EP2524384A1 - Electric contact element and method for producing an electric contact element - Google Patents
Electric contact element and method for producing an electric contact elementInfo
- Publication number
- EP2524384A1 EP2524384A1 EP11700420A EP11700420A EP2524384A1 EP 2524384 A1 EP2524384 A1 EP 2524384A1 EP 11700420 A EP11700420 A EP 11700420A EP 11700420 A EP11700420 A EP 11700420A EP 2524384 A1 EP2524384 A1 EP 2524384A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- wire
- contact
- conductive material
- semifinished product
- contact element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000011265 semifinished product Substances 0.000 claims abstract description 27
- 239000004020 conductor Substances 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 230000013011 mating Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 13
- 238000003466 welding Methods 0.000 claims description 10
- 229910000510 noble metal Inorganic materials 0.000 claims description 8
- 238000007790 scraping Methods 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
- 239000004332 silver Substances 0.000 description 9
- 239000010970 precious metal Substances 0.000 description 8
- 229910052709 silver Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000002905 metal composite material Substances 0.000 description 7
- IVQODXYTQYNJFI-UHFFFAOYSA-N oxotin;silver Chemical compound [Ag].[Sn]=O IVQODXYTQYNJFI-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 3
- 229910000416 bismuth oxide Inorganic materials 0.000 description 3
- 229910000431 copper oxide Inorganic materials 0.000 description 3
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 3
- 229910003437 indium oxide Inorganic materials 0.000 description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 3
- 229910052714 tellurium Inorganic materials 0.000 description 3
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 241001674044 Blattodea Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- -1 Fe 2 03 Chemical compound 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
- H01H1/0237—Composite material having a noble metal as the basic material and containing oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H11/00—Apparatus or processes specially adapted for the manufacture of electric switches
- H01H11/04—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
- H01H11/06—Fixing of contacts to carrier ; Fixing of contacts to insulating carrier
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49204—Contact or terminal manufacturing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/54—Miscellaneous apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24298—Noncircular aperture [e.g., slit, diamond, rectangular, etc.]
- Y10T428/24314—Slit or elongated
Definitions
- the present invention relates to a method for producing an electrical contact element from a semifinished product as well as to the electrical contact element and the corresponding semifinished product.
- Electrical contacts are found in electrical appliances and switchgear, such as e.g. in light switches, circuit breakers or relays, diverse applications and are widely used.
- noble metal / metal oxide composite materials for example silver / tin oxide
- a contact carrier material by welding
- the object underlying the present invention can therefore be seen to provide a method for producing a contact element, on the one hand ensures optimum properties of the contact element during operation and on the other hand, a material-saving and cost-effective manufacturability.
- This object is solved by the subject matter of the independent patent claims.
- Advantageous developments of the present invention are the subject of the dependent claims.
- the present invention is based on the idea that for the production of the actual contact as a semi-finished part of a wire of metal composite material is used as the first conductive material, which is provided with a metal coating as a second electrically conductive material, wherein the metal coating on a part the surface was removed again to expose the core of metal composite at the later contact surface.
- the metal composite material may consist of a suitable metal, such as copper, copper-nickel alloy, chromium-nickel alloy or silver, which oxides such as tin oxide, zinc oxide, iron oxide such as Fe 2 03, copper oxide, cadmium oxide, indium oxide, antimony oxide, lanthanum oxide, magnesium oxide , Manganese oxide, bismuth oxide, tellurium oxide, carbon (in the form of carbon blacks, graphite or carbon fibers), or else nickel, if the metal is otherwise different from nickel.
- a suitable metal such as copper, copper-nickel alloy, chromium-nickel alloy or silver, which oxides such as tin oxide, zinc oxide, iron oxide such as Fe 2 03, copper oxide, cadmium oxide, indium oxide, antimony oxide, lanthanum oxide, magnesium oxide , Manganese oxide, bismuth oxide, tellurium oxide, carbon (in the form of carbon blacks, graphite or carbon fibers), or else nickel, if the metal is otherwise different from nickel.
- a metal composite material Particularly suitable as a metal composite material are described, for example, described in EP 508055, EP 1505164, EP 725154, EP 736885, EP 795367, DE 10012250, EP 1 142661, EP 1915765 and EP 2004349 and the documents cited therein.
- Particularly advantageous are the silver-based metal composites of EP 508055 and EP 1505164, to which reference is made.
- These are contact materials based on silver-tin oxide, which may additionally contain indium oxide, tellurium oxide, bismuth oxide, copper oxide, nickel oxide or mixtures thereof. Such materials can be produced by powder metallurgy or by internal oxidation.
- the metal coating may consist of the same metal (s) as the metal composite forming the core, but does not contain any of the ingredients which cause the weld strength of the metal composite.
