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EP2884162A1 - Fluidized bed heat exchanger - Google Patents

Fluidized bed heat exchanger Download PDF

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Publication number
EP2884162A1
EP2884162A1 EP13197364.6A EP13197364A EP2884162A1 EP 2884162 A1 EP2884162 A1 EP 2884162A1 EP 13197364 A EP13197364 A EP 13197364A EP 2884162 A1 EP2884162 A1 EP 2884162A1
Authority
EP
European Patent Office
Prior art keywords
fluidized bed
chamber
heat exchanger
solid particles
heat transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13197364.6A
Other languages
German (de)
French (fr)
Inventor
Damian Goral
Klaus-Dieter Pohl
Oguzhan Narin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Doosan Lentjes GmbH
Original Assignee
Doosan Lentjes GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Doosan Lentjes GmbH filed Critical Doosan Lentjes GmbH
Priority to EP13197364.6A priority Critical patent/EP2884162A1/en
Priority to CN201480063961.5A priority patent/CN105723152A/en
Priority to PCT/EP2014/067488 priority patent/WO2015090636A1/en
Priority to US15/038,641 priority patent/US20160356488A1/en
Priority to ARP140104207A priority patent/AR098354A1/en
Publication of EP2884162A1 publication Critical patent/EP2884162A1/en
Priority to HK16111171.0A priority patent/HK1224000A1/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/02Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K5/00Plants characterised by use of means for storing steam in an alkali to increase steam pressure, e.g. of Honigmann or Koenemann type
    • F01K5/02Plants characterised by use of means for storing steam in an alkali to increase steam pressure, e.g. of Honigmann or Koenemann type used in regenerative installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus
    • F22B31/0007Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed
    • F22B31/0084Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed with recirculation of separated solids or with cooling of the bed particles outside the combustion bed
    • F22B31/0092Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed with recirculation of separated solids or with cooling of the bed particles outside the combustion bed with a fluidized heat exchange bed and a fluidized combustion bed separated by a partition, the bed particles circulating around or through that partition
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D13/00Heat-exchange apparatus using a fluidised bed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0041Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for only one medium being tubes having parts touching each other or tubes assembled in panel form
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/08Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being otherwise bent, e.g. in a serpentine or zig-zag
    • F28D7/082Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being otherwise bent, e.g. in a serpentine or zig-zag with serpentine or zig-zag configuration
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/0265Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits by using guiding means or impingement means inside the header box
    • F28F9/0268Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits by using guiding means or impingement means inside the header box in the form of multiple deflectors for channeling the heat exchange medium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/22Arrangements for directing heat-exchange media into successive compartments, e.g. arrangements of guide plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00Fluidised bed combustion
    • F23C2206/10Circulating fluidised bed
    • F23C2206/103Cooling recirculating particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/22Arrangements for directing heat-exchange media into successive compartments, e.g. arrangements of guide plates
    • F28F2009/222Particular guide plates, baffles or deflectors, e.g. having particular orientation relative to an elongated casing or conduit
    • F28F2009/226Transversal partitions

