EP3746296A1 - Laminated glazing with an electrically controllable device, and production thereof - Google Patents
Laminated glazing with an electrically controllable device, and production thereofInfo
- Publication number
- EP3746296A1 EP3746296A1 EP19709546.6A EP19709546A EP3746296A1 EP 3746296 A1 EP3746296 A1 EP 3746296A1 EP 19709546 A EP19709546 A EP 19709546A EP 3746296 A1 EP3746296 A1 EP 3746296A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- face
- glazing
- electrically controllable
- plastic strip
- controllable device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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Classifications
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- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10541—Functional features of the laminated safety glass or glazing comprising a light source or a light guide
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- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10816—Making laminated safety glass or glazing; Apparatus therefor by pressing
- B32B17/10871—Making laminated safety glass or glazing; Apparatus therefor by pressing in combination with particular heat treatment
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- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
- B32B17/10935—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin as a preformed layer, e.g. formed by extrusion
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Definitions
- the invention relates to a laminated glazing incorporating an electrically controllable device and its manufacture.
- Automotive glazing increasingly integrates the lighting or light signaling function by means of inorganic light-emitting diodes.
- WO2016079459 discloses a light laminated glazing motor vehicle windshield incorporating diodes on a printed circuit board (PCB for printed circuit board in English) for providing warning light signals to the driver.
- PCB printed circuit board
- the luminous windshield comprising:
- a laminated glazing unit comprising:
- first glazing unit forming an external glazing unit with first and second main faces designated F1 and F2
- PVB polyvinyl butyral lamination interlayer
- a second glazing forming an interior glazing unit with third and fourth main faces, called F3 and F4,
- the second and third faces being the internal faces of the laminated glazing
- each diode having a transmitting face emitting in the direction of the inner lens on the so-called front face of the PCB
- a double-sided adhesive tape with a thickness of less than 0.05mm forming a connection between the glazing unit and the PCB.
- the manufacture of such a luminous laminated glazing for the automobile or for any other application can thus be improved. More broadly the manufacture of any laminated glazing incorporating an electrically controllable device (discrete, surface etc.) can be improved. Also, the present invention firstly relates to a method of manufacturing a glazing electrically controllable device including a vehicle comprising a particularly curved laminated glazing comprising:
- first glazing element transparent, in particular made of mineral or plastic glass, in particular curved, possibly clear, extraclear or tinted in particular gray or green, preferably curved, often forming external glazing, with first and second main faces respectively said face F1; and face F2, in particular F1 or F2 being each naked or coated with a layer (transparent or opaque), in particular mineral (functional layer, monolayer or multilayer etc, in particular layer with a thickness of at most 50 ⁇ m or even submicron), glazing preferably of thickness for automotive glazing of not more than 2.5 mm, not more than 2.2 mm - in particular 1, 9 mm, 1, 8 mm, 1, 6 mm and 1, 4 mm - or not more than 1 , 3mm or not more than 1 mm
- a second glazing transparent, in particular of mineral glass and preferably clear or extraclear or even tinted or plastic, in particular curved, often forming an interior glazing with third and fourth main faces respectively said face F3 and face F4, in particular F3 or F4 each being bare or coated with a layer (transparent or opaque) in particular mineral (functional layer, monolayer or multilayer etc including layer thickness of at most 50pm or even submicron), thick glazing for automotive glazing preferably less than that of the first glazing, not more than 2.2 mm apart - in particular 1, 9mm, 1, 8mm, 1, 6mm and 1, 4mm - or not more than 1, 3mm or more than 1 mm, the total thickness of the first and second glazings being preferably strictly less than 4 mm, even at 3.7 mm
- first or second glazings being made of mineral glass, in particular F1 or F2 or F3, F4 each being bare or coated with a layer (transparent or opaque) in particular mineral (functional layer, single or multilayer etc. in particular thick layer of at most 50pm or even submicron)
- a lamination interlayer of thermoplastic polymeric material in particular in one or more layers, in particular having a main face FA in adhesive contact with the second face F2 (bare or coated) and a main face FB in adhesive contact with the face F3 (bare or coated), and in particular a thickness e1 subcentimetric, preferably the majority of the face F2 and the face F3 is in adhesive contact with the lamination interlayer, for automotive glazing preferably e1 at most 1, 8mm, better not more than 1, 2mm and not more than 0,9mm (and better by at least 0.3 mm and even at least 0.5 mm), in particular recessed from the edge of the first glazing by at most 2 mm and set back from the edge of a second glazing of at most 2 mm
- first or second glazings being made of mineral glass and the laminated glazing comprising between the faces F2 and F3:
- an electrically controllable device in particular a strip (elongate, for example square, rectangular, L-shaped, T-shaped, combed, etc.), comprising a support, in particular a strip (elongate, for example square, rectangular, L-shaped, T-shaped, comb, etc.), in particular of width W2 of at most 1 m or at most 40 cm and even at most 20 cm, 10 cm or 5 cm, of thickness e 2 in particular submillimetric and even at most 0.15 mm, with a front face, a rear face and a wafer, the front face being a carrier in a so-called functional zone of an electrically controllable system of thickness e2, preferably submillimetric, in particular of width W'2-in particular of not more than 5cm; subcentimetric - (discrete component etc) or substantially equal to W2 (surface system), and the front face possibly comprising a power supply area adjacent to the functional area including opening or with an extension beyond the singing of the first or second th glazing, the electrically controll
- a polymeric connecting element having a thickness e3 of at most 0.3 mm, 25mm and even at most 0.15mm, in particular 25 to 100pm, 40 to 70pm and even at most 50pm, in adhesive contact with the rear face and with one of the faces F2 or F3 called contact face (naked or coated, of the aforesaid layer) -, in particular of width W3 of at least 0.8W2 or 0.9W2 and / or of at most 1m or at most 40cm and even at most 20cm , 10cm or 5cm, the connecting element preferably having a lower surface area than the lamination interlayer,
- the electrically controllable system in particular equipped with discrete electronic (opto) components or surface system
- another polymeric connection element of thickness e3 not more than 0.3mm, 0.25mm and not more than 0.15mm, particularly 25 to 100pm, 40 to 70pm and even not more than 50pm, in adhesive contact with the electrically controllable device and with the one of the faces F2 or F3 then called bonding face (naked or coated, of said layer mentioned above), opposite the contact face in the case of the two strips
- the other connecting element preferably having a lower surface area than the lamination interlayer, in particular of width W '3 of not less than 0.8W2 or 0.9W2 and / or not more than 1m or not more than 40cm and not more than 20cm,
- the method comprises the following steps:
- a preassembled element comprising the electrically controllable device, said connecting element and / or the other connecting element and possibly at least one sheet of the lamination interlayer
- said assembly sheet, connecting element comprising a plastic strip, preferably thermoplastic, which has a main face called connection face F L opposite the rear face of the support, preferably in the functional zone and / or in the electrical supply zone, in particular covering (essentially) the back side, plastic strip preferably recessed by at most 5mm or 2mm or 1mm from the edge of the support, or flush with the edge of the support or protruding from the edge of the support (preferably over a limited area ), and the plastic strip having a free main face F '(non-sticky), opposite to the connecting face F L ,
- the connecting face F L being in adhesive contact or bonded to the rear face (the connecting face F L protruding or not from the edge of the support)
- the other connecting element comprising a plastic strip, preferably thermoplastic, which has a main face called another connecting face F ' L facing the front surface of the device, and the plastic strip having a free main face F "( non-tacky), opposite to the other bonding face F ' L the other bonding face F ' L being in adhesive contact or glued to the electrically controllable device (to the electrically controllable system, and / or to the front face), the other connecting face F' L protruding or not from the edge of the support)
- the other protruding zone Z'D is in adhesive contact or glued with the zone Z'A
- Z'A is at most 10cm or 5cm or 1 cm from the edge of the support -et even protruding on two sides preferably opposite, on three sides, around the periphery of the functional zone etc-, in particular with another protruding zone Z ⁇ facing a zone ZB of one of the main faces of the assembly sheet, by example Z'D and Z ⁇ protruding from two opposite sides of the support, preferably Z'A and Z'B are at most 10cm or 5cm or 1 cm from the edge of the support
- the double-sided adhesive tape used in the prior art laminated roof requires the removal of a protective film ('liner') and the surface is tacky before positioning and therefore does not allow easy readjustment of the support. if necessary. In addition liner residues can lead to bubbling or blur.
- the plastic strip is therefore already linked (full surface or punctually) with the device and / or with the assembly sheet.
- the strip is protruding (larger than the device), the link between the strip and the sheet can serve alone to maintain the device and there is no need for additional connection back and plastic strip.
- the plastic strip is able to bond with the face of the glazing by the lamination. Unlike the double-sided adhesive tape, the free face of the thermoplastic strip is non-sticky and ready for use.
- the plastic strip according to the invention allows precise positioning without loss of time online.
- the manufacturing process is thus optimized and more compatible with automation.
- the (thermo) plastic strip also allows degassing (escape of microbubbles coming from the degassing cycle in an oven), the vacuum serving to evacuate the bubbles being present before reaching the temperature necessary for the adhesion of the plastic (preferably thermoplastic) of the strip on the contact face.
- the (thermo) plastic strip can thus be more transparent than the double-sided tape.
- thermoplastic strip can also provide better mechanical strength especially when the support is large.
