EP4061319A1

EP4061319A1 - Sunscreen compositions with multiple photoprotecting uv filters

Info

Publication number: EP4061319A1
Application number: EP20824816.1A
Authority: EP
Inventors: Marc Pissavini; Karine Julien; Carine GUILLERMINET; Olivier Doucet
Original assignee: Coty Inc
Current assignee: Coty Inc
Priority date: 2019-11-20
Filing date: 2020-11-19
Publication date: 2022-09-28
Also published as: CN114746070A; BR112022009548A2; WO2021102113A1

Abstract

Provided is a UV filter composition comprising: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter.

Description

SUNSCREEN COMPOSITIONS WITH MULTIPLE PHOTOPROTECTING UV

FILTERS

RELATED APPLICATIONS [001] This application claims the benefit of priority to U S. Provisional Patent

Application Serial No. 62/937,989 entitled “SUNSCREEN COMPOSITIONS WITH MULTIPLE PHOTOPROTECTING UV FILTERS,” filed November 20, 2019, the disclosure of which is incorporated herein in its entirety by reference. This application also claims the benefit of priority to U.S. Provisional Patent Application Serial No. 62/948,990 entitled “SUNSCREEN COMPOSITIONS WITH MULTIPLE PHOTOPROTECTING UV FILTERS,” filed December 17, 2019, the disclosure of which is incorporated herein in its entirety by reference.

[002] Disclosed herein are new compositions for use as sunscreens that comprise multiple photoprotecting UV filters. The combination of UV filters provides efficient protection, upon application to exposed skin, from a broad range of UV wavelengths.

BACKGROUND

[003] Exposure to sunlight presents a hazard to health, whose significance has increased in recent decades. Acute exposure to sunlight can lead to sunburn, which is characterized by skin irritation and reddenning. More significantly, prolonged exposure to the sun increases the risk of skin cancer. Of the various subtypes of skin cancer, melanoma presents the greatest risk, since it is particularly aggressive and difficult to treat if not caught before spreading. The American Cancer Society estimates that nearly 100,000 cases of melanoma will be diagnosed in 2019, accompanied by about 7,000 fatalities. Finally, exposure to sunlight has been implicated in premature skin aging, hair damage, and eye damage (including cataracts).

[004] The ultraviolet region of solar radiation, falling between 200 nm to 400 nm, can be classified into three regions: from 320 to 400 nm (UV-A), from 290 to 320 nm (UV-B), and from 200 to 290 nm (UV-C), the latter of which generally does not penetrate Earth’s atmosphere. Historically, more attention has been paid to the health risks of UV-B exposure; more recently, however, the damage that can be potentially caused by UV-A has been more greatly appreciated., and melanoma and other skin cancers. Therefore, protection from too much UV-A and UV-B radiation is an important part of personal care. [005] Despite the long history for the marketing use of sunscreens, newly identified health and (especially) environmental concerns are prompting the development of new compounds and compositions, both for improved preventative properties and increased consumer acceptance. There is a significant, unmet need for methods for new sunscreens. The present disclosure fulfills these and other needs, as evident in reference to the following disclosure.

[006] Provided is a sunscreen composition.

[007] Provided is a UV filter composition comprising: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter.

SUMMARY

[008] Also provided is a sunscreen composition comprising a UV filter composition described herein.

[009] Also provided is a method for protecting skin from sun damage comprising applying a sunscreen composition described herein to the skin.

[010] These and other aspects of the invention will be apparent upon reference to the following detailed description. To this end, various references are set forth herein which describe in more detail certain background information, procedures, compounds, and/or compositions, and are each hereby incorporated by reference in their entirety.

BRIEF DESCRIPTION OF THE FIGURES [011] The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present document.

[012] FIG. 1 is a graph that shows that the in vivo SPF of Formula 1 and Formula 2 are substantially the same as the SPF of Comparative Formula, according to Example 5.

[013] FIG. 2 is a graph that shows that Formula 1 has substantialy the same PPD as Comparative Formula, according to Example 5.

[014] FIG. 3 is a graph that shows that Formula 1 has substantially the same SPF/PPD quotient as Comparative Formula, according to Example 5. [015] FIG. 4 is a graph that shows that Formula 3 has an improved SPF relative to

Comparative Formula, according to Example 5.

[016] FIG. 5 is a graph that shows that Formula 3 has substantially the same SPF/PPD quotient as Comparative Formula, according to Example 5. [017] FIG. 6 is a graph that shows that Formula 3 has substantially the same SPF/PPD quotient as Comparative Formula, according to Example 5.

DETAILED DESCRIPTION [018] In the following description, certain specific details are set forth in order to provide a thorough understanding of various embodiments. However, one skilled in the art will understand that the invention may be practiced without these details. In other instances, well-known structures have not been shown or described in detail to avoid unnecessarily obscuring descriptions of the embodiments. Unless the context requires otherwise, throughout the specification and claims which follow, the word “comprise” and variations thereof, such as, “comprises” and “comprising” are to be construed in an open, inclusive sense, that is, as “including, but not limited to." Further, headings provided herein are for convenience only and do not interpret the scope or meaning of the claimed invention.

[019] Reference throughout this specification to “one embodiment” or “an embodiment” or “some embodiments” or “a certain embodiment” means that a particular feature, structure or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” or “in some embodiments” or “in a certain embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments.

[020] Also, as used in this specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the content clearly dictates otherwise.

[021] Where applicable, chemicals are specified according to their INCI Name. Additional information, including definitions, suppliers, and trade names, can be found under the appropriate INCI monograph in the International Cosmetic Ingredient Dictionary and Handbook, 16th Edition published by the Personal Care Products Council, Washington D.C. Also available via the Personal Care Products Council On-Line INFOBASE (http://online.personalcarecouncil.Org/j sp/Home.j sp). [022] When ranges of values are disclosed, and the notation “from n1 ... to n2” or

“between n1 ... and n2” is used, where n1 and n2 are the numbers, then unless otherwise specified, this notation is intended to include the numbers themselves and the range between them. This range may be integral or continuous between and including the end values. By way of example, the range “from 2 to 6 carbons" is intended to include two, three, four, five, and six carbons, since carbons come in integer units. Compare, by way of example, the range “from 1 to 3 μΜ (micromolar),” which is intended to include 1 μΜ, 3 μΜ, and everything in between to any number of significant figures (e.g., 1.255 μΜ, 2.1 μΜ, 2.9999 μΜ, etc.).

[023] The term “about,” as used herein, is intended to qualify the numerical values which it modifies, denoting such a value as variable within a margin of error. When no particular margin of error, such as a standard deviation to a mean value given in a chart or table of data, is recited, the term “about” should be understood to mean that range which would encompass the recited value and the range which would be included by rounding up or down to that figure as well, taking into account significant figures. [024] Unless otherwise indicated, a percentage or concentration refers to a percentage or concentration by weight (i.e., % (W/W)). Unless stated otherwise, all ranges are inclusive of the endpoints, e g., “from 4 to 9” includes the endpoints 4 and 9.

[025] As used herein, the term “cosmetically effective amount” refers an amount of a physiologically active compound or composition sufficient for treating one or more conditions, but low enough to avoid serious side effects. The cosmetically effective amount of the compound or composition will vary with the condition being treated, the age and physical condition of the end user, the severity of the condition being treated/prevented, the duration of the treatment, the nature of other treatments, the specific compound or product/composition employed, the cosmetically-acceptable carrier utilized, and like factors. [026] As used herein, the term “cosmetically acceptable” means refers to a composition, the the ingredients of which being suitable for use in contact with tissues (e.g., the skin) without undue toxicity, irritation, incompatibility, instability, allergic response, or other adverse effect.

[027] The term “sun protection factor”, abbreviated as “SPF”, or “UV protection factor”, is determined using a combination of experimental and theoretical absorption data as disclosed in US 6,820,014, which is hereby incorporated by reference. Other methods for determining SPF are known in the art.

[028] The term “persistent pigment darkening”, abbreviated as “PPD”, is a method of measuring UVA protection, similar to the SPF method of measuring sunburn protection. Instead of measuring erythema, the PPD method uses UVA radiation to cause a persistent darkening or tanning of the skin. Theoretically, a sunscreen with a PPD rating of 10 should allow a person 10 times as much UVA exposure as would be without protection. Methods for determining PPD are known in the art. [029] As used herein, the term “UV-A” refers to electromagnetic radiation having a wavelength between 320 and 400 nm.

[030] As used herein, the term “UV-B” refers to electromagnetic radiation having a wavelength between 290 and 320 nm. [031] As used herein, the term “broad spectrum” UV refers to electromagnetic radiation having a wavelength from 290 to 400 nm. Determination of “ broad spectrum” is made in accordance with 21 C.F.R. 201.327(j) (2019).

[032] As used herein, the term “critical wavelength” is the wavelength at which the integral of the spectral absorbance curve is 90 percent of the integral over the UV spectrum from 290 to 400 nm.

[033] As used herein, the term “photostable” refers to the ability of a molecule to remain intact with irradiation. Photostability can be quantified by comparing the degree of protection and after irradiation. See, e.g., Pissavini, et al. (2012) “New Method to Reproduce In Vitro Cosmetic Product Photostability Findings” Cosmetics & Toiletries 127(3):208-218, which is incorporated by reference for all purposes. Other methods known in the art can also be used to determine photostability.

[034] As used herein, the term “topical application” refers to the directly application by spraying, wiping, or spreading on outer skin or the scalp. Topical application can be performed with the hands, or with the use of an applicator such as a wipe, roller, or spray. [035] As used herein, the term “cosmetic” refers to a beautifying substance or preparation which preserves, restores, bestows, simulates, or enhances the appearance of bodily beauty or appears to enhance the beauty or youthfulness, specifically as it relates to the appearance of tissue or skin.

