ES2039637T3 - Membranas de poliurea/uretano con elevado contenido de compuestos aromaticos y su uso para separar compuestos aromaticos de compuestos no aromaticos. - Google Patents
Membranas de poliurea/uretano con elevado contenido de compuestos aromaticos y su uso para separar compuestos aromaticos de compuestos no aromaticos.Info
- Publication number
- ES2039637T3 ES2039637T3 ES198888309631T ES88309631T ES2039637T3 ES 2039637 T3 ES2039637 T3 ES 2039637T3 ES 198888309631 T ES198888309631 T ES 198888309631T ES 88309631 T ES88309631 T ES 88309631T ES 2039637 T3 ES2039637 T3 ES 2039637T3
- Authority
- ES
- Spain
- Prior art keywords
- aromatic compounds
- polyurea
- membranes
- aromatics
- urethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/11—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by dialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/54—Polyureas; Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
MEMBRANAS NUEVAS, UTILES PARA LA SEPARACION DE AROMATICOS DE SUS MEZCLAS CON NO AROMATICOS EN, POR EJEMPLO, UNA CORRIENTE DE ALIMENTACION DE NAFTA, SE CARACTERIZA POR POSEER UN INDICE DE UREA DE APROXIMADAMENTE 20 % POR LO MENOS, PERO MENOS QUE 100 %, UN CONTENIDO EN CARBONO AROMATICO DE 15 % EN MOLES APROXIMADAMENTE POR LO MENOS, UNA CONCENTRACION DE GRUPOS FUNCIONALES POR LO MENOS 10 POR 100 G DE POLIMERO Y UNA RELACION C=O/NH MENOR QUE 8,0. ESTAS MEMBRANAS DE POLIUREA/URETANO MUY AROMATICAS SON MEMBRANAS DE PELICULA DENSA, SIMETRICAS, HECHAS DE LOS CORRESPONDIENTES POLIMEROS DE POLIUREA/URETANO POR TECNICAS DE FUNDICION DE MEMBRANAS PATRON. LOS COPOLIMEROS DE POLIUREA/URETANO PREFERIBLEMENTE SE PRODUCEN POR REACCION DE COMPUESTOS DIHIDROXI Y POLIHIDROXI, TALES COMO POLIETERES Y POLIESTERES QUE TIENEN PESOS MOLECULARES ENTRE 500 Y 5000 APROXIMADAMENTE, CON DIISOCIANATOS O POLIISOCIANATOS ALIFATICOS, ALQUILAROMATICOS O AROMATICOS Y EXTENSORES DE CADENA DE PESO MOLECULAR BAJO, TALES COMO DIAMINAS, POLIAMINAS O AMINOALCOHOLES. LAS MEMBRANAS SON UTILES PARA SEPARAR AROMATICOS DE NO AROMATICOS EN, POR EJEMPLO, REFINERIAS DE PETROLEO Y APLICACIONES QUIMICAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/108,822 US4914064A (en) | 1987-10-14 | 1987-10-14 | Highly aromatic polyurea/urethane membranes and their use for the separation of aromatics from non-aromatics |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2039637T3 true ES2039637T3 (es) | 1993-10-01 |
Family
ID=22324251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888309631T Expired - Lifetime ES2039637T3 (es) | 1987-10-14 | 1988-10-14 | Membranas de poliurea/uretano con elevado contenido de compuestos aromaticos y su uso para separar compuestos aromaticos de compuestos no aromaticos. |
Country Status (7)
Country | Link |
---|---|
US (1) | US4914064A (es) |
EP (1) | EP0312374B1 (es) |
JP (1) | JPH022854A (es) |
KR (1) | KR890006717A (es) |
BR (1) | BR8805321A (es) |
DE (1) | DE3879856T2 (es) |
ES (1) | ES2039637T3 (es) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5063186A (en) * | 1987-10-14 | 1991-11-05 | Exxon Research & Engineering Company | Highly aromatic polyurea/urethane membranes and their use of the separation of aromatics from non-aromatics |
US5055632A (en) * | 1987-10-14 | 1991-10-08 | Exxon Research & Engineering Company | Highly aromatic polyurea/urethane membranes and their use for the separation of aromatics from non-aromatics |
US4946594A (en) * | 1989-10-16 | 1990-08-07 | Exxon Research And Engineering Company | Crosslinked copolymers of aliphatic polyester diols and dianhydrides |
US4962271A (en) * | 1989-12-19 | 1990-10-09 | Exxon Research And Engineering Company | Selective separation of multi-ring aromatic hydrocarbons from distillates by perstraction |
US5120900A (en) * | 1990-12-05 | 1992-06-09 | Exxon Research And Engineering Company | Integrated solvent extraction/membrane extraction with retentate recycle for improved raffinate yield |