- the other plastic strip provides the same advantages as those mentioned above for the plastic strip.
- plastic strip and other plastic strip preferably one of which is protruding on the lamination interlayer, which is preferably in one single sheet (PVB, composite, PVB / functional PET / PVB) possibly perforated.
- the other plastic strip can be perforated to the right of discrete electronic components (opto).
- the plastic strip according to the invention is called in the text back plastic strip because of its connection with the rear face.
- the other plastic strip according to the invention is referred to in the text plastic strip before because of its position on the front side.
- the connecting element and therefore the plastic strip
- the connecting element is in direct adhesive contact with the contact face.
- the connecting element is in indirect adhesive contact with the contact face.
- a mineral layer is preferred.
- it is a deposited layer for example obtained liquid (screen printing, printing, etc.), physical vapor deposition (cathodic sputtering) or even chemical.
- the other connecting element (and therefore the other plastic strip) is in direct adhesive contact with the bonding face.
- the bonding face is coated with a layer (mono or multilayer) including functional (masking layer, electroconductive, low emissivity, heating, etc.) opposite the other connecting element
- the other connecting element is in indirect adhesive contact with the bonding face.
- a mineral layer is preferred.
- it is a deposited layer for example obtained by liquid (screen printing, printing, etc.), physical vapor deposition (cathode sputtering) or even chemical.
- plastic strip or the other plastic strip, respectively
- shape of the plastic strip or the other plastic strip, respectively
- the preassembled element and the lamination interlayer in particular the assembly sheet
- the electrically controllable device can partially cover the laminated glazing for example at most 50% or 40% or 30% or even at most 20% or 10).
- the (thermo) plastic (local) tape can partially cover the laminated glazing (eg at most 50% or 40% or 30% or even at most 20% or 10%.)
- the tape coverage rate can be preferably the same or a little higher than that of the electrically controllable device.
- the lamination interlayer (the assembly sheet, etc.) is of a surface (well) greater than this plastic strip (front or rear), and can cover at least 70%, 80% or 90% or 95% of the glazing. electrically controllable device.
- the lamination interlayer (the assembly sheet, etc.) may be set back from the edge of the first glazing unit (and / or second glazing) in particular of at most 2 mm.
- the lamination interlayer surround the support (so that the interlayer is present between the support and the edge of the nearest laminated glazing).
- a thin plastic band front or rear
- a lower surface area than the interlayer is preferred for cost optimization and even for better handling during manufacture, given its thinness.
- the (thermo) plastic strip front or rear may protrude from the edge of the support in the laminated glazing area with the lamination interlayer, preferably at most 20 cm, 10 cm or 5 cm and even 1 cm from the edge of the support to facilitate the installation (without folds etc) especially if the preassembly intervenes between rear face and plastic band (back).
- the expression "at most X, Y or Z" means at most X, (even) at most Y and (even more) at most Z.
- the plastic strip (rear) is transparent (and without defects) and / or the other plastic strip (front) is transparent
- the support is transparent (the electrically controllable system is optionally transparent or at least leaving an overall transparency)
- the placement of said preassembled element between the first and second glazings is in a transparent zone of the first and / or second glazing (face F2 and / or F3 bare or coated with transparent layer)
- the transparent strip (rear) covering the rear face at minus opposite side to said functional area and / or the other plastic band (front) is transparent covering said functional area.
- the method comprises, forming said preassembled element according to at least one of the following configurations (a) or b) or a) + b)): a) assembling the connecting element (rear plastic strip) with the support, the connecting face F L being placed in adhesive contact or bonded with the rear face, bonding face F L is brought into full-surface or spot adhesive contact with the punctual rear face by a network of spaced apart spot adhesive contacts / or is bonded with the rear face, for example in the open surface or punctually via a network of spaced apart ad hoc adhesive zones or else via an adhesive frame (bead of adhesive or double-sided adhesive tape, in particular with a thickness of at most 100 ⁇ m) by example peripheral -forming a seal- or by adhesive strips (bead of glue or double-sided adhesive tape) for example two peripheral strips a) assembly of the other connecting element (front plastic strip), the other side of link F ' L being placed in adhesive contact or glued on the electrically controllable device (and / or
- the adhesive contact which does not involve the addition of adhesive material, is preferably by softening the plastic strip (rear) and / or the other plastic strip (front), preferably thermoplastic, which leads to the adhesive contact. between faces.
- the adhesive contact is by heating and possibly also by pressure, in particular induction heating, hot air, radiation (laser) or using a solution such as alcohol.
- the adhesive contact is point and local heating and possibly also by pressure, including induction heating, hot air, radiation (laser) or using a solution such as alcohol.
- Each point adhesive contact is for example of width of at most 15mm.
- Each ad hoc adhesive bonding is for example of a width of at most 15 mm.
- a heating tool especially local or multi local (and better pressure) can be used a metal pen, a "soldering iron", with a flat tip (and preferably with an anti-adhesive film (silicone, Teflon, PTFE, elastomer etc) able to pass the heat, one or more heated fingers, a heat gun.
- a metal pen a "soldering iron"
- a flat tip and preferably with an anti-adhesive film (silicone, Teflon, PTFE, elastomer etc) able to pass the heat, one or more heated fingers, a heat gun.
- an anti-adhesive film silicone, Teflon, PTFE, elastomer etc
- the point adhesive contacting may be in one operation for all the contacts. You can choose a heating tool that allows you to perform the various spot adhesive spots in one operation.
- the local heating can make it possible not only to form local adhesive contact between the plastic strip (rear) and the rear side support but also between the device and a sheet of the interlayer.
- the local heating may be by application of a heating tool on the back side and / or on the front side. We prefer the back side.
- the electrically controllable device (the rear face or the front surface respectively) is for example on a first sheet of the lamination interlayer, face of the first sheet which is opposite side to said connecting element or to said other connecting element, and a second sheet of the lamination interlayer (in particular the assembly sheet) is on the first sheet, the local heating leads to a one-off contacting of the first sheet with the second slip.
- the front surface of the electrically controllable device is on a first sheet of the lamination interlayer, in particular the assembly sheet, the local heating leads to a point contacting of the front surface of the electrically controllable device with said first sheet of the lamination interlayer.
- the (thermo) plastic strip and said lamination interlayer are in contact or spaced before the lamination for example of at most 5 mm or 1 mm, and after lamination (by creep) the (thermo) plastic strip and said interlayer lamination, are in continuous contact, without leaving a gap between the rear face and contact face and / or the other plastic strip and said interlayer lamination are spaced before the lamination and after lamination the other plastic strip and said interlayer lamination are in continuous contact, leaving no space between the front surface of the device and the bonding face.
- the strip is thermoplastic, is based on polyvinyl butyral
- plasticizers containing less than 15% by weight of plasticizers, preferably less than 10% by weight and more preferably less than 5% by weight and in particular without plasticizer and in particular of thickness e3 of at most 0.15 mm, in particular from 25 to 100 ⁇ m, 40 to 70 ⁇ m and even at most 50 ⁇ m.
- laminating interlayer G is based on poly (vinyl butyral) (PVB) - with plasticizer, in particular with more than 15% by weight of plasticizers, conventional - and in particular with a thickness of at least 0.3 mm and even with at least 0.6 mm and / or the other band is thermoplastic, based on polyvinyl butyral (PVB) containing less than 15% by weight of plasticizers, preferably less than 10% by weight and even more preferably less than 5% by weight. % by weight and in particular without plasticizer, and said lamination interlayer is preferably based on polyvinyl butyral (PVB) especially with more than 15% by weight of plasticizers.
- the support is flexible, plastic, preferably is transparent preferably polyester, especially poly (ethylene terephthalate) or polyimide, in particular with a thickness of 25 to 150pm and even 50 to 100pm.
- the support may be made of plastics material (in particular thermoplastic, polyethylene terephthalate PET, polyethylene naphthalate PEN, polyethylene PE, poly (methyl methacrylate) PMMA, polydimethylsiloxane PDMS, polyamide, polyimide, polycrylate, polyester, polycarbonate, polysulfones, polyethersulfones, thermoplastic polyurethane.
- thermoplastic strip (the other thermoplastic strip) can be integrated / whole or with the local cuts.
- the electrically controllable device glazing may comprise another or more electrically controllable devices spaced apart, each with a plastic strip (respectively another plastic strip) or with a common plastic strip (respectively another plastic strip) for example along the part or all of the edge of the laminated glazing.
- the support has an L-shape, bent, etc.
- the shape of the plastic strip (respectively of the other plastic strip) or alternatively use for simplicity a rectangular, square-shaped strip.
- the plastic strip in this configuration with a rectangular strip and a first support in L or F or E comb, the plastic strip (respectively of the other plastic strip) can protrude substantially from the edge of the first support towards the edge of the first nearest glazing.
- the support can be sufficiently flexible (flexible) to adapt to the curvatures of the curved laminated glazing.
- the support can be associated with a flat connector extending to the edge of the glazing and even beyond it.
- a flexible connector adapted to the curvatures of the glazing comprising a plastic for example PEN, polyimide.
- the flat connector may be of width (dimension along the edge) less than or equal to the dimension of the support (of diodes) especially along the edge.
- the support may be local, for example covering less than 10% of the surface of the laminated glazing, in particular in a peripheral region of the laminated glazing (windshield).
