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EP2926073B1 - Heat exchanger - Google Patents

Heat exchanger Download PDF

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Publication number
EP2926073B1
EP2926073B1 EP13799266.5A EP13799266A EP2926073B1 EP 2926073 B1 EP2926073 B1 EP 2926073B1 EP 13799266 A EP13799266 A EP 13799266A EP 2926073 B1 EP2926073 B1 EP 2926073B1
Authority
EP
European Patent Office
Prior art keywords
refrigerant
flow channel
heat exchanger
flow
region
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13799266.5A
Other languages
German (de)
French (fr)
Other versions
EP2926073A1 (en
Inventor
Uwe FÖRSTER
Gottfried DÜRR
Herbert Hofmann
Christoph Walter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mahle International GmbH
Original Assignee
Mahle International GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of EP2926073A1 publication Critical patent/EP2926073A1/en
Application granted granted Critical
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/04Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
    • F28D1/0408Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids
    • F28D1/0417Multi-circuit heat exchangers, e.g. integrating different heat exchange sections in the same unit or heat exchangers for more than two fluids with particular circuits for the same heat exchange medium, e.g. with the heat exchange medium flowing through sections having different heat exchange capacities or for heating/cooling the heat exchange medium at different temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B39/00Evaporators; Condensers
    • F25B39/04Condensers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0093Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2339/00Details of evaporators; Details of condensers
    • F25B2339/04Details of condensers
    • F25B2339/047Water-cooled condensers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2500/00Problems to be solved
    • F25B2500/18Optimization, e.g. high integration of refrigeration components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/008Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for vehicles
    • F28D2021/0084Condensers