- the silver sheath of a silver tin oxide wire is removed from the region of the subsequent contact point by scraping or splitting. In this way, a minimum loss of precious metal is guaranteed and at the same time a contamination of the switching component with the noble metal in the region of the contact point is avoided and thus prevents welding of the switching contact.
- the production can be greatly simplified and the manufacturing cost can be kept low.
- the use of precious metals is minimal because the precious metal does not have to be used for mechanical tasks. In the area of the switching point there is no weldable metallic precious metal.
- a part of the wire is scraped in an axial direction so that a segment is removed at the circular cross section of the wire.
- the advantageous properties of the present invention are particularly useful when the contact element according to the invention in a switching device, such as an electromagnetic relay, is used, since the problem of welding is particularly critical here.
- FIG. 1 is a schematic perspective view of a finished contact element
- FIG. 2 shows a perspective view of the welded-on semifinished product according to the invention before forming
- FIG. 1 is a schematic perspective view of a finished contact element
- Fig. 3 is a cross-section of the sheathed wire before cockroaches
- Fig. 6 shows a cross section of the wire after performing several Schabesiane.
- FIG. 1 shows a perspective view of the contact element 100 according to the invention using the example of a relay contact.
- the actual electrical contact 102 is connected to a contact carrier 104 shown here only schematically by welding.
- the contact surface 106 which comes into electrical connection with a mating contact during operation, is formed by a material which has no tendency to weld. According to the present embodiment, this is a silver-tin oxide composite material. But there are also other composite materials in question, for example, cadmium oxide, indium oxide, zinc oxide, copper oxide, antimony oxide, lanthanum oxide, magnesium oxide, manganese oxide, bismuth oxide, or tellurium oxide or a combination thereof.
- a metal shell 1 14 in particular a noble metal sheath, in the present case, metallic silver, before, whereby the fixation of the contact 102 on the carrier 104 via a simple welding is possible.
- FIG. 2 shows a perspective view of a preliminary stage of the contact 100, in which the semifinished product 1 10 according to the invention is fixed on the contact carrier 104.
- the semifinished product consists of a cylindrical noble metal / metal oxide core 1 12 which is partially surrounded by a metallic noble metal shell 14.
- the jacket 1 14, which consists of a weldable material is arranged in particular in the region of the weld 108. In the area of the later contact point 106, however, the jacket is removed.
- the semifinished product 1 10 is subsequently connected. Unless applied to the contact carrier 104, the semifinished product 1 10 is subsequently connected. . cid transformed into the actual contact 102. It should be noted that the preforming direction 1 16 extends transversely to a longitudinal axis 118 of the piece of wire.
- FIGS. 3 to 6 explain various special possibilities for freeing the later contact region 106 from the metallic silver layer.
- a section through the wire 120, from which the semifinished product 110 is produced by cutting transversely to its longitudinal axis is shown.
- Fig. 3 shows the blank, in which a core 1 12, which, as already mentioned, may for example consist of silver-tin oxide composite material, with a metallic noble metal sheath 1 14 is surrounded.
- the precious metal is, for example, metallic silver.
- the partial removal of the metallic cladding layer 1 14 can be done by scraping a segment of the cross section.
- FIG. 6 shows an embodiment in which as much as possible of the metallic silver sheath 14 is removed from the later contact region by carrying out two further shaving steps in a radially offset direction to the first shaving step.
- the production according to the invention of contact elements for example for switching or leading contacts on relays, on the one hand allows easy manufacturability by the direct welding of the silver-tin oxide contact material, but on the other hand a particularly low tendency to weld in the region of the actual electrical Contact ensures.
- the costs can be further reduced.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Contacts (AREA)
- Manufacture Of Switches (AREA)
- Manufacturing Of Electrical Connectors (AREA)
Abstract
Description
Elektrisches Kontaktelement und Verfahren zur Herstellung eines Electric contact element and method for producing a
elektrischen Kontaktelements electrical contact element
Die vorliegende Erfindung bezieht sich auf ein Verfahren zur Herstellung eines elektrischen Kontaktelements aus einem Halbzeug sowie auf das elektrische Kontaktelement und das entsprechende Halbzeug. The present invention relates to a method for producing an electrical contact element from a semifinished product as well as to the electrical contact element and the corresponding semifinished product.
