EP3701810B1 - Papier d'emballage en bandes imprimé par héliogravure - Google Patents
Papier d'emballage en bandes imprimé par héliogravure Download PDFInfo
- Publication number
- EP3701810B1 EP3701810B1 EP20159740.8A EP20159740A EP3701810B1 EP 3701810 B1 EP3701810 B1 EP 3701810B1 EP 20159740 A EP20159740 A EP 20159740A EP 3701810 B1 EP3701810 B1 EP 3701810B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibrous crystalline
- crystalline cellulosic
- cellulosic material
- banded
- fibrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 claims description 163
- 239000002002 slurry Substances 0.000 claims description 121
- 230000000391 smoking effect Effects 0.000 claims description 57
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 32
- 241000208125 Nicotiana Species 0.000 claims description 32
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 32
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 32
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 32
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 32
- 230000035699 permeability Effects 0.000 claims description 23
- 238000007639 printing Methods 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 20
- 235000010980 cellulose Nutrition 0.000 claims description 19
- 229920002678 cellulose Polymers 0.000 claims description 19
- 239000001913 cellulose Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229920002749 Bacterial cellulose Polymers 0.000 claims description 4
- 239000005016 bacterial cellulose Substances 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims 9
- 239000002356 single layer Substances 0.000 claims 2
- 210000004027 cell Anatomy 0.000 claims 1
- 210000002421 cell wall Anatomy 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 21
- 238000007646 gravure printing Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 8
- 235000019504 cigarettes Nutrition 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229940072056 alginate Drugs 0.000 description 4
- 235000010443 alginic acid Nutrition 0.000 description 4
- 229920000615 alginic acid Polymers 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229960003563 calcium carbonate Drugs 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229960002713 calcium chloride Drugs 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/005—Treatment of cigarette paper
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/025—Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/045—Cigars; Cigarettes with mouthpieces or filter-tips with smoke filter means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/16—Bands for cigars or cigarettes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
Definitions
- the Ignition Propensity value for a smoking article should preferably be no greater than about 25%, when tested in accordance with ASTM E2187. More preferably, the IP value should be no greater than about 20%, and even more preferably no greater than about 10%. Accordingly, efforts to meet such limits are undertaken by various manufacturers of smoking articles.
- US5417228A is directed to a paper wrapper to control the burn rate of a cigarette.
- the burn rate is controlled by the use of a paper wrapper to which regions of cellulosic material is applied and bonded.
- the cellulosic material can be microcrystalline cellulose, bacterial cellulose, or microfibrillated cellulose.
- the adhesion of the refined fibrous cellulose to an underlying base paper web allows regions of burn rate altering material to be formed on a smoking article wrapper.
- a desirable feature of this burn altering region is that it only includes fibrous cellulose with or without binder.
- Binders which may be used with the cellulosic material are carboxymethyl cellulose (CMC), hydroxypropyl cellulose, starch, guar, or other polysaccharide binders or the like.
- US2006/021625A1 is directed to controlling the burn rate of a "make-your-own" cigarette by application of an add-on material such as a refined form of fibrous cellulose to a tobacco rod wrapper used to form an assembled cigarette.
- the add-on material may comprise a binder, a filler (chalk), a burn modifier, a starch or other polysaccharide, and/or flavorant.
- the add-on material when comprising a highly refined fibrous cellulose (and optionally a chalk loading of 1 to 12%), may have a basis weight of approximately 0.5 to 15 gsm.
- US8863757B2 is directed to a process for reducing the permeability of a paper wrapper used in the construction of a smoking article.
- the paper wrapper is treated with a film-forming composition that forms treated discrete areas on the wrapper.
- the film-forming composition contains a film forming material with relatively low viscosity.
- the film-forming composition can have a higher solids content and yet have a solution viscosity capable of being used in conventional application techniques.
- the solids content of the film-forming composition can be at least 6% by weight, particularly at least 10% by weight, and more particularly in an amount from about 10% to about 20% by weight.
- the film-forming material can be, for instance, an alginate, such as sodium alginate.
- alginate compositions made in accordance with the present invention can contain alginate and water.
- other ingredients may also be included in the composition.
- a filler can be contained within the composition.
- the filler can be, calcium carbonate, calcium chloride, calcium lactate, calcium gluconate, and the like.
- a smoking article includes a tobacco rod comprising a column of filler and a wrapper surrounding the column of filler.
- the tobacco rod has a circumferential direction, a longitudinal direction, a lit end, and a mouth end.
- the wrapper includes a base web having generally parallel first and second side edges extending in the longitudinal direction and two ends extending in the circumferential direction wherein the base web is disposed around the column of filler such that the first and second side edges of the base web overlap and form a seam.
- the base web includes at least one circumferentially extending banded region of fibrous crystalline cellulosic material thereon.
- the fibrous crystalline cellulosic material is in a condition of having been gravure printed on the base web as a fibrous crystalline cellulosic slurry that comprises water, crystalline cellulose, and chalk wherein the fibrous crystalline cellulosic slurry has a solids content of about 10% or less by weight of the fibrous crystalline cellulosic slurry and the fibrous crystalline cellulosic material consists essentially of about 95% microcrystalline cellulose and about 5% chalk.
- a wrapper for smoking articles includes a base web having generally parallel first and second side edges extending in a longitudinal direction, two ends extending in a transverse direction, and a plurality of longitudinally spaced banded regions of fibrous crystalline cellulosic material thereon, the fibrous crystalline cellulosic material having been gravure printed on the base web as a fibrous crystalline cellulosic slurry comprising water, crystalline cellulose, and chalk wherein the fibrous crystalline cellulosic slurry has a solids content of about 10% or less by weight of the fibrous crystalline cellulosic slurry and the fibrous crystalline cellulosic material consists essentially of about 95% microcrystalline cellulose and about 5% chalk.
- a method of making banded wrapper paper for smoking articles includes advancing a base web to a first printing station and printing a first layer of a fibrous crystalline cellulosic slurry on the base web.
- the fibrous crystalline cellulosic slurry includes water, crystalline cellulose, and chalk and has a solids content of about 10% or less by weight of the fibrous crystalline cellulosic slurry.
- the printing includes applying the fibrous crystalline cellulosic slurry to a patterned gravure roller, and contacting the advancing base web with the patterned gravure roller to apply bands of the fibrous crystalline cellulosic slurry on the base web.
- Banded regions of fibrous crystalline cellulosic material are formed on the base web by drying the bands of the fibrous crystalline cellulosic slurry wherein the fibrous crystalline cellulosic material (126) consists essentially of about 95% microcrystalline cellulose and about 5% chalk.