Definitions

  • the invention relates to a heat exchanger with a first flow channel for a refrigerant, with a second flow channel for a refrigerant and with a third flow channel for a coolant, wherein the first flow channel a first region for first cooling of the refrigerant and a second region for further cooling of the refrigerant wherein, in the first flow channel, the refrigerant can be flowed in a high-pressure phase and in the second flow channel, the refrigerant can be flowed in a low-pressure phase.
  • a heat exchanger with the features of the preamble of claim 1 is made FR 2 924 490 known.
  • condensers are used to cool a refrigerant to the condensation temperature and then condense the refrigerant. This occurs in particular with refrigerants which experience at least one phase transition from gaseous to liquid within the refrigerant circuit.
  • capacitors have a collector, in which a volume of refrigerant can be kept in order to compensate for volume fluctuations in the refrigerant circuit. As a result, a stable supercooling of the refrigerant can be achieved.
  • the collector is usually arranged on the capacitor. It is flowed through by the refrigerant, which has already flowed through part of the condenser. After flowing through the collector, the refrigerant is returned to the condenser and subcooled in a subcooling below the condensation temperature.
  • capacitors are known in which the refrigerant undergoes no phase transition. These capacitors regularly have only one cooling section, in which the refrigerant is brought into thermal contact with a coolant.
  • heat exchangers which after the condensation section and the subcooling an internal heat exchanger is connected downstream.
  • a collector is preferably arranged between the condensation section and the subcooling section. While heat transfer takes place between a refrigerant and a coolant within the condensation section and the subcooling section, a heat transfer takes place in the internal heat exchanger between the refrigerant in two different states, namely in a high pressure phase and a low pressure phase.
  • a disadvantage of the devices known from the prior art is in particular that when using CO 2 (R744) as refrigerant high pressures within the refrigerant circuit occur, which burden the previously known heat exchanger beyond their load limits.
  • the heat exchanger should characterized by a compact design and cost-effective production.
  • An embodiment of the invention relates to a heat exchanger with a first flow channel for a refrigerant, with a second flow channel for a refrigerant and with a third flow channel for a coolant, wherein the first flow channel has a first region for first cooling of the refrigerant and a second region for further cooling of the refrigerant, wherein in the first flow channel, the refrigerant is flowable in a high pressure phase and in the second flow channel, the refrigerant is flowable in a low pressure phase, wherein a first heat transfer between the refrigerant in the first region of the first flow channel and the coolant takes place in the third flow channel and a second Heat transfer between the refrigerant takes place in the second region of the first flow channel and the refrigerant in the second flow channel.
  • the temperature of the refrigerant can be further lowered in the high pressure phase.
  • the cooling capacity in the refrigerant circuit can be increased overall.
  • the second region of the first flow channel and the second flow channel form a first unit and the first region of the first flow channel and the third flow channel form a second unit, wherein the first unit and the second unit can be connected as a unit.
  • the heat exchanger has an accumulator which stores a storage volume of the refrigerant and / or means for filtering and / or means for drying the refrigerant.
  • the accumulator serves as a storage medium for the refrigerant.
  • it stores the refrigerant in the low pressure phase between. This is used to compensate for volume fluctuations of the refrigerant or to compensate for refrigerant losses, which may arise for example due to leaks.
  • the accumulator may advantageously comprise means for drying and / or filtering the refrigerant. This has an advantageous effect on the quality of the refrigerant and thus also on the efficiency of the refrigerant circuit.
  • the accumulator is assigned to the heat exchanger.
  • the additional accumulator may be particularly advantageous if the heat exchanger itself must be made as compact as possible.
  • the accumulator can be installed independently of the heat exchanger in the vehicle.
  • the passage of refrigerant out of the second region of the first flow channel leads into the second flow channel via the accumulator.
  • the refrigerant passing through the accumulator can be ensured that volume fluctuations of the refrigerant can be fully compensated at any time. Overall, it improves the efficiency of the refrigerant circuit.
  • the third flow channel is adjacent to the first region of the first flow channel and the second flow channel is adjacent to the second region of the first flow channel.
  • first unit and / or the second unit is formed in stacked disc design.
  • a construction in stacking disk design is particularly simple and particularly cost-effective due to the small number of different elements.
  • first unit and / or the second unit is formed in tube-rib construction.
  • the first unit and / or the second unit is formed by a plurality of tubes, wherein the tubes are adjacent to each other and at least partially in thermal contact with each other, wherein the tubes of each the refrigerant and / or the coolant can flow through.
  • the flow of the refrigerant and the coolant in pipes is particularly advantageous, in particular with regard to the pressure resistance of the heat exchanger.
  • a particularly high compressive strength can be achieved.
  • the first unit and / or the second unit is formed by a plurality of tubes, wherein between the tubes turbulence inserts are arranged, wherein the arrangement of tubes and turbulence inserts is encased by a housing, wherein the tubes of a Coolant and / or a refrigerant can flow through and can be flowed around by a coolant and / or a refrigerant.
  • a structure in which a part of the tubes is flowed through by a first fluid and at the same time flows around a second fluid is particularly advantageous, since in this way a particularly high heat transfer can be realized.
  • a preferred embodiment of the invention is characterized in that the heat exchanger is formed in a stacked disk construction, wherein the stacking of individual disc elements, a heat exchanger block is formed and formed between the disc elements channels, wherein a first number of channels is associated with the first flow channel, a second number the channels is associated with the second flow channel and a third number of the channels is associated with the third flow channel.
  • one or more of the flow channels experience one or more deflections of their flow direction, as a result of which the fluid flows in the flow channels can run in cocurrent and / or countercurrent and / or crosstalk.
  • the fluid flows can be advantageously controlled.
  • the heat transfer can be significantly increased and the efficiency of the refrigerant circuit can be improved.
  • the accumulator has the second region of the first flow channel and the second flow channel, wherein heat transfer takes place within the accumulator between the second region of the first flow channel and the second flow channel.
  • Such a design is advantageous because the heat exchanger can be made even more compact, which is particularly advantageous in terms of the available space.
  • a further preferred embodiment is characterized in that the accumulator and the heat exchanger are designed as a structural unit.
  • An assembly of the accumulator and the heat exchanger is advantageous because the required space can be reduced overall. In addition, a simpler installation in the vehicle is possible because no additional piping between the heat exchanger and the accumulator must be provided.
  • the refrigerant is CO 2 (R744).
  • the heat exchanger has a compressive strength that allows internal pressures greater than 100 bar.
  • the compressive strength of 100 bar and more is particularly advantageous for the areas through which the high-pressure refrigerant flows. Also for the areas through which the low-pressure refrigerant and the coolant flow, this pressure resistance may be advantageous.
  • the Fig. 1 shows a schematic view of a heat exchanger 1.
  • the heat exchanger 1 is divided into a cooling section 6 and in an inner heat exchanger 5.
  • a refrigerant in a high-pressure phase (high-pressure refrigerant) 2 is brought into thermal contact with a coolant 3, so that a heat transfer from the high-pressure refrigerant 2 to the coolant 3 is formed.
  • the Hochdrucckältesch 2 is thus further cooled.
  • the high-pressure refrigerant 2 flows via a fluid inlet 7 into the cooling section 6.
  • a plurality of flow channels are arranged, which are partially flowed through by the high-pressure refrigerant 2 and through which the coolant 3 flows.
  • Within the internal heat exchanger 5 also a plurality of flow channels are arranged, wherein a number of these flow channels is associated with the low-pressure refrigerant 4 and a further number of channels is associated with the high-pressure refrigerant 2. Both the flow channels in the internal heat exchanger 5 and in the cooling section 6 are not shown for reasons of clarity.
  • the flow channels for the high-pressure refrigerant 2, the coolant 3 and the low-pressure refrigerant 4 may be arranged within the heat exchanger in any order.
  • the flow channels of the different fluids can be arranged, for example, alternately.
  • an arrangement may be provided in which a plurality of flow channels for the same fluid are arranged adjacent to each other.
  • the flow of the high-pressure refrigerant 2 through the heat exchanger 1 runs along the fluid inlet 7 through the flow channels in the interior of the cooling section 6 along the flow channels in the inner heat exchanger 5 and finally out of the heat exchanger 1 from the fluid outlet 8.
  • the coolant 3 flows via the fluid inlet 9 into the cooling section 6 of the heat exchanger 1 and there along the flow channels within the cooling section 6 to the fluid outlet 10. There, it flows out of the heat exchanger 1 from.
  • the low-pressure refrigerant 4 flows via a fluid inlet 11 into the inner heat exchanger 5 and there along the flow channels associated therewith through the inner heat exchanger 5. It finally flows out of the inner heat exchanger 5 via the fluid outlet 12.
  • deflections may be provided, whereby the flow direction of the individual fluids is deflected. In this case, areas can be generated in which two fluids flow in cocurrent or in countercurrent to each other.
  • the high-pressure refrigerant 2 is within the refrigerant circuit, softer in the Fig. 1 is not shown, transferred via a likewise not shown expansion valve in a low pressure phase and thus to the low pressure refrigerant 4.
  • the Fig. 2 shows a further schematic view of the heat exchanger 1, as already in Fig. 1 was shown.
  • the with the Fig. 1 identical features of the heat exchanger 1 are denoted by identical reference numerals.
  • an accumulator 13 is shown.
  • This accumulator 13 serves to store the low-pressure refrigerant 4, which flows into the accumulator 13 via a fluid inlet 14 and flows out of the accumulator 13 via a fluid outlet 15.
  • the accumulator 13 may include means for filtering, cleaning and drying the low-pressure refrigerant 4. Via a storage volume in the interior of the accumulator 13, a fluctuation of the refrigerant volume within the refrigerant circuit can be compensated. This ensures a stable cooling of the refrigerant 2, 4 within the refrigerant circuit. Likewise, leaks within the refrigerant circuit can be at least partially compensated.
  • the accumulator 13 is arranged immediately in front of the fluid inlet 11 of the heat exchanger 1.
  • the low-pressure refrigerant 4 thus flows directly from the accumulator 13 into the internal heat exchanger 5 of the heat exchanger 1.
  • the accumulator 13 can as in Fig. 2 be shown as a separate component, which is arranged in the vicinity of the heat exchanger 1.
  • an integration of the accumulator in the heat exchanger is providable.
  • the design of the heat exchanger and the accumulator in a unit is particularly advantageous in terms of the required installation space of the unit.
  • the Fig. 3 shows a sectional view through a heat exchanger.
  • the arrangement of the various flow channels 23, 24, 25 is shown.
  • the high-pressure refrigerant 20 is assigned the first flow channel 23, which divides into a first region 23a and a second region 23b.
  • the high-pressure refrigerant 20 comes into thermal contact with a coolant 21, whereby a heat transfer between the high-pressure refrigerant 20 and the coolant 21 is formed.
  • the second region 23b of the first flow channel 23 the heat transfer between the high-pressure refrigerant 20 and the low-pressure refrigerant 22 takes place.
  • the flow channel 23 is in thermal contact with another flow channel 24.
  • the flow channel 24 in this case has a plurality of rib elements 26, which serve to increase the heat transfer surface.
  • FIG. 3 shown example of the arrangement of the flow channels within a heat exchanger provides that the heat transfer between the high-pressure refrigerant 20 and the coolant 21 via flow channels in pipe rib design.
  • the first region 23a of the flow channels 23 flows through the refrigerant, wherein the flow channels 24 are arranged between the flow channels 23 and by a coolant, such as the ambient air or cooling water, flows through.
  • a coolant such as the ambient air or cooling water
  • the first regions 23a of the flow channels 23 are substantially bypassed by the coolant 21 while flowing through the high-pressure refrigerant 20.
  • the operation of the cooling section 27 corresponds to the ordinary pipe-fin type heat exchanger in which a fluid flows through a first number of pipes while a second fluid flows around this number of pipes.
  • Fig. 3 shown arrangement can be covered by a housing.
  • the housing can be flowed through by the coolant whereby the tubes through which the refrigerant flows, are flowed around.
  • the heat transfer between the high-pressure refrigerant 20 and the low-pressure refrigerant 22 takes place between the second region 23b of the flow channels 23 of the high-pressure refrigerant 20 and the flow channels 25 of the low-pressure refrigerant 22.
  • the area of Fig. 3 which is formed by the flow channels 24 and the first region 23 of the first flow channels 23, corresponds to the Abkühlumble 27.
  • the range of Fig. 3 which is formed by the second region 23b of the first flow channels 23 and the flow channels 25, corresponds to the internal heat exchanger 28.
  • the cooling section 27 can be represented by flow channels brought together in thermally conductive contact. It is also conceivable to use a liquid coolant.
  • the first unit of the heat exchanger which is formed by the second region 23b of the first flow channel 23 and the second flow channel 25 and the second unit of the heat exchanger, which is formed from the first region 23a of the first flow channel 23 and the third flow channel 24 can optionally by a construction in stacking disk construction, in pipe-fin construction or by a juxtaposition of pipes, which are flowed through by the refrigerant or the coolant to be formed.
  • a housing is advantageously provided, which surrounds the arrangement of tubes and turbulence inserts.
  • the Fig. 4 shows an alternative embodiment of the heat exchanger 30.
  • the heat exchanger 30 now consists only of a cooling section, in which the high-pressure refrigerant 39 is brought into thermal contact with the coolant 40.
  • the structure of the heat exchanger 30 corresponds essentially to the cooling section 6 of the heat exchanger 1 of Fig. 1 ,
  • a low-pressure refrigerant 41 flows in via the fluid inlet 32 and out of the accumulator 31 out of the fluid outlet 33.
  • the high-pressure refrigerant 39 which has flowed out of the fluid outlet 36 of the heat exchanger 30, flows into the accumulator 31.
  • the accumulator 31 has in particular the second region 34 of the first flow channel, which is brought into thermally conductive contact with the low-pressure refrigerant 41.
  • the accumulator 31 may have in its interior a plurality of flow channels.
  • the accumulator 31 of the Fig. 4 be designed as a separate component as shown. In alternative embodiments, it may also be integrated directly into the heat exchanger 30.
  • the positioning of the fluid inlets and the fluid outlets represents only one possibility of the arrangement.
  • the fluid inlets and fluid outlets can be arbitrarily arranged on the heat exchanger and the accumulator.
  • Advantageous solutions result in particular by the choice of the internal structure of the Heat exchanger.
  • the fluid inlets and the fluid outlets are advantageously arranged on the two outer disc elements closing off the stack.
  • Fig. 1 to 4 the refrigerant circuit surrounding each heat exchanger is not shown.
  • the embodiments of the Fig. 1 to 4 are merely exemplary in nature and are not an exhaustive list and representation of the embodiments. They are not of a restrictive nature.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

Technisches GebietTechnical area

Die Erfindung betrifft einen Wärmeübertrager mit einem ersten Strömungskanal für ein Kältemittel, mit einem zweiten Strömungskanal für ein Kältemittel und mit einem dritten Strömungskanal für ein Kühlmittel, wobei der erste Strömungskanal einen ersten Bereich zur ersten Abkühlung des Kältemittels und einen zweiten Bereich zur weiteren Abkühlung des Kältemittels aufweist, wobei im ersten Strömungskanal das Kältemittel in einer Hochdruckphase strömbar ist und im zweiten Strömungskanal das Kältemittel in einer Niederdruckphase strömbar ist. Ein Wärmeübertrager mit den Merkmalen des Oberbegriff von Anspruch 1 ist aus FR 2 924 490 bekannt.The invention relates to a heat exchanger with a first flow channel for a refrigerant, with a second flow channel for a refrigerant and with a third flow channel for a coolant, wherein the first flow channel a first region for first cooling of the refrigerant and a second region for further cooling of the refrigerant wherein, in the first flow channel, the refrigerant can be flowed in a high-pressure phase and in the second flow channel, the refrigerant can be flowed in a low-pressure phase. A heat exchanger with the features of the preamble of claim 1 is made FR 2 924 490 known.