Elektrische Kontakte finden in elektrischen Geräten und Schaltgeräten, wie z.B. in Lichtschaltern, Schutzschaltern oder Relais, vielfältige Anwendung und sind weit verbreitet. An die an den Schaltvorgängen beteiligten Bestandteile eines elektrischen Kontaktes, insbesondere an die Kontaktschicht, werden hinsichtlich elektrischer Leitfähigkeit, Abnutzungsfestigkeit, mechanischer Stabilität und Widerstandsfähigkeit gegen Verschweißen vor allem bei Temperatureinwirkungen, hohe Anforderungen gestellt. Es hat sich gezeigt, dass diese die Werkstoffwahl oft gegensätzlich bestimmenden Anforderungen besonders zufriedenstellend von Edelmetall/Metalloxid- Verbundwerkstoffen erfüllt werden können. Electrical contacts are found in electrical appliances and switchgear, such as e.g. in light switches, circuit breakers or relays, diverse applications and are widely used. The components involved in the switching operations of an electrical contact, in particular to the contact layer, high demands are made in terms of electrical conductivity, wear resistance, mechanical stability and resistance to welding, especially at temperature effects. It has been shown that these choice of materials often contradictory requirements can be met particularly satisfactorily of precious metal / metal oxide composite materials.
Gerade wegen ihrer Schweißresistenz können aber derartige Edelmetall/Metalloxid- Verbundwerkstoffe, beispielsweise Silber/Zinnoxid, auf einem Kontaktträgermaterial nicht direkt durch Schweißen befestigt werden. Precisely because of their perspiration resistance, however, such noble metal / metal oxide composite materials, for example silver / tin oxide, can not be attached directly to a contact carrier material by welding.
Daher ist bekannt, die Kontakte mittels einer Vernietung zu befestigen, wie dies beispielsweise bei den sogenannten Bimetallnieten der Fall ist, oder aber eine schweißbare Schicht durch Aufbauen eines Multilayerkontakts bereitzustellen. Hier wird die Verbindung durch ein Kaltschweißverfahren oder Walzplattieren hergestellt. Bei diesen Konzepten ist aber von Nachteil, dass ein hoher Fabrikationsaufwand nötig ist und darüber hinaus ein verfahrenbedingtes Mindestvolumen für das aufzubringende Kontaktmaterial gefordert werden muss. Bei Massivkontakten oder beim Drahtabschnittsnieten wird außerdem ein Teil des Edelmetalls nicht für die eigentliche Schaltfunktion und somit zweckentfremdet verwendet. Therefore, it is known to fasten the contacts by means of a riveting, as is the case for example in the so-called bimetal rivets, or to provide a weldable layer by constructing a multilayer contact. Here, the connection is made by cold welding or roll cladding. In these concepts, however, is a disadvantage that a high production cost is necessary and beyond a procedural minimum volume for the applied contact material must be required. In solid contacts or Drahtabschnittsnieten also a part of the precious metal is not used for the actual switching function and thus misused.
Die Aufgabe, die der vorliegenden Erfindung zugrunde liegt, kann daher darin gesehen werden, ein Verfahren zum Herstellen eines Kontaktelements anzugeben, das einerseits optimale Eigenschaften des Kontaktelements im Betrieb und andererseits eine materialsparende und kostengünstige Herstellbarkeit gewährleistet. Diese Aufgabe wird durch den Gegenstand der unabhängigen Patentansprüche gelöst. Vorteilhafte Weiterbildungen der vorliegenden Erfindung sind Gegenstand der abhängigen Patentansprüche. The object underlying the present invention can therefore be seen to provide a method for producing a contact element, on the one hand ensures optimum properties of the contact element during operation and on the other hand, a material-saving and cost-effective manufacturability. This object is solved by the subject matter of the independent patent claims. Advantageous developments of the present invention are the subject of the dependent claims.
Die vorliegende Erfindung basiert auf der Idee, dass für die Herstellung des eigentlichen Kontaktes als Halbzeug ein Teil eines Drahtes aus Metall-Verbundwerkstoff als erstes leitfähiges Material verwendet wird, der mit einem Metallüberzug als zweites elektrisch leitfähiges Material versehen ist, wobei der Metallüberzug an einem Teil der Oberfläche wieder entfernt wurde, um den Kern aus Metall-Verbundwerkstoff an der späteren Kontaktfläche freizulegen. The present invention is based on the idea that for the production of the actual contact as a semi-finished part of a wire of metal composite material is used as the first conductive material, which is provided with a metal coating as a second electrically conductive material, wherein the metal coating on a part the surface was removed again to expose the core of metal composite at the later contact surface.
