EP4150168A1 - Plumbing fixture sanitising system - Google Patents
Plumbing fixture sanitising systemInfo
- Publication number
- EP4150168A1 EP4150168A1 EP21726961.2A EP21726961A EP4150168A1 EP 4150168 A1 EP4150168 A1 EP 4150168A1 EP 21726961 A EP21726961 A EP 21726961A EP 4150168 A1 EP4150168 A1 EP 4150168A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- plumbing fixture
- concentration
- ppm
- cistern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009428 plumbing Methods 0.000 title claims abstract description 128
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 184
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 69
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 6
- 239000008400 supply water Substances 0.000 claims abstract description 6
- 239000002351 wastewater Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 8
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 230000002401 inhibitory effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 26
- ZKHQWZAMYRWXGA-KQYNXXCUSA-J ATP(4-) Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O)[C@@H](O)[C@H]1O ZKHQWZAMYRWXGA-KQYNXXCUSA-J 0.000 description 16
- ZKHQWZAMYRWXGA-UHFFFAOYSA-N Adenosine triphosphate Natural products C1=NC=2C(N)=NC=NC=2N1C1OC(COP(O)(=O)OP(O)(=O)OP(O)(O)=O)C(O)C1O ZKHQWZAMYRWXGA-UHFFFAOYSA-N 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
- 102000004190 Enzymes Human genes 0.000 description 13
- 108090000790 Enzymes Proteins 0.000 description 13
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 13
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 11
- 229940116269 uric acid Drugs 0.000 description 11
- 230000003749 cleanliness Effects 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 238000011010 flushing procedure Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- -1 uric salts Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 230000035943 smell Effects 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 230000005484 gravity Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 230000001960 triggered effect Effects 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- YCKZWPNTMNXDRR-UHFFFAOYSA-N 1-(1,2,2,3-tetramethyl-3,4,4a,5,6,7-hexahydronaphthalen-1-yl)ethanone Chemical class C1CCC=C2C(C)(C(C)=O)C(C)(C)C(C)CC21 YCKZWPNTMNXDRR-UHFFFAOYSA-N 0.000 description 1
- JRJBVWJSTHECJK-PKNBQFBNSA-N 3-Methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one Chemical compound CC(=O)C(\C)=C\C1C(C)=CCCC1(C)C JRJBVWJSTHECJK-PKNBQFBNSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000048246 Gallicrex cinerea Species 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004479 aerosol dispenser Substances 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000029918 bioluminescence Effects 0.000 description 1
- 238000005415 bioluminescence Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000013568 food allergen Substances 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000010800 human waste Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
- E03D9/033—Devices placed inside or dispensing into the cistern
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/002—Automatic cleaning devices
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/007—Devices for eliminating smells by diffusing deodorants in lavatories
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D2009/028—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing using a liquid substance
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D5/00—Special constructions of flushing devices, e.g. closed flushing system
Definitions
- the present application relates to a plumbing fixture sanitising system, a method of sanitising a plumbing system, and a use of ozonated water to sanitise a plumbing system.
- the plumbing system may be a toilet or a urinal.
- urinal installations are typically formed of a plurality of urinals, each of which are connected to a cistern which provides a supply of water to flush the urinals. Similar systems may be provided for commercial toilet installations where a plurality of toilets are connected to the cistern in order for the cistern to provide a water supply to flush the toilets.
- a single elongate multi-user urinal may include a plurality of water inlets spaced from one another, each of which is connected to the cistern.
- the cistern provides a supply of water to flush the multi-user urinal at a number of spaced apart locations.
- Urine presents a particular problem as the smell can be particularly strong over time.
- uric acid crystals also known as uric salts
- cleaning chemicals may include, for example, liquid or solid detergent compositions. This may include one or more of: sodium hypochlorite solution, sodium (C12-14) alkyl ethoxy sulphate, 1,2-benzisothiazolin-3-one, benzenesulphonic acid mono C10-C13 alkyl derivs. Some toilet cleaners may also include sodium salts. These cleaning chemicals must be carefully stored and disposed of, as there is otherwise a risk of environmental damage.
- Alternative solutions involve the use of an enzyme mat or sleeve which then leads down to a bottle trap of the waste water outlet of the plumbing fixture.