US5045206A (en) * | 1990-12-05 | 1991-09-03 | Exxon Research & Engineering Company | Selective multi-ring aromatics extraction using a porous, non-selective partition membrane barrier |
US5095170A (en) * | 1990-12-05 | 1992-03-10 | Exxon And Research And Engineering Company | Intergrated membrane pre-extraction/solvent extraction of distillates |
US5039417A (en) * | 1990-12-06 | 1991-08-13 | Exxon Research And Engineering Company | Membrane made from a multi-block polymer comprising an imide or amide-acid prepolymer chain extended with a compatible second prepolymer and its use in separations |
US5130017A (en) * | 1990-12-06 | 1992-07-14 | Exxon Research And Engineering Company | Multi-block polymer comprising a first amide acid prepolymer, chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations |
US5221481A (en) * | 1990-12-06 | 1993-06-22 | Exxon Research And Engineering Company | Multi-block polymer comprising an ester prepolymer, made by combining epoxy with polyester, chain extended with a compatible second prepolymer, the membrane made therefrom and its use for separations |
US5039422A (en) * | 1990-12-06 | 1991-08-13 | Exxon Research And Engineering Company | Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations |
US5049281A (en) * | 1990-12-06 | 1991-09-17 | Exxon Research And Engineering Company | Multi-block polymer comprising a first prepolymer, made by combining epoxy with diamine, chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations |
US5098570A (en) * | 1990-12-06 | 1992-03-24 | Exxon Research And Engineering Company | Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations |
US5039418A (en) * | 1990-12-06 | 1991-08-13 | Exxon Research And Engineering Company | Membrane made from a multi-block polymer comprising an oxazolidone prepolymer chain extended with a compatible second prepolymer and its use in separations |
US5095171A (en) * | 1991-04-08 | 1992-03-10 | Exxon Research And Engineering Company | Control of oxygen level in feed for improved aromatics/non-aromatics pervaporation (OP-3602) |
US5229045A (en) * | 1991-09-18 | 1993-07-20 | Kontron Instruments Inc. | Process for making porous membranes |
US5254795A (en) * | 1992-10-07 | 1993-10-19 | Exxon Research And Engineering Company | Removal of 2-ring aromatics from low boiling streams containing low concentrations of same using membranes |
US5298669A (en) * | 1993-03-23 | 1994-03-29 | Exxon Chemical Patent Inc. | Perstraction sweep stream for a membrane reactor |
US5401891A (en) * | 1993-12-17 | 1995-03-28 | Exxon Chemical Patents Inc. | Production of polymerization grade dicyclopentadiene |
US5430224A (en) * | 1994-04-15 | 1995-07-04 | Exxon Research & Engineering Company | Supercritical perstraction process |
US5635055A (en) | 1994-07-19 | 1997-06-03 | Exxon Research & Engineering Company | Membrane process for increasing conversion of catalytic cracking or thermal cracking units (law011) |
NL1001062C2 (nl) | 1995-08-25 | 1997-02-27 | Tno | Membraan en werkwijze voor het scheiden van aromatische koolwaterstoffen uit een mengsel van diverse aromatische koolwaterstoffen of uit een mengsel van dergelijke aromatische koolwaterstoffen en niet-aromatische koolwaterstoffen. |
US6793864B1 (en) | 1997-02-26 | 2004-09-21 | Dunlop Sports | Polyurethane material for two and three piece golf balls |
US7244384B1 (en) | 1998-02-04 | 2007-07-17 | Taylormade-Adidas Golf Company | Method for manufacturing two and three piece golf balls constructed from polyurethane material |
US6719646B2 (en) | 2000-01-25 | 2004-04-13 | Dunlop Slazenger Sports | Polyurethane covered three-piece golf ball |
WO2003064015A2 (en) * | 2002-01-25 | 2003-08-07 | Colorado School Of Mines | Polymer blends and methods of separation using the same |
US7785471B2 (en) * | 2006-08-08 | 2010-08-31 | Exxonmobil Research And Engineering Company | Chromatographic membrane separation |
US20080035574A1 (en) * | 2006-08-08 | 2008-02-14 | Sabottke Craig Y | Membrane Barrier films and method of use |
US7749387B2 (en) * | 2006-08-08 | 2010-07-06 | Exxonmobil Research And Engineering Company | Integrally-layered polymeric membranes and method of use |