- a smoking article 120 such as a cigarette, can comprise a tobacco rod 122 and a filter 132 attached to one end of the tobacco rod 122 with tipping paper 129.
- the tobacco rod 122 comprises a column of shredded tobacco ("cut filler") and a piece of banded wrapper paper 123 disposed about the column of shredded tobacco.
- the tobacco rod 122 has a lightable or lit end 124 and a tipped end 130, which, in the case of non-filtered cigarettes, is referenced as the mouth end 130 of the smoking article 120. Cut filler tobacco is an industry-standard designation.
- the tobacco rod 122 has a generally circular cross section. In other example embodiments, the tobacco rod 122 can have an oval cross section or other non-circular shape cross section.
- the wrapper 123 is sealed along a longitudinal seam to form the tobacco rod 122.
- the smoking article 120 has a nominal length measured from the edge 131 of the tipping paper to the lit end 124 of the tobacco rod 122 along a longitudinal axis of smoking article 120.
- that nominal length may lie in the range of about 60 to about 100 mm.
- the banded wrapper paper 123 can include a base web 140 that may be made from flax, wood pulp, cellulose fiber, or the like.
- the base web 140 has a plurality of bands of fibrous crystalline cellulosic material 126 on one or both sides thereof.
- the bands of fibrous crystalline cellulosic material 126 are applied to a wire side of the base web 140 such that they are on the inside of the banded wrapper paper 123 when a piece of the wrapper 123 surrounds a column of shredded tobacco to form a tobacco rod 122.
- base web 140 In the manufacture of base web 140 suited for the construction of the various embodiments of banded wrapper paper disclosed herein, such manufacture usually will include the production of a roll of base web 140 of several feet across (usually about 3 feet to about 5 feet across or in transverse dimension), which is then slit into ribbons that are wound on bobbins. Printing operations are conducted on the rolls, but could be conducted after slitting.
- the bobbins themselves will have a transverse dimension equivalent to the width needed to make tobacco rods 122 or an integral number of such widths (e.g., 1, 2, or 4 of such widths).
- the bobbins are adapted for use with typical cigarette making machines.
- the banded wrapper paper has a dimension in cross-direction that takes into account the nominal circumference of the tobacco rod 122 and an overlapping seam. As a result, when the banded wrapper paper 123 is slit, the smoking article 120 formed therefrom always has a longitudinal seam with an exact overlap.
- longitudinal refers to the direction along the length of a tobacco rod 122 (e.g., along the axis 134 in FIG. 1 ), or along the length of a base web 140 (e.g., arrow 142 in FIGs. 2 and 6 ) used in the preparation of banded wrapper paper 123 that, in turn, may be used to fabricate a tobacco rod 122.
- transverse refers to the direction circumferentially around a tobacco rod 122 (see FIG. 1 ) or the direction perpendicular to the length of the base web 140 (e.g., arrow 144 in FIGs. 2 and 6 ) used in the preparation of banded wrapper paper 123 that, in turn, may be used to fabricate a tobacco rod 122.
- a “band” or “banded region” 126 is an area (see FIG. 2 ) on an underlying base web 140 to which a fibrous crystalline cellulosic slurry has been printed to form a region of fibrous crystalline cellulosic material.
- the phrase “leading edge” refers to the edge 146 (see FIG.
- band spacing refers to the distance between the trailing edge 148 of one banded region 126 and the leading edge 146 of an adjacent banded region 126 on the base web 140 from which banded wrapper paper 123 is fashioned.
- phase refers to the distance from the leading edge 146 of one banded region 126 to the leading edge 146 of an adjacent banded region 126.
- the banded regions of fibrous crystalline cellulosic material 126 extend transversely across the base web 140 and are separated by regions free of added fibrous crystalline cellulosic material in the longitudinal direction 142 of the base web 140.
- the banded regions of fibrous crystalline cellulosic material 126 are applied to the base web 140 of the banded wrapper paper 123 to obtain satisfactory or improved Ignition Propensity ("IP") characteristics for a smoking article including a piece of the banded wrapper paper 123 and optionally to also obtain improved Self-Extinguishment ("SE”) characteristics for the smoking article.
- IP Ignition Propensity
- SE Self-Extinguishment
- the banded regions of fibrous crystalline cellulosic material 126 are arranged on the base web 140 such that at least one banded region of fibrous crystalline cellulosic material 126 is positioned between the lit end 124 and the tipped end 130 of the tobacco rod 122 in each finished smoking article 120 that includes the banded wrapper paper 123. In an example embodiment, at least two banded regions of fibrous crystalline cellulosic material 126 are positioned between the lit end 124 and the tipped end 130 of the tobacco rod 122 in each finished smoking article 120 that includes the banded wrapper paper 123. In an example embodiment, the banded regions of fibrous crystalline cellulosic material 126 extend circumferentially around the tobacco rod at one or more longitudinally spaced locations along the axis 134 thereof.
- band or banded region "width” extends in a longitudinal direction along axis 142 of the base web 140 (see FIG. 2 ) or axis 134 of the tobacco rod 122, whereas a dimension in the circumferential direction will be expressed as “circumferential” or “transverse” or “in cross-direction.”
- the "width" of the banded regions of fibrous crystalline cellulosic material 126 is measured in the longitudinal direction 142 from a leading edge 146 to a trailing edge 148 thereof.
- the widths of the banded regions of fibrous crystalline cellulosic material 126 are each about 5 to about 9 mm (from the leading edge 146 to the trailing edge 148).
- the widths of the banded regions of fibrous crystalline cellulosic material 126 are each about 5.5 to about 7.5 mm.
- the widths of the banded regions of fibrous crystalline cellulosic material 126 are each about 6 to about 7 mm.
- adjacent banded regions of fibrous crystalline cellulosic material 126 are longitudinally spaced by regions of the base web 140 free of added fibrous crystalline cellulosic material by a distance of about 20 mm to about 30 mm.
- the phase i.e., the spacing from the leading edge 146 of one banded region 126 to the leading edge 146 of an adjacent banded region 126) is about 25 mm or 27 mm.
- banded regions of fibrous crystalline cellulosic material 126 are depicted in this disclosure as solid bands, other configurations of the banded regions 126 on the base web 140 are within the spirit and scope of this disclosure, including, but not limited to, configurations in which the banded regions 126 have one or more areas free of added fibrous crystalline cellulosic material between the leading and trailing edges 146, 148 thereof.
- the base web 140 of the banded wrapper paper 123 is permeable to air. Permeability of the base web 140 is typically identified in CORESTA units.