- the enzyme mat includes enzymes and/or bacteria which break down the build-up of uric salts. While this does not use the same cleaning chemicals as other conventional systems, the trap is typically made from non-recyclable plastics. Further, if any of the conventional cleaning chemicals are added to the plumbing fixture, such as during a supplemental cleaning routine, the enzymes in the mat may be deactivated or denatured. Additionally, each type of enzyme has a relatively small pH range in which it is optimally effective. Once it falls out of this range, the enzymes may denature and stop working. The mat then needs replacement, generating more waste which may be difficult to dispose of in an environmentally friendly manner.
- fragrance delivery devices are usually installed. These may be in the form of aerosol dispensers such as automated air fresheners. Typically these fragrances will also include cleaning chemicals to mask the unpleasant smells, and hence suffer from the same issues regarding storage, handling and disposal of these cleaning chemicals as other systems discussed above. For example, these may contain one or more of: C11-15-ISO-alkanes, alpha-isomethyl ionone, butylphenyl methylpropional, cyclamen aldehyde, geraniol, limonene, tetramethyl acetyloctahydronaphthalenes, isopropanol, dipropylene, and/or Glycol.
- ozone O3
- An electrochemical cell is provided to produce ozone in water flowing into the toilet bowl.
- the electrolysis of water at high electrode potential produces ozone at the anode in the electrochemical cell.
- the electrochemical cell is provided in the conduit between the cistern and the toilet bowl to produce ozone in water flowing to the bowl for flushing.
- the electrochemical cell is provided on the conduit between the mains supply of water and the toilet bowl.
- the concentration of ozone generated in the water will determine the rate of oxidation and hence the degree of disinfection.
- the concentration of ozone depends upon the effective contact time between the water and the electrochemical cell, which is limited by the flow rate of the water passing the cell.
- the flow rate of the water passing the cell must be sufficiently large enough to have a mechanical flushing effect on the toilet bowl to dislodge debris.
- the concentration of ozone generated in WO 2018/100349 A1 is limited to around 0.5 ppm (0.5 mg/L). This will naturally decrease in the portion of the conduit between the electrochemical cell and the toilet bowl as the ozonated water contacts the conduit walls, air, and debris in the conduit.
- US 2011/0277227 A1 discloses a procedure for disinfecting a toilet appliance in which water for flushing a toilet is introduced from a cistern into a flush pipe and from there into the interior of the toilet. Ozone gas is injected so as to provide ozone gas to the air around the toilet appliance.
- US 2004/0133968 A1 discloses water which is electrochemically treated to achieve disinfectant properties.
- US 2020/0131749 A1 discloses an antimicrobial toilet including one or more pairs of electrodes positioned below a water line when the hydraulic circuit is at equilibrium.
- JP H06158701 A discloses city water which is supplied to a shower nozzle through a stop cock and a branching water cock, and an ion formation device and an ozonizer which are connected into a pipe line thereof.
- the ozonizer generates gaseous ozone from air, which is injected into the water line.
- EP 1939366 A1 discloses flush toilet equipment comprising a bowl, a flush mechanism that supplies flush water to the bowl through a flush water passage, and a minute bubble generator.
- DE 10048299 A1 discloses a device for electrolytic disinfection of drinking water, service water and waste water using anodically generated disinfectants.
- the present invention provides a plumbing fixture sanitising system according to claim 1.
- the system allows a large concentration of ozone to be generated in water to be used in a flush event, before entering the cistern to clean and wash the plumbing fixture.
- the ozonated water effectively reduces bacteria on the plumbing fixture, and eliminates malodour.
- the arrangement of the electrochemical cell assembly upstream of the cistern improves the ozone generation, and allows for the cistern itself to be cleaned. As a result, traditional cleaning chemicals do not have to be used in the system.
- the invention is therefore more environmentally friendly than known systems.
- the plumbing fixture sanitising system may further comprise one or more further plumbing fixtures, each comprising a water inlet arranged to receive water from the cistern.
- the ozonated water can thereby be used to clean a plurality of plumbing fixtures, for example in a commercial lavatory set-up.
- the plumbing fixture sanitising system may further comprise a control system comprising: an inlet valve arranged on the supply pipe, moveable between: an open position where water can flow through the supply pipe; and an inhibited position where water is inhibited from flowing through the supply pipe; and a controller configured to control operation of the inlet valve between the open and inhibited positions.
- the inhibited position may be a fully closed position, or may allow a trickle flow therethrough. This valve can selectively allow a full flushing flow of water through the system. As a result, flushing of the system can be triggered when appropriate.
