EP3438426A1 - Exhaust purification system - Google Patents
Exhaust purification system Download PDFInfo
- Publication number
- EP3438426A1 EP3438426A1 EP17774649.2A EP17774649A EP3438426A1 EP 3438426 A1 EP3438426 A1 EP 3438426A1 EP 17774649 A EP17774649 A EP 17774649A EP 3438426 A1 EP3438426 A1 EP 3438426A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- exhaust
- injection nozzle
- reducing agent
- exhaust gas
- mixer member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000746 purification Methods 0.000 title claims abstract description 14
- 238000002347 injection Methods 0.000 claims abstract description 54
- 239000007924 injection Substances 0.000 claims abstract description 54
- 239000003054 catalyst Substances 0.000 claims abstract description 31
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 27
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 26
- WTHDKMILWLGDKL-UHFFFAOYSA-N urea;hydrate Chemical compound O.NC(N)=O WTHDKMILWLGDKL-UHFFFAOYSA-N 0.000 claims description 28
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- 239000007789 gas Substances 0.000 claims description 19
- 229910021529 ammonia Inorganic materials 0.000 claims description 12
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 3
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000013618 particulate matter Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
- F01N3/2073—Selective catalytic reduction [SCR] with means for generating a reducing substance from the exhaust gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9431—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/21—Mixing gases with liquids by introducing liquids into gaseous media
- B01F23/213—Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids
- B01F23/2132—Mixing gases with liquids by introducing liquids into gaseous media by spraying or atomising of the liquids using nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/314—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
- B01F25/3141—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit with additional mixing means other than injector mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/421—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path
- B01F25/423—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path by means of elements placed in the receptacle for moving or guiding the components
- B01F25/4231—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path by means of elements placed in the receptacle for moving or guiding the components using baffles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
- F01N3/208—Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2892—Exhaust flow directors or the like, e.g. upstream of catalytic device
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/20—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a flow director or deflector
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/14—Arrangements for the supply of substances, e.g. conduits
- F01N2610/1453—Sprayers or atomisers; Arrangement thereof in the exhaust apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- This disclosure relates to an exhaust purification system, and particularly to an exhaust purification system which is provided with a reduction catalyst.
- an exhaust purification system includes an injection nozzle that adds urea water into an exhaust pipe, and a selective reduction catalyst (referred to as SCR catalyst hereinafter) that takes ammonia generated from the urea water by hydrolysis with exhaust heat as a reducing agent and reduces and purifies nitrogen compounds (referred to as NOx hereinafter) contained in exhaust gas.
- SCR catalyst selective reduction catalyst
- the mixer plate is arranged vertically with respect to a pipe axial direction of an exhaust pipe and urea water is injected obliquely from the injection nozzle into the exhaust pipe with respect to the pipe axial direction.
- the urea water obliquely injected in a substantially conical shape from the injection nozzle cannot collide with an entire surface of the plate, and particularly a plate region which is distant from the injection nozzle cannot be utilized effectively.
- An object of the disclosure is to provide a system in which urea water (reducing agent) injected from an injection nozzle can effectively collide with an entire mixer member.
- the system of the disclosure includes an exhaust pipe, which has a straight line shape, and through which exhaust gas discharged from an engine flows; an injection nozzle configured to inject a reducing agent into the exhaust pipe in a direction obliquely with respect to a pipe axial direction into the exhaust pipe; a reduction catalyst provided in an exhaust system that is on a downstream side of the injection nozzle and configured to purify the exhaust gas by reacting the exhaust gas with the reducing agent; and a mixer member provided inside the exhaust pipe on the downstream side of the injection nozzle and on an upstream side of the reduction catalyst and configured to mix and diffuse the reducing agent with the exhaust gas, in which the mixer member includes a plurality of fins protruding to the downstream side, and the mixer member is arranged inside the exhaust pipe in an inclined manner such that an upstream side surface of the mixer member, which is on an opposite side of the fins, faces an injection port surface of the injection nozzle.
- the mixer member may be arranged inside the exhaust pipe in an inclined manner such that the upstream side surface is perpendicular to an injection axial direction of the injection nozzle.
