ES2387430B1 - STONE PROTECTOR - Google Patents
STONE PROTECTOR Download PDFInfo
- Publication number
- ES2387430B1 ES2387430B1 ES201130251A ES201130251A ES2387430B1 ES 2387430 B1 ES2387430 B1 ES 2387430B1 ES 201130251 A ES201130251 A ES 201130251A ES 201130251 A ES201130251 A ES 201130251A ES 2387430 B1 ES2387430 B1 ES 2387430B1
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- Spain
- Prior art keywords
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn - After Issue
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- 239000004575 stone Substances 0.000 title claims abstract description 18
- 230000001012 protector Effects 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 9
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims abstract description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 7
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 16
- 239000010438 granite Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000004579 marble Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 239000000443 aerosol Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims 4
- 241001331901 Mediterranea Species 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 2
- 229960000943 tartrazine Drugs 0.000 description 2
- 235000012756 tartrazine Nutrition 0.000 description 2
- 239000004149 tartrazine Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/463—Organic solvents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4838—Halogenated polymers
- C04B41/4842—Fluorine-containing polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
La presente invención se refiere a una composición que comprende: 5-25% en peso de acetato de butilo, 1-20% en peso de copolímero fluorado acrilato, 20-60% en peso de N-octiltrietoxi-silano, 30-50% en peso de disolvente y al uso de la misma para el tratamiento y/o protección de superficies pétreas.The present invention relates to a composition comprising: 5-25% by weight of butyl acetate, 1-20% by weight of fluorinated acrylate copolymer, 20-60% by weight of N-octyltriethoxy silane, 30-50% by weight of solvent and its use for the treatment and / or protection of stone surfaces.
Description
Protector de piedra. Stone protector.
La presente invención se refiera a una composición química y a su uso como protector de superficies de piedra y en particular como protector de granito. The present invention relates to a chemical composition and its use as a protector of stone surfaces and in particular as a granite protector.
Actualmente existen distintos tipos de composiciones para proteger las superficies de piedra y en concreto las superficies de granito. Currently there are different types of compositions to protect stone surfaces and specifically granite surfaces.
La mayoría de los productos existentes en el mercado son hidrófugos y oleófugo, sin embargo presentan problemas de penetrabilidad o alteran las características de la piedra. Most of the products on the market are water repellent and oleophobic, however they have penetrability problems or alter the characteristics of the stone.
Existe pues la necesidad de proporcionar un producto protector de superficies de piedra y en concreto de granitos que sean hidrófugo, oleófugo, con un alto grado de penetración y durabilidad sin que afecte a las propiedades tales como el color o el tono de la superficie a tratar. There is therefore a need to provide a protective product of stone surfaces and in particular of granites that are water-repellent, oleophobic, with a high degree of penetration and durability without affecting properties such as the color or tone of the surface to be treated. .
Así pues, en un primer aspecto, la presente invención se refiere a una composición que comprende: Thus, in a first aspect, the present invention relates to a composition comprising:
-5-25% en peso de acetato de butilo -5-25% by weight of butyl acetate
-1-20% en peso de copolimero fluorado acrilato -1-20% by weight of fluorinated acrylate copolymer
-20-60% en peso de N-octiltrietoxi-silano -20-60% by weight of N-octyltriethoxy silane
-30-50% en peso de disolvente -30-50% by weight of solvent
En la presente invención cuando nos referimos a copolimero fluorado acrilato, nos referimos a cualquier copolimero fluorado acrilato de 6 a 4 átomos de carbono y con base solvente. En un aspecto más en particular de la presente el disolvente es una mezcla de etanol e isopropanol. En un aspecto más In the present invention when we refer to fluorinated acrylate copolymer, we refer to any fluorinated acrylate copolymer of 6 to 4 carbon atoms and solvent based. In a more particular aspect of the present the solvent is a mixture of ethanol and isopropanol. In one more aspect
en particular, la mezcla de etanol/isopropanol está en una relación 80/20. En otro aspecto más en particular la composición de la presente invención comprende: in particular, the ethanol / isopropanol mixture is in an 80/20 ratio. In another aspect in particular the composition of the present invention comprises:
- --
- 10% en peso de acetato de butilo 10% by weight of butyl acetate
- --
- 10% en peso de copolimero fluorado acrilato 10% by weight of fluorinated acrylate copolymer
- --
- 40% en peso de N-octiltrietoxi-silano 40% by weight of N-octyltriethoxy silane
- --
- 40% en peso de etanol/isopropanol En otro aspecto más en particular la composición de la presente invención comprende: 40% by weight of ethanol / isopropanol In yet another aspect in particular the composition of the present invention comprises:
-14% en peso de acetato de butilo -14% by weight of butyl acetate
-6% en peso de copolimero fluorado acrilato -6% by weight of fluorinated acrylate copolymer
-40% en peso de N-octiltrietoxi-silano -40% by weight of N-octyltriethoxy silane
- --
- 40% en peso de etanol/isopropanol En un aspecto más en particular de la presente invención, la composición es para la protección de superficies pétreas. En un aspecto más en particular de la presente invención, las superficies pétreas son seleccionadas entre granito, 40% by weight of ethanol / isopropanol In a more particular aspect of the present invention, the composition is for the protection of stone surfaces. In a more particular aspect of the present invention, stone surfaces are selected from granite,
mármol, sílice, cuarzo y/o cristal. En un aspecto más en particular, la composición de la presente invención, está en forma líquida. En otro aspecto más en particular, la composición de la presente invención está en forma de aerosol. En otro aspecto más en particular, la composición de la presente invención está en forma de gel. marble, silica, quartz and / or crystal. In a more particular aspect, the composition of the present invention is in liquid form. In another aspect in particular, the composition of the present invention is in aerosol form. In another aspect in particular, the composition of the present invention is in gel form.