- the preferably flexible support may comprise an external electrical supply portion extending up to the edge of the laminated glazing unit and protruding from the edge of the glazing unit and even folded over the face F4 (or F1) or the another plastic strip protrudes from the edge of one of the first and second glazings and is folded over the face F4 (or F1).
- thermo plastic strip front or rear
- the (thermo) plastic strip may protrude from the edge of one of the first and second windows and is folded on the face F4 or F1 by prefixing with an adhesive tape to the face F4 or F1 and removed after lamination.
- the lamination interlayer before the placement of said preassembled element with the other connecting element, the lamination interlayer comprises a so-called back sheet, which is possibly said assembly sheet, with a main face F'x against the rear face of the support, and the main face F'x optionally comprising said Z'A zone, the other plastic strip called the front plastic strip is against the front face, and on the controllable system which comprises a set of discrete and thin components of preferably with é2 ⁇ 0,15mm, front plastic band possibly having through-holes in the right of the discrete components and after the lamination, the backsheet is in adhesive contact with the rear face, the faces F2 and F3 (out of device zone) and preferably in contact with the other plastic strip (front band).
- the backsheet is in adhesive contact with the rear face, the faces F2 and F3 (out of device zone) and preferably in contact with the other plastic strip (front band).
- the lamination interlayer comprises a so-called front sheet (tinted, wedge , acoustic multilayer, son, composite PVB / PET / PVB), which is possibly said assembly sheet, with a main face Fx placed against the front surface of the electrically controllable device, in particular the front face of the support (especially with a system discrete as an electronic component (opto), and the main face Fx possibly including said zone ZA.
- the front leaflet Particularly unique
- the face Fx is in adhesive contact with the front surface of the device, in particular the front face of the bare or coated support, with electrical circuit, etc.
- the front sheet may be in adhesive contact with (the majority of) the other of the faces F2 or F3 and with (the majority of) the contact face.
- the lamination interlayer comprises a second face-side sheet Fx (in particular perforated sheet with a reserve for accommodating the device in particular)
- the second sheet (perforated) may be in adhesive contact with (the majority of) the contact face and the front slip may be in adhesive contact with (the majority of) the other faces F2 or F3.
- the front sheet may have a blind reserve in the area of the electrically controllable device extending the reserve of the second sheet (perforated).
- the main face Fx of the front sheet has at least one blind hole or through W1 width of at most 20mm, 15mm, 10mm, 5mm, 2mm and even length of at most 10mm ,, 5mm , 2mm housing the so-called discrete electro-controllable system, in particular an electronic (opto) component - such as a photodiode or an inorganic diode - with e2> 0,15mm (requiring the cutting of the interlayer) and in particular submillimetric even of 'at most 0.5mm, width W'2 not more than 20mm, 10mm, 5mm, 2mm and even not more than 10mm, 5mm, 2mm, and e2 ⁇ 0.15mm and e3 ⁇ 0.15mm.
- an electronic (opto) component - such as a photodiode or an inorganic diode - with e2> 0,15mm (requiring the cutting of the interlayer) and in particular submillimetric even of 'at most 0.5mm, width W'2 not more than
- the front sheet is in adhesive contact with the front face of the support.
- the hole is wider than the surface of the electrically controllable system (electronic (opto) component), preferably wider than at most 0.5 mm or even at most 0.1 mm.
- the hole is through and the other plastic band between the bonding face and the front sheet covers each component in a through hole.
- the main face Fx of the front sheet may comprise as many holes as components on the support or even holes common to several adjacent components on the support.
- the other plastic strip or front plastic strip may be between the perforated sheet (through hole) and the contact face for example for a protection of the front surface of or preferably of the components (optoelectronic) the sheet may extend beyond the edge of the support.
- the sheet of the insert is back side in adhesive contact with the back side.
- the other plastic strip front plastic strip
- the other plastic strip is on the front and on the components or has holes in the right of the components to limit the number of interfaces.
- the electrically controllable system When the electrically controllable system is too thick but surface (quite extensive) it is preferably housed in a blind or through hole in a lamination interlayer sheet. Also, in a second configuration, before the placement of said preassembled element (before or after the pre-assembly) with said connecting element and / or the other connecting element, the laminating interlayer comprises a perforated sheet (single sheet, composite sheet etc.
- the perforated leaflet having the main face Fx which is free and possibly comprising said zone ZA (oriented towards the contact face after placement) or F'x (facing towards the bonding face after placement) and possibly including zone Z'A
- the band e (thermo) plastic is next to savings, with a difference in height H1 between the face Fx and the free face of the plastic strip of at most 0.3mm, 0.2mm, 0.15mm and / or l
- Another plastic strip is next to the savings, with a height difference H ⁇ between the face F'x and the free face F ' L of the other plastic strip of at most 0.3mm.
- the free face of the plastic strip being flush with the face of at most 0.3mm, 0.2mm, 0.15mm, flush with the Fx or emerging fax (in excess thickness) of at most 0.3mm, 0, 2mm, 0.15mm.
- the free face of the other plastic strip being flush with the face of at most 0.3mm, 0.2mm, 0.15mm, flush with the Fx fax or emergent (with extra thickness) of at most 0.3mm, 0.2mm, 0.15mm.
- the electrically controllable device emerges from the perforated leaflet (the rear face of the support or the front surface) the electrically controllable device and the main face Fx are spaced from a non-zero height H2 greater than e2 (and smaller than e2 + e'2), H2 being equal to at most 0.3mm, 0.2mm, 0.15mm, and the rear face emerging from the perforated leaflet.
- the method comprises the positioning of an additional thermoplastic plastic strip (and even plastic identical to said plastic strip on the rear face) forming a frame on all or part of the edge of the support of thickness Ex of at most 0, 15mm and less than or equal to H2, and against the edge of the support or spaced at most 1/0, 5mm, and is opposite an area of the perforated sheet.
- the additional plastic strip has a free main face F ", opposite to a connecting face FC, optionally the additional plastic strip comprises a single band or a plurality of plastic strips in staircase and Ex is then the total thickness of the plastic strips
- the bonding face FC may be in adhesive contact with the perforated sheet before the placing of said preassembled element between the first and second glazings, adhesive contact by the aforementioned tools for pre-assembly (softening, local heating, etc.).
- the hole or reserve is for example one-eyed in the first or second PVB.
- the first glazing is external glazing
- the first face is often called F1 face
- the second face is often called face F2
- the second glazing is the external glazing
- the third face is often called F3 face
- the fourth face is often called F4 face.
- the first glazing is external glazing
- the first face is often called F4 face
- the second face is often called F3 face
- the second face is glazing is the internal glazing
- the third face is often called F2 face
- the fourth face is often called F4 face.
- the first and the second windows are made of mineral glass
- the first glazing is in mineral glass and the second glazing is in plastic for example thinner (film), etc., for example in PC, PMMA, PET,
- the second glazing is made of mineral glass and the first glazing is of plastic for example thinner (film) etc., for example in PC, PMMA, PET.
- the laminated glazing with electrically controllable device according to the invention may be part of a double glazing (glazing on the outside of the building or glazing on the inside of the building) or even triple glazing.
- the laminated glazing can form or be part of a partition, an equipment door of a window, a roof.
- the invention also relates to an electrically controllable device glazing, especially obtained according to the manufacturing method as described above, comprising a laminated glazing unit comprising:
- first glazing element transparent, in particular made of mineral or plastic glass, in particular curved, possibly clear, extraclear or tinted in particular gray or green, preferably curved, often forming external glazing, with first and second main faces respectively said face F1; and face F2, in particular F1 or F2 being each naked or coated with a layer (transparent or opaque), in particular mineral (functional layer, monolayer or multilayer etc. in particular layer with a thickness of at most 50 ⁇ m or even submicron) of preferably thickness for automotive glazing of not more than 2.5mm, not more than 2.2mm - in particular 1, 9mm, 1, 8mm, 1, 6mm and 1, 4mm- or even not more than 1, 3mm or not more than 1 mm
- a second glazing transparent, in particular of mineral glass and preferably clear or extraclear or even tinted or plastic, in particular curved, often forming an interior glazing with third and fourth main faces respectively said face F3 and face F4, in particular F3 or F4 each being bare or coated with a layer (functional layer, monolayer or multilayer etc., in particular a layer with a thickness of at most 50 ⁇ m or even submicron), thickness glazing for an automotive glazing preferably lower than that of the first glazing, even not more than 2.2mm - in particular 1, 9mm, 1, 8mm, 1, 6mm and 1, 4mm- or not more than 1, 3mm or more than 1 mm, the total thickness of the first and second glazing preferably being less than 4mm, even at 3.7mm
- first or second glazings being made of mineral glass, in particular F1 or F2 or F3, F4 each being bare or coated with a particularly mineral layer (functional layer, mono or multilayer etc., in particular thickness of not more than 50 pm or even submicron)
- a lamination interlayer of thermoplastic polymeric material in particular in one or more sheets, in particular having a main face FA in adhesive contact with the second face F2 and a main face FB in adhesive contact with the face F3, and in particular a thickness e1 which is subcentiometric, preferably the majority of the face F2 and the face F3 is in adhesive contact with the lamination interlayer, for a car glazing preferably e1 at most 1, 8mm, better not more than 1, 2mm and even at most 0 , 9mm (and better still of at least 0.3mm and even at least 0.5mm), in particular recessed from the edge of the first glazing of at most 2mm and set back from the edge of a second glazing of not more than 2mm
- first or second glazings being of mineral glass and the laminated glazing comprising between the faces F2 and F3:
- an electrically controllable device in particular a strip (elongate, for example square, rectangular, L-shaped, T-shaped, combed, etc.), comprising a support, in particular a strip (elongate, for example square, rectangular, L-shaped, T-shaped, comb, etc.), in particular of width W2 of at most 1 m or at most 40 cm and even at most 20 cm, 10 cm or 5 cm, of thickness e 2 in particular submillimetric and even at most 0.15 mm, with a front face, a rear face and a wafer, the front face being a carrier in a so-called functional zone of an electrically controllable system of thickness e2, preferably submillimetric, in particular with a width W'2 in particular of at most 5 cm or subcentiometric (discrete component etc) or substantially equal to W2 (surface system), and the front face possibly comprising a power supply zone adjacent to the functional area including opening or with an extension beyond the singing of the first or second glazing, the electrically controllable device being
- a polymeric connecting element which is a plastic strip having a thickness e3 of at most 0.3 mm, 0.25 mm and even at most 0.15 mm, in particular from 25 to 100 ⁇ m, 70pm and even at most 50pm in adhesive contact with the rear face and with one of the faces F2 or F3 then called contact face, the connecting element being of lower surface to the lamination interlayer, in particular width W3 of at least 0.8W2 or 0.9W2 and / or not more than 1m or not more than 40cm and not more than 20cm, 10cm or 5cm, the bonding element being less than 1 lamination interlayer
- another polymeric bonding element which is another plastic strip of thickness e3 of at most 0.3 mm, 0.25 mm and even at most 0.15 mm, in particular of 25 to 100pm, 40 to 70pm and even at most 50pm in adhesive contact with the front surface and with one of the faces F2 or F3 then called bonding surface, in particular W'3 width of at least 0 , 8W2 or 0.9W2 and / or not more than 1m or not more than 40cm and not more than 20cm, the other connecting element being of lower surface than the lamination interlayer.
