EP3131955A1

EP3131955A1 - Method for a composite material impregnated with thermoplastic polymer, obtained from a prepolymer and a chain extender

Info

Publication number: EP3131955A1
Application number: EP15725736.1A
Authority: EP
Inventors: Gilles Hochstetter; Thierry Briffaud; Mathieu Capelot
Original assignee: Arkema France SA
Current assignee: Arkema France SA
Priority date: 2014-04-15
Filing date: 2015-04-15
Publication date: 2017-02-22
Also published as: WO2015159021A1; JP2017513739A; US10240016B2; US20170037208A1; FR3019824B1; FR3019824A1; KR20160147265A; CN106459435A

Abstract

The invention relates to a method for a composite material, comprising an assembly of one or more reinforcement fibres, impregnated with at least one thermoplastic polymer having a glass transition temperature (T_g) no higher than 75 °C and a melting temperature from 150 °C to less than 250 °C or a T_g higher than 75 °C, said method including: i) a step of bulk melt impregnating said assembly with at least one thermoplastic polymer, which is the product of an addition polymerization reaction of a reactive precursor composition including: a) at least one prepolymer P(X)n of said thermoplastic polymer including a hydrocarbon molecular chain P and having at the ends thereof n identical reactive X functions, wherein X is a reactive function among: OH, NH₂or COOH, wherein n ranges from 1 to 3; b) at least one chain extender, represented by Y-A-Y, including two identical Y functions that are reactive with at least one of said X functions of said prepolymer a), wherein A is a single covalent bond linking the two Y functions or a non-polymer hydrocarbon biradical; ii) a step of cooling and obtaining a fibrous prepreg; iii) a step of implementing said composite material and final shaping of same. The invention also relates to the use of said thermoplastic polymer as a matrix for impregnating said assembly of fibres enabling the implementation of a fibrous prepreg or composite parts.

Description

The present invention relates to a specific method of manufacturing a thermoplastic composite material comprising impregnating an assembly of one or more of a thermoplastic composite material comprising an impregnation of an assembly of one or more thermoplastics. reinforcing fibers with at least one specific polymer in the molten state and in bulk, said polymer being the polymerization product by polyaddition reaction of a precursor reactive composition based on a prepolymer of said polymer and a chain extender nonpolymeric reactive with said prepolymer. In particular, the invention relates to the use of said non-reactive polymer as melt impregnating binder and bulk of said fibrous assembly, for the manufacture of a thermoplastic composite material wherein said polymer is the thermoplastic matrix. More particularly, this use relates to mechanical moldings or structural parts based on said composite material for lighter composite material parts with sufficient mechanical performance, in particular to replace the metal in various fields of application such as aeronautics, the automotive, rail, road transport, wind, photovoltaics, boating and shipbuilding, sports and recreation, building or civil engineering.

Composite materials and more particularly composite materials comprising reinforcing fibers impregnated with a polymer matrix are used in many technical fields, in particular in the aeronautical, aerospace, wind turbine, automobile, railway, Marine. These applications mainly require composites with high mechanical performance, especially for certain applications at high operating temperatures.

Composites, with matrix based on thermosetting polymers, occupy a preponderant place in these markets thanks to their manufacturing processes and their ease of implementation. These materials are increasingly used for lightening structures, for example in the aeronautics and automotive industries. However, thermosetting polymers can not meet the increasingly important requirements that weigh on manufacturers, which are limiting constraints for these materials, in particular for the automobile with regard to: reducing cycle times, reduced energy consumption and recyclability of the materials used. Other disadvantages of these materials include the toxicity of some of their components and the emission of volatile organic compounds, for example monomers such as styrene, during their handling and implementation and thus requiring protection and / or special handling and implementation conditions. A Another disadvantage of thermosetting materials is the volume shrinkage after firing which affects the dimensional stability and surface appearance after molding which requires specific treatment.

Also, thermoplastic polymers which have the advantage of being easily recyclable and which, in the case of polyamides, are lighter than thermosetting polymers, offer new perspectives in the field of composites as a polymer matrix. However, the current processes for manufacturing thermoplastic matrix composites are more restrictive than those using thermosets and therefore the quality of the composite manufactured is not always optimal. The limiting factor essential for the implementation of a thermoplastic composite is the viscosity of the thermoplastic polymer which will be used as a matrix, impregnating the fibrous substrate. In general, even in the molten state, this viscosity remains high and thus makes the impregnation of the fibrous substrate more difficult than a liquid resin, such as for example a thermosetting resin based on unsaturated polyester or vinyl ester.

The polymer matrix must first have a good impregnation of the reinforcing fibers in order to allow the transmission to the reinforcing fibers of the mechanical stresses to which the composite material is subjected, with a more efficient response of said composite material to the mechanical stress. Next, the coating of said reinforcing fibers with this matrix provides chemical protection to these fibers. In particular, for a thermoplastic matrix composite to have good mechanical properties at the end use, especially in terms of impact resistance, it is necessary that the molecular weight of the thermoplastic polymer of the matrix is as high as possible. On the other hand, this high mass characteristic generally results, for the thermoplastic polymers of the state of the art, during the manufacture of the composite, by a high melt viscosity of the thermoplastic polymer of the matrix. This high viscosity therefore poses serious difficulties for achieving proper impregnation of the fibers: thus, the resulting composite may exhibit impregnation defects with microvoids created which are likely to cause mechanical deficiencies, in particular delamination of the fibers and weaken the final composite material.

Various solutions are known to overcome the problem of impregnation of the fibers. It is possible, for example, to impregnate said fibers under pressure or higher temperature and / or to lengthen the impregnation time. These solutions are unsatisfactory because, under the effect of pressure, the fibers can be disoriented locally causing a loss of properties of the composite or under the effect of a higher temperature, the polymer matrix can degrade thermally with a detrimental effect on the final mechanical performance. On the other hand, increasing the impregnation time to compensate for the high viscosity of the thermoplastic resin proves to be too long to be compatible with mass production of parts. In addition, equipment operating at high pressure is incompatible with the production of large parts because of the cost of such equipment.

