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ES460830A1 - Un procedimiento para etilar tolueno o etilbenceno. - Google Patents

Un procedimiento para etilar tolueno o etilbenceno.

Info

Publication number
ES460830A1
ES460830A1 ES460830A ES460830A ES460830A1 ES 460830 A1 ES460830 A1 ES 460830A1 ES 460830 A ES460830 A ES 460830A ES 460830 A ES460830 A ES 460830A ES 460830 A1 ES460830 A1 ES 460830A1
Authority
ES
Spain
Prior art keywords
para
mono alkyl
zeolite
alkyl benzene
xylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES460830A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of ES460830A1 publication Critical patent/ES460830A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/868—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains sulfur as hetero-atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento para etilar tolueno o etilbenceno, que comprende poner en contacto el mismo, en condiciones de conversión, con un agente de etilación en presencia de un catalizador que comprende una zeolita de aluminosilicato cristalino, caracterizándose dicha zeolita por una actividad, en términos del valor alfa, entre 2 y 5000, una capacidad de porción de xileno mayor de 1 g/100 g de zeolita y un tiempo de porción de orto-xileno para 30% de dicha capacidad mayor de 10 minutos, midiéndose dicha capacidad de porción y dicho tiempo de porción a 120ºC y una presión de xileno de 4,5 más menos 0,8 mm de mercurio, teniendo dicha zeolita de aluminosilicato cristalino una relación de sílice a alúmina de al menos 12 y un índice de restricción dentro del intervalo aproximado de 1 a 12.
ES460830A 1976-07-19 1977-07-16 Un procedimiento para etilar tolueno o etilbenceno. Expired ES460830A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/706,981 US4086287A (en) 1976-07-19 1976-07-19 Selective ethylation of mono alkyl benzenes

Publications (1)

Publication Number Publication Date
ES460830A1 true ES460830A1 (es) 1978-04-16

Family

ID=24839877

Family Applications (1)

Application Number Title Priority Date Filing Date
ES460830A Expired ES460830A1 (es) 1976-07-19 1977-07-16 Un procedimiento para etilar tolueno o etilbenceno.

Country Status (17)

Country Link
US (2) US4086287A (es)
JP (1) JPS5312816A (es)
AR (1) AR218259A1 (es)
BE (1) BE856820A (es)
CA (1) CA1084532A (es)
CS (1) CS199682B2 (es)
DD (1) DD132778A5 (es)
DE (1) DE2730989A1 (es)
ES (1) ES460830A1 (es)
FR (1) FR2359104A1 (es)
GB (1) GB1536828A (es)
IN (1) IN146056B (es)
IT (1) IT1085095B (es)
MX (1) MX5122E (es)
NL (1) NL7707999A (es)
PL (2) PL199748A1 (es)
ZA (1) ZA774347B (es)