- the plastic strip is thermoplastic, based on polyvinyl butyral (PVB) containing less than 15% by weight of plasticizers, preferably less than 10% by weight and more preferably less than 10% by weight and in particular without plasticizer, and said laminating interlayer is based on polyvinyl butyral (PVB) in particular containing more than 15% by weight of plasticizers
- plastic strip and / or the other plastic strip is thermoplastic, based or poly (vinyl butyral) (PVB) containing less than 15% by weight of plasticizers, preferably less than 10% by weight and more preferably less than 10% by weight and in particular without plasticizer, and said lamination interlayer is based on polyvinyl butyral (PVB) in particular containing more than 15% by weight of plasticizers
- the transparent (thermo) plastic strip has a blur of less than 5% and without bubble-type defects (size of less than 0.1 mm) has a TL of at least 70%, 80%, 90%
- transparent support assembly and thermoplastic strip has a TL of at least 70% and has a blur of less than 5% and / or the other transparent (thermo) plastic strip has a blur of less than 5% and free from defects in bubble type (size less than 0.1 mm) has a TL of at least 70%, 80%, 90%
- the transparent support assembly and thermoplastic strip has a TL of at least 70% and has a blur of less than 5%.
- said plastic strip protrudes from the rear face (at most 10 cm) on at least one side, and even two sides, is in adhesive contact with the lamination interlayer and / or said other plastic strip protrudes from the front surface (not more than 10 cm) on at least one side and even two sides and is in adhesive contact with the lamination interlayer
- the lamination interlayer is made of polyvinyl butyral (PVB), in particular PVB with a hole or reserve comprising the electrically controllable device, optionally
- PVB polyvinyl butyral
- acoustically in particular for a windshield or a roof of a vehicle and / or a corner, in particular for a windshield
- the functional plastic film preferably transparent, such as a polyester, a PET, carrying a functional electroconductive layer, in particular PVB with a hole or blind reserve in the first PVB.
- the electrically controllable system may be chosen in particular from: a capacitive or inductive control switch, an antenna
- one or more electronic (opto) components mounted on the surface of the front face of said support), in particular discrete, in particular of width W2 ⁇ 20 mm, in particular a sensor, a camera, a photodiode, an inorganic light-emitting diode, of which microled
- the plastic strip and the lamination interlayer are in adhesive contact with the front face of the support, in particular the lamination interlayer houses the electronic (opto) component (s) with in particular e2> 0.15mm and e2 ⁇ 0 , 15mm and even e3 ⁇ 015mm, in a blind or through opening preferably a dedicated aperture by optoelectronic component, the possible other connecting element is between the interlayer and the bonding surface and covers the opening or openings
- the other plastic strip is alone on the device, without the plastic strip, possibly perforated to the right of the (opto) electronic components with particular é2 ⁇ 0,15mm and e2 ⁇ 0,15mm and even e3 ⁇ 015mm and e3 greater than or equal to e2, in particular one hole per electronic component (opto), and the lamination interlayer (PVB preferably) is in adhesive contact with the rear face.
- the lamination interlayer PVB preferably
- the sensor in the laminated glazing in particular W'2 width of at most 10mm and / or thickness of at most 2mm or 1 mm and is chosen for example from at least one of the following sensors:
- a rain detector (preferably in the windscreen wiper zone) typically of size from 100 mm 2 to 600 mm 2
- CCD charge coupled device
- CMOAS Complementary Metal Oxide Semi conductor in English
- one or more (typically 6) light sensors such as a photodiode, typically of size 1, 2 x 1, 4 mm 2 to 1, 4 x 1, 8 mm 2 or even of thickness e 2 of at most 0.7 mm and even 0.7mm and / or width W'2 of at most 2mm, for example type APDS-9005 of the company AVAGO TECHNOLOGIES
- thermocouple typically a wire of thickness 0.5mm or less
- an alarm sensor detection of a glazing integrity defect, etc.
- a fog detector typically of conductive wire size of 12 to 150 ⁇ m in diameter, or by an electroconductive layer (opposite F2 or F3) a fog detector and linked to a heating element (resistive, etc.), such as an anti-fog, anti-condensation, anti-freeze, typically of 100-200 cm 2, for example integrated in a rain detector;
- an antenna-forming sensor for example a conductor wire with a thickness of typically 12 ⁇ m to 0.5 mm, for receiving and / or transmitting electromagnetic waves (radio, TV, in particular a local communication network such as BLUETOOTH, WIFI, WLAN) , in particular within the lamination or embedded in a polymeric material (film, etc.)
- an acoustic sensor (based on a piezoelectric element)
- an ultrasonic signal detector preferably on the face F2, (for example based on a piezoelectric element)
- a diagnostic sensor (defects of the laminated vehicle glazing, in particular windscreen or side glazing) based on an electroconductive layer (full surface)
- control detector for example IR control or voice control (piezoelectric).
- the electrically controllable system may be surface-shaped, in particular with a width W2 of at least 20 mm and even 50 mm, and may especially be chosen from
- a surface light system such as an organic electroluminescent system OLED (which can form a pictogram, etc.), a TFEL (thin-film electroluminescent element), or a quantum dot electroluminescent diode called QLED,
- OLED organic electroluminescent system
- TFEL thin-film electroluminescent element
- QLED quantum dot electroluminescent diode
- a dynamic display system (screen) -in any technology, for example AM-OLED-,
- liquid crystal system variable diffusion
- PDLC high band of a windshield, office partition, etc.
- electrochromic system electrochromic system
- lamination interlayer accommodates the device (via a stockpile)
- said plastic strip is on the electrically controllable device without the other plastic strip, in particular said plastic strip projecting and in adhesive contact with the lamination interlayer and is preferably in adhesive contact with the front surface of the support
- the other plastic strip is on the electrically controllable device without the plastic strip, in particular the other plastic strip protruding in adhesive contact with the lamination interlayer and the lamination interlayer is in adhesive contact with the rear face of the support , or k) said plastic strip is on the electrically controllable device in particular protruding and in adhesive contact with the lamination interlayer and the other plastic strip is on the electrically controllable device in particular protruding in adhesive contact with the lamination interlayer (a sheet).
- AMOLED screen can be referred to those described in the patents
- WO2017 / 1 15040 WO2017 / 1 15041 WO2017 / 1 15042 WO2017 / 1 15043.
- a pictogram (enamel etc.) can be referred to those described in WO2017103425 and WO2017103426.
- liquid crystal system for example partition of a habitat can be referred to those described in WO201 1/161391 and WO2012 / 045973.
- liquid crystal system for example a sun protection strip in a windshield or as an optical valve system (SPD)
- SPD optical valve system
- As luminous touch switch can be referred to those described in patents WO2018 / 002707 or WO2018 / 002723.
- the electrically controllable device selected light source LED, OLED, TFEL, QLED etc
- a collimation optics for preferably without the other plastic strip or interlayer of lamination between the collimation optics and the face of the glass in contact.
- the light source and collimation optics assembly may form a (third) stop lamp or a flashing (repeater), a clearance light, a position light.
- the light source emits preferably in the red (auto) is particularly preferably rectangular and peripheral light strip and horizontal;
- the light source preferably emits in the yellow (auto) is especially a luminous band preferably rectangular and peripheral and horizontal, in particular horizontal at the bottom or side edge of the window.