Another way to facilitate the impregnation of the fibers is to act on the fiber-matrix interface. Patent EP 0 201 367 thus proposes a fiber-reinforced thermoplastic polymer composite material in which the bond between the polymer and the fibers is ensured by a second thermoplastic polymer of low viscosity favoring the wetting of the fibers. This solution is not easy to implement because it requires not only the presence of a second polymer, but in addition, it is necessary that this second polymer has a good wetting ability of the fibers and that it also has a good compatibility with the main polymer. In addition, this polymer may be a weak point because of its low molecular weight and / or low thermal resistance at low Tg and low melting point.

On the other hand, FR 2 936 441 describes the use as a thermoplastic matrix of a low molecular weight polyamide "resin" with Mw ranging from 5000 to 25,000 and non-scalable, for impregnating a reinforcing fabric for a composite article. . The polyamide resin has as specificity a content of amine or carboxy terminal groups of not more than 20 meq / kg essentially corresponding to polyamides having only amine or carboxy terminal functions. This also explains the non-increase or non-evolution of the molecular masses of these polyamides which is their essential characteristic. The resin is presented as a melt fluid for impregnating the reinforcing fabric. However, the limitation of the molecular weight of said polymers already limits their application performance.

FR 2 603 891 describes a method of manufacturing a composite material consisting of a polyamide matrix reinforced with long reinforcing fibers. These fibers are impregnated with a prepolymer or a polyamide oligomer which has terminal reactive functional groups, capable of reacting with each other under the effect of heating, causing the extension of the polymer chain. The oligomer or prepolymer has a low molecular weight. The reactive functions described in this document react by condensation with, consequently, the formation of volatile condensation by-products such as water, which, if not eliminated, can affect the performance mechanical parts obtained because of the presence of bubbles formed by said volatile by-products.

WO 2005/061209 discloses a precursor article of a composite material comprising a thermoplastic polymeric matrix and reinforcing fibers, wherein the polymeric matrix is itself in the form of son and / or fibers, so as to be able to form a material perfusion composite of said precursor article, in particular by thermocompression. This solution requires a preliminary co-mixing operation, often expensive and this does not solve the problem of the compromise to be made between the viscosity of the thermoplastic resin and its molecular weight.

There is therefore a need first of an improved method of manufacturing a specific thermoplastic polymeric matrix composite material, wherein process, said thermoplastic polymer has a low melt viscosity during the impregnation step fibers despite a high molecular weight Mn which can be for example from 15,000 to 40,000, preferably from 15,000 to 30,000, while allowing a short production cycle, that is to say less than 30 min and more particularly lower at 3 min and therefore high productivity suitable for the manufacture of composite parts, complex geometry and mass production. Said method also offers the technical advantages associated with the use of thermoplastic polymers of high molecular weight, particularly favored by their structure in terms of mechanical performance, lightness (especially in the case of polyamides) and recyclability. These last two environmental constraints are increasingly imposed in a context of energy saving and sustainable development.

More particularly, the challenge facing the present invention is to find a technical solution which is a compromise between a good impregnation of the reinforcing fibers with a specific thermoplastic matrix, which has a low viscosity at the melt impregnation. mass and a high molecular mass thus making it easier to implement fiber prepregs which can be more easily consolidated under low pressure and thus requiring only low pressure molding systems or techniques, with less expensive molds for the manufacture of composite parts large size, by common techniques under reduced pressure, such as for example the RTM, compression injection or infusion, under reduced pressure.

More particularly, said polymer has a glass transition temperature which may be less than or equal to 75 ° C for a semi-crystalline Tf polymer ranging from 150 ° C to less than 250 ° C or a Tg greater than 75 ° C, preferably at least 80 ° C. This last particular case with a particular Tg greater than 75 ° C., in addition to the advantages mentioned, allows to ensure high mechanical performance, especially hot. In particular, the use of said polymer according to the invention must be compatible with a manufacturing technology of said closed mold composite such as RTM (resin transfer molding) or S-RIM (structural RIM or reaction injection molding, structural) or injection-compression or infusion, particularly under reduced pressure, with in particular the absence of any byproduct to be removed or present as a residue of the preparation of said polymer.

Applicant's application WO 2013/060976 already describes a process with impregnation of said fibrous assembly from the precursor reactive composition of said polymer and without any description or suggestion of use of said polymer as produced by said reactive composition, as polymer impregnation in the molten state and in mass of said fiber assembly. What is surprising is that said specific polymer resulting from the chain extension of a prepolymer of said polymer by a reactive extender, itself has a lower viscosity with respect to a polymer and in particular a polyamide of the same molecular weight Mn but without said lengthener incorporated in its structure, thus allowing the easier implementation of fiber prepregs that can be consolidated more easily under low pressure and thus requiring only low pressure molding systems, with less expensive molds for the manufacture of large parts, with common techniques such as RTM, compression injection or infusion, under reduced pressure.

More particularly, the method of the present invention allows a very good impregnation of the reinforcing fibers using a low viscosity thermoplastic polymer derived from a specific precursor reactive composition, while already having a high molecular weight controlled before impregnation. The use of such a polymer allows a good impregnation of the reinforcing fibers and therefore the high mechanical performance targeted. More particularly, for a Tg greater than 75 ° C and preferably at least 80 ° C, more preferably at least 90 ° C, even more preferably at least 100 ° C, said polymer allows a mechanical strength to high temperature, that is to say a creep resistance and in particular with mechanical performance, in terms of modulus and tensile stress, which evolve little to a temperature of at least 90 ° C and preferably at least 100 ° C. This good compromise between the good impregnation of the fibers and the high mechanical performances and, in particular, stable at high temperature for a targeted high specific target, is permitted by the direct use of said thermoplastic polymer obtained by the polyaddition polymerization reaction of a polymer. reactive composition precursor of said polymer thermoplastic, said reactive composition comprising prepolymers a) having identical reactive functions, low molecular weight Mn and not higher than 10000 and chain extenders b) bearing coreactive functions with the functions of said prepolymers a). These elongators and prepolymers are specifically selected to prevent the formation and elimination of gaseous or volatile by-products under the conditions of preparation of said polymer and thus to avoid the formation of microbubbles in said polymer and consequently in the final composite material, as happens in a (poly) condensation polymerization reaction, which is by definition excluded for obtaining the polymer of the present invention.