- the controller may be further configured to control operation of the electrochemical cell assembly to produce ozone when the inlet valve is in the open position, and cease production of ozone when the inlet valve is in the inhibited position. This prevents the electrochemical cell from operating when there is insufficient water for it to do so, or for when it is unnecessary for it to do so. This may allow the controller to optimise the operation of the electrochemical cell assembly to deliver the required concentration of ozone to the plumbing fixture.
- the controller may be configured to move the inlet valve to the open position after a predetermined time period. This may ensure that water is not wasted by flush events which are unnecessary.
- the control system may further comprise a sensor arranged to generate a signal indicative of the presence of a person. This can further reduce the wastage of water in the system.
- the controller may be configured to adjust the predetermined time period based upon the signal indicative of the presence of a person. This allows the system to adjust based upon the use of the plumbing fixture.
- the inlet valve may be arranged upstream of the electrochemical cell assembly in the supply pipe. This prevents water from flowing past the electrochemical cell when a flush event is not desired.
- the control system may further comprise a cistern valve for selectively inhibiting flow of water from the cistern to the plumbing fixture(s), wherein the controller is configured to: actuate the inlet valve at a first time to allow a flow of water through the supply pipe to the cistern with the cistern valve in a closed position; and open the cistern valve a predetermined delay period after the first time to provide water to each plumbing fixture.
- the cistern valve may completely prevent a flow of water from the cistern to any of the attached plumbing fixtures.
- a trickle flow therethrough may be permitted. This allows the cistern to fill and thereby build up a head pressure.
- the head pressure results in the water entering the sanitary fixture with a greater force and thus producing a stronger mechanical cleaning action.
- the flow of water through the electrochemical cell assembly can be slowed, thereby increasing the contact time and hence the concentration of ozone generated. This slower water flow would normally have a weaker mechanical cleaning action, but the filling of the cistern first ensures this is not the case.
- the predetermined delay period may be between two and five minutes. This may allow a suitable pressure level for a reasonable mechanical cleaning force.
- the controller may be configured to control operation of the electrochemical cell assembly based upon the position of the inlet valve and/or the cistern valve. This may allow the controller to optimise the operation of the electrochemical cell assembly to deliver the required concentration of ozone to the plumbing fixture.
- the controller may be configured to activate the electrochemical cell assembly to generate ozone when the inlet valve and/or the cistern valve is in the open position, and deactivate the electrochemical cell assembly when the inlet valve and/or the cistern valve is in the inhibited position. This may mean that the ozone does not spend a significant amount of time in the cistern, where it would decay. As a result, ozone at a higher concentration may be delivered to the plumbing fixture.
- the electrochemical cell assembly may be arranged to produce ozone at a concentration of at least 0.7 ppm, preferably a concentration of at least 0.8 ppm, more preferably a concentration of at least 1 ppm, most preferably a concentration of at least 1.1 ppm.
- the present invention has shown particular effectiveness with these concentration levels, particularly in the ozone level delivered to the plumbing fixture when balanced with the difficulty of achieving these higher concentrations.
- Each plumbing fixture may be a urinal or a toilet. These are typically installed in commercial lavatory set-ups where the present invention may be particularly effective.
- the present invention also provides a plumbing fixture sanitising system according to claim 13.
- Ozone generated at this level is particularly effective at breaking down uric acid crystals (also known as uric salts) which are a main cause of unpleasant odours.
- Ozone generated at this level will typically reach the plumbing fixture at a sufficiently large concentration. This may be following some commissioning flushes which act to establish a reasonably stable state for the system.
- the electrochemical cell may be arranged to produce ozone at a concentration of at least 0.8 ppm, preferably at a concentration of at least 1 ppm, most preferably at a concentration of at least 1.1 ppm.
- the present invention has shown particular effectiveness with these concentration levels, particularly in the ozone level delivered to the plumbing fixture when balanced with the difficulty of achieving these higher concentrations.
- the electrochemical cell may be arranged to produce ozone that is delivered to the plumbing fixture at a concentration of at least 0.6ppm, preferably at a concentration of at least 0.7 ppm. Ozone delivered at this level may effectively clean and wash the plumbing fixture, in particular it is effective for breaking down uric acid crystals. As noted above, these concentrations may be achieved following commissioning flushes which act to establish a reasonably steady state for the system.
- the plumbing fixture may comprise a waste water outlet with a bottle trap, wherein the electrochemical cell is arranged to produce ozone that is received in the bottle trap at a concentration of at least 0.2 ppm, preferably at a concentration of at least 0.3 ppm.
- the water may flow through the bottle trap to a waste water outlet 2.
