EP2945754B1 - Metering apparatus - Google Patents
Metering apparatus Download PDFInfo
- Publication number
- EP2945754B1 EP2945754B1 EP14716327.3A EP14716327A EP2945754B1 EP 2945754 B1 EP2945754 B1 EP 2945754B1 EP 14716327 A EP14716327 A EP 14716327A EP 2945754 B1 EP2945754 B1 EP 2945754B1
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- EP
- European Patent Office
- Prior art keywords
- bellows
- outlet opening
- closing unit
- closing
- actuator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/30—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages
- B05B1/3033—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head
- B05B1/304—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a lift valve
- B05B1/3046—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a lift valve the valve element, e.g. a needle, co-operating with a valve seat located downstream of the valve element and its actuating means, generally in the proximity of the outlet orifice
- B05B1/306—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a lift valve the valve element, e.g. a needle, co-operating with a valve seat located downstream of the valve element and its actuating means, generally in the proximity of the outlet orifice the actuating means being a fluid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
- B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
- B05C11/1034—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves specially designed for conducting intermittent application of small quantities, e.g. drops, of coating material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
- B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
- B05C5/0225—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work characterised by flow controlling means, e.g. valves, located proximate the outlet
- B05C5/0237—Fluid actuated valves
Definitions
- the invention relates to a metering device, in particular a metering device with a long service life for delivering free-flying drops of low to high viscosity liquid media.
- liquid media is a task that many fields of technology are faced with.
- the spectrum ranges from inkjet printing applications in the areas of medicine, pharmacy and biochemistry, which mostly involve the dispensing of aqueous or other low-viscosity media, to the dosing of highly viscous media such as sealants and adhesives.
- dosing devices Following the general trend towards miniaturization, dosing devices must be able to dispense ever smaller quantities precisely. In order to achieve the frequently also required higher throughput rates, a non-contact drop dispensing is used in many cases, eliminating the time required for a method of metering device for discontinuing the metered liquid. Dosing devices that deliver the amount of liquid to be dosed as free-flying drops are known for low-viscosity media, especially in the field of inkjet printers, see, for example EP 0 422 870 B1 . US Pat. No. 4,509,057 and WO 2013/013983 A1 ,
- highly viscous media can only be conveyed from a reservoir when pumped or pressurized fluid, e.g. Compressed air, pressure is applied to the medium.
- pressurized fluid e.g. Compressed air
- a pressure difference between the reservoir and metering device remains and ensures that a sufficiently high flow rate is maintained.
- the metering is interrupted, the pressures within the overall system are equal, so that the media delivery pressure is applied directly to the discharge opening of the metering device. In an open system, this pressure ensures that the surface tension of the dosing liquid is overcome and uncontrolled medium flows out of the discharge opening of the dosing device.
- the metering device it is essential for metering devices for highly viscous media that either the delivery pressure taken from the system or the channel from the reservoir to the outlet of the metering device is actively closed when the dosage ends. If in the second case, e.g. a high-viscosity adhesive containing solid fillers are metered at a high repetition rate from a drop metering device, the metering device must contain a closure device which is fast on the one hand, but on the other hand also releases a sufficiently large passage opening so that the filler particles can flow through unhindered.
- a pressure pulse for example, a shock wave generated by a piezoelectric actuator or a gas bubble is so low that the surface tension is overcome at the outlet opening and a drop detaches.
- the location where the pressure pulse is generated, and the outlet opening can therefore be relatively far apart.
- High viscosities therefore provide, in two respects, that high pressures must be built up at the outlet to produce a single drop: first, because the viscosity reduces the flow rate, and second, because the flow rate must be higher, the higher which are cohesive forces in the medium.
- a valve tappet In the dosing device disclosed therein, a valve tappet is moved up and down via an engine and a crankshaft, which closes an elongated cylindrical outlet opening in the lowest position and releases it upwards during the stroke. The rapid downward movement during the closing operation, the highly viscous medium is compressed at the inlet of the outlet opening and thus generates a high pressure, which can flow out of the dosing medium with high flow velocity from the outlet, so that it comes to the formation of individual drops.
- the valve stem thus simultaneously assumes the two described tasks of closing the metering device and building up the pressure required to produce individual drops.
- a disadvantage of this design is that the motor continuously passes through and forms the droplets of the metering medium only with a fixed or slowly variable repetition rate. Also, the repetition rate must not be too low, since then the plunger moves too slowly and does not cause sufficient pressures. Because of the inertia of the drive thus the production of individual drops is not possible as needed. Finally, the crankshaft causes the speed of the valve tappet to have a sinusoidal course, so that the speed and therefore the compression at zero is just at the moment of closing in which the highest pressure in the medium should be built up.
- a drop dispenser which includes a pneumatically driven valve lifter.
- the actuator includes a piston that can move within a cylinder. If compressed air is injected into the volume under the piston, the piston and the valve tappet firmly connected to it are pushed upwards, thereby opening the outlet opening of the metering device for the metering medium. If the cylinder is then vented again, a spring pushes the piston down again from the opposite side and the outlet opening is closed again.
- the disadvantage of this solution is that the pressure chamber of the cylinder and piston is sealed by a fixedly connected to the piston seal that slides during the lifting movement along the cylinder inner wall.
- DE 2 553 163 A1 discloses a pressure-controlled shut-off valve for blocking the flow of a cryomedium, in which a bellows separates the space of the cryomedium from the space of the control pressure. This valve is not suitable for dropping doses of liquids or even for dosing highly viscous liquids.
- CH 678 754 A5 discloses a shut-off valve in a conduit.
- a part of the conduit wall is formed by a bellows, which is moved to actuate the valve disposed inside.
- the bellows is concentrically surrounded by another bellows and the actuation is done by injecting compressed air into the annular chamber between the two bellows.
- This valve is also unsuitable for drop dosing of liquids or even for dispensing high-viscosity media. Because the contact of the bellows with the medium in the line makes the movement sluggish.
- media such as adhesives, which cure under certain conditions, can adhere the bellows. Because of the wave or fold shape of the bellows wall, cleaning in such cases is difficult or impossible.
- the object of the invention is therefore to provide a metering device which has an actuator which is virtually maintenance-free, can also dose highly viscous media as free-flying single drops and can also dispense mixed metering media with larger filler particles.
- the metering device should be as compact as possible in order to be able to easily integrate it into production systems.
- the metering device according to the invention is largely low maintenance. It can impart a high impulse and a high speed to a closing unit, such as a valve tappet, in order to dose even highly viscous media as free-flying single drops. It can reach a large stroke to dispense metered media even with larger filler particles.
- Such a metering device comprises an outlet unit with an outlet opening, through which the metering medium is ejected in the form of individual free-flying drops.
- a feed channel is connected, via which the metering medium is conveyed from a storage container by a pump or by applying a delivery pressure to the outlet opening.
- the outlet opening is closed or opened by a movable closing unit, so that the flow of the metering medium through the outlet opening can be controlled by means of the movement of the closing unit.
- the movement of the closing unit is by an actuator or a Actuator having a housing, one or more Metallbälge and a power transmission element for transmitting the force to the clamping unit.
- the metal bellows are hermetically sealed on one side and tightly and firmly connected to the actuator housing on the other side. Channels are provided in the actuator housing establish a connection between at least one control valve and the interior of the metal bellows. By switching the control valve, a pressurized fluid is directed into the interior of the hermetically sealed metal bellows so that the metal bellows can expand.
- the ambient atmosphere is applied to this expansion from the outside no friction, so that the speed on the part of the actuator essentially by the pressure force, the restoring forces of the metal bellows, the internal friction of the pressurized fluid and the masses of the moving elements is determined .
- a gas is used as the pressure fluid, so that the internal friction of the pressure fluid is minimized and the speed is increased accordingly.
- the hermetically sealed end of the metal bellows is connected to the power transmission element, which transmits the movement and force of the pressurized metal bellows to the closing unit. If the pressurized fluid is allowed to escape from the metal bellows via a control valve, the metal bellows retract again.
- This return movement can be generated either by the restoring forces of the metal bellows itself or preferably by an additional spring, a return spring, which counteracts the expansion of the metal bellows supported.
- the spring acts on the power transmission element or the closing unit such that the closing unit closes the outlet opening when the metal bellows are not under pressure.
- the closing unit is thus arranged on that side of the outlet opening, from which the supply of the metering medium takes place. As it closes, it moves towards the outlet opening and then sits on its edge to close it. Thus it supports the ejection of a drop of the dosing medium from the outlet opening.
- the magnetically acting element exerts an additional force on the force transmission element.
- this force acts in the closing direction of the closing element.
- the force curve of the magnetically acting element is such that the force increases, the closer the closing element comes to the closed position. In this way, the magnetically acting element compensates for the release of the spring force of the return spring and thus unfolds maximum support of the pressure fluid discharge.
- the magnetically acting element has one or more permanent magnets.
- the magnetically acting element has one or more electromagnets.
- the magnetically acting element has a combination of an electric and a permanent magnet, wherein the electromagnet is controlled such that the force effect of the combination only supports one or, if the electromagnet is reversed, both directions of movement of the force transmission element.