By the implementation of such a method, excellent cohesion of the composite material is obtained and optimum transmission of forces to the reinforcing fibers and high mechanical performance. More particularly, when said polymer is chosen with a Tg greater than 75 ° C., preferably at least 80 ° C. and more preferably at least 100 ° C., it is suitable for use at high temperature, in particular with mechanical performance that evolves little in terms of modulus and breaking stress up to a temperature of at least 90 ° C, preferably at least 100 ° C.

The invention also allows the use of forming technologies which are generally reserved for thermosetting polymers, at least in the field of composites. According to the invention, it is thus possible to manufacture a thermoplastic matrix composite part by injection and reaction structured molding (SRIM) or by injection-compression or by infusion or by RTM, in particular under reduced pressure.

The first object of the invention therefore relates to a method of manufacturing a composite material comprising an assembly of one or more reinforcing fibers, synthetic or natural, preferably long, assembly impregnated in the molten state by at least one thermoplastic polymer. as a matrix, preferably having a glass transition temperature Tg less than or equal to 75 ° C and a Tf ranging from 150 ° C to less than 250 ° C or a Tg greater than 75 ° C and preferably at least 80 ° C, more preferably from 100 to 200 ° C, even more preferably from 1 to 200 ° C, in particular from 110 ° C to less than 180 ° C and even more preferably from 120 ° C to 170 ° C, said process comprising:

i) a step of impregnating said mass-melt assembly with at least one thermoplastic polymer, in particular having a viscosity at the melt impregnation temperature by mass, not exceeding 200 Pa.s, preferably not exceeding 150 Pa.s, with said at least one polymer being the product of the polyaddition reaction polymerization of a reactive precursor composition comprising:

a) at least one prepolymer P (X) n of said thermoplastic polymer, comprising a hydrocarbon molecular chain P and having at its ends n identical reactive functions X, with X being a reactive functional group of: OH,

Nhb or COOH, with n ranging from 1 to 3, preferably n being 1 or 2, more preferably 2, preferably said prepolymer having a semi-aromatic and / or semi-cycloaliphatic structure and in particular a number-average molecular weight Mn ranging from 500 to 10,000, preferably 1000 to 10,000, more preferably from 1000 to 6000 and even more preferably from 2000 to 6000 g. mol ^"1

b) at least one chain extender, represented by Y-AY, comprising two Y functions identical and reactive with at least one of said functions X of said prepolymer a), with A being a single covalent bond linking the two functions Y or a non-polymeric hydrocarbon biradical, preferably said elongator having Y selected from: oxazine, oxazoline, oxazolinone, oxazinone, imidazoline, epoxy, isocyanate, maleimide, cyclic anhydride or aziridine, preferably oxazoline or oxazine and a molecular weight of less than 500, in particular less than 400

ii) a step of cooling and obtaining a fibrous prepreg

iii) a step of implementation and final formatting of said composite material.

More particularly, said thermoplastic polymer is obtained by polymerization of a precursor reactive composition comprising a prepolymer of said impregnating polymer, chosen from: a polyamide, a polyester, their copolymers including polyamide-polyethers or mixtures thereof and preferably a polyamide.

Said prepolymer a) P (X) n corresponds in particular to n = 1 or 2, preferably n = 2 and X reactive functional group selected from: OH, NH 2, COOH, preferably NH 2 or COOH with said hydrocarbon molecular chain P being of semi-cycloaliphatic or semi-aromatic structure with said polymer having a Tg greater than 75 ° C, preferably at least 80 ° C and more preferably at least 90 ° C. The term "semi-cycloaliphatic" means for the polymer or prepolymer according to the invention that said polymer or prepolymer comprises in its units a cycloaliphatic structure and preferably with at least 25 mol% of its units comprising said cycloaliphatic structure. Similarly, a semi-aromatic structure can be defined. "Semi-crystalline" means for the thermoplastic polymer of the invention a polymer which has a melting peak corresponding to a melting temperature Tf, measured by DSC according to the methods indicated below. The molecular weight values Mn, the glass transition temperature Tg and, as the case may be, the melting temperature Tf or the crystallization temperature Te and the melt viscosity or the inherent viscosity are determined in the absence of Specific contrary indication, according to the methods given on page 36 of WO 2013/060476 and more specifically as follows below.

The melt viscosity of the polymer or prepolymer or precursor composition is measured according to the manufacturer's reference manual of the measuring apparatus used, which is a Physica MCR301 rheometer, under a nitrogen sweep at the temperature given under shear 100s ^"1 , between two parallel planes with a diameter of 50 mm.

The Mn of the prepolymer or the thermoplastic polymer is determined from the titration (assay) of the terminal functions X according to a potentiometric method (back-titration of a reagent in excess with respect to the OH terminal functions and direct assay for NH 2 or carboxy) and from the theoretical functionality ncale (vs X) calculated from the material balance and the functionality of the reactants.

Measurement of intrinsic or inherent viscosity is performed in m-cresol. The method is well known to those skilled in the art. The ISO 937 standard is followed but the solvent is changed (use of m-cresol instead of sulfuric acid and the temperature is 20 ° C).

The glass transition temperature Tg of the thermoplastic polymers used or polymeric fibers (Tg ') used is measured by using a differential scanning calorimeter (DSC) after a ^2nd pass in heaters, according to ISO January 1357 -2. The heating and cooling rate is 20 ° C / min.

The melting point Tf and the crystallization temperature Tc is measured by DSC, after a ^1st heater, according to ISO 1 1357-3. The heating and cooling rate is 20 ° C / min.

According to a more particular option of the process of the invention, said thermoplastic polymer is obtained from a precursor composition comprising an extender b) with said function Y being chosen from the following with respect to the function X of said prepolymer:

for X being Nh or OH, in particular NH2: ^■ Y chosen from the groups: maleimide, optionally blocked isocyanate, oxazinone and oxazolinone, cyclic anhydride, epoxide, preferably oxazinone and oxazolinone

and

when X is COOH:

^■ Y chosen from the groups: oxazoline, oxazine, imidazoline or aziridine such as 1, 1 '-iso- or terephthalic phthaloyl-bis (2-methyl aziridine), preferably oxazoline.