Definitions

  • the invention relates to so-called Circulating Fluidized Bed Apparatus (CFBA) and its components, in particular
  • CFBA Circulating Fluidized Bed Apparatus
  • the aerated particulate material/fuel mixture allows to promote the incineration process and effectivity.
  • the incineration charge is fluidized by the air/gas, often blown in via nozzles.
  • the fluidized bed comprises a so-called denseboard area, above said grate and adjacent to the said permeable reactor bottom, while the density of the particulate material within the fluidized bed gets less within the upper part of the reactor space, also called the freeboard area of the fluidized bed.
  • the reaction chamber is often limited by outer water tube walls, made of tubes, through which water runs, wherein said tubes are either welded directly to each other to give a wall structure or with fins/ribs between parallel running tube sections.
  • the CFBR typically has at least one outlet port at its upper end, wherein said outlet port allows the mixture of gas and solid particles exhausted from the reactor, to flow into at least one associated separator.
  • the invention provides the following improvements with respect to a Circulating Fluidized Bed Apparatus, hereinafter also called CFBA, fluidized bed apparatus or apparatus and its components, which may be realized individually or in arbitrary combinations as far those combinations are not explicitly excluded hereinafter or excluded by technical reasons. Accordingly individual construction features may be realized individually and/or in arbitrary combinations. Different embodiments may be realized within one apparatus if proper. Accordingly features, disclosed in connection with one of the following improvements may also be realized in connection with another improvement.
  • CFBA Circulating Fluidized Bed Apparatus
  • Fluidized bed apparatus comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the circulating fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger and return means to transport at least part of the solid particles back into the circulating fluidized bed reactor, wherein the circulating fluidized bed reactor, the separator and the fluidized bed heat exchanger are mounted in a suspended manner.
  • the totally suspended (for example hanging) construction allows to adapt the thermal expansions of the associated construction elements and avoids mechanical forces, thermo-mechanical forces and/or moments between adjacent construction parts.
  • Improvement B refers to a:
  • Fluidized bed apparatus comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into a number (n) of associated separators for separating solid particles from said gas, a number (n) of means to transfer said separated solid particles from said (n) separators into a number (up to n) of discrete fluidized bed heat exchangers, and return means to transport at least part of said solid particles back from said discrete fluidized bed heat exchangers into the circulating fluidized bed reactor, wherein the number (up to n) of discrete fluidized bed heat exchangers are mechanically connected to provide one common fluidized bed heat exchanger with water cooled intermediate walls between adjacent discrete fluidized bed heat exchangers.
  • each separator is followed by one heat exchanger (with a syphon like seal in between), while the improvement reduces the number of construction parts insofar as at least two, or three, or all (namely n) heat exchangers are combined into one element.
  • Cooling means water cooled walls
  • Fluidized bed heat exchanger with a chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means arranged within said chamber, wherein the heat transfer means is designed in a wall-like pattern and extending substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port.
  • the wall like structure (a flat and compact design of an individual heat transfer means) in combination with its orientation are the main features, allowing to arrange a group (set) of multiple heat transfer means at a distance to each other with channels like "cavities/gaps" in between, extending as well in the flow/transport direction of the solid particles towards the outlet area of the chamber.
  • wall like does not refer to a cubic design with flat surfaces but the overall volume which the respective heat transfer means take.
  • a tube, meandering (zig-zag) such that the central longitunal axis of the tube lies in one imaginary plane is an example for a wall-like pattern.
  • Tube sections may extend in different directions along two axis of the coordinate system.
  • This design allows the solid particles within the fluidized bed to flow between said individual heat transfer means, namely within said spaces (channels) formed between adjacent heat transfer means, without any obstacles (baffles) but including the option to flow from one of said channels/spaces/gaps into an adjacent one.
  • Fluidized bed heat exchanger with one chamber comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least two heat transfer means within said one chamber, each being provided with a heat transfer medium inlet port and a heat transfer medium outlet port, wherein a first heat transfer means is designed as a reheater and second heat transfer means is designed as a superheater to achieve a heat transfer medium pressure above that of the reheater.
  • This design is best realized with at least two distinct groups/sets of heat transfer means to provide different thermodynamic features within the FBHE and to allow to optimize the heat transfer and efficiency of the FBHE.
  • All heat transfer means for example distinct steam tubes
  • All heat transfer means may be linked to one central steam feeding line and steam outlet line respectively. Insofar the extra work for installation is reduced to one further feeding and extracting line, in case of two groups of heat exchangers, while allowing to achieve different thermodynamic conditions within the chamber.
  • Fluidized bed apparatus comprising a circulating fluidized bed reactor of a vertical axial length L in its functional position, with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger and return means to transport at least part of said the solid particles back into the fluidized bed reactor, wherein the return means are designed such that their lowermost point enters into the fluidized bed reactor at a minimum height of 0,1 L, calculated from the lowermost end of said axial length (L) of the fluidized bed reactor in its functional position.
  • This design gives an optimized return position for the solid particles back into the CFBR.
  • the minimum distance between the bottom area of the CFBR and the place, where the solid particles enter the CFBR, guarantees that the solid particles may freely enter the combustion chamber (the fluidized bed) and avoids any backflow from the fluidized bed, especially from the denseboard ( high pressure zone) of the fluidized bed, being the lowermost section of the fluidized bed, right above the aerated/pressurized bottom.
  • FBHE does not require any complex sealing systems along the return means/outlet port.
  • the length L of the CFBR is defined as the distance between the upper surface of the aerated bottom (grate-/nozzle area) and the inner surface of the chamber ceiling.
  • Yet another improvement (F) relates to a :
  • Fluidized bed heat exchanger with a chamber comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means, arranged within said chamber, wherein at least one distribution means being arranged in a transition region between said inlet port and said chamber and upstream of said heat transfer means to allow dilution of said solid particles.
  • This improvement relates to feeding of the particulate material into the fluidized bed heat exchanger (FBHE).
  • FBHE fluidized bed heat exchanger
  • the FBHE (its inner chamber/space) typically has a cubic or cylindrical shape of high volume.
  • the improvement allows to distribute the solid particles on their way into the chamber over a much larger area, depending on the shape and size of the distribution means. At the same time the density of the solids within the particle stream is reduced, which further increases the heat transfer efficiency from the hot particles into the heat transfer medium (a brine, steam or the like).
  • the heat transfer medium a brine, steam or the like.
  • transition region includes the end section of the inlet port adjacent to the chamber of the FBHE as well the adjacent section of the chamber and any area in between.
  • Improvement G refers to a design with a common wall between the CFBR and FBHE, namely a
  • Fluidized bed apparatus comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger as well as return means to transport at least part of said solid particles back into the circulating fluidized bed reactor, wherein the said circulating fluidized bed reactor and said fluidized bed heat exchanger have at least one common wall and said return means are provided within said common wall.
  • the integration of the return means allows further reductions in construction work, material costs and increases the efficiency.
  • the material flow from the FBHE into the combustion reactor becomes more reliable and more homogeneous.
  • Optional feature to this improvement include:
  • a further improvement H relates to a:
  • Fluidized bed heat exchanger with a chamber comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means, arranged within said chamber, wherein said means for introducing the fluidizing gas are provided by a multiplicity of nozzles arranged along the bottom area of said chamber and different nozzles being charged with different gas pressure.
  • the aerated bottom (the air/gas permeable bottom as part of the fluidized bed) is divided into sections/zones/areas, where air is applied under different pressure. This allows to provide a custom-made pressure profile within the FBHE and thus to optimize the heat transfer and particle transport.
  • a multiplicity of air openings mostly provided by air nozzles, can be linked to a common air feeding duct or funnel.
  • a similar design may be used for a syphon arranged between separator and CFBR according to the following improvement I:
  • the overall design of said syphon, serving as a gas seal between components of the fluidized bed apparatus connected upstream and downstream of said syphon, is similar to that of the fluidized bed heat exchanger as disclosed above. The main difference is, that the syphon does not necessarily comprise any heat transfer means.
  • a first nozzle set blows air in a counterflow to the solid particles into the entrance port
  • a second nozzle set provides nozzles which blow air/gas into the mostly horizontally oriented stream of solid particles along the intermediate section while a third nozzle set blows air into the solid particles leaving the syphon via the exit port, wherein air/gas and solid particles have the same transport direction along this exit section.