Stand der TechnikState of the art

In Kältemittelkreisläufen von Klimaanlagen für Kraftfahrzeuge werden Kondensatoren eingesetzt, um ein Kältemittel auf die Kondensationstemperatur abzukühlen und anschließend das Kältemittel zu kondensieren. Dies geschieht insbesondere bei Kältemitteln, die innerhalb des Kältemittelkreislaufes zumindest einen Phasenübergang von gasförmig zu flüssig erfahren. Regelmäßig weisen Kondensatoren einen Sammler auf, in welchem ein Kältemittelvolumen vorgehalten werden kann, um Volumenschwankungen im Kältemittelkreislauf auszugleichen. Dadurch kann eine stabile Unterkühlung des Kältemittels erreicht werden.In automotive vehicle air conditioning refrigerant circuits, condensers are used to cool a refrigerant to the condensation temperature and then condense the refrigerant. This occurs in particular with refrigerants which experience at least one phase transition from gaseous to liquid within the refrigerant circuit. Regularly, capacitors have a collector, in which a volume of refrigerant can be kept in order to compensate for volume fluctuations in the refrigerant circuit. As a result, a stable supercooling of the refrigerant can be achieved.

Oftmals sind in dem Sammler zusätzliche Mittel zur Trocknung und/oder Filterung des Kältemittels vorgesehen. Der Sammler ist im Regelfall am Kondensator angeordnet. Er wird von dem Kältemittel durchströmt, welches bereits einen Teil des Kondensators durchströmt hat. Nach dem Durchströmen des Sammlers wird das Kältemittel in den Kondensator zurückgeleitet und in einer Unterkühlungsstrecke unter die Kondensationstemperatur unterkühlt.Often, additional means for drying and / or filtering the refrigerant are provided in the collector. The collector is usually arranged on the capacitor. It is flowed through by the refrigerant, which has already flowed through part of the condenser. After flowing through the collector, the refrigerant is returned to the condenser and subcooled in a subcooling below the condensation temperature.

Auch sind Kondensatoren bekannt, bei denen das Kältemittel keinen Phasenübergang erfährt. Diese Kondensatoren weisen regelmäßig nur eine Abkühlstrecke auf, in welcher das Kältemittel mit einem Kühlmittel in thermischen Kontakt gebracht wird.Also, capacitors are known in which the refrigerant undergoes no phase transition. These capacitors regularly have only one cooling section, in which the refrigerant is brought into thermal contact with a coolant.

Weiterhin sind Wärmeübertrager bekannt, denen nach der Kondensationsstrecke und der Unterkühlstrecke ein innerer Wärmeübertrager nachgeschaltet ist. Ein Sammler ist dabei vorzugsweise zwischen der Kondensationsstrecke und der Unterkühlstrecke angeordnet. Während innerhalb der Kondensationsstrecke und der Unterkühlstrecke ein Wärmeübertrag zwischen einem Kältemittel und einem Kühlmittel stattfindet, findet im inneren Wärmeübertrager ein Wärmeübertrag zwischen dem Kältemittel in zwei verschiedenen Zuständen, nämlich in einer Hochdruckphase und einer Niederdruckphase, statt.Furthermore, heat exchangers are known, which after the condensation section and the subcooling an internal heat exchanger is connected downstream. A collector is preferably arranged between the condensation section and the subcooling section. While heat transfer takes place between a refrigerant and a coolant within the condensation section and the subcooling section, a heat transfer takes place in the internal heat exchanger between the refrigerant in two different states, namely in a high pressure phase and a low pressure phase.

Nachteilig an den aus dem Stand der Technik bekannten Vorrichtungen ist insbesondere, dass bei der Verwendung von CO2 (R744) als Kältemittel hohe Drücke innerhalb des Kältemittelkreislaufes auftreten, die die bisher bekannten Wärmeübertrager über ihre Belastungsgrenzen hinaus belasten.A disadvantage of the devices known from the prior art is in particular that when using CO 2 (R744) as refrigerant high pressures within the refrigerant circuit occur, which burden the previously known heat exchanger beyond their load limits.

Darstellung der Erfindung, Aufgabe, Lösung, VorteilePresentation of the invention, object, solution, advantages

Daher ist es die Aufgabe der vorliegenden Erfindung einen Wärmeübertrager bereitzustellen, der mit hohen Drücken, wie sie beispielsweise beim Einsatz von CO2 (R744) auftreten, beaufschlagt werden kann. Darüber hinaus soll sich der Wärmeübertrager durch ein kompakte Bauform und eine kostengünstige Herstellung auszeichnen.It is therefore the object of the present invention to provide a heat exchanger which can be subjected to high pressures, as occur, for example, when CO 2 (R 744) is used. In addition, the heat exchanger should characterized by a compact design and cost-effective production.

Die Aufgabe der vorliegenden Erfindung wird durch einen Wärmeübertrager mit den Merkmalen gemäß Anspruch 1 gelöst.The object of the present invention is achieved by a heat exchanger with the features of claim 1.

Ein Ausführungsbeispiel der Erfindung betrifft einen Wärmeübertrager mit einem ersten Strömungskanal für ein Kältemittel, mit einem zweiten Strömungskanal für ein Kältemittel und mit einem dritten Strömungskanal für ein Kühlmittel, wobei der erste Strömungskanal einen ersten Bereich zur ersten Abkühlung des Kältemittels und einen zweiten Bereich zur weiteren Abkühlung des Kältemittels aufweist, wobei im ersten Strömungskanal das Kältemittel in einer Hochdruckphase strömbar ist und im zweiten Strömungskanal das Kältemittel in einer Niederdruckphase strömbar ist, wobei ein erster Wärmeübertrag zwischen dem Kältemittel im ersten Bereich des ersten Strömungskanals und dem Kühlmittel im dritten Strömungskanal stattfindet und ein zweiter Wärmeübertrag zwischen dem Kältemittel im zweiten Bereich des ersten Strömungskanals und dem Kältemittel im zweiten Strömungskanal stattfindet.An embodiment of the invention relates to a heat exchanger with a first flow channel for a refrigerant, with a second flow channel for a refrigerant and with a third flow channel for a coolant, wherein the first flow channel has a first region for first cooling of the refrigerant and a second region for further cooling of the refrigerant, wherein in the first flow channel, the refrigerant is flowable in a high pressure phase and in the second flow channel, the refrigerant is flowable in a low pressure phase, wherein a first heat transfer between the refrigerant in the first region of the first flow channel and the coolant takes place in the third flow channel and a second Heat transfer between the refrigerant takes place in the second region of the first flow channel and the refrigerant in the second flow channel.

Durch einen zusätzlichen Wärmeübertrag zwischen dem Kältemittel in seiner Hochdruckphase und dem Kältemittel in seiner Niederdruckphase kann die Temperatur des Kältemittels in der Hochdruckphase noch weiter abgesenkt werden. Dadurch kann die Kühlleistung im Kältemittelkreislauf insgesamt erhöht werden.By an additional heat transfer between the refrigerant in its high pressure phase and the refrigerant in its low pressure phase, the temperature of the refrigerant can be further lowered in the high pressure phase. As a result, the cooling capacity in the refrigerant circuit can be increased overall.

In einer weiteren Ausgestaltung der Erfindung kann es vorgesehen sein, dass der zweite Bereich des ersten Strömungskanals und der zweite Strömungskanal eine erste Einheit bilden und der erste Bereich des ersten Strömungskanals und der dritte Strömungskanal eine zweite Einheit bilden, wobei die erste Einheit und die zweite Einheit als Baueinheit verbindbar sind.In a further embodiment of the invention, it may be provided that the second region of the first flow channel and the second flow channel form a first unit and the first region of the first flow channel and the third flow channel form a second unit, wherein the first unit and the second unit can be connected as a unit.

