EP2313055A1 - COMPOSITION ANTIPERSPIRANTE ANHYDRE COMPRENANT UN ALCANE C9-C17 LINÉAIRE VOLATIL, ET DISPOSITIF AÉROSOL& xA; - Google Patents
COMPOSITION ANTIPERSPIRANTE ANHYDRE COMPRENANT UN ALCANE C9-C17 LINÉAIRE VOLATIL, ET DISPOSITIF AÉROSOL& xA;Info
- Publication number
- EP2313055A1 EP2313055A1 EP09779882A EP09779882A EP2313055A1 EP 2313055 A1 EP2313055 A1 EP 2313055A1 EP 09779882 A EP09779882 A EP 09779882A EP 09779882 A EP09779882 A EP 09779882A EP 2313055 A1 EP2313055 A1 EP 2313055A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- volatile linear
- weight
- alkanes
- alkane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Definitions
- the present invention relates to an antiperspirant composition, characterized in that it comprises, in a cosmetically acceptable anhydrous liquid vehicle:
- the invention also relates to an aerosol device composed of:
- the invention also relates to a method for the treatment of human perspiration and the human body odours and in particular axillary odours resulting therefrom using this composition.
- antiperspirant products comprising active substances of antiperspirant type to reduce the flow of sweat, indeed even to reduce body odours.
- Antiperspirant substances have the effect of limiting the flow of sweat. They are generally composed of aluminium and/or zirconium salts.
- the most widely used anhydrous aerosols in the field of antiperspirants mainly comprise a solid antiperspirant active principle suspended in an emollient oil by virtue of a modified clay.
- the phase proportion of dispensable to propellant generally lies within ratios of concentrations, expressed as percentage by weight, of between 10/90 and 30/70.
- Disposable is understood to mean the product which is introduced into the aerosol device, to which a propellant gas is added in order to place it under pressure .
- the qualities desired for an anhydrous antiperspirant composition in the aerosol form are:
- the anhydrous antiperspirant aerosols known in the prior art generally comprise suspending agents of modified clay or silica type.
- suspending agents such as silicas
- silicas can cause blockage of the nozzle in the aerosol device.
- anhydrous antiperspirant aerosols generally comprise volatile emollient silicone oils which exhibit the advantage of having a good dry feel.
- the separation by settling of the antiperspirant active principle obtained in the presence of these volatile silicones often still remains excessively rapid and can result in deliveries of nonhomogeneous product.
- anhydrous antiperspirant aerosol compositions are obtained in which the active principle settling time is substantially longer.
- the compositions in accordance with the invention simultaneously exhibit good effectiveness and good cosmetic properties.
- a subject-matter of the invention is thus an antiperspirant composition, characterized in that it comprises, in a cosmetically acceptable anhydrous liquid vehicle: (a) at least one antiperspirant active principle;
- composition at least one propellant; with the proviso that the composition is different from the following formulations, in which the amounts of the ingredients are expressed as percentage by weight, with respect to the total weight of the composition:
- the invention also relates to an aerosol device composed of:
- a container comprising a composition composed, on the one hand, of an anhydrous liquid phase (or dispensable) comprising at least one antiperspirant active principle and at least one volatile linear Cg-Ci 7 alkane or a mixture of volatile linear Cg-Ci 7 alkanes, and
- a second subject-matter of the present invention is also a method consisting in using such a composition to prevent or limit the flow of sweat and thus to limit the body odours resulting therefrom.
- “Anhydrous” is understood to mean, within the meaning of the invention, a composition having a content of free or added water of less than 3% by weight and preferably having a content of added water of less than 1% by weight, with respect to the total weight of the composition.
- the volatile linear alkanes in accordance with the invention comprise from 9 to 17 carbon atoms, in particular from 10 to 15 carbon atoms and more particularly from 11 to 13 carbon atoms.
- the volatile linear alkanes in accordance with the invention can advantageously be of vegetable origin.
- Such alkanes can be obtained, directly or in several stages, from a vegetable raw material, such as an oil, a butter, a wax, and the like.
