EP2467518B1 - Reinforcement strands of parallel glass fibers - Google Patents
Reinforcement strands of parallel glass fibers Download PDFInfo
- Publication number
- EP2467518B1 EP2467518B1 EP10754571.7A EP10754571A EP2467518B1 EP 2467518 B1 EP2467518 B1 EP 2467518B1 EP 10754571 A EP10754571 A EP 10754571A EP 2467518 B1 EP2467518 B1 EP 2467518B1
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- EP
- European Patent Office
- Prior art keywords
- fibers
- layer
- molding reinforcement
- reinforcement
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
- D04H1/08—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres and hardened by felting; Felts or felted products
- D04H1/10—Felts made from mixtures of fibres
- D04H1/14—Felts made from mixtures of fibres and incorporating inorganic fibres
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/002—Inorganic yarns or filaments
- D04H3/004—Glass yarns or filaments
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/02—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/06—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/12—Glass fibres
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24058—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
- Y10T428/24124—Fibers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/609—Cross-sectional configuration of strand or fiber material is specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/643—Including parallel strand or fiber material within the nonwoven fabric
- Y10T442/644—Parallel strand or fiber material is glass
Definitions
- the present invention relates to coherent and flexible textile reinforcement used as a reinforcing product of composite articles, that is to say of resin-based articles (polyester or other) reinforced with reinforcing fibers.
- the textile reinforcement is generally in the form of a flexible sheet packaged in a reel, which can thus be transported and handled at the place of use for the production of a composite article.
- a piece of appropriate surface of textile reinforcement is cut, it is placed in a mold, and a resin is penetrated which comes to drown the reinforcement in the mold. After polymerization, the resin and the reinforcement form a mechanically resistant structure.
- the mechanical strength properties are obtained provided that the resin penetrates perfectly between the fibers forming the reinforcement, without leaving areas devoid of resin, and adhering perfectly to the fibers. It is also necessary that the fibers regularly occupy the volume of the composite article to be produced, in particular by following the shapes of the article when it is not flat.
- the document EP 0 395 548 discloses the use of two layers of textile reinforcement, for example glass fibers, arranged on either side of a central layer consisting of a sheet of permanent-wave synthetic fibers, for example polyester fibers of 40 to 70 mm long that received a texturizing treatment.
- the textile reinforcement layers are bonded to the central layer by stitching / knitting.
- the document EP 0 694 643 discloses the use of two layers of textile reinforcement disposed on either side of a central layer giving the thickness of said material, the layers being bonded together by sewing / knitting, and is provided against one of the outer faces a veil of synthetic fibers glued or sewn.
- Sewing / knitting techniques are relatively slow, and the textile reinforcement thus produced have non-uniform deformation capabilities, and surface appearance defects.
- thermofusible surface fiber segments penetrate along part of their length into the inner layer and partially adhere to each other and to the synthetic fibers of the inner layer.
- An advantage of this structure is to give textile reinforcements great flexibility and great deformation capacity to follow the shapes of complex molds, the crimped synthetic fibers ensuring the maintenance of a sufficient volume of the inner layer for good penetration of the resin during subsequent molding.
- the reinforcing fibers such as sections of 50 mm glass fibers, present in the outer layers, make it possible to improve the mechanical characteristics of the composite article. But this improvement is small, because these reinforcing fibers are short and necessarily small, the proportion of glass fibers being limited by the presence of predominant synthetic fibers permanently crimped. For some applications, it remains desirable to significantly increase the mechanical characteristics of the composite article, including its resistance to rupture or bending.
- wire refers to a set of single glass filaments, which generally have a diameter of 5 ⁇ m to 24 ⁇ m.
- a thread usually includes the order of 40 filaments.
- a set of threads is called a wick.
- a wick generally comprises about 50 wires.
- the disadvantage of this known technique is the necessary presence of an adhesive to ensure the cohesion of the reinforcing product during its handling before injection molding. Indeed, the glue is likely to reduce the penetration capacity of the resin during molding, and to reduce the short or long term mechanical strength of the composite article from the molding.
- the locks are assembled by stitching, which is a relatively slow process, and there is a need to increase substantially the speed of production of the textile reinforcements, to reach speeds of more than 10 m / min.
- the invention goes against these difficulties and makes it possible to solve them.
- the problem proposed by the present invention is to substantially increase the mechanical strength of the composite articles made from glass fiber molding reinforcements, while retaining the properties of consistency, flexibility and deformability of the molding reinforcements before molding, and retaining good properties of penetration and printing of the resin during molding.
- the invention aims to design a molding reinforcement that can be produced at high speed, reaching speeds of more than 10 m / min.
- the invention proposes to improve if necessary the regularity of the surface of the composite articles made by molding the molding reinforcements.
- the invention also aims to allow the realization of reinforcing products continuous web, can be packaged in a coil, and can be cut or cut without risk of fraying or degradation of the edges.
- thermofusible surface fibers of the bonding layer ensure the effective bonding of the strands of glass son without external glue, while maintaining flexibility and regularity of the molding reinforcement, and without deforming or breaking the glass son.
- such a molding reinforcement structure can be realized at a high speed, since interpenetration of the hot-melt surface fibers can be achieved by a light needling step, which is much faster than the sewing process.
- the sections of thermofusible surface fibers that penetrate the reinforcing layer are relatively spaced from each other, this spacing being equal to or greater than the needle pitch of a light needling: the surface density of such a light needling is about 5 to 10 needle penetrations per cm 2 of backing layer. This results in a reduction of the bending stresses exerted on the glass fibers, and a corresponding reduction in the risks of rupture of the glass fibers.
- the invention thus makes it possible to use the excellent mechanical properties of the unidirectional wicks of glass fibers, conferring excellent mechanical properties on composite articles made by molding such a reinforcement.
- the bonding layer of which certain fiber sections penetrate and adhere to the fibers of the reinforcing layer, provides a sufficient temporary retention of the glass strands of the reinforcing layer after manufacture and before use of the molding reinforcement, conferring on the molding reinforcement a satisfactory coherence.
- the penetrating and adherent fiber bonding layer makes it possible to maintain the glass strands with only a small amount of material other than glass, that is to say by maximizing the relative amount of glass in the reinforcement. molding.
- the bonding layer may be particularly thin, in the form of a web of fibers, for example with a basis weight of about 25 to 30 g / m 2 .
- the strands of glass strands may advantageously have a titer of between 2,400 and 4,800 tex approximately.
- the glass strands may advantageously be formed of an assembly of filaments having a unit diameter of between about 14 microns and about 17 microns.
- the glass strands of the wicks may have a unitary title of 40 to 80 tex approximately.
- the reinforcing layer is bonded to a single heat-fusible surface fiber bonding layer.
- the reinforcing layer is bonded to two heat-fusible surface fiber bonding layers disposed on either side of the reinforcing layer.
- the intermediate layer may comprise a layer of glass threads of approximately 160 to 200 tex, parallel and oriented perpendicularly to the wicks, and / or a layer of glass fibers cut at approximately 50 mm, in bulk at all orientations, according to a weight of Approximately 50 to 80 g / m 2 .
- the molding reinforcement according to the invention may have a grammage of between 400 and 1800 g / m 2 . This provides a good compromise between the thickness of the molding reinforcement and its deformation capacity before molding. For example, with five locks of 2400 tex per cm is produced a weight of 1200 g / m 2 .