Erfindungsgemäß weist der Wärmeübertrager einen Akkumulator auf, der ein Speichervolumen zur Bevorratung des Kältemittels aufweist und/oder Mittel zur Filterung und/oder Mittel zur Trocknung des Kältemittels.According to the invention, the heat exchanger has an accumulator which stores a storage volume of the refrigerant and / or means for filtering and / or means for drying the refrigerant.

Der Akkumulator dient als Speichermedium für das Kältemittel. Vorteilhafterweise speichert er das Kältemittel in der Niederdruckphase zwischen. Dies dient zum Ausgleich von Volumenschwankungen des Kältemittels oder zur Kompensation von Kältemittelverlusten, die beispielsweise durch Leckagen entstehen können. Zusätzlich kann der Akkumulator vorteilhafterweise Mittel zur Trocknung und/oder Filterung des Kältemittels aufweisen. Dies wirkt sich vorteilhaft auf die Qualität des Kältemittels und damit auch auf die Effizienz des Kältemittelkreislaufes aus.The accumulator serves as a storage medium for the refrigerant. Advantageously, it stores the refrigerant in the low pressure phase between. This is used to compensate for volume fluctuations of the refrigerant or to compensate for refrigerant losses, which may arise for example due to leaks. In addition, the accumulator may advantageously comprise means for drying and / or filtering the refrigerant. This has an advantageous effect on the quality of the refrigerant and thus also on the efficiency of the refrigerant circuit.

Auch kann es vorteilhaft sein, wenn der Akkumulator dem Wärmeübertrager zugeordnet ist.It may also be advantageous if the accumulator is assigned to the heat exchanger.

Durch eine Zuordnung des zusätzlichen Akkumulators zum Wärmeübertrager kann besonders vorteilhaft sein, wenn der Wärmeübertrager selbst möglichst kompakt ausgeführt sein muss. Der Akkumulator kann dabei unabhängig vom Wärmeübertrager im Fahrzeug verbaut werden.By assigning the additional accumulator to the heat exchanger may be particularly advantageous if the heat exchanger itself must be made as compact as possible. The accumulator can be installed independently of the heat exchanger in the vehicle.

Erfindungsgemäß führt der Kältemittelübertritt aus dem zweiten Bereich des ersten Strömungskanals in den zweiten Strömungskanal über den Akkumulator.According to the invention, the passage of refrigerant out of the second region of the first flow channel leads into the second flow channel via the accumulator.

Durch den Kältemittelübertritt durch den Akkumulator kann sichergestellt werden, dass Volumenschwankungen des Kältemittels zu jeder Zeit vollständig ausgeglichen werden können. Insgesamt verbessert sie die Effizienz des Kältemittelkreislaufes.By the refrigerant passing through the accumulator can be ensured that volume fluctuations of the refrigerant can be fully compensated at any time. Overall, it improves the efficiency of the refrigerant circuit.

Weiterhin kann es zweckmäßig sein, wenn dem ersten Bereich des ersten Strömungskanals der dritte Strömungskanal benachbart ist und dem zweiten Bereich des ersten Strömungskanals der zweite Strömungskanal benachbart ist.Furthermore, it may be expedient if the third flow channel is adjacent to the first region of the first flow channel and the second flow channel is adjacent to the second region of the first flow channel.

Durch die Anordnung der Strömungskanäle in dieser Weise wird der Wärmeübertrag zwischen dem Kältemittel im ersten Bereich des ersten Strömungskanals und dem Kühlmittel im dritten Strömungskanal und außerdem der Wärmeübertrag zwischen dem Kältemittel im zweiten Bereich des ersten Strömungskanals und dem Kältemittel im zweiten Strömungskanal begünstigt.By arranging the flow channels in this way, the heat transfer between the refrigerant in the first region of the first flow channel and the coolant in the third flow channel and also the heat transfer between the refrigerant in the second region of the first flow channel and the refrigerant in the second flow channel is favored.

Außerdem kann es vorteilhaft sein, wenn die erste Einheit und/oder die zweite Einheit in Stapelscheibenbauweise gebildet ist.In addition, it may be advantageous if the first unit and / or the second unit is formed in stacked disc design.

Ein Aufbau in Stapelscheibenbauweise ist besonders einfach und aufgrund der geringen Anzahl an unterschiedlichen Elementen besonders kostengünstig.A construction in stacking disk design is particularly simple and particularly cost-effective due to the small number of different elements.

Auch ist es zu bevorzugen, wenn die erste Einheit und/oder die zweite Einheit in Rohr-Rippe-Bauweise gebildet ist.It is also preferable if the first unit and / or the second unit is formed in tube-rib construction.

In einer weiteren Ausführungsform der Erfindung kann es vorgesehen sein, dass die erste Einheit und/oder die zweite Einheit durch eine Mehrzahl von Rohren gebildet ist, wobei die Rohre benachbart zueinander angeordnet sind und zumindest teilweise in thermischen Kontakt miteinander stehen, wobei die Rohre jeweils von dem Kältemittel und/oder dem Kühlmittel durchströmbar sind.In a further embodiment of the invention, it may be provided that the first unit and / or the second unit is formed by a plurality of tubes, wherein the tubes are adjacent to each other and at least partially in thermal contact with each other, wherein the tubes of each the refrigerant and / or the coolant can flow through.

Das Strömen des Kältemittels und des Kühlmittels in Rohren ist insbesondere hinsichtlich der Druckfestigkeit des Wärmeübertragers besonders vorteilhaft. Durch die Verwendung von Rohren lässt sich eine besonders hohe Druckfestigkeit erreichen.The flow of the refrigerant and the coolant in pipes is particularly advantageous, in particular with regard to the pressure resistance of the heat exchanger. By using pipes, a particularly high compressive strength can be achieved.

Weiterhin kann es vorteilhaft sein, wenn die erste Einheit und/oder die zweite Einheit von einer Mehrzahl von Rohren gebildet ist, wobei zwischen den Rohren Turbulenzeinlagen angeordnet sind, wobei die Anordnung von Rohren und Turbulenzeinlagen von einem Gehäuse ummantelt ist, wobei die Rohre von einem Kühlmittel und/oder einem Kältemittel durchströmbar sind und von einem Kühlmittel und/oder einem Kältemittel umströmbar sind.Furthermore, it may be advantageous if the first unit and / or the second unit is formed by a plurality of tubes, wherein between the tubes turbulence inserts are arranged, wherein the arrangement of tubes and turbulence inserts is encased by a housing, wherein the tubes of a Coolant and / or a refrigerant can flow through and can be flowed around by a coolant and / or a refrigerant.

Ein Aufbau, bei der ein Teil der Rohre von einem ersten Fluid durchströmt wird und gleichzeitig von einem zweiten Fluid umströmt wird ist besonders vorteilhaft, da auf diese Weise ein besonders hoher Wärmeübertrag realisiert werden kann.A structure in which a part of the tubes is flowed through by a first fluid and at the same time flows around a second fluid is particularly advantageous, since in this way a particularly high heat transfer can be realized.

Insbesondere durch eine Mischbauweise aus einer Einheit, die in Stapelscheibenbauweise gebildet ist und einer Einheit, die in Rohr-Rippe-Bauweise gebildet ist, lassen sich die Vorteile beider Bauweisen kombinieren.In particular, by a mixed construction of a unit which is formed in stacked disk construction and a unit which is formed in tube-rib construction, the advantages of both designs can be combined.

Ein bevorzugtes Ausführungsbeispiel der Erfindung ist dadurch gekennzeichnet, dass der Wärmeübertrager in Stapelscheibenbauweise gebildet ist, wobei durch das Aufeinanderstapeln von einzelnen Scheibenelementen ein Wärmeübertragerblock entsteht und zwischen den Scheibenelementen Kanäle ausgebildet sind, wobei eine erste Anzahl der Kanäle dem ersten Strömungskanal zugeordnet ist, eine zweite Anzahl der Kanäle dem zweiten Strömungskanal zugeordnet ist und eine dritte Anzahl der Kanäle dem dritten Strömungskanal zugeordnet ist.A preferred embodiment of the invention is characterized in that the heat exchanger is formed in a stacked disk construction, wherein the stacking of individual disc elements, a heat exchanger block is formed and formed between the disc elements channels, wherein a first number of channels is associated with the first flow channel, a second number the channels is associated with the second flow channel and a third number of the channels is associated with the third flow channel.