- the electroluminescent system is an organic light-emitting diode called OLED in particular transparent (TOLED) or a quantum dot electroluminescent diode called QLED
- OLED organic light-emitting diode
- TOLED transparent
- QLED quantum dot electroluminescent diode
- the electroluminescent system, in particular OLED or QLED is transparent and has a light transmission of at least 20% and even at least 50%.
- the electroluminescent system is an OLED which is rear-emission comprising the support (transparent or opaque or with an opaque layer) which bears on the front side in this order while moving away from the support: a possible functional sub-layer, a transparent anode, organic electroluminescent system, reflective cathode.
- the OLED can also comprise an encapsulation layer covering the whole (the active surface): resin for example transparent or adhesive plastic film, this plastic film provided with electroconductive zones can be used for the electrical connection.
- the electroluminescent system may be masked from the outside by a masking layer (enamel, etc.) opposite F1 or F2.
- the lamination interlayer is for example formed from one or more sheets.
- the lamination interlayer may comprise at least one so-called central layer of viscoelastic plastic material with vibroacoustic damping properties, especially based on polyvinyl butyral (PVB) and plasticizer, and the interlayer, and further comprising two outer layers of PVB standard, the central layer being between the two outer layers.
- PVB polyvinyl butyral
- patent EP0844075 can be cited. Acoustic PVB described in the patent applications WO2012 / 025685, WO2013 / 175101, especially stained as in WO2015079159.
- the lamination interlayer may comprise an acoustic PVB and / or is (a tinted PVB).
- the lamination interlayer in particular is a PVB at least partially in its thickness.
- the tinted portion being at least (and even at most) between the electroluminescent element (OLED, QLED ..) is the F2 side.
- the preferably internal glass in a laminated glazing unit is preferably chemically hardened. It is preferably clear Examples of applications WO2015 / 031594 or WO2015066201 may be cited.
- the first glazing unit or at least one of the glazings is tinted.
- the glazing in particular laminated, may also comprise a reflective layer or absorber of solar radiation, preferably face F4 or face F2 or F3, in particular a transparent electrolyte oxide layer.
- the TCO layer (of a transparent electro-conductive oxide) is preferably a fluorine-doped tin oxide layer (SnO 2 : F) or a tin-indium mixed oxide (ITO) layer. .
- IZO mixed oxides of indium and zinc
- the doping level i.e., the weight of aluminum oxide based on the total weight
- the doping rate may be higher, typically in a range of 5 to 6%.
- the atomic percentage of Sn is preferably in a range from 5 to 70%, especially from 10 to 60%.
- the atomic percentage of fluorine is preferably at most 5%, usually 1 to 2%.
- ITO is particularly preferred, especially with respect to SnO 2 : F.
- Higher electrical conductivity, its thickness may be lower to achieve the same level of emissivity. Easily deposited by a cathodic sputtering method, especially assisted by magnetic field, called “magnetron process", these layers are distinguished by a lower roughness, and therefore a lower fouling.
- fluorine-doped tin oxide is its ease of deposition by chemical vapor deposition (CVD), which in contrast to the sputtering process, does not require any subsequent heat treatment, and can be implemented on the float flat glass production line.
- CVD chemical vapor deposition
- emissivity is meant the normal emissivity at 283 K according to EN12898.
- the thickness of the low-emissivity layer (TCO, etc.) is adjusted, depending on the nature of the layer, so as to obtain the desired emissivity, which depends on the desired thermal performance.
- the emissivity of the low-emissivity layer is, for example, less than or equal to 0.3, in particular to 0.25 or even 0.2.
- the thickness will generally be at least 40 nm, or even at least 50 nm and even at least 70 nm, and often at most 150 nm or at most 200 nm.
- fluorine-doped tin oxide layers the thickness will generally be at least 120 nm, even at least 200 nm, and often at most 500 nm.
- the low-emissivity layer comprises the following sequence: high-index sub-layer / low-index sub-layer / an optional TCO-dielectric overcoat layer.
- a low-emissivity layer protected during quenching, it is possible to choose high-index sub-layer ( ⁇ 40 nm) / low-index underlayer ( ⁇ 30 nm) / an ITO layer / high-index overcoat (5-15 nm) )) / overlay low index ( ⁇ 90 nm) barrier / last layer ( ⁇ 10 nm).
- the first and / or second glazing is tinted and / or the lamination interlayer is tinted on all of its thickness
- a low emissivity layer in particular comprising a transparent electroconductive oxide layer (TCO) especially a thin layer stack with TCO layer or a stack of thin layers with silver layer (s)
- TCO transparent electroconductive oxide layer
- a solar control layer in particular comprising a transparent electrically conductive oxide layer (TCO) in particular a thin layer stack with TCO layer or a stack of thin layers with silver layer (s)
- TCO transparent electrically conductive oxide layer
- an additional film (polymeric, such as a tinted polyethylene terephthalate PET etc.) is between the faces F2 and F3 or (bonded) at F4 or even face F1.
- the face F4 is coated with a transparent functional layer including low emissivity, preferably comprising a TCO layer, including a zone (electrically powered, therefore electrode) forming a touch button (for controlling the first light surface).
- a transparent functional layer including low emissivity preferably comprising a TCO layer, including a zone (electrically powered, therefore electrode) forming a touch button (for controlling the first light surface).
- a transparent film (PET etc.) carrying a functional layer F2 side face (or F3 face alternatively), may form a capacitive touch switch, It may be the protective film.
- the invention of course relates to any vehicle including automotive comprising at least one glazing as described above.
- a diode may be of the "chip on board” type or even more preferably a surface mounted component (SMD in English) then comprising a peripheral envelope (often referred to as "packaging").
- SMD surface mounted component
- the chip on board may be devoid of optical element (above the chip-semiconductor (embedded or not in the material) to facilitate compactness.
- the envelope is for example epoxy.
- the polymeric envelope may eventually settle (the final thickness after lamination may be less than the initial thickness) during the lamination
- the envelope (polymer) may be opaque.
- Inorganic diodes are for example based on gallium phosphide, gallium nitride, gallium and aluminum.
- diodes can be mentioned the range of OSLON BLACK FLAT sold by OSRAM.
- OSRAM OSLON BLACK FLAT Lx H9PP.
- OSRAM OSLON BLACK FLAT Lx H9PP.
- LCY H9PP yellow light (amber)
- OSRAM LCY H9PP.
- Flexible PCBs include the range of AKAFLEX® products (including PCL FW) from KREMPEL.
- Figure 1 is a front view of a laminated windshield of a motor vehicle on a road, windshield with internal light signaling by means of diodes and OLED in a first embodiment.
- FIG. 1a is a front view of a laminated windshield of a motor vehicle on a road, windshield with internal light signaling by means of diodes and OLEDs in a variant of the first embodiment .
- Figure T is a front view of a laminated windshield of a motor vehicle on a road, windshield with internal light signaling by means of diodes and OLED in a variant of the first embodiment.
- Figure 1 is a schematic front view of a laminated rear window with external light signaling in one embodiment of the invention.
- FIG. 2 is a schematic cross sectional view of an internal light laminated glazing unit in an embodiment of the invention.
- FIG. 2 is a diagrammatic cross-sectional view of a diode-based light-laminated glazing unit in an alternative embodiment of FIG. 2 with its collimation optics for the internal display.
- Figure 2a is a top view of the collimation optics.
- Figure 2b is an overview of the collimation optics.
- FIG. 2bis is a diagrammatic cross-sectional view of a diode light-laminated glazing unit in an alternative embodiment of FIG.
- FIG. 2 "shows a diode mounted on the surface of a diode support.
- Figure 3 is a schematic cross-sectional view of a laminated glazing incorporating an electronic (opto) component in an embodiment of the invention.
- Figure 4 is a perspective view of a LED light pane with the diode support.
- Figure 5 is a front view showing a preassembly of the electrically controllable device using the lamination interlayer and by spot adhesive contact.
- Figure 6 is a front view showing a preassembly of the electrically controllable device using the lamination interlayer and by spot adhesive contact.
- Figure 7 is a front view showing a preassembly of the electrically controllable device with a plastic strip and by spot adhesive contact.
- Figure 7a is a front view showing a preassembly of the electrically controllable device with a plastic strip and by spot adhesive contact.
- Figure 7b is a front view showing a preassembly of the electrically controllable device with a plastic strip and by spot adhesive contact.
- Figure 8 is a sectional view of the preassembly electrically controllable device and rear plastic strip and insert before placement between the glass sheets and lamination.
- Figure 8 is a pre-assembly sectional view of the device and rear plastic strip and interlayer lamination before placement between the glass sheets and lamination.
- FIG. 9a shows an F1 side view of a laminated glazing unit with an electrically controllable device, for example a surface element, such as an OLED for a light function (possibly forming a pictogram) or an OLED screen.
- Figure 9b shows this sectional glazing.
- FIG. 9c shows an F1 side view of a laminated glazing unit with an electrically controllable device, for example a surface element, such as an OLED for a light function (possibly forming a pictogram) or an OLED screen.
- Figure 9d shows this sectional glazing.
- Figure 10 is a sectional view of the pre-assembly electrically controllable device and plastic strip and insert before placement between the glass sheets and lamination to form the glazing of Figure 9d.