- step a) a second web of chemical fibers with a hot-melt surface is placed on the support, constituting a second bonding layer, and then the strands of glass strands on the second bonding layer; in step c), a light double-sided switch is made.
- step a) In the case of an intermediate layer reinforcement, between step a) and step b), the pre-cut yarns or glass fibers of the intermediate layer are placed on the reinforcing layer.
- needles are used whose driving barbs are placed in a diametral plane parallel to the direction of the son son of glass strands. In this way, it is avoided to break the glass son, and it is guaranteed to obtain a reinforcement providing a high mechanical strength to composite articles made from such a reinforcement.
- a molding reinforcement 1 according to the invention comprises two fiber layers, namely a reinforcing layer 2 and a bonding layer 3.
- the reinforcing layer 2 comprises strands of glass threads, such as the strands 2a, 2b, 2c ( figure 5 ), which are parallel and arranged side by side in a single layer of wicks.
- the figure 2 represents such a wick 2a or wire bundle such as son 20a, 20b, 20c, generally parallel to each other.
- the continuous wires 20a, 20b, 20c are normally in contact with each other.
- the wick 2a is illustrated partially exploded, the son 20a, 20b, 20c deviating from each other in the right part of the figure, for a better understanding of the wick structure.
- the wires 20a, 20b, 20c remain in contact with each other.
- strands of continuous glass strands 20a ( figure 3 ), from a coil or "roving".
- the son are formed of an assembly of filaments such as filaments 200a, 200b, 200c whose unit diameter is between about 14 microns and about 17 microns.
- the unitary title of the glass strands 20a, 20b, 20c may for example be between 40 and 80 tex, by assembling about 50 glass filaments.
- the wires 20a, 20b, 20c are actually formed of a sufficient number of filaments to prevent them from breaking during handling and use according to the invention, it being observed that the isolated filaments, in the size in which they usually come out of manufacturing, are too fragile for such manipulations and uses.
- strands of cut glass strands having a length of about 10 cm to about 100 cm, are advantageously chosen, the strands being able to be offset longitudinally. relative to each other to overlap each other, and remaining each formed of an assembly of filaments.
- the length of such son is sufficient to ensure good mechanical properties to the composite article made by molding this molding reinforcement 1, and the elongation capacity improves the adaptation to a pre-existing object, for example to a tube for the covering of its outer or inner surface.
- This embodiment allows for example an application to the renovation of pipes in the basement.
- the bonding layer 3 comprises fiber sections 3a with a hot-melt surface.
- the fiber sections 3a with a hot-melt surface may be of any material having a sufficiently low melting temperature and good bonding properties with the glass strands 20a, 20b, 20c of the reinforcing layer 2.
- the fiber sections 3a with a hot-melt surface may be two-component chemical fibers, comprising a central core in polyamide, polyester or polypropylene, and an outer sheath of copolyester, polyethylene or any other material having a lower melting temperature than that of the central core.
- Good results can be obtained by using a central core made of polyester and an outer sheath made of copolyester, or a central core of polypropylene and an outer sheath of polyethylene.
- Other pairs of materials can be used as coaxial two-component fibers: polypropylene and copolypropylene, polypropylene and ethyl vinyl acetate.
- the central core of the two-component fiber has a higher melting temperature than the outer sheath, an accidental risk of complete melting of the first sections of hot-melt-surface fibers is avoided during the manufacture of the molding reinforcement.
- the hot-melt fiber sections are, by excessively high or poorly controlled heating, completely melted, forming uniform or impervious layers. to the resin by spreading their constituent material on the upper and lower faces of the reinforcing layer 2.
- the core of the bi-component fibers is not (or very little) impaired, and the properties of the tie layer 3 are thus preserved.
- bi-component hot-melt surface fibers outer sheath and central core reduces the polyolefin content of the molding reinforcement 1. This is advantageous, the resin being incompatible with the polyolefins.
- the fiber sections 3a with a hot-melt surface of the connecting layer 3 at least some of these sections, for example the penetrating sections 3b on the figure 1 , penetrate along part of their length in the reinforcing layer 2 and partially adhere to each other and to the glass strands 20a, 20b, 20c of the reinforcing layer 2.
- the penetrating sections 3b of fibers are regularly distributed along the surface of the molding reinforcement 1, for example at a surface density of 5 to 10 sections per cm 2 of molding reinforcement, and ensure cohesion of the assembly, while retaining the deformability and flexibility properties of the molding reinforcement 1.
- the molding reinforcement 1 according to the invention can be produced in the form of a continuous strip which is packaged in a long coil.
- the wicks 2a, 2b, 2c are formed of continuous glass strands 20a, 20b, 20c and are oriented in the direction of the strip length, or warp direction.
- a ply of strands of glass strands is deposited on a flat support to constitute the reinforcing layer 2
- a layer of fibers with a hot-melt surface is deposited on the reinforcing layer 2 to constitute the bonding layer 3.
- the assembly thus obtained is subjected to a light needling which penetrates at least 3b of the fiber sections 3a with hot-melt surface of the bonding layer in the reinforcing layer 2, the whole is heated to a temperature sufficient to soften the thermofusible portion of the penetrating sections 3b of thermofusible surface fibers and to ensure after cooling their bonding to the glass son 20a, 20b, 20c of the reinforcing layer 2.
- the figure 4 schematically illustrates the light needling operation, in which one distinguishes needles 8 of pre-needling, which cause penetrating sections 3b of hot-melt surface fibers to penetrate the reinforcing layer 2.
- the light needling carried out for example produces a surface density of perforations of about 5 to 10 perforations per cm 2 . This must be compared to needling processes which typically achieve densities at least 10 times higher.
- the light needling allows a large flow during the manufacture of the molding reinforcement according to the invention.
- the entrainment barbs such as the barbs 8a and 8b of the needles 8 are placed in a diametral plane containing the axis of the needle and parallel to the direction D of the son of the strands of threads. glass such as wick 2a. Due to the axial movement (arrow 8c) of the needle 8 during needling, the barbs 8a and 8b pass through the locks 2a by spacing the wires 20a, 20b, 20c ( figure 2 ) without breaking them.
- the light needling performed is sufficient to ensure cohesion during the transfer of the molding reinforcement blank to a next work station, but it is insufficient to ensure the final cohesion of the molding reinforcement 1 and it is still not transportable at the exit of the needling machine for use as reinforcement.
- the heating which is carried out after the light needling operation makes it possible to soften the hot-melt surface layer of the penetrating sections 3b of fibers of the tie layer 3 to make it adherent.
- the penetrating sections 3b of fibers which have been driven by the light needling needles 8 adhere to the glass strands 20a, 20b, 20c of the reinforcement layer 2.
- the various layers 2, 3 of the molding reinforcement 1 are thus bonded together by the 3b needled and glued fibers.
- the molding reinforcement 1 is then transportable.
- the heating is set to soften and adhere the penetrating sections 3b of hot-melt surface fibers, but without melting them.
- FIG 8 schematically illustrates a second embodiment of the molding reinforcement according to the invention.
- This second embodiment differs from the first embodiment of the figure 1 by the additional presence of a second bonding layer 4 on the other side of the reinforcing layer 2.
- Each bonding layer 3 or 4 is based on hot-melt surface fibers.