En un segundo aspecto, la presente invención se refiere al uso de la composición de la presente invención, tal y como se ha descrito anteriormente, para el tratamiento y/o protección de superficies pétreas. Más en particular, las superficies pétreas son seleccionadas entre granito, mármol, sílice, cuarzo y/o cristal. In a second aspect, the present invention relates to the use of the composition of the present invention, as described above, for the treatment and / or protection of stone surfaces. More particularly, the stone surfaces are selected from granite, marble, silica, quartz and / or crystal.
Ejemplo 1: Composiciones de la presente invención Example 1: Compositions of the present invention
- FORMULA 1 FORMULA 1
- COMPUESTO COMPOUND
- % en peso % in weigh
- Acetato de butilo Acetate of butilo
- 14 14
- Copolimero fluorado acrilato Acrylate fluorinated copolymer
- 6 6
- Etanol/IPA (80/40) Ethanol / IPA (80/40)
- 40 40
- N-octiltrietoxi-silanoN-octyltriethoxy silane
- 40 40
- FÓRMULA 2 FORMULA 2
- COMPUESTO COMPOUND
- % en peso % in weigh
- Acetato de butilo Acetate of butilo
- 10 10
- Copolimero fluorado acrilato Acrylate fluorinated copolymer
- 10 10
- Etanol/IPA (80/40) Ethanol / IPA (80/40)
- 40 40
- N-octiltrietoxi-silanoN-octyltriethoxy silane
- 40 40
Ejemplo 2: Ensayo de penetrabilidad Example 2: Penetrability Test
Se preparó una disolución de tartrazina, a continuación seccionamos las piezas tratadas con las fórmulas A, 1 y 2 y las A solution of tartrazine was prepared, then we sectioned the pieces treated with formulas A, 1 and 2 and the
10 introducimos en el baño de tartrazina sin que dicha disolución cubriera por completo la pieza, con un contacto fue suficiente, con la cara tratada de la pieza hacia arriba. 10 we introduced into the tartrazine bath without said solution completely covering the piece, with sufficient contact, with the treated side of the piece facing up.
Se estableció un índice de penetrabilidad de 1 a 5 en orden creciente, donde asignamos penetrabilidad máxima 5 a la proporcionada por el producto comercial SENGUARD y penetrabilidad mínima 1 a la proporcionada por el producto comercial PROTECTOR MG. A penetrability index of 1 to 5 was established in increasing order, where we assign maximum penetrability 5 to that provided by the commercial product SENGUARD and minimum penetrability 1 to that provided by the commercial product PROTECTOR MG.
15 SENGUARD PROTECTOR MG 15 SENGUARD PROTECTOR MG
PENETRACIÓN PENETRATION
- FÓRMULA A FORMULA A
- COMPUESTO COMPOUND
- % en peso % in weigh
- PropiltrietoxisilanoPropyltriethoxysilane
- 40 40
- Etano/IPA Ethane / IPA
- 40 40
- Copolímero fluorado ref.25 Fluorinated copolymer ref. 25
- 10 10
- Acetato de butilo Acetate of butilo
- 10 10
TABLA DE PENETRABILIDAD: PENETRABILITY TABLE:
- Granito blanco White granite
- Granito Amarillo Granito rojo Granito verde Yellow granite Red granite Green granite
- FÓRMULA A FORMULA A
- 3 3 3 3 3 3 3 3
- FÓRMULA 1 FORMULA 1
- 5 4 4 5 5 4 4 5
- FÓRMULA 2 FORMULA 2
- 4 4 5 4 4 4 5 4
Una vez comprobada la penetrabilidad de las fórmulas 1 y 2, pasamos a determinar el carácter hidro y olefugante manchando la superficie de cuatro granitos distintos con agua, aceite a temperatura ambiente y caliente. Once the penetrability of formulas 1 and 2 has been verified, we will determine the hydro and olefugant character by staining the surface of four different granites with water, oil at room temperature and hot.