- the linear piping may be formed in a cylindrical shape
- the mixer member may include a ring member having an elliptic annular shape, an outer periphery of the ring member being fixed to an inner periphery of the linear piping, a plurality of the plate members arranged inside the ring member in a grid shape, and the plurality of fins that is integrally formed with the plurality of plate members and is bent at a predetermined angle.
- the injection nozzle may be configured to inject urea water into the linear piping and the reduction catalyst may be a selective reduction catalyst that takes ammonia generated from the urea water by hydrolysis with exhaust heat as a reducing agent and reduces and purifies nitrogen compounds contained in the exhaust gas.
- the urea water (reducing agent) injected from the injection nozzle can collide with the entire mixer member effectively.
- an exhaust system of a diesel engine (hereinafter, simply referred to as engine) 10 is provided with an exhaust manifold 11, an upstream piping 12, a front stage casing 20, a linear piping 13, a rear stage casing 40 and a discharge piping 14, in order from an exhaust upstream side.
- the upstream piping 12 is formed in a substantially cylindrical shape, and an upstream end thereof is connected to the exhaust manifold 11 and a downstream end thereof is connected to an upstream side opening part of the front stage casing 20.
- the front casing 20 is formed in a substantially cylindrical shape, and a first oxidation catalyst 21 and a filter 22 are accommodated therein in order from the exhaust upstream side.
- the first oxidation catalyst 21 is formed by supporting a catalyst component or the like on a surface of a ceramic carrier such as a cordierite honeycomb structure, for example.
- a ceramic carrier such as a cordierite honeycomb structure, for example.
- the filter 22 for example, is formed by arranging a number of cells divided by porous partition walls along a flow direction of exhaust, and alternately sealing upstream sides and downstream sides of the cells.
- the filter 22 collects particulate matter (PM) in the exhaust to fine pores or surfaces of the partition walls, and performs filter forced regeneration in which the PM are burned and removed when a PM accumulation estimation amount reaches a predetermined amount.
- PM particulate matter
- the linear piping 13 is formed in a substantially straight cylindrical shape, and connects a downstream side opening part of the front stage casing 20 and an upstream side opening part of the rear stage casing 40.
- An injection nozzle 33 configuring a part of a urea water injection device 30 is provided in the linear piping 13, and a mixer plate 50 that will be described in detail later is further provided in the linear piping 13 on a downstream side of the injection nozzle 33.
- the urea water injection device 30 includes a urea water tank 31 that stores urea water, a urea water pump 32 that pumps up the urea water from the urea water tank 31 and an injection nozzle 33 that injects the urea water into the linear piping 13.
- the urea water that is injected from the injection nozzle 33 into the linear piping 13 generates ammonia (NH3) by hydrolysis with exhaust heat and the ammonia is supplied to an SCR catalyst 41 on the downstream side as a reducing agent.
- NH3 ammonia
- the rear stage casing 40 is formed in a substantially cylindrical shape, and the SCR catalyst 41 and a second oxidation catalyst 42 are accommodated therein in order from the exhaust upstream side.
- the SCR catalyst 41 is formed by supporting zeolite or the like on a porous ceramic carrier, for example.
- the SCR catalyst 41 absorbs ammonia that is supplied from the injection nozzle 33 as the reducing agent, and selectively reduces and purifies NOx from the exhaust passing through by the absorbed ammonia.
- the second oxidation catalyst 42 is formed by, for example, supporting a catalyst component or the like on a surface of a ceramic carrier such as a cordierite honeycomb structure, and has a function of oxidizing ammonia slipped from the SCR catalyst 41 to the downstream side.
- configuration of the mixer member 50 includes an elliptic annular shaped ring member 51, a plurality of plate members 53A, 53B that are arranged in a grid shape inside the ring member 51 so as to form an exhaust gas passage, and a plurality of fins 54A, 54B that are formed integrally with the plate members 53A and protrude toward the exhaust downstream side.
- Each of the fins 54A, 54B is formed by making a V-shaped notch on the plate member53A and bending a left portion in a trapezoid shape at a predetermined angle. Further, each of the fins 54A, 54B is formed such that fins 54A bent in one direction (direction A as shown) and fins 54B bent in another direction (direction B as shown) are alternately arranged in parallel.
- the fins 54A, 54B bent in opposite directions are alternately arranged, so that turbulence is generated in the exhaust gas passing through the mixer member 50, and mixing and diffusing of the reducing agent with the exhaust gas is effectively promoted. Further, a plurality of fins 54A, 54B is attached with the urea water and contacts with high temperature exhaust gas that passes through, so that efficiency of generating ammonia from the urea water is effectively improved.