- alkanes are obtained from fatty alcohols, themselves obtained from coconut or palm oil. Mention may be made, as examples of volatile linear alkanes suitable for the invention, of n-nonane (Cg) , n-decane (Cio) , n-undecane (Cn) , n-dodecane (C12) , n-tridecane (C13) , n-tetradecane (Ci 4 ) , n-pentadecane (Ci 5 ) , n-hexadecane (Ci ⁇ ) and n-heptadecane (Ci 7 ) , and their mixtures.
- volatile linear alkanes suitable for the invention of n-nonane (Cg) , n-decane (Cio) , n-undecane (Cn) , n-dodecane (C12) , n-tridecane (C13)
- the said mixture will comprise from 50 to 90% by weight of undecane and from 10 to 50% by weight of tridecane, with respect to the total weight of the mixture.
- the volatile linear alkane or the mixture of volatile linear alkanes of the invention are preferably present in a content ranging from 10% to 95% by weight, with respect to the total weight of the dispensable of the composition, and more preferably ranging from 30% to 95% by weight.
- the antiperspirant active principles in accordance with the invention are preferably chosen from aluminium hydrohalides ; aluminium zirconium hydrohalides, complexes of zirconium hydroxychloride and of aluminium hydroxychloride with an amino acid, such as those described in Patent US-3 792 068, commonly known under the name "ZAG complexes".
- ZAG complexes Such complexes are generally known under the name ZAG (when the amino acid is glycine) .
- the ZAG complexes ordinarily exhibit an Al/Zr quotient ranging from approximately 1.67 to 12.5 and a metal/Cl quotient ranging from approximately 0.73 to 1.93.
- aluminium zirconium octachlorohydrex GLY aluminium zirconium pentachlorohydrex GLY, aluminium zirconium tetrachlorohydrate GLY and aluminium zirconium trichlorohydrate GLY.
- aluminium salts of aluminium chlorohydrate in the activated or non-activated form
- aluminium chlorohydrex the aluminium chlorohydrex polyethylene glycol complex
- aluminium chlorohydrex propylene glycol complex aluminium dichlorohydrate
- aluminium dichlorohydrex polyethylene glycol complex the aluminium dichlorohydrex propylene glycol complex
- aluminium sesquichlorohydrate aluminium sesquichlorohydrex polyethylene glycol complex
- aluminium sesquichlorohydrex propylene glycol complex aluminium sesquichlorohydrex polyethylene glycol complex
- aluminium sesquichlorohydrex propylene glycol complex aluminium sulphate buffered with sodium aluminium lactate .
- aluminium zirconium salts of aluminium zirconium octachloro- hydrate, aluminium zirconium pentachlorohydrate, aluminium zirconium tetrachlorohydrate or aluminium zirconium trichlorohydrate.
- the complexes of zirconium hydroxychloride and of aluminium hydroxychloride with an amino acid are generally known under the name ZAG (when the amino acid is glycine) .
- aluminium zirconium octachlorohydrex glycine aluminium zirconium pentachlorohydrex glycine, aluminium zirconium tetrachlorohydrex glycine and aluminium zirconium trichlorohydrex glycine complexes.
- the antiperspirant active principles present in the compositions of the invention are preferably chosen from aluminium and/or zirconium salts; or complexes of zirconium hydroxychloride and of aluminium hydroxychloride with an amino acid, such as those described in Patent US-3 792 068, commonly known under the name "ZAG complexes".
- ZAG complexes Such complexes are generally known under the name ZAG (when the amino acid is Glycine) .
- the ZAG complexes ordinarily exhibit an Al/Zr quotient ranging from approximately 1.67 to 12.5 and a metal/Cl quotient ranging from approximately 0.73 to 1.93.
- aluminium zirconium octachlorohydrex GLY aluminium zirconium pentachlorohydrex GLY, aluminium zirconium tetrachlorohydrate GLY and aluminium zirconium trichlorohydrate GLY.