- thermofusible surface fibers are found which solidify the layers 2, 3 and 4.
- FIG. 7 schematically illustrates a third embodiment of the molding reinforcement according to the invention.
- This third embodiment differs from the first embodiment of the figure 1 by the additional presence of an intermediate layer 5 of glass threads between the reinforcing layer 2 and the bonding layer 3.
- the intermediate layer 5 comprises a layer 5a of glass threads of about 160 to 200 tex, parallel and oriented perpendicular to the wicks 2a, 2b and 2c, that is to say in the weft direction, and continuous along the entire width of the reinforcement.
- the intermediate layer 5 comprises a layer 5b of glass fibers cut about 50 mm, in bulk at all orientations, with a weight of 50 to 80 g / m 2 approximately.
- the intermediate layer 5 comprises a layer 5a of glass yarns in the weft direction and a layer 5b of glass fibers cut in bulk.
- This third embodiment is suitable for applications requiring transverse reinforcement in the weft direction, and can improve the surface regularity of the composite article.
- thermofusible surface fibers are found which solidify the layers 2, 3 and 5.
- the basis weight of the molding reinforcement 1 is between about 400 and 1,800 g / m 2 .
- the molding reinforcement 1 according to the invention can find advantageous applications in the manufacture of long composite parts, in particular wind turbine blades.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Nonwoven Fabrics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Moulding By Coating Moulds (AREA)
Description
La présente invention concerne les armatures textiles cohérentes et souples utilisées comme produit de renforcement d'articles composites, c'est-à-dire d'articles à base de résine (polyester ou autres) armée de fibres de renforcement.The present invention relates to coherent and flexible textile reinforcement used as a reinforcing product of composite articles, that is to say of resin-based articles (polyester or other) reinforced with reinforcing fibers.
On connaît déjà de nombreuses structures d'armature textile cohérente de renforcement constituées d'une ou plusieurs couches de fibres liées entre elles. L'armature textile se présente généralement sous forme d'une nappe souple conditionnée en bobine, que l'on peut ainsi transporter et manipuler sur le lieu d'utilisation pour la réalisation d'un article composite.Numerous coherent reinforcing textile reinforcing structures consisting of one or more layers of fibers bonded together are already known. The textile reinforcement is generally in the form of a flexible sheet packaged in a reel, which can thus be transported and handled at the place of use for the production of a composite article.
Pour la réalisation d'un article composite, on procède généralement de la façon suivante : on découpe une pièce de surface appropriée d'armature textile, on la place dans un moule, et l'on fait pénétrer une résine qui vient noyer l'armature dans le moule. Après polymérisation, la résine et l'armature forment une structure mécaniquement résistante.For the production of a composite article, the following procedure is generally carried out: a piece of appropriate surface of textile reinforcement is cut, it is placed in a mold, and a resin is penetrated which comes to drown the reinforcement in the mold. After polymerization, the resin and the reinforcement form a mechanically resistant structure.
Les propriétés de résistance mécanique sont obtenues à condition que la résine pénètre parfaitement entre les fibres formant l'armature, sans laisser de zones dépourvues de résine, et en adhérant parfaitement aux fibres. Il faut en outre que les fibres occupent de façon régulière le volume de l'article composite à réaliser, notamment en suivant les formes de l'article lorsque celui-ci n'est pas plan.The mechanical strength properties are obtained provided that the resin penetrates perfectly between the fibers forming the reinforcement, without leaving areas devoid of resin, and adhering perfectly to the fibers. It is also necessary that the fibers regularly occupy the volume of the composite article to be produced, in particular by following the shapes of the article when it is not flat.
Il faut enfin que les fibres présentent en elle-même une résistance mécanique satisfaisante pour réaliser une armature efficace.Finally, it is necessary that the fibers themselves have a satisfactory mechanical strength to achieve an effective reinforcement.
Diverses structures d'armatures textiles de renforcement ont déjà été proposées.Various reinforcing textile reinforcement structures have already been proposed.
Ainsi, le document
Le document
Les techniques de couture/tricotage sont relativement lentes, et les armatures textiles ainsi réalisées présentent des capacités de déformation non uniformes, et des défauts d'aspect en surface.Sewing / knitting techniques are relatively slow, and the textile reinforcement thus produced have non-uniform deformation capabilities, and surface appearance defects.
Pour augmenter les cadences de production et réduire des défauts résultant du tricotage, on a récemment proposé, dans les documents
Un intérêt de cette structure est de conférer aux renforts textiles une grande souplesse et une grande capacité de déformation pour suivre les formes de moules complexes, les fibres synthétiques frisées assurant le maintien d'un volume suffisant de la couche interne pour une bonne pénétration de la résine lors du moulage ultérieur.An advantage of this structure is to give textile reinforcements great flexibility and great deformation capacity to follow the shapes of complex molds, the crimped synthetic fibers ensuring the maintenance of a sufficient volume of the inner layer for good penetration of the resin during subsequent molding.
Les fibres de renfort telles que des tronçons de fibres de verre de 50 mm, présentes dans les couches externes, permettent d'améliorer les caractéristiques mécaniques de l'article composite. Mais cette amélioration est faible, car ces fibres de renfort sont courtes et sont nécessairement en faible quantité, la proportion de fibres de verre étant limitée par la présence prépondérante des fibres synthétiques à frisure permanente. Pour certaines applications, il reste souhaitable d'augmenter sensiblement les caractéristiques mécaniques de l'article composite, notamment sa résistance à la rupture ou à la flexion.The reinforcing fibers, such as sections of 50 mm glass fibers, present in the outer layers, make it possible to improve the mechanical characteristics of the composite article. But this improvement is small, because these reinforcing fibers are short and necessarily small, the proportion of glass fibers being limited by the presence of predominant synthetic fibers permanently crimped. For some applications, it remains desirable to significantly increase the mechanical characteristics of the composite article, including its resistance to rupture or bending.
Selon une technique connue de longue date et décrite dans le document
On appelle fil un ensemble de filaments unitaires de verre, qui ont généralement un diamètre de 5 µm à 24 µm. Un fil comprend généralement de l'ordre de 40 filaments. On appelle mèche un ensemble de fils. Une mèche comprend généralement 50 fils environ.The term "wire" refers to a set of single glass filaments, which generally have a diameter of 5 μm to 24 μm. A thread usually includes the order of 40 filaments. A set of threads is called a wick. A wick generally comprises about 50 wires.
L'inconvénient de cette technique connue reste la présence nécessaire d'une colle pour assurer la cohésion du produit de renforcement lors de ses manipulations avant moulage par injection. En effet, la colle est susceptible de réduire la capacité de pénétration de la résine lors du moulage, et de réduire la résistance mécanique à court ou long terme de l'article composite issu du moulage.The disadvantage of this known technique is the necessary presence of an adhesive to ensure the cohesion of the reinforcing product during its handling before injection molding. Indeed, the glue is likely to reduce the penetration capacity of the resin during molding, and to reduce the short or long term mechanical strength of the composite article from the molding.
Jusqu'à présent, dans les renforts cohérents à base de mèches unidirectionnelles de fibres de verre, les mèches sont assemblées par couture, ce qui est un procédé relativement lent, et un besoin existe d'augmenter sensiblement la vitesse de production des renforts textiles, pour atteindre des vitesses de plus de 10 m/min.Until now, in the coherent reinforcements based on unidirectional strands of glass fibers, the locks are assembled by stitching, which is a relatively slow process, and there is a need to increase substantially the speed of production of the textile reinforcements, to reach speeds of more than 10 m / min.