[036] As used herein, the term “sunscreen composition” refers to a formulation, including but not limited to: a spray, oil, lotion, cream, gel, butter, paste, ointment, stick, powder, wipe, towelette, body wash, shampoo, or other topical product, that absorbs and/or reflects some of the sun's ultraviolet (UV) radiation. A sunscreen composition will thus provide protection against negative effects of sun exposure, e g. sunburn, premature aging, etc. [037] Provided is a UV filter composition comprising: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter. Also provided is a UV filter composition consisting of: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter.

[038] In certain embodiments, the UV-A filter is chosen from • Butyl methoxydibenzoylmethane or l-(4-tert-Butylphenyl)-3-(4-methoxyphenyl) propane- 1 , 3 -dione,

• Terephthalylidene dicamphor sulphonic acid or 3,3'-(l,4-Phenylenedimethylene) bis (7,7-dimethyl-2-oxobicyclo-[2.2.1] hept-l-ylmethanesulfonic acid) and its salts,

• Menthyl Anthranilate,

• Bisdisulizole Disodium or di sodium phenyl dibenzimidazole tetrasulfonate,

• Diethylamino Hydroxybenzoyl Hexyl Benzoate, and

• Dimethoxyphenyl-[l-(3,4)]-4, 4-dimethyl 1,3-pentanedione.

[039] In certain embodiments, the UV-A filter is chosen from butyl methoxydibenzoylmethane, diethylamino hydroxy benzoyl hexyl benzoate, disodium phenyl dibenzylimidazole tetrasulfonate, and terephthalylidene dicamphor sulfonic acid.

[040] In certain embodiments, the UV-A filter is chosen from butyl methoxydibenzoylmethane, and menthyl anthranilate.

[041] In certain embodiments, the UV-A filter is butyl methoxydibenzoylmethane. [042] In certain embodiments, the three UV-B filters are independently chosen from

• 3-Benzylidene camphor,

• Benzylidene camphor sulfonic acid,

• Enzacamene or 4-methylbenzylidene camphor or 4-MBC,

• 2-ethoxyethyl-p-methoxycinnamate,

• DEA methoxycinnamate,

• Iscotrizinol or diethylhexyl butamido triazone or Benzoic acid, 4,4-{[6-[[[(l,l- dimethylethyl)amino]carbonyl]phenyl]amino]-l,3-5-triazine-2,4-diyl]diimino}bis-, bis(2-ethylhexyl)ester,

• Digalloyl trioleate,

• Diisopropyl methyl cinnamate,

• Ethyl dihydroxypropyl PABA,

• Ethylhexyl dimethoxy benzylidene dioxoimidazoline propionate,

• Octyl dimethyl-PABA or 2-Ethylhexyl 4-(dimethylamino)benzoate,

• Octyl Methoxycinnamate or 2-Ethylhexyl 4-methoxycinnamate,

• Octyl Salicylate or 2-Ethylhexyl salicylate,

• Octyl Triazone or Ethylhexyl triazone or 2, 4, 6-Trianilino-(p-carbo-2' -ethylhexyl- 1 '- oxy)-l,3,5-triazine,

• Ferulic acid, Glyceryl ethylhexanoate dimethoxycinnamate,

Glyceryl PABA,

Benzoic acid, 2-hydroxy-, 3,3,5-trimethylcyclohexyl ester,

Isoamyl p-methoxycinnamate or Isopentyl-4-methoxycinnamate,

Isopentyl trimethoxycinnamate trisiloxane,

Isopropyl benzyl salicylate,

Isopropyl methoxycinnamate,

Lawsone + dihydoxyacetone,

4-Methylbenzylidene camphor,

2-Cyano-3, 3-diphenyl acrylic acid 2-ethylhexyl ester,

Aminobenzoic Acid (PABA),

PEG-25 PABA,

Pentyl dimethyl PABA,

Phenylbenzimidazole sulfonic acid or 2-Phenylbenzimidazole-5-sulphonic acid and its potassium, sodium and triethanolamine salts,

Polyacrylamido methylbenzylidene camphor, poly silicone- 15 or Dimethicodiethylbenzalmalonate,

Salicylic acid, and

TEA salicylate (Trolamine Salicylate). [043] In certain embodiments the three UV-B filters are independently chosen from ethylhexyl dimethyl PABA, ethylhexyl methoxycinnamate, ethylhexyl salicylate, homosalate, octocrylene, PABA, and phenyl benzimidazole sulfonic acid. In certain embodiments, any compositions described herein can be free of octocrylene.

[044] In certain embodiments the three UV-B filters are independently chosen from 3- benzylidene camphor, benzylidene camphor sulfonic acid, camphor benzalkonium methosulfate, diethylhexyl butamido triazone, ethylhexyl dimethyl PABA. ethylhexyl methoxycinnamate, ethylhexyl salicylate, ethylhexyl triazone, homosalate, isoamyl p- methoxycinnamate, 4-methylbenzylidene camphor, octocrylene, PABA, PEG-25 PABA, phenyl benzimidazole sulfonic acid, polyacrylamido methylbenzylidene camphor, and polysilicone-15. In certain embodiments the three UV-B filters are independently chosen from cinoxate, ethylhexyl dimethyl PABA, ethylhexyl methoxycinnamate, ethylhexyl salicylate, homosalate, octocrylene, PABA, phenyl benzimidazole sulfonic acid, and TEA salicylate. In certain embodiments, the three UV-B filters are independently chosen from isoamyl p-methoxycinnamate, ethylhexyl triazone, diethylhexyl butamido triazone, and ethylhexyl salicylate. In certain embodiments, the three UV-B filters are isoamyl p- methoxycinnamate, ethylhexyl triazone, and octyl salicylate.

[045] In certain embodiments, the broad band UV-A and UV-B filter is chosen from

• Benzophenone,

• Benzophenone- 1,

• Benzophenone-2,

• Benzophenone-3 or 2-Hydroxy-4-methoxybenzophenone,

• Benzophenone-4 or 2-Hydroxy-4-methoxybenzophenone-5 -sulfonic acid (Benzophenone-5) and its sodium salt,

• Benzophenone-5,

• Benzophenone-6,

• Dioxybenzone (Benzophenone-8),

• Benzophenone-9,

• Beta-2-Glucopyranoxy propyl hydroxy benzophenone,

• Bemotrizinol or bis-ethylhexyloxyphenol methoxyphenyl triazine or 2,2'-(6-(4- Methoxyphenyl)-l,3,5-triazine-2,4-diyl)bis(5-((2-ethylhexyl)oxy)phenol),

• Drometrizole,

• Drometrizole Trisiloxane or Phenol, 2-(2H-Benzotriazol-2-yl)-4-Methyl-6-(2-Methyl- 3-(l ,3,3,3-Tetramethyl-l -(Trimethylsilyl)Oxy)-Disiloxanyl)Propyl,

• Bisoctrizol or methylene bis-benzotriazolyl tetramethylbutylphenol,

• Titanium Dioxide, and

• Zinc Oxide.

[046] In certain embodiments, the broad band UV-A and UV-B filter is chosen from benzophenone-3 and titanium dioxide. In certain embodiments, the broad band UV-A and UV-B filter is chosen from benzophenone-3, benzophenone-4, benzophenone-5, bis- ethylhexyloxyphenol methoxyphenyl triazine, drometrizole trisiloxane, Methylene bis- benzotriazolyl tetramethylbutylphenol, and titanium dioxide. In certain embodiments, the broad band UV-A and UV-B filter is chosen from benzophenone-3, benzophenone-4, benzophenone-8, titanium dioxide and zinc oxide. In certain embodiments, the UV-A + UV- B broadband filter is bis ethylhexyloxyphenol methoxyphenyl triazine. [047] Also provided is a UV filter composition comprising isoamyl p- methoxycinnamate, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane and bis-ethylhexyloxyphenol methoxyphenyl triazine.

[048] Also provided is a UV filter composition consisting of isoamyl p- methoxycinnamate, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane and bis-ethylhexyloxyphenol methoxyphenyl triazine.

[049] Also provided is a UV filter composition comprising diethylhexyl butamido triazone, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane, and bis- ethylhexyloxyphenol methoxyphenyl triazine. [050] Also provided is a UV filter composition consisting of diethylhexyl butamido triazone, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane, and bis- ethylhexyloxyphenol methoxyphenyl triazine.

[051] Also provided is a UV filter composition comprising diethylhexyl butamido triazone, isoamyl p-methoxycinnamate, octyl salicylate, butyl methoxydibenzoylmethane, and bis-ethylhexyloxyphenol methoxyphenyl triazine.

[052] Also provided is a UV filter composition consisting of diethylhexyl butamido triazone, isoamyl p-methoxycinnamate, octyl salicylate, butyl methoxydibenzoylmethane, and bis-ethylhexyloxyphenol methoxyphenyl triazine.

[053] Also provided is a sunscreen composition comprising a UV filter composition comprising isoamyl p-methoxycinnamate, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane and bis-ethylhexyloxyphenol methoxyphenyl triazine.

[054] Also provided is a sunscreen composition comprising a UV filter composition comprising diethylhexyl butamido triazone, ethylhexyl triazone, octyl salicylate, butyl methoxydibenzoylmethane, and bis-ethylhexyloxyphenol methoxyphenyl triazine. [055] Also provided is a sunscreen composition comprising a UV filter composition comprising diethylhexyl butamido triazone, isoamyl p-methoxycinnamate, octyl salicylate, butyl methoxydibenzoylmethane, and bis-ethylhexyloxyphenol methoxyphenyl triazine. [056] In certain embodiments, the sunscreen composition does not comprise nanoparticles. [057] In certain embodiments, the sunscreen composition does not comprise benzonephenone-3.

[058] In certain embodiments, the sunscreen composition does not comprise octyl methoxycinnamate. [059] In certain embodiments, the composition does not comprise a cinnamate ester other than isoamyl p-methoxy cinnamate.

[060] In certain embodiments, the sunscreen composition does not comprise 2- ethylhexyl 2-cyano-3,3-diphenylacrylate. [061] In certain embodiments, the sunscreen composition does not comprise 2-

(Benzotriazol-2-yl)-4,6-di-tertbutylphenol, 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl) phenol, 2-(Benzotriazol-2-yl)-4,6-bis-(l,l-dimethylpropyl)-phenol, or 2-(Benzotriazol-2-yl)- 6-butan2-yl-4-tertbutyl phenol .