Der Metallverbundwerkstoff kann aus einem geeigneten Metall, wie Kupfer, Kupfer- Nickel-Legierung, Chrom-Nickel-Legierung oder Silber bestehen, welcher Oxide wie Zinnoxid, Zinkoxid, Eisenoxid wie Fe203, Kupferoxid, Cadmiumoxid, Indiumoxid, Antimonoxid, Lanthanoxid, Magnesiumoxid, Manganoxid, Wismutoxid, Telluroxid, Kohlenstoff (in Form von Rußen, Graphit oder Kohlenstofffasern) enthält, oder auch Nickel, wenn das Metall ansonsten von Nickel verschieden ist. Besonders geeignet als Metall-Verbundwerkstoff sind beispielsweise beschrieben in EP 508055, EP 1505164, EP 725154, EP 736885, EP 795367, DE 10012250, EP 1 142661 , EP 1915765 und EP 2004349 sowie den dort zitierten Dokumenten beschrieben. Vorteilhaft sind insbesondere die auf Silber basierenden Metall-Verbundwerkstoffe aus EP 508055 und EP 1505164, worauf Bezug genommen wird. Hierbei handelt es sich um auf Silber-Zinnoxid basierende Kontaktwerkstoffe, welche zusätzlich noch Indiumoxid, Telluroxid, Wismutoxid, Kupferoxid, Nickeloxid oder deren Mischungen enthalten können. Solche Werkstoffe können pulvermetallurgisch oder durch innere Oxi- dation hergestellt werden. The metal composite material may consist of a suitable metal, such as copper, copper-nickel alloy, chromium-nickel alloy or silver, which oxides such as tin oxide, zinc oxide, iron oxide such as Fe 2 03, copper oxide, cadmium oxide, indium oxide, antimony oxide, lanthanum oxide, magnesium oxide , Manganese oxide, bismuth oxide, tellurium oxide, carbon (in the form of carbon blacks, graphite or carbon fibers), or else nickel, if the metal is otherwise different from nickel. Particularly suitable as a metal composite material are described, for example, described in EP 508055, EP 1505164, EP 725154, EP 736885, EP 795367, DE 10012250, EP 1 142661, EP 1915765 and EP 2004349 and the documents cited therein. Particularly advantageous are the silver-based metal composites of EP 508055 and EP 1505164, to which reference is made. These are contact materials based on silver-tin oxide, which may additionally contain indium oxide, tellurium oxide, bismuth oxide, copper oxide, nickel oxide or mixtures thereof. Such materials can be produced by powder metallurgy or by internal oxidation.
Der Metallüberzug kann aus dem gleichen Metall bzw. Metallen bestehen wie der Metall-Verbundwerkstoff, welcher den Kern bildet, enthält jedoch keine der Inhaltsstoffe, welche die Verschweißfestigkeit des Metall-Verbundwerkstoffes bewirken. The metal coating may consist of the same metal (s) as the metal composite forming the core, but does not contain any of the ingredients which cause the weld strength of the metal composite.
Gemäß der vorliegenden Erfindung wird durch Schaben oder Spalten der Silbermantel eines Silberzinnoxiddrahtes aus dem Bereich der späteren Kontaktstelle entfernt. Auf diese Weise ist ein minimaler Edelmetallverlust gewährleistet und gleichzeitig wird eine Kontamination des schaltenden Bauteils mit dem Edelmetall im Bereich der Kontaktstelle vermieden und somit ein Verschweißen des Schaltkontakts verhindert. According to the present invention, the silver sheath of a silver tin oxide wire is removed from the region of the subsequent contact point by scraping or splitting. In this way, a minimum loss of precious metal is guaranteed and at the same time a contamination of the switching component with the noble metal in the region of the contact point is avoided and thus prevents welding of the switching contact.
Andererseits kann durch das direkte Aufschweißen des Silberzinnoxid- Kontaktmaterials auf einen Kontaktträger die Herstellung stark vereinfacht werden und die Fabrikationskosten niedrig gehalten werden. Der Edelmetalleinsatz ist minimal, da das Edelmetall nicht für mechanische Aufgaben verwendet werden muss. Im Bereich der Schaltstelle befindet sich kein schweißbares metallisches Edelmetall. On the other hand, by directly welding the silver tin oxide contact material to a contact carrier, the production can be greatly simplified and the manufacturing cost can be kept low. The use of precious metals is minimal because the precious metal does not have to be used for mechanical tasks. In the area of the switching point there is no weldable metallic precious metal.
Gemäß einer vorteilhaften Ausführungsform der vorliegenden Erfindung wird ein Teil des Drahtes in einer axialen Richtung abgeschabt, so dass an dem kreisförmigen Querschnitt des Drahts ein Segment entfernt ist. Nach dem Aufteilen in zylindrische Halbzeuge und dem Umformen in einen elektrischen Kontakt kann auf diese Weise besonders einfach und mit vergleichsweise wenig Materialverlust der gewünschte Kontakt hergestellt werden. Will man noch mehr von dem metallischen Mantel entfernen, so können weitere Schabeschritte in radial versetzter Richtung durchgeführt werden. According to an advantageous embodiment of the present invention, a part of the wire is scraped in an axial direction so that a segment is removed at the circular cross section of the wire. After dividing into cylindrical semi-finished products and forming into an electrical contact, the desired contact can be produced in a particularly simple manner and with comparatively little material loss in this way. If you want to remove more of the metallic shell, so further scraper steps can be performed in radially offset direction.