L'invention va à l'encontre de ces difficultés et permet de les résoudre.The invention goes against these difficulties and makes it possible to solve them.
Le problème proposé par la présente invention est d'augmenter sensiblement la résistance mécanique des articles composites réalisés à partir de renforts de moulage à fibres de verre, tout en conservant les propriétés de cohérence, de souplesse et de déformabilité des renforts de moulage avant moulage, et en conservant de bonnes propriétés de pénétration et d'impression de la résine lors du moulage.The problem proposed by the present invention is to substantially increase the mechanical strength of the composite articles made from glass fiber molding reinforcements, while retaining the properties of consistency, flexibility and deformability of the molding reinforcements before molding, and retaining good properties of penetration and printing of the resin during molding.
Simultanément, l'invention vise à concevoir un renfort de moulage qui puisse être produit à grande vitesse, en atteignant des vitesses de plus de 10 m/min.Simultaneously, the invention aims to design a molding reinforcement that can be produced at high speed, reaching speeds of more than 10 m / min.
En complément, l'invention propose d'améliorer si nécessaire la régularité de la surface des articles composites réalisés par moulage des renforts de moulage.In addition, the invention proposes to improve if necessary the regularity of the surface of the composite articles made by molding the molding reinforcements.
De préférence, l'invention vise également à permettre la réalisation de produits de renforcement en bande continue, pouvant être conditionnée en bobine, et pouvant être découpée ou tronçonnée sans risque d'effilochage ou de dégradation des bords.Preferably, the invention also aims to allow the realization of reinforcing products continuous web, can be packaged in a coil, and can be cut or cut without risk of fraying or degradation of the edges.
Pour atteindre ces buts ainsi que d'autres, l'invention propose un renfort de moulage en nappe à base de fibres, comprenant :
- une première couche de fibres,
- au moins une couche de liaison en tronçons de fibres à surface thermofusible, liée à la première couche de fibres,
- certains au moins des tronçons de fibres à surface thermofusible pénétrant selon une partie de leur longueur dans la première couche de fibres et adhérant partiellement entre eux et aux fibres de la première couche de fibres,
- a first layer of fibers,
- at least one bonding layer of fiber sections with a hot-melt surface, bonded to the first layer of fibers,
- at least some sections of thermofusible surface fibers penetrating along part of their length in the first layer of fibers and partially adhering to each other and to the fibers of the first layer of fibers,
Les fibres à surface thermofusible de la couche de liaison assurent la liaison efficace des mèches de fils de verre sans apport extérieur de colle, tout en conservant une souplesse et une régularité du renfort de moulage, et sans déformer ou rompre les fils de verre.The thermofusible surface fibers of the bonding layer ensure the effective bonding of the strands of glass son without external glue, while maintaining flexibility and regularity of the molding reinforcement, and without deforming or breaking the glass son.
Simultanément, une telle structure de renfort de moulage peut être réalisée à grande vitesse, du fait que l'interpénétration des fibres à surface thermofusible peut être obtenue par une étape d'aiguilletage léger, qui est beaucoup plus rapide que le procédé de couture.Simultaneously, such a molding reinforcement structure can be realized at a high speed, since interpenetration of the hot-melt surface fibers can be achieved by a light needling step, which is much faster than the sewing process.
De préférence, les tronçons de fibres à surface thermofusible qui pénètrent dans la couche de renfort sont relativement écartés les uns des autres, cet écartement étant égal ou supérieur au pas des aiguilles d'un aiguilletage léger : la densité surfacique d'un tel aiguilletage léger est d'environ 5 à 10 pénétrations d'aiguille par cm2 de couche de renfort. Il en résulte une réduction des contraintes de flexion exercées sur les fibres de verre, et une réduction correspondante des risques de rupture des fibres de verre.Preferably, the sections of thermofusible surface fibers that penetrate the reinforcing layer are relatively spaced from each other, this spacing being equal to or greater than the needle pitch of a light needling: the surface density of such a light needling is about 5 to 10 needle penetrations per cm 2 of backing layer. This results in a reduction of the bending stresses exerted on the glass fibers, and a corresponding reduction in the risks of rupture of the glass fibers.
L'invention permet ainsi d'utiliser les excellentes propriétés mécaniques des mèches unidirectionnelles de fils de verre, conférant d'excellentes propriétés mécaniques aux articles composites réalisés par moulage d'un tel renfort. La couche de liaison, dont certains tronçons de fibres pénètrent et adhèrent aux fibres de la couche de renfort, assure un maintien provisoire suffisant des fils de verre de la couche de renfort après fabrication et avant utilisation du renfort de moulage, conférant au renfort de moulage une cohérence satisfaisante.The invention thus makes it possible to use the excellent mechanical properties of the unidirectional wicks of glass fibers, conferring excellent mechanical properties on composite articles made by molding such a reinforcement. The bonding layer, of which certain fiber sections penetrate and adhere to the fibers of the reinforcing layer, provides a sufficient temporary retention of the glass strands of the reinforcing layer after manufacture and before use of the molding reinforcement, conferring on the molding reinforcement a satisfactory coherence.
Simultanément, la couche de liaison à fibres pénétrantes et adhérentes permet d'assurer le maintien des fils de verre avec seulement une faible quantité de matière autre que le verre, c'est-à-dire en maximisant la quantité relative de verre dans le renfort de moulage.At the same time, the penetrating and adherent fiber bonding layer makes it possible to maintain the glass strands with only a small amount of material other than glass, that is to say by maximizing the relative amount of glass in the reinforcement. molding.
La couche de liaison peut être particulièrement mince, sous forme d'un voile de fibres, par exemple selon un grammage de l'ordre de 25 à 30 g/m2.The bonding layer may be particularly thin, in the form of a web of fibers, for example with a basis weight of about 25 to 30 g / m 2 .
Les mèches de fils de verre peuvent avantageusement avoir un titre compris entre 2 400 et 4 800 tex environ.The strands of glass strands may advantageously have a titer of between 2,400 and 4,800 tex approximately.
Dans une telle mèche les fils de verre peuvent avantageusement être formés d'un assemblage de filaments ayant un diamètre unitaire compris entre environ 14 µm et environ 17 µm.In such a wick the glass strands may advantageously be formed of an assembly of filaments having a unit diameter of between about 14 microns and about 17 microns.
En alternative ou en complément, les fils de verre des mèches peuvent avoir un titre unitaire de 40 à 80 tex environ.Alternatively or in addition, the glass strands of the wicks may have a unitary title of 40 to 80 tex approximately.
Selon un premier mode de réalisation, la couche de renfort est liée à une seule couche de liaison en fibres à surface thermofusible.According to a first embodiment, the reinforcing layer is bonded to a single heat-fusible surface fiber bonding layer.
Selon un second mode de réalisation, la couche de renfort est liée à deux couches de liaison en fibres à surface thermofusible, disposées de part et d'autre de la couche de renfort.According to a second embodiment, the reinforcing layer is bonded to two heat-fusible surface fiber bonding layers disposed on either side of the reinforcing layer.