  • Improvement K relates to a:
  • This at least one baffle does not influence the flow of the solid particles within the part of the FBHE equipped with the heat transfer means as it is arranged above said heat transfer means and only serves to redirect the incoming solid particle stream (downwardly) and to equalize the pressure above the fluidized bed and along the horizontal cross section of the chamber, in particular, if provided with opening(s).
  • the baffles have the function of separation walls and avoid short circuits of the solid material flow (directly from the inlet port to the outlet port). They urge the solid particle stream to penetrate into the heat transfer zone between the heat transfer means (the channels mentioned above).
  • the baffle construction may interact with improvement H.
  • Figure 1 discloses the general concept of a fluidized bed apparatus and its main components according to the present invention.
  • the invention includes one or more of the following features:
  • the fluidized bed heat exchanger 24 displays an inlet port 22 at its upper end (in Figure 2 : top left) and an outlet port 30 at its upper end (in Figure 2 : top right), i. e. opposite to each other.
  • Said outlet port 30 provides return means for solid particles transported along transfer duct 20 into said FBHE and is provided within a common wall 14w of chamber 14 and FBHE 24.
  • Outlet port 30 comprises multiple flow through openings, arranged in a horizontal row with a distance to each other along a corresponding wall section of said wall 14w.
  • Said wall 14w is water-cooled, namely constructed of vertically extending tubes with fins running between adjacent tubes.
  • the tubes are cooled by water fed through said tubes.
  • the through holes having the function of discrete outlet ports are shown in Figure 2 in a slightly inclined orientation, with a lower end towards the fluidized bed heat exchanger 24 and a higher end towards the fluidized bed reactor chamber 14.
  • This inclined orientation can be provided as part of a 3-dimensional profile (for example as a convexity 14w') of said wall 14w towards the inner space/chamber of the fluidized bed heat exchanger 24 as shown in dotted lines in Figure 2 and characterized by numeral 30'.
  • FIG 2 further shows the design and construction of heat transfer means 28 within the fluidized bed heat exchanger 24. In the Figure only one of said heat transfer means is shown. Further heat transfer means of equal design are placed at a distance to each other within FBHE 24 (perpendicular to the plane of projection).
  • each of said means 28 is designed in a wall-like pattern and extending substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port 30, symbolized in Figure 2 by arrow S.
  • All tubes 28 are connected to the same feeding line 42 and outlet line 44.
  • the meandering tubes not only give the heat transfer means 28 a wall-like pattern but as well a grid-like structure to allow the particulate material to pass through as well in a horizontal direction.
  • the horizontally extending sections of said tubes are about three times longer than the vertically extending sections ( Figure 2 is not drawn to scale). Adjacent horizontal sections extent to a distance to each other being about the tube diameter.
  • the heat transfer means 28 extent about more than 60 % of the chamber height, being the distance between a chamber bottom 24b and a chamber sealing 24c.
  • each of said wall-like heat transfer means 28 extends from slightly above bottom 24b to slightly below inlet port 22 and from slightly off wall 14w to slightly off opposite wall 24w.
  • the particulate material may take a direct way from the inlet port 22 to the outlet port 30 (see arrow S) along the channels/gaps C formed between adjacent tubes (heat transfer means), as may be seen in Figure 3 .
  • Fluidization of the particulate material within FBHE 24 is achieved by air nozzles 46 in the bottom area 24b.
  • the particulate material is circulated by said purging means within FBHE 24 in order to optimize heat transfer from the hot solid particles P onto the steam flowing within tube like heat transfer means 28.
  • FIG. 4 differs from that of Figures 2 , 3 insofar as two baffles 50, 52 extent from sealing 24c downwardly, ending shortly above heat transfer means 28. These baffles 50, 52 extend substantially perpendicular to a straight line between inlet port 22 and outlet port 30 (dotted line L).
  • Both baffles 50, 52 extend between opposite walls of FBHE 24 (only one, namely 24s is shown), being the walls bridging said walls 14w, 24w.
  • the baffles 50, 52 are arranged at a distance to each other.
  • Each of said baffles 50, 52 comprise one opening symbolized by dotted line O to allow pressure adjustment (equalization) within the inner space of FBHE 24.
  • the said baffle(s) 50, 52 may as well be designed like a curtain, fulfilling the same function as a continuous board, namely to urge the particulate material to flow through said channels C ( Figure 3 ) between adjacent heat transfer means 28 on their way between inlet port 22 and outlet port 30.
  • outlet port 30 is extended, namely protruding into circulating fluidized bed reactor 10.
  • multiplicity of heat transfer means 28 is split into two groups.
  • a first group G1 is made of a number of heat transfer means 28 as shown in Figures 2 , 3 with the exception that the horizontal extension between walls 24w, 14w is much shorter and ending about half the way between said walls 14w, 24w.
  • This group G1 of multiple heat transfer tubes 28 connected to a common feeding line 42 and a common outlet line 44 is characterized by a feeding temperature of 480°C and an outlet temperature of 560°C of the heat transfer medium (steam) and an average steam pressure of 32 bar, thus fulfilling the function of a so called reheater.
  • the second group G2 of several heat transfer means 28 is constructed the same way as group G1 but connected so separate inlet lines 42' and outlet lines 44' for said steam and designed to achieve a heat transfer medium temperature of between 510°C (inlet temperature) and 565°C (outlet temperature) as well as an average 170 bar pressure.
  • tubes of group G2 are arranged closer to the outlet port 30 and adjacent to wall 14w while tubes of group G1 are arranged adjacent to wall 24w with a distance between groups G1 and G2.
  • Figure 6 is a top view of Figure 5 along line 6-6 in Figure 5 .
  • the fluidized bed heat exchanger 24 displays a different design around inlet port 22, which widens towards the inner space of chamber 24, wherein said widened section 22w is further inclined towards the bottom area 24b of FBHE 24 to provide a distributor means allowing the entering stream of solid particles to spread over substantially the full width of said inner space of chamber 24, wherein the width is defined by the distance of side wall 24s.
  • This distributor means (section 22s) are arranged in a transition region defined by end section of inlet port 22 and the adjacent section of chamber 24, extending upstream of said heat transfer means 28 and extending over about 2/3 of the chamber width.
  • Ribs 22r protrude from the surface of said distributor 22s and are arranged in a star-like pattern.
  • Figure 8a displays an FBHE 24 characterized by a modified bottom area 24b.
  • Each nozzle comprises an outer end 46o, protruding downwardly from the outer surface of bottom 24b and an inner end 46i, protruding into the hollow space of FHBE 24 equipped with groups G1, G2 of heat exchange tubes 28.
  • the nozzles 46 are assembled into five nozzle sets N1, N2, N3, N4 and N5, one behind the other in a row between walls 24w and 14w. All nozzles 46 of a nozzle set are commonly connected to a respective common gas channel 48. If air is fed along one of these channels all corresponding nozzles 46 will be activated to allow air to enter into FBHE 24.
  • discrete nozzle sets N1...N5 with discrete channels 48 make it possible to set different air pressure in different channels and accordingly to introduce air into the fluidized bed of solid particles within FBHE under different pressure at different areas to optimize homogenisation of the particles within the fluidized bed.
  • a similar design may be used to improve the syphon-type seal 26 between separator 18 and FBHE 24 or reactor 10 respectively, as illustrated in Fig. 8b .
  • the multiplicity of air nozzles 27 is split into three nozzles sets SN1, SN2 and SN3, each with a certain number of nozzles 27, and each coupled to a respective air duct D1, D2 and D3, feeding air to the respective nozzles 27 under same or different pressure.
  • the air ducts D1..D3 have a funnel shape at their upper ends.
  • Figure 9 represents a fluidized bed apparatus wherein its main components, namely the CFBR 10, the FBHE 24 as well as corresponding separators 18 are mounted in a suspended manner to a central supporting structure, namely a frame 60.
  • the frame 60 has the shape of an inverted U with its legs 60l fixed within ground GR.
  • the FBHE 24 is mounted in a suspended manner from separator 18.
  • the fluidized bed heat exchanger has no refractory lining; all walls are water cooled metal walls.
  • the hanging structure allows an integration of a syphon 26 with its return duct 26r without transferring mechanical forces or moments between the respective construction parts.
  • the lowermost point LP1 of outlet port 30 of fluidized bed heat exchanger 24 enters the circulating fluidized bed reactor 10 at a height of >0,15L, calculated from the lowermost end of the axial length L of CFBR 10.
  • the lowermost end is defined by grate 12 of the fluidized bed.
  • the minimum distance of >0,1L, better >0,2L allows to place the return means 30 out of the so called denseboard DB and avoids the risk of any backflow of solid particles from the fluidized bed within reactor 10 into the associated construction elements like FBHE 24.
  • This feature may be combined with sloped outlet ports 30 as disclosed in Figure 2 or sloped return ducts 26r.
  • the lowermost point of return duct 26r of syphon 26 enters the CFBR at a height of the denseboard DB, close to grate 12 and below outlet port 30.
  • Figure 10 discloses an embodiment with three corresponding fluidized bed heat exchangers 24.1, 24.2, 24.3 which are mechanically connected to provide one common fluidized bed heat exchanger 24 of corresponding, suitable size, with water-cooled intermediate walls 24i. Again: all three wall sections 14w of the common heat exchanger 24 are part of the reactor wall 14, i.e. a common water-cooled wall with integrated outlet openings 30.
  • Walls 14i, 14w are made of metal tubes, welded to each other and connected with a fluid source to feed cooling water through said tubes.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Dairy Products (AREA)