[062] In certain embodiments, each of the UV filters in the sunscreen composition is present in an amount of from about 0.1 to about 25% w/w, about 0.1 to about 20% w/w, about 0.1 to about 18% w/w, 0.1 to about 15% w/w, about 0.1 to about 12% w/w, about 0.1 to about 10% w/w, 0.1 to about 8% w/w, about 0.1 to about 6% w/w, wherein the weight percent is based on the total weight of the sunscreen composition.

[063] In certain embodiments, the sunscreen composition comprises less than about 35% w/w UV filters. In certain embodiments, the sunscreen composition comprises between about 5% and about 25% w/w UV filters. In certain embodiments, the sunscreen composition comprises about 20% w/w UV filters.

[064] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine.

[065] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine.

[066] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine. [067] In certain embodiments, the sunscreen composition comprises the following: UV-

A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 : 7: 1. [068] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bi s-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 : 5.5 : 1.

[069] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 2 : 7 : 1.

[070] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 : 7 : 1.

[071] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 : 11 : 2.

[072] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 1 : 3 : 1.

[073] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 : 13 : 2.

[074] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 : 13 : 2.

[075] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 4 : 13 : 2.

[076] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 6.

[077] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4.

[078] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 6 : 17 : 6.

[079] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 13 : 6.

[080] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4.

[081] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 7 : 13 : 6.

[082] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 : 2 : 1.

[083] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 3 : 8.5 : 2.

[084] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 1 : 2 : 1.

[085] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 11 : 6.

[086] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 11 : 6.

[087] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxy ci nnam ate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 7 : 11 : 6. [088] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8.

[089] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7.

[090] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 24 : 8.

[091] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 19 : 8.

[092] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 19 : 8.

[093] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 19 : 8.

[094] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 17 : 8.

[095] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7.

[096] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 17 : 8.

[097] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 25 : 7.

[098] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 25 : 7.

[099] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 25 : 7.

[0100] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9: 23 : 8.

[0101] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 23 : 8.

[0102] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 23 : 8.

[0103] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8.

[0104] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7.

[0105] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 18 : 8.

[0106] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8.

[0107] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7. [0108] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 18 : 8.

[0109] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 15 : 8.

[0110] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8.

[0111] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxy ci nnam ate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 15 : 8.

[0112] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 16 : 8.

[0113] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8.

[0114] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 16 : 8.

[0115] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter Isoamyl p-methoxycinnamate, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 15 : 8.

[0116] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Ethylhexyl triazone, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8.

[0117] In certain embodiments, the sunscreen composition comprises the following: UV- A filter Butyl methoxydibenzoylmethane, UV-B filter Isoamyl p-methoxycinnamate, UV-B filter octyl salicylate, UV-B filter diethylhexyl butamido triazone, and broad band UV-A and UV-B filter bis-ethylhexyloxyphenol methoxyphenyl triazine wherein the mass ratio of UV- A filter to UV-B filters to broad band filter is about 9 : 15 : 8.

[0118] In certain embodiments, the ratio of UVAAJVB filters in the sunscreen composition is between about 0.6 and about 0.8. In certain embodiments, the ratio of UVAAJVB filters in the sunscreen composition is about 0.7.

[0119] In certain embodiments, the sunscreen composition has a mean critical wavelength of about 370 nm or greater. In certain embodiments, the sunscreen composition has a mean critical wavelength of about 375 nm.

[0120] In certain embodiments, the sunscreen composition has an SPF of at least about 15, such as about 15. In certain embodiments, the composition has an SPF of at least about

30. In certain embodiments, the composition has an SPF of at least about 50. In certain embodiments, the composition has an SPF of at least about 60.

[0121] In certain embodiments, the sunscreen composition further comprises a solubilizer. In certain embodiments, the solubilizer acts to solubilize the UV filters. In certain embodiments, the solubilizer acts to avoid solid particles formation. In certain embodiments, the sunscreen composition comprises a lower level of solubilizers. In certain embodiments, the ratio of UV solubilizers to UV filters is between about 0.5 and about 2.3, such as about 0.5, about 0.6, about 0.7, about 0.8, about 0.9, about 1, about 1.1, about 1.2, about 1.3, about 1.4, about 1.5, about 1.6, about 1.7, about 1.8, about 1.9, or about 2.0. [0122] In certain embodiments, the sunscreen composition comprises at most about 36% w/w solubilizer. In certain embodiments, the sunscreen composition comprises about 20% w/w solubilizer. In certain embodiments, the sunscreen composition comprises less than about 20% w/w solubilizer. In certain embodiments, the sunscreen composition comprises between about 15 and 20% w/w solubilizer.

[0123] In certain embodiments, the sunscreen composition comprises between about 0.1% to about 5% w/w solubilizer. In certain embodiments, the sunscreen composition comprises between about 0.1% to about 15% w/w solubilizer. In certain embodiments, the sunscreen composition comprises between about 0.1% to about 25% w/W solubilizer. In certain embodiments, the sunscreen composition comprises between about 0.1% to about

35% w/w solubilizer.

[0124] In certain embodiments, the sunscreen composition comprises at least one solubilizer chosen from the one or more solubilizers are chosen from diisopropyl sebacate, dicapiylyl carbonate, decyl cocoate, diisopropyl adipate, isopropyl lauroyl sarcosinate, dibutyl adipate, butyloctyl salicylate, C 12-15 alkyl benzoate, and diethylhexyl succinate. In certain embodiments, the sunscreen composition comprises at least one solubilizer chosen from Diisopropyl sebacate, Diisopropyl adipate, Dicapiylyl carbonate, Dibutyl adipate, Butyloctyl salicylate, Decyl cocoate, Cl 2- 15 alkyl benzoate, Diethylhexyl succinate, Diethylhexyl carbonate, and Isopropyl lauroyl sarcosinate. [0125] In certain embodiments, the sunscreen composition comprises two solubilizers chosen from Diisopropyl sebacate, Diisopropyl adipate, Dicapiylyl carbonate, Dibutyl adipate, Butyloctyl salicylate, Decyl cocoate, Cl 2- 15 alkyl benzoate, Diethylhexyl succinate, Diethylhexyl carbonate, and Isopropyl lauroyl sarcosinate. In certain embodiments, the sunscreen composition comprises three solubilizers chosen from Diisopropyl sebacate, Diisopropyl adipate, Dicaprylyl carbonate, Dibutyl adipate, Butyloctyl salicylate, Decyl cocoate, C12-15 alkyl benzoate, Diethylhexyl succinate, Diethylhexyl carbonate, and Isopropyl lauroyl sarcosinate.

[0126] In certain embodiments, the sunscreen composition comprises 0.1% to 5% w/w of ethylhexyl salicylate and optionally at least one additional solubilizer. [0127] In certain embodiments, the sunscreen composition comprises 0.1% to 25% w/w of at least one solubilizer chosen from Dibutyl adipate, Cl 2- 15 alkyl benzoate, Diethylhexyl succinate, Diethylhexyl carbonate, and Isopropyl lauroyl sarcosinate and optionally at least one additional solubilizer. [0128] In certain embodiments, the sunscreen composition comprises 0.1 % to 25% w/w of at least one solubilizer chosen from Diisopropyl sebacate, Diisopropyl adipate, Dicaprylyl carbonate, and Decyl cocoate and optionally at least one additional solubilizer.

[0129] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

7 : 1, and wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 5% to about 9% of diisopropyl sebacate, e.g., from about 6% to about 8% of diisopropyl sebacate.

[0130] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

5.5 : 1, wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 8% to 10% of diisopropyl sebacate.

[0131] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

[0132] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

7 : 2, and wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 5% to about 9% of diisopropyl sebacate, e.g., from about 6% to about 8% of diisopropyl sebacate.

[0133] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bi s-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

11 : 2 and wherein the composition comprises the solubilizer dibutyl adipate, such as from about 8% to about 11% of dibutyl adipate, e.g., from about 9% to about 10%.

[0134] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 :

3 : 1, and wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 5% to about 9% of diisopropyl sebacate, e.g., from about 6% to about 8% of diisopropyl sebacate.

[0135] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

13 : 2, and wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 5% to about 9% of diisopropyl sebacate, e.g., from about 6% to about 8% of diisopropyl sebacate. [0136] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl m ethoxy dibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

13 : 2, and wherein the composition comprises the solubilizer diisopropyl sebacate, such as from about 5% to about 9% of diisopropyl sebacate, e.g., from about 6% to about 8% of diisopropyl sebacate.

[0137] In certain embodiments, the sunscreen composition comprises, wherein: the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4, and wherein the composition further comprises diisopropyl sebacate and dicapiylyl carbonate, such as from about 13% to about 15.5% of a mixture of diisopropyl sebacate and dicaprylyl carbonate, e.g., from about 13.5% to about 15% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0138] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4 and wherein the composition further comprises diisopropyl sebacate and dicaprylyl carbonate, such as from about 13% to about 15.5% of a mixture of diisopropyl sebacate and dicaprylyl carbonate, e.g., from about 13.5% to about 15% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0139] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4, and wherein the composition further comprises diisopropyl sebacate and dicaprylyl carbonate, such as from about 13% to about 15.5% of a mixture of diisopropyl sebacate and dicaprylyl carbonate, e g., from about 13.5% to about 15% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0140] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 17 : 6, and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 18% to about 20% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e.g., from about from about 18.5% to about 19.5% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0141] In certain embodiments, the sunscreen composition comprises the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about is about 6 : 17: 4 and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 18% to about 20% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e g., from about from about 18.5% to about 19.5% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0142] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 13 : 6, and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 16% to about 18% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e.g., from about 16.5% to about 17.5% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate. [0143] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 :

2 : 1, and wherein the composition further comprises decyl cocoate and diisopropyl sebacate, such as from about 19% to about 21% of a mixture of decyl cocoate and diisopropyl sebacate, e.g., from about 19.5% to about 20.5% of a mixture of decyl cocoate and diisopropyl se. [0144] In certain embodiments, the sunscreen composition comprises, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 3 : 8.5 : 2, and wherein the composition further comprises decyl cocoate and diisopropyl sebacate, such as from about 19% to about 21% of a mixture of decyl cocoate and diisopropyl sebacate, e.g., from about 19.5% to about 20.5% of a mixture of decyl cocoate and diisopropyl sebacate. [0145] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 :

2 : 1, and wherein the composition further comprises decyl cocoate and diisopropyl sebacate, such as from about 19% to about 21% of a mixture of decyl cocoate and diisopropyl sebacate, e.g., from about 19.5% to about 20.5% of a mixture of decyl cocoate and diisopropyl se.