- FIG. 10 is a sectional view in pre-assembly of an electrically controllable plastic interlayer device of FIG. 9d before placement between the glass sheets and the lamination.
- Figure 1 shows (from the vision of the interior of the vehicle) a windshield 1000 of a motor vehicle driving on a three-lane road with a car in front.
- the windshield is a laminated glazing unit with internal light signaling and comprising:
- a masking peripheral zone opaque enamel ..
- PCB 3 integrated between the external glazing and the internal glazing 1 'of the laminated glazing
- These diodes in particular of the first set can emit red light alerting the driver when the car before (or any other means of locomotion or an animal) is detected too close. When the front car is far enough away (respect of the safety distance), the diodes are off.
- These diodes in particular the second set can emit red light alerting the driver when a car (or any other means of locomotion or an animal) is detected too close on the left side of the car.
- the signal light may also change from a color (eg orange or amber) when the vehicle at a risky distance to another color eg red when the vehicle at a shorter distance even more dangerous.
- diodes as many diodes as necessary are provided, for example a row with an alternation of red diodes and orange diodes, or one row per color.
- the vehicle integrates at least one sensor (preferably one per set of diodes) to detect these dangerous situations (non-compliance with the safety distance or other) and at least one control unit for driving the diodes.
- the diodes are not necessarily in a row, in particular parallel to the edge of the glazing.
- the PCBs 3 with diodes 4 are for example in the lower quadrant driver side.
- the windshield comprises a set of metal son, almost invisible, for example 50pm which are placed on one side for example face side F3 of the lamination interlayer (over the entire surface), shaped lines straight or not.
- PCB 3 Being here in the clear glass is preferred PCB 3 transparent.
- Each PCB 3 is glued with a transparent thermoplastic band (back) and thin e3 thickness of at most 0.15mm and better less than 100pm and identical in size to the PCB, tape bonded back side of the card ( oriented towards the face F2) and which is in full-surface adhesive contact with the face F2 called the contact face.
- back transparent thermoplastic band
- e3 thickness thin e3 thickness of at most 0.15mm and better less than 100pm and identical in size to the PCB
- each PCB 3 and the so-called transparent thermoplastic strip forms a preassembled element.
- the manufacture of the preassembled element will be described in more detail later.
- the transparent and thin thermoplastic strip of thickness e3 of at most 0.15 mm and better at most 100 ⁇ m and of identical size to the PCB is said before and bonded to the front face 30 of the card (oriented to the face F3) and which is in full surface adhesive contact with the face F3 called bonding face.
- the front band can then be drilled to the right of the diodes or other components (opto) electronic discrete, alternative (sensors, etc.) or in addition, for example ultrafine thickness e2 ⁇ 0.15mm.
- the transparent thermoplastic front strip forms a preassembled element. The manufacture of the preassembled element will be described in more detail later.
- the windshield further comprises two other electrically controllable surface-type devices here of rectangular shape 4 ', 4 "such as OLED screens for example in the middle and along the lower and upper longitudinal edges of the windshield. These screens are for example transparent and in the clear glass.
- thermoplastic transparent or non-so-called front and thin strip of thickness e3 of at most 0.15 mm and better at most 100 ⁇ m and of identical size to the OLED is glued to the front surface of the screen OLED (electroluminescent system side) and which is in full surface adhesive contact with the face F3 called bonding face (bare or coated).
- the OLED screen and the transparent thermoplastic front strip forms a preassembled element. The manufacture of the preassembled element will be described in more detail later.
- a thin and thin transparent thermoplastic strip with a thickness e3 of at most 0.15 mm and better at most 100 ⁇ m and of identical size to the OLED is bonded to the surface of the OLED support (preferably flexible substrate including polyester, PET) and which is in full-surface adhesive contact with the face 12 F2 said contact face (bare or coated).
- the OLED screen and the transparent thermoplastic back band forms a preassembled element. The manufacture of the preassembled element will be described in more detail later.
- This capacitive switch for example, may be pre-assembled with a front and / or rear plastic strip as mentioned above.
- a luminous laminated roof with diodes and / or OLEDS, or QLEDS or TFEL for example, providing a decorative ambient light, or a reading lamp oriented towards the face F4.
- a collimation optics On the front surface can be used a collimation optics and preferably without front plastic strip or lamination interlayer between the collimating optics and the face of the glass in contact.
- Figure 1a shows another windshield of a motor vehicle, windshield 1000 with light signaling in a variant of the first embodiment.
- the face 12 F2 comprises a solid black enamel masking frame preferably and the F4 face 14 (or the face 13 F3) comprises a black enamel masking frame 72 preferably, with openings 70 at the right of the diodes 4.
- the front or rear thermoplastic joining strip 5 may be transparent (tinted, etc.) or opaque. This band 5 is in adhesive contact with the masking layer 71.
- the OLED screen 4 'at the bottom of the windshield is in the enameling zone and there has been a saving 70 at the right of the screen 4'.
- FIG. 1 ' is a front view of a windshield of a motor vehicle on a road, windshield 1000' with internal or even external light signaling by means of diodes in a variant of the first embodiment .
- the first set of diodes 4c on a support type PCB 30C, forms a triangle with a possible central exclamation point. It therefore forms a danger signal.
- flashing repeaters can be visible from the outside (external signaling). It is possible to move the left flashing as far left as possible (if in zone of masking opposite F2 with saving to the right of the diodes) in or to split it and the flashing right as right as possible (if in zone of masking in face F2 with save the diodes or duplicate it.
- Each PCB 30a, 30b, 30c is bonded with a thin thermoplastic strip of thickness e3 of at most 0.15mm and identical in size to the PCB, bonded strip on the rear side of the card (oriented towards the face F2) and which is in full surface adhesive contact with the face F2 called contact face.
- each PCB 30a, 30b, 30c and the thermoplastic strip forms a preassembled element.
- PCBs 30a, 30b, 30c and transparent thermoplastic thin strips are preferred. It can be provided to move them in a similar manner to FIG. 1 bis in a peripheral masking frame.
- the OLED screen 4 "in the upper and central peripheral position of the windshield is in the enameling zone 72 which is enlarged in the center and there has been a saving 70 to the right of the screen.
- Figure 1 is a schematic front view (face side F1 or face 12) of a rear window with external light signaling 100" in one embodiment of the invention.
- a third brake light 101 is formed with, for example, six red diodes 4 on the PCB 3 along the upper longitudinal edge.
- a flasher 102 is formed with, for example, six diodes 4 emitting in the yellow on the PCB 3 along the side edge in play, or a signaling light 103 with, for example, six diodes 4 on the PCB 3 along the lower longitudinal edge in play.
- Each PCB is glued with a thin thermoplastic strip e3 thickness of at most 0.15mm and identical in size to the PCB, tape bonded on the back side of the card (facing F3) and which is in full surface adhesive contact with the face F3 called contact face.
- each PCB 3 and the thermoplastic strip forms a preassembled element. If in the clear glass are preferred PCBs 3 and transparent thermoplastic thin strips. It can be provided to move them in a similar manner to FIG. 1 bis in a peripheral masking frame.
- the bezel further comprises another electrically controllable surface-type device here of rectangular shape 4 ', such as an OLED for example in the middle and along the lower longitudinal edges of the windshield.
- the OLED is for example transparent and in the clear of glass.
- a thin or transparent thermoplastic strip before and thin with a thickness e3 of at most 0.15 mm and better at most 100 ⁇ m and of identical size to the OLED is bonded to the front surface of G OLED ( electroluminescent system side) and which is in full-surface adhesive contact with the face F3 called bonding face.
- G OLED and the transparent thermoplastic front band forms a preassembled element.
- a thin and thin transparent thermoplastic band of thickness e3 of at most 0.15 mm and better at most 100 ⁇ m and of identical size to the OLED and is bonded to the surface of the OLED support (preferably flexible substrate including polyester, PET) and which is in full-surface adhesive contact with the face F2 called contact face.
- the OLED and the transparent back thermoplastic strip form a preassembled element.
- a laminated glazing unit forming a lateral glazing (fixed or opening) with an external luminous signage such as a flashing repeater or else an advertising, informative or decorative display.
- FIG. 2 is a schematic cross-sectional view of an internal light-signal windshield 100 in a first embodiment of the invention, comprising a curved laminated glazing unit, comprising:
- first glazing for example TSA glass and 2.1 mm thick, forming outer glazing, preferably tinted, with first and second main faces January 1, respectively face F1 said - and face F2, and a slice 10
- a lamination interlayer 2 made of polymeric material, preferably PVB, preferably clear, of submillimetric thickness e1, preferably between 0.2 mm and 1 m conventionally about 0.38 mm, for example a PVB sheet (RC41 Solutia or Eastman) of thickness about 0.76 mm or alternatively if necessary an acoustic PVB (tricouche or quadricouche) for example of thickness 0, Approximately 81 mm, of which face FB face F3 side is possibly carrying a set of metal son covering the surface (substantially) in particular opposite the diode or diodes
- the lamination interlayer has a region 21 comprises an opening therethrough surrounding the wafer of the di
- PVB is used with blind holes or even this sheet is retained with through holes and we add a back sheet (between F3 and the so-called hole sheet before) full surface (to insert other elements thicker to d ' other functionalities etc.) PVB or even PVB / PET functional / PVB.