Abstract

A fluidized bed heat exchanger with a chamber (24) comprises a solid particles inlet port (22), a solid particles outlet port (30), arranged at a distance to the inlet port (22), means (46) for introducing a fluidizing gas from a bottom area into the chamber (24). The heat exchanger has furthermore several heat exchange tubes (28) being arranged at a distance to each other. The heat exchange tubes (28) are each arranged in a meandering fashion and a wall-like pattern and extend substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port (30).

Description

  • The invention relates to so-called Circulating Fluidized Bed Apparatus (CFBA) and its components, in particular
    • a Circulating Fluidized Bed Reactor (CFBR) designed as a combustor, incineration reactor, boiler, gasifier, steam generator etc. as disclosed - i.a. - in US 6,802,890 B2 . In a typical CFBR gas (air) is passed through a permeable grate-like bottom area of the reactor, which grate (grid) supports a fluidized bed of particulate material, the so-called incineration charge, mostly including a fuel-like material such as coal. This gives the fuel material and other components within the fluidized bed the behaviour of a boiling liquid.
  • The aerated particulate material/fuel mixture allows to promote the incineration process and effectivity.
  • The incineration charge is fluidized by the air/gas, often blown in via nozzles. The fluidized bed comprises a so-called denseboard area, above said grate and adjacent to the said permeable reactor bottom, while the density of the particulate material within the fluidized bed gets less within the upper part of the reactor space, also called the freeboard area of the fluidized bed.
  • The reaction chamber is often limited by outer water tube walls, made of tubes, through which water runs, wherein said tubes are either welded directly to each other to give a wall structure or with fins/ribs between parallel running tube sections.
  • As most of said fuel materials like coal, timber etc. contain sulphur and/or harmful substances it is necessary to clean the gases leaving the reaction chamber, in a suitable way.
  • The CFBR typically has at least one outlet port at its upper end, wherein said outlet port allows the mixture of gas and solid particles exhausted from the reactor, to flow into at least one associated separator.
    • The separator, for example a cyclone separator, serves to separate solid particles (the particulate material, including ash) from said gas. A typical design of such a separator is disclosed in US 4,615,715 . Again the outer walls of the separator can be designed with hollow spaces to allow water flowing through.
    • Means for the transfer of said separated solid particles into at least one Fluidized Bed Heat Exchanger (FBHE) via a corresponding inlet port of said FBHE. These means may be ducts/pipes/channels or the like.
    • A syphon along the way from the separator to the CFBR and/or FBHE to allow decoupling of pressure (fields) between separator and CFBR.
    • At least one Fluidized Bed Heat Exchanger (FBHE) allowing to use the heat, provided by the particulate material, for generating power, for example to heat up and increase the pressure of a steam transported as a heat transfer medium via tubes or the like, through said FBHE and further to turbines or the like.
    • The FBHE is equipped with at least one outlet port, also called return means, for at least part of the solid particles on their way out of the FBHE and back into the Circulating Fluidized Bed Reactor CFBR.
  • Numerous designs of such apparatus and components have been developed over the past decades.
  • Nevertheless there is a continuous demand for improvements, especially with respect to energy efficiency (typical capacity range: 50-600MW - electrical -), effectiveness, simple construction, avoidance of mechanical and thermo-mechanical stresses, compactness (typical data of a reactor chamber are: height:30-60m, width: 13-40m, depth: 15-40m).
  • The invention provides the following improvements with respect to a Circulating Fluidized Bed Apparatus, hereinafter also called CFBA, fluidized bed apparatus or apparatus and its components, which may be realized individually or in arbitrary combinations as far those combinations are not explicitly excluded hereinafter or excluded by technical reasons. Accordingly individual construction features may be realized individually and/or in arbitrary combinations. Different embodiments may be realized within one apparatus if proper. Accordingly features, disclosed in connection with one of the following improvements may also be realized in connection with another improvement.
  • Improvement A refers to a
  • Fluidized bed apparatus, comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the circulating fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger and return means to transport at least part of the solid particles back into the circulating fluidized bed reactor, wherein the circulating fluidized bed reactor, the separator and the fluidized bed heat exchanger are mounted in a suspended manner.
  • The totally suspended (for example hanging) construction allows to adapt the thermal expansions of the associated construction elements and avoids mechanical forces, thermo-mechanical forces and/or moments between adjacent construction parts.
  • Different thermal loads within the CFBR and an associated FBHR typically lead to different thermal expansions of both construction elements (parts of the apparatus). Accordingly return means (for the solid particles), for example a solid return duct, extending from the FBHR to the CFBR, typically undergoes considerable thermo-mechanical stresses, which now can be avoided.
  • This is contrary to prior art devices with a suspended reactor, a heat exchanger mounted to ground and a return duct in between.
  • Optional features are:
    • The circulating fluidized bed reactor, the separator and the fluidized bed heat exchanger are suspended from a supporting structure, which may be a common supporting structure, for example a tripod like or a gateway-like structure, a frame etc.. The suspended mounting may be realized directly or indirectly.
    • The fluidized bed heat exchanger is suspended from the separator. This is an example for an indirect suspension/hanging. The separator may be suspended from a traverse/bar, while the FBHE is suspended from the separator.
    • The fluidized bed heat exchanger is fixedly secured to the circulating fluidized bed reactor. Again this is an indirect type of suspension. The FBHE is coupled to the CFBR, which itself may be hung to a corresponding frame.
    • The fluidized bed heat exchanger and the fluidized bed reactor have a common wall. This gives a compact design and saves one wall.
    • The common wall is water-cooled.
    • The common wall has one or more openings fulfilling the function of the return means or the function of an outlet port for the solid particles respectively. A separate outlet port (for example a duct) may be avoided.
    • The return means are designed as a coupling without transferring mechanical forces or moments from said fluidized bed reactor into said fluidized bed heat exchanger or vice versa. This embodiment in-situ provides a suspended connection between the two construction parts and avoids any mechanical stresses.
    • The fluidized bed heat exchanger has no refractory lining. This makes is lighter and thus easier to hang.
    • The fluidized bed heat exchanger has chamber walls being at least partially water-cooled.
    • No structural means within the FBHE, which tend to urge the solid particles to meander within the fluidized bed heat exchanger. Contrary to common designs the FBHE does not provide any separate entrance chamber and/or return chamber through which the solid particles must pass after entering the FBHE and/or before leaving it. No pre-homogenization of the solid particles being necessary any more. The solid particle stream enters the FBHE and is immediately directed through/along the heat exchangers.
    Improvement B refers to a:
  • Fluidized bed apparatus, comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into a number (n) of associated separators for separating solid particles from said gas, a number (n) of means to transfer said separated solid particles from said (n) separators into a number (up to n) of discrete fluidized bed heat exchangers, and return means to transport at least part of said solid particles back from said discrete fluidized bed heat exchangers into the circulating fluidized bed reactor, wherein the number (up to n) of discrete fluidized bed heat exchangers are mechanically connected to provide one common fluidized bed heat exchanger with water cooled intermediate walls between adjacent discrete fluidized bed heat exchangers.
  • Typically each separator is followed by one heat exchanger (with a syphon like seal in between), while the improvement reduces the number of construction parts insofar as at least two, or three, or all (namely n) heat exchangers are combined into one element. This make the apparatus more compact and more effective. Cooling means (water cooled walls) can be designed as common walls between adjacent sections of a combined heat exchanger.
  • Optional features are:
    • The discrete fluidized bed heat exchangers are arranged in a row (a line) to provide the common fluidized bed heat exchanger, which allows a very compact design.
    • The water cooled intermediate walls comprise water-cooled pipes, in particular metal pipes.
    • The water cooled intermediate walls comprise water-cooled pipes, wherein adjacent pipes are connected by metal fins. Fins and pipes can be welded.
    • The common fluidized bed heat exchanger is suspended from the separator(s). This hanging construction reduces the installation costs and required space.
    • The common fluidized bed heat exchanger is fixedly secured to the circulating fluidized bed reactor, allowing a compact overall design.
    • The common fluidized bed heat exchanger and the circulating fluidized bed reactor have a common wall. Again this makes the installation compact.
    • The common wall is water-cooled.
    • The common wall has one or more openings fulfilling the function of the return means (outlet port). Space for a separate return duct or the like can thus be avoided
    • The fluidized bed heat exchanger has outer chamber walls being at least partially water-cooled.
    • The FBHE is designed without any structural means urging the solid particles to meander within the fluidized bed heat exchanger. Contrary to common designs the FBHE does not provide any separate entrance chamber and/or return chamber through which the solid particles must pass after entering the FBHE and/or before leaving it. No pre-homogenization of the solid particles being necessary any more.
    Improvement C refers to a:
  • Fluidized bed heat exchanger (FBHE) with a chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means arranged within said chamber, wherein the heat transfer means is designed in a wall-like pattern and extending substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port.
  • The wall like structure (a flat and compact design of an individual heat transfer means) in combination with its orientation are the main features, allowing to arrange a group (set) of multiple heat transfer means at a distance to each other with channels like "cavities/gaps" in between, extending as well in the flow/transport direction of the solid particles towards the outlet area of the chamber.
  • Insofar the term "wall like" does not refer to a cubic design with flat surfaces but the overall volume which the respective heat transfer means take. A tube, meandering (zig-zag) such that the central longitunal axis of the tube lies in one imaginary plane is an example for a wall-like pattern. Tube sections may extend in different directions along two axis of the coordinate system.