[0146] In certain embodiments, the sunscreen composition comprises, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, w wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7

: 11 : 6, and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 19.5% to about 21.5% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 20% to about 21% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0147] In certain embodiments, the sunscreen composition comprises, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 :

17 : 4, and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 19.5% to about 21.5% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 20% to about 21% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0148] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxyci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bi s-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 :

11 : 6, and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 19.5% to about 21.5% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 20% to about 21% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0149] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bi s-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 :

17 : 4 and wherein the composition further comprises diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, such as from about 16% to about 18% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, e.g., from about 16.5% to about 17.5% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0150] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 :

[0151] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido tiiazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 11: 6, and wherein the composition further comprises diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, such as from about 16% to about 18% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, e g., from about 16.5% to about 17.5% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0152] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 18% to about 22% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 19% to about 21% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0153] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 25% to about 29% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 26% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0154] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 25% to about 29% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 26% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0155] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises diisopropyl sebacate and diisopropyl adipate, such as from about 32.5% to about 35.5% of a mixture of diisopropyl sebacate and diisopropyl adipate, e.g., from about 33% to about 35% of a mixture of diisopropyl sebacate and diisopropyl adipate. [0156] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is 9 : 20 : 7, and wherein the composition further comprises diisopropyl sebacate and diisopropyl adipate, such as from about 32.5% to about 35.5% of a mixture of diisopropyl sebacate and diisopropyl adipate, e.g., from about 33% to about 35% of a mixture of diisopropyl sebacate and diisopropyl adipate.

[0157] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

24 : 8, and wherein the composition further comprises diisopropyl sebacate and diisopropyl adipate, such as from about 32.5% to about 35.5% of a mixture of diisopropyl sebacate and diisopropyl adipate, e.g., from about 33% to about 35% of a mixture of diisopropyl sebacate and diisopropyl adipate.

[0158] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, such as from about 22.5% to about 25.5% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, e.g., from about 23% to 25% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate. [0159] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7, wherein the composition further comprises diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, such as from about 22.5% to about 25.5% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, e.g., from about 23% to 25% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate. [0160] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, such as from about 22.5% to about 25.5% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate, e.g., from about 23% to 25% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate. [0161] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 28% to about 31% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e.g., from about 29% to about 30% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0162] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7, and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 28% to about 31% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e.g., from about 29% to about 30% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate. [0163] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8, and wherein the composition further comprises decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, such as from about 28% to about 31% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate, e.g., from about 29% to about 30% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0164] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

19 : 8, and wherein the composition further comprises diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, such as from about 18% to about 22% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate, e.g., from about 20% to about 21% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0165] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

[0166] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

19 : 8, and wherein the composition further comprises diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, such as from about 29% to about 33% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, e g., from about 30% to about 32% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0167] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

19 : 8, and wherein the composition further comprises diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, such as from about 29% to about 33% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, e.g.,from about 30% to about 32% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0168] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 17 : 8, and wherein the composition further comprises diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0169] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7, and wherein the composition further comprises diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0170] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 17 : 8, and wherein the composition further comprises diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate. [0171] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 25 : 7 and wherein the composition further comprises diisopropyl sebacate and dicaprylyl carbonate, such as from about 17% to about 20% of a mixture of diisopropyl sebacate and dicaprylyl carbonate, e.g., from about 18% to about 19% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0172] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 25 : 7 and wherein the composition further comprises diisopropyl sebacate and dicaprylyl carbonate, such as from about 17% to about 20% of a mixture of diisopropyl sebacate and dicaprylyl carbonate, e.g., from about 18% to about 19% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0173] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 23 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 20% to about 23% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 21% to about 22% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0174] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 23 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 20% to about 23% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 21% to about 22% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0175] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 24% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 25% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0176] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8 and wherein the composition further comprises diisopropyl sebacate, dicapiylyl carbonate, and decyl cocoate, such as from about 24% to about 28% of a mixture of diisopropyl sebacate, dicapiylyl carbonate, and decyl cocoate, e.g., from about 25% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0177] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

18 : 8 and wherein the composition further comprises diisopropyl sebacate, dicapiylyl carbonate, and decyl cocoate, such as from about 23% to about 26% of a mixture of diisopropyl sebacate, dicapiylyl carbonate, and decyl cocoate, e.g., from about 24% to about 25% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0178] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

20 : 7, and wherein the composition further comprises dibutyl adipate, and decyl cocoate, such as from about 31% to about 34% of a mixture of dibutyl adipate, and decyl cocoate, e.g., from about 32% to about 33% of a mixture of dibutyl adipate, and decyl cocoate.

[0179] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

18 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 23% to about 26% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 24% to about 25% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0180] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8 and wherein the composition further comprises diisopropyl sebacate, decyl cocoate, and diisopropyl adipate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate. [0181] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8 and wherein the composition further comprises diisopropyl sebacate, decyl cocoate, and diisopropyl adipate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate.

[0182] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 16 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 24% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 25% to about 26% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0183] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8 and wherein the composition further comprises dibutyl adipate, such as from about 36% to about 39% of dibutyl adipate, e.g., from about 37% to about 38% dibutyl adipate. [0184] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxy ci nnam ate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 16 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 24% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 25% to about 26% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0185] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 16 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0186] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8 and wherein the composition further comprises dibutyl adipate, and decyl cocoate, such as from about 31% to about 34% of a mixture of dibutyl adipate, and decyl cocoate, e.g., from about 32% to about 33% of a mixture of dibutyl adipate, and decyl cocoate.

[0187] In certain embodiments, the sunscreen composition comprises: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 15 : 8 and wherein the composition further comprises diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, such as from about 25% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate, e.g., from about 26% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0188] In certain embodiments, the sunscreen composition is an emulsion. In certain embodiments, the composition is an oil-in-water emulsion. In certain embodiments, the composition is a water-in-oil emulsion. In certain embodiments, the sunscreen composition is a spray. In certain embodiments, the sunscreen composition is an oil. In certain embodiments, the sunscreen composition is a lotion. In certain embodiments, the sunscreen composition is a cream. In certain embodiments, the sunscreen composition is a gel. In certain embodiments, the sunscreen composition is a butter. In certain embodiments, the sunscreen composition is a paste. In certain embodiments, the sunscreen composition is an ointment. In certain embodiments, the sunscreen composition is a stick. In certain embodiments, the sunscreen composition is a powder. In certain embodiments, the sunscreen composition is a wipe. In certain embodiments, the sunscreen composition is a towelette. In certain embodiments, the sunscreen composition is a body wash. In certain embodiments, the sunscreen composition is a shampoo. In certain embodiments, the sunscreen composition is a mist. In certain embodiments, the sunscreen composition is a poured compact. In certain embodiments, the sunscreen composition is a solution. In certain embodiments, the sunscreen composition is an ointment. In certain embodiments, the sunscreen composition is a liquid. In certain embodiments, the sunscreen composition is a solid. In certain embodiments, the sunscreen composition is a milk. In certain embodiments, the sunscreen composition is a suspension. In certain embodiments, the sunscreen composition is a microemulsion. In certain embodiments, the sunscreen composition is a dispersion. In certain embodiments, the sunscreen composition is a microencapsulated product. In certain embodiments, the sunscreen composition is a balm. In certain embodiments, the sunscreen composition is a tonic. In certain embodiments, the sunscreen composition is a paste. In certain embodiments, the sunscreen composition is a peel. In certain embodiments, the sunscreen composition is a soap. In certain embodiments, the sunscreen composition is an aerosol. In certain embodiments, the sunscreen composition is a mousse. In certain embodiments, the sunscreen composition is a wax. In certain embodiments, the sunscreen composition is a pomade. In certain embodiments, the sunscreen composition is a spritz. In certain embodiments, the sunscreen composition is a laquer. In certain embodiments, the sunscreen composition is a serum. In certain embodiments, the sunscreen composition is a powder. In certain embodiments, the sunscreen composition is a pencil. In certain embodiments, the sunscreen composition is a blush. In certain embodiments, the sunscreen composition is a highlighter. In certain embodiments, the sunscreen composition is a bronzer. In certain embodiments, the sunscreen composition is a concealer.

[0189] The vehicle may comprise an aqueous phase, an oil phase, an alcohol, a silicone phase or mixtures thereof. The cosmetically acceptable vehicle may also comprise an emulsion. Non-limiting examples of suitable emulsions include water-in-oil emulsions, oil- in-water emulsions, silicone-in-water emulsions, water-in-silicone emulsions, wax-in-water emulsions, water-oil-water triple emulsions or the like having the appearance of a cream, gel or microemulsions. The emulsion may include an emulsifier, such as a nonionic, anionic or amphoteric surfactant.

[0190] The oil phase of the emulsion in one embodiment has one or more organic compounds, including emollients; humectants (such as butylene glycol, propylene glycol, Methyl gluceth-20, and glycerin); other water-dispersible or water-soluble components including thickeners such as veegum or hydroxy alkyl cellulose; gelling agents, such as high MW polyacrylic acid, i.e. CARBOPOL 934; and mixtures thereof. The emulsion may have one or more emulsifiers capable of emulsifying the various components present in the composition.