Eine Ausführungsform, bei der überhaupt kein Abfall anfällt, ist dann gegeben, wenn der Draht mittig gespalten wird und beide Teile verwendbar bleiben. An embodiment in which there is no waste at all is given when the wire is split in the middle and both parts remain usable.
Die vorteilhaften Eigenschaften der vorliegenden Erfindung kommen insbesondere dann zum Tragen, wenn das erfindungsgemäße Kontaktelement in einem Schaltgerät, wie beispielsweise einem elektromagnetischen Relais, eingesetzt wird, da hier die Problematik des Verschweißens besonders kritisch ist. The advantageous properties of the present invention are particularly useful when the contact element according to the invention in a switching device, such as an electromagnetic relay, is used, since the problem of welding is particularly critical here.
Zum besseren Verständnis der vorliegenden Erfindung wird diese anhand der in den nachfolgenden Figuren dargestellten Ausführungsbeispiele näher erläutert. Dabei werden gleiche Teile mit gleichen Bezugszeichen und gleichen Bauteilbezeichnungen versehen. Weiterhin können auch einige Merkmale oder Merkmalskombinationen aus den gezeigten und beschriebenen Ausführungsformen für sich eigenständige erfinderische oder erfindungsgemäße Lösungen darstellen. Es zeigen: For a better understanding of the present invention, this will be explained in more detail with reference to the embodiments illustrated in the following figures. The same parts are provided with the same reference numerals and the same component names. Furthermore, some features or combinations of features from the embodiments shown and described may also represent separate inventive or inventive solutions. Show it:
Fig. 1 eine schematische Perspektivdarstellung eines fertigen Kontaktelements; Fig. 2 eine perspektivische Darstellung des aufgeschweißten erfindungsgemäßen Halbzeugs vor dem Umformen; Fig. 1 is a schematic perspective view of a finished contact element; FIG. 2 shows a perspective view of the welded-on semifinished product according to the invention before forming; FIG.
Fig. 3 einen Querschnitt des ummantelten Drahts vor dem Schaben; Fig. 3 is a cross-section of the sheathed wire before cockroaches;
Fig. 4 einen Querschnitt des Drahtes nach einem ersten Schabeschritt; 4 shows a cross section of the wire after a first scraping step;
Fig. 5 einen Querschnitt des Drahtes nach einem Spaltschritt; 5 shows a cross section of the wire after a splitting step;
Fig. 6 einen Querschnitt des Drahtes nach dem Durchführen mehrerer Schabeschritte. Fig. 6 shows a cross section of the wire after performing several Schabeschritte.
Fig. 1 zeigt in einer perspektivischen Darstellung das erfindungsgemäße Kontaktelement 100 am Beispiel eines Relaiskontakts. Der eigentliche elektrische Kontakt 102 ist mit einem hier nur schematisch dargestellten Kontaktträger 104 durch Verschweißen verbunden. Die Kontaktfläche 106, die im Betrieb mit einem Gegenkontakt in elektrische Verbindung kommt, ist dabei durch ein Material gebildet, welches keine Verschweißneigung aufweist. Gemäß der vorliegenden Ausführungsform ist dies ein Silber-Zinnoxid-Verbundmaterial. Es kommen hier aber auch andere Verbundmaterialien in Frage, die beispielsweise Cadmiumoxid, Indiumoxid, Zinkoxid, Kupferoxid, Antimonoxid, Lanthanoxid, Magnesiumoxid, Manganoxid, Wismutoxid, oder Telluroxid oder eine Kombination daraus enthalten. In dem Bereich der Schweißstelle 108 liegt ein Metallmantel 1 14, insbesondere ein Edelmetallmantel, im vorliegenden Fall metallisches Silber, vor, wodurch die Fixierung des Kontakts 102 an dem Träger 104 über ein einfaches Schweißen möglich ist. 1 shows a perspective view of the contact element 100 according to the invention using the example of a relay contact. The actual electrical contact 102 is connected to a contact carrier 104 shown here only schematically by welding. The contact surface 106, which comes into electrical connection with a mating contact during operation, is formed by a material which has no tendency to weld. According to the present embodiment, this is a silver-tin oxide composite material. But there are also other composite materials in question, for example, cadmium oxide, indium oxide, zinc oxide, copper oxide, antimony oxide, lanthanum oxide, magnesium oxide, manganese oxide, bismuth oxide, or tellurium oxide or a combination thereof. In the region of the weld 108 is a metal shell 1 14, in particular a noble metal sheath, in the present case, metallic silver, before, whereby the fixation of the contact 102 on the carrier 104 via a simple welding is possible.