  • This design allows the solid particles within the fluidized bed to flow between said individual heat transfer means, namely within said spaces (channels) formed between adjacent heat transfer means, without any obstacles (baffles) but including the option to flow from one of said channels/spaces/gaps into an adjacent one.
  • This is true especially if the discrete heat transfer means are provided be bended tubes/pipes, for example according to one of the following optional features:
    • The wall like pattern comprises a grid-like structure. This allows the solid particles to flow in all directions of the coordinate system but keeps the barrier free main transport direction towards the outlet port.
    • The heat transfer means is designed as a heat exchange tube for conveying a heat transfer medium and arranged in a meandering fashion, thereby providing a vertically oriented wall-like pattern.
    • Multiple heat transfer means are arranged at a distance to each other, forming a set/group of heat transfer means. This gives a package/set of heat transfer means, extending over more than 50% of the chamber volume.
    • Heat transfer means extend about more than 60% of the chamber height.
    • Heat transfer means extend about more than 70% of the chamber height.
    • Heat transfer means extend from shortly above the bottom upwardly to shortly below the ceiling of said chamber. The larger the heat transfer means are the more efficient is the total heat exchange.
    • Horizontally extending sections of the meandering heat exchange tube are at least 3 times longer than vertically extending sections of the heat exchange tube. This underlies the main transport direction of the solid particles.
    • Adjacent sections of the same heat exchange tube extend at a distance to each other being 0,5 to 2 of the heat exchange tube diameter.
    • Chamber walls being at least partially water-cooled.
    • No structural means urging the solid particles to meander within the chamber. They may pass the FBHE in a main direction parallel to the wall-like heat exchangers.
    • No entrance chamber and/or return chamber for the solid particles being provided in the FBHE to allow a continuous flow pattern.
    • The FBHE may have a common wall with an adjacent circulating fluidized bed reactor (CFBR) and return means for the solid particles may extend at least partially within said common wall to make the installation more compact.
    • The common wall is a water-cooled wall.
    Improvement D refers to a:
  • Fluidized bed heat exchanger with one chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least two heat transfer means within said one chamber, each being provided with a heat transfer medium inlet port and a heat transfer medium outlet port, wherein a first heat transfer means is designed as a reheater and second heat transfer means is designed as a superheater to achieve a heat transfer medium pressure above that of the reheater.
  • This design is best realized with at least two distinct groups/sets of heat transfer means to provide different thermodynamic features within the FBHE and to allow to optimize the heat transfer and efficiency of the FBHE.
  • All heat transfer means (for example distinct steam tubes) of one group may be linked to one central steam feeding line and steam outlet line respectively. Insofar the extra work for installation is reduced to one further feeding and extracting line, in case of two groups of heat exchangers, while allowing to achieve different thermodynamic conditions within the chamber.
  • This can be complete by one or more of the following features:
    • The reheater is constructed to allow a heat transfer medium temperature of up to 600°C (while the inlet temperature of the heat transfer medium, for example steam, is typically about 450-550°C).
    • The reheater is constructed to allow a heat transfer medium pressure of up to 50bar (typically in the range of 30-40bar).
    • The superheater is constructed to allow a heat transfer medium temperature of up to 600°C (typically with inlet temperatures between 500 and 580°C).
    • The superheater is constructed to allow a heat transfer medium pressure of up to 190bar (typically between 160 and 180 bar).
    • The fluid pressure in the superheater tubes is typically more than 3, or more than 4 or even more than 5 times the pressure in the reheater tubes.
    • The reheater and/or the superheater each are made of a multiplicity of heat transfer tubes, each arranged in a meandering fashion and with a distance to each other. Accordingly the reheater and the superheater each have a 3-dimensional profile similar to a cube. Each tube may provide a wall-like (plate-like) structure with a grate-like pattern according to the meandering tube sections. The solid particles pass through channels between the heat transfer means.
    • The chamber walls can be at least partially water-cooled.
    • Again this FBHE and an associated circulation fluidized bed reactor CFBR may have a common wall to reduce costs and make the apparatus compact.
    • This common wall can be water-cooled.
    Improvement E refers to a :
  • Fluidized bed apparatus, comprising a circulating fluidized bed reactor of a vertical axial length L in its functional position, with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger and return means to transport at least part of said the solid particles back into the fluidized bed reactor, wherein the return means are designed such that their lowermost point enters into the fluidized bed reactor at a minimum height of 0,1 L, calculated from the lowermost end of said axial length (L) of the fluidized bed reactor in its functional position.
  • In other words: This design gives an optimized return position for the solid particles back into the CFBR.
  • The minimum distance between the bottom area of the CFBR and the place, where the solid particles enter the CFBR, guarantees that the solid particles may freely enter the combustion chamber (the fluidized bed) and avoids any backflow from the fluidized bed, especially from the denseboard (=high pressure zone) of the fluidized bed, being the lowermost section of the fluidized bed, right above the aerated/pressurized bottom. FBHE does not require any complex sealing systems along the return means/outlet port.
  • The length L of the CFBR is defined as the distance between the upper surface of the aerated bottom (grate-/nozzle area) and the inner surface of the chamber ceiling.
  • Optional features are:
    • The return means of FBHE are designed such that their lowermost point enters into the fluidized bed reactor at a minimum height of 0,15L or 0,20L, calculated from the lowermost end of said axial length (L) of the fluidized bed reactor.
    • The lowermost point of said return means of FBHE enters into the fluidized bed reactor at a distance to the uppermost point of a dense board of said fluidized bed reactor.
    • Said return means comprise multiple flow through openings for said solid particles; a row of flow through openings, arranged at a distance to each other, equalizes the flow of the solid particles (like ash) on their way back into the reactor.
    • The fluidized bed heat exchanger is fixedly secured to the fluidized bed reactor. A very simple construction with a precise return position for the solid particles.
    • This is in particular true if the fluidized bed heat exchanger and the fluidized bed reactor have a common wall.
    • The common wall has one or more openings fulfilling the function of the return means. This allows again a very compact structure.
    • The return means are designed as a coupling without transferring mechanical forces or moments from said fluidized bed reactor into said fluidized bed heat exchanger or vice versa.
    • The fluidized bed heat exchanger has a refractory lining.
    • The chamber walls of the FBHE are at least partially water-cooled.
    • Any further return means from the separator and/or a syphon enter the CFBR shortly above its grate, i.e. directly into the denseboard (dense part) of the circulating fluidized bed and below the FBHE return means.
  • Yet another improvement (F) relates to a :
  • Fluidized bed heat exchanger with a chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means, arranged within said chamber, wherein at least one distribution means being arranged in a transition region between said inlet port and said chamber and upstream of said heat transfer means to allow dilution of said solid particles.
  • This improvement relates to feeding of the particulate material into the fluidized bed heat exchanger (FBHE). The FBHE (its inner chamber/space) typically has a cubic or cylindrical shape of high volume.
  • If the solid particles, coming from the separator, enter said chamber along a discrete inlet port of limited size, problems may arise in distributing the said particulate material within the chamber and around/between the heat transfer means to achieve the required heat transfer.
  • The improvement allows to distribute the solid particles on their way into the chamber over a much larger area, depending on the shape and size of the distribution means. At the same time the density of the solids within the particle stream is reduced, which further increases the heat transfer efficiency from the hot particles into the heat transfer medium (a brine, steam or the like).
  • The term "transition region" includes the end section of the inlet port adjacent to the chamber of the FBHE as well the adjacent section of the chamber and any area in between.
  • Possible alternatives and embodiments include a fluidized bed heat exchanger with one or more of the following features:
    • The distribution means are provided by construction elements protruding from an inner surface of said inlet port and/or chamber. They may protrude from a wall or ceiling section.
    • The distribution means are provided by at least one of the following construction elements: bar, knob, prism, grid, grate, pyramid, spiral, saw tooth, dowel, nib, nozzle.
    • The distributions means extend >30,>40 or>50% of the length or width of the chamber to homogenize the stream of the fluidized bed within the chamber to its best.
    • The distributions means are arranged shortly downstream of the inlet port, i.e.
      along the upper part of the chamber.
    • The inlet port enters the chamber by its ceiling. This gives the solid particles a transport direction following gravity.
    • The inlet port enters the chamber through an upper end of a chamber wall (). Then the flow of the solid particles is substantially horizontal before entering the chamber.
    • Multiple heat transfer means which are arranged at a distance to each other, allow to give the solid particles a certain flow profile through the chamber (along intermediate channels).
    • The chamber walls may be at least partially water-cooled.
    • A fluidized bed heat exchanger without any structural means (except that distribution means at the entrance area and the heat transfer means) allows the solid particles to pass the chamber without further meandering.
  • Improvement G refers to a design with a common wall between the CFBR and FBHE, namely a
  • Fluidized bed apparatus comprising a circulating fluidized bed reactor with at least one outlet port at its upper part, wherein said outlet port allows a mixture of gas and solid particles exhausted from the fluidized bed reactor to flow into at least one associated separator for separating solid particles from said gas, means to transfer said separated solid particles into at least one fluidized bed heat exchanger as well as return means to transport at least part of said solid particles back into the circulating fluidized bed reactor, wherein the said circulating fluidized bed reactor and said fluidized bed heat exchanger have at least one common wall and said return means are provided within said common wall.