US20080035567A1 (en) * | 2006-08-08 | 2008-02-14 | Sabottke Craig Y | Enhanced membrane separation system |
US8083946B2 (en) * | 2006-08-08 | 2011-12-27 | Exxonmobil Research And Engineering Company | Chemically cross-linked polymeric membranes and method of use |
US7708151B2 (en) * | 2006-08-08 | 2010-05-04 | Exxonmobil Research And Engineering Company | Membrane for separating aromatic and aliphatic compounds |
US20100155300A1 (en) * | 2008-12-24 | 2010-06-24 | Sabottke Craig Y | Process for producing gasoline of increased octane and hydrogen-containing co-produced stream |
US7951224B2 (en) * | 2008-12-24 | 2011-05-31 | Exxonmobil Research And Engineering Company | Process for improving the cetane rating of distillate and diesel boiling range fractions |
US8857629B2 (en) | 2010-07-15 | 2014-10-14 | International Business Machines Corporation | Composite membrane with multi-layered active layer |
US8727135B2 (en) | 2010-09-01 | 2014-05-20 | International Business Machines Corporation | Composite filtration membranes and methods of preparation thereof |
US8709536B2 (en) | 2010-09-01 | 2014-04-29 | International Business Machines Corporation | Composite filtration membranes and methods of preparation thereof |
US8258363B2 (en) | 2010-09-27 | 2012-09-04 | Phillips 66 Company | Separation of aromatics with pervaporation membrane |
US9022227B2 (en) | 2011-03-21 | 2015-05-05 | International Business Machines Corporation | Composite membranes and methods of preparation thereof |
US8765824B2 (en) | 2011-04-19 | 2014-07-01 | Exxonmobil Research And Engineering Company | Ethanol stable polyether epoxy based membrane for ethanol and aromatics separation |
JP6188731B2 (ja) | 2012-03-02 | 2017-08-30 | サウジ アラビアン オイル カンパニー | 非芳香族から芳香族を分離するための促進輸送膜 |
US9561474B2 (en) | 2012-06-07 | 2017-02-07 | International Business Machines Corporation | Composite membrane with multi-layered active layer |
EP3000801A4 (en) | 2013-05-20 | 2017-01-25 | Lotte Chemical Corporation | Method for separating aromatic compounds contained in naphtha |
EP3316998A1 (en) | 2015-07-01 | 2018-05-09 | 3M Innovative Properties Company | Composite membranes with improved performance and/or durability and methods of use |
CN107735163B (zh) | 2015-07-01 | 2021-02-23 | 3M创新有限公司 | 含pvp和/或pvl的复合膜以及使用方法 |
KR20180023971A (ko) | 2015-07-01 | 2018-03-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중합체성 이오노머 분리막 및 사용 방법 |
KR102087753B1 (ko) | 2016-11-01 | 2020-03-12 | 주식회사 엘지화학 | 벤젠과 톨루엔의 분리방법 |
CN113509840B (zh) * | 2020-04-09 | 2023-01-03 | 中国石油化工股份有限公司 | 一种复合纳滤膜及其制备方法与应用 |
Family Cites Families (36)
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DE151952C (es) * | ||||
DE151874C (de) * | 1903-01-24 | 1904-06-02 | Hans Henrik Jensen | Sicherheitslaterne mit beim Ab-oder Umfallen durch Federwirkung den Docht bedeckenden Klappen |
US2930754A (en) * | 1954-07-16 | 1960-03-29 | Pan American Refining Corp | Method of separating hydrocarbons |
US2958656A (en) * | 1954-07-16 | 1960-11-01 | American Oil Co | Method of separating hydrocarbons using ethyl cellulose permselective membrane |
US2970106A (en) * | 1958-01-31 | 1961-01-31 | American Oil Co | Aromatic separation process |
US3456037A (en) * | 1964-12-14 | 1969-07-15 | Du Pont | Polyurethane-polyureas |
US3595732A (en) * | 1966-08-15 | 1971-07-27 | Minnesota Mining & Mfg | Process and microporous product |
FR92377E (fr) * | 1966-12-26 | 1968-10-31 | Kuhlmann Ets | Composition de polyuréthane-polyurée conduisant en un seul stade à un produit cellulaire et à un élastomère compact |
US3715326A (en) * | 1967-01-10 | 1973-02-06 | Bayer Ag | Using monoisocyanates to prepare microporous polyurethanes |
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US3936409A (en) * | 1969-03-10 | 1976-02-03 | Textron, Inc. | Urea-urethane compositions and films prepared therefrom |
US3635908A (en) * | 1969-11-10 | 1972-01-18 | Basf Wyandotte Corp | Process of preparing polyurethane-urea thermoplastic products base on a polyamine carbamate as chain extender |