- exemplary embodiments which are a variant of another exemplary embodiment and to which the figures specifically show the features of the variant, correspond to this other exemplary embodiment.
- Fig. 1 shows an embodiment of a metering device 1 in the sectional side view.
- the metering device has an actuator unit or an actuator with an actuator housing 2, a force transmission element 3 and at least one bellows 4 (bellows), which is hermetically sealed by a closure piece 5 at one end and at its opposite end in the longitudinal direction and tight is firmly connected to the actuator housing 2.
- bellows 4 bellows
- the power transmission element 3 is a Traverse, which connects the end pieces 5 of the bellows 4 together.
- channels 6 which connect the interior of the bellows 4 with a (not shown) valve. This valve is designed to direct a pressurized fluid into the interior of the bellows 4 as needed.
- a valve stem or a valve needle 10 is connected as a closing unit, which is movable in the longitudinal direction and protrudes down between the bellows 4 in a feed unit 9 for the metering 14.
- the feed unit 9 contains a channel 11, via which the metering medium 14 is conveyed from a storage container 13 to an outlet unit 15 or nozzle with an outlet opening 16 which has the shape of a short channel (outlet channel 16) passing through the wall of the outlet unit 15 passes.
- valve needle 10 protrudes into the channel 11, immersed in the dosing and presses in the lower starting position with its tip against the inlet of the outlet 16 and thus closes the metering device 1.
- the next step in the dosing process is the filling of the bellows 4 with the pressurized fluid, so that the in Fig. 2 shown state is reached.
- both liquids and gases are considered as pressurized fluid.
- Liquid, less compressible pressure fluids have the advantage that only small volumes would have to flow in or out to build up a high pressure in the interior of the bellows 4.
- the internal friction of the pressurized fluid should be as low as possible. Therefore, gaseous pressurized fluids such as air, nitrogen, carbon dioxide, hydrogen or other gases are preferable.
- a static sealing element or a welding, gluing or similar ensures that the bellows 4 are tightly connected to the actuator housing 2 and there is no loss of pressure fluid at this junction.
- the end piece 5 at the other end of the respective bellows 4 is also by an additional sealing element or a Welding, gluing or similar tightly and firmly connected to the bellows 4. All these Seals are loaded purely statically and in particular are not subjected to any rubbing or sliding load during operation.
- the bellows 4 should each be designed so that the radially outward force causes only a small radial extent and consequent increase in volume of the bellows 4 and substantially only by the force on the end piece 5 a desired increase in length of the bellows 4 along the longitudinal axis takes place.
- this is achieved by making the bellows 4 of a preferably inelastic material, e.g.
- the walls of the bellows 4 should be as thin as possible, so that a deformation along the axis is as little resistance as possible. Even if metal such as e.g. Stainless steel is the preferred material for the bellows 4 and therefore the term metal bellows is possible, it should be noted that other materials such. Plastics come into question, especially if by additional constructive measures such. Stiffening rings made of the same material as the wall or a combination of different materials outside or inside of the ribs of the bellows 4 a radial stabilization is made.
- the bellows 4 can withstand proper dimensioning of a very high number of load changes, which is equal to a virtually unlimited life of the actuator.
- the travel ranges which can typically be achieved are at the same dynamics and size but many times greater than the achievable with a piezoelectric actuator with leverage strokes.
- the outer space of the bellows 4 is connected to the ambient atmosphere, which may possibly also be a vacuum or an overpressure compared to normal atmosphere. Due to the largely constant ambient pressure and the gaseous environment, the end pieces 5 of the metal bellows 4 exert on the force transmission element 3 a defined force which ensures largely friction-free elongation of the metal bellows 4 along their axis.
- the termination pieces 5 may e.g. be firmly connected by a screw or a material connection with the power transmission element 3.
- devices 7 such as e.g. Springs (return springs) are present, which exert a counter force to the force transmission element 3 to the bellows 4, also extends a non-positive connection of the end piece 5 and the power transmission element.
- valve needle 10 Due to the elongation of the bellows 4 and the resulting displacement of the force transmission element 3, the valve needle 10 is retracted (lifted) in the longitudinal direction and releases the outlet channel 16 of the outlet unit 15 for the discharge of the metering medium 14.
- Fig. 3 The last phase of the dosing process is in Fig. 3 shown.
- the pressurized fluid flows rapidly from the interior of the bellows 4.
- the fluid valve that accomplishes the emptying of the bellows 4 a 3-way valve, the also controls the filling.
- separate fluid valves for filling and emptying are also conceivable. In order to allow the emptying process to take place quickly and thus rapidly reduce the pressure forces in the bellows 4, the fluid valves should have typical switching times in the lower millisecond range.
- the bellows 4 go back to their original length, so that the power transmission element 3 and the valve needle 10 again in Fig. 1 reach shown starting position.
- the tip of the valve needle 10 performs a fast forward movement, by means of which the dosing medium 14 is compressed in the region of the outlet opening 16 and the dosing medium 14 accelerated in the outlet channel by the build-up dynamic pressure and finally as free flying drop 57 is expelled from the outlet opening 16.
- the tip of the valve needle 10 sits in the interior of the outlet unit 15 again on its seat on the edge of the outlet opening 16 and closes it as in Fig. 1 shown, so that no further dosing medium 14 can flow out until the next Dosierhub.
- the actuator contains no sliding sealing elements in the metering device 1 just described, it works in contrast to the prior art friction and wear, which ensures a long life and high speeds of the valve needle 10.
- Fig. 4 shows an example of a section of an actuator housing 2 with a linear arrangement of four bellows 4.
- the associated plan view of the force transmission element 3 and the bellows 4 can be found in Fig. 4a , Without enlarging the lateral extent of the metering device is so compared to the arrangement in Fig. 1-3 the double actuator power available.
- the Figures 4b and 4c show further symmetrical arrangements of several bellows 4, here three or four bellows 4 around the attachment point of the valve needle 10 on the power transmission element 3 around.
- the arrangement is point-symmetrical or two-fold ( Fig. 4a and 4c ), triple ( Fig. 4b ) or generally multiple rotationally symmetrical about the attachment point.
- the attachment point is located in Focus of the forces exerted by the bellows (4) when filled with the same pressure fluid to the power transmission element.
- a metering device can advantageously also be constructed with metal bellows 4 with other than circular cross sections.
- bellows with rectangular or circular segment-shaped cross sections are conceivable in order to optimize the ratio between effective area and installation space.
- sectional views in Fig. 1-3 not only to be understood to mean that two separate, equal sized metal bellows are shown with different axes, but the same sectional view also applies to a variant with two concentric bellows of different diameters, between which an annular pressure chamber is formed.
- the power transmission element 3 also does not have to be completely free to move. It is also conceivable that the force transmission element 3 is designed as a lever, which on one side via a joint, e.g. a non-sliding solid joint, is connected to the actuator housing 2 and is moved on the other side of one or more Metallbälgen 4. Depending on whether an amplification of the stroke or an amplification of the force acting on the valve needle 10 is to be achieved, the point of attachment of the valve needle 10 may be arranged on the force transmission element 3, viewed from the joint, beyond the metal bellows 4 or between metal bellows 4 and joint.
- a joint e.g. a non-sliding solid joint
- the closing unit 10 for the outlet opening 16 does not necessarily have to have the illustrated needle shape. It is also conceivable to use a pressure piece which only traces the contour of the outlet unit 15 in the region of the outlet opening 16.
- the interior of the bladders 4 can be filled with pressurized fluid for actuating the metering device, while the outer space of the bladders 4 remains essentially at constant pressure, in particular at atmospheric pressure.
- the outer space of the bellows 4 can be filled with pressurized fluid in order to actuate the metering device, while the interior space remains essentially at constant pressure.
- the pressure fluid is passed through corresponding passages in the actuator housing alternately in the interior of the bellows 4 and in the outer space to move the valve needle 10 back and forth.
- This variant can achieve particularly fast opening and closing operations even with high-viscosity metering media and large stroke of the valve needle 10 and is also advantageous to accelerate the closing process and the tearing of a drop from the outlet opening 16 of the outlet 15 by the pulse of the valve needle 10 during the closing process to favor.
- valve needle 10 in a drop metering device In order for the valve needle 10 in a drop metering device to generate the highest possible back pressure in the metering medium at the outlet opening 16, it is necessary for the valve needle to be as close as possible to the edge of the outlet opening 16 at the moment of impact has high speed. If the closing operation as described above accomplished by a mechanical spring 7 such as a screw or a plate spring, then this has the advantage that the outlet opening 16 of the metering device is closed without applied pressure fluid, but has the disadvantage that the Spring force is the lowest even when the closing position is reached.
- a mechanical spring 7 such as a screw or a plate spring
- this disadvantage of the spring 7 can be compensated or even overcompensated by a magnetically acting element is installed in addition to or even completely in place of the mechanical spring 7.
- a magnetically acting element is installed in addition to or even completely in place of the mechanical spring 7.