  • This allows to use one wall (section) commonly for 2 independent components of the apparatus and thus to reduce the material and construction costs.
  • The integration of the return means allows further reductions in construction work, material costs and increases the efficiency. The material flow from the FBHE into the combustion reactor becomes more reliable and more homogeneous.
  • Optional feature to this improvement include:
    • The return means are provided by at least one through hole within said common wall, this is a very simple and effective design.
    • The return means are multiple through holes arranged at a distance to each other (for example in a horizontal row) within said common wall.
    • The at least one through hole is inclined, with a lower end towards the fluidized bed heat exchanger and a higher end towards the fluidized bed reactor. This reduces the danger of infiltration of particles from the fluidized bed of the CFBR into the FBHE.
    • The common wall provides a three-dimensional profile towards the fluidized bed heat exchanger. This allows to partly or fully integrate the sloping outlet port into the common wall area.
    • The common wall provides a convexity towards the fluidized bed heat exchanger. Again this allows to integrate the inclined outlet duct/openings into the shared wall and keeps the pressure on said outflowing material low.
  • A further improvement H relates to a:
  • Fluidized bed heat exchanger with a chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means, arranged within said chamber, wherein said means for introducing the fluidizing gas are provided by a multiplicity of nozzles arranged along the bottom area of said chamber and different nozzles being charged with different gas pressure.
  • In other words:
  • The aerated bottom (the air/gas permeable bottom as part of the fluidized bed) is divided into sections/zones/areas, where air is applied under different pressure. This allows to provide a custom-made pressure profile within the FBHE and thus to optimize the heat transfer and particle transport. A multiplicity of air openings, mostly provided by air nozzles, can be linked to a common air feeding duct or funnel.
  • Possible embodiments include:
    • A multiplicity of nozzles is split into two or more nozzle sets; each nozzle set comprising a plurality of nozzles, wherein each nozzle sets may be charged with an individual gas pressure, for example with a different gas pressure.
    • The nozzles of one nozzle set are arranged within one common area. This allows to split the overall bottom area into two, three or more larger sections.
    • The gas pressure of a nozzle set is adjustable. This allows to adapt the gas pressure according to local demands.
    • Each nozzle set is coupled to a corresponding gas channel or gas distribution space respectively in order to adjust the required pressure in the respective manner with respect to all nozzles of a nozzle set connected thereto.
    • A fluidized bed heat exchanger without any structural means (except distribution means at the entrance area and the heat transfer means) allows the solid particles to pass the chamber without further meandering, to the contrary: their path through the FBHE is mostly influenced by the air pressure along the bottom grate.
  • A similar design may be used for a syphon arranged between separator and CFBR according to the following improvement I:
    • Fluidized bed syphon with a U-shaped chamber, comprising a vertically oriented solid particles entrance port, a vertically oriented solid particles exit port, arranged at a distance to the entrance port, and a horizontally oriented intermediate section in fluidic connection with said entrance port and said exit port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, wherein said means for introducing the fluidizing gas are provided by a multiplicity of nozzles,
    • arranged along the bottom area of said chamber and different nozzles being charged with different gas pressure.
  • The overall design of said syphon, serving as a gas seal between components of the fluidized bed apparatus connected upstream and downstream of said syphon, is similar to that of the fluidized bed heat exchanger as disclosed above. The main difference is, that the syphon does not necessarily comprise any heat transfer means.
  • To provide a bottom area of the syphon as a fluidized bed and the partition of said fluidized bed into discrete sections allows to adapt the air/gas volume and pressure individually for each of said sections.
  • One possible arrangement is: A first nozzle set blows air in a counterflow to the solid particles into the entrance port, a second nozzle set provides nozzles which blow air/gas into the mostly horizontally oriented stream of solid particles along the intermediate section while a third nozzle set blows air into the solid particles leaving the syphon via the exit port, wherein air/gas and solid particles have the same transport direction along this exit section.
  • Optional features for this type of syphon are:
    • The multiplicity of nozzles is split into two or more nozzle sets, each nozzle set comprising a plurality of nozzles, wherein each nozzle set is charged with a different gas pressure.
    • The nozzles of one nozzle set are arranged within one common area.
    • The gas pressure of a nozzle set is adjustable.
    • Each nozzle set is coupled to a corresponding gas channel or gas distribution space respectively.
    • Chamber walls being at least partially water-cooled.
    • The bottom area of the chamber extends along substantially the full width and length of the U-shaped chamber.
    • A first nozzle set extends along the bottom area of the intermediate chamber section and discrete second and third nozzle sets along sections of said entrance port and exit port, which follow the bottom area of the intermediate section to both sides.
  • Improvement K relates to a:
    • Fluidized bed heat exchanger with a chamber, comprising at least one solid particles inlet port, at least one solid particles outlet port, arranged at a distance to the at least one inlet port, means for introducing a fluidizing gas from a bottom area of said chamber into said chamber, at least one heat transfer means, arranged within said chamber, at least one baffle which extends downwardly from a chamber ceiling,
    • substantially perpendicular to a straight line between inlet port and outlet port, with its lower end at a distance to the heat transfer means.
  • This at least one baffle does not influence the flow of the solid particles within the part of the FBHE equipped with the heat transfer means as it is arranged above said heat transfer means and only serves to redirect the incoming solid particle stream (downwardly) and to equalize the pressure above the fluidized bed and along the horizontal cross section of the chamber, in particular, if provided with opening(s).
  • The baffles have the function of separation walls and avoid short circuits of the solid material flow (directly from the inlet port to the outlet port). They urge the solid particle stream to penetrate into the heat transfer zone between the heat transfer means (the channels mentioned above). The baffle construction may interact with improvement H.
  • The following embodiments are optionally included:
    • At least one baffle extends between opposite walls of the chamber to improve the describe effect.
    • At least one baffle has at least one opening to allow pressure adjusting/compensation within the chamber.
    • At least one baffle is at least partially water-cooled.
    • At least one baffle is designed as a curtain. The curtain defines a baffle with numerous small openings which allow pressure equalization but avoids penetration of the solid particles to great extent.
    • Multiple baffles are arranged at a distance to each other along said line between inlet port and outlet port.
    • The heat transfer means are designed as a heat exchange tube for conveying a heat transfer medium and arranged in a meandering fashion, thereby providing a vertically oriented wall-like pattern. The individual heat transfer walls extend perpendicular to the baffles.
  • The invention is now described with reference to the attached drawing, showing - all in a very schematic way - in
    • Figure 1
      A general concept of a fluidized bed apparatus according to prior art
    • Figure 2
      A cross sectional view of a fluidized bed heat exchanger
    • Figure 3
      A top view on the FBHE 24 of Figure 2 along line 3-3
    • Figure 4
      A cross sectional view of another embodiment of a fluidized bed heat exchanger
    • Figure 5
      A cross sectional view of further embodiment of a fluidized bed heat exchanger A with 2 groups of heat exchangers
    • Figure 6
      A top view on the FBHE of Figure 5 along line 6-6
    • Figure 7
      A top view on a further example for a FBHE 24 with an amended inlet port
    • Figure 8a
      A cross sectional view of an FBHE with multiple nozzles sets in the bottom area
    • Figure 8b
      A cross sectional view of a syphon with multiple nozzles sets in the bottom area
    • Figure 9
      An general view of a fluidized bed apparatus mounted in a suspended manner
    • Figure 10
      A compact fluidized bed heat exchanger in a 3-dmensional view
  • In the Figures identical an similar acting construction parts are identified by same numerals.
  • Figure 1 discloses the general concept of a fluidized bed apparatus and its main components according to the present invention.
  • It comprises:
    • A circulating fluidized bed reactor (CFBR) 10. Its lower part comprises a grate-like structure 12 through which air (arrow A1) is blown into a reactor chamber 14 via (not shown) nozzles, thus providing a fluidized bed (denseboard - DB -) above said grate 12, wherein said denseboard comprises a particulate material like coal, wood etc. to be burnt.
    • The CFBR has two outlet ports 16 at opposite sides of its upper part, allowing a mixture of gas and solid particles exhausted from the CFBR to flow into associated separators 18, namely cyclone separators. The separators serve to separate solid particles from the gas.
    • Transfer means 20, designed as ducts, extend from the lower end of each separator 18 downwardly and into an inlet port 22 along the ceiling 24c of a fluidized bed heat exchanger (FBHE) 24.
    • A syphon-like tube construction 26 (U-shaped) extends from the lower end of each separator 18 into reactor chamber 14 and enters into chamber 14 shortly above grate 12 of said CFBR.
    • The FBHE is equipped with (plate-like) heat transfer means 28 and an outlet port 30 merging into reactor chamber 14 at the same vertical height as tube construction 26.
  • This concept belongs to prior art. Insofar details are not further illustrated as known to the skilled person.
  • The invention includes one or more of the following features:
  • According to Figure 2 the fluidized bed heat exchanger 24 displays an inlet port 22 at its upper end (in Figure 2: top left) and an outlet port 30 at its upper end (in Figure 2: top right), i. e. opposite to each other. Said outlet port 30 provides return means for solid particles transported along transfer duct 20 into said FBHE and is provided within a common wall 14w of chamber 14 and FBHE 24.
  • Outlet port 30 comprises multiple flow through openings, arranged in a horizontal row with a distance to each other along a corresponding wall section of said wall 14w.
  • Said wall 14w is water-cooled, namely constructed of vertically extending tubes with fins running between adjacent tubes. The tubes are cooled by water fed through said tubes.