[0191] The compounds suitable for use in the oil phase include without limitation, vegetable oils; esters such as octyl palmitate, isopropyl myristate and isopropyl palmitate; ethers such as dicapiyl ether; fatty alcohols such as cetyl alcohol, stearyl alcohol and behenyl alcohol; isoparaffins such as isooctane, isododecane and isohexadecane; silicone oils such as dimethicones, cyclic silicones, and polysiloxanes; hydrocarbon oils such as mineral oil, petrolatum, isoeicosane and polyisobutene; natural or synthetic waxes; and the like. Suitable hydrophobic hydrocarbon oils may be saturated or unsaturated, have an aliphatic character and be straight or branched chained or contain alicyclic or aromatic rings. The oil-containing phase may be composed of a singular oil or mixtures of different oils.

[0192] Hydrocarbon oils include those having 6-20 carbon atoms, more in one embodiment 10-16 carbon atoms. Representative hydrocarbons include decane, dodecane, tetradecane, tri decane, and C8-2o isoparaffins. Paraffinic hydrocarbons are available from Exxon under the ISOPARS trademark, and from the Permethyl Corporation. In addition, C8-2o paraffinic hydrocarbons such as C12 isoparaffin (isododecane) manufactured by the Permethyl Corporation having the tradename Permethyl 99A.TM. are also contemplated to be suitable. Various commercially available Ci6 isoparaffins, such as isohexadecane (having the tradename Permethyl) are also suitable. Examples of in one embodiment volatile hydrocarbons include polydecanes such as isododecane and isodecane, including for example, Permethyl-99A (Presperse Inc.) and the C7-C8 through C12-C15 isoparaffins such as the Isopar Series available from Exxon Chemicals. A representative hydrocarbon solvent is isododecane.

[0193] The oil phase may comprise one or more waxes, including for example, rice bran wax, camauba wax, ouri curry wax, candelilla wax, montan waxes, sugar cane waxes, ozokerite, polyethylene waxes, Fischer-Tropsch waxes, beeswax, microcrystalline wax, silicone waxes, fluorinated waxes, and any combination thereof.

[0194] Non-limiting emulsifiers include emulsifying waxes, emulsifying polyhydric alcohols, polyether polyols, polyethers, mono- or di-ester of polyols, ethylene glycol mono- stearates, glycerin mono-stearates, glycerin di-stearates, silicone-containing emulsifiers, soya sterols, fatty alcohols such as cetyl alcohol, acrylates, fatty acids such as stearic acid, fatty acid salts, and mixtures thereof. The in one embodiment emulsifiers include soya sterol, cetyl alcohol, stearic acid, emulsifying wax, acrylates, silicone containing emulsifiers and mixtures thereof. Other specific emulsifiers that can be used in the composition of the present invention include, but are not limited to, one or more of the following: Cto-30 alkyl acrylate crosspolymer; Dimethicone PEG-7 isostearate, acrylamide copolymer; mineral oil; sorbitan esters; poly glyceryl-3 -diisostearate; sorbitan monostearate, sorbitan tristearate, sorbitan sesquioleate, sorbitan monooleate; glycerol esters such as glycerol monostearate and glycerol monooleate; polyoxyethylene phenols such as polyoxyethylene octyl phenol and polyoxyethylene nonyl phenol; polyoxyethylene ethers such as polyoxyethylene cetyl ether and polyoxyethylene stearyl ether; polyoxyethylene glycol esters; polyoxyethylene sorbitan esters; dimethicone copolyols; polyglyceryl esters such as polyglyceryl-3-diisostearate; glyceryl laurate; Steareth-2, Steareth-10, and Steareth-20, to name a few. Additional emulsifiers are provided in the INCI Ingredient Dictionary and Handbook 11^th Edition 2006, the disclosure of which is hereby incorporated by reference.

[0195] These emulsifiers typically will be present in the composition in an amount from about 0.001% to about 10% by weight, in particular in an amount from about 0.01% to about 5% by weight, and more in one embodiment, from about 0.1% to about 3% by weight. [0196] The oil phase may comprise one or more volatile and/or non-volatile silicone oils.

Volatile silicones include cyclic and linear volatile dimethylsiloxane silicones. In one embodiment, the volatile silicones may include cyclodimethicones, including tetramer (D*), pentamer (D5), and hexamer (D6) cyclomethicones, or mixtures thereof. Particular mention may be made of the volatile cyclomethicone-hexamethyl cyclotrisiloxane, octamethyl- cyclotetrasiloxane, and decamethyl-cyclopentasiloxane. Suitable dimethicones are available from Dow Coming under the name Dow Coming 200 Fluid and have viscosities ranging from 0.65 to 600,000 centistokes or higher. Suitable non-polar, volatile liquid silicone oils are disclosed in U.S. Pat. No. 4,781,917, herein incorporated by reference in its entirety. Additional volatile silicones materials are described in Todd et al., "Volatile Silicone Fluids for Cosmetics", Cosmetics and Toiletries, 91 :27-32 (1976), herein incorporated by reference in its entirety. Linear volatile silicones generally have a viscosity of less than about 5 centistokes at 25° C, whereas the cyclic silicones have viscosities of less than about 10 centistokes at 25° C. Examples of volatile silicones of varying viscosities include Dow Coming 200, Dow Coming 244, Dow Coming 245, Dow Coming 344, and Dow Coming 345, (Dow Coming Corp.); SF-1204 and SF-1202 Silicone Fluids (G.E. Silicones), GE 7207 and 7158 (General Electric Co.); and SWS-03314 (SWS Silicones Corp.). Linear, volatile silicones include low molecular weight polydimethylsiloxane compounds such as hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and dodecamethylpentasiloxane, to name a few. [0197] Non-volatile silicone oils will typically comprise polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, or mixtures thereof. Polydimethylsiloxanes are in one embodiment non-volatile silicone oils. The non-volatile silicone oils will typically have a viscosity from about 10 to about 60,000 centistokes at 25° C, in one embodiment between about 10 and about 10,000 centistokes, and more in one embodiment still between about 10 and about 500 centistokes; and a boiling point greater than 250° C at atmospheric pressure. Non limiting examples include dimethyl polysiloxane (dimethicone), phenyl trimethicone, and diphenyldimethicone. The volatile and non-volatile silicone oils may optionally be substituted with various functional groups such as alkyl, aryl, amine groups, vinyl, hydroxyl, haloalkyl groups, alkylaryl groups, and acrylate groups, to name a few.

[0198] The water-in-silicone emulsion may be emulsified with a nonionic surfactant (emulsifier) such as, for example, polydiorganosiloxane-polyoxyalkylene block copolymers, including those described in U.S. Pat. No. 4,122,029, the disclosure of which is hereby incorporated by reference. These emulsifiers generally comprise a polydiorganosiloxane backbone, typically polydimethylsiloxane, having side chains comprising -(EO)m- and/or - (PO)n- groups, where EO is ethyleneoxy and PO is 1,2-propyleneoxy, the side chains being typically capped or terminated with hydrogen or lower alkyl groups (e.g., Ct-6, typically C₁-3). Other suitable water-in-silicone emulsifiers are disclosed in U.S. Pat. No. 6,685,952, the disclosure of which is hereby incorporated by reference herein. Commercially available water-in-silicone emulsifiers include those available from Dow Coming under the trade designations 3225C and 5225C FORMULATION AID; SILICONE SF-1528 available from General Electric; ABIL EM 90 and EM 97, available from Goldschmidt Chemical Corporation (Hopewell, Va.); and the SILWET series of emulsifiers sold by OSI Specialties (Danbury, Conn.). [0199] Examples of water-in-silicone emulsifiers include, but are not limited to, dimethicone PEG 10/15 crosspolymer, dimethicone copolyol, cetyl dimethicone copolyol, PEG- 15 lauryl dimethicone crosspolymer, lamylmethicone crosspolymer, cyclomethicone and dimethicone copolyol, dimethicone copolyol (and) caprylic/capric triglycerides, polyglyceryl-4 isostearate (and) cetyl dimethicone copolyol (and) hexyl laurate, and dimethicone copolyol (and) cyclopentasiloxane. In one embodiment examples of water-in- silicone emulsifiers include, without limitation, PEG/PPG-18/18 dimethicone (trade name 5225C, Dow Coming), PEG/PPG-19/19 dimethicone (trade name BY25-337, Dow Coming), Cetyl PEG/PPG- 10/1 dimethicone (trade name Abil EM-90, Goldschmidt Chemical Corporation), PEG-12 dimethicone (trade name SF 1288, General Electric), lauryl PEG/PPG- 18/18 methicone (trade name 5200 FORMULATION AID, Dow Coming), PEG-12 dimethicone crosspolymer (trade name 9010 and 9011 silicone elastomer blend, Dow Coming), PEG-10 dimethicone crosspolymer (trade name KSG-20, Shin-Etsu), dimethicone PEG-10/15 crosspolymer (trade name KSG-210, Shin-Etsu), and dimethicone PEG-7 isostearate.

[0200] The water-in-silicone emulsifiers typically will be present in the composition in an amount from about 0.001% to about 10% by weight, in particular in an amount from about 0.01% to about 5% by weight, and more in one embodiment, below 1% by weight.

[0201] The aqueous phase of the emulsion may include one or more additional solvents, including lower alcohols, such as ethanol, isopropanol, and the like. The volatile solvent may also be a cosmetically acceptable ester such as butyl acetate or ethyl acetate; ketones such as acetone or ethyl methyl ketone; or the like.

[0202] The oil-containing phase will typically comprise from about 10% to about 99%, in one embodiment from about 20% to about 85%, and more in one embodiment from about 30% to about 70% by weight, based on the total weight of the emulsion, and the aqueous phase will typically comprise from about 1% to about 90%, in one embodiment from about 5% to about 70%, and more in one embodiment from about 20% to about 60% by weight of the total emulsion. The aqueous phase will typically comprise from about 25% to about 100%, more typically from about 50% to about 95% by weight water. [0203] The compositions may include liposomes. The liposomes may comprise other additives or substances and/or may be modified to more specifically reach or remain at a site following administration.