- the diodes are then in blind openings and preferably the front face is in contact with the bottom of the hole or spaced at most 0.2 mm or at most 0.1 mm.
- the diodes 4 (with a single semiconductor chip here) are square in width of the order of 5mm or less.
- a diode may be of the "chip on board” type or even more preferably a surface mounted component (SMD in English) then comprising a peripheral envelope (often referred to as "packaging").
- SMD surface mounted component
- a PCB 3 the finest possible, flexible and preferably even the most discrete possible (minimum width or even transparency) for example comprising a transparent film such as PET, PEN or polyimide and even for the circuit board transparent connection tracks (rather than copper except to make them sufficiently thin).
- the PCB may protrude from the edge of the laminated glazing.
- the lamination interlayer 2 is present between the face F3 and the front face of the PCB 3 on the entire front face of the PCB out of diodes, in the laminated glazing.
- the lamination interlayer 2 is absent from the rear face 30 '.
- the PCB 3 is bonded with a thin thermoplastic strip 5 having a thickness e3 of at most 0.15 mm, in particular 25 to 100 ⁇ m, 40 to 70 ⁇ m and even at most 50 ⁇ m, and of identical size to the PCB or protruding slightly as shown here of the wafer 34, the band whose front face 50 is glued to the rear face 30 'of the card (facing the face F3) and whose rear face 50' is in full surface adhesive contact with the face F2 12 called contact face.
- a thin thermoplastic strip 5 having a thickness e3 of at most 0.15 mm, in particular 25 to 100 ⁇ m, 40 to 70 ⁇ m and even at most 50 ⁇ m, and of identical size to the PCB or protruding slightly as shown here of the wafer 34, the band whose front face 50 is glued to the rear face 30 'of the card (facing the face F3) and whose rear face 50' is in full surface adhesive contact with the face F2 12 called contact face.
- each PCB 3 and the thermoplastic strip 5 form a preassembled element.
- thermoplastic strip is based on polyvinyl butyral (PVB) containing less than 15% by weight of plasticizers, preferably less than 10% by weight and more preferably less than 5% by weight and in particular without plasticizer.
- the laminating interlayer is made of conventional polyvinyl butyral (PVB).
- plasticizer-free PVB tape the product "MOWITAL LP BF" KURARAY company with the thickness e3 that is desired.
- another plastic band of similar size, nature and thickness e3 is added between the face 13 F3 and the face 20 of the PVB.
- each diode is an electronic component including at least one semiconductor chip 41, and is equipped with a peripheral envelope 42 (often called "packaging"), polymeric or ceramic, encapsulating the wafer of the electronic component (and defining the slice of the diode), surrounding the semiconductor chip.
- the envelope may correspond to the maximum thickness (height) e2 of the diode.
- the envelope is for example epoxy.
- a polymeric envelope may eventually settle (the final thickness after lamination may be less than the initial thickness) during the lamination.
- the (polymeric) envelope may be opaque.
- the envelope may comprise a base portion 42 carrying the chip and a reflector portion flared away from the base higher than the chip, and containing a protective resin and / or material with color conversion function.
- the front surface 40 can be defined as the surface of this material covering the recessed chip or at the "front" surface of the reflector.
- the diode may comprise a protective resin or a color conversion function material even just on the semiconductor chip.
- the semiconductor chip can be embedded in a material (resin, etc.).
- FIG. 2 ' is a diagrammatic cross-sectional view of a luminous laminated glazing unit with diodes in an alternative embodiment of FIG. 2 by the addition of a collimation optic 8 which is here a prismatic film 81 with its prisms joined end face 80 and with a rear face 80 'side diode front surface 4, housed in a hole 21 of the PVB, film held by tabs 82 on the front face of the support PCB 3.
- Figure 2a is a view of above the collimation optics which is here a prismatic film with its contiguous prisms 80 and a slice 85.
- Figure 2b is an overview of the prismatic film with its contiguous prisms 80.
- collimation optics such as a Fresnel lens or a prismatic film are described in the application WO2017203171 (for example FIG. 3a and FIG. 2'a to 2'c).
- collimation optics such as two crossed prismatic films or a two-dimensional array are described in WO2017 / 203175 (for example, FIG. 2'a to 2'c and FIG. 1a to 1'z).
- FIG. 2bis is a schematic cross-sectional view of a luminous laminated glazing unit 200a by diodes in an alternative embodiment of FIG. 2.
- plastic strip 5 is on the masking enamel on the face F2 12 and savings 72 'to the right of the diodes are made in masking enamel 72 on the face F4 14.
- the front face is glued by glue dots 6 'to the PVB before the lamination.
- the invention has been described in relation to diodes but is suitable for other electrically controllable discrete devices such as sensors (photodiode, camera, etc.).
- Figure 3 is a schematic cross-sectional view of a laminated glazing unit 300 incorporating an electronic (opto) component as a sensor in an embodiment of the invention.
- the support 3 is here bonded to the contact face 13 which is the face F3 by a thermoplastic band such as a thin and transparent PVB as already described in the preceding figures.
- the support extends beyond the PVB following the wafer by a portion 51 and is folded by a portion 52 in the face F4 14 and the band 5 sticks to the edge and to the face F4.
- a connector 53 is connected to the end of the portion 52.
- FIG. 4 is a schematic cross-sectional view of a luminous laminated glazing unit 400 by diodes in an alternative embodiment of FIG. 2.
- the support 3 is in L with a diode zone 31 and a power supply zone 32 with an extension 33 protruding from the wafer 10 'of the glazing l' linked to wires 9, 9 'and partly
- the back plastic strip (shown for explanatory purposes) is of the same shape, therefore in L.
- the PVB is set back from the wafer 10 '.
- Figure 5 is a front view showing a preassembly of the electrically controllable device 500 using the lamination interlayer and by spot adhesive contact.
- FIG. 5 shows the spot adhesive contact of a front face 50 of a preferably square or rectangular transparent local rear thin plastic strip, ad hoc adhesive contact with a connecting face 20 'of a PVB backsheet. 2 intended to be in contact with the contact face F2 12 of the glazing (slice 10 shown) or the bonding face F3.
- the support 3 of diodes 4 is of rectangular shape and protrudes from the wafer 10.
- the front face 50 of the plastic strip 5 is against the rear face of the diode support and the plastic band 5 protrudes from the wafer 34.
- the spot adhesive contact is by a network of point contacts 60 on either side of the diode zone 31 between PVB and protruding strip 5.
- the PVB and / or the plastic strip 5 are softened by local heating. punctually or using a solution such as alcohol.
- Figure 6 is a front view showing a preassembly of the electrically controllable device 600 using the lamination interlayer and by spot adhesive contact.
- the preassembly differs from FIG. 5 in that the support 3 is in L just as the rear plastic strip 5 is thin and transparent, preferably.
- Figure 7 is a front view showing a preassembly of the electrically controllable device 700 with a plastic strip and by spot adhesive contact.
- the pre-assembly differs from FIG. 6 in that the band 5 is not protruding from the wafer 34.
- the spot adhesive contact is by a network of point contacts 60 opposite the diode area 31 on either side of the diodes 31 between the rear face 30 'of the PCB 3 and the strip 5 and the opposite side to the zone 32 power supply. To do this, the plastic strip 5 is softened by spot local heating.
- Figure 7a is a front view showing a preassembly of the electrically controllable device 700a with a plastic strip 5 and by spot adhesive contact.
- the pre-assembly differs from FIG. 7 in that the support is T-shaped and the local thin plastic band 5 is identical in T-shape.
- Figure 7b is a front view showing a preassembly of the electrically controllable device 700b with a plastic strip and by spot adhesive contact.
- Fig. 8 is a sectional view of the preassembly 800 of an electrically controllable device of a rear local plastic strip and lamination interlayer 2 before placement between the glass and lamination sheets.
- the front face 50 of the thin and transparent plastic backing strip 5 is brought into ad hoc contact with the rear face 30 'of the support 3 of the diodes 4 by a contact network 60 coming from a local heating 7.
- the front face 30 of the diode support is brought into ad hoc contact with the face 20 'of the PVB 2 by a contact network 60' from a local heating 7.
- the PVB may be a set PCB / PET / PVB.
- Figure 8 ' is a pre-assembly sectional view 800' of the electrically controllable device of a rear plastic strip and a lamination interlayer before placement between the glass sheets and lamination.
- the front face 50 of the thin and transparent plastic back strip 5 is brought into point-selective contact with the so-called connecting face 20 of the PVB 2 by a contact network 60a originating from a local heating.
- the front face 50 of the thin and transparent plastic back strip 5 is optionally placed in point contact with the rear face 30 'of the support of the diodes 3 by a contact network 6 from a local heating.
- the front face 30 of the diode support is placed in point-selective contact with the face 20 'of the PVB 2 by a contact network 6' coming from a local heating, PVB 2 provided with individual blind holes housing the diodes 4.
- FIG. 9a shows an F1 side view of a laminated glazing unit with an electrically controllable device 900, for example a surface element, such as an OLED for a light function (possibly forming a pictogram) or an OLED screen.
- Figure 9b shows this sectional glazing.