- the injection nozzle 33 is fixed to a seat portion 13A of the linear piping 13 by a bolt or the like (not shown) such that an injection axis Y of the injection nozzle 33 is inclined with respect to a pipe axial direction X of the linear piping 13 at a predetermined angle.
- an outer periphery of the ring member 51 is fixed to an inner periphery of the linear piping 13 by welding or the like, such that an upstream side surface 50A (a side surface on an opposite side of fins 54A, 54B) of the mixer member 50 is inclined with respect to the pipe axial direction X and is perpendicular to the injection axis Y.
- the upstream side surface 50A of the mixer member 50 is not necessarily completely perpendicular to the injection axis Y of the injection nozzle 33 and may incline ⁇ 5 degrees.
- the mixer member 50 is mounted inside the linear piping 13 such that the upstream side surface 50A thereof faces substantially in parallel with an opening surface of an injecting opening 33A of the injection nozzle 33. Accordingly, the upstream side surface 50A of the mixer member 50 is made to face the injection nozzle 33 directly, so that the urea water (reducing agent) injected in a substantially conical shape from the injection nozzle 33 collides with an entire surface of the upstream side surface 50A evenly.
- the mixer member 50 is mounted inside the linear piping 13 in an inclined manner and the upstream side surface 50A of the mixer member 50 faces the injecting opening 33A of the injection nozzle 33 directly, so that the urea water injected in a substantially conical shape from the injection nozzle 33 can collide with the entire surface of the upstream side surface 50A evenly. Accordingly, the entire mixer member 50 can be utilized effectively to promote mixing and diffusing of the exhaust gas with the reducing agent, and reducing efficiency of the SCR catalyst 41 can be reliably improved.
- ammonia reducing agent
- an inclination angle of the mixer member 50 may be set gentler than that in the above embodiment.
- the mixer member 50 may be arranged inside the exhaust pipe in an inclined manner such that the upstream side surface 50A of the mixer member 50 is about 60 degrees to about 85 degrees with respect to the injection axis Y of the injection nozzle 33.
- the mixer member 50 may be arranged inside the exhaust pipe in an inclined manner such that the upstream side surface 50A of the mixer member 50 is about 60 degrees to about 85 degrees with respect to the injection axis Y of the injection nozzle 33.
- a mechanism for mixing and diffusing the reducing agent and the exhaust gas is not limited to the mixer member 50, and as shown in Fig. 5 , a mixer 60 which includes a plurality of blades (fins) 62 radially provided around a hub 61 can also be used. In this case, an upstream side surface of the mixer 60 may be arranged in an inclined manner to face the injection nozzle 33 (see Fig. 3 ) directly.
- the engine 10 is not limited to a diesel engine, and the present invention can be applied to other internal combustion engines such as a gasoline engine.
- the present invention has an effect of enabling urea water (reducing agent) injected from an injection nozzle collide with an entire mixer member effectively, and can be used as an exhaust purification system or the like.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
- This disclosure relates to an exhaust purification system, and particularly to an exhaust purification system which is provided with a reduction catalyst.
- There has been known that such an exhaust purification system includes an injection nozzle that adds urea water into an exhaust pipe, and a selective reduction catalyst (referred to as SCR catalyst hereinafter) that takes ammonia generated from the urea water by hydrolysis with exhaust heat as a reducing agent and reduces and purifies nitrogen compounds (referred to as NOx hereinafter) contained in exhaust gas.
- When distribution of the reducing agent supplied to the SCR catalyst is uneven, the ammonia becomes excessive in a region where a supply amount is large while the NOx cannot be sufficiently reduced and purified in a region where a supply amount is insufficient. Therefore, in order to improve reduction efficiency, it is necessary to mix and diffuse the reducing agent in the exhaust gas so as to evenly distribute the reducing agent in the SCR catalyst. For example, there is disclosed in PTL 1 a technology in which a mixer plate that includes a plurality of fins is provided between a reducing agent injection nozzle and an SCR catalyst so that a reducing agent can be efficiently mixed and diffused in exhaust gas.