Fig. 2 zeigt in perspektivischer Ansicht eine Vorstufe des Kontakts 100, bei der das erfindungsgemäße Halbzeug 1 10 auf dem Kontaktträger 104 fixiert ist. 2 shows a perspective view of a preliminary stage of the contact 100, in which the semifinished product 1 10 according to the invention is fixed on the contact carrier 104.
Wie in Fig. 2 schematisch angedeutet, besteht das Halbzeug aus einem zylindrischen Edelmetall/Metalloxidkern 1 12, der teilweise von einem metallischen Edelmetallmantel 1 14 umgeben ist. Der Mantel 1 14, der aus einem schweißbaren Material besteht, ist insbesondere im Bereich der Schweißstelle 108 angeordnet. Im Bereich der späteren Kontaktstelle 106 ist der Mantel dagegen entfernt. Durch Ausüben von Druck in einer Richtung 1 16 auf den Kontaktträger 104 zu, wird das Halbzeug 1 10 anschlie- ßend in den eigentlichen Kontakt 102 umgeformt. Dabei ist zu bemerken, dass die Vorformrichtung 1 16 quer zu einer Längsachse 118 des Drahtstücks verläuft. As indicated schematically in FIG. 2, the semifinished product consists of a cylindrical noble metal / metal oxide core 1 12 which is partially surrounded by a metallic noble metal shell 14. The jacket 1 14, which consists of a weldable material is arranged in particular in the region of the weld 108. In the area of the later contact point 106, however, the jacket is removed. By applying pressure in a direction 1 16 to the contact carrier 104, the semifinished product 1 10 is subsequently connected. ßend transformed into the actual contact 102. It should be noted that the preforming direction 1 16 extends transversely to a longitudinal axis 118 of the piece of wire.
Die Fig. 3 bis 6 erläutern verschiedene spezielle Möglichkeiten, den späteren Kontaktbereich 106 von der metallischen Silberschicht zu befreien. Dabei wird jeweils ein Schnitt durch den Draht 120, aus dem durch Schneiden quer zu seiner Längsachse das Halbzeug 110 hergestellt wird, gezeigt. Fig. 3 zeigt das Rohteil, bei dem ein Kern 1 12, der wie bereits erwähnt, beispielsweise aus Silber-Zinnoxid-Verbundwerkstoff bestehen kann, mit einem metallischen Edelmetallmantel 1 14 umgeben ist. Bei dem Edelmetall handelt es sich beispielsweise um metallisches Silber. Wie in Fig. 4 gezeigt, kann das teilweise Entfernen der metallischen Mantelschicht 1 14 durch Abschaben eines Segments des Querschnitts erfolgen. FIGS. 3 to 6 explain various special possibilities for freeing the later contact region 106 from the metallic silver layer. In each case, a section through the wire 120, from which the semifinished product 110 is produced by cutting transversely to its longitudinal axis, is shown. Fig. 3 shows the blank, in which a core 1 12, which, as already mentioned, may for example consist of silver-tin oxide composite material, with a metallic noble metal sheath 1 14 is surrounded. The precious metal is, for example, metallic silver. As shown in Fig. 4, the partial removal of the metallic cladding layer 1 14 can be done by scraping a segment of the cross section.
Alternativ kann entweder bis zur Mitte 122 des Drahtes 120 geschabt werden oder der Draht in zwei Hälften gespalten werden, wie dies in Fig. 5 dargestellt ist. Die in Fig. 5 gezeigte Variante bietet zwar als Halbzeug den Vorteil, eine möglichst große, silberfreie Kontaktfläche 106 zu bieten, hat aber den Nachteil, dass vergleichsweise viel Material verloren geht, wenn dieser Querschnitt durch Schaben hergestellt wird. Verwendet man ein Spaltverfahren, bei dem beide Hälften des Drahtes verwendbar bleiben, stellt diese Variante allerdings die materialsparendste Lösung dar. Alternatively, either scraping to the center 122 of the wire 120 or splitting the wire into two halves, as shown in FIG. Although the variant shown in FIG. 5 offers the advantage, as semi-finished product, of offering the largest possible silver-free contact surface 106, it has the disadvantage that comparatively much material is lost if this cross section is produced by scraping. However, if a split method is used in which both halves of the wire remain usable, this variant represents the material-saving solution.
Fig. 6 zeigt eine Ausführungsform, bei der möglichst viel von dem metallischen Silbermantel 1 14 aus dem späteren Kontaktbereich dadurch entfernt wird, dass zwei weitere Schabeschritte in radial versetzter Richtung zu dem ersten Schabeschritt durchgeführt werden. FIG. 6 shows an embodiment in which as much as possible of the metallic silver sheath 14 is removed from the later contact region by carrying out two further shaving steps in a radially offset direction to the first shaving step.