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US4117024A (en) * 1977-07-29 1978-09-26 Mobil Oil Corporation Ethylation of aromatic compounds
US4250345A (en) * 1978-01-10 1981-02-10 Mobil Oil Corporation Selective production of para-xylene
US4176144A (en) * 1978-01-19 1979-11-27 Mobil Oil Corporation Block copolymers
US4306049A (en) * 1978-01-19 1981-12-15 Mobil Oil Corporation Polymers of methyl ethenyl benzene
US4205114A (en) 1978-09-18 1980-05-27 Mobil Oil Corporation Heat and grease resistant containers comprising poly (p-methylstyrene)
CA1135286A (en) * 1978-12-14 1982-11-09 Mobil Oil Corporation Alkylation of aromatic hydrocarbons
US4822943A (en) * 1978-12-14 1989-04-18 Mobil Oil Corporation Production of para-diisopropylbenzene
CA1128549A (en) * 1978-12-14 1982-07-27 Lewis B. Young Production of 3-methylphenol
US4281083A (en) * 1978-12-20 1981-07-28 Mobil Oil Corporation Blends of poly(p-methylstyrene) with polyfunctional monomer
AU538578B2 (en) * 1979-01-31 1984-08-23 Mobil Oil Corp. Zeolite catalyst containing gp za or gp8 metal and its use to convert hydrocarbons
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US4230836A (en) * 1979-04-26 1980-10-28 Mobil Oil Corporation Chemically cross-linked poly(p-methylstyrene)
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US4584422A (en) * 1979-06-06 1986-04-22 Mobil Oil Corporation Selective alkylation of xylenes with ethylene
US5288396A (en) * 1979-10-15 1994-02-22 Union Oil Company Of California Hydrocracking process using a catalyst selective for making middle distillates
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US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
US4384155A (en) * 1980-04-11 1983-05-17 Mobil Oil Corporation Shape selective reactions with cadmium-modified zeolite catalysts
US4380685A (en) * 1980-05-19 1983-04-19 Mobil Oil Corporation Shape selective reactions with zeolite catalysts modified with iron and/or cobalt
US4335181A (en) * 1980-07-01 1982-06-15 Mobil Oil Corporation Microwaveable heat and grease resistant containers
US4387012A (en) * 1980-08-01 1983-06-07 Mobil Oil Corporation Blends of poly(p-methylstyrene) with polyfunctional monomer and shaped article
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US4554394A (en) * 1982-03-18 1985-11-19 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
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US4505961A (en) * 1982-04-30 1985-03-19 Mobil Oil Corporation Microwavable heat and grease resistant containers and method for their preparation
US4508836A (en) * 1982-07-27 1985-04-02 Mobil Oil Corporation Catalytic conversion process for aromatic feedstocks with hydrogen regeneration of coke-selectivated zeolite catalyst
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DE3361440D1 (en) * 1982-12-30 1986-01-16 Asahi Chemical Ind A crystalline aluminosilicate, a process for producing the same, and a catalyst comprising the crystalline aluminosilicate
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US4560818A (en) * 1984-12-24 1985-12-24 Mobil Oil Corporation Process for the oxidative dehydrogenation of ethyltoluene to methylstyrene
US4812536A (en) * 1986-08-29 1989-03-14 Amoco Corporation Selective para-ethylation of toluene with magnesium compound-impregnated, crystalline, gallosilicate based, molecular sieve catalyst compositions
US5157185A (en) * 1989-09-01 1992-10-20 Mobil Oil Corporation Alkylation of aromatics
JPH07507562A (ja) * 1992-06-05 1995-08-24 モービル・オイル・コーポレーション エチルトルエンの製造
KR100290970B1 (ko) * 1992-06-05 2001-06-01 데니스 피. 산티니 에틸톨루엔의 제조 방법
US5659098A (en) * 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
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US5698756A (en) * 1993-05-28 1997-12-16 Mobil Oil Corporation Toluene alkylation with ethylene to produce para-ethyloluene
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CN1761522A (zh) * 2003-03-21 2006-04-19 斯通&维布斯特公司 带有催化剂再活化的烷基芳香族化合物的生产
CN1902147B (zh) * 2003-12-31 2010-08-25 埃克森美孚化学专利公司 芳族化合物的烷基化方法
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Also Published As

Publication number Publication date
NL7707999A (nl) 1978-01-23
DD132778A5 (de) 1978-11-01
JPS5312816A (en) 1978-02-04
BE856820A (fr) 1978-01-16
MX5122E (es) 1983-03-24
US4086287A (en) 1978-04-25
AR218259A1 (es) 1980-05-30
FR2359104B1 (es) 1983-09-16
ZA774347B (en) 1979-02-28
CS199682B2 (en) 1980-07-31
JPS615454B2 (es) 1986-02-18
IN146056B (es) 1979-02-10
DE2730989A1 (de) 1978-02-02
CA1084532A (en) 1980-08-26
IT1085095B (it) 1985-05-28
GB1536828A (en) 1978-12-20
PL108320B1 (en) 1980-04-30
US4094921A (en) 1978-06-13
PL199748A1 (pl) 1978-04-24
FR2359104A1 (fr) 1978-02-17

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19971201