- a CORESTA unit measures paper permeability in terms of volumetric flow rate (i.e., cm 3 /sec) per unit area (i.e., cm 2 ) per unit pressure drop (i.e., cm of water).
- the base web 140 of the banded wrapper paper 123 has a permeability of at least about 20 CORESTA units and a basis weight of about 22 to 30 gram(s) per square meter in regions outside of the banded regions of fibrous crystalline cellulosic material 126.
- the base web 140 of the banded wrapper paper 123 has a permeability of at least about 20 CORESTA units and a basis weight of about 25 to 27 gsm in regions outside of the banded regions of fibrous crystalline cellulosic material 126. In an example embodiment, the base web 140 of the wrapper 123 has a permeability greater than about 30 CORESTA in regions outside of the banded regions of fibrous crystalline cellulosic material 126.
- the base web 140 of the wrapper 123 has a permeability of about 33 CORESTA with a basis weight of about 25 gsm in regions outside of the banded regions of fibrous crystalline cellulosic material 126. In an example embodiment, the base web 140 of the wrapper 123 has a permeability of about 46 CORESTA with a basis weight of about 25 gsm in regions outside of the banded regions of fibrous crystalline cellulosic material 126. In an example embodiment, the base web 140 of the wrapper 123 has a permeability of about 60 CORESTA in regions outside of the banded regions of fibrous crystalline cellulosic material 126.
- the base web 140 of the wrapper 123 has a permeability of about 60 CORESTA with a basis weight of about 25 gsm in regions outside of the banded regions of fibrous crystalline cellulosic material 126. In an example embodiment, the base web 140 of the wrapper 123 has a permeability of about 60 CORESTA with a basis weight of about 26 gsm in regions outside of the banded regions of fibrous crystalline cellulosic material 126.
- the base web 140 has a permeability greater than about 60 CORESTA with a basis weight of about 25 gsm or more, a permeability greater than about 80 CORESTA with a basis weight of about 25 gsm or more, or a permeability greater than about 100 CORESTA with a basis weight of about 25 gsm or more in regions outside of the banded regions of fibrous crystalline cellulosic material 126.
- application of the fibrous crystalline cellulosic slurry to a base web 140 and drying thereof forms a banded region of fibrous crystalline cellulosic material 126 on the base web 140 that is effective to locally reduce the permeability of the base web 140 within the banded region 126.
- bands of fibrous crystalline cellulosic slurry are printed on the base web 140 with a gravure roller 610 to reduce the permeability of the base web 140 within the banded regions of fibrous crystalline cellulosic material 126 to about 0 to about 12 CORESTA.
- the permeability of the base web 140 within the banded regions of fibrous crystalline cellulosic material 126 is 7 CORESTA or less.
- application of the fibrous crystalline cellulosic slurry to the base web 140 and drying thereof forms a banded region of fibrous crystalline cellulosic material 126 on the base web 140 that is effective to locally reduce diffusivity values of the base web 140 from a diffusivity level of about 2 cm/sec or greater (for the base web 140 in regions free of added fibrous crystalline cellulosic material) to a value in the range of 0.0 to about 0.2 cm/sec as measured by a Sodim CO 2 Diffusivity Tester (purchased from Sodim SAS of France).
- the banded wrapper paper 123 is positioned within a clamping head so that the banded wrapper paper 123 separates two vertically arranged chambers.
- the upper chamber contains a carrier gas, such as nitrogen, while the lower chamber contains a marker gas, such as carbon dioxide.
- a carrier gas such as nitrogen
- the lower chamber contains a marker gas, such as carbon dioxide.
- the concentration of carbon dioxide within the nitrogen stream of the upper chamber is measured in an analyzer.
- a computer then converts the detected level of concentration into a measure of diffusivity.
- the diffusivity of the base web 140 within the banded regions of fibrous crystalline cellulosic material 126 is less than about 0.15 cm/sec.
- the diffusivity of the base web 140 within the banded regions of fibrous crystalline cellulosic material 126 is about 0 to about 0.1 cm/sec (e.g. about 0.01 to about 0.09 cm/sec, about 0.02 to about 0.08 cm/sec, about 0.03 to about 0.07 cm/sec or about 0.04 to about 0.06 cm/sec).
- each banded region of fibrous crystalline cellulosic material 126 may be formed by gravure printing a "layer" of a fibrous crystalline cellulosic slurry on the base web 140 to reduce the permeability of the base web 140 in the corresponding banded region.
- the fibrous crystalline cellulosic slurry is aqueous.
- FIG. 3 is a schematic view of a single stage printing apparatus 602.
- a supply reel 601 supplies a blank base web 140 to a gravure printing station 602 where a banded region of fibrous crystalline cellulosic slurry is printed on the blank base web 140 by the gravure roller 610 and dried in a drier 634.
- the drier 634 can include at least one steam can.
- the drier 634 can include two steam cans wherein the base web 140 is advanced and pressed between the steam cans to reduce wrinkling of the base web 140.
- the dried, patterned base web 140 then advances to a collection reel 608.
- a wide base web 140 may be slit or divided by a slitter 635 into a plurality of narrower strips of base web that may be wound to form individual bobbins after the printing operation, where the bobbins have a width corresponding to that required for a smoking article 120.
- the optional slitter 635 may be used on the base web 140 as that base web 140 leaves the printing station, or the slitter and slitting operation may be conducted at a different location.
- Example embodiments of gravure printing the fibrous crystalline cellulosic slurry as disclosed herein enable high-speed printing on the base web 140.
- "high-speed" printing refers to printing processes where the base web 140 advances through the printing process at a linear speed greater than about 300 feet/min.
- the size of the crystalline fibers in the fibrous crystalline cellulosic slurry, and the deposition rate and viscosity of the fibrous crystalline cellulosic slurry are selected such that base web printing speeds of greater than 500 feet/minute can be achieved.
- the gravure cylinder (roller) 610 includes a plurality of cells 700 arranged in a pattern corresponding to a band that is to be printed on the base web 140 by the gravure roller 610.
- the gravure cylinder 610 includes two or more circumferentially spaced regions 701 of cells 700 wherein each region 701 of cells 700 is arranged in a pattern corresponding to a band that is to be printed on the base web 140 by the gravure roller 610.
- adjacent regions 701 of cells 700 are circumferentially spaced by cell free surfaces 703 of the gravure roller 610 which extend a distance corresponding to the spacing between adjacent banded regions to be printed on the base web 140.