According to another option, said polymer is semi-crystalline with a Tg lower than 75 ° C. and a melting temperature Tf ranging from 150 ° C. to less than 250 ° C., preferably said polymer and its prepolymer a) as defined above. top may be based on a polyamide PA6, PA1 1, PA12, PA 6.10, PA6.12, PA10.10, PA10.12.

With regard to said extenders b) suitable for obtaining said polymer used in the impregnation step i), examples of chain extenders with reactive functions Y oxazoline or oxazine, suitable for the implementation of the polymer, may be mentioned. used in the process of the invention. We can refer to those described under references A, B, C and D on page 7 of the application EP 0 581 642 of the Applicant and their preparation processes and their reaction modes which are exposed. A is bisoxazoline, bisoxazine, 1,3-phenylene bisoxazoline and 1,4-phenylene bisoxazoline.

As examples of suitable Y imidazoline reactive chain extenders, reference may be made to those described (A to F) on pages 7 to 8 and Table 1 on page 10 in the Applicant's application EP 0 739 924 as well as only to their preparation processes and their modes of reaction which are exposed to them.

As examples of Y = oxazinone or oxazolinone reactive chain extenders, reference may be made to those described under references A to D on pages 7 to 8 of the Applicant's Application EP 0 581 641 and to their processes. of preparation and their reaction modes which are exposed to it.

Examples of groups Y oxazinones (ring with 6 atoms) and oxazolinones (ring with 5 atoms) are suitable Y groups derived from: oxazinone benzoxazinone or oxazolinone, with A being a simple covalent bond with respective corresponding lengtheners being bis (benzoxazinone), bisoxazinone and bisoxazolinone.

A may also be C 1 -C ₄ alkylene, preferably C ₂ -C 10 alkylene, but preferably A is arylene and, more particularly, may be phenylene (1, 2 or 1, 3 or 1, 4 substituted with Y) or naphthalene (disubstituted with Y) or phthaloyl (iso- or terephthaloyl) or A may be cycloalkylene.

For the Y functions such as oxazine (6-ring), oxazoline (5-ring) and imidazoline (5-ring), the radical A can be as described above with A possibly being a single covalent bond and with the respective corresponding extenders being: bisoxazine, bisoxazoline and bisimidazoline. A may also be C 1 to C 12 alkylene, preferably C 2 to C 10 alkylene. The radical A is preferably an arylene and, more particularly, it may be a phenylene (1, 2 or 1, 3 or 1, 4 substituted with Y) or a naphthalene (disubstituted with Y) radical or a phthaloyl radical (iso- or terephthaloyl) or A may be cycloalkylene.

The presence of a catalyst for the reaction between the prepolymer a) (P (X) n) and the Y-YY extender at a level ranging from 0.001 to 2%, preferably from 0.01 to 0.5% by relative to the total weight of said two co-reactants can accelerate the reaction of (poly) addition and thus shorten the duration of the polyaddition reaction for obtaining said polymer. Such a catalyst may be chosen from: 4,4'-dimethylaminopyridine, p-toluenesulphonic acid, phosphoric acid, NaOH and optionally those described for polycondensation or transesterification as described in EP 0 425 341, page 9, lines 1 to 7.

More particularly, said elongator corresponds to Y chosen from oxazinone, oxazolinone, oxazine, oxazoline or imidazoline, preferably oxazoline and A representing a single covalent bond between the two functions Y or alkylene - (CH2) m - with m ranging from 1 to 14 and preferably 2 to 10 where A is cycloalkylene or substituted or unsubstituted arylene, in particular benzene arylenes, phenylenes o-, m-, p- or naphthalenic arylenes, preferably A being a cycloalkylene or an arylene or A being a simple covalent bond between the two functions Y.

According to a particularly preferred option, the weight ratio of said elongate in said thermoplastic polymer ranges from 1 to 20% and preferably from 5 to 20% by weight. This level is the level of lengthener chemically incorporated by polyaddition with said prepolymer into said polymer used for melt impregnation of said fiber assembly.

A chain of said polymer may comprise and preferably comprises at least 2 chains of said prepolymer a) linked together by an elongator molecule b) and more particularly the number of prepolymer chains a) per chain of said polymer may vary from 2 to 80 and preferably from 2 to 50. The Mn of said polymer may vary from 12,000 to 40,000, preferably from 12,000 to 30,000.

More preferably, said prepolymer a) carries a function X = carboxy with n = 2 (at ± 0.1) and said extension b) carries a function Y = oxazoline. In this case, said thermoplastic polymer has a repeating unit structure according to the following formula (I):

- 0 - C - P - C - 0 ~ R '- NH - C - R ~ C ~ NH - R' -

I l 1 8

o o o o

(I)

with R = A with A being as defined above according to the invention for said Y-A-Y extender and chosen from a single covalent bond or an optionally substituted aliphatic or cycloaliphatic or aromatic hydrocarbon chain biradical,

R 'being an optionally substituted aliphatic or cycloaliphatic or aromatic hydrocarbon chain and whose shortest chain connecting the neighboring -O- and -NH- units has 2 or 3 carbon atoms,

P being the chain of said prepolymer a) bearing X = carboxy functions.

Preferably in the structure of said polymer, the extender b) is between two prepolymer chains a) and not at the ends. This means that said polymer is obtained with a molar excess of the prepolymer a) with respect to said elongator b) and functions X with respect to the functions Y.

Even more particularly in the latter two cases, said extender is selected from: phenylene bis oxazolines, preferably 1,3-phenylene bis (2-oxazoline) and 1,4-phenylene bis (2-oxazoline).

Regarding said polymer, it is preferably a polyamide which is the reaction product of a prepolymer a) polyamide with an extender b) as defined above. In this particular case, said prepolymer a) is a polyamide prepolymer obtained from: the polycondensation of at least one linear or branched aliphatic diamine and at least one aromatic and / or cycloaliphatic dicarboxylic acid containing at least one ring at 4, 5 or 6 optionally substituted carbon atoms and / or the polycondensation of at least one cycloaliphatic diamine with at least one linear or branched, cycloaliphatic or aromatic aliphatic dicarboxylic acid and optionally with the presence of at least one compound chosen from: lactam, an aminocarboxylic acid or the stoichiometric combination of an aliphatic dicarboxylic acid and an aliphatic diamine.