US3806474A (en) * | 1970-11-23 | 1974-04-23 | Princeton Polymer Sponge Corp | Hydrophilic polyester urethane foam |
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CA1084647A (en) * | 1974-02-21 | 1980-08-26 | Shigeyoshi Hara | Nitrogen-containing aromatic polymers and process for their preparation |
US4009307A (en) * | 1975-07-24 | 1977-02-22 | Ppg Industries, Inc. | Polyurea-urethane coatings |
DE2627629C3 (de) * | 1976-06-19 | 1979-12-20 | Bayer Ag, 5090 Leverkusen | Verfahren zur Abtrennung von aromatischen* Kohlenwasserstoffen aus Gemischen mit anderen organischen Verbindungen mit Hilfe von Kunststoffmembranen |
US4107151A (en) * | 1976-10-28 | 1978-08-15 | Ihara Chemical Company Co., Ltd. | Process for producing urethane elastomer |
JPS5850121B2 (ja) * | 1978-05-01 | 1983-11-09 | 日東電工株式会社 | 微孔性透過膜 |
DE2916139A1 (de) * | 1979-04-20 | 1980-10-30 | Bayer Ag | Neue polyurethanharnstoffe mit schwefel enthaltenden aromatischen harnstoffgruppen und verfahren zu ihrer herstellung |
US4374210A (en) * | 1981-09-18 | 1983-02-15 | The Upjohn Company | Polyurea-polyurethane from a mixture of a polyol, an aromatic diamine, and an isocyanate-terminated prepolymer |
DE3215908A1 (de) * | 1982-04-29 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von foermkoerpern auf basis von polyurethan- oder polyurethan-polyharnstoff-elastomeren mit verbesserter licht- und witterungsbestaendigkeit |
JPS5959220A (ja) * | 1982-09-28 | 1984-04-05 | Teijin Ltd | 気体分離用複合透過膜の製造法 |
JPS6080082A (ja) * | 1983-10-08 | 1985-05-07 | Hisaka Works Ltd | プレ−ト式蒸発器 |
DE3405679A1 (de) * | 1984-02-17 | 1985-08-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von gegebenenfalls zelligen polyurethan-polyharnstoff-formkoerpern |
US4532316A (en) * | 1984-05-29 | 1985-07-30 | W. L. Gore & Assoc., Inc. | Phase separating polyurethane prepolymers and elastomers prepared by reacting a polyol having a molecular weight of 600-3500 and isocyanate and a low molecular weight chain extender in which the ratios of reactants have a limited range |
US4596685A (en) * | 1984-10-18 | 1986-06-24 | Basf Corporation | Oxyethylated aromatic amines and their use as chain extenders in the preparation of polyurethane-polyurea elastomers |
JPS61115570A (ja) * | 1984-11-12 | 1986-06-03 | 住友ベークライト株式会社 | 血液浄化用多孔質膜 |
US4568702A (en) * | 1985-04-15 | 1986-02-04 | Atlantic Richfield Company | Method for the preparation of semi-rigid polyurethane modified polyurea foam compositions |
DE3513980A1 (de) * | 1985-04-18 | 1986-10-30 | Bayer Ag, 5090 Leverkusen | Matrixwerkstoffe, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von verbundwerkstoffen |
US4745137A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from solutions or dispersions of polymers of rigid polyaromatic monomers in polyols |
JPH07239079A (ja) * | 1994-02-28 | 1995-09-12 | Osaka Gas Co Ltd | 可撓管接続継手 |
JP2953562B2 (ja) * | 1994-07-18 | 1999-09-27 | 東京応化工業株式会社 | リソグラフィー用下地材及びそれを用いた多層レジスト材料 |
-
1987
- 1987-10-14 US US07/108,822 patent/US4914064A/en not_active Expired - Fee Related
-
1988
- 1988-10-14 JP JP63259242A patent/JPH022854A/ja active Pending
- 1988-10-14 DE DE8888309631T patent/DE3879856T2/de not_active Expired - Fee Related
- 1988-10-14 ES ES198888309631T patent/ES2039637T3/es not_active Expired - Lifetime
- 1988-10-14 KR KR1019880013413A patent/KR890006717A/ko not_active Application Discontinuation
- 1988-10-14 BR BR8805321A patent/BR8805321A/pt not_active Application Discontinuation
- 1988-10-14 EP EP88309631A patent/EP0312374B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0312374A2 (en) | 1989-04-19 |
BR8805321A (pt) | 1989-05-30 |
DE3879856D1 (de) | 1993-05-06 |
DE3879856T2 (de) | 1993-07-08 |
JPH022854A (ja) | 1990-01-08 |
EP0312374A3 (en) | 1990-01-10 |
KR890006717A (ko) | 1989-06-15 |
US4914064A (en) | 1990-04-03 |
EP0312374B1 (en) | 1993-03-31 |
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FG2A | Definitive protection |
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