Se estableció un índice del 1 al 10 en orden creciente de resistencia a manchas, para determinar el comportamiento de la superficie frente a las mismas, tras un periodo de 2 días se revisó el comportamiento de las piezas. An index from 1 to 10 was established in increasing order of resistance to stains, to determine the behavior of the surface against them, after a period of 2 days the behavior of the pieces was reviewed.
Tabla de resultados:Results table:
- GRANITOGRANITE
- AGUA ACEITE ACEITE CALIENTE WATER OIL HOT OIL
- Muestra 1 blanco Sample 1 blank
- FÓRMULA 1 FORMULA 1
- 10 10 10 10 10 10
- FÓRMULA 2 FORMULA 2
- 10 10 10 10 10 10
- SENGUARDSENGUARD
- 10 10 10 10 10 10
- Muestra 2 Amarilla Sample 2 Yellow
- FÓRMULA 1 FORMULA 1
- 10 9 9 10 9 9
- FÓRMULA 2 FORMULA 2
- 10 8 8 10 8 8
- SENDGUARDSENDGUARD
- 10 10 10 10 10 10
- Muestra 3 Rojo Sample 3 Red
- FÓRMULA 1 FORMULA 1
- 10 9 9 10 9 9
- FÓRMULA 2 FORMULA 2
- 10 9 9 10 9 9
- SENDGUARDSENDGUARD
- 10 8 9 10 8 9
- Muestra 4 Verde Sample 4 Green
- FÓRMULA 1 FORMULA 1
- 10 10 10 10 10 10
- FÓRMULA 2 FORMULA 2
- 10 9 9 10 9 9
- SENGUARDSENGUARD
- 10 10 10 10 10 10
Claims (9)
- 2.2.
- Composición según la reivindicación 1, donde el disolvente es una mezcla de etanol e isopropanol. Composition according to claim 1, wherein the solvent is a mixture of ethanol and isopropanol.
- 3.3.
- Composición según la reivindicación 2, donde la mezcla de etanol/isopropanol está en una relación 80/20. Composition according to claim 2, wherein the ethanol / isopropanol mixture is in an 80/20 ratio.
- 4.Four.
- Composición según cualquiera de las reivindicaciones anteriores para la protección de superficies pétreas. Composition according to any of the preceding claims for the protection of stone surfaces.
- 10 5. Composición según la reivindicación 4, donde las superficies pétreas son seleccionadas entre granito, mármol, sílice, cuarzo y/o cristal. Composition according to claim 4, wherein the stone surfaces are selected from granite, marble, silica, quartz and / or crystal.
- 6.6.
- Composición según cualquiera de las reivindicaciones anteriores caracterizada por que está en forma líquida. Composition according to any of the preceding claims characterized in that it is in liquid form.
- 7.7.
- Composición según cualquiera de las reivindicaciones anteriores caracterizada por que está en forma de aerosol. Composition according to any of the preceding claims characterized in that it is in the form of an aerosol.
- 8.8.
- Composición según cualquiera de las reivindicaciones 1-5, caracterizada por que está en forma de gel. Composition according to any of claims 1-5, characterized in that it is in the form of a gel.
- 15 9. Uso de una composición según cualquiera de las reivindicaciones 1-8, para el tratamiento y/o protección de superficies pétreas. Use of a composition according to any of claims 1-8, for the treatment and / or protection of stone surfaces.