- the pattern of cells 700 corresponding to banded regions are arranged in a chevron pattern wherein angle "A" at the tip or apex of the chevron is preferably greater than about 170 degrees.
- angle "A" at the tip or apex of the chevron is preferably greater than about 170 degrees.
- the cells of the gravure roller 610 can be formed by etching the gravure roller 610. Suitable etching processes and gravure cylinders can be obtained from Heliograph Holding GmbH.
- photoresist 801 is applied to a metallic surface 800, and lasers 802 are used to activate the photoresist, which serves to mask areas where walls are desired.
- the gravure roller 610 (shown in FIG. 4 ) has a plurality of cells 700 which have a generally hexagonal shape.
- the cells 700 of the gravure roller 610 can have walls 702 ranging from about 12 to about 80 microns in width between adjacent cells 700 depending on the desired final volume of each cell 700. In an example embodiment, the cells 700 of the gravure roller 610 can have walls 702 ranging from about 12 to about 20 microns in width between adjacent cells 700. In an example embodiment, the gravure cylinder 610 can be formed such that certain cells within a region of cells are thinner than walls of other cells of the gravure roller 610. In an example embodiment, the cells 700 of the gravure roller 610 can have a generally circular shape. In an example embodiment, the depth of the cells 700 is uniform. However, in other embodiments, the depth of the cells 700 can vary.
- the cells 700 are filled with the fibrous crystalline cellulosic slurry such that they may print the fibrous crystalline cellulosic slurry on the base web 140.
- the cells 700 are sized to print dots of the fibrous crystalline cellulosic slurry which spread to form a continuous band of fibrous crystalline cellulosic material 126 on the base web 140 when the fibrous crystalline cellulosic slurry is dried.
- the cells 700 are sized to print dots of the fibrous crystalline cellulosic slurry to form a substantially continuous band of fibrous crystalline cellulosic material 126 on the base web 140 when the fibrous crystalline cellulosic slurry is dried.
- the cells 700 are sized to print small enough dots of the fibrous crystalline cellulosic slurry to form a non-continuous band of fibrous crystalline cellulosic material 126 on the base web 140 when the fibrous crystalline cellulosic slurry is dried wherein one or more areas within the non-continuous band of fibrous crystalline cellulosic material 126 are free of added fibrous crystalline cellulosic material. Adjustment of diffusivity of the banded regions of fibrous crystalline cellulosic material 126 can be facilitated by changing the size and/or number of cells 700 which apply fibrous crystalline cellulosic slurry.
- a gravure roller 610 is supplied fibrous crystalline cellulosic slurry, and moves through a doctor blade 630 that extends along the length of the gravure roller 610.
- the doctor blade 630 is positioned so that is wipes the surface of the gravure roller 610 such that portions 703 of the gravure roller 610 that define the nominal spacing between adjacent banded regions 126 are essentially wiped clean of the fibrous crystalline cellulosic slurry, while the cells 700 of the gravure roller 610 advance toward a nip 616 of the printing station 602 full of the fibrous crystalline cellulosic slurry.
- the gravure roller 610 contacts one side of the base web 140 in the nip 616 between the gravure roller 610 and an impression cylinder 612 backed by backing roller 614 to print the fibrous crystalline cellulosic slurry in the cells of the gravure roller 610 on the base web 140.
- the fibrous crystalline cellulosic slurry is delivered from a reservoir 618 to an applicator 624 by a suitable pump 620.
- the fibrous crystalline cellulosic slurry is spread on the gravure roller 610 by the applicator 624.
- Excess fibrous crystalline cellulosic slurry accumulates in a bath 626 held by collector 627 from which excess fibrous crystalline cellulosic slurry returns via drain 628 to the reservoir 618.
- the fibrous crystalline cellulosic slurry is continuously circulated between the reservoir 618 and the bath 626 to prevent the solids in the fibrous crystalline cellulosic slurry from settling in the bottom of the reservoir 618 or the bottom of the bath 626.
- the fibrous crystalline cellulosic slurry in the reservoir 618 is continuously agitated or mixed, to prevent solids in the fibrous crystalline cellulosic slurry from settling in the bottom of the reservoir 618.
- the fibrous crystalline cellulosic slurry printed on the base web 140 at room temperature.
- the fibrous crystalline cellulosic slurry can be prepared by mixing fibrous crystalline cellulosic material and chalk with a sufficient amount of water to make an aqueous slurry having a composition of less than about 10% solids.
- the fibrous crystalline cellulosic material is insoluble in the water such that mixing the fibrous crystalline cellulosic material and chalk with the water suspends the fibrous crystalline cellulosic material and the chalk in the water to form a stable slurry.
- the fibrous crystalline cellulosic material is free of any modified cellulose.
- the fibrous crystalline cellulosic material is free of any binders.
- the fibrous crystalline cellulosic material is free of any binders and modified cellulose. In an example embodiment, the fibrous crystalline cellulosic material is free of any bacterial cellulose. In an example embodiment, the fibrous crystalline cellulosic material is microcrystalline cellulose and is free of any binders and modified cellulose. In an example embodiment, the fibrous crystalline cellulosic material is microcrystalline cellulose and a binder.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose and a binder, and is free of any modified cellulose.
- the fibrous crystalline cellulosic material is free of starch, guar gum, alginate, and/or cellulose derivatives.
- the fibrous crystalline cellulosic material is free of any film forming material.
- the fibrous crystalline cellulosic material includes a binder such as sodium carboxymethyl cellulose or carboxymethyl cellulose.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose and a binder wherein the binder is less than about 9% by weight of the fibrous crystalline cellulosic material.
- the fibrous crystalline cellulosic material includes AVICEL TM microcrystalline cellulose.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose and a binder, and is free of any modified cellulose.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose wherein the fibers of the microcrystalline cellulose are predominately of a size of about 200 microns or less.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose wherein at least 90% of the fibers of the microcrystalline cellulose have a size of about 200 microns or less.
- the fibrous crystalline cellulosic material includes microcrystalline cellulose wherein the fibers of the microcrystalline cellulose are predominately of a size of about 10 microns or more.
- the fibrous crystalline cellulosic material is insoluble in room temperature water wherein the fibrous crystalline cellulosic material is mixed with room temperature water.
- the fibrous crystalline cellulosic material is insoluble in water having a temperature less than about 38° C wherein the fibrous crystalline cellulosic material is mixed with water having a temperature less than about 38° C.
- the fibrous crystalline cellulosic material and chalk is mixed with non-deionized water such as tap water.
- the fibrous crystalline cellulosic slurry is a composition having less than about 9.5% fibrous crystalline cellulosic material and less than about 5.5% chalk.