- aluminium salts of aluminium chlorohydrate, aluminium chlorohydrex, aluminium chlorohydrex PEG, aluminium chlorohydrex PG, aluminium dichlorohydrate, aluminium dichlorohydrex PEG, aluminium dichlorohydrex PG, aluminium sesquichlorohydrate, aluminium sesquichlorohydrex PEG, aluminium sesquichlorohydrex PG, alum salts, aluminium sulphate, in particular buffered by sodium aluminium lactate, aluminium zirconium octachlorohydrate, aluminium zirconium pentachlorohydrate, aluminium zirconium tetrachlorohydrate, aluminium zirconium trichlorohydrate and more particularly the aluminium hydroxychloride sold by Reheis under the name Reach 301 or by Guilini Chemie under the name Aloxicoll PF 40.
- Aluminium zirconium salts are, for example, that sold by Reheis under the name Reach AZP-908-SUF.
- Use will more particularly be made of the aluminium salts and more particularly still of activated or nonactivated aluminium hydroxychloride .
- the antiperspirant active principles can be present in the composition according to the invention in a proportion of 0.1 to 40% by weight, with respect to the dispensable, and preferably in a proportion of 5 to 35% by weight, with respect to the dispensable.
- the propellant can be chosen from dimethyl ether; volatile hydrocarbons, such as n-butane, propane, isopropane, n-butane, isobutane, pentane and isopentane, and their mixtures; or volatile fluorinated hydrocarbons, such as 1, 1-difluoroethane and 1,1,1- trifluoro-2-fluoroethane .
- volatile hydrocarbons such as n-butane, propane, isopropane, n-butane, isobutane, pentane and isopentane, and their mixtures
- volatile fluorinated hydrocarbons such as 1, 1-difluoroethane and 1,1,1- trifluoro-2-fluoroethane .
- Use may also be made, as propellant, of carbon dioxide gas, nitrous oxide, nitrogen or compressed air.
- the composition comprising the antiperspirant active principle or principles and the propellant or propellants can occur in the same compartment or in different compartments in the aerosol container.
- the pressurized concentration of propellant generally varies from 5 to 90% by weight and more preferably from 15 to 60% by weight, with respect to the total weight of the pressurized composition.
- the dispensable/propellant ratio preferably varies from 10/90 to 50/50 and more preferably from 15/85 to 30/70.
- the cosmetic composition according to the invention can thus be provided in the form of a lotion, cream or fluid gel dispensed in the aerosol spray and can comprise, in this respect, the ingredients generally used in products of this type and which are well known to a person skilled in the art.
- the dispensing means which forms a part of the aerosol device, is generally composed of a dispensing valve controlled by a dispensing head, itself comprising a nozzle via which the aerosol composition is vaporized.
- the container comprising the pressurized composition can be opaque or transparent. It can be made of glass, of polymer or of metal, optionally covered with a layer of protective lacquer.
- composition according to the invention can also comprise at least one additional deodorant active principle.
- the preferred active principles are 2,4,4'- trichloro-2 ' -hydroxydiphenyl ether (triclosan); polyhexamethylene biguanide salts (known under the name of polyaminopropyl biguanide salts), for example the product Cosmocil CQTM (Zeneca) ; or 3, 7, ll- trimethyldodeca-2, 5, 10-trienol (farnesol) .
- the cosmetically acceptable anhydrous liquid vehicle comprises an oily phase which can either be composed solely of the linear Cg-Ci 7 alkane or alkanes as defined above or else can comprise, in addition to the said alkanes, one or more volatile or nonvolatile silicone, hydrocarbon or fluorinated oils.
- the oily phase of the compositions according to the invention will preferably represent from 60% to 95% by weight, with respect to the total weight of the dispensable .
- the linear Cg-Ci 7 alkane or alkanes preferably represent from 60 to 100% by weight, with respect to the amount of the oily phase.
- the volatile silicones are defined in a known way as compounds which are volatile at ambient temperature. Mention may be made, among these compounds, of volatile cyclic and linear silicones of dimethylsiloxane type, the chains of which comprise from 3 to 9 silicone residues.
- the cyclomethicones D4, D5 or D6 are chosen.