  • The through holes having the function of discrete outlet ports are shown in Figure 2 in a slightly inclined orientation, with a lower end towards the fluidized bed heat exchanger 24 and a higher end towards the fluidized bed reactor chamber 14.
  • This inclined orientation (sloped outlet port 30) can be provided as part of a 3-dimensional profile (for example as a convexity 14w') of said wall 14w towards the inner space/chamber of the fluidized bed heat exchanger 24 as shown in dotted lines in Figure 2 and characterized by numeral 30'.
  • Figure 2 further shows the design and construction of heat transfer means 28 within the fluidized bed heat exchanger 24. In the Figure only one of said heat transfer means is shown. Further heat transfer means of equal design are placed at a distance to each other within FBHE 24 (perpendicular to the plane of projection).
  • Steam is fed into said means 28 via a central feeding line 42, then flowing through the meandering tube (as shown), providing said means 28, and escaping via a common outlet line 44, allowing to take heat from the particulate material (symbolized by dots P) moving through FBHE 24 between inlet port 22 and outlet port 30.
  • It is important that each of said means 28 is designed in a wall-like pattern and extending substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port 30, symbolized in Figure 2 by arrow S.
  • All tubes 28 are connected to the same feeding line 42 and outlet line 44.
  • The meandering tubes not only give the heat transfer means 28 a wall-like pattern but as well a grid-like structure to allow the particulate material to pass through as well in a horizontal direction.
  • The horizontally extending sections of said tubes are about three times longer than the vertically extending sections (Figure 2 is not drawn to scale). Adjacent horizontal sections extent to a distance to each other being about the tube diameter.
  • As shown in Figure 2 the heat transfer means 28 extent about more than 60 % of the chamber height, being the distance between a chamber bottom 24b and a chamber sealing 24c. In the embodiment each of said wall-like heat transfer means 28 extends from slightly above bottom 24b to slightly below inlet port 22 and from slightly off wall 14w to slightly off opposite wall 24w.
  • This allows to avoid any structural means within FBHE 24 which could otherwise urge the solid particles to meander within FBHE. In particular the new design allows to avoid any entrance chamber and/or return chamber for the particulate material to homogenize.
  • In prior art devices a separate entrance chamber EC with a discrete partition wall is constructed between wall 24 w and adjacent part of heat transfer means 28 as well as a separate return chamber RC between wall 14 w and parts 28. These walls and chambers caused the stream of solid particles to flow up and down, which is now avoided with the new design without any partition walls.
  • The particulate material may take a direct way from the inlet port 22 to the outlet port 30 (see arrow S) along the channels/gaps C formed between adjacent tubes (heat transfer means), as may be seen in Figure 3.
  • Fluidization of the particulate material within FBHE 24 is achieved by air nozzles 46 in the bottom area 24b. The particulate material is circulated by said purging means within FBHE 24 in order to optimize heat transfer from the hot solid particles P onto the steam flowing within tube like heat transfer means 28.
  • The embodiment of Figure 4 differs from that of Figures 2,3 insofar as two baffles 50, 52 extent from sealing 24c downwardly, ending shortly above heat transfer means 28. These baffles 50, 52 extend substantially perpendicular to a straight line between inlet port 22 and outlet port 30 (dotted line L).
  • Both baffles 50, 52 extend between opposite walls of FBHE 24 (only one, namely 24s is shown), being the walls bridging said walls 14w, 24w. The baffles 50, 52 are arranged at a distance to each other.
  • Each of said baffles 50, 52 comprise one opening symbolized by dotted line O to allow pressure adjustment (equalization) within the inner space of FBHE 24.
  • The said baffle(s) 50, 52 may as well be designed like a curtain, fulfilling the same function as a continuous board, namely to urge the particulate material to flow through said channels C (Figure 3) between adjacent heat transfer means 28 on their way between inlet port 22 and outlet port 30.
  • In Figure 4 outlet port 30 is extended, namely protruding into circulating fluidized bed reactor 10.
  • In the embodiment according to Figure 5 the multiplicity of heat transfer means 28 is split into two groups.
  • A first group G1 is made of a number of heat transfer means 28 as shown in Figures 2, 3 with the exception that the horizontal extension between walls 24w, 14w is much shorter and ending about half the way between said walls 14w, 24w.
  • This group G1 of multiple heat transfer tubes 28 connected to a common feeding line 42 and a common outlet line 44 is characterized by a feeding temperature of 480°C and an outlet temperature of 560°C of the heat transfer medium (steam) and an average steam pressure of 32 bar, thus fulfilling the function of a so called reheater.
  • The second group G2 of several heat transfer means 28 is constructed the same way as group G1 but connected so separate inlet lines 42' and outlet lines 44' for said steam and designed to achieve a heat transfer medium temperature of between 510°C (inlet temperature) and 565°C (outlet temperature) as well as an average 170 bar pressure. This allows to use the tubes of group G2 as a so called superheater. As shown in Figure 5 tubes of group G2 are arranged closer to the outlet port 30 and adjacent to wall 14w while tubes of group G1 are arranged adjacent to wall 24w with a distance between groups G1 and G2.
  • Figure 6 is a top view of Figure 5 along line 6-6 in Figure 5.
  • The fluidized bed heat exchanger 24 according to Fig. 7 displays a different design around inlet port 22, which widens towards the inner space of chamber 24, wherein said widened section 22w is further inclined towards the bottom area 24b of FBHE 24 to provide a distributor means allowing the entering stream of solid particles to spread over substantially the full width of said inner space of chamber 24, wherein the width is defined by the distance of side wall 24s.
  • This distributor means (section 22s) are arranged in a transition region defined by end section of inlet port 22 and the adjacent section of chamber 24, extending upstream of said heat transfer means 28 and extending over about 2/3 of the chamber width.
  • Ribs 22r protrude from the surface of said distributor 22s and are arranged in a star-like pattern.
  • Again all walls 14w, 24w and 24s of said FBHE are made of water-cooled tubes with fins between adjacent tubes, symbolized in the right part of Figure 7.
  • Figure 8a displays an FBHE 24 characterized by a modified bottom area 24b.
  • Numerous air nozzles 46 are mounted within bottom 24b. Each nozzle comprises an outer end 46o, protruding downwardly from the outer surface of bottom 24b and an inner end 46i, protruding into the hollow space of FHBE 24 equipped with groups G1, G2 of heat exchange tubes 28.
  • The nozzles 46 are assembled into five nozzle sets N1, N2, N3, N4 and N5, one behind the other in a row between walls 24w and 14w. All nozzles 46 of a nozzle set are commonly connected to a respective common gas channel 48. If air is fed along one of these channels all corresponding nozzles 46 will be activated to allow air to enter into FBHE 24.
  • The arrangements of discrete nozzle sets N1...N5 with discrete channels 48 make it possible to set different air pressure in different channels and accordingly to introduce air into the fluidized bed of solid particles within FBHE under different pressure at different areas to optimize homogenisation of the particles within the fluidized bed.
  • A similar design may be used to improve the syphon-type seal 26 between separator 18 and FBHE 24 or reactor 10 respectively, as illustrated in Fig. 8b.
  • A mixture of gas and solid particles like ash coming from separator 18
    • enters the inlet tube of the U-shaped syphon 26 in a downward direction,
    • is then fluidized by a fluidized bed construction in a bottom area 26b of said inlet tube via nozzles 27,
    • turns about 90 degrees,
    • flows along an intermediate chamber section 26i, where further fluidization takes place,
    • then turns up into an outlet tube of the U-shaped syphon 26, where further fluidization by nozzles 27 at the bottom area of said outlet tube may take place, before
    • flowing along another U-shaped tube section and entering the CFBR 10 via a corresponding return line.
  • Similar to the embodiment of Fig. 8a, the multiplicity of air nozzles 27 is split into three nozzles sets SN1, SN2 and SN3, each with a certain number of nozzles 27, and each coupled to a respective air duct D1, D2 and D3, feeding air to the respective nozzles 27 under same or different pressure.
  • Similar to Figure 8a the air ducts D1..D3 have a funnel shape at their upper ends.
  • Figure 9 represents a fluidized bed apparatus wherein its main components, namely the CFBR 10, the FBHE 24 as well as corresponding separators 18 are mounted in a suspended manner to a central supporting structure, namely a frame 60. The frame 60 has the shape of an inverted U with its legs 60l fixed within ground GR.
  • While the CFBR 10 and the separator 18 are each directly suspended from base 60b of frame structure 60 (by posts 62), the FBHE 24 is mounted in a suspended manner from separator 18.
  • Mechanical stability of FBHE 24 is further achieved by said common, water-cooled wall 14w with CFBR 10.
  • Because of the hanging structure thermal expansion and constriction take place at all components in the same direction and avoids mechanical as well as thermo-mechanical tensions between adjacent construction parts at most.
  • To make the construction wear resistant, the fluidized bed heat exchanger has no refractory lining; all walls are water cooled metal walls.
  • The hanging structure allows an integration of a syphon 26 with its return duct 26r without transferring mechanical forces or moments between the respective construction parts.
  • According to Figure 9 the lowermost point LP1 of outlet port 30 of fluidized bed heat exchanger 24 enters the circulating fluidized bed reactor 10 at a height of >0,15L, calculated from the lowermost end of the axial length L of CFBR 10. The lowermost end is defined by grate 12 of the fluidized bed. The minimum distance of >0,1L, better >0,2L, allows to place the return means 30 out of the so called denseboard DB and avoids the risk of any backflow of solid particles from the fluidized bed within reactor 10 into the associated construction elements like FBHE 24. This feature may be combined with sloped outlet ports 30 as disclosed in Figure 2 or sloped return ducts 26r.
  • The lowermost point of return duct 26r of syphon 26 enters the CFBR at a height of the denseboard DB, close to grate 12 and below outlet port 30.
  • This positioning of the two outlet ports/return means 30,26r to each other is an important combined feature valid for various applications.
  • In case of an apparatus comprising more than one separator 18, for example 3 separators, Figure 10 discloses an embodiment with three corresponding fluidized bed heat exchangers 24.1, 24.2, 24.3 which are mechanically connected to provide one common fluidized bed heat exchanger 24 of corresponding, suitable size, with water-cooled intermediate walls 24i. Again: all three wall sections 14w of the common heat exchanger 24 are part of the reactor wall 14, i.e. a common water-cooled wall with integrated outlet openings 30.
  • Walls 14i, 14w are made of metal tubes, welded to each other and connected with a fluid source to feed cooling water through said tubes.