- the fibrous crystalline cellulosic slurry is a composition having about 9.5% fibrous crystalline cellulosic material and about 5.5% chalk.
- the fibrous crystalline cellulosic slurry includes up to 9.5 weight % cellulosic fibrous crystalline material and up to 5.5 weight % chalk.
- a room temperature viscosity of the fibrous crystalline cellulosic slurry is no greater than about 40 centipoises.
- a room temperature viscosity of the fibrous crystalline cellulosic slurry is between about 30 to 40 centipoises.
- a room temperature viscosity of the fibrous crystalline cellulosic slurry is less than about 30 to 40 centipoises.
- the fibrous crystalline cellulosic slurry is a composition having less than about 10% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 95 to 5. In an example embodiment, the fibrous crystalline cellulosic slurry is a composition having less than about 8% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 95 to 5.
- the fibrous crystalline cellulosic slurry is a composition having less than about 6% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 95 to 5. In an embodiment, the fibrous crystalline cellulosic slurry is a composition having less than about 5% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 95 to 5.
- the fibrous crystalline cellulosic slurry is a composition having about 2% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 95 to 5. In an embodiment, the fibrous crystalline cellulosic slurry is a composition having less than about 10% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 94.5 to 5.5.
- the fibrous crystalline cellulosic slurry is a composition having less than about 8% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 94.5 to 5.5. In an embodiment, the fibrous crystalline cellulosic slurry is a composition having less than about 6% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 94.5 to 5.5.
- the fibrous crystalline cellulosic slurry is a composition having less than about 5% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 94.5 to 5.5. In an embodiment, the fibrous crystalline cellulosic slurry is a composition having about 2% solids wherein a ratio fibrous crystalline cellulosic material to chalk in the fibrous crystalline cellulosic slurry is about 94.5 to 5.5.
- the final fibrous crystalline cellulosic slurry can be printed as longitudinally spaced apart banded regions, as described with respect to FIG. 2 , to a base web 140 used to form banded wrapper paper 123 for smoking articles wherein the base web 140 has a nominal width ranging from about 36 inches (i.e., about 920 mm) to about 60 inches at the gravure printing press.
- the moisture content of the base web 140 at the time of gravure printing is at least 3%.
- the base web 140 is passed through a sprayer operable to spray water on the base web 140 before gravure printing to increase the moisture level of the base web 140 to at least 3%.
- the fibrous crystalline cellulosic slurry can be applied to the base web 140 at a target rate of about 5 to 50 BCM (billion cubic microns per square inch). In an embodiment, the fibrous crystalline cellulosic slurry can be applied to the base web 140 at a target rate of about 5 BCM to about 38 BCM. Thereafter the base web 140 can be dried so that the printing solution dries. In an example embodiment, the fibrous crystalline cellulosic slurry is gravure printed on the base web 140 in a single pass to form bands of fibrous crystalline cellulosic material 126 wherein the total dry weight of the added fibrous crystalline cellulosic material of each band is up to about 2.5 gsm.
- the fibrous crystalline cellulosic slurry is gravure printed on the base web 140 in a single pass to form bands of fibrous crystalline cellulosic material 126 wherein the total dry weight of the added fibrous crystalline cellulosic material of each band is about 2.5 gsm.
- the fibrous crystalline cellulosic slurry is gravure printed on the base web 140 in multiple passes to form bands having multiple layers of fibrous crystalline cellulosic material 126 wherein the total dry weight of the added fibrous crystalline cellulosic material is up to about 2.5 gsm.
- the fibrous crystalline cellulosic slurry is gravure printed on the base web 140 in multiple passes to form bands having multiple layers of fibrous crystalline cellulosic material 126 wherein the total dry weight of the added fibrous crystalline cellulosic material is about 2.5 gsm.
- the base web 140 may be passed through a drier 634, such as a heated can drier, to dry or partially dry the base web 140 between passes.
- the base web 140 can be passed through the drier 634 and advanced under tension to a slitter 635 where the nominal width of the base web can be longitudinally cut into a plurality of strips or ribbons, each strip having a width of about 27 mm (e.g., the width required to surround a conventional tobacco rod and have a longitudinal glue seam). While the base web 140 is still under tension, the plurality of strips can be simultaneously wound onto individual bobbins.
- Ignition Propensity or IP is a standard test conducted as set forth in ASTM E 2187-04, "Standard Test Method for Measuring the Ignition Strength of Smoking Articles", which is incorporated herein in its entirety by this reference thereto.
- Ignition propensity measures the probability that a smoking article, when smoldering and placed on a substrate, will generate sufficient heat to maintain smoldering of the tobacco rod.
- Low values for IP are desirable as such values correlate with a reduced likelihood that a smoldering smoking article, when inadvertently left unattended upon a substrate, will cause combustion in the substrate.
- An IP value of a smoking article should be no greater than about 25%, and preferably no greater than about 20%, and even more preferably no greater than about 10% as described in US Patent Application Publication No. 2013/0306082 published Nov. 21, 2013 , the entire content of which is incorporated herein by reference thereto.
- Self-Extinguishment or SE herein is a reference to smoldering characteristics of a smoking article under free burn conditions.
- SE Self-Extinguishment
- a laboratory test is conducted at a temperature of 23° C +- 0.3° C and relative humidity of 55% +- 0.5%, both of which should be monitored by a recording hygrothermograph. Exhaust hood(s) remove combustion products formed during testing.
- smoking articles to be tested Prior to testing, smoking articles to be tested are conditioned at 55% +-0.5% relative humidity and 23° C +- 0.3° C for 24 hours. Just prior to testing, the smoking articles are placed in glass beakers to assure free air access.
- SE testing takes place within an enclosure or test box.
- a single port smoking machine or an electric lighter is used to ignite the smoking articles for the test.
- an apparatus or "angle holder” holds the smoking articles to be tested by holding an end at angles of 0° (horizontal), 45°, and/or 90° (vertical).
- 0° horizontal
- 45° 45°
- 90° 90°
- twenty (20) smoking articles are tested at each of the 0°, 45°, and 90° positions.
- the apparatuses are preferably positioned such that the smoking articles face away from each other to avoid cross interference.
- an SE value of 95% indicates that 95% of the smoking articles tested exhibited self-extinguishment under free burn conditions; while an SE value of 20% indicates that only 20% of the smoking articles tested exhibited self-extinguishment under such free burn conditions.