According to a particular option of the process of the invention, said thermoplastic polymer is a polyamide which may be a homopolyamide or copolyamide, aromatic and / or semi-cycloaliphatic, more particularly corresponding to one of the following formulas: polyamides from: 8.T, 9.T, 10.T, 11.1T, 12.T, 6.T / 9. T, 9.T / 10.T, 9.T / 1 1.T, 9.T / 12.T, 9 / 6.T, 10 / 6.T, 1 1 / 6.T, 12/6. T, 10 / 9.T, 10 / 10.T, 10/1 1.T, 10 / 12.T, 1 1 / 9.T, 1 1 / 10.T, 1 1/1 1 .T, 1 1 / 12.T, 12 / 9.T, 12 / 10.T, 12/1 1.T, 12 12.T, 6.10 / 6.T, 6.12 6.T, 9.10 / 6.T, 9.12 / 6 T, 10.10 / 6.T, 10.12 / 6.T, 6.10 / 9.T, 6.12 9.T, 9.10 / 9.T, 9.12 / 9.T, 10.10 / 9.T 10.12 / 9.T, 6.10 /10.T, 6.12 10.T, 9.10 / 10.T, 9.12 10.T, 10.10 / 10.T, 10.12 / 10.T, 6.10 / 12.T, 6.12 12.T, 9.10 / 12.T, 9.12 12.T, 10.10 / 12.T, 1 1 / 6.T / 9.T, 1 1 / 6.T / 10.T, 1 1 / 6.T / 1 1T, 1 1/6. T / 12.T, 1 1 / 9.T / 10.T, 1 1 / 9.T / 1 1 .T, 1 1 / 9.T / 12.T, 1 1 / 10.T / 1 1, 1 1 / 10.T / 12.T, 1 1/1 1 /12.T, 6.T / 10.T, 6.T / 1 1.T, 6.T / 12.T, 10.T / 1 1 .T, 10.T / 12.T, 1 1 .T / 12.T, 12 / 6.T / 10.T, 12 6.T / 1 1 .T, 12 / 6.T / 12. T, 12 9.T / 10.T, 12 9.T / 1 1.T, 12 9.T / 12.T, 12 / 10.T / 1 1 T, 12 / 10.T / 12.T, 12/1 1 .T / 12.T or previous terpolymer polyamides with 12 / replaced by 9 /, 10 /, 6.10 /, 6.12 /, 10.10 /, 10.12 /, 9.10 / and 9.12 / or all the polyamides mentioned above where the terephthalic (T) is partially or completely replaced by isophthalic (I), naphthalene 2 , 6 dicarboxylic and / or 1, 3 or 1, 4 CHDA (cyclohexane dicarboxylic acid), with all or part of the aliphatic diamines may be replaced by cycloaliphatic diamines or all the polyamides mentioned above, with replacement of the C 6 to C 12 aliphatic diamine with a cycloaliphatic diamine from BMACM (bis (3-methyl, 4-amino cyclohexyl) methane), BACM (bis (amino cyclohexyl) methane) and / or IPDA (isophorone diamine) and with replacement of all or part of the aromatic diacid T, with a linear or branched C 6 to C 18 aliphatic diacid.

It is obvious that it is the polyamide structure of said prepolymer a) incorporated in said polymer by the polyaddition reaction which gives said polyamide said structure mentioned above. The structure of said elongate or extended chain polyamide comprises a chain extender located between two polyamide prepolymer chains a). Therefore, the structure quoted above corresponds perfectly to that of said polyamide prepolymer a) used to prepare said higher molecular weight polyamide and this is how it should be interpreted.

According to a more particular variant of the process, said thermoplastic polymer is a semi-crystalline polyamide. Still, this polyamide structure includes the structure of said prepolymer a), with an extender b) being located between two prepolymer chains a). It is this overall structure of the polymer that is semi-crystalline. In this case, the polyamide prepolymer a) is or can be also semi-crystalline.

The semi-crystalline structure is characterized by a melting temperature Tf and a crystallization temperature Te which can be measured by DSC according to the methods indicated above (according to description on page 6 of WO 2013/060976). According to a particular option of said method of the invention, it may comprise a step i ') prior to step i) of impregnation, of preparation of said polymer by polyaddition reaction in said reactive precursor composition between said prepolymer a) and said extender b), preferably said reaction being carried out in bulk melt in an extruder in line transferring said polymer in the molten state to said fiber assembly for said impregnation step i).

As regards the impregnation step i), it may be carried out in a mold for final processing of said composite material, in particular by transfer of said polymer in the molten state to said fiber assembly. Otherwise, the impregnation step i) can also be performed outside the final processing mold of said composite material.

Said step i) of melt impregnation may also comprise a preliminary step of dusting said fiber assembly with said polymer in powder form, followed by a step of heating and melting said powder and optionally a calendering step, thus making it possible to obtain a preimpregnated fibrous material as an intermediate product in step ii), before said final step iii) of implementation.

With respect to said implementation step iii), it can be carried out in closed mold with resin transfer molding (RTM), injection and reaction structured molding (S-RIM) or infusion molding or injection-compression molding, particularly under reduced pressure. Said implementation step iii) can also be carried out in open mold by pultrusion through a heating die, with possible further processing of the semi-finished products obtained. In particular, an implementation can be carried out by superimposition of unidirectional ribbons (UD) obtained by the AFP technique (automatic fiber placement) or by thermocompression and more particularly by AFP comprising a laser heating, with said polymer used comprising, via the precursor reactive composition, specific additives which absorb at the wavelength of a laser, in particular UV or IR laser, when the UD ribbons are based on glass fibers or carbon fibers.

In the case where the step i) of impregnating said fiber assembly is carried out in a mold, said fiber assembly may be in the form of a preform placed in said mold. Preferably, the fibers of said preform are bound by a polymer identical to the impregnating polymer or different from said polymer but compatible with said impregnating polymer. It is considered as compatible a binder polymer of said preform which is at least partially miscible with said impregnating polymer.