- Uric acid crystals often form in these areas, producing a significant unpleasant odour. Ozonated water delivered to these areas with a sufficiently high concentration may effectively break down these crystals and remove malodour.
- the plumbing fixture sanitising system may further comprise one or more further plumbing fixtures, the water supply assembly arranged to supply water to each of the further plumbing fixtures.
- the ozonated water can thereby be used to clean a plurality of plumbing fixtures, for example in a commercial lavatory set-up.
- the ozonated water can be delivered at the noted concentration levels to each of the plumbing fixtures.
- Each plumbing fixture may be a urinal or a toilet. These are typically installed in commercial lavatory set-ups where the present invention may be particularly effective.
- the present invention further provides a method of sanitising a plumbing fixture according to claim 19. This method may be particularly effective for cleaning the plumbing fixture, particularly in breaking down uric acid crystals and hence removing malodour.
- the ozonated water may be generated having a concentration of at least 0.7 ppm, preferably a concentration of at least 0.8 ppm, more preferably a concentration of at least 1 ppm, most preferably a concentration of at least 1.1 ppm.
- the present invention has shown particular effectiveness with these concentration levels, particularly in the ozone level delivered to the plumbing fixture when balanced with the difficulty of achieving these higher concentrations.
- the plumbing fixture may be a urinal or a toilet. These are typically installed in commercial lavatory set-ups where the present invention may be particularly effective.
- the present invention further provides a use of ozonated water according to claim 21. This use may be particularly effective for cleaning the plumbing fixture, particularly in breaking down uric acid crystals and hence removing malodour.
- the ozonated water may have a concentration of at least 0.7 ppm, preferably a concentration of at least 0.8 ppm, more preferably a concentration of at least 1 ppm, most preferably a concentration of at least 1.1 ppm.
- the present invention has shown particular effectiveness with these concentration levels, particularly in the ozone level delivered to the plumbing fixture when balanced with the difficulty of achieving these higher concentrations.
- the plumbing fixture may be a urinal or a toilet. These are typically installed in commercial lavatory set-ups where the present invention may be particularly effective.
- Figure 1 shows a schematic of a first plumbing fixture sanitising system according to the present invention.
- Figure 2 shows a schematic of a second plumbing fixture sanitising system according to the present invention.
- a plumbing fixture sanitising system 100 is depicted in Figure 1.
- a plurality of plumbing fixtures 20 are provided, in this embodiment the plumbing fixtures 20 are urinals 20.
- the system 100 may be applied to any suitable plumbing fixture 20 including, but not limited to, urinals, toilets and bidets.
- Each of the plumbing fixtures 20 comprises a water inlet 22 which is supplied with water from a cistern, or reservoir 40. This may be, for example, via a conduit that branches into a plurality of supply conduits 23. Alternatively, each supply conduit 23 may connect directly to the cistern 40.
- the water inlet 22 may be, for example, a nozzle or other spray device arranged to distribute the supply water over an area.
- the cistern 40 is connected via a supply pipe 42 to a source of water 1.
- the source of water 1 may be, for example, a mains water supply or a larger supply tank.
- water is supplied from the source 1 to fill the cistern 40.
- the water stored in the cistern 40 is then used to flush the plumbing fixtures 20. That is, the water from the cistern is released to flow through each supply conduit 23 to the water inlets 22, where it is then dispersed around an inner surface 21 of the plumbing fixture 20. This may be referred to as a “flush event.
- the dispersal of water around the inner surface 21 acts to wash the plumbing fixture. This washing produces a mechanical cleaning effect by dislodging debris on the inner surface.
- the inner surface 21 may be, for example, a toilet bowl 21 which is arranged to receive a user’s waste in use.
- the water flowing from the water inlets 22 acts to clean the inner surface 21 and remove any debris.
- a waste water outlet 24 At a lower end when installed of each plumbing fixture 20 is a waste water outlet 24.
- the waste water outlet 24 connects to a waste water return 2.
- the waste water outlet 24 includes a bottle trap which the water exiting the plumbing fixture 20 flows through.
- the bottle trap acts to collect debris from the water exiting the plumbing fixture 20.
- the waste water outlet 24 may return the waste water to a mains waste water system, or any other suitable disposal method such as to a cesspit or a septic tank. In use, the water is drawn via gravity through this waste water outlet 24.
- An enzyme mat or sleeve 26 may be provided in the region of the waste water outlet 24.
- the enzyme mat 26 may generally be formed as a grill or lattice extending across a portion of the plumbing fixture 20.