- the SE value for a smoking article should be no greater than about 80% (at horizontal orientation) and preferably no greater than about 50% and even more preferably no greater than about 25% as described in US Patent Application Publication No. 2013/0306082 published Nov. 21, 2013 , the entire content of which is incorporated herein by reference thereto. It is desirable to achieve IP performance that meets and exceeds governmental requirements. Moreover, as also previously noted, that desired IP performance often adversely impacts the SE performance of the smoking article. Stated differently, while the IP performance may meet or exceed the governmental requirements, that IP performance is typically associated with a smoking article that will self-extinguish when hand held by a smoker--an SE of 100%. Since smokers ordinarily prefer not to need to relight a smoking article, improvement of SE performance while maintaining IP performance constitutes a highly desirable feature for improved wrappers.
- a band 126 configuration such as shown in FIG. 6 is capable of better sustaining smoldering during free burns, yet when placed adjacent a substrate, does not sustain smoldering.
- about 10% IP can be obtained for paper having diffusion ranging from about 0 to about 0.2 cm/sec, while maintaining about 18% SE, by controlling the print area and volume of fibrous crystalline cellulosic slurry printed on the base web 140.
- banded wrapper paper 123 can include a base web 140 which includes a plurality of bands of fibrous crystalline cellulosic material 126 on one or both sides thereof.
- the bands of fibrous crystalline cellulosic material 126 can be arranged on the base web 140 such that a smoking article 120 (see e.g., FIG.
- each band of fibrous crystalline cellulosic material has a first zone 202, a second zone 203, and optionally a third zone 204 of fibrous crystalline cellulosic material wherein the amount of the fibrous cellulosic crystalline cellulosic material within each zone can be selected to control the IP performance and/or SE performance of a smoking article including the wrapper paper.
- the first zone 202 and the third zone 204 include about the same amount of fibrous crystalline cellulosic material on the base web 140, while the second zone 203 has about 20% to about 80% (e.g., about 25% to about 75%, about 30% to about 70%, about 35% to about 65%, about 40% to about 60%, or about 45% to about 55%) less fibrous crystalline cellulosic material on the base web 140 than the first or third zones 202, 204.
- the fibrous crystalline cellulosic material of each zone is applied as a plurality of dots of fibrous crystalline cellulosic slurry arranged in a pattern, generally within the zone, to produce a banded region of fibrous crystalline cellulosic material on the base web 140.
- each dot of fibrous crystalline cellulosic slurry printed in the second zone 203 has smaller dimensions than each dot of fibrous crystalline cellulosic slurry printed in the first zone 202 and the third zone 204.
- FIG. 7 shows an example embodiment of a patterned portion of a gravure cylinder (roller) 610 that may be used to print banded regions of fibrous crystalline cellulosic slurry to form banded regions of fibrous crystalline cellulosic material 126 which have a first zone 202, a second zone 203, and a third zone 204 of fibrous crystalline cellulosic material.
- the first, second, and third zones 202, 203, 204 of each banded region 126 are directly adjacent to one another such that they are not separated by a length of base web 140 that is free of added fibrous crystalline cellulosic material. As shown in FIG.
- the gravure roller 610 includes a plurality of cells 700 etched thereon in a pattern corresponding to the aforementioned zones 202, 203, 204 wherein the cells 700 have a generally hexagonal shape.
- the gravure cylinder 610 includes first and third zones 712 and a second zone 710 therebetween wherein walls 720 between adjacent cells 722 in the first and third zones 712 have a narrower width than walls 724 between adjacent cells 726 of the second zone 710.
- dots of printed slurry in the first zone 202 and third zone 204 are formed by a gravure roller 610 including cells 722 having thinner walls 720 between adjacent cells 726, such that a greater amount of fibrous crystalline cellulosic slurry is applied and the dots of printed slurry tend to run together when printed on the base web 140.
- the walls 724 of the cells 726 may be configured such that the dots of printed slurry run together when printed on the base web 140.
- the walls 720 between adjacent cells 726 of the first and/or third zones 202, 204 may be configured such that the dots printed thereby tend to stay separated once printed on the base web 140.
- the first zone 202 and the third zone 204 can have a diffusivity ranging from about 0 to about 0.1 cm/sec (e.g. about 0.01 to about 0.09 cm/sec, about 0.02 to about 0.08 cm/sec, about 0.03 to about 0.07 cm/sec or about 0.04 to about 0.06 cm/sec), and the second zone 203 can have a diffusivity ranging from about 0.1 to about 0.4 cm/sec (e.g. about 0.15 to about 0.35 cm/sec or about 0.2 to about 0.3 cm/sec).
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Claims (13)
- Article à fumer (120), comprenant :
un bâton de tabac (122) comprenant une colonne de charges et une enveloppe (123) entourant la colonne de charges, le bâton de tabac (122) possédant une direction circonférentielle, une direction longitudinale (142), une extrémité allumée (124) et une extrémité buccale (130), l'enveloppe (123) incluant en outre une bande de base (140) ayant généralement des premier et deuxième bords latéraux s'étendant dans la direction longitudinale et deux extrémités s'étendant dans la direction circonférentielle, où la bande de base (140) est disposée autour de la colonne de charges de sorte que les premier et deuxième bords latéraux de la bande de base (140) se superposent et forment un ourlet, la bande de base (140) ayant au moins une zone en bandes s'étendant circonférentiellement à base d'une matière cellulosique cristalline et fibreuse (126) au-dessus, la matière cellulosique cristalline et fibreuse ayant été imprimée par gravure sur la bande de base (140) sous forme d'une boue cellulosique cristalline et fibreuse comprenant de l'eau, de la cellulose cristalline et de la craie, où la boue cellulosique cristalline et fibreuse possède une teneurs en solides d'environ 10 % ou moins en poids de la boue cellulosique cristalline et fibreuse et la matière cellulosique cristalline et fibreuse est constituée essentiellement d'environ 95 % de cellulose microcristalline et d'environ 5 % de craie. - Article à fumer (120) selon la revendication 1, dans lequel (a) le bâton de tabac (122) a un filtre fixé à l'extrémité buccale ; (b) la craie est du carbonate de calcium ; (c) la bande de base (140) comporte au moins deux zones en bandes s'étendant longitudinalement espacées circonférentiellement de matière cellulosique cristalline et fibreuse (126) au-dessus ; (d) l'au moins une zone en bandes s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126) est imprimée comme une seule couche ; (e) l'au moins une zone en bande s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126) est imprimée en au moins deux couches ; (f) la bande de base (140) possède une perméabilité supérieure à environ 20 CORESTA et inférieure à environ 100 CORESTA dans des zones à l'extérieur de l'au moins une région en bande s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126), et une CORESTA de 12 ou moins dans des zones dans l'au moins une zone en bande s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126) ; (g) l'au moins une zone en bandes s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126) comporte de la cellulose microcristalline ; (h) l'au moins une zone en bandes s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126) est exempte de tout liant, cellulose modifiée et cellulose bactérienne ; (j) la matière cellulosique cristalline et fibreuse comporte de la cellulose microcristalline, un liant et de la craie, où le liant est compris dans une quantité d'environ 9 % ou moins en poids de cellulose microcristalline ; (k) la matière cellulosique cristalline et fibreuse comporte de la cellulose microcristalline, où au moins 90 % des fibres de la cellulose microcristalline possèdent une taille d'environ 200 microns ou moins ; (1) la matière cellulosique cristalline et fibreuse comporte de la cellulose microcristalline, où au moins 90 % des fibres de la cellulose microcristalline possèdent une taille d'environ 200 microns ou moins ; (m) l'au moins une zone en bandes de matière cellulosique cristalline et fibreuse (126) comporte jusqu'à 2,5 gsm de matière cellulosique cristalline et fibreuse ajoutée ; (n) la propension à l'ignition de l'article à fumer (120) n'est pas supérieure à 25 % et l'auto-extinction de l'article à fumer (120) n'est pas supérieure à 50 % ; ou (o) l'au moins une zone en bandes de matière cellulosique cristalline et fibreuse (126) comporte une première zone, une deuxième zone et une troisième zone, où les première et troisième zones comportent la même quantité de matière cellulosique cristalline et fibreuse et la deuxième zone comporte moins de matière cellulosique cristalline et fibreuse que les première et troisième zones.