Said fibers may be natural, that is to say fibers of vegetable or animal origin and also synthetic prepared by man. As natural fiber of origin Preferred vegetable is flax fiber. Synthetic fibers are even more preferred and selected from carbon, glass, ceramic or aramid fibers. Preferred fibers are long fibers selected from carbon, glass, ceramic or aramid fibers.

Said fibers are in particular long fibers of L / D> 1000 and preferably

> 2000.

Said impregnation polymer as a polymer matrix may comprise, in the dispersed state, carbonaceous fillers, in particular carbon black or carbon nanofillers, preferably carbon nanofillers, among graphenes and / or carbon nanotubes and / or carbon nanofibrils or mixtures thereof.

More particularly, the presence of such fillers or additives in said impregnating polymer, either initially or by addition to the molten state, makes it possible to render the matrix of said conductive composite material enabling particular applications requiring elimination and prevention. electrostatic charges or to allow during the implementation of the composite material a uniform and homogeneous heating by the induction technique.

According to another option, said method according to the invention comprises a step of implementation carried out by thermocompression of prepregs under reduced pressure, in particular according to the vacuum covering technique.

The composite material, which can be obtained by the process of the invention, can be in the form of a part or a composite article, for applications in the field of aeronautics, the automobile, railway, road transport. , wind, photovoltaic, boating, sports and recreation, building, civil engineering, electrical or electronics.

More particularly, this may relate to the manufacture of profiled reinforcements, hulls such as a boat hull, panels, including sandwich panels, composite tanks such as an automobile tank, composite pipes such as pumping tubes and pipes. for transporting oil or gas, hollow bodies, airplane wings, aircraft fuselage, beam or bulkhead in a house or boat, spar, spoiler, automobile crankcase, brake disc, cylinder body or steering wheel, car body, wagon, shoe sole or golf club.

The present invention also covers and in particular the use of a polymer as defined above, in particular polyamide, as mass impregnation polymer in the molten state of an assembly of one or more synthetic or natural reinforcing fibers, for the manufacture of a preimpregnated fibrous material or of a final piece of composite material.

More particularly, this use relates to the manufacture of a composite part, in particular of mechanical part or structure, in the field of aeronautics, automobile, railway, road transport, wind, photovoltaic , boating, sports and recreation, building or civil engineering, electrical or electronics.

The following examples are presented to illustrate the invention and its performance and in no way limit its scope.

Methods of determining the characteristics quoted

The melt viscosity of the prepolymer or precursor composition is measured according to the manufacturer's reference manual of the meter used which is a Physica MCR301 rheometer, under a nitrogen sweep at the given temperature under 100 shear. s ^"1 , between two parallel planes with a diameter of 50 mm.

The Mn of the prepolymer or thermoplastic polymer is determined by potentiometry, steric exclusion chromatography in PMMA equivalents or by

NMR following indication.

The glass transition temperature Tg of the thermoplastic polymers used is measured using a differential scanning calorimeter (DSC), after a second heat-up, according to the standard ISO 1,1357-2. The heating and cooling rate is 20 ° C / min.

The melting temperature Tf and the crystallization temperature Te are measured by DSC, after a first heating, according to the standard ISO 1,1357-3. The heating and cooling rate is 20 ° C / min.

The enthalpy of crystallization of said matrix polymer is measured in Differential Scanning Calorimetry (DSC) according to the standard ISO 1,1357-3. Examples

Preparation of a polyamide polymer by chain extension of a prepolymer

(or oligomer) reactive

A-1 Preparation of the reactive prepolymer P (X) n

This procedure is representative of all the polyamide prepolymers according to the invention.

In a 14 liter autoclave reactor, 5 kg of the following raw materials are introduced:

500 g of water,

diamines,

amino acids or lactams,

the diacids,

35 g of sodium hypophosphite in solution,

0.1 g of WACKER AK1000 antifoam (company Wacker Silicones).

The nature and molar ratios of the units and molecular structures of the reactive prepolymer polyamides (by reference test) are given in Table 1 below.

The closed reactor is purged of its residual oxygen and then heated to a temperature of 230 ° C of the material. After stirring for 30 minutes under these conditions, the pressurized steam which has formed in the reactor is gradually relieved in 60 minutes, while gradually increasing the material temperature so that it is established at a minimum of Tf + 10 ° C at atmospheric pressure for semi-crystalline polymers of Tf> 230 ° C or 250 ° C for the other polymers.

The oligomer (prepolymer) is then drained through the bottom valve, then cooled in a bucket of water, and then ground.

The characteristics are presented in Table 1 below:

Table 1: Characteristics of Prepared Prepolymers

(*): Milliequivalents per kilogram

(**): amorphous polymer

A-2 Preparation of the polyamide polymer E by chain extension with a Y-A-Y type extender

10 g of the above dried and ground prepolymer are mixed with a stoichiometric amount of 1,3-phenylene-bis (2-oxazoline) (PBO).

The mixture is introduced under a nitrogen sweep into a co-rotating conical screw micro-extruder DSM (volume 15 mL) preheated to a temperature T1 equal to 200 ° C. for prepo 1 and 2 and T1: 280 ° C. for prépo 3, under rotation of the screws at 100 rpm. The mixture is left under recirculation in the micro-extruder and the increase in viscosity is monitored by measuring the normal force. After about 2 minutes, a plateau is reached and the contents of the micro-extruder are drained in the form of a rod. The air-cooled product is granulated.

Table 2: Analytical Characteristics of Polyamides E

obtained with chain extension

(*) Amorphous polymer

A-3 Preparation of comparative polyamides PA without chain extender

The comparative polyamides lacking chain extenders are synthesized according to a procedure identical to the reactive prepolymers P (X) n with this procedure being representative of all the comparative polyamides prepared, except that the molar mass Mn of the comparative polymer is adjusted. with an excess of diacid less important than that with the corresponding prepolymer, according to the method well known to those skilled in the art.

The characteristics of these comparative polyamides CE are presented in Table 3 below.

Table 3: Analytical Characteristics of Comparative Polyamides CE

without chain extenders

(*) Amorphous polymer

A-4 Comparison of the Melt Viscosities of the PAs According to the Invention E and Comparative PAs CE

The viscosities of the polymers according to the invention CE and comparative polyamides lacking EC chain extenders are reported in Tables 4 to 6 below: Table 4: Viscosities of the polyamides E1 of the invention

and comparative CE1 (base PA 1 1)

These results are shown in Figure 1.