- Categoría Category
- 56 Documentos citados Reivindicaciones afectadas 56 Documents cited Claims Affected
- X X
- WO 2007127267 A2 (DOW CORNING ET AL.) 08/11/2007, Ejemplo 23, Tabla 24; página 12, línea 28-página 13, línea 10. 1-10 WO 2007127267 A2 (DOW CORNING ET AL.) 08/11/2007, Example 23, Table 24; page 12, line 28-page 13, line 10. 1-10
- A TO
- WO 2006092450 A1 (MEDITERRANEA DE INVESTIGACION ET AL.) 08/09/2006, Ejemplo 1. 1-10 WO 2006092450 A1 (MEDITERRANEA DE INVESTIGACION ET AL.) 08/09/2006, Example 1. 1-10
- A TO
- EP 2154164 A1 (DAIKIN IND LTD) 17/02/2010, párrafos [0010], [0034], [0037],[0038],[0041],[0045]; Ejemplos. 1-10 EP 2154164 A1 (DAIKIN IND LTD) 02/17/2010, paragraphs [0010], [0034], [0037], [0038], [0041], [0045]; Examples 1-10
- A TO
- US 5990212 A (WACKER-CHEMIE GMBH ET AL.) 23/11/1999, columna 1, líneas 5-11; columna 2, líneas 1-12; Ejemplos. 1-10 US 5990212 A (WACKER-CHEMIE GMBH ET AL.) 11/23/1999, column 1, lines 5-11; column 2, lines 1-12; Examples 1-10
- Categoría de los documentos citados X: de particular relevancia Y: de particular relevancia combinado con otro/s de la misma categoría A: refleja el estado de la técnica O: referido a divulgación no escrita P: publicado entre la fecha de prioridad y la de presentación de la solicitud E: documento anterior, pero publicado después de la fecha de presentación de la solicitud Category of the documents cited X: of particular relevance Y: of particular relevance combined with other / s of the same category A: reflects the state of the art O: refers to unwritten disclosure P: published between the priority date and the date of priority submission of the application E: previous document, but published after the date of submission of the application
- El presente informe ha sido realizado • para todas las reivindicaciones • para las reivindicaciones nº: This report has been prepared • for all claims • for claims no:
- Fecha de realización del informe 24.07.2012 Date of realization of the report 24.07.2012
- Examinador M. C. Bautista Sanz Página 1/4 Examiner M. C. Bautista Sanz Page 1/4
- Novedad (Art. 6.1 LP 11/1986) Novelty (Art. 6.1 LP 11/1986)
- Reivindicaciones 2, 3 Reivindicaciones 1, 4-10 SI NO Claims 2, 3 Claims 1, 4-10 IF NOT
- Actividad inventiva (Art. 8.1 LP11/1986) Inventive activity (Art. 8.1 LP11 / 1986)
- Reivindicaciones Reivindicaciones 1-10 SI NO Claims Claims 1-10 IF NOT
- Documento Document
- Número Publicación o Identificación Fecha Publicación Publication or Identification Number publication date
- D01 D01
- WO 2007127267 A2 (DOW CORNING et al.) 08.11.2007 WO 2007127267 A2 (DOW CORNING et al.) 08.11.2007
- D02 D02
- WO 2006092450 A1 (MEDITERRANEA DE INVESTIGACION et al.) 08.09.2006 WO 2006092450 A1 (MEDITERRANEA DE INVESTIGACION et al.) 08.09.2006
- D03 D03
- EP 2154164 A1 (DAIKIN IND LTD) 17.02.2010 EP 2154164 A1 (DAIKIN IND LTD) 02.17.2010
- D04 D04
- US 5990212 A (WACKER-CHEMIE GMBH et al.) 23.11.1999 US 5990212 A (WACKER-CHEMIE GMBH et al.) 11/23/1999
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201130251A ES2387430B1 (en) | 2011-02-25 | 2011-02-25 | STONE PROTECTOR |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201130251A ES2387430B1 (en) | 2011-02-25 | 2011-02-25 | STONE PROTECTOR |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2387430A1 ES2387430A1 (en) | 2012-09-21 |
| ES2387430B1 true ES2387430B1 (en) | 2013-08-02 |
Family
ID=46766558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES201130251A Withdrawn - After Issue ES2387430B1 (en) | 2011-02-25 | 2011-02-25 | STONE PROTECTOR |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2387430B1 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19634500A1 (en) * | 1996-08-26 | 1998-03-05 | Wacker Chemie Gmbh | Compositions for the water and oil repellent treatment of absorbent materials |
| WO2006092450A1 (en) * | 2005-02-25 | 2006-09-08 | Mediterranea De Investigacion Cientifica, S.L. | Acrylate-based polymeric composition for coating architectural surfaces, which has been improved with the inclusion of suitable solvents |
| WO2007127267A2 (en) * | 2006-04-27 | 2007-11-08 | Dow Corning Corporation | Composition for treating masonry |
| US20100227173A1 (en) * | 2007-05-15 | 2010-09-09 | Daikin Industries, Ltd. | Water-repellent oil-repellent antifouling agent having good solubility in solvent |
-
2011
- 2011-02-25 ES ES201130251A patent/ES2387430B1/en not_active Withdrawn - After Issue
Also Published As
| Publication number | Publication date |
|---|---|
| ES2387430A1 (en) | 2012-09-21 |
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