- Article à fumer (120) selon la revendication 2, dans lequel la bande de base (140) est exempte de matière cellulosique cristalline et fibreuse ajoutée dans des zones à l'extérieur des au moins deux zones en bandes s'étendant longitudinalement espacées circonférentiellement de matière cellulosique cristalline et fibreuse (126).
- Enveloppe (123) pour articles à fumer (120), comprenant :
une bande de base (140) ayant généralement des premier et deuxième bords latéraux s'étendant dans une direction longitudinale et deux extrémités s'étendant dans une direction transversale et une pluralité de zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuse (126) au-dessus, la matière cellulosique cristalline et fibreuse ayant été imprimée par gravure sur la bande de base (140) sous forme d'une boue cellulosique cristalline et fibreuse comprenant de l'eau, de la cellulose cristalline, et de la craie, où la boue cellulosique cristalline et fibreuse possède une teneurs en solides d'environ 10 % ou moins en poids de la boue cellulosique cristalline et fibreuse et la matière cellulosique cristalline et fibreuse est constituée essentiellement d'environ 95 % de cellulose microcristalline et d'environ 5 % de craie. - Enveloppe (123) selon la revendication 4, dans laquelle : (a) la craie est du carbonate de calcium ; (b) la bande de base (140) est exempte de matière cellulosique cristalline et fibreuse ajoutée dans des zones à l'extérieur de la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuse (126) ; (c) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuse (126) est chaque fois imprimée comme une seule couche ; (d) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuse (126) est chaque fois imprimée en au moins deux couches ; (e) la bande de base (140) possède une perméabilité supérieure à environ 20 CORESTA et inférieure à environ 100 CORESTA dans des zones à l'extérieur de l'au moins une pluralité de zones en bandes s'étendant circonférentiellement de matière cellulosique cristalline et fibreuse (126), et une CORESTA de 12 ou moins dans des zones dans l'au moins une zone en bandes s'étendant espacées longitudinalement de matière cellulosique cristalline et fibreuse (126) ; (f) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuses (126) comporte de la cellulose microcristalline ; (g) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuses (126) est exempte de tout liant, cellulose modifiée et cellulose bactérienne ; (i) la matière cellulosique cristalline et fibreuse comporte de la cellulose microcristalline, un liant et de la craie, où le liant est compris dans une quantité d'environ 9 % ou moins en poids de cellulose microcristalline ; (j) la matière cellulosique cristalline et fibreuse comporte de la cellulose microcristalline, où au moins 90 % des fibres de la cellulose microcristalline possèdent une taille d'environ 200 microns ou moins ; (k) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuses (126) comporte chaque fois jusqu'à 2,5 gsm de matière cellulosique cristalline et fibreuse ajoutée ; ou (l) la pluralité des zones en bandes espacées longitudinalement de matière cellulosique cristalline et fibreuses (126) comporte chaque fois une première zone, une deuxième zone et une troisième zone, où les première et troisième zones comportent environ la même quantité de matière cellulosique cristalline et fibreuse et la deuxième zone comporte moins de matière cellulosique cristalline et fibreuse que les première et troisième zones.
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) pour des articles à fumer (120), le procédé comprenant :l'avancée d'une bande de base (140) à un premier poste d'impression (602) ;l'impression d'une première couche d'une boue cellulosique cristalline et fibreuse sur la bande de base (140), la boue cellulosique cristalline et fibreuse comprenant de l'eau, de la cellulose cristalline et de la craie, où la boue cellulosique cristalline et fibreuse possède une teneurs en solides d'environ 10 % ou moins en poids de la boue cellulosique cristalline et fibreuse, ladite impression comprenant l'application de la boue cellulosique cristalline et fibreuse sur un rouleau de gravure à motifs (610), et la mise en contact de la bande de base (140) avançant avec le rouleau de gravure à motifs (610) pour appliquer des bandes de boue cellulosique cristalline et fibreuse sur la bande de base (140) ; etla formation de zones en bandes de matière cellulosique cristalline et fibreuse (126) sur la bande de base (140) en séchant les bandes de boue cellulosique cristalline et fibreuse, où la matière cellulosique cristalline et fibreuse (126) est constituée d'environ 95 % de cellulose microcristalline et d'environ 5 % de craie.
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 6, dans lequel :
(a) la boue cellulosique cristalline et fibreuse n'est pas chauffée lorsqu'elle est appliquée sur le rouleau de gravure (610) ; (b) le séchage comprend le passage de la bande de base (140) par-dessus au moins une canette de vapeur (634) ; (c) uniquement la première couche de boue cellulosique cristalline et fibreuse est imprimée sur la bande de base (140) ; (d) la quantité de boue cellulosique cristalline et fibreuse appliquée à la bande de base (140) est suffisante pour former des zones en bandes de matière cellulosique cristalline et fibreuse (126) ayant un poids d'environ 2,5 gsm ; ou (e) la perméabilité du papier d'enveloppe en bandes (123) dans des zones à l'extérieur des zones en bandes de matière cellulosique cristalline et fibreuse (126) est d'environ 20 CORESTA à environ 100 CORESTA, et la perméabilité du papier d'enveloppe en bandes (123) dans des zones à l'intérieur des zones en bandes de matière cellulosique cristalline et fibreuse (126) est d'environ 12 CORESTA ou moins. - Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 6, incluant une étape d'impression d'une deuxième couche de boue cellulosique cristalline et fibreuse sur le dessus de la première couche.