- the additional volatile hydrocarbon oils can be chosen from in particular branched Cs-Ci6 alkanes, such as Cs-Ci6 isoalkanes (also known as isoparaffins) , isododecane, isodecane, isohexadecane and, for example, the oils sold under the Isopar or Permethyl trade names, branched Cs-Ci6 esters, such as isohexyl neopentanoate, and their mixtures; use is preferably made of isododecane.
- Cs-Ci6 isoalkanes also known as isoparaffins
- isododecane also known as isoparaffins
- isohexadecane also known as isohexadecane
- the oils sold under the Isopar or Permethyl trade names branched Cs-Ci6 esters, such as isohexyl neopentanoate, and their mixtures; use is
- the nonvolatile silicones are defined in a known way as compounds with a low vapour pressure at ambient temperature. These compounds include: polyalkylsiloxanes, in particular linear polyalkylsiloxanes, such as, for example, linear polydimethylsiloxanes or dimethicones, sold by Dow Corning under the name of "Dow Corning 245 Fluid"; cyclopolydimethylsiloxanes (cyclomethicones) ; polydimethylsiloxanes comprising pendent alkyl, alkoxy or phenyl groups or alkyl, alkoxy or phenyl groups at the end of the silicone chain, which groups have from 2 to 24 carbon atoms; or phenylated silicones, such as phenyl trimethicones, phenyl dimethicones, phenyl-
- nonvolatile fluorinated oils can be chosen from those which partially comprise hydrocarbon and/or silicone, such as those described in the document JP-A-2-295912.
- the nonvolatile hydrocarbon oils can be of mineral, synthetic or animal origin. They can be chosen from liquid paraffins, such as liquid petrolatum, perhydrosqualene, polydecenes, isohexadecane, isododecane or hydrogenated polyisobutene (or hydrogenated isoparaffin) , such as Parleam oil; or fatty esters, preferably those obtained from an alcohol comprising a linear or branched chain having from 1 to 17 carbon atoms and from a fatty acid comprising a linear or branched chain having from 3 to 18 and preferably from 12 to 17 carbon atoms.
- liquid paraffins such as liquid petrolatum, perhydrosqualene, polydecenes, isohexadecane, isododecane or hydrogenated polyisobutene (or hydrogenated isoparaffin) , such as Parleam oil
- fatty esters preferably those obtained from an alcohol comprising a linear or branched chain having from 1 to 17 carbon
- the said ester is a saturated ester which does not include either an ether group or a hydroxyl group (the total amount of carbon atoms in the ester can vary from 12 to 50 and preferably from 20 to 50) .
- the nonvolatile hydrocarbon oils can also be dialkyl ethers, such as dicaprylyl ether (Cetiol OE from Cognis) .
- the nonvolatile hydrocarbon oils can be oils of vegetable origin, such as, for example, sweet almond oil, avocado oil, castor oil, coriander oil, olive oil, jojoba oil, sesame oil, groundnut oil, grape seed oil, rapeseed oil, coconut oil, hazelnut oil, shea butter, palm oil, apricot kernel oil, calophyllum oil, rice bran oil, maize oil, wheat germ oil, soybean oil, sunflower oil, evening primrose oil, safflower oil, passionflower oil, rye oil or triglycerides of caprylic/capric acids, such as those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by Dynamit Nobel.
- oils of vegetable origin such as, for example, sweet almond oil, avocado oil, castor oil, coriander oil, olive oil, jojoba oil, sesame oil, groundnut oil, grape seed oil, rapeseed oil, coconut oil, hazelnut oil, she
- the nonvolatile hydrocarbon oils can also be chosen from fatty acids, fatty alcohols, such as lauryl, cetyl, myristyl, stearyl, palmityl or oleyl alcohol, and 2-octyldodecanol .
- a suspending agent which is preferably chosen form hydrophobic modified montmorillonite clays, such as hydrophobic modified bentonites or hectorites.
- CFA name Stearalkonium Bentonite
- CTFA name reaction product of bentonite and of the quaternary ammonium stearalkonium chloride
- CTFA name Disteardimonium Hectorite
- the suspending agents are preferably present in amounts ranging from 0.1 to 5% by weight and more preferably from 0.2 to 3% by weight, with respect to the total weight of the composition.