Der Aufbau in einer Stapelscheibenbauwese ist besonders vorteilhaft, da eine große Anzahl von Gleichteilen verwendet werden kann. Je nach Ausführung des Wärmeübertragers müssen nur die beiden jeweils äußeren Scheibenelemente von den übrigen abweichen. Dadurch können die Kosten und der Herstellungsaufwand deutlich reduziert werden.The construction in a Stapelscheibenbauwese is particularly advantageous because a large number of identical parts can be used. Depending on the design of the heat exchanger, only the two respective outer disk elements must deviate from the others. As a result, the costs and the production costs can be significantly reduced.

Außerdem kann es vorteilhaft sein, wenn einer oder mehrere der Strömungskanäle eine oder mehrerer Umlenkungen ihrer Strömungsrichtung erfahren, wodurch die Fluidströmungen in den Strömungskanälen zueinander im Gleichstrom und/oder im Gegenstrom und/oder im Kreuzstrom verlaufen können.In addition, it may be advantageous if one or more of the flow channels experience one or more deflections of their flow direction, as a result of which the fluid flows in the flow channels can run in cocurrent and / or countercurrent and / or crosstalk.

Durch Umlenkungen im Inneren des Wärmeübertragers können die Fluidströme vorteilhaft gelenkt werden. Dadurch kann der Wärmeübertrag deutlich erhöht werden und die Effizienz des Kältemittelkreislaufes verbessert werden.By deflections in the interior of the heat exchanger, the fluid flows can be advantageously controlled. As a result, the heat transfer can be significantly increased and the efficiency of the refrigerant circuit can be improved.

Erfindungs gemäß weist der Akkumulator den zweiten Bereich des ersten Strömungskanals und den zweiten Strömungskanal auf, wobei innerhalb des Akkumulators ein Wärmeübertrag zwischen dem zweiten Bereich des ersten Strömungskanals und dem zweiten Strömungskanal stattfindet.According to the Invention, the accumulator has the second region of the first flow channel and the second flow channel, wherein heat transfer takes place within the accumulator between the second region of the first flow channel and the second flow channel.

Eine solche Gestaltung ist vorteilhaft, da der Wärmeübertrager dadurch noch kompakter gebaut werden kann, was insbesondere hinsichtlich des zur Verfügung stehenden Bauraumes vorteilhaft ist.Such a design is advantageous because the heat exchanger can be made even more compact, which is particularly advantageous in terms of the available space.

Ein weiteres bevorzugtes Ausführungsbeispiel ist dadurch gekennzeichnet, dass der Akkumulator und der Wärmeübertrager als Baueinheit ausgeführt sind.A further preferred embodiment is characterized in that the accumulator and the heat exchanger are designed as a structural unit.

Eine Baueinheit des Akkumulators und des Wärmeübertragers ist vorteilhaft, da der benötigte Bauraum insgesamt verringert werden kann. Außerdem ist eine einfachere Montage im Fahrzeug möglich, da keine zusätzlichen Verrohrungen zwischen dem Wärmeübertrager und dem Akkumulator vorgesehen werden müssen.An assembly of the accumulator and the heat exchanger is advantageous because the required space can be reduced overall. In addition, a simpler installation in the vehicle is possible because no additional piping between the heat exchanger and the accumulator must be provided.

Weiterhin ist es vorteilhaft, wenn das Kältemittel CO2 (R744) ist.Furthermore, it is advantageous if the refrigerant is CO 2 (R744).

Auch kann es zweckmäßig sein, wenn der Wärmeübertrager eine Druckfestigkeit aufweist, die Innendrücke größer 100 bar erlaubt.It may also be expedient if the heat exchanger has a compressive strength that allows internal pressures greater than 100 bar.

Insbesondere bei der Verwendung von CO2 (R744) als Kältemittel ist es vorteilhaft, wenn der Wärmeübertrager hohen Innendrücken standhalten kann. Im Betrieb mit CO2 (R744) als Kältemittel können Drücke von 100 bar und mehr auftreten.In particular, when using CO 2 (R744) as a refrigerant, it is advantageous if the heat exchanger can withstand high internal pressures. When operating with CO 2 (R744) as a refrigerant, pressures of 100 bar and more can occur.

Die Druckfestigkeit von 100 bar und mehr ist insbesondere für die Bereiche vorteilhaft, die von dem Hochdruckkältemittel durchströmt sind. Auch für die Bereiche, die von dem Niederdruckkältemittel und dem Kühlmittel durchströmt sind, kann diese Druckfestigkeit vorteilhaft sein.The compressive strength of 100 bar and more is particularly advantageous for the areas through which the high-pressure refrigerant flows. Also for the areas through which the low-pressure refrigerant and the coolant flow, this pressure resistance may be advantageous.

Vorteilhafte Weiterbildungen der vorliegenden Erfindung sind in den Unteransprüchen und der nachfolgenden Figurenbeschreibung beschrieben.Advantageous developments of the present invention are described in the subclaims and the following description of the figures.

Kurze Beschreibung der ZeichnungenBrief description of the drawings

Im Folgenden wird die Erfindung anhand von Ausführungsbeispielen unter Bezugnahme auf die Zeichnungen detailliert erläutert. In den Zeichnungen zeigen:

Fig.1
eine perspektivische Ansicht eines Wärmeübertragers mit einer inneren Abkühlstrecke und einem inneren Wärmeübertrager,
Fig. 2
eine perspektivische Ansicht eines Wärmeübertragers gemäß Figur 1 und einen zusätzlichen Akkumulator,
Fig. 3
eine Schnittansicht durch einen Wärmeübertrager mit einer Mehrzahl von Strömungskanälen für ein Niederdruckkältemittel, ein Hochdruckkältemittel und ein Kühlmittel, und
Fig. 4
eine perspektivische Ansicht eines Wärmeübertragers mit einer Abkühlstrecke und einen Akkumulator, in den ein innerer Wärmeübertrager integriert ist.
In the following the invention will be explained in detail by means of embodiments with reference to the drawings. In the drawings show:
Fig.1
a perspective view of a heat exchanger with an inner cooling path and an internal heat exchanger,
Fig. 2
a perspective view of a heat exchanger according to FIG. 1 and an additional accumulator,
Fig. 3
a sectional view through a heat exchanger having a plurality of flow channels for a low-pressure refrigerant, a high-pressure refrigerant and a coolant, and
Fig. 4
a perspective view of a heat exchanger with a cooling line and an accumulator, in which an internal heat exchanger is integrated.

Bevorzugte Ausführung der ErfindungPreferred embodiment of the invention

Die Fig. 1 zeigt eine schematische Ansicht eines Wärmeübertragers 1. Der Wärmeübertrager 1 ist in eine Abkühlstrecke 6 und in einen inneren Wärmeübertrager 5 unterteilt. Innerhalb der Abkühlstrecke 6 wird ein Kältemittel in einer Hochdruckphase (Hochdruckkältemittel) 2 mit einem Kühlmittel 3 in thermischen Kontakt gebracht, so dass ein Wärmeübertrag vom Hochdruckkältemittel 2 auf das Kühlmittel 3 entsteht. Im inneren Wärmeübertrager 5 wird das Hochdruckkältemittel 2 mit dem gleichen Kältemittel, jedoch in einer Niederdruckphase (Niederdruckkältemittel) 4 in thermischen Kontakt gebracht. Im inneren Wärmeübertrager 5 wird somit das Hochdrucckältemittel 2 weiter abgekühlt.The Fig. 1 shows a schematic view of a heat exchanger 1. The heat exchanger 1 is divided into a cooling section 6 and in an inner heat exchanger 5. Within the cooling section 6, a refrigerant in a high-pressure phase (high-pressure refrigerant) 2 is brought into thermal contact with a coolant 3, so that a heat transfer from the high-pressure refrigerant 2 to the coolant 3 is formed. In the internal heat exchanger 5, the high-pressure refrigerant 2 with the same refrigerant, but in a low-pressure phase (low-pressure refrigerant) 4 in thermal Brought in contact. In the inner heat exchanger 5, the Hochdrucckältemittel 2 is thus further cooled.

