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ES2105507T3 - Mezcla de polimeros en emulsion. - Google Patents

Mezcla de polimeros en emulsion.

Info

Publication number
ES2105507T3
ES2105507T3 ES94301173T ES94301173T ES2105507T3 ES 2105507 T3 ES2105507 T3 ES 2105507T3 ES 94301173 T ES94301173 T ES 94301173T ES 94301173 T ES94301173 T ES 94301173T ES 2105507 T3 ES2105507 T3 ES 2105507T3
Authority
ES
Spain
Prior art keywords
latex
mixture
emulsion polymers
amts
stage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94301173T
Other languages
English (en)
Inventor
Barry Samuel Snyder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=21816471&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2105507(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of ES2105507T3 publication Critical patent/ES2105507T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)
  • Glass Compositions (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Polymerisation Methods In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Materials For Medical Uses (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Sealing Material Composition (AREA)

Abstract

ESTA INVENCION SE REFIERE A UNA MEZCLA DE POLIMEROS EN EMULSION QUE CONTIENE DE UN 95 A UN 40 POR CIENTO EN PESO, PREFERENTEMENTE DE UN 90 A UN 60 POR CIENTO EN PESO, DE AL MENOS UN PRIMER LATEX DE MULTIPLES ETAPAS QUE CONTIENE DE UN 95 A UN 50 POR CIENTO EN PESO, PREFERENTEMENTE DE UN 75 A UN 60 POR CIENTO EN PESO, DE AL MENOS UN POLIMERO DE ETAPA BLANDA QUE TIENE UNA TG INFERIOR A 50 (GRADOS) C, PREFERENTEMENTE INFERIOR A 10 (GRADOS) C, Y DE UN 5 AUN 50 POR CIENTO EN PESO, PREFERENTEMENTE DE UN 25 A UN 40 POR CIENTO EN PESO, DE AL MENOS UN POLIMERO DE ETAPA DURA QUE TIENE UNA TG DE 20 (GRADOS) C A 160 (GRADOS) C, SIENDO LA TG DEL POLIMERO DE ETAPA BLANDA INFERIOR A LA DEL POLIMERO DE ETAPA DURA Y QUE SE CARACTERIZA PORQUE HAY DE UN 5 A UN 60 POR CIENTO EN PESO, PREFERENTEMENTE DE UN 10 A UN 40 POR CIENTO EN PESO, DE AL MENOS UN SEGUNDO LATEX EL CUAL NO FORMA UNA PELICULA A TEMPERATURA AMBIENTE. LA MEZCLA DE POLIMEROS EN EMULSION DE ESTA INVENCION SE PUEDE UTILIZA COMO FORMULA PARA UNA VARIEDAD DE COMPOSICIONES DE REVESTIMIENTO ACUOSAS, TALES COMO, POR EJEMPLO, PINTURAS, MASTIQUES, MASILLA DE CALAFATO, ADHESIVOS, BARNICES, CERAS PARA SUELOS Y SIMILARES. LA MEZCLA DE POLIMEROS EN EMULSION DE ESTA INVENCION TAMBIEN ES UTIL PARA LA FORMULACION DE UNA COMPOSICION DE REVESTIMIENTO ACUOSA SIN COALESCENTES.
ES94301173T 1993-02-26 1994-02-18 Mezcla de polimeros en emulsion. Expired - Lifetime ES2105507T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/023,658 US5308890A (en) 1993-02-26 1993-02-26 Emulsion polymer blend of a multi-stage latex and a non-film forming latex

Publications (1)

Publication Number Publication Date
ES2105507T3 true ES2105507T3 (es) 1997-10-16

Family

ID=21816471

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94301173T Expired - Lifetime ES2105507T3 (es) 1993-02-26 1994-02-18 Mezcla de polimeros en emulsion.

Country Status (25)

Country Link
US (2) US5308890A (es)
EP (1) EP0612805B1 (es)
JP (1) JPH0741683A (es)
CN (1) CN1041102C (es)
AT (1) ATE155803T1 (es)
AU (1) AU666245B2 (es)
BR (1) BR9400672A (es)
CA (1) CA2114711A1 (es)
CZ (1) CZ42594A3 (es)
DE (1) DE69404336T2 (es)
ES (1) ES2105507T3 (es)
FI (1) FI940897A (es)
HK (1) HK1000305A1 (es)
HU (1) HU9400564D0 (es)
IL (1) IL108684A (es)
LV (1) LV10785B (es)
MY (1) MY110846A (es)
NO (1) NO940555L (es)
NZ (1) NZ250932A (es)
PH (1) PH29939A (es)
PL (1) PL302395A1 (es)
RU (1) RU2134279C1 (es)
SG (1) SG45317A1 (es)
TW (1) TW308603B (es)
ZA (1) ZA941117B (es)

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US5308890A (en) 1994-05-03
CA2114711A1 (en) 1994-08-27
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NO940555D0 (no) 1994-02-18
CN1041102C (zh) 1998-12-09
PH29939A (en) 1996-09-16
AU666245B2 (en) 1996-02-01
CN1095084A (zh) 1994-11-16
EP0612805A2 (en) 1994-08-31
MY110846A (en) 1999-05-31
DE69404336T2 (de) 1998-01-08
AU5526994A (en) 1994-09-01
JPH0741683A (ja) 1995-02-10
ATE155803T1 (de) 1997-08-15
FI940897A0 (fi) 1994-02-25
IL108684A0 (en) 1994-05-30
LV10785B (en) 1996-06-20
TW308603B (es) 1997-06-21
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HU9400564D0 (en) 1994-05-30
US5344675A (en) 1994-09-06
EP0612805B1 (en) 1997-07-23
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EP0612805A3 (en) 1995-06-28
ZA941117B (en) 1994-08-26
BR9400672A (pt) 1994-11-01
LV10785A (lv) 1995-08-20
RU2134279C1 (ru) 1999-08-10
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CZ42594A3 (en) 1994-10-19
HK1000305A1 (en) 1998-02-20
FI940897A (fi) 1994-08-27
IL108684A (en) 1997-09-30
SG45317A1 (en) 1998-01-16

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