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 8, dans lequel (a) la deuxième couche est imprimée avec un poids de revêtement qui est au moins de 1 % supérieur à un poids de revêtement de la première couche imprimée ; ou (b) incluant le séchage de la bande de base (140) entre les impressions des première et deuxième couches.
- Procédé de fabrication d'un papier d'enveloppe en bandes selon la revendication 6, dans lequel la boue cellulosique cristalline et fibreuse comporte un liant.
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 6, dans lequel la boue cellulosique cristalline et fibreuse est agitée en continu avant d'être appliquée sur le rouleau de gravure (610).
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 6, dans lequel le rouleau de gravure (610) est conçu pour appliquer une quantité de boue cellulosique cristalline et fibreuse en une seule passe suffisante pour provoquer une auto-extinction d'un papier d'enveloppe en bandes (123) incorporant un article à fumer (120).
- Procédé de fabrication d'un papier d'enveloppe en bandes (123) selon la revendication 6, dans lequel : (a) la boue cellulosique cristalline et fibreuse comporte de la cellulose microcristalline avec une taille de fibre inférieure à 200 microns ; (b) le rouleau de gravure (610) a des cellules hexagonales (700) séparées par des parois de cellules d'un épaisseur de 12 à 20 microns ; ou (c) l'impression de la pluralité des zones en bandes espacées longitudinalement de boue cellulosique cristalline et fibreuse comporte l'application de la boue cellulosique cristalline et fibreuse de chaque zone en bande dans une première zone (202), une deuxième zone (203) et une troisième zone (204), où les première et troisième zones (202, 204) comportent environ la même quantité de boue cellulosique cristalline et fibreuse et la deuxième zone (203) comporte moins de boue cellulosique cristalline et fibreuse que les première et troisième zones (202, 204).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22166022.8A EP4108106A1 (fr) | 2019-03-01 | 2020-02-27 | Papier d'emballage en bandes imprimé par héliogravure |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/290,327 US20200275690A1 (en) | 2019-03-01 | 2019-03-01 | Gravure printed banded wrapper paper |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22166022.8A Division EP4108106A1 (fr) | 2019-03-01 | 2020-02-27 | Papier d'emballage en bandes imprimé par héliogravure |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3701810A1 EP3701810A1 (fr) | 2020-09-02 |
EP3701810B1 true EP3701810B1 (fr) | 2022-04-06 |
Family
ID=69742730
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20159740.8A Active EP3701810B1 (fr) | 2019-03-01 | 2020-02-27 | Papier d'emballage en bandes imprimé par héliogravure |
EP22166022.8A Pending EP4108106A1 (fr) | 2019-03-01 | 2020-02-27 | Papier d'emballage en bandes imprimé par héliogravure |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22166022.8A Pending EP4108106A1 (fr) | 2019-03-01 | 2020-02-27 | Papier d'emballage en bandes imprimé par héliogravure |
Country Status (2)
Country | Link |
---|---|
US (1) | US20200275690A1 (fr) |
EP (2) | EP3701810B1 (fr) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5263999A (en) * | 1991-09-10 | 1993-11-23 | Philip Morris Incorporated | Smoking article wrapper for controlling burn rate and method for making same |
US6779530B2 (en) * | 2002-01-23 | 2004-08-24 | Schweitzer-Mauduit International, Inc. | Smoking articles with reduced ignition proclivity characteristics |
US20060021625A1 (en) * | 2004-07-30 | 2006-02-02 | Philip Morris Usa Inc. | Make-your-own smoking article with controlled burn rate |
DE102009030546B3 (de) * | 2009-06-25 | 2011-01-20 | Delfortgroup Ag | Filmbildende Zusammensetzung zum Aufbringen auf Zigarettenpapier, Zigarettenpapier, Zigarette sowie Verfahren zum Herstellen eines Zigarettenpapiers |
CA2873781A1 (fr) | 2012-05-16 | 2013-11-21 | Altria Client Services Inc. | Nouveau papier a cigarette a bague dote de bagues de zone ouverte |
-
2019
- 2019-03-01 US US16/290,327 patent/US20200275690A1/en active Pending
-
2020
- 2020-02-27 EP EP20159740.8A patent/EP3701810B1/fr active Active
- 2020-02-27 EP EP22166022.8A patent/EP4108106A1/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
US20200275690A1 (en) | 2020-09-03 |
EP3701810A1 (fr) | 2020-09-02 |
EP4108106A1 (fr) | 2022-12-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6929013B2 (en) | Wrapping materials for smoking articles | |
US6976493B2 (en) | Wrapping materials for smoking articles | |
CA2688157C (fr) | Papier d'emballage a motifs avec agent anti-plissement | |
EP2849585B1 (fr) | Nouveau papier à cigarette à bague doté de bagues de zone ouverte | |
WO2002037991A1 (fr) | Procede de production de produits du tabac permettant de reduire le risque d'allumage, et produits fabriques selon ce procede | |
EP2180799B1 (fr) | Papier à cigarette à anneaux en créneaux | |
US11602161B2 (en) | Cigarette wrapper with novel pattern | |
EP2160105B1 (fr) | Papier à cigarette à bandeau en créneaux | |
US20230301343A1 (en) | Low ignition propensity cigarette paper and manufacture thereof | |
EP3701810B1 (fr) | Papier d'emballage en bandes imprimé par héliogravure | |
US20230210165A1 (en) | Cigarette wrapper with novel pattern |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20210226 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20211012 |
|
INTG | Intention to grant announced |
Effective date: 20211027 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1480453 Country of ref document: AT Kind code of ref document: T Effective date: 20220415 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602020002495 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20220406 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220808 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220706 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220707 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220706 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220806 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602020002495 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20230110 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230525 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: UEP Ref document number: 1480453 Country of ref document: AT Kind code of ref document: T Effective date: 20220406 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20230228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230227 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220406 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230228 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240228 Year of fee payment: 5 Ref country code: CH Payment date: 20240301 Year of fee payment: 5 Ref country code: GB Payment date: 20240227 Year of fee payment: 5 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20240226 Year of fee payment: 5 |