- PTL 1:
JP-A-2009-24654 - Incidentally, in the technology described in PTL 1, the mixer plate is arranged vertically with respect to a pipe axial direction of an exhaust pipe and urea water is injected obliquely from the injection nozzle into the exhaust pipe with respect to the pipe axial direction. For this reason, the urea water obliquely injected in a substantially conical shape from the injection nozzle cannot collide with an entire surface of the plate, and particularly a plate region which is distant from the injection nozzle cannot be utilized effectively.
- An object of the disclosure is to provide a system in which urea water (reducing agent) injected from an injection nozzle can effectively collide with an entire mixer member.
- The system of the disclosure includes an exhaust pipe, which has a straight line shape, and through which exhaust gas discharged from an engine flows; an injection nozzle configured to inject a reducing agent into the exhaust pipe in a direction obliquely with respect to a pipe axial direction into the exhaust pipe; a reduction catalyst provided in an exhaust system that is on a downstream side of the injection nozzle and configured to purify the exhaust gas by reacting the exhaust gas with the reducing agent; and a mixer member provided inside the exhaust pipe on the downstream side of the injection nozzle and on an upstream side of the reduction catalyst and configured to mix and diffuse the reducing agent with the exhaust gas, in which the mixer member includes a plurality of fins protruding to the downstream side, and the mixer member is arranged inside the exhaust pipe in an inclined manner such that an upstream side surface of the mixer member, which is on an opposite side of the fins, faces an injection port surface of the injection nozzle.
- The mixer member may be arranged inside the exhaust pipe in an inclined manner such that the upstream side surface is perpendicular to an injection axial direction of the injection nozzle.
- The linear piping may be formed in a cylindrical shape, and the mixer member may include a ring member having an elliptic annular shape, an outer periphery of the ring member being fixed to an inner periphery of the linear piping, a plurality of the plate members arranged inside the ring member in a grid shape, and the plurality of fins that is integrally formed with the plurality of plate members and is bent at a predetermined angle.
- The injection nozzle may be configured to inject urea water into the linear piping and the reduction catalyst may be a selective reduction catalyst that takes ammonia generated from the urea water by hydrolysis with exhaust heat as a reducing agent and reduces and purifies nitrogen compounds contained in the exhaust gas.
- According to the system of the disclosure, the urea water (reducing agent) injected from the injection nozzle can collide with the entire mixer member effectively.
-
- [
Fig. 1] Fig. 1 is a schematic overall configuration diagram illustrating an exhaust purification system according to one embodiment of the present disclosure. - [
Fig. 2] Fig. 2 is a schematic perspective view illustrating a mixer member according to one embodiment of the present disclosure. - [
Fig. 3] Fig. 3 is a schematic cross-sectional view illustrating main parts of an exhaust purification system according to one embodiment of the present disclosure. - [
Fig. 4] Fig. 4 is a schematic cross-sectional view illustrating main parts of an exhaust purification system according to another embodiment of the present disclosure. - [
Fig. 5] Fig. 5 is a schematic front view illustrating a mixer according to another embodiment of the present disclosure. - Hereinafter, an exhaust purification system according to one embodiment of the present disclosure will be described based on the accompanying drawings. Same reference numbers are attached to same components, and names and functions thereof are also the same. Therefore, detailed descriptions with respect to these same components will not be repeated.