Selon un troisième mode de réalisation, dans une structure de l'un des modes de réalisation précédents, on prévoit en outre une couche intermédiaire de fils de verre entre la couche de renfort et la couche de liaison.According to a third embodiment, in a structure of one of the preceding embodiments, there is further provided an intermediate layer of glass son between the reinforcing layer and the bonding layer.
La couche intermédiaire peut comprendre une couche de fils de verre de 160 à 200 tex environ, parallèles et orientés perpendiculairement aux mèches, et/ou une couche de fibres de verre coupées de 50 mm environ, en vrac à toutes orientations, selon un grammage de 50 à 80 g/m2 environ.The intermediate layer may comprise a layer of glass threads of approximately 160 to 200 tex, parallel and oriented perpendicularly to the wicks, and / or a layer of glass fibers cut at approximately 50 mm, in bulk at all orientations, according to a weight of Approximately 50 to 80 g / m 2 .
De façon avantageuse, le renfort de moulage selon l'invention peut présenter un grammage compris entre 400 et 1 800 g/m2. On réalise ainsi un bon compromis entre l'épaisseur du renfort du moulage et sa capacité de déformation avant moulage. A titre d'exemple, avec cinq mèches de 2 400 tex au cm on réalise un grammage de 1 200 g/m2.Advantageously, the molding reinforcement according to the invention may have a grammage of between 400 and 1800 g / m 2 . This provides a good compromise between the thickness of the molding reinforcement and its deformation capacity before molding. For example, with five locks of 2400 tex per cm is produced a weight of 1200 g / m 2 .
Selon un autre aspect, l'invention propose un procédé de fabrication d'un tel renfort de moulage, comprenant les étapes de :
- a) sur un support, déposer côte à côte une pluralité de mèches de fils de verre parallèles, pour former une nappe de mèches de fils de verre constituant une couche de renfort,
- b) déposer, sur la couche de renfort, un voile de fibres chimiques à surface thermofusible, constituant une couche de liaison,
- c) effectuer un aiguilletage léger pour faire pénétrer des tronçons de fibres à surface thermofusible de la couche de liaison dans la couche de renfort,
- d) chauffer l'ensemble à une température suffisante pour ramollir et rendre collantes les fibres à surface thermofusible,
- e) calandrer à froid l'ensemble.
- a) on a support, depositing side by side a plurality of strands of parallel glass son, to form a sheet of strands of glass son constituting a reinforcing layer,
- b) depositing, on the reinforcing layer, a web of chemical fibers with a hot-melt surface, constituting a tie layer,
- c) lightly needling to penetrate sections of thermofusible surface fibers of the tie layer in the reinforcing layer,
- d) heating the assembly to a temperature sufficient to soften and make sticky the hot-melt surface fibers,
- e) cold calendering the whole.
Dans le cas d'un renfort à deux couches de liaison, à l'étape a) on dispose sur le support un second voile de fibres chimiques à surface thermofusible, constituant une seconde couche de liaison, puis on dépose les mèches de fils de verre sur la deuxième couche de liaison ; à l'étape c), on effectue un aiguillage léger double face.In the case of a reinforcement with two bonding layers, in step a) a second web of chemical fibers with a hot-melt surface is placed on the support, constituting a second bonding layer, and then the strands of glass strands on the second bonding layer; in step c), a light double-sided switch is made.
Dans le cas d'un renfort à couche intermédiaire, entre l'étape a) et l'étape b), on place sur la couche de renfort les fils ou fibres de verre précoupés de la couche intermédiaire.In the case of an intermediate layer reinforcement, between step a) and step b), the pre-cut yarns or glass fibers of the intermediate layer are placed on the reinforcing layer.
De préférence, lors de l'étape d'aiguilletage léger, on utilise des aiguilles dont les barbes d'entraînement sont placées dans un plan diamétral parallèle à la direction des fils des mèches de fils de verre. De la sorte, on évite de rompre les fils de verre, et on garantit l'obtention d'un renfort procurant une grande résistance mécanique aux articles composites réalisés à partir d'un tel renfort.Preferably, during the light needling step, needles are used whose driving barbs are placed in a diametral plane parallel to the direction of the son son of glass strands. In this way, it is avoided to break the glass son, and it is guaranteed to obtain a reinforcement providing a high mechanical strength to composite articles made from such a reinforcement.
D'autres objets, caractéristiques et avantages de la présente invention ressortiront de la description suivante de modes de réalisation particuliers, faite en relation avec les figures jointes, parmi lesquelles :
- la
figure 1 est une vue schématique en coupe longitudinale d'un renfort de moulage selon un premier mode de réalisation de l'invention ; - la
figure 2 est une vue schématique en perspective d'une mèche de fils de verre continus, en partie éclatée ; - la
figure 3 illustre en perspective un fil de verre continu ; - la
figure 4 est une vue schématique en coupe longitudinale du renfort de moulage de lafigure 1 , en cours d'aiguilletage léger ; - la
figure 5 est une vue schématique en perspective d'un renfort de moulage selon un mode de réalisation de l'invention ; - la
figure 6 illustre l'orientation des barbes d'entraînement des aiguilles lors de l'aiguilletage léger ; - la
figure 7 est une vue schématique en coupe longitudinale d'un renfort de moulage selon un autre mode de réalisation de l'invention ; et - la
figure 8 est une vue schématique en coupe longitudinale d'un renfort de moulage selon un autre mode de réalisation de l'invention.
- the
figure 1 is a schematic longitudinal sectional view of a molding reinforcement according to a first embodiment of the invention; - the
figure 2 is a schematic perspective view of a wick of continuous glass son, partly exploded; - the
figure 3 illustrates in perspective a continuous glass wire; - the
figure 4 is a schematic view in longitudinal section of the molding reinforcement of thefigure 1 , during light needling; - the
figure 5 is a schematic perspective view of a molding reinforcement according to an embodiment of the invention; - the
figure 6 illustrates the orientation of the barbs driving the needles during light needling; - the
figure 7 is a schematic longitudinal sectional view of a molding reinforcement according to another embodiment of the invention; and - the
figure 8 is a schematic longitudinal sectional view of a molding reinforcement according to another embodiment of the invention.