- the enzyme mat 26 substantially extends over the waste water outlet 24 such that any water must pass through the enzyme mat 26 before it exits the plumbing fixture 20 via the waste water outlet 24 and the bottle trap.
- an enzyme may be applied to the bottle trap such that the bottle trap provides some of the performance of the enzyme mat 26.
- An electrochemical cell assembly 10 is provided in the flow between the water supply 1 and the cistern 40. Collectively, the electrochemical cell assembly 10 and the water supply pipe 42 define a water supply assembly.
- the electrochemical cell assembly 10 may be provided in-line with the water supply pipe 42.
- the electrochemical cell assembly 10 is operable to produce ozone via the electrolysis of water. Any suitable electrochemical cell assembly 10 may be used..
- the electrochemical cell assembly 10 may have a cell input and a cell output. Water is received by the cell input, flows through the electrochemical cell assembly 10, and out of the cell output.
- the electrochemical cell assembly 10 may further comprise a power input for receiving electrical power to drive the electrochemical cell assembly 10.
- the electrochemical cell assembly 10 may include an anode and cathode, and the water flowing through the electrochemical cell assembly 10 may flow over the anode and cathode. This results in ozone being continuously produced.
- the electrochemical cell assembly 10 may be configured such that ozone is generated in the water flowing therethrough at a concentration of at least 0.7 parts per million (ppm). It is noted that, at least in the current field, 1 ppm is generally equivalent to 1 mg/L. Preferably, the ozone is generated at a concentration of at least 0.8 ppm, more preferably at least 0.9 ppm. In particular embodiments the ozone may be generated at a concentration in the region of 1 to 1.1 ppm.
- the ozone concentration of the water may be tested, for example, by using an activator solution, which is added to the liquid to be tested. This liquid is then drawn into an ampoule, and after 1 minute, this is matched against a colour comparator to identify the ozone reading. Immediately on generation, ozone will start to decay. This decay will be quicker if it is in contact with bacteria and organic matter. Additionally the ozone will decay faster if the liquid is subject to turbulence. The colour comparator gives a reading of ozone levels using parts per million, ppm.
- the ozonated water may then collect in the cistern 40.
- the ozonated water is released from the cistern to flow to the plumbing fixtures 20.
- concentration of ozone delivered to the plumbing fixtures 20 will depend upon the length of the water supply pipes 23, and their cleanliness.
- the system 100 is used to sanitise the plumbing fixture 20 for a first time after a period of non-use, more of the ozone will react with matter in the supply pipe 23 and thereby reduce the concentration delivered to the plumbing fixture 20.
- commissioning a number of flushing cycles
- the system 100 has typically settled into a relatively stable operating mode. In particular testing embodiments the number of commissioning cycles may be five.
- ozonated water may be delivered to the plumbing fixture 20 with a concentration of at least 0.7 ppm of ozone. Such a concentration of ozonated water should allow for effective cleaning of the plumbing fixture 20, in particular the breaking-down of uric acid crystals (uric salts).
- the ozone concentration in the water collected in the waste water outlet 24, for example in the bottle trap, will also depend upon the cleanliness of the supply pipe 23, as well as the cleanliness of and amount of debris on the inner surface 21. Again, after a number of commissioning cycles the system 100 will have settled into a relatively stable operating mode.
- Ozonated water may be delivered to the waste water outlet 24, such as to the bottle trap, with a concentration of at least 0.6 ppm. Again, this allows for effective breaking-down of uric acid crystals (uric salts) which may otherwise build up in these regions.
- the ozonated water then is drawn via gravity through the waste water outlet 24 and bottle trap into the waste water return 2.
- the remaining ozone in the water will act to provide a cleaning effect to the waste water return 2, though this is merely ancillary to the purpose of the present invention to sanitize the plumbing fixture 20.
- the system 100 may further include a control system 30 as a part of the water supply assembly.
- the control system 30 may comprise an inlet valve arranged on the supply pipe 42.
- the inlet valve may selectively allow water to flow between the water source 1 and the cistern 40.
- the inlet valve is moveable between an open position where water can flow through the supply pipe; and an inhibited position (or closed position) where water from the water source 1 is inhibited from flowing through the supply pipe 42. In the inhibited position, water may be completely prevented from flowing into and filling the cistern 40. Alternatively, a trickle-flow of water may be allows past the inlet valve in the inhibited position.
- the system 100 may be controlled by a controller which is a part of the control system 30.