[0204] The composition may optionally comprise other cosmetic actives and excipients, obvious to those skilled in the art including, but not limited to, fillers, emulsifying agents, antioxidants, surfactants, film formers, chelating agents, gelling agents, thickeners, emollients, humectants, moisturizers, vitamins, minerals, viscosity and/or rheology modifiers, sunscreens, keratolytics, depigmenting agents, retinoids, hormonal compounds, alpha- hydroxy acids, alpha-keto acids, anti-mycobacterial agents, antifungal agents, antimicrobials, antivirals, analgesics, lipidic compounds, anti-allergenic agents, HI or H2 antihistamines, anti-inflammatory agents, anti-irritants, antineoplastics, immune system boosting agents, immune system suppressing agents, anti-acne agents, anesthetics, antiseptics, insect repellents, skin cooling compounds, skin protectants, skin penetration enhancers, exfollients, lubricants, fragrances, colorants, depigmenting agents, hypopigmenting agents, preservatives (e.g., DMDM Hydantoin/Iodopropynylbutylcarbonate), stabilizers, pharmaceutical agents, photostabilizing agents, neutralizers (e.g., triethanolamine) and mixtures thereof. In addition to the foregoing, the cosmetic compositions of the invention may contain any other compound for the treatment of skin disorders.

[0205] Examples of film formers include a poly CIO-30 alkyl acrylate as well as a trimethylpentanediol/ adipic acid / glycerin crosspolymer.

[0206] In certain embodiments, the sunscreen composition may may also include other cosmetic ingredients such as, but not limited to, humectants, emollients, moisturizers, antiwrinkle ingredients, concealors, matte finishing agents, pigments, colorants, proteins, antioxidants, bronzers, chelating agents, emulsifiers, ultraviolet (UV) absorbing agents, oil absorbing agents, anti-foam agents, anti-tack agents, thickeners, fragrances, preservatives, anti-microbials, fungistats, neutralizing agents, vitamins, plasticizers, cohesion agents, basifying and acidifying agents, fillers, solvents, and mixtures thereof. It is understood to those skilled in the art that any other cosmetically acceptable ingredient, i.e., those included in the CFTA Cosmetic Ingredient Dictionary, 3rd ed. may be used. [0207] The compositions may contain additional ingredients such as alkalinizing agents, emulsifying agents, emollients, plasticizers, preservatives, humectants, moisturizing agents, solvents, and tonicity agents or active ingredients suitable to provide anti-aging benefits. Examples of preferred additional ingredients include glycerin. Viscosifying agents such as gellants may also be used. Examples include, bentone, triglycerides, aluminum stearate, CIS- C36 acid glycol esters, glyceryl tribehenate, glycerol monostearate, alginates, carbomers, celluloses, gums, carageenans, starches or silicates. Fillers can also optionally be added, in an amount from about 1% to about 20%, preferably from about 1% to about 10%. Examples of fillers include silica, PMMA, nylon, alumina, barium sulfate, or any other filler typically used in such compositions. [0208] The composition may also contain at least one cosmetic active ingredient and/or at least one dermatological active ingredient, i.e. an agent having a beneficial effect on the skin. The loading of such active ingredient can be achieved in any means known to those skilled in the art. The composition may comprise further comprise other whitening or lightening agents that either hide the discoloration with pigments or other light-reflecting materials, or treat the cause of the discoloration.

[0209] In certain embodiments, the sunscreen composition is substantially stable to sunlight. In certain embodiments, the AUC in the spectral absorption spectrum after irradiation with a solar simulator is at least 80% of the AUC in the spectral absorption spectrum prior to irradiation. The AUC in the spectral absorption spectrum after irradiation with a solar simulator is at least 90% of the AUC in the spectral absorption spectrum prior to irradiation. Sunlight stability can be measured by methods known to those of skill in the art. [0210] In certain embodiments, the sunscreen composition is substantially water resistant. Water resistance can be measured by methods known to those of skill in the art. In certain embodiments, the composition is water resistant for 40 or 80 minutes as codified by the US Food and Drug Administration at Section 201.327(i)(7) of Volume 21 of the Code of Federal Regulations (2019).

[0211] In certain embodiments, the sunscreen composition is phase stable. “Phase stability” as used herein, means the maintenance of interfacial stability or suspension stability or both at each of the temperatures 4°C, 32-37°C, 40-45°C, 25°C for at least 4 weeks.

“Interfacial stability” refers to stability against coalescence and coarsening of a discontinuous phase in a composition having two or more phases. “Suspension stability” refers to stability against creaming and/or sedimentation of a discontinuous phase, for example solids, suspended in continuous phase. [0212] In certain embodiments, the sunscreen composition maintains both interfacial stability and suspension stability at each of the temperatures 4°C, 32-37°C, 40-45°C, 25°C for at least 4 weeks. To assess such stability conditions, the composition may be filled into an appropriately sized vessel where it is fully visible, such as a clear 4 oz. glass jar.

[0213] The interfacial stability of the sunscreen composition can be assessed visually and is considered unstable if at least two distinct, immiscible phases of the composition are observed, as well known in the art.

[0214] In certain embodiments, the sunscreen composition is not phase stable and, e.g., is shaken before use.

[0215] Also as known in the art, the suspension stability of the sunscreen composition can be assessed visually or tactilely and is considered unstable if a distinct separation or gradient in color, opacity, grittiness, or other indicator of non-uniformity between different regions in a sample (i.e., top and bottom, or other different regions) is observed. The suspension stability of the composition can alternatively be assessed through, but not limited to, Brookfield viscosity and is considered unstable if there are significant changes in viscosity measurement (5 or 10 or 20% for example) between different regions in a sample (i.e., top and bottom or other different regions). Brookfield viscosity may be measured with a Brookfield Laboratory Viscometer from AMETEK Inc. (Middleboro, Mass.), using a setting, spindle, and speed appropriate for the composition's viscosity. [0216] Overall phase stability may also be assessed by other techniques known in the art, for example significant changes in chemical composition as determined by analytical chemistry testing between different regions in a sample (i.e. top and bottom or other different regions). [0217] The sunscreen composition can be used by topically applying to the skin. The method for application can include the direct spraying, laying on, wiping or spreading of the composition on the skin.

[0218] The sunscreen composition may be prepared using mixing and blending methodology well established in the sunscreen and cosmetic art. In one embodiment, the composition is produced by preparing an oil phase by mixing the UV-absorbing compounds with optional oil soluble or oil-miscible ingredients; and preparing a water phase, by mixing water and optional water-soluble or water-miscible ingredients. The oil phase and the water phase may then be mixed in a manner sufficient to disperse the oil phase substantially homogeneously in the water phase such that the water phase is continuous and the oil phase discontinuous.

[0219] The percentage by weight of water phase included in the compositions may range from about 30% to about 85% such as from about 35% to about 75%, such as from about 40% to about 70%. The percentage by weight of water in the water phase may be about 60% or more, such as about 70% or more, such as about 90% or more. [0220] The composition may be combined with a “cosmetically-acceptable topical carrier,” i.e., a carrier for topical use that capable of containing the other ingredients dispersed or dissolved therein, and possessing acceptable properties rendering it safe to use topically.

[0221] The cosmetically-acceptable topical carrier may optionally comprise a wide variety of additional oil-soluble materials and/or water-soluble materials conventionally used in compositions for use on skin, at their art-established levels. For example, surfactants, emulsifiers, pearlescent or opacifying agents, thickeners, emollients, conditioners, humectants, chelating agents, exfoliants, preservatives, pH adjusting agents, and additives that enhance the appearance, feel, or scent of the composition, such as colorants, fragrances, tactile modifiers, and the like, can be included.

[0222] In certain embodiments, the composition includes a pigment suitable for providing color or hiding power. The pigment may be one suitable for use in a color cosmetic product, including compositions for application to the hair, nails and/or skin, especially the face. Color cosmetic compositions include, but are not limited to, foundations, concealers, primers, blush, mascara, eyeshadow, eyeliner, lipstick, nail polish and tinted moisturizers. The pigment suitable for providing color or hiding power may be composed of iron oxides, including red and yellow iron oxides, titanium dioxide, ultramarine and chromium or chromium hydroxide colors, and mixtures thereof. The pigment may be a lake pigment, e.g. an organic dye such as azo, indigoid, triphenylmethane, anthraquinone, and xanthine dyes that are designated as D&C and FD&C blues, browns, greens, oranges, reds, yellows, etc., precipitated onto inert binders such as insoluble salts. Examples of lake pigments include Red #6, Red #7, Yellow #5, Violet #2 and Blue #1. The pigment may be an interference pigment. Examples of interference pigments include those containing mica substrates, bismuth oxycloride substrates, and silica substrates, for instance mica/bismuth oxychloride/iron oxide pigments commercially available as CHROMALITE pigments (BASF), titanium dioxide and/or iron oxides coated onto mica such as commercially available FLAMENCO pigments (BASF), mica/titanium dioxide/iron oxide pigments including commercially available KTZ pigments (Kobo products), CELLINI pearl pigments (BASF), and borosilicate-containing pigments such as REFLECKS pigments (BASF).

[0223] In one embodiment, the composition comprises a humectant such as glycols, glycerin or propanediol. The composition may comprise for example at least about 1.0 weight percent of a humectant.

[0224] The composition may further comprise one or more other cosmetically acceptable active agents include for example anti-acne agents, shine control agents, anti-microbial agents, anti-mycotic agents, anti-parasite agents (including anti-mosquito agents), external analgesics, antioxidants, moisturizers, nutrients, vitamins, energy enhancers, anti-perspiration agents, astringents, deodorants, firming agents, anti-callous agents, and agents for skin conditioning, tanning agent, anti-wrinkles and anti-dark spots. [0225] In certain embodiments, the composition is intended for use as a non-therapeutic treatment. In certain embodiments, the composition is an article intended to be rubbed, poured, sprinkled, or sprayed on, introduced into, or otherwise applied to the human body for cleansing, beautifying, promoting attractiveness, or altering the appearance, in accordance with the US FD&C Act, § 201(i). [0226] The amount of other cosmetically active agents may range from about 0.001% to about 20% by weight of the composition, e.g., about 0.005% to about 10% by weight of the composition, such as about 0.01% to about 5% by weight of the composition.