- compositions according to the invention can additionally comprise at least one filler.
- Fill is understood to mean, in the present patent application, any solid which is insoluble in the medium at ambient temperature (25°C) .
- the cosmetic composition according to the invention can additionally comprise cosmetic adjuvants chosen from softeners, antioxidants, opacifiers, stabilizers, antifoaming agents, moisturizing agents, vitamins, fragrances, preservatives, polymers, lipophilic thickening agents or any other ingredient commonly used in cosmetics in this type of application.
- cosmetic adjuvants chosen from softeners, antioxidants, opacifiers, stabilizers, antifoaming agents, moisturizing agents, vitamins, fragrances, preservatives, polymers, lipophilic thickening agents or any other ingredient commonly used in cosmetics in this type of application.
- the lipophilic thickeners can be chosen from modified clays, such as, for example, hectorite modified by distearyldimethylammonium chloride (CTFA name: Disteardimonium Hectorite) , such as the product sold under the trade name Bentone Gel MIO by NL Industries or the product "Bentone 38 CE” sold by Rheox; magnesium aluminium silicate, in particular the product sold under the trade name Veegum Ultra by RT Vanderbilt Inc.; or Quaternium-18 Bentonite, such as the product sold under the trade name Tixogel MP 250 by Rockwood Additives.
- CTFA name Disteardimonium Hectorite
- Bentone Gel MIO by NL Industries
- Bentone 38 CE sold by Rheox
- magnesium aluminium silicate in particular the product sold under the trade name Veegum Ultra by RT Vanderbilt Inc.
- Quaternium-18 Bentonite such as the product sold under the trade name Tixogel MP 250 by Rockwood Additives
- the amounts of these various constituents which can be present in the cosmetic composition according to the invention are those conventionally used in anhydrous antiperspirant aerosols.
- Another subject-matter of the present invention is an aerosol device composed of a container comprising an aerosol composition composed of an anhydrous liquid phase (or dispensable) comprising (a) at least one antiperspirant active principle, (b) at least one volatile linear Cg-Ci 7 alkane and (c) at least one propellant, as are defined above, and of a means for dispensing the said aerosol composition.
- an aerosol composition composed of an anhydrous liquid phase (or dispensable) comprising (a) at least one antiperspirant active principle, (b) at least one volatile linear Cg-Ci 7 alkane and (c) at least one propellant, as are defined above, and of a means for dispensing the said aerosol composition.
- Another subject-matter of the present invention is a cosmetic method for treating human perspiration and the human body odours, in particular axillary odours, resulting therefrom which consists in applying, to the axillary surface, an effective amount of a composition as defined above.
- Another subject-matter of the invention is the use of a volatile linear C9-C17 alkane as defined above in an anhydrous antiperspirant composition packaged in an aerosol as agent which makes it possible to slow down the rate of settling of the antiperspirant active principle .
- phase A fatty phase
- phase B the thickener
- phase C active principle
- Dispersing is carried out for 15 min.
- each of the formulations 1 and 2 is packaged in an aerosol container comprising 85% of isobutane (propellant) and 15% of dispensable.
- the measurment is carried out after pressurization .
- a demarcation line is traced, on a glass aerosol, at the level of the liquefied gas (at the top) and then a second demarcation line is traced 1 cm below.
- the aerosol is agitated manually for 10 seconds (time necessary to disperse the cake formed at the bottom of the aerosol) .
- the aerosol is immediately placed on a horizontal surface and the stopwatch is started as soon as the dispensable is positioned at the level of the top line.
- the stopwatch is halted as soon as the dispensable reaches the second line (1 cm below) .