- FIG. 5 the force-displacement characteristic 72 of a magnet is shown, which is attracted by a ferromagnetic body or another magnet. The attractive force is greater, the more the magnet approaches the zero position, ie its contact with the ferromagnetic body or other magnet. The same applies to the repulsive forces of two magnets whose poles face each other. The characteristic of the magnet thus shows the reverse slope of the characteristic of a mechanical spring.
- the combined force-displacement curve 73 which shows a much more constant force or related to a drop metering even at the end of the closing process by the action of the magnet in a particularly advantageous manner can have the highest accelerating forces.
- the zero positions of the characteristic curves do not have to match.
- the zero position of the magnetic characteristic curve 72 ie the point at which the magnet and the ferromagnetic body touch, and the point at which the spring is completely relaxed can and must possibly be different. In the characteristic diagram, this means that the characteristic curves 71 and 72 are horizontally shifted from one another and consequently a correspondingly different sum characteristic 73 results.
- Fig. 6 shows an embodiment of a corresponding metering device 1, which has a magnet 98 as a magnetically acting element.
- an actuator 84 is connected, which is a metal bellows 4 as described above.
- the power transmission element 3 is again connected, with which the valve needle 10 is connected, which opens or closes the outlet opening 16 of the outlet unit 15 depending on the position of the force transmission element 3.
- springs 7 restoring spring ensure that the force transmission element 3 and with it the valve needle 10 are returned to the starting position.
- a magnet 98 is connected, which serves as an anchor serving as an anchor member connected to the force transmission element ferromagnetic element or magnet 99 or, if the force transmission element 3 consists of a ferromagnetic material, the armature serving as an element 3 directly opposite so that both dress and support the spring force.
- the force-displacement characteristic curve of the springs 7 does not select an area from the zero point, but only a certain section by biasing the respective spring, so that a minimum spring force is not undershot even in the closed position.
- a range of the force-displacement curve are chosen so that in the combination of spring 7 and magnet 98 of the desired total force curve adjusts, in which the power transmission element 3 to the closing position driving force increases shortly before reaching the closed position.
- the maximum force of the magnet 98 and the ferromagnetic element 99 is achieved when both in the closed position in to be in direct contact. Nevertheless, the magnet 98 and the ferromagnetic element 99 should not drive during the closing process to stop, but also in the closed position leave a small gap between them, otherwise the valve needle 10, the outlet opening 16 no longer tightly closes.
- the attracting force between magnet 98 and ferromagnetic element 99 or armature decreases and increases in the subsequent closing operation again, the more the force transmission element 3 approaches the closed position.
- Fig. 7 shows such an arrangement in which an annularly shown here solenoid 118 is connected to the actuator housing 2.
- solenoid 118 For its counterpart 99, which is firmly connected to the power transmission element 3, either a ferromagnetic material can be used, which then act only attractive forces, or a permanent magnet, so that the electromagnet 118 depending on polarity attractive or repulsive forces on the counterpart 99th exercises.
- the advantage of such a construction is that by appropriate polarity of the electromagnet 118, both the opening and the closing stroke of the force transmission element 3 and the valve needle 10 connected to it can be accelerated. Incidentally, this applies to FIG. 6 Also said here.
- the magnetically acting element includes a permanent magnet.
- a component of the magnetic force of the magnetically acting element counteracts the expansion of the active expansion element 4 and decreases the further the active expansion element expands in the direction not perpendicular to the closing unit.
- the magnetically acting element may also include an electromagnet.
- the electromagnet is energized variable in time and the polar direction of the energization is chosen so that its force effect contains a component parallel to the ⁇ ffungshub and / or the closing stroke of the expansion element 4.
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- Loading And Unloading Of Fuel Tanks Or Ships (AREA)
Description
Die Erfindung betrifft eine Dosiervorrichtung, insbesondere eine Dosiervorrichtung mit hoher Lebensdauer zur Abgabe von frei fliegenden Tropfen von nieder- bis hochviskosen flüssigen Medien.The invention relates to a metering device, in particular a metering device with a long service life for delivering free-flying drops of low to high viscosity liquid media.
Die genaue Dosierung flüssiger Medien ist eine Aufgabe, mit der sich viele Felder der Technik konfrontiert sehen. Die Spanne reicht von Tintendruckanwendungen über die Bereiche Medizin, Pharmazie und Biochemie, in denen es meist um die Abgabe wässriger oder anderer niederviskoser Medien geht, bis zur Dosierung von hochviskosen Medien wie Dicht- und Klebstoffen.The exact dosage of liquid media is a task that many fields of technology are faced with. The spectrum ranges from inkjet printing applications in the areas of medicine, pharmacy and biochemistry, which mostly involve the dispensing of aqueous or other low-viscosity media, to the dosing of highly viscous media such as sealants and adhesives.
Dem allgemeinen Trend zur Miniaturisierung folgend müssen Dosiervorrichtungen immer kleinere Mengen präzise abgeben können. Um die häufig außerdem geforderten höheren Durchsatzraten zu erreichen, wird in vielen Fällen eine berührungslose Tropfendosierung eingesetzt, durch die der Zeitaufwand für ein Verfahren der Dosiervorrichtung zum Absetzen der dosierten Flüssigkeit entfällt. Dosiervorrichtungen, die die zu dosierende Flüssigkeitsmenge als frei fliegenden Tropfen abgeben, sind für niederviskose Medien speziell im Bereich der Tintenstrahldrucker bekannt, siehe z.B.
Allerdings unterscheiden sich Tropfen-Dosiervorrichtungen für hoch- und für niederviskose Medien in der Art und Weise wie der Dosiervorgang kontrolliert wird und wie frei fliegende Einzeltropfen erzeugt werden:
- Dosiervorrichtungen für niederviskose Medien benötigen wegen des geringen Strömungswiderstands nur einen sehr geringen bis gar keinen Druck, um das Dosiermedium aus einem Vorratsbehälter in die eigentliche Dosiervorrichtung zu fördern. Folglich ist es vielfach nicht notwendig, die Austrittsöffnung der Dosiervorrichtung aktiv zu verschließen, um das Austreten des Dosiermediums im inaktiven Zustand zu verhindern. Häufig reicht die Oberflächenspannung aus, um das Medium in der Austrittsöffnung zurück zu halten.
- Dosing devices for low-viscosity media require only a very little to no pressure due to the low flow resistance in order to promote the dosing from a reservoir into the actual metering device. Consequently, it is often not necessary to actively close the outlet opening of the metering device in order to prevent the leakage of the metering medium in the inactive state. Frequently, the surface tension is sufficient to retain the medium in the exit opening.
Hochviskose Medien dagegen können nur dann aus einem Vorratsbehälter gefördert werden, wenn durch eine Pumpe oder durch das Anlegen eines Druckfluids, wie z.B. Druckluft, Druck auf das Medium aufgebracht wird. Solange das Medium ausdosiert und aus dem Vorratsbehälter nachgefördert wird, bleibt eine Druckdifferenz zwischen Vorratsbehälter und Dosiervorrichtung bestehen und sorgt dafür, dass ein ausreichend hoher Durchfluss aufrecht erhalten bleibt. Wird die Dosierung allerdings unterbrochen, gleichen sich die Drücke innerhalb des Gesamtsystems an, so dass unmittelbar an der Austrittsöffnung der Dosiervorrichtung der Medienförderdruck anliegt. In einem offenen System sorgt dieser Druck dafür, dass die Oberflächenspannung der Dosierflüssigkeit überwunden wird und unkontrolliert Medium aus der Austrittsöffnung der Dosiervorrichtung ausfließt. Daher ist es bei Dosiervorrichtungen für hochviskose Medien unumgänglich, dass entweder der Förderdruck vom System genommen oder der Kanal vom Vorratsbehälter zur Austrittsöffnung der Dosiervorrichtung aktiv verschlossen wird, sobald die Dosierung endet. Soll im zweiten Fall z.B. ein hochviskoser Klebstoff, der feste Füllstoffe enthält, mit einer hohen Wiederholrate aus einer Tropfen-Dosiervorrichtung dosiert werden, muss die Dosiervorrichtung eine Verschlussvorrichtung enthalten, die einerseits schnell ist, andererseits aber auch eine hinreichend große Durchlassöffnung freigibt, damit die Füllstoffpartikel ungehindert hindurchströmen können.On the other hand, highly viscous media can only be conveyed from a reservoir when pumped or pressurized fluid, e.g. Compressed air, pressure is applied to the medium. As long as the medium is dispensed and nachgefördert from the reservoir, a pressure difference between the reservoir and metering device remains and ensures that a sufficiently high flow rate is maintained. However, if the metering is interrupted, the pressures within the overall system are equal, so that the media delivery pressure is applied directly to the discharge opening of the metering device. In an open system, this pressure ensures that the surface tension of the dosing liquid is overcome and uncontrolled medium flows out of the discharge opening of the dosing device. Therefore, it is essential for metering devices for highly viscous media that either the delivery pressure taken from the system or the channel from the reservoir to the outlet of the metering device is actively closed when the dosage ends. If in the second case, e.g. a high-viscosity adhesive containing solid fillers are metered at a high repetition rate from a drop metering device, the metering device must contain a closure device which is fast on the one hand, but on the other hand also releases a sufficiently large passage opening so that the filler particles can flow through unhindered.