[0227] According to some aspects, the sunscreen formulations described herein are eco- compatable compositions. For example, the sunscreen formulations are compatible with organism life and not harmful to marine ecosystems (in particular for tropical environments with coral reefs). Specifically, the sunscreen formulaitons are free of components that inhibit cell growth or cell replication in a marine environment. In some examples, this can be accomplished by the sunscreen formulations being free of bis ethylhexyloxyphenol methoxyphenyl triazine (BEMT), cinnamates, benzophenones, camphor derivatives, titanium oxide, melaleuca essential oil, ylang ylang flower extracts, Bambousa Arundinacea extracts, Karite, animal-derived fats, argan oil, ocopheiyl acetate, tocopherol, retinol, polyphenolic compounds extracted from green tea or mixtures thereof. In some aspects, the sunscreen formulations can include diisopropyl sebacate, dimethylmethoxy chromanol, gluconolactone, potassium sorbate, dimethylmethoxy chromanol, decyl cocoate, pentylene glycol, dimethicone, hydrolyzed citrus aurantium dulcis fruit extract

Exemplary Aspects.

[0228] The following exemplary aspects are provided, the numbering of which is not to be construed as designating levels of importance:

[0229] Aspect 1 provides a UV filter composition comprising: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter. [0230] Aspect 2 provides a sunscreen composition comprising a UV filter composition of

Aspect 1.

[0231] Aspect 3 provides the sunscreen composition of Aspect 2, further comprising one or more solubilizers.

[0232] Aspect 4 provides the sunscreen composition of Aspect 3, wherein the one or more solubilizers are chosen from diisopropyl sebacate, dicaprylyl carbonate, decyl cocoate, diisopropyl adipate, isopropyl lauroyl sarcosinate, dibutyl adipate, butyloctyl salicylate, C12- 15 alkyl benzoate, and diethylhexyl succinate.

[0233] Aspect 5 provides the sunscreen composition of any one of Aspects 2 to 4, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine. [0234] Aspect 6 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

7 : 1.

[0235] Aspect 7 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl m ethoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

11 : 2.

[0236] Aspect 8 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

13 : 2. [0237] Aspect 9 provides the sunscreen composition of any one of Aspects 2 to 4, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine. [0238] Aspect 10 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 : 5.5 : 1.

[0239] Aspect 11 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

11 : 2.

[0240] Aspect 12 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

13 : 2.

[0241] Aspect 13 provides the sunscreen composition of any one of Aspects 2 to 4, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine. [0242] Aspect 14 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 :

7 : 1.

[0243] Aspect 15 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 : 3 : 1.

[0244] Aspect 16 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 :

13 : 2.

[0245] Aspect 17 provides the sunscreen composition of any one of Aspects 2 to 16, wherein the one or more solubilizers is diisopropyl sebacate.

[0246] Aspect 18 provides the sunscreen composition of Aspect 17, wherein the composition comprises from about 8% to about 10% of diisopropyl sebacate.

[0247] Aspect 19 provides the sunscreen composition of Aspect 18, wherein the composition comprises from about 6% to about 8% of diisopropyl sebacate. [0248] Aspect 20 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4. [0249] Aspect 21 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4.

[0250] Aspect 22 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 6 : 17 : 4. [0251] Aspect 23 provides the sunscreen composition of any one of Aspects 22 to 24, wherein the one or more solubilizers are diisopropyl sebacate and dicaprylyl carbonate. [0252] Aspect 24 provides the sunscreen composition of Aspect 25, wherein the composition comprises from about 13% to about 15.5% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0253] Aspect 25 provides the sunscreen composition of Aspect 26, wherein the composition comprises from about 13.5% to about 15% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0254] Aspect 26 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 :

13 : 6.

[0255] Aspect 27 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 :

17 : 6.

[0256] Aspect 28 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 13 : 6.

[0257] Aspect 29 provides the sunscreen composition of any one of Aspects 26 to 28, wherein the one or more solubilizers are decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0258] Aspect 30 provides the sunscreen composition of Aspect 29, wherein the composition comprises from about 16% to about 18% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0259] Aspect 31 provides the sunscreen composition of Aspect 30, wherein the composition comprises from about 16.5% to about 17.5% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate. [0260] Aspect 32 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 : 2 : 1. [0261] Aspect 33 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 3 : 8.5 : 2. [0262] Aspect 34 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl m ethoxy dibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 1 : 2 : 1. [0263] Aspect 35 provides the sunscreen composition of any one of Aspects 32 to 34, wherein the one or more solubilizers are decyl cocoate and diisopropyl sebacate.

[0264] Aspect 36 provides the sunscreen composition of Aspect 35, wherein the composition comprises from about 19% to about 21% of a mixture of decyl cocoate and diisopropyl sebacate.

[0265] Aspect 37 provides the sunscreen composition of Aspect 36, wherein the composition comprises from about 19.5% to about 20.5% of a mixture of decyl cocoate and diisopropyl sebacate. [0266] Aspect 38 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 13 : 6. [0267] Aspect 39 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 11 : 6. [0268] Aspect 40 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 7 : 11 : 6. [0269] Aspect 41 provides the sunscreen composition of any one of Aspects 38 to 40, wherein the one or more solubilizers are diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0270] Aspect 42 provides the sunscreen composition of Aspect 41, wherein the composition comprises from about 19.5% to about 21.5% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0271] Aspect 43 provides the sunscreen composition of Aspect 42, wherein the composition comprises from about 20% to about 21% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0272] Aspect 44 provides the sunscreen composition of any one of Aspects 38 to 40, wherein the one or more solubilizers are diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0273] Aspect 45 provides the sunscreen composition of Aspect 44, wherein the composition comprises from about 16% to about 18% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0274] Aspect 46 provides the sunscreen composition of Aspect 45, wherein the composition comprises from about 16.5% to about 17.5% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate. [0275] Aspect 47 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

24 : 8.

[0276] Aspect 48 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

4 : 8.

[0277] Aspect 49 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 24 : 8.

[0278] Aspect 50 provides the sunscreen composition of any one of Aspects 47 to 49, wherein the one or more solubilizers are diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0279] Aspect 51 provides the sunscreen composition of Aspect 5, wherein the composition comprises from about 25% to about 29% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0280] Aspect 52 provides the sunscreen composition of Aspect 51, wherein the composition comprises from about 26% to about 28% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0281] Aspect 53 provides the sunscreen composition of any one of Aspects 47 to 51, wherein the one or more solubilizers are diisopropyl sebacate and diisopropyl adipate.

[0282] Aspect 54 provides the sunscreen composition of Aspect 53, wherein the composition comprises from about 32.5% to about 35/5% of a mixture of diisopropyl sebacate and diisopropyl adipate. [0283] Aspect 55 provides the sunscreen composition of Aspect 54, wherein the composition comprises from about 33% to about 35% of a mixture of diisopropyl sebacate and diisopropyl adipate.

[0284] Aspect 56 provides the sunscreen composition of any one of Aspects 47 to 49, wherein the one or more solubilizers are diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate.

[0285] Aspect 57 provides the sunscreen composition of Aspect 56, wherein the composition comprises from about 22.5% to about 25.5% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate. [0286] Aspect 58 provides the sunscreen composition of Aspect 57, wherein the composition comprises from about 23% to about 25% of a mixture of diisopropyl sebacate, decyl cocoate and isopropyl lauroyl sarcosinate.

[0287] Aspect 59 provides the sunscreen composition of any one of Aspects 47 to 49, wherein the one or more solubilizers are decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0288] Aspect 60 provides the sunscreen composition of Aspect 59, wherein the composition comprises from about 28% to about 31% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate. [0289] Aspect 61 provides the sunscreen composition of Aspect 60, wherein the composition comprises from about 29% to about 3-% of a mixture of decyl cocoate, isopropyl lauroyl sarcosinate, and dibutyl adipate.

[0290] Aspect 62 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 19 : 8.

[0291] Aspect 63 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

19 : 8.

[0292] Aspect 64 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

19 : 8.

[0293] Aspect 65 provides the sunscreen composition of any one of Aspects 62 to 64, wherein the one or more solubilizers are diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0294] Aspect 66 provides the sunscreen composition of Aspect 65, wherein the composition comprises from about 18% to about 22% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0295] Aspect 67 provides the sunscreen composition of Aspect 66, wherein the composition comprises from about 20% to about 21% of a mixture of diisopropyl sebacate, decyl cocoate, and isopropyl lauroyl sarcosinate.

[0296] Aspect 68 provides the sunscreen composition of any one of Aspects 62 to 64, wherein the one or more solubilizers are diisopropyl sebacate, diisopropyl adipate, and decyl cocoate. [0297] Aspect 69 provides the sunscreen composition of Aspect 68, wherein the composition comprises from about 29% to about 33% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0298] Aspect 70 provides the sunscreen composition of Aspect 69, wherein the composition comprises from about 30% to about 32% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0299] Aspect 71 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

17 : 8.

[0300] Aspect 72 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

20 : 7.

[0301] Aspect 73 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 17 : 8.

[0302] Aspect 74 provides the sunscreen composition of any one of Aspects 71 to 73, wherein the one or more solubilizers are diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0303] Aspect 75 provides the sunscreen composition of Aspect 74, wherein the composition comprises from about 25% to about 2827% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate.

[0304] Aspect 76 provides the sunscreen composition of Aspect 75, wherein the composition comprises from about 26% to about 27% of a mixture of diisopropyl sebacate, diisopropyl adipate, and decyl cocoate. [0305] Aspect 77 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

25 : 7.

[0306] Aspect 78 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

25 : 7.

[0307] Aspect 79 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 25 : 7.