- the bright and curved laminated glazing comprising:
- first glazing for example TSA glass and 2.1 mm thick, forming outer glazing, preferably tinted, with first and second main faces January 1, respectively face F1 said - and face F2, and a slice 10, the face F2 optionally coated with a functional layer (masking etc)
- a lamination interlayer 2 made of polymeric material, preferably PVB, preferably clear, of submillimetric thickness e1, preferably between 0.2 mm and 1 m conventionally about 0.38 mm, for example formed from a first solid sheet 2a and in adhesive contact with the face 13 F3 after lamination and a second perforated sheet PVB 2b provided with a reserve 25 and on the first sheet in adhesive contact with the face 12 F2 and with the first sheet after foliation
- the OLED 4 comprising a support 3 and a front-face electroluminescent system housed in the reserve 25 and of thickness e2 + e2 less than the thickness of the perforated sheet 2b,
- thermoplastic band including PVB without plasticizer of thickness e3 of at most 0.3 mm and of identical size to the OLED, the rear face of the strip is in full surface adhesive contact with F2 side 12
- thermoplastic strip is based on polyvinyl butyral (PVB) containing less than 15% by weight of plasticizers, preferably less than 10% by weight and more preferably less than 5% by weight and in particular without plasticizer.
- PVB polyvinyl butyral
- plasticizer-free PVB tape the product "MOWITAL LP BF" KURARAY company with the thickness e3 that is desired.
- the laminating interlayer is made of conventional polyvinyl butyral (PVB). It can be acoustic, corner (for a head-up display), composite PVB / functional PET / PVB.
- the solid sheet in particular can be acoustic, corner (for a head-up display), composite PVB / functional PET / PVB.
- the holey sheet in particular can be tinted. Alternatively, a single PVB with a blind hole is used.
- the plastic strip 5 Before the lamination (and before placement between the two windows) there is assembly of the plastic strip 5 with the OLED 4 by local heating giving a ad hoc adhesive contact or by gluing (glue or double-sided) and possibly OLED 4 with the solid sheet 2a for example by local heating.
- OLED 4 transmits towards the face F4 (internal light) and the OLED is emitted through the support of OLED 3 (bottom emitting in English). Then the plastic strip 5 is on the front surface of the OLED, on the electroluminescent system (having or not a polymeric encapsulation).
- OLED 4 transmits towards the F4 side (internal light) and the OLED is top-emitting. Then the plastic strip is on the rear face of the support 3, so the opposite of the electroluminescent system (having or not a polymeric encapsulation).
- FIG. 9c shows an F1 side view of a laminated glazing unit with an electrically controllable device, for example a surface element, such as an OLED for a light function (possibly forming a pictogram) or an active matrix OLED screen (AMOLED).
- Figure 9d shows this sectional glazing.
- This glazing 900 'differs from the glazing of FIG. 9 in that:
- the light is emitted on the F1 1 side face 1, for example for a rear window light signal or a side glazing or even windshield (flashing repeater etc)
- a PVB frame 5a plastic identical to the plastic strip 5 is on the periphery of the OLED.
- the plastic strip 5 is chosen to be protruding on the PVB and preassembled with the PVB 2b, for example by local heating.
- the laminating interlayer is made of conventional polyvinyl butyral (PVB). It can be acoustic, corner (for a head-up display), composite PVB / functional PET / PVB.
- the solid sheet in particular can be stained, acoustic, corner (for a head-up display), composite PVB / functional PET / PVB.
- the holey sheet in particular can be tinted.
- FIG. 10 is a sectional view of the preassembly electrically controllable device, plastic strip and lamination interlayer 900 before placement between the glass sheets and laminating to form for example the glazing 900 of Figure 9d.
- the front face 50 of the thin and transparent plastic strip 5 is placed in point-selective contact with the rear face of the support of the diodes 3 by a contact network 60 coming from a local heating 7 creating a softening and an adhesion.
- the front surface 30 of the OLED 4 is optionally placed in spot contact with the face 20 of the solid PVB sheet 2a by a contact network 60b from the same local heating 7.
- the front face 50a of the plastic frame 5a of material similar to the strip 5 is brought into adhesive contact with the face of the solid PVB sheet 2a by a contact network 60a from a local heating 7.
- the pre-assembled element is placed between two panes, the free faces of the two sheets 2a and 2b are in adhesive contact with the faces F2 and F3 (bare or coated with a layer) after lamination and the free faces of the plastic strips 5, 5a are in adhesive contact with one of the faces F2 or F3 (naked or coated) optionally after laminating as well.
- FIG. 10 ' is a sectional view of the pre-assembly electrically controllable device, plastic strip and lamination interlayer 900' before placement between the glass and lamination sheets to form, for example, a variant of the glazing 900 of FIG. 9d.
- PVB laminating interlayer sheet 2b
- the front face of the rear plastic strip 5 is optionally placed in point contact with the rear face 30 'of the support of the diodes 3 by a network of point contacts 60b from a local heating 7 creating a softening and adhesion.
- the front face 50 of the rear plastic strip 5 is brought into point-selective contact with a face 20 of the PVB 2b by a network of point contacts 60a from a local heating 7 creating a softening and adhesion.
- the front face of the plastic strip before 5 ' is placed in pointwise adhesive contact with the other face 20' of the PVB 2b by a network of spot contacts 60 'from a local heating 7 creating softening and adhesion.
- the same side-side heater 20 may suffice on the side 20 '.
- the pre-assembled element is placed between two panes, the faces 20 'and 20' are in adhesive contact with the faces F2 and F3 (bare or coated with a layer) after lamination and the free faces of the plastic strips 5, 5 ' also.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Transportation (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Fluid Mechanics (AREA)
- Human Computer Interaction (AREA)
- Crystallography & Structural Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Light Receiving Elements (AREA)
- Instrument Panels (AREA)
- Led Device Packages (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1850775A FR3077219B1 (en) | 2018-01-31 | 2018-01-31 | SHEET GLAZING WITH ELECTRICALLY CONTROLLED DEVICE AND MANUFACTURE |
PCT/FR2019/050197 WO2019150037A1 (en) | 2018-01-31 | 2019-01-29 | Laminated glazing with an electrically controllable device, and production thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3746296A1 true EP3746296A1 (en) | 2020-12-09 |
Family
ID=63637938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19709546.6A Pending EP3746296A1 (en) | 2018-01-31 | 2019-01-29 | Laminated glazing with an electrically controllable device, and production thereof |
Country Status (12)
Country | Link |
---|---|
US (1) | US11407204B2 (en) |
EP (1) | EP3746296A1 (en) |
JP (1) | JP2021512039A (en) |
KR (1) | KR20200115553A (en) |
CN (1) | CN110325359B (en) |
AR (1) | AR114744A1 (en) |
BR (1) | BR112020014076A2 (en) |
FR (1) | FR3077219B1 (en) |
MX (1) | MX2020008003A (en) |
PE (1) | PE20210309A1 (en) |
RU (1) | RU2764164C1 (en) |
WO (1) | WO2019150037A1 (en) |
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CN115362097A (en) * | 2020-04-15 | 2022-11-18 | 上海延锋金桥汽车饰件系统有限公司 | Vehicle interior component |
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CN113408059B (en) * | 2021-06-30 | 2022-06-07 | 吉林大学 | Multi-objective optimization method for thickness of automobile composite bumper anti-collision beam |
WO2023038797A1 (en) * | 2021-09-09 | 2023-03-16 | Apple Inc. | Windows with laminated glass layers |
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GB202207366D0 (en) * | 2022-05-19 | 2022-07-06 | Pilkington Group Ltd | Laminated pane comprising an electrical element |
JP7456586B2 (en) * | 2023-05-29 | 2024-03-27 | 昭三郎 丸山 | vehicle display system |
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-
2018
- 2018-01-31 FR FR1850775A patent/FR3077219B1/en active Active
-
2019
- 2019-01-29 US US16/966,361 patent/US11407204B2/en active Active
- 2019-01-29 PE PE2020000949A patent/PE20210309A1/en unknown
- 2019-01-29 JP JP2020541664A patent/JP2021512039A/en active Pending
- 2019-01-29 CN CN201980000862.5A patent/CN110325359B/en active Active
- 2019-01-29 MX MX2020008003A patent/MX2020008003A/en unknown
- 2019-01-29 RU RU2020127872A patent/RU2764164C1/en active
- 2019-01-29 BR BR112020014076-7A patent/BR112020014076A2/en not_active Application Discontinuation
- 2019-01-29 KR KR1020207024187A patent/KR20200115553A/en not_active Application Discontinuation
- 2019-01-29 EP EP19709546.6A patent/EP3746296A1/en active Pending
- 2019-01-29 WO PCT/FR2019/050197 patent/WO2019150037A1/en unknown
- 2019-01-31 AR ARP190100224A patent/AR114744A1/en unknown
Also Published As
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RU2764164C1 (en) | 2022-01-13 |
PE20210309A1 (en) | 2021-02-12 |
WO2019150037A1 (en) | 2019-08-08 |
FR3077219B1 (en) | 2020-06-26 |
CN110325359B (en) | 2022-09-02 |
AR114744A1 (en) | 2020-10-14 |
FR3077219A1 (en) | 2019-08-02 |
CN110325359A (en) | 2019-10-11 |
MX2020008003A (en) | 2020-09-22 |
US20200369007A1 (en) | 2020-11-26 |
JP2021512039A (en) | 2021-05-13 |
KR20200115553A (en) | 2020-10-07 |
US11407204B2 (en) | 2022-08-09 |
BR112020014076A2 (en) | 2020-12-01 |
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