Für die Erzeugung eines einzelnen, frei fliegenden Tropfens reicht es bei niederviskosen Medien in der Regel aus, einen Druckimpuls auf die zu dosierende Flüssigkeit zu geben, damit ein Tropfen aus der Austrittsöffnung ausgestoßen wird. Die Dämpfung eines solchen Druckimpulses, z.B. einer durch einen Piezoaktor oder eine Gasblase erzeugten Schockwelle ist so gering, dass die Oberflächenspannung an der Austrittsöffnung überwunden wird und sich ein Tropfen ablöst. Der Ort, wo der Druckimpuls erzeugt wird, und die Austrittsöffnung können daher auch relativ weit voneinander entfernt sein.For the production of a single, free-flying droplet, it is generally sufficient for low-viscosity media to give a pressure pulse to the liquid to be metered, so that a drop is ejected from the outlet opening. The damping of such a pressure pulse, for example, a shock wave generated by a piezoelectric actuator or a gas bubble is so low that the surface tension is overcome at the outlet opening and a drop detaches. The location where the pressure pulse is generated, and the outlet opening can therefore be relatively far apart.
Bei hochviskosen Medien funktioniert dieser Ansatz nicht. Um einen einzelnen Tropfen des Dosiermediums vom Rest abzutrennen, müssen starke kohäsive Kräfte überwunden werden. Eine Schockwelle, die entfernt im Dosiermedium erzeugt wird, wird dazu viel zu schnell gedämpft. Der erfolgversprechendste Ansatz wäre, das auszustoßende Medium auf eine ausreichend hohe Geschwindigkeit gegenüber dem Rest des Mediums zu beschleunigen, damit der kinetische Impuls des Tropfens die rückhaltenden Kräfte im Medium überwinden kann. Dabei gilt, dass der Impuls umso höher sein muss, je höher die Viskosität - und damit die kohäsive Kraft - des Dosiermediums ist. Die Geschwindigkeit, die eine strömende Flüssigkeit in einem Strömungskanal, wie ihn eine Auslassöffnung darstellt, erreicht, hängt dabei von der Viskosität und der Druckdifferenz zwischen den Enden des Kanals ab. Hohe Viskositäten sorgen daher in zweierlei Hinsicht dafür, dass hohe Drücke an der Auslassöffnung aufgebaut werden müssen, um einen einzelnen Tropfen zu erzeugen: zum einen, weil die Viskosität die Strömungsgeschwindigkeit reduziert, und zum anderen, weil die Strömungsgeschwindigkeit umso höher ausfallen muss, je höher die kohäsiven Kräfte im Medium sind.For high-viscosity media, this approach does not work. To separate a single drop of the dosing medium from the rest, strong cohesive forces must be overcome. A shockwave that is generated remotely in the dosing medium is damped too fast. The most promising approach would be to accelerate the medium to be ejected to a high enough velocity with respect to the rest of the medium so that the kinetic momentum of the droplet can overcome the restraining forces in the medium. In this case, the higher the viscosity - and thus the cohesive force - of the dosing medium, the higher the impulse must be. The velocity that a flowing liquid reaches in a flow channel, such as an outlet opening, depends on the viscosity and the pressure difference between the ends of the channel. High viscosities therefore provide, in two respects, that high pressures must be built up at the outlet to produce a single drop: first, because the viscosity reduces the flow rate, and second, because the flow rate must be higher, the higher which are cohesive forces in the medium.
Ein Ansatz zur Lösung dieser Probleme findet sich in
Auf demselben Grundprinzip basieren weitere Lösungen für Tropfen-Dosiervorrichtungen, die aber an Stelle der motorbetriebenen Kurbelwelle andere Aktoren verwenden.Based on the same basic principle, further solutions are based on drop metering devices, but instead of using the motor-driven crankshaft, they use other actuators.
So offenbart
In
In einer vollautomatisierten industriellen Fertigung ist es wünschenswert, den Wartungsaufwand auf ein Minimum zu reduzieren. Gleichzeitig ist es wünschenswert, die Viskositätsobergrenze der dosierbaren Medien nach oben zu setzten, damit die Vorteile einer berührungslosen Tropfendosierung für ein möglichst breites Spektrum zu dosierender Medien (Dosiermedien) einschließlich Klebstoffen nutzbar werden.In fully automated industrial manufacturing, it is desirable to reduce maintenance to a minimum. At the same time, it is desirable to set the viscosity upper limit of the metered media upwards, so that the advantages of a contactless drop metering for a broad spectrum of dosing media (dosing) including adhesives can be used.
Aufgabe der Erfindung ist es daher, eine Dosiervorrichtung bereit zu stellen, die über einen Aktor verfügt, der praktisch wartungsfrei ist, auch höchstviskose Medien als frei fliegende Einzeltropfen dosieren kann und auch mit größeren Füllstoffpartikeln versetzte Dosiermedien ausbringen kann. Vorzugsweise sollte die Dosiervorrichtung möglichst kompakt sein, um sie leicht in Fertigungsanlagen integrieren zu können.The object of the invention is therefore to provide a metering device which has an actuator which is virtually maintenance-free, can also dose highly viscous media as free-flying single drops and can also dispense mixed metering media with larger filler particles. Preferably, the metering device should be as compact as possible in order to be able to easily integrate it into production systems.
Die Lösung dieser Aufgabe gelingt mit der in dem unabhängigen Anspruch 1 angegebenen Dosiervorrichtung. Die abhängigen Ansprüche betreffen bevorzugte Ausgestaltungen der Erfindung.The solution of this problem is achieved with the metering device specified in the
Die erfindungsgemäße Dosiervorrichtung ist weitgehend wartungsarm. Sie kann einer Schließeinheit wie beispielsweise einem Ventilstößel einen hohen Impuls und eine hohe Geschwindigkeit verleihen, um auch hochviskose Medien als frei fliegende Einzeltropfen zu dosieren. Sie kann einen großen Hub erreichen, um auch mit größeren Füllstoffpartikeln versetzte Dosiermedien auszubringen.The metering device according to the invention is largely low maintenance. It can impart a high impulse and a high speed to a closing unit, such as a valve tappet, in order to dose even highly viscous media as free-flying single drops. It can reach a large stroke to dispense metered media even with larger filler particles.
Die Ausgestaltung der Erfindung löst das obige Problem, indem sie einen Aktor verwendet, der vollständig auf gleitende Dichtelemente verzichtet. Eine solche Dosiervorrichtung umfasst eine Auslasseinheit mit einer Auslassöffnung, durch die das Dosiermedium in Form von einzelnen frei fliegenden Tropfen ausgestoßen wird. Mit dieser Auslasseinheit ist ein Zuführkanal verbunden, über den das Dosiermedium aus einem Vorratsbehälter durch eine Pumpe oder durch Anlegen eines Förderdrucks zur Auslassöffnung gefördert wird. Auf der Seite des Zuführkanals wird die Auslassöffnung durch eine bewegliche Schließeinheit verschlossen bzw. geöffnet, so dass der Fluss des Dosiermediums durch die Auslassöffnung mittels der Bewegung der Schließeinheit gesteuert werden kann. Die Bewegung der Schließeinheit wird durch eine Aktoreinheit bzw. einen Aktor erzeugt, die ein Gehäuse, einen oder mehrere Metallbälge und ein Kraftübertragungselement zur Übertragung der Kraft auf die Schließeinheit aufweist. Die Metallbälge sind auf einer Seite hermetisch abgeschlossen und auf der anderen Seite dicht und fest mit dem Aktorgehäuse verbunden. Im Aktorgehäuse sind Kanäle vorgesehen, die eine Verbindung zwischen mindestens einem Steuerventil und dem Inneren der Metallbälge herstellen. Durch Schalten des Steuerventils wird ein Druckfluid in das Innere der hermetisch abgeschlossenen Metallbälge geleitet, so dass sich die Metallbälge ausdehnen können. Da außen an den Metallbälgen die Umgebungsatmosphäre anliegt, entsteht bei dieser Ausdehnung von außen keine Reibung, so dass die Geschwindigkeit auf Seiten des Aktors im Wesentlichen durch die Druckkraft, die Rückstellkräfte der Metallbälge, die innere Reibung des Druckfluids und die Massen der bewegten Elemente bestimmt wird. Vorzugsweise wird als Druckfluid ein Gas eingesetzt, so dass die innere Reibung des Druckfluids minimiert und die Geschwindigkeit entsprechend erhöht wird. Das hermetisch dichte Ende der Metallbälge ist mit dem Kraftübertragungselement verbunden, das die Bewegung und die Kraft der mit Druck beaufschlagten Metallbälge auf die Schließeinheit überträgt. Lässt man das Druckfluid über ein Steuerventil wieder aus den Metallbälgen entweichen, ziehen sich die Metallbälge wieder zusammen. Diese Rückbewegung kann entweder durch die Rückstellkräfte der Metallbälge selbst erzeugt werden oder vorzugsweise durch eine zusätzliche Feder, eine Rückstellfeder, die der Ausdehnung der Metallbälge entgegen wirkt, unterstützt werden. Vorzugsweise wirkt die Feder so auf das Kraftübertragungselement oder die Schließeinheit, dass die Schließeinheit die Auslassöffnung verschließt, wenn die Metallbälge nicht unter Druck stehen.The embodiment of the invention solves the above problem by using an actuator which completely dispenses with sliding sealing elements. Such a metering device comprises an outlet unit with an outlet opening, through which the metering medium is ejected in the form of individual free-flying drops. With this outlet unit, a feed channel is connected, via which the metering medium is conveyed from a storage container by a pump or by applying a delivery pressure to the outlet opening. On the side of the feed channel, the outlet opening is closed or opened by a movable closing unit, so that the flow of the metering medium through the outlet opening can be controlled by means of the movement of the closing unit. The movement of the closing unit is by an actuator or a Actuator having a housing, one or more Metallbälge and a power transmission element for transmitting the force to the clamping unit. The metal bellows are hermetically sealed on one side and tightly and firmly connected to the actuator housing on the other side. Channels are provided in the actuator housing establish a connection between at least one control valve and the interior of the metal bellows. By switching the control valve, a pressurized fluid is directed into the interior of the hermetically sealed metal bellows so that the metal bellows can expand. Since the outside of the metal bellows, the ambient atmosphere is applied to this expansion from the outside no friction, so that the speed on the part of the actuator essentially by the pressure force, the restoring forces of the metal bellows, the internal friction of the pressurized fluid and the masses of the moving elements is determined , Preferably, a gas is used as the pressure fluid, so that the internal friction of the pressure fluid is minimized and the speed is increased accordingly. The hermetically sealed end of the metal bellows is connected to the power transmission element, which transmits the movement and force of the pressurized metal bellows to the closing unit. If the pressurized fluid is allowed to escape from the metal bellows via a control valve, the metal bellows retract again. This return movement can be generated either by the restoring forces of the metal bellows itself or preferably by an additional spring, a return spring, which counteracts the expansion of the metal bellows supported. Preferably, the spring acts on the power transmission element or the closing unit such that the closing unit closes the outlet opening when the metal bellows are not under pressure.