- This controller may be configured to control operation of the inlet valve between the open and closed positions. That is, the controller may send a control signal to the inlet valve to instruct it to move to the open position in order to fill the cistern 40 in order to prepare the system for a flush event.
- This signal may be triggered, for example, by a user input requesting a flush event.
- the user input may be those conventionally associated with flushing a toilet or urinal including, but not limited to, actuating a lever, pulling a chain, activating an optical sensor (such as a motion or light sensor, for example by waving their hand over the sensor), pressing a button, or voice activated.
- the system 100 may further comprise a sensor arranged to generate a signal indicative of the presence of a user.
- the controller may receive this signal and trigger opening of the inlet valve a predetermined time period after receipt of this signal.
- the sensor may be able to determine the number of people detected in a given period and the controller may adjust the predetermined time period accordingly. For example, if there are a lot of users detected the time period may be reduced to trigger a flush event sooner.
- the inlet valve may be arranged upstream of the electrochemical cell assembly 10. As a result, water does not flow past the electrochemical cell assembly 10 until the inlet valve has been opened in the prelude to a flush event.
- the cistern 40 may include a cistern valve which is arranged on the water outlet of the cistern 40.
- the cistern valve may be moveable between a closed position where water is unable to flow from the cistern 40 to the water inlet pipes 23, and an open position where water is able to flow from the cistern 40 to the water inlet pipes 23 (i.e. during a flush event).
- the cistern valve may allow a trickle flow of water.
- a head of water is able to build in the cistern 40 by the flow of water from the water source 1.
- the cistern valve may be opened to allow the flow of water through the water inlet pipes 23 into the plumbing fixtures 20.
- the head of water in the cistern 40 results in the water being delivered at a pressure caused by the weight of the water in the cistern 40.
- the opening of the cistern valve may be triggered by the controller.
- the opening may be in response to a signal detected by a sensor which is indicative of the presence of users of the plumbing fixture 20.
- a sensor which is indicative of the presence of users of the plumbing fixture 20.
- the plumbing fixture 20 may be installed in a bathroom and the sensor may detect the number of people entering the bathroom.
- the controller may actuate the cistern valve to the open position a predetermined delay period after opening the water inlet valve.
- This predetermined delay period allows enough time for the cistern 40 to fill to produce the necessary head pressure for mechanical cleaning.
- the length of time for the predetermined delay period may be programmed into the controller, such as stored in a memory unit attached to the controller.
- This predetermined delay period may be selected based upon a number of variables such as the flow rate of water through the inlet pipe 42, the number and/or type of plumbing fixtures 20 supplied with water by the cistern 40, the capacity of the cistern 40, the intended users of the plumbing fixtures 20, etc.. In particular embodiments, the predetermined delay period may be between 2 and 5 minutes.
- the controller may be configured to control operation of the electrochemical cell assembly based upon the position of the cistern valve. For example, the controller may be configured to activate the electrochemical cell assembly to generate ozone when cistern valve is in the open position, and deactivate the electrochemical cell assembly when the cistern valve is in the inhibited position.
- the predetermined delay period may be adjusted by the controller in response to a signal indicative of users of the plumbing fixtures 20 from a sensor.
- the plumbing fixture 20 may be installed in a bathroom and the sensor may detect the number of people entering the bathroom.
- the sensor may indicate to the controller that there has been no visitors to the bathroom since the previous flush event.
- it may still be necessary to trigger a flush event despite there being no use of the plumbing fixture 20.
- the controller may therefore adjust the predetermined delay period to a shorter time, potentially even down to having a 0 second predetermined delay period if appropriate for the particular system 100.
- the adjustment may be between a plurality of discrete levels, or may be a continuous adjustment.
- the controller may adjust the predetermined delay period to a shorter time as there will likely be less debris requiring mechanical cleaning. Conversely, if the sensor detects a large number of users the controller may extend the predetermined delay period so that more water collects in the cistern 40 before a flush event. The greater amount of water in the cistern 40 will increase the head pressure and hence the effectiveness of mechanical cleaning. The controller may increase the delay period such that the cistern 40 is completely filled if the sensor detects a number of users greater than a threshold.
- the cistern valve may be manually actuated between the open and closed positons.
- the cistern valve may be moved to the open position in response to a user input.
- the user input may be those conventionally associated with flushing a toilet or urinal including, but not limited to, actuating a lever, pulling a chain, activating an optical sensor (such as a motion or light sensor, for example by waving their hand over the sensor), pressing a button, or voice activated.