- As shown in
Fig. 1 , an exhaust system of a diesel engine (hereinafter, simply referred to as engine) 10 is provided with anexhaust manifold 11, anupstream piping 12, afront stage casing 20, alinear piping 13, arear stage casing 40 and adischarge piping 14, in order from an exhaust upstream side. - The
upstream piping 12 is formed in a substantially cylindrical shape, and an upstream end thereof is connected to theexhaust manifold 11 and a downstream end thereof is connected to an upstream side opening part of thefront stage casing 20. - The
front casing 20 is formed in a substantially cylindrical shape, and afirst oxidation catalyst 21 and afilter 22 are accommodated therein in order from the exhaust upstream side. - The
first oxidation catalyst 21 is formed by supporting a catalyst component or the like on a surface of a ceramic carrier such as a cordierite honeycomb structure, for example. When unburned fuel is supplied by post injection of theengine 10 or by exhaust pipe injection of an exhaust pipe nozzle (not shown), thefirst oxidation catalyst 21 oxides the unburned fuel and raises exhaust temperature. - The
filter 22, for example, is formed by arranging a number of cells divided by porous partition walls along a flow direction of exhaust, and alternately sealing upstream sides and downstream sides of the cells. Thefilter 22 collects particulate matter (PM) in the exhaust to fine pores or surfaces of the partition walls, and performs filter forced regeneration in which the PM are burned and removed when a PM accumulation estimation amount reaches a predetermined amount. - The
linear piping 13 is formed in a substantially straight cylindrical shape, and connects a downstream side opening part of thefront stage casing 20 and an upstream side opening part of therear stage casing 40. Aninjection nozzle 33 configuring a part of a ureawater injection device 30 is provided in thelinear piping 13, and amixer plate 50 that will be described in detail later is further provided in thelinear piping 13 on a downstream side of theinjection nozzle 33. - The urea
water injection device 30 includes aurea water tank 31 that stores urea water, aurea water pump 32 that pumps up the urea water from theurea water tank 31 and aninjection nozzle 33 that injects the urea water into thelinear piping 13. The urea water that is injected from theinjection nozzle 33 into thelinear piping 13 generates ammonia (NH3) by hydrolysis with exhaust heat and the ammonia is supplied to anSCR catalyst 41 on the downstream side as a reducing agent. - The
rear stage casing 40 is formed in a substantially cylindrical shape, and theSCR catalyst 41 and asecond oxidation catalyst 42 are accommodated therein in order from the exhaust upstream side. - The
SCR catalyst 41 is formed by supporting zeolite or the like on a porous ceramic carrier, for example. TheSCR catalyst 41 absorbs ammonia that is supplied from theinjection nozzle 33 as the reducing agent, and selectively reduces and purifies NOx from the exhaust passing through by the absorbed ammonia. - The
second oxidation catalyst 42 is formed by, for example, supporting a catalyst component or the like on a surface of a ceramic carrier such as a cordierite honeycomb structure, and has a function of oxidizing ammonia slipped from theSCR catalyst 41 to the downstream side. - Next, detailed configurations of a
mixer member 50 of the present embodiment will be described based onFig. 2 . - As shown in
Fig. 2 , configuration of themixer member 50 includes an elliptic annularshaped ring member 51, a plurality ofplate members ring member 51 so as to form an exhaust gas passage, and a plurality offins plate members 53A and protrude toward the exhaust downstream side. Each of thefins fins fins 54A bent in one direction (direction A as shown) andfins 54B bent in another direction (direction B as shown) are alternately arranged in parallel. - Accordingly, the
fins mixer member 50, and mixing and diffusing of the reducing agent with the exhaust gas is effectively promoted. Further, a plurality offins - Next, configurations of the
linear piping 13 and themixer member 50 of the present embodiment will be described based onFig. 3 . - As shown in
Fig. 3 , theinjection nozzle 33 is fixed to aseat portion 13A of thelinear piping 13 by a bolt or the like (not shown) such that an injection axis Y of theinjection nozzle 33 is inclined with respect to a pipe axial direction X of thelinear piping 13 at a predetermined angle. In themixer member 50, an outer periphery of thering member 51 is fixed to an inner periphery of thelinear piping 13 by welding or the like, such that anupstream side surface 50A (a side surface on an opposite side offins mixer member 50 is inclined with respect to the pipe axial direction X and is perpendicular to the injection axis Y. Incidentally, theupstream side surface 50A of themixer member 50 is not necessarily completely perpendicular to the injection axis Y of theinjection nozzle 33 and may incline ± 5 degrees. - That is, the
mixer member 50 is mounted inside thelinear piping 13 such that theupstream side surface 50A thereof faces substantially in parallel with an opening surface of an injecting opening 33A of theinjection nozzle 33. Accordingly, theupstream side surface 50A of themixer member 50 is made to face theinjection nozzle 33 directly, so that the urea water (reducing agent) injected in a substantially conical shape from theinjection nozzle 33 collides with an entire surface of theupstream side surface 50A evenly. - As described specifically above, according to the present embodiment, the
mixer member 50 is mounted inside thelinear piping 13 in an inclined manner and theupstream side surface 50A of themixer member 50 faces the injecting opening 33A of theinjection nozzle 33 directly, so that the urea water injected in a substantially conical shape from theinjection nozzle 33 can collide with the entire surface of theupstream side surface 50A evenly. Accordingly, theentire mixer member 50 can be utilized effectively to promote mixing and diffusing of the exhaust gas with the reducing agent, and reducing efficiency of theSCR catalyst 41 can be reliably improved. - Further, by distributing the ammonia (reducing agent) on the
SCR catalyst 41 evenly, it is possible to suppress ammonia slip effectively, and capacity reduction of thesecond oxidation catalyst 42 on the downstream side or cost reduction of the entire device can be effectively realized. - Incidentally, the present disclosure is not limited to the above-described embodiment and can be appropriately modified and practiced without departing from the spirit of the present disclosure.