Vorteilhafterweise ist die Schließeinheit also auf derjenigen Seite der Auslassöffnung angeordnet, von der die Zufuhr des Dosiermediums erfolgt. Beim Schließvorgang bewegt sie sich auf die Auslassöffnung zu und sitzt dann auf deren Rand auf, um sie zu verschließen. Damit unterstützt sie den Ausstoß eines Tropfens des Dosiermediums aus der Auslassöffnung.Advantageously, the closing unit is thus arranged on that side of the outlet opening, from which the supply of the metering medium takes place. As it closes, it moves towards the outlet opening and then sits on its edge to close it. Thus it supports the ejection of a drop of the dosing medium from the outlet opening.
Da die Ausstoßgeschwindigkeit des Dosiermediums umso höher ist, je größer der Impuls ist, den die Schließeinheit beim Schließvorgang auf die Auslassöffnung ausübt, kann die Schließbewegung durch ein zusätzliches magnetisch wirkendes Element unterstützt werden. In einer Ausgestaltung der Dosiervorrichtung, die mit Druckfluid beaufschlagte Metallbälge als bewegungserzeugende Aktoren sowie eine Rückstellfeder enthält, übt das magnetisch wirkende Element eine zusätzliche Kraft auf das Kraftübertragungselement aus. Vorzugsweise wirkt diese Kraft in Schließrichtung des Schließelements. Vorzugsweise ist der Kraftverlauf des magnetisch wirkenden Elements so, dass die Kraft ansteigt, je näher das Schließelement der Schließposition kommt. Auf diese Weise kompensiert das magnetisch wirkende Element das Nachlassen der Federkraft der Rückstellfeder und entfaltet so maximale Unterstützung des Druckfluidausstoßes.Since the ejection speed of the metering medium is higher, the greater the pulse that the closing unit exerts on the outlet opening during the closing operation, the closing movement can be assisted by an additional magnetically acting element. In one embodiment of the metering device, which contains pressurized fluid loaded metal bellows as motion-generating actuators and a return spring, the magnetically acting element exerts an additional force on the force transmission element. Preferably, this force acts in the closing direction of the closing element. Preferably, the force curve of the magnetically acting element is such that the force increases, the closer the closing element comes to the closed position. In this way, the magnetically acting element compensates for the release of the spring force of the return spring and thus unfolds maximum support of the pressure fluid discharge.
In einer bevorzugten Ausführungsform weist das magnetisch wirkende Element einen oder mehrere Permanentmagneten auf.In a preferred embodiment, the magnetically acting element has one or more permanent magnets.
In einer weiteren bevorzugten Ausführungsform weist das magnetisch wirkende Element einen oder mehrere Elektromagneten auf.In a further preferred embodiment, the magnetically acting element has one or more electromagnets.
In einer weiteren bevorzugten Ausführungsform weist das magnetisch wirkende Element eine Kombination aus einem Elektro- und einem Permanentmagneten auf, wobei der Elektromagnet so angesteuert wird, dass die Kraftwirkung der Kombination jeweils nur eine, oder bei Umpolung des Elektromagneten beide Bewegungsrichtungen des Kraftübertragungselements unterstützt.In a further preferred embodiment, the magnetically acting element has a combination of an electric and a permanent magnet, wherein the electromagnet is controlled such that the force effect of the combination only supports one or, if the electromagnet is reversed, both directions of movement of the force transmission element.
Im Folgenden werden bevorzugte Ausführungsbeispiele der Erfindung an Hand der Zeichnungen beschrieben. Es zeigen:
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Fig. 1 eine schematische Schnittansicht einer erfindungsgemäßen Dosiervorrichtung vor Beginn des Dosiervorgangs, -
Fig. 2 eine schematische Schnittansicht der Dosiervorrichtung vonFig. 1 während des Dosiervorgangs mit Auslassöffnung in geöffnetem Zustand, -
Fig. 3 eine schematische Schnittansicht der Dosiervorrichtung vonFig. 1 und Fig. 2 nach Abschluss des Dosiervorgangs, -
Fig. 4 schematisch eine seitliche Schnittansicht eines Ausschnitts einer Aktoreinheit mit einer größeren Anzahl Metallbälge gemäß einer Variante der Dosiervorrichtung vonFig. 1 , -
Fig. 4a eine schematische Aufsicht auf ein Kraftübertragungselement mit vier linear angeordneten Metallbälgen gemäß einer Variante der Dosiervorrichtung vonFig. 1 , -
Fig. 4b eine schematische Aufsicht auf ein Kraftübertragungselement mit drei auf einem Kreis angeordneten Metallbälgen gemäß einer Variante der Dosiervorrichtung vonFig. 1 , -
Fig. 4c eine schematische Aufsicht auf ein Kraftübertragungselement mit vier als Rechteck angeordneten Metallbälgen gemäß einer weiteren Variante der Dosiervorrichtung vonFig. 1 , -
Fig. 5 die Weg-Kraft-Kennlinien einer Spiralfeder und eines Permanentmagneten, -
Fig. 6 eine schematische Schnittansicht einer Dosiervorrichtung mit einem zusätzlichen magnetisch wirkenden Element nach einem Ausführungsbeispiel der Erfindung, und -
Fig. 7 eine schematische Schnittansicht einer Dosiervorrichtung mit einem zusätzlichen Elektromagneten gemäß einer Variante der Dosiervorrichtung vonFig. 6 ,
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Fig. 1 a schematic sectional view of a metering device according to the invention before the start of dosing, -
Fig. 2 a schematic sectional view of the metering ofFig. 1 during the dosing process with outlet opening in the opened state, -
Fig. 3 a schematic sectional view of the metering ofFig. 1 and Fig. 2 after completion of the dosing process, -
Fig. 4 schematically a side sectional view of a section of an actuator unit with a larger number of metal bellows according to a variant of the metering device ofFig. 1 . -
Fig. 4a a schematic plan view of a power transmission element with four linearly arranged Metallbälgen according to a variant of the metering device ofFig. 1 . -
Fig. 4b a schematic plan view of a power transmission element with three arranged on a circle Metallbälgen according to a variant of the metering device ofFig. 1 . -
Fig. 4c a schematic plan view of a power transmission element with four arranged as a rectangle Metallbälgen according to another variant of the metering ofFig. 1 . -
Fig. 5 the path-force characteristics of a spiral spring and a permanent magnet, -
Fig. 6 a schematic sectional view of a metering device with an additional magnetically acting element according to an embodiment of the invention, and -
Fig. 7 a schematic sectional view of a metering device with an additional electromagnet according to a variant of the metering device ofFig. 6 .