Dans un premier mode de réalisation illustré sur les
La couche de renfort 2 comprend des mèches de fils de verre, telles que les mèches 2a, 2b, 2c (
A titre d'illustration, la
Pour obtenir une bonne résistance mécanique à l'allongement, on choisira avantageusement des mèches de fils de verre continus 20a (
Les fils 20a, 20b, 20c sont en réalité formés d'un nombre suffisant de filaments pour éviter leur rupture lors des manipulations et utilisations selon l'invention, étant observé que les filaments isolés, dans la taille dans laquelle ils sortent habituellement des filières de fabrication, sont trop fragiles pour de telles manipulations et utilisations.The
En alternative, pour obtenir une capacité d'allongement du renfort de moulage 1 avant l'étape de moulage, on choisira avantageusement des mèches de fils de verre tronçonnés, ayant une longueur de 10 cm à 100 cm environ, les fils pouvant être décalés longitudinalement les uns par rapport aux autres pour se chevaucher, et restant formés chacun d'un assemblage de filaments. La longueur de tels fils est suffisante pour garantir de bonnes propriétés mécaniques à l'article composite réalisé par moulage de ce renfort de moulage 1, et la capacité d'allongement améliore l'adaptation à un objet préexistant, par exemple à un tube pour le recouvrement de sa surface extérieure ou intérieure. Ce mode de réalisation permet par exemple une application à la rénovation de conduites en sous-sol.Alternatively, in order to obtain an elongation capacity of the
La couche de liaison 3 comprend des tronçons de fibres 3a à surface thermofusible.The
Les tronçons de fibres 3a à surface thermofusible peuvent être en toute matière ayant une température de fusion suffisamment basse et de bonnes propriétés de collage avec les fils de verre 20a, 20b, 20c de la couche de renfort 2.The
En alternative, les tronçons de fibres 3a à surface thermofusible peuvent être des fibres chimiques bi-composant, comportant une âme centrale en polyamide, polyester ou polypropylène, et une gaine externe en copolyester, en polyéthylène ou en toute autre matière ayant une température de fusion inférieure à celle de l'âme centrale. De bons résultats pourront être obtenus en utilisant une âme centrale en polyester et une gaine externe en copolyester, ou une âme centrale en polypropylène et une gaine externe en polyéthylène. D'autres couples de matières peuvent être utilisés sous forme de fibres bi-composant coaxiales : le polypropylène et le copolypropylène, le polypropylène et l'acétate d'éthyle vinyle.Alternatively, the
Par le fait que l'âme centrale de la fibre bi-composant a une température de fusion plus élevée que la gaine externe, on évite un risque accidentel de fusion complète des premiers tronçons de fibres à surface thermofusible lors de la fabrication du renfort de moulage 1.In that the central core of the two-component fiber has a higher melting temperature than the outer sheath, an accidental risk of complete melting of the first sections of hot-melt-surface fibers is avoided during the manufacture of the molding reinforcement. 1.
On limite aussi efficacement le risque, lors d'une étape d'échauffement pour la fabrication du renfort de moulage 1, que les tronçons de fibres thermofusibles soient, par un échauffement trop élevé ou mal contrôlé, complètement fondus, formant des couches uniformes ou imperméables à la résine par étalement de leur matière constitutive sur les faces supérieure et inférieure de la couche de renfort 2. L'âme des fibres bi-composant n'est pas (ou très peu) altérée, et les propriétés de la couche de liaison 3 sont ainsi conservées.It is also effective to limit the risk, during a heating step for the manufacture of the
En outre, l'utilisation de fibres à surface thermofusible bi-composant à gaine externe et âme centrale permet de réduire la teneur en polyoléfine du renfort de moulage 1. Cela s'avère avantageux, la résine étant peu compatible avec les polyoléfines.In addition, the use of bi-component hot-melt surface fibers outer sheath and central core reduces the polyolefin content of the
Parmi les tronçons de fibres 3a à surface thermofusible de la couche de liaison 3, certains au moins de ces tronçons, par exemple les tronçons pénétrants 3b sur la
Les tronçons pénétrants 3b de fibres sont répartis régulièrement selon la surface du renfort de moulage 1, par exemple selon une densité surfacique de 5 à 10 tronçons par cm2 de renfort de moulage, et assurent une cohésion de l'ensemble, tout en conservant les propriétés de déformabilité et de souplesse du renfort de moulage 1.The penetrating
Le renfort de moulage 1 selon l'invention peut être réalisé sous forme de bande continue que l'on conditionne en bobine de grande longueur. Dans une telle bande continue, les mèches 2a, 2b, 2c sont formées de fils de verre continus 20a, 20b, 20c et sont orientées dans le sens de la longueur de bande, ou sens de chaîne.The
Par exemple, on dépose sur un support plan une nappe de mèches de fils de verre pour constituer la couche de renfort 2, on dépose sur la couche de renfort 2 un voile de fibres à surface thermofusible pour constituer la couche de liaison 3.For example, a ply of strands of glass strands is deposited on a flat support to constitute the reinforcing
On soumet l'ensemble ainsi obtenu à un aiguilletage léger qui fait pénétrer certains au moins 3b des tronçons de fibres 3a à surface thermofusible de la couche de liaison dans la couche de renfort 2, on chauffe l'ensemble à une température suffisante pour ramollir la partie thermofusible des tronçons pénétrants 3b de fibres à surface thermofusible et pour assurer après refroidissement leur collage aux fils de verre 20a, 20b, 20c de la couche de renfort 2.The assembly thus obtained is subjected to a light needling which penetrates at least 3b of the
La
L'aiguilletage léger effectué réalise par exemple une densité surfacique de perforations d'environ 5 à 10 perforations par cm2. Cela doit être comparé aux procédés d'aiguilletage qui réalisent, de façon classique, des densités au moins 10 fois supérieures. L'aiguilletage léger permet un grand débit lors de la fabrication du renfort de moulage selon l'invention.The light needling carried out for example produces a surface density of perforations of about 5 to 10 perforations per cm 2 . This must be compared to needling processes which typically achieve densities at least 10 times higher. The light needling allows a large flow during the manufacture of the molding reinforcement according to the invention.
Comme illustré sur la
L'aiguilletage léger effectué est suffisant pour assurer la cohésion pendant le transfert de l'ébauche de renfort de moulage jusqu'à un poste de travail suivant, mais il est insuffisant pour assurer la cohésion définitive du renfort de moulage 1 et celui-ci n'est toujours pas transportable en sortie de l'aiguilleteuse pour un usage comme produit de renfort.The light needling performed is sufficient to ensure cohesion during the transfer of the molding reinforcement blank to a next work station, but it is insufficient to ensure the final cohesion of the
L'échauffement qui est réalisé après l'opération d'aiguilletage léger permet de ramollir la couche superficielle thermofusible des tronçons pénétrants 3b de fibres de la couche de liaison 3 pour la rendre adhérente. Les tronçons pénétrants 3b de fibres qui ont été entraînés par les aiguilles 8 d'aiguilletage léger adhèrent aux fils de verre 20a, 20b, 20c de la couche de renfort 2. Après refroidissement, les différentes couches 2, 3 du renfort de moulage 1 sont ainsi liées entre elles par les fibres 3b aiguilletées et collées. Le renfort de moulage 1 est alors transportable. Le chauffage est réglé pour ramollir et rendre adhésifs les tronçons pénétrants 3b de fibres à surface thermofusible, mais sans les fondre.The heating which is carried out after the light needling operation makes it possible to soften the hot-melt surface layer of the penetrating
On considère maintenant la
Ce second mode de réalisation se distingue du premier mode de réalisation de la
On retrouve des tronçons pénétrants 3b et 4b de fibres à surface thermofusible, qui solidarisent les couches 2, 3 et 4.
On considère maintenant la
Ce troisième mode de réalisation se distingue du premier mode de réalisation de la
Selon une première possibilité, la couche intermédiaire 5 comprend une couche 5a de fils de verre de 160 à 200 tex environ, parallèles et orientés perpendiculairement aux mèches 2a, 2b et 2c, c'est-à-dire dans le sens de trame, et continus selon toute la largeur du renfort.According to a first possibility, the
Selon une seconde possibilité, la couche intermédiaire 5 comprend une couche 5b de fibres de verre coupées de 50 mm environ, en vrac à toutes orientations, selon un grammage de 50 à 80 g/m2 environ.According to a second possibility, the
Selon une troisième possibilité, illustrée sur la
Ce troisième mode de réalisation est adapté à des applications nécessitant un renfort transversal dans le sens de trame, et peut améliorer la régularité de surface de l'article composite.This third embodiment is suitable for applications requiring transverse reinforcement in the weft direction, and can improve the surface regularity of the composite article.