- the sanitising flush event may trigger the controller opening the water inlet valve to begin the ozonation of water filling the cistern 40. Then, once the user of the plumbing fixture 20 leaves the area, the sensor (or a different presence sensor) may detect that the user has left and initiate the flush event by opening the cistern valve. If the user leaves too quickly and a sufficient water head has not built up in the cistern 40, the controller may apply the predetermined delay period until the cistern 40 is sufficiently full for the degree of mechanical cleaning desired.
- the controller may further include a water sensor arranged to generate a signal indicative of the amount of water in the cistern 40.
- the water sensor may include, for example, a flow sensor in the water supply pipe 42 (or in any other part of the water supply assembly), a float sensor in the cistern 40, and/or a balance arranged to detect the mass of water in the cistern 40.
- the predetermined delay period may not be defined as a period of time directly, but as a trigger event when a certain amount of water has entered the cistern 40. That is, the predetermined delay period may be “the period in which the cistern receives 5 litres of water 1 ’. Of course, the exact volume of water required will depend upon the particular system 100 and can be selected and adjusted accordingly.
- any reference to a predetermined delay period must be interpreted to include such an arrangement.
- the adjustment of such a predetermined delay period by the controller is then achieved by the adjustment of the amount of water necessary to trigger the flush event.
- the delay period may be “the period in which the cistern receives 2 litres of water”
- the delay period may be “the period in which the cistern receives 8 litres of water 1 ’.
- the adjustment may be between a plurality of discrete levels, or may be a continuous adjustment.
- the rate of water flow can be reduced.
- the reduction in the water flow rate means that the water has a longer effective contact time with the electrochemical cell assembly 10.
- a greater concentration of ozone in the water can be achieved compared to using the same electrochemical cell assembly 10 with water flowing at a faster rate therethrough.
- the arrangement allows water to have both a high ozone concentration (and hence a high chemical cleaning effect) and a high mechanical cleaning effect due to the head pressure.
- the controller may selectively control operation of the electrochemical cell assembly 10.
- the controller may only activate the electrochemical cell assembly 10 to generate ozone when the cistern valve is in the open position. Otherwise, the ozone in the water would spend a significant period of time in the cistern 40 and the ozone would therefore decay, reducing its concentration in the water eventually delivered to the plumbing fixture 20.
- the present invention may also be applied to systems 100 where a single plumbing fixture 20 is supplied by a cistern 40, such as shown in Figure 2.
- the single plumbing fixture 20 may be an elongated urinal 20 (also known as a trough or slab urinal) which is designed to be used simultaneously by multiple users.
- a trough or slab urinal also known as a trough or slab urinal
- multiple users may use the same urinal 20, with a shared trough for collecting fluids provided at a lower edge (when installed).
- a back wall and the trough collectively form the inner surface 21 or toilet bowl 21.
- the plumbing fixture 20 may include a plurality of water supply inlets 22.
- the plumbing fixture 20 may include a single water supply inlet 22 which is arranged to suitably direct the incoming water around the entire inner surface 21.
- the supply pipes 23 may collectively form a header pipe with the inlets extending therefrom or attached thereto.
- the water supply inlets 22 may be formed as holes in the header pipe.
- the water supply assembly and cistern 40 of this embodiment may operate in accordance with any of the disclosure relating to the embodiment of Figure 1.
- a water outlet (not shown) is formed at a lower (when installed) is formed.
- each water outlet may include a bottle trap as discussed above in relation to Figure 1.
- a system 100 according to the present invention can effectively clean and sanitise a plumbing assembly.
- the invention may be defined as the use of ozonated water having at least 0.7 ppm of ozone to clean a plumbing fixture.
- a system 100 in accordance with the present invention was tested.
- the system 100 included an electrochemical cell 10 installed downstream of an inlet flow valve and upstream of a cistern 40 for a urinal.
- the urinal included a left-hand and a right-hand urinal. Each of these urinals had a bottle trap.
- the bottle trap of the left-hand urinal was replaced with a new bottle trap the start of testing, while the right-hand urinal was left with its old bottle trap.
- the urinal Prior to the start of this test, the urinal was used with a conventional sanitising system to establish a comparative baseline. The urinal was regularly urinated in before the test and during the test.
- ATP monitoring is a rapid testing method used in Food and Beverage, Hospitality, Healthcare and many otherwhere the need to quickly assess the cleanliness of surfaces or liquid samples is needed.
- ATP is present in all organic material and is produced and/or broken down in metabolic processes in all living systems. ATP drives processes such as photosynthesis in plants, muscle contraction in humans, respiration in fungi, and fermentation in yeast. Therefore, most foods and microbial cells will contain some level of naturally occurring ATP.