Gleiche Elemente in den Figuren sind jeweils mit den gleichen Bezugszeichen versehen. Ausführungsbeispiele, die eine Variante eines anderen Ausführungsbeispiels sind und zu denen die Figuren speziell die Merkmale der Variante zeigen, entsprechen im Übrigen diesem anderen Ausführungsbeispiel.Identical elements in the figures are each provided with the same reference numerals. By way of example, exemplary embodiments, which are a variant of another exemplary embodiment and to which the figures specifically show the features of the variant, correspond to this other exemplary embodiment.
Solange die Bälge 4 nicht mit dem Druckfluid befüllt sind, befindet sich das Kraftübertragungselement 3 in der unteren Ausgangslage, wie in
Der nächste Schritt im Dosiervorgang ist das Befüllen der Bälge 4 mit dem Druckfluid, so dass der in
Als Druckfluid kommen grundsätzlich sowohl Flüssigkeiten als auch Gase in Betracht. Flüssige, wenig kompressible Druckfluide haben den Vorteil, dass nur kleine Volumina ein- bzw. ausströmen müssten, um einen hohen Druck im Inneren der Bälge 4 aufzubauen. Um die Druckbeaufschlagung bzw. Entlastung der Bälge so schnell wie möglich durchführen zu können, sollte allerdings die innere Reibung des Druckfluids so gering wie möglich sein. Daher sind gasförmige Druckfluide wie Luft, Stickstoff, Kohlendioxid, Wasserstoff oder andere Gase zu bevorzugen.In principle, both liquids and gases are considered as pressurized fluid. Liquid, less compressible pressure fluids have the advantage that only small volumes would have to flow in or out to build up a high pressure in the interior of the
Ein statisches Dichtelement oder eine Verschweißung, Verklebung o.ä. stellt sicher, dass die Bälge 4 dicht mit dem Aktorgehäuse 2 verbunden sind und es zu keinen Verlusten des Druckfluids an dieser Verbindungsstelle kommt. Das Abschlussstück 5 am anderen Ende des jeweiligen Balgs 4 ist ebenfalls durch ein zusätzliches Dichtelement oder eine Verschweißung, Verklebung o.ä. dicht und fest mit dem Balg 4 verbunden. Alle diese Dichtungen sind rein statisch belastet und unterliegen insbesondere keiner reibenden oder gleitenden Belastung im Betrieb.A static sealing element or a welding, gluing or similar ensures that the
Sobald zwischen Innen- und Außenraum der Bälge 4 ein positiver Differenzdruck herrscht, entsteht eine resultierende radial nach außen wirkende Kraftkomponente auf die Wandungen der Bälge 4 sowie eine Kraftkomponente in Richtung der Längsachse der Bälge 4 auf das Abschlussstück 5. Um einen möglichst großen Wirkungsgrad des Aktors zu erreichen, sollte der Balg 4 jeweils so ausgelegt sein, dass die radial nach außen wirkende Kraft nur eine geringe radiale Ausdehnung und dadurch bedingte Volumenzunahme der Bälge 4 bewirkt und im Wesentlichen nur durch die Kraft auf das Abschlussstück 5 eine gewünschte Längenzunahme des Balges 4 entlang der Längsachse erfolgt. Vorzugsweise wird dies erreicht, indem die Bälge 4 aus einem möglichst inelastischen Material wie z.B. einem Metall gefertigt werden, das einer radialen Ausdehnung entgegen wirkt. Gleichzeitig sollten die Wandungen der Bälge 4 möglichst dünn sein, damit einer Verformung entlang der Achse möglichst wenig Widerstand entgegen gesetzt wird. Auch wenn Metall wie z.B. Edelstahl das bevorzugte Material für die Bälge 4 ist und daher auch die Bezeichnung Metallbalg möglich ist, sei darauf hingewiesen, dass auch andere Materialien wie z.B. Kunststoffe in Frage kommen, insbesondere dann, wenn durch zusätzliche konstruktive Maßnahmen wie z.B. Versteifungsringe aus demselben Material wie der Wandung oder einer Kombination verschiedener Materialien außen oder innen an den Rippen der Bälge 4 eine radiale Stabilisierung vorgenommen wird.Once there is a positive differential pressure between the inner and outer space of the
Solange der Hub der Bälge 4 nicht zu groß wird, können die Bälge bei richtiger Dimensionierung einer sehr hohen Zahl von Lastwechseln standhalten, was einer nahezu unbegrenzten Lebensdauer des Aktors gleich kommt. Trotz dieser Hubbegrenzung sind die typischerweise erreichbaren Stellwege bei gleicher Dynamik und Baugröße aber um ein Vielfaches größer als die mit einem piezoelektrischen Aktor mit Hebelübersetzung erreichbaren Hübe.As long as the stroke of the
Der Außenraum der Bälge 4 ist mit der Umgebungsatmosphäre verbunden, die ggf. auch ein Vakuum oder ein Überdruck gegenüber Normalatmosphäre sein kann. Durch den weitgehend konstanten Umgebungsdruck und die gasförmige Umgebung üben die Abschlussstücke 5 der Metallbälge 4 auf das Kraftübertragungselement 3 eine definierte Kraft aus, die für eine weitgehend reibungsfreie Längung der Metallbälge 4 entlang ihrer Achse sorgt.The outer space of the
Die Abschlusstücke 5 können z.B. durch eine Verschraubung oder eine stoffschlüssige Verbindung fest mit dem Kraftübertragungselement 3 verbunden sein. Wenn allerdings wie in diesem bevorzugten Ausführungsbeispiel Vorrichtungen 7 wie z.B. Federn (Rückstellfedern) vorhanden sind, die auf das Kraftübertragungselement 3 eine Gegenkraft zu der der Bälge 4 ausüben, reicht auch eine kraftschlüssige Verbindung von Abschlussstück 5 und Kraftübertragungselement 3.The
Durch die Längung der Bälge 4 und die daraus resultierende Verschiebung des Kraftübertragungselements 3 wird die Ventilnadel 10 in Längsrichtung zurückgezogen (angehoben) und gibt den Auslasskanal 16 der Auslasseinheit 15 für den Austritt des Dosiermediums 14 frei.Due to the elongation of the
Die letzte Phase des Dosiervorganges ist in
Da der Aktor in der gerade beschriebenen Dosiervorrichtung 1 keine gleitenden Dichtelemente enthält, arbeitet er im Unterschied zum Stand der Technik reibungs- und verschleißfrei, was für eine hohe Lebensdauer und hohe Geschwindigkeiten der Ventilnadel 10 sorgt.Since the actuator contains no sliding sealing elements in the
Da außerdem die Bälge 4 nicht direkt in Kontakt mit dem Dosiermedium 14 kommen und somit die Druckräume für das Dosiermedium 14 und für die Fluide im Inneren und Äußeren der Bälge 4 konsequent von einander getrennt sind, ist die Kraft, die das Kraftübertragungselement 3 auf die Ventilnadel 10 bringt, und damit das dynamische Verhalten des Aktors im Unterschied zum Stand der Technik unabhängig vom Druck des Dosiermediums 14. Eine Dämpfung der Aktorbewegung durch hochviskose Dosiermedien tritt kaum auf. Mit der Trennung der Druckräume und der zugehörigen Viskositätsregime können somit die Verhältnisse zwischen treibenden und bremsenden Kräften optimiert werden, da für die Metallbälge 4 große Wirkquerschnitte bei geringer Reibung und für die Ventilnadel 10 kleine Querschnitte bei großer viskoser Reibung gewählt werden können. Dadurch werden die eingangs genannten hohen Geschwindigkeiten zur Dosierung von frei fliegenden Tropfen erreicht.In addition, since the
Zudem wird eine Kontamination der Aktorbälge mit dem Dosiermedium vermieden, was vorteilhaft ist, da bei Medien wie Klebstoffen, die ggf. auch in der Dosiervorrichtung teilweise aushärten können, eine Reinigung z.B. der Hinterschnitte der Bälge nahezu unmöglich wäre.In addition, a contamination of the Aktorbälge is avoided with the dosing, which is advantageous because in media such as adhesives, which may also partially cure in the metering device, a cleaning, e.g. the undercuts of the bellows would be almost impossible.