In der nachfolgenden Tabelle 1 werden für die Versionen der Fig. 4, 5 und 6 in Bezug auf die Querschnittsfläche die jeweiligen Materialverluste für den Fall verglichen, dass ein Drahtdurchmesser von ca. 1 ,2 mm mit einer Silberbeschichtung von 40 μιη betrachtet wird. Tabelle 1 In the following Table 1, the respective material losses for the versions of FIGS. 4, 5 and 6 in relation to the cross-sectional area are compared in the case that a wire diameter of approximately 1.2 mm is considered with a silver coating of 40 μm. Table 1
Wie aus dieser Übersicht deutlich wird, ist der geringste Materialverlust bei der Variante der Fig. 4 zu verzeichnen, während aber die Variante der Fig. 6 die effektivste Entfernung des Mantelmaterials beinhaltet. As is clear from this overview, the least loss of material is recorded in the variant of FIG. 4, but the variant of FIG. 6 involves the most effective removal of the jacket material.
Zusammenfassend lässt sich feststellen, dass die erfindungsgemäße Herstellung von Kontaktelementen, beispielsweise für schaltende oder führende Kontakte an Relais, zum Einen eine einfache Herstellbarkeit durch das direkte Aufschweißen des Silber- Zinnoxid-Kontaktmaterials erlaubt, aber zum Anderen eine besonders geringe Verschweißneigung im Bereich des eigentlichen elektrischen Kontakt sicherstellt. Durch sparsame Verwendung von edelmetallhaltigen Ausgangsstoffen können die Kosten weiter gesenkt werden. In summary, it can be stated that the production according to the invention of contact elements, for example for switching or leading contacts on relays, on the one hand allows easy manufacturability by the direct welding of the silver-tin oxide contact material, but on the other hand a particularly low tendency to weld in the region of the actual electrical Contact ensures. Through economical use of precious metal-containing raw materials, the costs can be further reduced.
BezugszeichenbeschreibungReference numeral Description
100 Kontaktelement 100 contact element
102 elektrischer Kontakt 102 electrical contact
104 Kontaktträger 104 contact carrier
106 Kontaktfläche 106 contact surface
108 Schweißstelle 108 weld
1 10 Halbzeug 1 10 semifinished product
1 12 Kern 1 12 core
1 14 Mantel 1 14 coat
1 16 Richtung des Umformdrucks 1 16 direction of the forming pressure
1 18 Längsachse des Drahtes1 18 longitudinal axis of the wire
120 Draht 120 wire
122 Mitte des Drahtquerschnitts 122 middle of the wire cross section
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US29553010P | 2010-01-15 | 2010-01-15 | |
DE102010014745A DE102010014745B4 (en) | 2010-01-15 | 2010-04-13 | Electric contact element and method for producing an electrical contact element |
PCT/EP2011/050482 WO2011086167A1 (en) | 2010-01-15 | 2011-01-14 | Electric contact element and method for producing an electric contact element |
Publications (2)
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EP2524384A1 true EP2524384A1 (en) | 2012-11-21 |
EP2524384B1 EP2524384B1 (en) | 2016-11-30 |
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EP11700420.0A Not-in-force EP2524384B1 (en) | 2010-01-15 | 2011-01-14 | Electrical contact element and method for producing it |
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US (1) | US8749330B2 (en) |
EP (1) | EP2524384B1 (en) |
JP (2) | JP2013517594A (en) |
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BR (1) | BR112012017590B1 (en) |
DE (1) | DE102010014745B4 (en) |
ES (1) | ES2613615T3 (en) |
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EP2644723B1 (en) * | 2012-03-26 | 2017-01-18 | Umicore AG & Co. KG | Composite material |
CN104810178B (en) * | 2015-03-30 | 2017-03-15 | 宁波金点电子有限公司 | A kind of three composite electric contact manufacture devices |
US10446336B2 (en) | 2016-12-16 | 2019-10-15 | Abb Schweiz Ag | Contact assembly for electrical devices and method for making |
CN112059168B (en) * | 2020-08-08 | 2022-07-05 | 浙江福达合金材料科技有限公司 | Method for preparing silver metal oxide electric contact material based on nano silver wire modification and 3D gradient printing and product thereof |
CN113192781B (en) * | 2021-03-17 | 2024-03-29 | 南京美铭信息技术服务有限公司 | Adjustable coating scraping electric contact semi-finished product preparation device |
Family Cites Families (18)