On retrouve des tronçons pénétrants 3b de fibres à surface thermofusible, qui solidarisent les couches 2, 3 et 5.
-
I) sur un support plan, on dépose plusieurs mèches de fils de verre, en les disposant parallèlement en nappe et en une seule épaisseur pour constituer une couche de renfort 2. Les fils de verre sont formés d'un assemblage de 40 filaments ayant un diamètre unitaire d'environ 15 µm, les fils ayant un titre unitaire d'environ 50 tex. Les mèches ont un titre de 2 400 tex, et sont présentes en quantité de cinq mèches au cm.I) on a flat support, several strands of glass strands are deposited, laying them parallel in sheet and in a single thickness to form a reinforcing
layer 2. The glass strands are formed of an assembly of 40 filaments having a unit diameter of about 15 μm, the threads having a title unitary of about 50 tex. The locks have a title of 2400 tex, and are present in quantity of five locks per cm. -
II) sur une carde conventionnelle, on réalise un voile de fibres chimiques à surface thermofusible. Les tronçons de fibres chimiques sont en fibres bi-composant, avec une âme centrale en polyester et une gaine externe thermofusible en copolyester. La gaine externe thermofusible en copolyester a une température de fusion d'environ 110°C.
Les fibres chimiques bi-composant ont un titre unitaire compris entre 2 deniers environ et 4 deniers environ. II) on a conventional card, a web of chemical fibers with a hot-melt surface is produced. The sections of chemical fibers are made of two-component fibers, with a central core of polyester and a thermofusible outer sheath made of copolyester. The thermofusible copolyester outer sheath has a melting temperature of about 110 ° C.
The two-component chemical fibers have a unit title of between about 2 deniers and about 4 deniers. -
III) on dépose le voile de fibres chimiques à surface thermofusible sur la couche de renfort 2.III) depositing the web of chemical fibers with a hot-melt surface on the reinforcing
layer 2. - IV) l'ébauche de renfort de moulage ainsi réalisée est introduite au moyen d'un tapis transporteur dans une aiguilleteuse. La densité des aiguilles est de 10/cm2. La profondeur de pénétration des aiguilles est de 12 mm. La vitesse de défilement du tapis est de 20 m/minute.IV) the molding reinforcement blank thus produced is introduced by means of a conveyor belt into a needling machine. The density of the needles is 10 / cm 2 . The penetration depth of the needles is 12 mm. The running speed of the carpet is 20 m / minute.
- V) après l'opération d'aiguilletage léger, l'ébauche de renfort de moulage est introduite dans un four à air traversant comportant une partie chauffante de 12 m de longueur et une vitesse de défilement de 20 m/minute. La température du four à air traversant est d'environ 120°C.V) after the light needling operation, the molding reinforcement blank is introduced into a through air oven having a heating portion of 12 m length and a running speed of 20 m / min. The temperature of the through air oven is about 120 ° C.
-
VI) en sortie du four à air traversant, on procède à un calandrage à froid qui donne au renfort de moulage 1 son épaisseur finale qui est voisine de 4 à 5 mm.VI) at the outlet of the through-air oven, a cold calendering is carried out which gives the
molding reinforcement 1 its final thickness which is close to 4 to 5 mm.
Le grammage du renfort de moulage 1 est compris entre 400 et 1 800 g/m2 environ.The basis weight of the
Le renfort de moulage 1 selon l'invention peut trouver des applications avantageuses dans la fabrication de pièces composites longues, notamment les pales d'éolienne.The
La présente invention n'est pas limitée aux modes de réalisation qui ont été explicitement décrits, mais elle en inclut les diverses variantes et généralisations contenues dans le domaine des revendications ci-après.The present invention is not limited to the embodiments which have been explicitly described, but it includes the various variants and generalizations thereof within the scope of the claims below.
Claims (15)
- Molding reinforcement (1) made of a fiber-based lap, comprising:- a first layer of fibers (2),- at least one coupling layer (3) made of portions of fibers (3a) with a hot melt surface, coupled to the first layer of fibers (2),- at least some (3b) of the portions (3a) of fibers with hot melt surface penetrating the first layer of fibers (2) over part of their length and adhering partially to one another and to the fibers of the first layer of fibers (2),characterized in that the first layer of fibers (2) comprises rovings (2a, 2b, 2c) of parallel glass strands (20a, 20b, 20c) arranged side by side in a lap, thus forming a reinforcing layer.
- Molding reinforcement as claimed in claim 1, characterized in that the rovings (2a, 2b, 2c) of glass strands have a count of around 2 400 to 4 800 tex.
- Molding reinforcement as claimed in one of claims 1 or 2, characterized in that the glass strands (20a, 20b, 20c) of the rovings (2a, 2b, 2c) are formed of an assembly of filaments of individual diameter ranging between around 14 µm and around 17 µm.
- Molding reinforcement as claimed in any one of claims 1 to 3, characterized in that the glass strands (20a, 20b, 20c) of the rovings (2a, 2b, 2c) have an individual count of around 40 to 80 tex.
- Molding reinforcement as claimed in any one of claims 1 to 4, characterized in that the penetrating portions of fibers are distributed with a surface density of 5 to 10 portions per cm2 of molding reinforcement.
- Molding reinforcement as claimed in any one of claims 1 to 5, characterized in that it comprises an intermediate layer (5) of glass strands between the reinforcing layer (2) and the coupling layer (3).
- Molding reinforcement as claimed in claim 6, characterized in that the intermediate layer (5) comprises a layer (5a) of glass strands of around 160 to 200 tex, which are parallel and oriented perpendicular to the rovings (2a, 2b, 2c), and/or a layer (5b) of chopped glass fibers around 50 mm long applied in bulk in all orientations, at a grammage of around 50 to 80 g/m2.
- Molding reinforcement as claimed in any one of claims 1 to 7, characterized in that the reinforcing layer (2) is coupled to a single coupling layer (3) of fibers with hot melt surface.
- Molding reinforcement as claimed in any one of claims 1 to 7, characterized in that the reinforcing layer (2) is coupled to two coupling layers (3, 4) made of fibers with hot melt surface, which are arranged one on each side of the reinforcing layer (2).
- Molding reinforcement as claimed in any one of claims 1 to 9, characterized in that it has a grammage of between 400 and 1 800 g/m2.
- Molding reinforcement as claimed in any one of claims 1 to 10, characterized in that it is in the form of a continuous strip packaged in a reel, the rovings (2a, 2b, 2c) being formed of continuous glass strands (20a, 20b, 20c) and being oriented in the lengthwise direction of the strip.
- Molding reinforcement as claimed in any one of claims 1 to 10, characterized in that it is in the form of a continuous strip packaged as a reel, the rovings (2a, 2b, 2c) being formed of chopped glass strands 10 to 100 cm long and oriented in the lengthwise direction of the strip.