Die in
Um die beschleunigenden Kräfte auf die Ventilnadel 10 zu erhöhen, ist es notwendig, die wirksamen Kräfte der Metallbälge 4 zu erhöhen. Dies kann entweder durch eine Erhöhung des Drucks des Druckfluids erreicht werden, der aber natürliche Grenzen durch die Stabilität des Metallbalgs gesetzt sind, oder durch eine Vergrößerung der wirksamen Querschnittsfläche. Eine große Querschnittsfläche kann von einem oder wenigen großen Bälgen oder mehreren kleineren Bälgen 4 bereitgestellt werden. Mehrere kleinere Bälge 4 weisen gegenüber einem oder wenigen größeren den Vorteil auf, dass sie kompakt um den Befestigungspunkt der Ventilnadel 10 am Kraftübertragungselement 3 herum angeordnet sein können. Auch ist der Krümmungsradius der Wandung kleinerer Bälge gering und damit ihre Steifigkeit gegenüber unerwünschter radialer Ausdehnung verhältnismäßig groß. Entsprechende Varianten des Ausführungsbeispiels werden im Folgenden anhand der
Auch wenn in der bisherigen Beschreibung aus Gründen der einfacheren Herstellbarkeit immer Bälge 4 mit runden Querschnitten vorrausgesetzt wurden, sei ausdrücklich darauf verwiesen, dass eine erfindungsgemäße Dosiervorrichtung vorteilhafterweise auch mit Metallbälgen 4 mit anderen als kreisförmigen Querschnitten aufgebaut werden kann. So sind z.B. Bälge mit rechteckigen oder kreissegmentförmigen Querschnitten denkbar, um das Verhältnis zwischen Wirkfläche und Bauraum zu optimieren. Ebenso sei auch erwähnt, dass die Schnittdarstellungen in
Weiters sei auch erwähnt, dass im Rahmen dieser Erfindung Anordnungen zum Einsatz kommen können, in denen die Achsen der Metallbälge 4 untereinander und /oder zur Achse der Ventilnadel 10 nicht parallel stehen. So ist es z.B. denkbar, die Metallbälge 4 schräg zur Achse der Ventilnadel 10 zu stellen, um eine seitliche Stabilisierung des Kraftübertragungselements 3 zu erreichen.Furthermore, it should also be mentioned that in the context of this invention, arrangements can be used in which the axes of the metal bellows 4 are not parallel to one another and / or to the axis of the
Im Sinne der vorliegenden Erfindung muss das Kraftübertragungselement 3 auch nicht vollständig frei beweglich sein. Denkbar ist auch, dass das Kraftübertragungselement 3 als Hebel ausgebildet ist, der auf einer Seite über ein Gelenk, z.B. ein nicht gleitendes Festkörpergelenk, mit dem Aktorgehäuse 2 verbunden ist und auf der anderen Seite von einem oder mehreren Metallbälgen 4 bewegt wird. Abhängig davon, ob eine Verstärkung des Hubs oder eine Verstärkung der auf die Ventilnadel 10 wirksamen Kraft erreicht werden soll, kann der Befestigungspunkt der Ventilnadel 10 am Kraftübertragungselement 3, vom Gelenk aus betrachtet, jenseits des Metallbalgs 4 oder zwischen Metallbalg 4 und Gelenk angeordnet sein.For the purposes of the present invention, the
Schließlich muss auch die Schließeinheit 10 für die Auslassöffnung 16 nicht zwangsläufig die dargestellte Nadelform haben. Denkbar ist auch die Verwendung eines Druckstückes, das nur im Bereich der Auslassöffnung 16 die Kontur der Auslasseinheit 15 nachzeichnet.Finally, the
Auch wenn die obige Beschreibung davon ausgegangen ist, dass die Auslassöffnung 16 durch das Befüllen der Bälge 4 mit dem Druckfluid geöffnet und durch deren Entleeren wieder geschlossen wird, so ist auch die umgekehrte Anordnung von Balg 4 und Rückstellelement 7 denkbar. Nachteilig ist in diesem Fall zwar, dass die Auslassöffnung 16 der Dosiervorrichtung ohne anliegendes Druckfluid geöffnet ist, dafür kann aber mit einem zeitlich variablen Druck des Druckfluids während des Schließvorganges die Kraftentwicklung und damit die Beschleunigung der Ventilnadel 10 beeinflusst werden. Insbesondere kann durch kurzzeitiges Anlegen eines erhöhten Druckfluiddrucks der Schließvorgang beschleunigt werden.Even if the above description is based on the fact that the
Wie zuvor beschrieben kann der Innenraum der Bälge 4 zur Betätigung der Dosiervorrichtung mit Druckfluid befüllt werden, während der Außenraum der Bälge 4 im Wesentlichen auf konstantem Druck, vor allem auf Atmosphärendruck verbleibt. In einer anderen Variante kann umgekehrt jedoch auch innerhalb des Aktorgehäuses 2 der Außenraum der Bälge 4 mit Druckfluid befüllt werden, um die Dosiervorrichtung zu betätigen, während der Innenraum im Wesentlichen auf konstantem Druck verbleibt. Jedoch ist auch eine Variante möglich, bei der das Druckfluid durch entsprechende Durchlässe im Aktorgehäuse wechselweise in den Innenraum der Bälge 4 und in den Außenraum geleitet wird, um die Ventilnadel 10 hin und her zu bewegen. Diese Variante kann besonders schnelle Öffnungs- und Schließvorgänge auch bei hochviskosen Dosiermedien und großem Hub der Ventilnadel 10 erzielen und ist auch vorteilhaft, um den Schließvorgang zu beschleunigen und durch den Impuls der Ventilnadel 10 beim Schließvorgang das Abreißen eines Tropfens von der Auslassöffnung 16 der Auslasseinheit 15 zu begünstigen.As described above, the interior of the
Damit die Ventilnadel 10 in einer Tropfen-Dosiervorrichtung einen möglichst hohen Staudruck im Dosiermedium an der Auslassöffnung 16 erzeugt, ist es notwendig, dass die Ventilnadel im Moment des Auftreffens auf den Rand der Auslassöffnung 16 eine möglichst hohe Geschwindigkeit besitzt. Wird der Schließvorgang wie weiter oben beschrieben durch eine mechanische Feder 7 wie z.B. eine Schrauben- oder eine Tellerfeder bewerkstelligt, dann hat das zwar den Vorteil, dass die Auslassöffnung 16 der Dosiervorrichtung ohne anliegendes Druckfluid geschlossen wird, ist jedoch mit dem Nachteil behaftet, dass die Federkraft gerade dann am geringsten ist, wenn die Schließposition erreicht wird.In order for the
Dieser Zusammenhang wird aus der in
Gemäß einem weiteren Ausführungsbeispiel, das eine Variante der zuvor erläuterten Ausführungsbeispiele ist, kann dieser Nachteil der Feder 7 kompensiert bzw. sogar überkompensiert werden, indem zusätzlich zu oder sogar komplett an Stelle der mechanischen Feder 7 ein magnetisch wirkendes Element eingebaut wird. Als Beispiel ist in
Wenn die Hübe des Kraftübertragungselements 3 gering sind, kann sogar vollständig auf eine Feder 7 als Rückstellelement verzichtet werden, da dann die kurzreichweitigen magnetischen Kräfte allein ausreichen, um die Ausgangslage wieder herzustellen.If the strokes of the
Wenn nur Permanentmagnete 98 verwendet werden, bedeutet das, dass der Aktor 84 beim Öffnungshub auch die Magnetkraft überwinden muss. Günstiger ist es daher, wenn an Stelle des Permanentmagneten 98 ein Elektromagnet 118 verwendet wird, der beim Öffnungshub ausgeschaltet ist und nur beim Schließhub aktiv ist.If only
Die bevorzugten Ausführungsbeispiele weisen also folgende Aspekte auf:The preferred embodiments thus have the following aspects:
Die Dosiervorrichtung umfasst die Auslasseinheit 15 mit der Auslassöffnung 16, durch die das Dosiermedium aus der Dosiervorrichtung strömt, den Kanal 11 zur Zuführung des Dosiermediums aus einem Vorratsbehälter zur Auslasseinheit, die bewegliche Schließeinheit 10, deren eines Ende in einer ersten Position die Auslassöffnung verschließt und in einer zweiten Position die Verbindung zwischen dem Kanal zur Zuführung des Dosiermediums und der Auslassöffnung der Auslasseinheit freigibt, und eine Aktoreinheit mit dem Aktor, die die Schließeinheit zwischen den beiden genannten Positionen hin und her bewegt, wobei:
- die
Aktoreinheit ein Gehäuse 2 beinhaltet, das mit der Auslasseinheit in einer festen räumlichen Beziehung steht, - die Aktoreinheit
ein aktives Ausdehnungselement 4 beinhaltet, dessen eines Ende mit der Schließeinheit in Verbindung steht und dessen anderes Ende mit dem Gehäuse in Verbindung steht und das sich durch die Zufuhr von Energie in einer zur Schließeinheit nicht senkrechten Richtung ausdehnt, - die
Aktoreinheit ein Federelement 7 beinhaltet, das mit dem Gehäuse und der Schließeinheit in Verbindung steht und dessen Kraftwirkung der zur Schließeinheit nicht senkrechten Ausdehnung des aktiven Ausdehnungselements entgegen wirkt, und - die Aktoreinheit zusätzlich ein magnetisch wirkendes
98, 99, 118 beinhaltet, das mit dem Gehäuse und der Schließeinheit in Verbindung steht und dessen magnetische Kraftwirkung eine Komponente parallel zur Ausdehnungsrichtung des aktiven Ausdehnungselements besitzt.Element
- the actuator unit includes a
housing 2 in a fixed spatial relationship with the outlet unit, - the actuator unit includes an
active expansion element 4 having one end communicating with the closing unit and the other end communicating with the housing and extending through the supply of energy in a direction not perpendicular to the closing unit, - the actuator unit includes a
spring element 7, which is in communication with the housing and the closing unit and whose force acts counter to the non-perpendicular to the closing unit expansion of the active expansion element, and - the actuator unit additionally includes a magnetically acting
98, 99, 118, which is in communication with the housing and the closing unit and whose magnetic force has a component parallel to the extension direction of the active expansion element.element
Vorteilhafterweise beinhaltet das magnetisch wirkende Element einen Permanentmagneten.Advantageously, the magnetically acting element includes a permanent magnet.