Das Hochdruckkältemittel 2 strömt über einen Fluideinlass 7 in die Abkühlstrecke 6. Im Inneren der Abkühlstrecke 6 ist eine Mehrzahl von Strömungskanälen angeordnet, welche teilweise vom Hochdruckkältemittel 2 durchströmt werden und teilweise von dem Kühlmittel 3 durchströmt werden. Innerhalb des inneren Wärmeübertragers 5 sind ebenfalls mehrere Strömungskanäle angeordnet, wobei eine Anzahl dieser Strömungskanäle dem Niederdruckkältemittel 4 zugeordnet ist und eine weitere Anzahl der Kanäle dem Hochdruckkältemittel 2 zugeordnet ist. Sowohl die Strömungskanäle im inneren Wärmeübertrager 5 als auch in der Abkühlstrecke 6 sind aus Gründen der Übersichtlichkeit nicht dargestellt.The high-pressure refrigerant 2 flows via a fluid inlet 7 into the cooling section 6. Inside the cooling section 6, a plurality of flow channels are arranged, which are partially flowed through by the high-pressure refrigerant 2 and through which the coolant 3 flows. Within the internal heat exchanger 5 also a plurality of flow channels are arranged, wherein a number of these flow channels is associated with the low-pressure refrigerant 4 and a further number of channels is associated with the high-pressure refrigerant 2. Both the flow channels in the internal heat exchanger 5 and in the cooling section 6 are not shown for reasons of clarity.

Die Strömungskanäle für das Hochdruckkältemittel 2, das Kühlmittel 3 und das Niederdruckkältemittel 4 können innerhalb des Wärmeübertragers in beliebiger Reihenfolge angeordnet sein. Hierbei können die Strömungskanäle der unterschiedlichen Fluide beispielsweise abwechselnd angeordnet sein. Alternativ kann auch eine Anordnung vorgesehen sein, bei der mehrere Strömungskanäle für das gleiche Fluid aneinander angrenzend angeordnet sind.The flow channels for the high-pressure refrigerant 2, the coolant 3 and the low-pressure refrigerant 4 may be arranged within the heat exchanger in any order. In this case, the flow channels of the different fluids can be arranged, for example, alternately. Alternatively, an arrangement may be provided in which a plurality of flow channels for the same fluid are arranged adjacent to each other.

Die Strömung des Hochdruckkältemittels 2 durch den Wärmeübertrager 1 verläuft entlang des Fluideinlasses 7 durch die Strömungskanäle im Inneren der Abkühlstrecke 6 entlang der Strömungskanäle im inneren Wärmeübertrager 5 und schließlich aus dem Fluidauslass 8 aus dem Wärmeübertrager 1 hinaus. Das Kühlmittel 3 strömt über den Fluideinlass 9 in die Abkühlstrecke 6 des Wärmeübertragers 1 ein und dort entlang der Strömungskanäle innerhalb der Abkühlstrecke 6 zum Fluidauslass 10. Dort strömt es aus dem Wärmeübertrager 1 aus.The flow of the high-pressure refrigerant 2 through the heat exchanger 1 runs along the fluid inlet 7 through the flow channels in the interior of the cooling section 6 along the flow channels in the inner heat exchanger 5 and finally out of the heat exchanger 1 from the fluid outlet 8. The coolant 3 flows via the fluid inlet 9 into the cooling section 6 of the heat exchanger 1 and there along the flow channels within the cooling section 6 to the fluid outlet 10. There, it flows out of the heat exchanger 1 from.

Das Niederdruckkältemittel 4 strömt über einen Fluideinlass 11 in den inneren Wärmeübertrager 5 ein und dort entlang der ihm zugeordneten Strömungskanäle durch den inneren Wärmeübertrager 5. Es strömt schließlich über den Fluidauslass 12 aus dem inneren Wärmeübertrager 5 aus.The low-pressure refrigerant 4 flows via a fluid inlet 11 into the inner heat exchanger 5 and there along the flow channels associated therewith through the inner heat exchanger 5. It finally flows out of the inner heat exchanger 5 via the fluid outlet 12.

Im Inneren des Wärmeübertragers 1 können Umlenkungen vorgesehen sein, wodurch die Strömungsrichtung der einzelnen Fluide umgelenkt wird. Dabei können Bereiche erzeugt werden, in denen zwei Fluide im Gleichstrom oder im Gegenstrom zueinander strömen. Durch eine geschickte Anordnung der Strömungskanäle und Umlenkungen im Inneren des Wärmeübertragers 1 ist auch erreichbar, dass zwei Fluide im Kreuzstrom zueinander fließen.In the interior of the heat exchanger 1 deflections may be provided, whereby the flow direction of the individual fluids is deflected. In this case, areas can be generated in which two fluids flow in cocurrent or in countercurrent to each other. By a clever arrangement of the flow channels and deflections in the interior of the heat exchanger 1 is also achievable that two fluids flow in a cross flow to each other.

Das Hochdruckkältemittel 2 wird innerhalb des Kältemittelkreislaufes, weicher in der Fig. 1 nicht dargestellt ist, über ein ebenfalls nicht dargestelltes Expansionsventil in eine Niederdruckphase und somit zum Niederdruckkältemittel 4 überführt.The high-pressure refrigerant 2 is within the refrigerant circuit, softer in the Fig. 1 is not shown, transferred via a likewise not shown expansion valve in a low pressure phase and thus to the low pressure refrigerant 4.

Die Fig. 2 zeigt eine weitere schematische Ansicht des Wärmeübertragers 1, wie er bereits in Fig. 1 gezeigt wurde. Die mit der Fig. 1 identischen Merkmale des Wärmeübertragers 1 sind mit identischen Bezugszeichen bezeichnet.The Fig. 2 shows a further schematic view of the heat exchanger 1, as already in Fig. 1 was shown. The with the Fig. 1 identical features of the heat exchanger 1 are denoted by identical reference numerals.

Zusätzlich ist in Fig. 2 ein Akkumulator 13 gezeigt. Dieser Akkumulator 13 dient zur Bevorratung des Niederruckkältemittels 4, welches über einen Fluideinlass 14 in den Akkumulator 13 einströmt und über einen Fluidauslass 15 aus dem Akkumulator 13 ausströmt. Zusätzlich kann der Akkumulator 13 Mittel zur Filterung, Reinigung und Trocknung des Niederruckkältemittels 4 enthalten. Über ein Speichervolumen im Inneren des Akkumulators 13 kann eine Schwankung des Kältemittelvolumens innerhalb des Kältemittelkreislaufs ausgeglichen werden. Dies sorgt für eine stabile Abkühlung des Kältemittels 2, 4 innerhalb des Kältemittelkreislaufs. Ebenso können Leckagen innerhalb des Kältemittelkreislaufs zumindest teilweise ausgeglichen werden.Additionally is in Fig. 2 an accumulator 13 is shown. This accumulator 13 serves to store the low-pressure refrigerant 4, which flows into the accumulator 13 via a fluid inlet 14 and flows out of the accumulator 13 via a fluid outlet 15. In addition, the accumulator 13 may include means for filtering, cleaning and drying the low-pressure refrigerant 4. Via a storage volume in the interior of the accumulator 13, a fluctuation of the refrigerant volume within the refrigerant circuit can be compensated. This ensures a stable cooling of the refrigerant 2, 4 within the refrigerant circuit. Likewise, leaks within the refrigerant circuit can be at least partially compensated.

Der Akkumulator 13 ist unmittelbar vor dem Fluideinlass 11 des Wärmeübertragers 1 angeordnet. Das Niederruckkältemittel 4 strömt somit aus dem Akkumulator 13 direkt in den inneren Wärmeübertrager 5 des Wärmeübertragers 1.The accumulator 13 is arranged immediately in front of the fluid inlet 11 of the heat exchanger 1. The low-pressure refrigerant 4 thus flows directly from the accumulator 13 into the internal heat exchanger 5 of the heat exchanger 1.

Der Akkumulator 13 kann wie in Fig. 2 gezeigt als gesondertes Bauteil ausgeführt sein, weiches in der Nähe des Wärmeübertragers 1 angeordnet ist. In alternativen Ausführungsformen ist auch eine Integration des Akkumulators in den Wärmeübertrager vorsehbar. Die Ausführung des Wärmeübertragers und des Akkumulators in einer Baueinheit ist insbesondere hinsichtlich des benötigen Bauraumes der Baueinheit vorteilhaft.The accumulator 13 can as in Fig. 2 be shown as a separate component, which is arranged in the vicinity of the heat exchanger 1. In alternative embodiments, an integration of the accumulator in the heat exchanger is providable. The design of the heat exchanger and the accumulator in a unit is particularly advantageous in terms of the required installation space of the unit.