- Method of manufacturing a molding reinforcement as claimed in any one of claims 1 to 12, comprising the steps of:a) laying a plurality of parallel glass strand rovings (2a, 2b, 2c) side by side on a support to form a lap of glass strand rovings constituting a reinforcing layer (2),b) laying a web of chemical fibers with hot melt surface (3a) on the reinforcing layer (2) to constitute a coupling layer (3),c) performing a light needling operation to cause the portions (3b) of fibers with hot melt surface in the coupling layer (3) to penetrate the reinforcing layer (2),d) heating the whole assembly to a temperature high enough to soften the fibers (3a) with hot melt surface and make them sticky,e) cold rolling the assembly.
- Method as claimed in claim 13, characterized in that, during the light needling step c), use is made of needles (8) the driving beards (8a, 8b) of which are positioned in a diametral plane parallel to the direction (D) of the strands of the glass strand rovings (2a, 2b, 2c).
- Application of a molding reinforcement as claimed in any one of claims 1 to 12 to the manufacture of wind turbine blades or other long composite components.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10754571T PL2467518T3 (en) | 2009-08-21 | 2010-08-11 | Reinforcement strands of parallel glass fibers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0904030A FR2949239B1 (en) | 2009-08-21 | 2009-08-21 | REINFORCEMENT HAVING GLASS THREAD PARRALLELES. |
PCT/IB2010/053636 WO2011021134A2 (en) | 2009-08-21 | 2010-08-11 | Reinforcement comprising parallel rovings of glass strands |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2467518A2 EP2467518A2 (en) | 2012-06-27 |
EP2467518B1 true EP2467518B1 (en) | 2014-11-26 |
Family
ID=42124690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10754571.7A Not-in-force EP2467518B1 (en) | 2009-08-21 | 2010-08-11 | Reinforcement strands of parallel glass fibers |
Country Status (14)
Country | Link |
---|---|
US (1) | US20120148790A1 (en) |
EP (1) | EP2467518B1 (en) |
JP (1) | JP2013502516A (en) |
CN (1) | CN102482815A (en) |
BR (1) | BR112012003544A2 (en) |
CA (1) | CA2771424A1 (en) |
ES (1) | ES2531429T3 (en) |
FR (1) | FR2949239B1 (en) |
IL (1) | IL218141A0 (en) |
MX (1) | MX2012002001A (en) |
MY (1) | MY173520A (en) |
PL (1) | PL2467518T3 (en) |
PT (1) | PT2467518E (en) |
WO (1) | WO2011021134A2 (en) |
Families Citing this family (6)
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FR2977262B1 (en) * | 2011-06-28 | 2013-07-05 | Gilbert Chomarat | THERMOFORMABLE TABLE WITH REINFORCING FIBERS |
EP2636783A1 (en) * | 2012-03-09 | 2013-09-11 | Quadrant Plastic Composites AG | Flat compound material |
US10632718B2 (en) * | 2014-09-30 | 2020-04-28 | The Boeing Company | Filament network for a composite structure |
US20160221298A1 (en) * | 2015-02-04 | 2016-08-04 | Sabic Global Technologies B.V. | Reinforced thermoplastic articles, compositions for the manufacture of the articles, methods of manufacture, and articles formed therefrom |
DE202016104070U1 (en) * | 2016-07-26 | 2017-10-27 | Autefa Solutions Germany Gmbh | Pile product with unidirectionally increased strength for the production of CFRP components |
DE102017127868A1 (en) * | 2017-11-24 | 2019-05-29 | Saertex Gmbh & Co. Kg | Unidirectional clutch and its use |
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FR1394271A (en) | 1964-02-21 | 1965-04-02 | Chomarat & Cie | Improvement in the manufacture of resin laminates |
JPS4948774B1 (en) * | 1969-12-30 | 1974-12-23 | ||
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JPS5735394U (en) * | 1980-08-01 | 1982-02-24 | ||
JPH01246453A (en) * | 1988-03-25 | 1989-10-02 | Fuji Fiber Glass Kk | Production of glass fiber heat insulating material for folded board |
FR2646442B1 (en) | 1989-04-28 | 1993-04-02 | Chomarat & Cie | TEXTILE REINFORCEMENT FOR USE IN THE PRODUCTION OF COMPOSITE MATERIALS AND SHAPED ARTICLES HAVING SUCH AN REINFORCEMENT |
FR2722802B1 (en) | 1994-07-21 | 1996-08-23 | Chomarat & Cie | TEXTILE REINFORCEMENT FOR USE IN THE PRODUCTION OF COMPOSITE MATERIALS |
JPH08134756A (en) * | 1994-11-07 | 1996-05-28 | Sekisui Chem Co Ltd | Heat-insulating mat of inorganic fiber and its production |
JPH0994900A (en) * | 1995-09-29 | 1997-04-08 | Nitto Boseki Co Ltd | Unidirectionally reinforced fiber composite base sheet |
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JP2976913B2 (en) * | 1997-01-13 | 1999-11-10 | 日本板硝子株式会社 | Composite long fiber reinforced thermoplastic resin stampable sheet and bumper beam obtained by molding the same |
JPH11268159A (en) * | 1998-03-26 | 1999-10-05 | Unitika Ltd | Laminated sheet for asphalt roofing |
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-
2009
- 2009-08-21 FR FR0904030A patent/FR2949239B1/en not_active Expired - Fee Related
-
2010
- 2010-08-11 BR BR112012003544A patent/BR112012003544A2/en not_active IP Right Cessation
- 2010-08-11 CA CA2771424A patent/CA2771424A1/en not_active Abandoned
- 2010-08-11 PL PL10754571T patent/PL2467518T3/en unknown
- 2010-08-11 CN CN2010800370117A patent/CN102482815A/en active Pending
- 2010-08-11 PT PT10754571T patent/PT2467518E/en unknown
- 2010-08-11 WO PCT/IB2010/053636 patent/WO2011021134A2/en active Application Filing
- 2010-08-11 US US13/391,112 patent/US20120148790A1/en not_active Abandoned
- 2010-08-11 MX MX2012002001A patent/MX2012002001A/en active IP Right Grant
- 2010-08-11 EP EP10754571.7A patent/EP2467518B1/en not_active Not-in-force
- 2010-08-11 JP JP2012525235A patent/JP2013502516A/en active Pending
- 2010-08-11 ES ES10754571.7T patent/ES2531429T3/en active Active
- 2010-08-11 MY MYPI2012000637A patent/MY173520A/en unknown
-
2012
- 2012-02-16 IL IL218141A patent/IL218141A0/en unknown
Also Published As
Publication number | Publication date |
---|---|
PT2467518E (en) | 2015-03-02 |
CA2771424A1 (en) | 2011-02-24 |
BR112012003544A2 (en) | 2016-03-08 |
WO2011021134A2 (en) | 2011-02-24 |
FR2949239B1 (en) | 2011-10-28 |
US20120148790A1 (en) | 2012-06-14 |
FR2949239A1 (en) | 2011-02-25 |
WO2011021134A3 (en) | 2011-05-12 |
IL218141A0 (en) | 2012-06-28 |
MY173520A (en) | 2020-01-30 |
JP2013502516A (en) | 2013-01-24 |
EP2467518A2 (en) | 2012-06-27 |
MX2012002001A (en) | 2012-09-12 |
CN102482815A (en) | 2012-05-30 |
ES2531429T3 (en) | 2015-03-16 |
PL2467518T3 (en) | 2015-04-30 |
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