Eine Komponente der magnetischen Kraft des magnetisch wirkenden Elements wirkt der Ausdehnung des aktiven Ausdehnungselements 4entgegen und lässt nach, je weiter sich das aktive Ausdehnungselement in der zur Schließeinheit nicht senkrechten Richtung ausdehnt.A component of the magnetic force of the magnetically acting element counteracts the expansion of the
Das magnetisch wirkende Element kann auch einen Elektromagneten beinhalten. Der Elektromagnet wird zeitlich variabel bestromt und die Polrichtung der Bestromung wird so gewählt, dass seine Kraftwirkung eine Komponente parallel zum Öffungshub und/oder zum Schließhub des Ausdehnungselements 4 enthält.The magnetically acting element may also include an electromagnet. The electromagnet is energized variable in time and the polar direction of the energization is chosen so that its force effect contains a component parallel to the Öffungshub and / or the closing stroke of the
Claims (8)
- A metering apparatus for dispensing a liquid medium to be metered, comprising
an outlet unit (15) having an outlet opening (16) for dispensing the medium from the metering apparatus,
a movable closing unit (10) which can assume positions for closing and for unblocking the outlet opening, and
an actuator (2, 3, 4, 7, 84) having an actuator housing (2), a bellows (4) which is disposed therein and has its one end tightly connected to the actuator housing and its other end hermetically sealed by a movable end piece which is connected to the closing unit, and a passage (6) in the actuator housing through which a pressure difference between the interior and exterior of the bellows can be applied by a pressure fluid, whereby the bellows (4) extends or contracts and moves the end piece and the closing unit back and forth between said positions,
characterised in that
the actuator housing (2) encloses the bellows (4) such that the interior and exterior of the bellows are kept free from the medium to be metered, and
the closing unit extends from its connection with the end piece (5) through a sealing member (12) and out of the actuator housing to the outlet opening (16) of the outlet unit (15). - A metering apparatus in accordance with claim 1, wherein
said bellows (4) is one of a plurality of bellows of the actuator which are arranged next to each other and each have one end tightly connected to the actuator housing and their other end hermetically sealed by a movable end piece,
the movable end pieces (5) of the plurality of bellows (4) are coupled to each other by a force transfer member (3), and
said closing unit (10) is connected to the force transfer member (3) at the balance point of the forces exerted from the bellows (4) to the force transfer member (3). - A metering apparatus in accordance with claim 2, wherein said plurality of bellows (4) are arranged to surround the connection of the closing unit (10) to the force transfer member (3), and said closing unit (10) is disposed between the bellows in said exterior space of the bellows.
- A metering apparatus in accordance with any of claims 1 to 3, wherein
the actuator comprises a spring (7) connected to the actuator housing (2) and disposed such that its spring force counteracts against movement of the closing unit (10) into the position for unblocking the outlet opening (16). - A metering apparatus in accordance with any of claims 1 to 4, wherein
the passage (6) is connected to the interior of each bellows (4), and the bellows (4), when being filled with the pressure fluid, move the closing unit (10) to the position for unblocking the outlet opening (16). - A metering apparatus in accordance with any of claims 1 to 5, wherein
a first said passage (6) in the actuator housing (2) is connected to the interior of each bellows (4) and a second passage in the actuator housing (2) is connected to the exterior space of the bellows within the actuator housing, so that the bellows (4) extends or contracts in accordance with the pressure difference between a first pressure fluid guided through the first passage and a second pressure fluid guided through the second passage, and thereby moves the closing unit (10) back and forth between said positions. - A metering apparatus in accordance with any of claims 1 to 6, wherein
the actuator comprises a magnet (98, 118) which generates a force that supports movement of the closing unit (10) into the position for closing the outlet opening (16). - A method for dispensing a liquid medium to be metered from a metering apparatus in accordance with any preceding claim, in which there is a pressure difference applied between the interior and the exterior of the bellows (4) by means of the pressure fluid, and the closing unit (10) is moved back and forth between said positions for closing and for unblocking the outlet opening (16), wherein
the closing unit (10) is moved to said position for closing the outlet opening (16) so quickly that the medium to be metered is given an impulse by which a free droplet of the medium breaks away from the outlet opening (16).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013006106.7A DE102013006106A1 (en) | 2013-04-09 | 2013-04-09 | metering |
PCT/EP2014/057216 WO2014167033A2 (en) | 2013-04-09 | 2014-04-09 | Metering apparatus |
Publications (2)
Publication Number | Publication Date |
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EP2945754A2 EP2945754A2 (en) | 2015-11-25 |
EP2945754B1 true EP2945754B1 (en) | 2017-03-15 |
Family
ID=50473313
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14716327.3A Active EP2945754B1 (en) | 2013-04-09 | 2014-04-09 | Metering apparatus |
Country Status (3)
Country | Link |
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EP (1) | EP2945754B1 (en) |
DE (1) | DE102013006106A1 (en) |
WO (1) | WO2014167033A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105772333A (en) * | 2016-05-09 | 2016-07-20 | 禹伟 | High-pressure dispensing head of long-travel automatic dispensing machine |
DE102017126307A1 (en) | 2017-11-09 | 2019-05-09 | Delo Industrie Klebstoffe Gmbh & Co. Kgaa | Dosing device and method for dosing of liquid media |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL299526A (en) | 1962-10-19 | |||
DE2553163A1 (en) | 1975-11-27 | 1977-06-02 | Ver Flugtechnische Werke | Remotely operated valve for cryogenic material - has sealing bellows to keep liq. gas separate from working mechanism |
CH615987A5 (en) * | 1976-07-23 | 1980-02-29 | Sulzer Ag | Injection valve for a turbocharger-washing device |
DE3146030A1 (en) * | 1981-11-20 | 1983-05-26 | Siemens AG, 1000 Berlin und 8000 München | PRESSURE VALVE FOR CONTAINERS |
US4509057A (en) * | 1983-03-28 | 1985-04-02 | Xerox Corporation | Automatic calibration of drop-on-demand ink jet ejector |
DE3600009A1 (en) * | 1986-01-02 | 1987-07-09 | Jaeth Michael | Device for the contact-free application of elastic viscous substances |
US4803393A (en) * | 1986-07-31 | 1989-02-07 | Toyota Jidosha Kabushiki Kaisha | Piezoelectric actuator |
SE456727B (en) * | 1987-03-11 | 1988-10-31 | Inst Verkstadstek Forsk Ivf | DEVICE FOR PROMOTING AND APPLYING A VISUAL SUBSTANCE |
CH678754A5 (en) * | 1988-03-22 | 1991-10-31 | Bechtiger Edelstahl | Valve arrangement for flow pipe - has valve plate and seating, with at least one sprung pipe |
ATE116908T1 (en) | 1989-10-10 | 1995-01-15 | Xaar Ltd | PRINTING PROCESS WITH MULTIPLE TONES. |
JPH06129563A (en) * | 1992-10-16 | 1994-05-10 | Toyota Motor Corp | Elector valve |
CH689735A5 (en) * | 1994-05-09 | 1999-09-30 | Balzers Hochvakuum | Vacuum valve. |
EP1437192A3 (en) * | 1995-11-16 | 2005-06-08 | Nordson Corporation | Method and apparatus for dispensing small amounts of liquid material |
US6715506B1 (en) * | 1998-12-28 | 2004-04-06 | Musashi Engineering, Inc. | Method and device for injecting a fixed quantity of liquid |
DE19940055C1 (en) * | 1999-08-24 | 2001-04-05 | Siemens Ag | Dosing valve |
DE20220800U1 (en) | 2002-10-24 | 2004-04-08 | Vermes Technik Gmbh & Co. Kg | Positioning system with piezoactuator has links between piezoactuator and transmission lever provided as rolling butt contact forming line contact and transmission lever is preloaded by spring |
US7789325B2 (en) * | 2007-01-23 | 2010-09-07 | Spraying Systems Co. | Air atomizing spray nozzle with magnetically actuated shutoff valve |
US7871058B2 (en) * | 2007-07-25 | 2011-01-18 | Illinois Tool Works Inc. | Dual inline solenoid-actuated hot melt adhesive dispensing valve assembly |
ES2553749T7 (en) * | 2011-07-22 | 2024-04-23 | Durst Group Ag | Print head for an inkjet printer |
-
2013
- 2013-04-09 DE DE102013006106.7A patent/DE102013006106A1/en not_active Withdrawn
-
2014
- 2014-04-09 EP EP14716327.3A patent/EP2945754B1/en active Active
- 2014-04-09 WO PCT/EP2014/057216 patent/WO2014167033A2/en active Application Filing
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DE102013006106A1 (en) | 2014-10-09 |
EP2945754A2 (en) | 2015-11-25 |
WO2014167033A3 (en) | 2015-01-08 |
WO2014167033A2 (en) | 2014-10-16 |
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