- Luminometers in conjunction with ATP swabs use bioluminescence to detect residual ATP as an indicator of surface cleanliness.
- the presence of ATP on a surface indicates improper cleaning and the presence of contamination, including food residue, allergens and/or bacteria. This implies a potential for the surface to harbour and support bacterial growth leading to malodours.
- ATP is measured using Relative Light Unit’s (RLU’s)
- RLU Relative Light Unit
- a test swab is activated a bioluminescent reaction occurs, generating light output, the luminometer device then measures and quantifies the light with an RLU output.
- the RLU reading is directly proportional to the amount of ATP collected. Any dirt or debris collected on the swab will have an effect on the RLU reading leading to a high RLU output.
- the odour testing was carried out at three locations, outside the testing location, inside the testing location and immediately above the urinal.
- ATP readings were taken at a number of locations in the urinal and system. The base of the urinals were swabbed for ATP testing just prior to the urinal flushing. This would be between 25 and 30 minutes since the last flush. An ATP reading was also taken from an internal wall of the bottle trap for each of the left-hand and right-hand urinals. As a reminder, the left-hand bottle trap was brand new, while the right-hand bottle trap was an old trap. The right-hand trap was not replaced and so had a significant build-up of hardened uric acid (and/or uric salt) on its surfaces. At the start of the testing this was completely solid with no residue within the water of the bottle trap.
- the right-hand trap showed considerable deterioration in the hardened uric acid as the testing progressed, this debris has been in the water in the trap and has thus tainted the ATP swab with dirt leading to high readings.
- the areas on the right-hand trap that had previously been clear as the uric salt disintegrated were developing a residue believed to be calcium (i.e. limescale).
- the left-hand bottle trap was visibly clean at the end of the testing.
- the data shows the ATP readings being maintained low for new equipment, and a general improvement for old equipment after an initial dislodgement of built-up debris.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Sanitary Device For Flush Toilet (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
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GB2006948.0A GB2594943B (en) | 2020-05-12 | 2020-05-12 | Plumbing fixture sanitising system |
PCT/GB2021/051131 WO2021229216A1 (en) | 2020-05-12 | 2021-05-12 | Plumbing fixture sanitising system |
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EP4150168A1 true EP4150168A1 (en) | 2023-03-22 |
EP4150168B1 EP4150168B1 (en) | 2024-05-01 |
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JPH0756151B2 (en) * | 1988-03-15 | 1995-06-14 | 関西テック株式会社 | Toilet |
JPH06158701A (en) * | 1992-11-25 | 1994-06-07 | Yamada Kiichiro | Washing device in toilet stool |
TW272244B (en) * | 1994-08-19 | 1996-03-11 | Toto Ltd | |
DE10048299A1 (en) | 2000-09-29 | 2002-05-29 | Aqua Butzke Werke Gmbh | Device for electrolytic water disinfection while avoiding cathodic hydrogen evolution |
DE10259997B4 (en) * | 2002-12-20 | 2007-09-13 | Airbus Deutschland Gmbh | Aircraft toilet system |
JP4215113B2 (en) | 2005-07-26 | 2009-01-28 | パナソニック電工株式会社 | Flush toilet facilities |
DE102009035234A1 (en) * | 2009-07-29 | 2011-02-17 | Nonnenmacher, Klaus, Prof. Dipl.-Ing. | Device and method for disinfecting a toilet device |
JP5952647B2 (en) * | 2012-06-07 | 2016-07-13 | 株式会社タムラテコ | Public toilet wash water supply system |
EP3070211B1 (en) * | 2015-03-18 | 2019-09-11 | Aero Engineering, S.L. | Sterilizing device and method for a toilet |
EP3529397A4 (en) * | 2016-10-20 | 2020-06-24 | Advanced Diamond Technologies, Inc. | Ozone generators, methods of making ozone generators, and methods of generating ozone |
GB2556948A (en) | 2016-11-29 | 2018-06-13 | Roseland Holdings Ltd | Toilet assembly and method for its operation |
US10920408B2 (en) * | 2018-10-24 | 2021-02-16 | Hall Labs Llc | Antimicrobial toilet with electrolyzer |
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WO2021229216A1 (en) | 2021-11-18 |
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GB202006948D0 (en) | 2020-06-24 |
EP4150168C0 (en) | 2024-05-01 |
GB2594943B (en) | 2022-08-24 |
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