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ES2010713B3 - Catalizador a base de mordenita para la isomerizacion de parafinas normales. - Google Patents

Catalizador a base de mordenita para la isomerizacion de parafinas normales.

Info

Publication number
ES2010713B3
ES2010713B3 ES87401858T ES87401858T ES2010713B3 ES 2010713 B3 ES2010713 B3 ES 2010713B3 ES 87401858 T ES87401858 T ES 87401858T ES 87401858 T ES87401858 T ES 87401858T ES 2010713 B3 ES2010713 B3 ES 2010713B3
Authority
ES
Spain
Prior art keywords
mordenite
weight
catalyst
oxychlorination
chlorine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES87401858T
Other languages
English (en)
Inventor
Jean-Paul Bournonville
Jean-Pierre Franck
Christine Travers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2010713B3 publication Critical patent/ES2010713B3/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/22—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

CATALIZADOR DE ISOMERIZACION, DE UNA PAREJA DE HIDROCARBUROS RICA EN N-PARAFINAS, CARACTERIZADA EN QUE ES EL PRODUCTO DE UNA OXICLORACION DIRIGIDA DE UN SOLIDO, ENCERRANDO AL MENOS UN METAL DEL GRUPO VIII SOPORTADO POR UNA MORDENITA ACIDA, DICHA MORDENITA TENIENDO UN CONTENIDO EN SODIO INFERIOR A 0,2% EN PESO, ABSORBIENDO MOLECULAS DE DIAMETRO CINETICO SUPERIOR A ALREDEDOR DE 6,6X10- 10M, TENIENDO UN VOLUMEN DE MALLA, V, DE LA MALLA ELEMENTAL DE 2,73 A 2,78 NM3 Y UNA CAPACIDAD DE ABSORCION DE BENCENO SUPERIOR A 5% EN PESO, DICHA OXICLORACION ESTANDO EFECTUADA A UNA TEMPERATURA ALREDEDOR DE 200 A 500 GRADOS CENTIGRADOS CON LA AYUDA DE UNA MEZCLA GASEOSA CONTENIENDO OXIGENO, AGUA Y CLORO O AL MENOS UN COMPUESTO CLORADO LA CANTIDAD DE CLORO O DE COMPUESTO CLORADO EMPLEADO REPRESENTANDO UN TOTAL DE 0,5 A 10% EN PESO DE CLORO POR PRODUCTO AL PESO DE MORDENITA. EL CATALIZADOR ENCERRAR ADEMAS UNA MATRIZ, LA CANTIDAD DE MORDENITA REPRESENTANDO AL MENOS 40% EN PESO DEL CONJUNTO MORDENITA Y MATRIZ.
ES87401858T 1986-08-13 1987-08-10 Catalizador a base de mordenita para la isomerizacion de parafinas normales. Expired ES2010713B3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8611795A FR2602696B1 (fr) 1986-08-13 1986-08-13 Catalyseur a base de mordenite pour l'isomerisation de paraffines normales

Publications (1)

Publication Number Publication Date
ES2010713B3 true ES2010713B3 (es) 1989-12-01

Family

ID=9338345

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87401858T Expired ES2010713B3 (es) 1986-08-13 1987-08-10 Catalizador a base de mordenita para la isomerizacion de parafinas normales.

Country Status (10)

Country Link
US (1) US4789655A (es)
EP (1) EP0256945B1 (es)
JP (1) JPS6349256A (es)
AT (1) ATE45176T1 (es)
CA (1) CA1300115C (es)
DE (1) DE3760391D1 (es)
ES (1) ES2010713B3 (es)
FR (1) FR2602696B1 (es)
GR (1) GR3000157T3 (es)
NO (1) NO170874C (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0829255B2 (ja) * 1986-10-04 1996-03-27 出光興産株式会社 芳香族炭化水素製造用触媒およびこれを用いた芳香族炭化水素の製造方法
US5196631A (en) * 1986-10-04 1993-03-23 Research Association For Utilization Of Light Oil Catalyst for production of aromatic hydrocarbons and process for production of aromatic hydrocarbons using same
JPH0678528B2 (ja) * 1986-11-18 1994-10-05 出光興産株式会社 炭化水素の転化方法
US4914068A (en) * 1988-03-21 1990-04-03 Exxon Chemical Patents Inc. Process for the dispersion of Group VIII metals in large pore zeolite catalysts
FR2643830B1 (fr) * 1989-03-03 1991-06-21 Inst Francais Du Petrole Catalyseur a base de mordenite renfermant au moins un metal des groupes iia, ivb, iib ou iva et son utilisation en isomerisation d'une coupe c8 aromatique
US5215736A (en) * 1989-10-10 1993-06-01 Institut Francais Du Petrole Mordenite type zeolite and its preparation process
US5185306A (en) * 1991-07-24 1993-02-09 Uop Prevention of noble metal migration in bound zeolites during thermal oxidation
FR2744458B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines par distillation reactive
FR2744441B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines
FR2761904B1 (fr) * 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
US8664144B2 (en) * 2008-12-23 2014-03-04 Chevron Phillips Chemical Company Lp Methods of reactivating an aromatization catalyst
US8716161B2 (en) 2012-03-05 2014-05-06 Chevron Phillips Chemical Company Methods of regenerating aromatization catalysts
US8912108B2 (en) 2012-03-05 2014-12-16 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts
US9387467B2 (en) 2012-09-26 2016-07-12 Chevron Phillips Chemical Company Lp Aromatization catalysts with high surface area and pore volume
FR3115475A1 (fr) * 2020-10-23 2022-04-29 IFP Energies Nouvelles Procede de preparation d’un catalyseur a base d’izm-2 par un traitement thermique specifique et utilisation dudit catalyseur pour l’isomerisation de charges paraffiniques en distillats moyens

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751502A (en) * 1970-05-04 1973-08-07 Universal Oil Prod Co Hydrocarbon isomerization process
JPS568080B1 (es) * 1971-04-23 1981-02-21
GB1436622A (en) * 1973-06-21 1976-05-19 British Petroleum Co Regeneration of zeolite catalysts
US4273753A (en) * 1979-09-10 1981-06-16 Mobil Oil Corporation De-aluminization of aluminosilicates
NL8004797A (nl) * 1980-08-26 1982-04-01 Shell Int Research Katalysatorbereiding.
CA1190206A (en) * 1982-03-30 1985-07-09 Brent M. Lok Modification of zeolites by treatment with chlorine gas
US4657874A (en) * 1984-01-18 1987-04-14 Mobil Oil Corporation Redispersion of agglomerated noble metals on zeolite catalysts

Also Published As

Publication number Publication date
EP0256945A1 (fr) 1988-02-24
NO873347L (no) 1988-02-15
DE3760391D1 (en) 1989-09-07
EP0256945B1 (fr) 1989-08-02
NO873347D0 (no) 1987-08-11
FR2602696B1 (fr) 1988-11-04
GR3000157T3 (en) 1990-12-31
US4789655A (en) 1988-12-06
NO170874B (no) 1992-09-14
FR2602696A1 (fr) 1988-02-19
NO170874C (no) 1992-12-23
JPS6349256A (ja) 1988-03-02
ATE45176T1 (de) 1989-08-15
CA1300115C (fr) 1992-05-05

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