Die Fig. 3 zeigt eine Schnittansicht durch einen Wärmeübertrager. Gezeigt ist die Anordnung der verschiedenen Strömungskanäle 23, 24, 25. Dem Hochdruckkältemittel 20 ist der erste Strömungskanal 23, welcher sich in einen ersten Bereich 23a und einen zweiten Bereich 23b teilt, zugeordnet. Am ersten Bereich 23a des ersten Strömungskanals 23 tritt das Hochdruckkältemittel 20 mit einem Kühlmittel 21 in thermischen Kontakt, wodurch ein Wärmeübertrag zwischen dem Hochdruckkältemittel 20 und dem Kühlmittel 21 entsteht. Am zweiten Bereich 23b des ersten Strömungskanals 23 findet der Wärmeübertrag zwischen dem Hochdruckkältemittel 20 und dem Niederdruckkältemittel 22 statt.The Fig. 3 shows a sectional view through a heat exchanger. The arrangement of the various flow channels 23, 24, 25 is shown. The high-pressure refrigerant 20 is assigned the first flow channel 23, which divides into a first region 23a and a second region 23b. At the first region 23 a of the first flow channel 23, the high-pressure refrigerant 20 comes into thermal contact with a coolant 21, whereby a heat transfer between the high-pressure refrigerant 20 and the coolant 21 is formed. At the second region 23b of the first flow channel 23, the heat transfer between the high-pressure refrigerant 20 and the low-pressure refrigerant 22 takes place.

Um einen Wärmeübertrag zwischen dem ersten Bereich 23a des ersten Strömungskanals 23 und dem darin strömenden Hochdruckkältemittel 20 und dem Kühlmittel 21 darzustellen, ist der Strömungskanal 23 mit einem weiteren Strömungskanal 24 in thermischen Kontakt. Der Strömungskanal 24 weist hierbei eine Mehrzahl von Rippenelementen 26 auf, welche der Vergrößerung der Wärmeübertragungsfläche dienen.In order to represent a heat transfer between the first region 23a of the first flow channel 23 and the high-pressure refrigerant 20 and the coolant 21 flowing therein, the flow channel 23 is in thermal contact with another flow channel 24. The flow channel 24 in this case has a plurality of rib elements 26, which serve to increase the heat transfer surface.

Das in Fig. 3 gezeigte Beispiel für die Anordnung der Strömungskanäle innerhalb eines Wärmeübertragers sieht vor, dass der Wärmeübertrag zwischen dem Hochdruckkältemittel 20 und dem Kühlmittel 21 über Strömungskanäle in Rohrrippe-Bauweise erfolgt. Dabei ist der erste Bereich 23a der Strömungskanäle 23 von dem Kältemittel durchströmt, wobei die Strömungskanäle 24 zwischen den Strömungskanälen 23 angeordnet sind und von einem Kühlmittel, wie beispielsweise der Umgebungsluft oder Kühlwasser, durchströmt werden. Dadurch wird der erste Bereich 23a vom Kühlmittel 21 umströmt.This in Fig. 3 shown example of the arrangement of the flow channels within a heat exchanger provides that the heat transfer between the high-pressure refrigerant 20 and the coolant 21 via flow channels in pipe rib design. In this case, the first region 23a of the flow channels 23 flows through the refrigerant, wherein the flow channels 24 are arranged between the flow channels 23 and by a coolant, such as the ambient air or cooling water, flows through. As a result, the first region 23a flows around the coolant 21.

Die ersten Bereiche 23a der Strömungskanäle 23 werden im Wesentlichen von dem Kühlmittel 21 umströmt, während sie von dem Hochdruckkältemittel 20 durchströmt werden. Die Funktionsweise des Abkühlbereichs 27 entspricht der gewöhnlicher Wärmeübertrager in Rohr-Rippe-Bauweise, bei der ein Fluid durch eine erste Anzahl von Rohren strömt, während diese Anzahl von Rohren von einem zweiten Fluid umströmt wird.The first regions 23a of the flow channels 23 are substantially bypassed by the coolant 21 while flowing through the high-pressure refrigerant 20. The operation of the cooling section 27 corresponds to the ordinary pipe-fin type heat exchanger in which a fluid flows through a first number of pipes while a second fluid flows around this number of pipes.

Die in Fig. 3 gezeigte Anordnung kann von einem Gehäuse ummantelt sein. Das Gehäuse kann dabei von dem Kühlmittel durchströmt werden wodurch die Rohre, durch welche das Kältemittel strömt, umströmt werden.In the Fig. 3 shown arrangement can be covered by a housing. The housing can be flowed through by the coolant whereby the tubes through which the refrigerant flows, are flowed around.

Der Wärmeübertrag zwischen dem Hochdruckkältemittel 20 und dem Niederruckkältemittel 22 findet zwischen dem zweiten Bereich 23b der Strömungskanäle 23 des Hochdruckkältemittels 20 und den Strömungskanälen 25 des Niederruckkältemittels 22 statt. Der Bereich der Fig. 3, welcher durch die Strömungskanäle 24 und den ersten Bereich 23 der ersten Strömungskanäle 23 gebildet ist, entspricht dabei der Abkühlstrecke 27. Der Bereich der Fig. 3, welcher durch den zweiten Bereich 23b der ersten Strömungskanäle 23 und die Strömungskanäle 25 gebildet ist, entspricht dem inneren Wärmeübertrager 28.The heat transfer between the high-pressure refrigerant 20 and the low-pressure refrigerant 22 takes place between the second region 23b of the flow channels 23 of the high-pressure refrigerant 20 and the flow channels 25 of the low-pressure refrigerant 22. The area of Fig. 3 , which is formed by the flow channels 24 and the first region 23 of the first flow channels 23, corresponds to the Abkühlstrecke 27. The range of Fig. 3 , which is formed by the second region 23b of the first flow channels 23 and the flow channels 25, corresponds to the internal heat exchanger 28.

In abweichenden Ausführungen kann auch die Abkühlstrecke 27 durch miteinander in thermisch leitenden Kontakt gebrachte Strömungskanälen dargestellt werden. Dabei ist es auch vorsehbar, ein flüssiges Kühlmittel einzusetzen.In alternative embodiments, the cooling section 27 can be represented by flow channels brought together in thermally conductive contact. It is also conceivable to use a liquid coolant.

Die erste Einheit des Wärmeübertragers, welche durch den zweiten Bereich 23b des ersten Strömungskanals 23 und dem zweiten Strömungskanal 25 gebildet ist und die zweite Einheit des Wärmeübertragers, welche aus dem ersten Bereich 23a des ersten Strömungskanals 23 und dem dritten Strömungskanal 24 gebildet ist, können wahlweise durch einen Aufbau in Stapelscheibenbauweise, in Rohr-Rippe-Bauweise oder durch eine Aneinanderreihung von Rohren, welche von dem Kältemittel oder dem Kühlmittel durchströmt werden gebildet sein.The first unit of the heat exchanger, which is formed by the second region 23b of the first flow channel 23 and the second flow channel 25 and the second unit of the heat exchanger, which is formed from the first region 23a of the first flow channel 23 and the third flow channel 24 can optionally by a construction in stacking disk construction, in pipe-fin construction or by a juxtaposition of pipes, which are flowed through by the refrigerant or the coolant to be formed.

Alternativ ist auch eine Anordnung von Rohren, zwischen welchen Turbulenzeinlagen angeordnet sind, vorsehbar, wobei die Rohre und Turbulenzeinlagen dann von entweder dem Kältemittel oder dem Kühlmittel umströmt werden. Dabei ist vorteilhafterweise ein Gehäuse vorgesehen, welches die Anordnung von Rohren und Turbulenzeinlagen ummantelt.Alternatively, an arrangement of tubes, between which turbulence liners are arranged, providable, wherein the tubes and turbulence inserts are then flowed around by either the refrigerant or the coolant. In this case, a housing is advantageously provided, which surrounds the arrangement of tubes and turbulence inserts.