- the time (in seconds) necessary in order for the dispensable to travel this distance is then determined. It is accepted that the rate of settling is within the standards when it is greater than or equal to 20 s.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
La présente invention concerne une composition antiperspirante, caractérisée en ce qu’elle comprend les éléments suivants dans un vecteur liquide anhydre cosmétiquement acceptable : (a) au moins un principe actif antiperspirant; (b) au moins un alcane C9-C17 linéaire volatil; et (c) au moins un propulseur. L’invention concerne également un dispositif aérosol composé des éléments suivants : (A) un récipient comprenant une composition composée d’une phase liquide anhydre (ou pouvant être délivrée) qui comporte au moins un principe actif antiperspirant et au moins un alcane C9-C17 linéaire volatil; et (B) au moins un propulseur et un moyen de délivrer ladite composition aérosol. L'invention porte en outre sur un procédé destiné au traitement de la transpiration humaine et des odeurs corporelles humaines en résultant – et en particulier des odeurs axillaires –, utilisant cette composition ou ce dispositif.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0854697 | 2008-07-10 | ||
US8121608P | 2008-07-16 | 2008-07-16 | |
PCT/EP2009/057775 WO2010003814A1 (fr) | 2008-07-10 | 2009-06-23 | Composition antiperspirante anhydre comprenant un alcane c<sb>9</sb>-c<sb>17</sb> linéaire volatil, et dispositif aérosol |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2313055A1 true EP2313055A1 (fr) | 2011-04-27 |
Family
ID=40394433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09779882A Withdrawn EP2313055A1 (fr) | 2008-07-10 | 2009-06-23 | COMPOSITION ANTIPERSPIRANTE ANHYDRE COMPRENANT UN ALCANE C9-C17 LINÉAIRE VOLATIL, ET DISPOSITIF AÉROSOL& xA; |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2313055A1 (fr) |
BR (1) | BRPI0910350A2 (fr) |
WO (1) | WO2010003814A1 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2949053B1 (fr) * | 2009-08-13 | 2011-11-04 | Oreal | Composition cosmetique comprenant un copolymere silicone particulier et un ou plusieurs alcanes lineaires volatils liquides |
FR2952528B1 (fr) * | 2009-11-17 | 2012-02-03 | Oreal | Melange de solvants hydrocarbones. |
WO2017049372A1 (fr) * | 2015-09-25 | 2017-03-30 | L'oreal | Composition anti-transpirante en aérosol anhydre qui fournit un effet adoucissant |
DE102020133123B4 (de) * | 2020-12-11 | 2024-06-06 | Henkel Ag & Co. Kgaa | Silikonölfreie Antitranspirantien II |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008017031A1 (de) * | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Kohlenwasserstoff Gemische und ihre Verwendung |
DE102008012457A1 (de) * | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Kohlenwasserstoff Gemische und ihre Verwendung |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1617797A1 (de) * | 1965-10-01 | 1972-03-23 | Carter Wallace | Schweissverhinderndes Aerosol sowie Aerosoldose |
GB1313863A (en) * | 1970-06-17 | 1973-04-18 | Tromans A | Aerosol composition |
DE2050712A1 (de) * | 1970-10-15 | 1972-04-20 | The J.B. Williams Co., Inc., New York, N.Y. (V.StA.) | Antitranspirant - Sprühpräparat |
US3792068A (en) * | 1971-04-02 | 1974-02-12 | Procter & Gamble | Dry powder aerosol antiperspirant composition incorporating dry powder antiperspirant active complex and process for its preparation |
DE2604395A1 (de) * | 1975-01-13 | 1976-08-26 | Procter & Gamble | Verfahren zur herstellung antiperspirativ wirksamer zirkonium- oder hafniumverbindungen |
MXPA05009301A (es) * | 2003-03-04 | 2005-10-05 | Colgate Palmolive Co | Desodorante en aerosol con poliamida. |
-
2009
- 2009-06-23 EP EP09779882A patent/EP2313055A1/fr not_active Withdrawn
- 2009-06-23 WO PCT/EP2009/057775 patent/WO2010003814A1/fr active Application Filing
- 2009-06-23 BR BRPI0910350A patent/BRPI0910350A2/pt not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008017031A1 (de) * | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Kohlenwasserstoff Gemische und ihre Verwendung |
DE102008012457A1 (de) * | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Kohlenwasserstoff Gemische und ihre Verwendung |
Non-Patent Citations (1)
Title |
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See also references of WO2010003814A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2010003814A1 (fr) | 2010-01-14 |
BRPI0910350A2 (pt) | 2015-10-06 |
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