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US2433687A (en) * | 1943-09-27 | 1947-12-30 | Metals & Controls Corp | Electrical contact |
US2434992A (en) * | 1943-09-27 | 1948-01-27 | Metals & Controls Corp | Electrical contact |
DE2036373A1 (en) * | 1970-07-17 | 1972-01-20 | Siemens Ag | SWITCHING UNIT FOR ELECTRIC SWITCHES |
US3775067A (en) * | 1971-12-06 | 1973-11-27 | Textron Inc | Copper backed electrical contact |
CH607729A5 (en) * | 1976-09-21 | 1978-10-13 | Rau Fa G | Contact body and a production method for said contact body |
US4706383A (en) * | 1986-10-27 | 1987-11-17 | Honeywell Inc. | Electrical contact assembly with composite contact construction |
JP2721248B2 (en) * | 1989-07-21 | 1998-03-04 | 田中貴金属工業株式会社 | Manufacturing method of composite contact strip |
EP0508055B1 (en) * | 1991-04-12 | 1997-05-02 | Mitsubishi Materials Corporation | Silver-base metal oxide material for electrical contacts |
DE19503182C1 (en) | 1995-02-01 | 1996-05-15 | Degussa | Sintered material used as electrical contacts for switching amperage rating |
DE19503184C1 (en) * | 1995-02-01 | 1996-05-02 | Degussa | Ag-based material for electrical contacts with improved erosion characteristics and resistant to welding |
DE19607183C1 (en) | 1996-02-27 | 1997-04-10 | Degussa | Sintered silver@-iron@ alloy for making electrical contacts |
DE10012250B4 (en) * | 2000-03-14 | 2006-06-01 | Umicore Ag & Co. Kg | Contact materials based on silver-iron-copper |
DE10017282C2 (en) * | 2000-04-06 | 2002-02-14 | Omg Ag & Co Kg | Process for the production of composite powder based on siler tin oxide and its use for the production of contact materials |
DE602004020844D1 (en) * | 2003-08-08 | 2009-06-10 | Mitsubishi Materials C M I Corp | A method of making an electrical contact of high electrical conductivity for an electromagnetic relay and electrical contact therewith |
WO2007020007A1 (en) | 2005-08-12 | 2007-02-22 | Umicore Ag & Co. Kg | Silver/carbon-based material and method for producing the same |
US7566437B2 (en) | 2006-03-31 | 2009-07-28 | Umicore Ag & Co. Kg | Process for manufacture of silver-based composite powders for electrical contact materials and composite powders so produced |
DE102007040171A1 (en) * | 2007-08-22 | 2009-02-26 | Siemens Ag | Contact lever for circuit-breaker of circuit-breaker arrangement, has composite material with one material arranged between side surfaces of another material, where latter material includes higher conductivity and higher density |
FR2931303A1 (en) * | 2008-05-15 | 2009-11-20 | Daniel Bernard | Electrical contact system i.e. electrical conductor, manufacturing method for e.g. circuit breaker, involves performing metallic or composite coating by cold or heat spray, and finishing layer by surfacing or polishing |
-
2010
- 2010-04-13 DE DE102010014745A patent/DE102010014745B4/en not_active Expired - Fee Related
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2011
- 2011-01-14 WO PCT/EP2011/050482 patent/WO2011086167A1/en active Application Filing
- 2011-01-14 CN CN201180005794.5A patent/CN102782787B/en active Active
- 2011-01-14 US US13/521,964 patent/US8749330B2/en active Active
- 2011-01-14 ES ES11700420.0T patent/ES2613615T3/en active Active
- 2011-01-14 JP JP2012548449A patent/JP2013517594A/en not_active Withdrawn
- 2011-01-14 EP EP11700420.0A patent/EP2524384B1/en not_active Not-in-force
- 2011-01-14 BR BR112012017590-4A patent/BR112012017590B1/en active IP Right Grant
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2015
- 2015-06-16 JP JP2015120999A patent/JP6280524B2/en active Active
Non-Patent Citations (1)
Title |
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See references of WO2011086167A1 * |
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US20130002380A1 (en) | 2013-01-03 |
JP2013517594A (en) | 2013-05-16 |
CN102782787B (en) | 2016-02-24 |
EP2524384B1 (en) | 2016-11-30 |
JP6280524B2 (en) | 2018-02-14 |
ES2613615T3 (en) | 2017-05-24 |
JP2015201454A (en) | 2015-11-12 |
WO2011086167A1 (en) | 2011-07-21 |
US8749330B2 (en) | 2014-06-10 |
BR112012017590A2 (en) | 2016-08-16 |
CN102782787A (en) | 2012-11-14 |
DE102010014745A1 (en) | 2011-07-21 |
DE102010014745B4 (en) | 2011-09-22 |
BR112012017590B1 (en) | 2020-03-31 |
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