Table 5: Viscosities of tests E3 and CE3 (PA base amorphous 61/101)

Table 6: Viscosities of tests E4 and CE4 (base PA MXDT / 10T)

The results clearly show that the melt viscosities of the PAs according to the invention are lower than those of the comparative PAs for T> Ti temperatures with a growing difference with increasing temperature.

Claims

1) A method of manufacturing a composite material comprising an assembly of one or more reinforcing fibers, synthetic or natural, preferably long, impregnated in the molten state by at least one thermoplastic polymer as a matrix, preferably having a temperature glass transition Tg less than or equal to 75 ° C and melting temperature (Tf) from 150 ° C to less than 250 ° C or a Tg greater than 75 ° C and preferably at least 80 ° C, more preferably from 100 to 200 ° C, even more preferably from 1 to 200 ° C, in particular from 1 to less than 180 ° C, said process comprising:

i) a step of impregnating said mass-melt assembly with at least one thermoplastic polymer, in particular having a viscosity at the melt impregnation temperature by mass, not exceeding 200 Pa.s. , preferably not exceeding 150 Pa.s, with said at least one polymer being the product of the polyaddition reaction polymerization of a reactive precursor composition comprising:

a) at least one prepolymer P (X) n of said thermoplastic polymer comprising a hydrocarbon molecular chain P and having at its ends n identical reactive functions X, with X being a reactive function of: OH, Nhb or COOH, with n ranging from 1 at 3, preferably n being 1 or 2, more preferably 2 and in particular a number-average molecular mass Mn ranging from 500 to 10,000, preferably from 1000 to 10,000, more preferably from 1000 to 6000 and even more preferably from 2000. at 6000 g. mol ^"1

b) at least one chain extender, represented by Y-AY, comprising two Y functions identical and reactive with at least one of said functions X of said prepolymer a), with A being a single covalent bond linking the two functions Y or a non-polymeric hydrocarbon biradical, preferably said elongator having Y selected from: oxazine, oxazoline, oxazolinone, oxazinone, imidazoline, epoxy, isocyanate, maleimide, cyclic anhydride, aziridine, preferably oxazoline or oxazine and a molecular weight of less than 500, in particular less than 400

ii) a step of cooling and obtaining a fibrous prepreg

iii) a step of implementation and final formatting of said composite material. 2) Process according to claim 1, characterized in that said thermoplastic polymer is obtained by polymerization of a precursor reactive composition comprising a prepolymer of said impregnating polymer chosen from: a polyamide, a polyester, their copolymers including polyamide-polyethers or mixtures thereof and preferably a polyamide.

3) Process according to claim 1 or 2, characterized in that said prepolymer P (X) n corresponds to n = 1 or 2, preferably n = 2 and that X is a reactive functional group chosen from: OH, Nhb, COOH, preferably NH 2 or COOH and said hydrocarbon molecular chain P is of semi-cycloaliphatic or semi-aromatic structure and said polymer has a Tg greater than 75 ° C, preferably at least 80 ° C.

4) Method according to one of claims 1 to 3, characterized in that said thermoplastic polymer is obtained from a precursor composition comprising an extender b) with said function Y being chosen from the following with respect to the function X said prepolymer:

for X being NH2 or OH, in particular NH2:

^■ Y chosen from the groups: maleimide, optionally blocked isocyanate, oxazinone and oxazolinone, cyclic anhydride, epoxide, preferably oxazinone and oxazolinone

and

when X is COOH:

5) Method according to one of claims 1 to 4, characterized in that when Y is selected from oxazinone, oxazolinone, oxazine, oxazoline or imidazoline, preferably oxazoline and A represents a single covalent bond between the two functions Y or an alkylene - (CH 2) _m - with m ranging from 1 to 14 and preferably from 2 to 10 or A represents a cycloalkylene or substituted arylene alkyl or unsubstituted, in particular benzene arylenes, among phenylenes o-, m-, p or the naphthalenic arylenes, preferably A being cycloalkylene or arylene where A is a single covalent bond between the two Y functions.

6) Method according to one of claims 1 to 5, characterized in that the weight ratio of said elongator in said thermoplastic polymer ranges from 1 to 20%, preferably from 5 to 20%. 7) Method according to one of claims 1 to 6, characterized in that a chain of said polymer comprises at least 2 chains of said prepolymer a) linked together by an elongator molecule b), preferably the number of prepolymer chains a) by chain of said polymer ranging from 2 to 80 and preferably from 2 to 50.

8) Method according to one of claims 1 or 2 and 4 to 7, characterized in that said polymer is semi-crystalline with a Tg less than 75 ° C and a melting temperature Tf ranging from 150 ° C to less than 250 ° C, preferably said polymer and its prepolymer a) being based on a polyamide PA6, PA1 1, PA12, PA 6.10, PA6.12, PA10.10, PA10.12.

9) Method according to one of claims 1 to 8, characterized in that said prepolymer a) carries X = carboxy function with n = 2 (to ± 0.1) and that said elongator is functional Y = oxazoline .

10) Process according to claim 9, characterized in that said thermoplastic polymer has a repeating unit structure according to the following formula (I):

- O - c - P - c o - R '- NH C - R - C - NH - R' -

8 8 ï 8

o o o o

(I)

with R = A with A being as defined in claim 1 or 5 and selected from a single covalent bond or an optionally substituted aliphatic or cycloaliphatic or aromatic hydrocarbon chain biradical,

P being the chain of said prepolymer a) bearing X = carboxy functions.

1 1) Process according to claim 9 to 10, characterized in that said extender is selected from: phenylene bis oxazolines, preferably 1,3-phenylene bis (2-oxazoline) and 1,4-phenylene bis (2- oxazoline).

12) Process according to any one of claims 1 to 7 and 9 to 1 1, characterized in that said prepolymer a) is a polyamide prepolymer obtained from: the polycondensation of at least one linear or branched aliphatic diamine and at least one aromatic and / or cycloaliphatic dicarboxylic acid having at least one optionally substituted 4-, 5- or 6-carbon ring and / or the polycondensation of at least one cycloaliphatic diamine with at least one linear aliphatic dicarboxylic acid or branched, cycloaliphatic or aromatic and optionally with the presence of at least one compound selected from: a lactam, an aminocarboxylic acid or the stoichiometric combination of an aliphatic dicarboxylic acid and an aliphatic diamine.