- For example, as shown in
Fig. 4 , an inclination angle of themixer member 50 may be set gentler than that in the above embodiment. For example, themixer member 50 may be arranged inside the exhaust pipe in an inclined manner such that theupstream side surface 50A of themixer member 50 is about 60 degrees to about 85 degrees with respect to the injection axis Y of theinjection nozzle 33. In this case, by setting a bending angle of each of thefins injection nozzle 33, attachment of the urea water to thefins - Further, a mechanism for mixing and diffusing the reducing agent and the exhaust gas is not limited to the
mixer member 50, and as shown inFig. 5 , amixer 60 which includes a plurality of blades (fins) 62 radially provided around ahub 61 can also be used. In this case, an upstream side surface of themixer 60 may be arranged in an inclined manner to face the injection nozzle 33 (seeFig. 3 ) directly. - Further, the
engine 10 is not limited to a diesel engine, and the present invention can be applied to other internal combustion engines such as a gasoline engine. - The present application is based on Japanese Patent Application No.
2016-064111 filed on March 28, 2016 - The present invention has an effect of enabling urea water (reducing agent) injected from an injection nozzle collide with an entire mixer member effectively, and can be used as an exhaust purification system or the like.
-
- 10
- engine
- 11
- exhaust manifold
- 12
- upstream piping
- 13
- linear piping
- 20
- front stage casing
- 30
- urea water injecting device
- 31
- urea water tank
- 32
- urea water pump
- 33
- injection nozzle
- 40
- rear stage casing
- 41
- SCR catalyst
- 50
- mixer member
- 51
- ring member
- 53A, B
- plate member
- 54A, B
- fin
Claims (4)
- An exhaust purification system comprising:an exhaust pipe, which has a straight line shape, and through which exhaust gas discharged from an engine flows;an injection nozzle configured to inject a reducing agent into the exhaust pipe in a direction obliquely with respect to a pipe axial direction;a reduction catalyst provided in an exhaust system that is on a downstream side of the injection nozzle and configured to purify the exhaust gas by reacting the exhaust gas with the reducing agent; anda mixer member provided inside the exhaust pipe on the downstream side of the injection nozzle and on an upstream side of the reduction catalyst and configured to mix and diffuse the reducing agent with the exhaust gas,wherein the mixer member comprises a plurality of fins protruding to the downstream side, and wherein the mixer member is arranged inside the exhaust pipe in an inclined manner such that an upstream side surface of the mixer member, which is on an opposite side of the fins, faces an injection port surface of the injection nozzle.
- The exhaust purification system according to claim 1, wherein the mixer member is arranged inside the exhaust pipe in an inclined manner such that the upstream side surface is perpendicular to an injection axial direction of the injection nozzle.