Die Fig. 4 zeigt eine alternative Ausführung des Wärmeübertragers 30. Der Wärmeübertrager 30 besteht nun nur noch aus einer Abkühlstrecke, in welcher das Hochdruckkältemittel 39 mit dem Kühlmittel 40 in thermischen Kontakt gebracht wird. Der Aufbau des Wärmeübertragers 30 entspricht im Wesentlichen der Abkühlstrecke 6 des Wärmeübertragers 1 der Fig. 1.The Fig. 4 shows an alternative embodiment of the heat exchanger 30. The heat exchanger 30 now consists only of a cooling section, in which the high-pressure refrigerant 39 is brought into thermal contact with the coolant 40. The structure of the heat exchanger 30 corresponds essentially to the cooling section 6 of the heat exchanger 1 of Fig. 1 ,

Ähnlich wie in Fig. 2 ist in Fig. 4 ein zusätzlicher Akkumulator 31 angeordnet. Durch diesen strömt über den Fluideinlass 32 ein Niederdruckkältemittel 41 ein und aus dem Fluidauslass 33 aus dem Akkumulator 31 aus. Zusätzlich strömt in den Akkumulator 31 das Hochdruckkältemittel 39, welches aus dem Fluidauslass 36 des Wärmeübertragers 30 ausgeströmt ist, ein.Similar to in Fig. 2 is in Fig. 4 an additional accumulator 31 is arranged. Through this, a low-pressure refrigerant 41 flows in via the fluid inlet 32 and out of the accumulator 31 out of the fluid outlet 33. In addition, the high-pressure refrigerant 39, which has flowed out of the fluid outlet 36 of the heat exchanger 30, flows into the accumulator 31.

Der Akkumulator 31 weist hierzu insbesondere den zweiten Bereich 34 des ersten Strömungskanals auf, welcher in thermisch leitenden Kontakt mit dem Niederruckkältemittel 41 gebracht wird. Hierzu kann der Akkumulator 31 in seinem Inneren eine Mehrzahl von Strömungskanälen aufweisen.For this purpose, the accumulator 31 has in particular the second region 34 of the first flow channel, which is brought into thermally conductive contact with the low-pressure refrigerant 41. For this purpose, the accumulator 31 may have in its interior a plurality of flow channels.

Wie auch in Fig. 2 bereits beschrieben, kann der Akkumulator 31 der Fig. 4 als gesondertes Bauteil wie dargestellt ausgeführt sein. In alternativen Ausführungsformen kann er auch direkt in den Wärmeübertrager 30 integriert sein.As well as in Fig. 2 already described, the accumulator 31 of the Fig. 4 be designed as a separate component as shown. In alternative embodiments, it may also be integrated directly into the heat exchanger 30.

Insbesondere die Positionierung der Fluideinlässe und der Fluidauslässe stellt nur eine Möglichkeit der Anordnung dar. Die Fluideinlässe und Fluidauslässe können beliebig am Wärmeübertrager und am Akkumulator angeordnet werden. Vorteilhafte Lösungen ergeben sich insbesondere durch die Wahl des inneren Aufbaus des Wärmeübertragers. So sind bei einer Ausführung in Stapelscheibenbauweise die Fluideinlässe und die Fluidauslässe vorteilhafterweise an den beiden den Stapel abschließenden äußeren Scheibenelementen angeordnet.In particular, the positioning of the fluid inlets and the fluid outlets represents only one possibility of the arrangement. The fluid inlets and fluid outlets can be arbitrarily arranged on the heat exchanger and the accumulator. Advantageous solutions result in particular by the choice of the internal structure of the Heat exchanger. Thus, in an embodiment in stacked disc design, the fluid inlets and the fluid outlets are advantageously arranged on the two outer disc elements closing off the stack.

In allen Fig. 1 bis 4 ist der jeweils den Wärmeübertrager umgebende Kältemittelkreislauf nicht dargestellt. Die Ausführungsbeispiele der Fig. 1 bis 4 haben lediglich beispielhaften Charakter und stellen keine abschließende Aufzählung und Darstellung der Ausführungsformen dar. Sie besitzen keinen beschränkenden Charakter.In all Fig. 1 to 4 the refrigerant circuit surrounding each heat exchanger is not shown. The embodiments of the Fig. 1 to 4 are merely exemplary in nature and are not an exhaustive list and representation of the embodiments. They are not of a restrictive nature.

Claims (10)

  1. A heat exchanger (1, 30) with a first flow channel (23) for a refrigerant (2, 20, 39), a second flow channel (25) for a refrigerant (4, 22, 41), and a third flow channel (24) for a coolant (3, 21, 40), wherein the first flow channel (23) has a first region (23a) for the initial cooling of the refrigerant (2, 20, 39) and a second region (23b) for the further cooling of the refrigerant (2, 20, 39), wherein the refrigerant (2, 20, 39) can flow in a high-pressure phase in the first flow channel (23) and the refrigerant (4, 22, 41) can flow in a low-pressure phase in the second flow channel (25), wherein a first heat transfer occurs between the refrigerant in the first region (23a) of the first flow channel (23) and the coolant in the third flow channel (24) and a second heat transfer occurs between the refrigerant in the second region (23b) of the first flow channel (23) and the refrigerant in the second flow channel (25), wherein the heat exchanger (1, 30) has an accumulator (13, 31) which has a storage volume for storing the refrigerant (4, 22, 41) and/or means for filtering and/or means for drying the refrigerant (4, 22, 41), wherein the refrigerant transfer from the second region (23b) of the first flow channel (23) to the second flow channel (25) passes through the accumulator (13, 31), and characterised in that the accumulator (31) has the second region (23b, 34) of the first flow channel (23) and the second flow channel (25), wherein a heat transfer occurs between the second region (23b, 34) of the first flow channel (23) and the second flow channel (25) within the accumulator (31).
  2. The heat exchanger (1, 30) according to claim 1, characterised in that the second region (23b) of the first flow channel (23) and the second flow channel (25) form a first unit and the first region (23a) of the first flow channel (23) and the third flow channel (24) form a second unit, wherein the first unit and the second unit can be connected as a structural unit.
  3. The heat exchanger (1, 30) according to claim 1 or 2, characterised in that the third flow channel (24) is adjacent to the first region (23a) of the first flow channel (23) and the second flow channel (25) is adjacent to the second region (23b) of the first flow channel (23).
  4. The heat exchanger (1, 30) according to one of claims 1 to 3, characterised in that the first unit and/or the second unit are formed with a stacked plate design.
  5. The heat exchanger (1, 30) according to one of claims 1 to 4, characterised in that the first unit and/or the second unit are formed with a tube-fin design.
  6. The heat exchanger (1, 30) according to one of claims 1 to 5, characterised in that the first unit and/or the second unit are formed by a plurality of tubes, wherein the tubes are arranged adjacent to one another and are at least partially in thermal contact with one another, wherein the refrigerant (2, 4, 20, 22, 39, 41) and/or the coolant (3, 21, 40) can flow through the tubes.
  7. The heat exchanger (1, 30) according to one of claims 1 to 6, characterised in that the first unit and/or the second unit are formed by a plurality of tubes, wherein turbulence inserts (26) are arranged between the tubes, wherein the arrangement of tubes and turbulence inserts (26) is encased by a housing, wherein a coolant (3, 21, 40) and/or a refrigerant (2, 4, 20, 22, 39, 41) can flow through the tubes and a coolant (3, 21, 40) and/or a refrigerant (2, 4, 20, 22, 39, 41) can flow around them.
  8. The heat exchanger (1, 30) according to one of the preceding claims, characterised in that one or more of the flow channels (23, 24, 25) experience one or more redirections in their flow direction, as a result of which the fluid flows in the flow channels (23, 24, 25) can run in a co-current flow and/or in a counter-flow and/or in a cross-flow to one another.
  9. The heat exchanger (1, 30) according to one of the preceding claims, characterised in that the accumulator (13, 31) and the heat exchanger (1, 30) are made as a structural unit.
  10. Use of the heat exchanger according to one of the preceding claims, wherein CO2 (R744) is used as the refrigerant.
EP13799266.5A 2012-11-29 2013-11-27 Heat exchanger Active EP2926073B1 (en)

Applications Claiming Priority (2)

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DE102012221925.0A DE102012221925A1 (en) 2012-11-29 2012-11-29 Heat exchanger
PCT/EP2013/074865 WO2014083061A1 (en) 2012-11-29 2013-11-27 Heat exchanger

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DE102014221168A1 (en) 2014-10-17 2016-04-21 Mahle International Gmbh Heat exchanger
CN111615290B (en) * 2019-02-25 2022-07-26 龙大昌精密工业有限公司 Heat radiation structure of condenser
DE102020202313A1 (en) * 2020-02-24 2021-08-26 Mahle International Gmbh Heat exchanger
DE102021213376A1 (en) 2021-11-26 2023-06-01 Mahle International Gmbh Heat exchanger and refrigerant circuit with a heat exchanger

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EP2926073A1 (en) 2015-10-07
US20150260457A1 (en) 2015-09-17
CN104823014A (en) 2015-08-05
DE102012221925A1 (en) 2014-06-05
WO2014083061A1 (en) 2014-06-05
US9945614B2 (en) 2018-04-17

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