[0308] Aspect 80 provides the sunscreen composition of any one of Aspects 77 to 79, wherein the one or more solubilizers are diisopropyl sebacate and dicaprylyl carbonate. [0309] Aspect 81 provides the sunscreen composition of Aspect 80, wherein the composition comprises from about 17% to about 20% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0310] Aspect 82 provides the sunscreen composition of Aspect 81, wherein the composition comprises from about 18% to about 19% of a mixture of diisopropyl sebacate and dicaprylyl carbonate.

[0311] Aspect 83 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

23 : 8.

[0312] Aspect 84 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

23 : 8. [0313] Aspect 85 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

23 : 8.

[0314] Aspect 86 provides the sunscreen composition of any one of Aspects 83 to 85, wherein the one or more solubilizers are diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0315] Aspect 87 provides the sunscreen composition of Aspect 86, wherein the composition comprises from about 20% to about 23% of a mixture of diisopropyl sebacate, dicapiylyl carbonate, and decyl cocoate. [0316] Aspect 88 provides the sunscreen composition of Aspect 87, wherein the composition comprises from about 21% to about 22% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0317] Aspect 89 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl m ethoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8.

[0318] Aspect 90 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

20 : 7. [0319] Aspect 91 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

18 : 8.

[0320] Aspect 92 provides the sunscreen composition of any one of Aspects 89 to 91, wherein the one or more solubilizers are dibutyl adipate. [0321] Aspect 93 provides the sunscreen composition of Aspect 92, wherein the composition comprises from about 36% to about 39% of dibutyl adipate.

[0322] Aspect 94 provides the sunscreen composition of Aspect 93, wherein the composition comprises from about 37% to about 38% dibutyl adipate.

[0323] Aspect 95 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8. [0324] Aspect 96 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 20 : 7. [0325] Aspect 97 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 18 : 8. [0326] Aspect 98 provides the sunscreen composition of any one of Aspects 94 to 97, wherein the one or more solubilizers are diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0327] Aspect 99 provides the sunscreen composition of Aspect 98, wherein the composition comprises from about 23% to about 26% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0328] Aspect 100 provides the sunscreen composition of Aspect 99, wherein the composition comprises from about 24% to about 25% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate. [0329] Aspect 101 provides the sunscreen composition of any one of Aspects 95 to 97, wherein the one or more solubilizers are diisopropyl sebacate, decyl cocoate, and diisopropyl adipate.

[0330] Aspect 102 provides the sunscreen composition of Aspect 101, wherein the composition comprises from about 25% to about 28% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate.

[0331] Aspect 103 provides the sunscreen composition of Aspect 102, wherein the composition comprises from about 26% to about 27% of a mixture of diisopropyl sebacate, decyl cocoate, and diisopropyl adipate.

[0332] Aspect 104 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxyci nnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

155 : 8.

[0333] Aspect 105 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl m ethoxy dibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

14 : 8. [0334] Aspect 106 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

15 : 8.

[0335] Aspect 107 provides the sunscreen composition of any one of Aspects 104 to 106, wherein the one or more solubilizers are dicapiylyl carbonate.

[0336] Aspect 108 provides the sunscreen composition of Aspect 107, wherein the composition comprises from about 26% to about 27% of dicaprylyl carbonate.

[0337] Aspect 109 provides the sunscreen composition of Aspect 108, wherein the composition comprises from about 24% to about 26% of dicapiylyl carbonate. [0338] Aspect 110 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

16 : 8.

[0339] Aspect 111 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 : 14 : 8.

[0340] Aspect 112 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

16 : 8. [0341] Aspect 113 provides the sunscreen composition of any one of Aspects 110 to 112, wherein the one or more solubilizers are diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0342] Aspect 114 provides the sunscreen composition of Aspect 113, wherein the composition comprises from about 24% to about 27% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0343] Aspect 115 provides the sunscreen composition of Aspect 114, wherein the composition comprises from about 25% to about 26% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0344] Aspect 116 provides the sunscreen composition of Aspect 5, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is Isoamyl p-methoxycinnamate, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

15 : 8.

[0345] Aspect 117 provides the sunscreen composition of Aspect 9, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Ethylhexyl triazone, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

14 : 8. [0346] Aspect 118 provides the sunscreen composition of Aspect 13, wherein the UV-A filter is Butyl methoxydibenzoylmethane, a first UV-B filter is Isoamyl p-methoxycinnamate, a second UV-B filter is octyl salicylate, a third UV-B filter is diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 9 :

15 : 8.

[0347] Aspect 119 provides the sunscreen composition of any one of Aspects 116 to 118, wherein the one or more solubilizers are dibutyl adipate, and decyl cocoate.

[0348] Aspect 120 provides the sunscreen composition of Aspect 119, wherein the composition comprises from about 31% to about 34% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0349] Aspect 121 provides the sunscreen composition of Aspect 120, wherein the composition comprises from about 32% to about 33% of a mixture of diisopropyl sebacate, dicaprylyl carbonate, and decyl cocoate.

[0350] Aspect 122 provides a method for protecting skin from sun damage comprising applying a sunscreen composition of any one of Aspects 2 to 121 to the skin. [0351]

Example 1

[0352] The following formulations can be prepared using methods known in the art.

Table 1. Sunscreen formulations. Example 2

[0353] The following formulations can be prepared using methods known in the art.

Table 2. Sunscreen formulations.

Example 3 [0354] The following formulations can be prepared using methods known in the art.

Table 3. Sunscreen formulations.

Example 4

[0355] The following formulations can be prepared using methods known in the art.

Table 4. Sunscreen formulations.

Example 5

[0356] A face cream with an SPF of at least 50 is prepared as an emulsion. An oil phase comprising a UV filter composition as described herein, one or more solubilizers as described herein, a thickener, an emulsier, and wax is prepared. The oil phase is added to an aqueous phase which comprises water and glycerine, with mixing. Rheology modifiers, pigments, preservatives, fragrances, and active ingredients can be added.

Example 6 Various sunscreens were formulated with varying concentrations of UV filters. Specifically, three sunsvrees each including at total of five UV filters were developed and compared to a sunscreen formulation that included nine UV filters. The formulaitons are presented below and list out the type and concentration of the UV filters.

Table 5: Comparative Formula Table 6: Formula 1

Table 7: Formula 2

Table 8: Formula 3 [0357] The sun protection factor (SPF), persistent pigment darkening (PPD), and quotient of SPF/PPD were compared between the Compartive Formula, Formula 1, Formula 2, and Formula 3. The results showed that Formula 1, Formula 2, and Formula 3 yieled equivalent or better performance than Comparative Formula. Notably, the equivalent or better performance was achieved by Formula 1, Formula 2, and Formula 3 having fewer total filters and a lower overall concentration of filters by wt%. Results are show in FIGs. 1-6.

[0358] FIG. 1 shows that the in vivo SPF of Formula 1 and Formula 2 are substantially the same as the SPF of Comparative Formula. FIG. 2 shows that Formula 1 has substantialy the same PPD as Comparative Formula. FIG. 3 shows that Formula 1 has substantially the same SPF/PPD quotient as Comparative Formula. FIG. 4 shows that Formula 3 has an improved SPF relative to Comparative Formula. FIG. 5 shows that Formula 3 has substantially the same PPD as Comparative Formula. FIG. 6 shows that Formula 3 has substantially the same SPF/PPD quotient as Comparative Formula. [0359] All references, patents or applications, U.S. or foreign, cited in the application are hereby incorporated by reference as if written herein in their entireties. Where any inconsistencies arise, material literally disclosed herein controls.

[0360] From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.

Claims

CLAIMS What is claimed is:

1. A UV filter composition comprising: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter.

2. A sunscreen composition comprising a UV filter composition of claim 1.

3. The sunscreen composition of claim 2, further comprising one or more solubilizers.

4. The simscreen composition of claim 3, wherein the one or more solubilizers are chosen from diisopropyl sebacate, dicaptylyl carbonate, decyl cocoate, diisopropyl adipate, isopropyl lauroyl sarcosinate, dibutyl adipate, butyloctyl salicylate, C12-15 alkyl benzoate, and diethylhexyl succinate.

5. The sunscreen composition of any one of claims 2-4, further comprising one or more emulsifiers.

6. The sunscreen composition of claim 5, wheiren the one or more emulsifiers are chosen from polyglyceryl 6 stearate, polyglyceryl 6 behenate, or potassium cetyl phosphate, or acrylate vinyl neodecanoate crosspolymer.

7. The sunscreen composition of any one of claims 2-4, wherein: the UV-A filter comprises butyl methoxydibenzoylmethane; the UV-B filter are chosen from Ethylhexyl triazone, octyl salicylate, and Isoamyl p-methoxyci nnam ate, diethylhexyl butamido triazone; and the broad band UV-A and UV-B filter comprises bis-ethylhexyloxyphenol methoxyphenyl triazine.

8. The sunscreen composition of any one of claims 1-7, wherein the UV filter composition comprises: three UV-B filters; a UV-A filter; and a UV-A + UV-B broadband filter

9. The sunscreen composition of any one of claims 2 to 4, wherein: the UV-A filter is Butyl methoxydibenzoylmethane, the UV-B filter is Ethylhexyl triazone, octyl salicylate, diethylhexyl butamido triazone, and the broad band UV-A and UV-B filter is bis-ethylhexyloxyphenol methoxyphenyl triazine.

10. The sunscreen composition of claim 5, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 2 : 7 : 1.

11. The sunscreen composition of claim 5, wherein the mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 : 11 : 2.

12. The sunscreen composition of claim 5, whereinthe mass ratio of UV-A filter to UV-B filters to broad band filter is about 4 : 13 : 2.

13. The sunscreen composition of any one of claims 2-12, wherein the composition comprises from about 8% to about 10% of of solubilizer.

14. The sunscreen composition of any one of claims 2-12, wherein the composition comprises from about 8% to about 10% of of film former.

15. The sunscreen composition of any one of claims 2-12, wherein the UV-B filter, a UV-A filter, and a UV-A + UV-B broadband filter, together range from about 5 wt% to about 25 wt% of the sunscreen composition.

16. A method for protecting skin from sun damage comprising applying a sunscreen composition of any one of claims 2 to 14 to the skin.