13) Process according to any one of claims 1 to 7 and 9 to 12, characterized in that said thermoplastic polymer is a polyamide, homopolyamide or copolyamide, semi-aromatic and / or semi-cycloaliphatic, more particularly corresponding to one of the following formulas: polyamides from: 8.T, 9.T, 10.T, 11.1T, 12.T, 6.T / 9.T, 9.T / 10.T, 9.T / 1 1.T, 9.T / 12.T, 9 / 6.T, 10 / 6.T, 1 1 / 6.T, 12 / 6.T, 10 / 9.T, 10 / 10.T, 10 / 1 1.T, 10 / 12.T, 1 1 / 9.T, 1 1 / 10.T, 1 1/1 1 .T, 1 1 / 12.T, 12 / 9.T, 12/10 .T, 12/1 1.T, 12 / 12.T, 6.10 / 6.T, 6.12 / 6.T, 9.10 / 6.T, 9.12 / 6.T, 10.10 / 6.T, 10.12 / 6. T, 6.10 / 9.T, 6.12 / 9.T, 9.10 / 9.T, 9.12 / 9.T, 10.10 / 9.T 10.12 / 9.T, 6.10 / 10.T, 6.12 / 10.T, 9.10 /10.T, 9.12 / 10.T, 10.10 / 10.T, 10.12 / 10.T, 6.10 / 12.T, 6.12 / 12.T, 9.10 / 12.T, 9.12 / 12.T, 10.10 / 12 .T, 1 1 / 6.T / 9.T, 1 1 / 6.T / 10.T, 1 1 / 6.T / 1 1T, 1 1 / 6.T / 12.T, 1 1 /9.T/10.T, 1 1 / 9.T / 1 1 .T, 1 1 / 9.T / 12.T, 1 1 / 10.T / 1 1 T, 1 1 / 10.T / 12.T, 1 1/1 1 /12.T, 6.T / 10.T, 6.T / 1 1.T, 6.T / 12.T, 10.T / 1 1 .T, 10. T / 12.T, 1 1 .T / 12.T, 12 / 6.T / 10.T, 12 / 6.T / 1 1 .T, 12 / 6.T / 12.T, 12 / 9.T / 10.T, 12 / 9.T / 1 1.T, 12/9. T / 12.T, 12 / 10.T / 1 1 T, 12 / 10.T / 12.T, 12/1 1 .T / 12.T or previous terpolymer polyamides with 12 / replaced by 9 /, 10 / , 6.10 /, 6.12 /, 10.10 /, 10.12 /, 9.10 / and 9.12 / or all the polyamides mentioned above where the terephthalic (T) is replaced partially or totally by isophthalic (I), naphthalene 2,6 dicarboxylic acid and / or 1, 3 or 1, 4 CHDA (cyclohexane dicarboxylic acid), with all or part of the aliphatic diamines being replaced by cycloaliphatic diamines or all the polyamides mentioned above, with replacement of the aliphatic diamine at C6 to C12 with a cycloaliphatic diamine from BMACM, BACM and / or IPDA and with replacement of all or part of the aromatic diacid T with a linear or branched C 6 aliphatic diacid 14) Process according to any one of Claims 1 to 13 characterized in that said thermoplastic polymer is a semi-crystalline polyamide istallin.

15) Method according to one of claims 1 to 14, characterized in that it comprises a step i ') prior to step i) of impregnation, preparation of said polymer by polyaddition reaction of said reactive precursor composition comprising said prepolymer a) and said elongator b), preferably said reaction being carried out in bulk melt in an extruder in line transferring said melt polymer to said fiber assembly for said impregnating step i).

16) Method according to one of claims 1 to 15, characterized in that the impregnation step i) is carried out in a mold for final implementation of said material composite, in particular by transfer of said polymer in the molten state on said fiber assembly.

17) Method according to one of claims 1 to 15, characterized in that the impregnation step i) is performed outside of the final processing mold of said composite material.

18) Process according to claim 1 to 17, characterized in that said step i) of melt impregnation comprises a preliminary step of dusting said fiber assembly with said polymer in the form of powder, followed by a step of heating and melting said powder and optionally a calendering step, thereby obtaining a preimpregnated fibrous material as an intermediate product in step ii), before said step iii) of final implementation.

19) Method according to claim 16, characterized in that said implementation step iii) is carried out in a closed mold with resin transfer molding (RTM), structured injection molding and reaction (S-RIM) or infusion molding. or injection-compression molding.

20) Method according to one of claims 1 to 15, characterized in that said step iii) implementation is carried out by thermocompression of prepregs under reduced pressure.

21) A method according to claim 16, characterized in that said implementation step iii) is carried out in open mold by pultrusion through a heating die, with possible further processing of the semi-finished products obtained.

22) Method according to claim 16, characterized in that said fiber assembly is in the form of a preform placed in said mold.

23) Method according to one of claims 1 to 22, characterized in that said fibers are long fibers selected from carbon fibers, glass, ceramic or aramid.

24) Method according to one of claims 1 to 23, characterized in that said polymer matrix comprises in the dispersed state carbonaceous fillers, in particular carbon black or carbon nanofillers, preferably carbon nanofillers, among graphenes and / or carbon nanotubes and / or carbon nanofibrils or mixtures thereof.

25) Method according to one of claims 1 to 24, characterized in that said composite material is in the form of part or composite article, for applications in the field of aeronautics, automotive, railway, road transport, wind, photovoltaic, boating, sports and recreation, building or civil engineering, electrical or electronics.

26) Use of a polymer as defined in one of claims 1 to 14, as melt-impregnating polymer of an assembly of one or more synthetic or natural reinforcing fibers, for manufacturing a preimpregnated fibrous material or a composite end piece.

27) Use according to claim 26, characterized in that it is the manufacture of a composite part, in particular of mechanical part or structure, in the field of aeronautics, automotive, railway , road transport, wind, photovoltaics, boating, sports and recreation, building, civil engineering, electrical or electronics.