Claims (14)

  1. Fluidized bed heat exchanger with a chamber (24), comprising 1.1 at least one solid particles inlet port (22)
    1.2 at least one solid particles outlet port (30), arranged at a distance to the at least one inlet port (22),
    1.3means (46) for introducing a fluidizing gas from a bottom area (24b) of said chamber into said chamber (24),
    1.4 at least one heat transfer means (28) arranged within said chamber (24), wherein
    1.5the heat transfer means (28) is designed in a wall-like pattern and extending substantially parallel to the main flow direction of the solid particles on their way to and through the outlet port (30).
  2. Fluidized bed heat exchanger according to claim 1, wherein the wall like pattern comprises a grid-like structure.
  3. Fluidized bed heat exchanger according to claim 1, wherein the heat transfer means (28) is designed as a heat exchange tube for conveying a heat transfer medium and arranged in a meandering fashion, thereby providing a vertically oriented wall-like pattern.
  4. Fluidized bed heat exchanger according to claim 1 with multiple heat transfer means (28) which are arranged at a distance to each other.
  5. Fluidized bed heat exchanger according to claim 1 wherein the heat transfer means (28) extend about more than 60% of the chamber height.
  6. Fluidized bed heat exchanger according to claim 1 wherein the heat transfer means (28) extend about more than 80% of the chamber height.
  7. Fluidized bed heat exchanger according to claim 1 wherein the heat transfer means (28) extend from shortly above the bottom (24b) upwardly to shortly below the ceiling (24c) of said chamber (24).
  8. Fluidized bed heat exchanger according to claim 3, wherein horizontally extending sections of the meandering heat exchange tube are at least 10 times longer than vertically extending sections of the heat exchange tube.
  9. Fluidized bed heat exchanger according to claim 3, wherein adjacent sections of the same heat exchange tube extend at a distance to each other being 0,5 to 2 of the heat exchange tube diameter.
  10. Fluidized bed heat exchanger according to claim 1 with chamber walls (14w)
    being at least partially water-cooled.
  11. Fluidized bed heat exchanger according to claim 1 without any structural means urging the solid particles to meander within the chamber.
  12. Fluidized bed heat exchanger according to claim 1 without any entrance chamber (EC) and/or return chamber (RC) being provided in the chamber ().
  13. Fluidized bed apparatus comprising a circulating fluidized bed reactor (10) with at least one outlet port (16) at its upper part, wherein said outlet port (16) allows a mixture of gas and solid particles exhausted from the fluidized bed reactor (10) to flow into at least one associated separator (18) for separating solid particles from said gas, means (20) to transfer said separated solid particles into at least one fluidized bed heat exchanger (24) according to claim 1 as well as return means to transport at least part of said solid particles back into the circulating fluidized bed reactor (10), wherein said return means extend at least partially in a common wall (14w) of said fluidized bed reactor (10) and said fluidized bed heat exchanger (24).
  14. Fluidized bed apparatus according to claim 13, wherein the common wall
    (14w) is water-cooled.
EP13197364.6A 2013-12-16 2013-12-16 Fluidized bed heat exchanger Withdrawn EP2884162A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP13197364.6A EP2884162A1 (en) 2013-12-16 2013-12-16 Fluidized bed heat exchanger
CN201480063961.5A CN105723152A (en) 2013-12-16 2014-08-15 Fluidized bed apparatus and components thereof
PCT/EP2014/067488 WO2015090636A1 (en) 2013-12-16 2014-08-15 Fluidized bed apparatus and its components
US15/038,641 US20160356488A1 (en) 2013-12-16 2014-08-15 Fluidized Bed Apparatus and its Components
ARP140104207A AR098354A1 (en) 2013-12-16 2014-11-10 FLUIDIZED MILK APPARATUS
HK16111171.0A HK1224000A1 (en) 2013-12-16 2016-09-23 Fluidized bed apparatus and its components

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP13197364.6A EP2884162A1 (en) 2013-12-16 2013-12-16 Fluidized bed heat exchanger

Publications (1)

Publication Number Publication Date
EP2884162A1 true EP2884162A1 (en) 2015-06-17

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US (1) US20160356488A1 (en)
EP (1) EP2884162A1 (en)
CN (1) CN105723152A (en)
AR (1) AR098354A1 (en)
HK (1) HK1224000A1 (en)
WO (1) WO2015090636A1 (en)

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EP3241804A1 (en) * 2016-05-03 2017-11-08 Casale SA Process for producing a synthesis gas
CN114688546B (en) * 2021-12-29 2023-01-10 浙江大学 Hot ash returning flow control device and method capable of achieving lateral air distribution and achieving double adjustment of bed temperature and steam temperature

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WO2015090636A1 (en) 2015-06-25
US20160356488A1 (en) 2016-12-08
AR098354A1 (en) 2016-05-26
CN105723152A (en) 2016-06-29

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