- The exhaust purification system according to claim 1 or 2,
wherein the linear piping is formed in a cylindrical shape, and
wherein the mixer member comprises:a ring member having an elliptic annular shape, an outer periphery of the ring member being fixed to an inner periphery of the linear piping;a plurality of plate members arranged inside the ring member in a grid shape; andthe plurality of the fins that is integrally formed with the plurality of plate members and is bent at a predetermined angle. - The exhaust purification system according to any one of claims 1 to 3,
wherein the injection nozzle is configured to inject urea water into the linear piping, and
wherein the reduction catalyst is a selective reduction catalyst that takes ammonia generated from the urea water by hydrolysis with exhaust heat as a reducing agent and reduces and purifies nitrogen compounds contained in the exhaust gas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016064111A JP6662144B2 (en) | 2016-03-28 | 2016-03-28 | Exhaust gas purification system |
PCT/JP2017/011671 WO2017170108A1 (en) | 2016-03-28 | 2017-03-23 | Exhaust purification system |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3438426A1 true EP3438426A1 (en) | 2019-02-06 |
EP3438426A4 EP3438426A4 (en) | 2019-02-06 |
EP3438426B1 EP3438426B1 (en) | 2020-05-13 |
Family
ID=59965511
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17774649.2A Active EP3438426B1 (en) | 2016-03-28 | 2017-03-23 | Exhaust purification system |
Country Status (5)
Country | Link |
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US (1) | US10450921B2 (en) |
EP (1) | EP3438426B1 (en) |
JP (1) | JP6662144B2 (en) |
CN (1) | CN109072752A (en) |
WO (1) | WO2017170108A1 (en) |
Families Citing this family (5)
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JP7003722B2 (en) * | 2018-02-20 | 2022-01-21 | いすゞ自動車株式会社 | Reducing agent sprayer |
CN108686531B (en) * | 2018-06-29 | 2024-04-05 | 东风商用车有限公司 | Simplified shell-and-tube fluid mixer |
DE112019006627T5 (en) * | 2019-01-11 | 2021-11-18 | Cummins Emission Solutions Inc. | Post-treatment system with several dosing modules |
JP7345405B2 (en) * | 2019-05-30 | 2023-09-15 | 日本碍子株式会社 | Mixer for exhaust gas purification equipment, exhaust gas purification equipment, and exhaust gas purification method |
CN112922705B (en) * | 2021-03-11 | 2022-04-01 | 无锡恒和环保科技有限公司 | Novel post-treatment urea mixer for diesel engine |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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ITMI20050655A1 (en) | 2005-04-15 | 2006-10-16 | Iveco Spa | STATIC MIXER |
CN101627190B (en) * | 2007-03-12 | 2012-05-30 | 博世株式会社 | Exhaust gas purification apparatus for internal combustion engine |
JP2009024654A (en) | 2007-07-23 | 2009-02-05 | Bosch Corp | Exhaust emission control device for internal combustion engine, mixer plate, mixer unit, and press molding device for mixer plate |
US9429058B2 (en) | 2008-12-01 | 2016-08-30 | GM Global Technology Operations LLC | Mixing devices for selective catalytic reduction systems |
KR101664494B1 (en) * | 2010-07-08 | 2016-10-13 | 두산인프라코어 주식회사 | Static mixer for mixing urea aqueous solution and engine exhaust gas |
CN201776091U (en) * | 2010-08-17 | 2011-03-30 | 广西玉柴机器股份有限公司 | Mixer |
JP5321667B2 (en) * | 2011-10-18 | 2013-10-23 | トヨタ自動車株式会社 | Dispersion plate |
JP5799788B2 (en) * | 2011-12-12 | 2015-10-28 | いすゞ自動車株式会社 | Internal combustion engine and control method thereof |
DE102013223956A1 (en) | 2013-11-22 | 2015-05-28 | Robert Bosch Gmbh | Device for exhaust aftertreatment |
EP3099906B1 (en) * | 2014-01-31 | 2018-10-10 | Donaldson Company, Inc. | Dosing and mixing arrangement for use in exhaust aftertreatment |
DE102014205158A1 (en) * | 2014-03-19 | 2015-09-24 | Eberspächer Exhaust Technology GmbH & Co. KG | Mixer for an exhaust system |
-
2016
- 2016-03-28 JP JP2016064111A patent/JP6662144B2/en active Active
-
2017
- 2017-03-23 US US16/090,136 patent/US10450921B2/en active Active
- 2017-03-23 EP EP17774649.2A patent/EP3438426B1/en active Active
- 2017-03-23 WO PCT/JP2017/011671 patent/WO2017170108A1/en active Application Filing
- 2017-03-23 CN CN201780020450.9A patent/CN109072752A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
CN109072752A (en) | 2018-12-21 |
JP6662144B2 (en) | 2020-03-11 |
US10450921B2 (en) | 2019-10-22 |
US20190120110A1 (en) | 2019-04-25 |
EP3438426B1 (en) | 2020-05-13 |
WO2017170108A1 (en) | 2017-10-05 |
JP2017180133A (en) | 2017-10-05 |
EP3438426A4 (en) | 2019-02-06 |
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