato y/o sulfonato, caracterizado porque la polimerización se realiza a una temperatura superior a 50ºC empleando un peroxidisulfato como iniciador y en presencia de un ácido mercaptocarboxílico correspondiente a la fórmula HS- (CH(sub, 2))(sub, x)- CO(sub, 2)H donde x es un número entero de 1 a 3, y/o las sales hidrosolubles del mismo.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782830393 DE2830393A1 (de) | 1978-07-11 | 1978-07-11 | Verfahren zur herstellung stippenfreier kautschuklatices mit hoher oberflaechenspannung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES482364A1 true ES482364A1 (es) | 1980-08-16 |
Family
ID=6044068
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES482364A Expired ES482364A1 (es) | 1978-07-11 | 1979-07-10 | Procedimiento para la obtencion de latex de caucho carboxi- lado. |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0007044B1 (es) |
JP (1) | JPS5512197A (es) |
BR (1) | BR7904381A (es) |
CA (1) | CA1137672A (es) |
DE (2) | DE2830393A1 (es) |
ES (1) | ES482364A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3010429A1 (de) * | 1980-03-19 | 1981-09-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von synthesekautschuklatices, deren verwedung als haftklebstoffrohstoff bei der herstellung von haftklebemassen sowie haftklebemassen |
DE3047084A1 (de) * | 1980-12-13 | 1982-07-22 | Bayer Ag, 5090 Leverkusen | Carboxylgruppen enthaltende synthesekautschukdispersionen, verfahren zu ihrer herstellung und ihre verwendung |
US4450261A (en) * | 1983-02-22 | 1984-05-22 | National Starch And Chemical Corporation | Preparation of low molecular weight styrene-maleic anhydride copolymers and sulfonated copolymers thereof |
US4661571A (en) * | 1984-10-02 | 1987-04-28 | Sumitomo Chemical Company, Limited | Process for the production of heat resistant methacrylic resin |
US4593081A (en) * | 1985-04-25 | 1986-06-03 | Phillips Petroleum Company | Chain-transfer agents for emulsion polymerization and polymer products produced therewith |
JPH0541936U (ja) * | 1991-11-06 | 1993-06-08 | 曙ブレーキ工業株式会社 | 自動車のアクセル操作ケーブルの移動検知装置 |
CN1062773C (zh) * | 1998-04-16 | 2001-03-07 | 中国纺织大学 | 一种聚酯类可吸收医用缝合线的制造方法 |
DE19929008A1 (de) | 1999-06-24 | 2001-01-11 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellung von in Wasser redispergierbaren Vinylaromat-Mischpolymerisat- Redispersionspulvern |
JP5825819B2 (ja) * | 2011-04-13 | 2015-12-02 | 住友ゴム工業株式会社 | ジエン系重合体及びその製造方法 |
EP3993393B1 (en) | 2019-07-24 | 2023-09-06 | Sony Group Corporation | Image capturing device and image capturing method |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2380905A (en) * | 1942-04-28 | 1945-07-31 | Goodrich Co B F | Polymerization of butadiene-1, 3 hydrocarbons |
DE1814209C3 (de) * | 1968-12-12 | 1974-08-01 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zum Herstellen wäßriger, carboxylgruppenhaltiger Synthesekautschuk Dispersionen mit hoher Oberflächenspannung |
-
1978
- 1978-07-11 DE DE19782830393 patent/DE2830393A1/de not_active Withdrawn
-
1979
- 1979-06-29 EP EP79102179A patent/EP0007044B1/de not_active Expired
- 1979-06-29 DE DE7979102179T patent/DE2963577D1/de not_active Expired
- 1979-07-09 JP JP8602579A patent/JPS5512197A/ja active Granted
- 1979-07-09 CA CA000331434A patent/CA1137672A/en not_active Expired
- 1979-07-10 ES ES482364A patent/ES482364A1/es not_active Expired
- 1979-07-10 BR BR7904381A patent/BR7904381A/pt unknown
Also Published As
Publication number | Publication date |
---|---|
CA1137672A (en) | 1982-12-14 |
EP0007044A1 (de) | 1980-01-23 |
DE2830393A1 (de) | 1980-01-24 |
EP0007044B1 (de) | 1982-08-25 |
DE2963577D1 (en) | 1982-10-21 |
JPS638129B2 (es) | 1988-02-20 |
BR7904381A (pt) | 1980-03-25 |
JPS5512197A (en) | 1980-01-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3498942A (en) | Emulsion polymerization of unsaturated monomers utilizing alkyl sulfide terminated oligomers as emulsifiers and resulting product | |
JPS5655414A (en) | Polymer particle | |
ES482364A1 (es) | Procedimiento para la obtencion de latex de caucho carboxi- lado. | |
GB1263807A (en) | Aqueous emulsion polymerization process | |
US3403122A (en) | Emulsion polymerization of water insoluble omega-(n-perfluoroalkanesulfonyl) aminoalkyl acrylates or methacrylates | |
US2375140A (en) | Emulsion polymerization of butadiene-1,3 hydrocarbons | |
ES8307011A1 (es) | Procedimiento para la obtencion de latex de caucho de nitrilo. | |
US2847404A (en) | High stability latices | |
US3923763A (en) | Novel sulfur compound modifiers for chloroprene polymerization | |
US3055855A (en) | Process for emulsion polymerization of butadiene-unsaturated carboxylic acid copolymers and product thereof | |
US2880186A (en) | Compositions containing natural rubber and a carboxyl-containing diene polymer, a film thereof, and method of making same | |
CA1183625A (en) | Synthetic rubber dispersions containing carboxyl groups, a process for their preparation and their use | |
US2393133A (en) | Manufacture of synthetic rubber latices | |
GB865863A (en) | Stable emulsifier-free latices and method of preparation thereof | |
GB1523387A (en) | Composition for us in polymerization reactors | |
US2616875A (en) | Shortstopping of butadiene-1,3 emulsion polymerization | |
GB1380713A (en) | Graft copolymer preparation | |
US2398321A (en) | Copolymers of diolefinic compounds | |
GB1490804A (en) | Process for producing a latex of chloroprene polymer | |
US3836497A (en) | Process for the production of high surface tension speck-free,heat-polymerized synthetic resin dispersions | |
US3740368A (en) | Polymerisation process | |
ES209776A1 (es) | UN PROCEDIMIENTO PARA LA OBTENCIoN DE PINTURAS ACUOSAS DE CONTENIDO POLiMERO Y RESISTENTES A LA CONGELACIoN | |
US2600679A (en) | Process for copolymerizing conjugated dienes with unsaturated nitriles in aqueous emulsion | |
US2684356A (en) | Synthetic rubber and preparation thereof | |
ES8304165A1 (es) | Procedimiento para la obtencion de dispersiones de caucho sintetico termosensibilizables. |