EP2175749B1 - Multi-component filter for a smoking article - Google Patents
Multi-component filter for a smoking article Download PDFInfo
- Publication number
- EP2175749B1 EP2175749B1 EP08827853A EP08827853A EP2175749B1 EP 2175749 B1 EP2175749 B1 EP 2175749B1 EP 08827853 A EP08827853 A EP 08827853A EP 08827853 A EP08827853 A EP 08827853A EP 2175749 B1 EP2175749 B1 EP 2175749B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter
- segment
- end segment
- flavour release
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000000391 smoking effect Effects 0.000 title claims abstract description 45
- 239000000796 flavoring agent Substances 0.000 claims abstract description 121
- 235000019634 flavors Nutrition 0.000 claims abstract description 89
- 239000000463 material Substances 0.000 claims abstract description 46
- 238000001914 filtration Methods 0.000 claims abstract description 34
- 239000004014 plasticizer Substances 0.000 claims abstract description 18
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 11
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical group CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 50
- 239000001771 mentha piperita Substances 0.000 claims description 37
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 25
- 229960002622 triacetin Drugs 0.000 claims description 25
- 229920002301 cellulose acetate Polymers 0.000 claims description 21
- 239000002594 sorbent Substances 0.000 abstract description 5
- 235000019504 cigarettes Nutrition 0.000 description 60
- 239000000779 smoke Substances 0.000 description 29
- 244000061176 Nicotiana tabacum Species 0.000 description 28
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 28
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 17
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 17
- 229940041616 menthol Drugs 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000010276 construction Methods 0.000 description 11
- 239000011324 bead Substances 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 235000006679 Mentha X verticillata Nutrition 0.000 description 4
- 235000002899 Mentha suaveolens Nutrition 0.000 description 4
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 4
- 235000011054 acetic acid Nutrition 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 244000246386 Mentha pulegium Species 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000016257 Mentha pulegium Nutrition 0.000 description 2
- 235000004357 Mentha x piperita Nutrition 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000001050 hortel pimenta Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 description 1
- 244000303040 Glycyrrhiza glabra Species 0.000 description 1
- 244000024873 Mentha crispa Species 0.000 description 1
- 235000014749 Mentha crispa Nutrition 0.000 description 1
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 244000290333 Vanilla fragrans Species 0.000 description 1
- 235000009499 Vanilla fragrans Nutrition 0.000 description 1
- 235000012036 Vanilla tahitensis Nutrition 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 229940102465 ginger root Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 239000008368 mint flavor Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- -1 oils Chemical class 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001877 single-ion monitoring Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000001841 zingiber officinale Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
- A24B15/303—Plant extracts other than tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/022—Applying additives to filter materials with liquid additives, e.g. application of plasticisers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Definitions
- the present invention relates to a multi-component filter for a smoking article and to a smoking article comprising such a multi-component filter.
- Filter cigarettes typically comprise a rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter aligned in end-to-end relationship with the wrapped tobacco rod and attached thereto by tipping paper. Ventllation In the form of circumferential perforations is commonly provided at a location along the filter, to mix the mainstream smoke produced during combustion of the wrapped tobacco rod with ambient air.
- the filter In conventional filter cigarettes, the filter usually consists of a plug of cellulose acetate tow wrapped in porous plug wrap.
- filter cigarettes with multi-component filters that comprise two or more segments of filtration material for the removal of particulate and gaseous components of the mainstream smoke are also known.
- filters that include flavourants In particular, it has been proposed to include flavourants in the form of plant material, such as leaves, seeds or roots, from one or more aromatic plants.
- a filter cigarette is proposed with a multi-component filter having a flavour release segment containing a mixture of plant materials, including liquorice plant material, ginger root and shredded peppermint leaf.
- WO-A-2006/090290 discloses a filter induding tobacco beads within the filter.
- the tobacco beads optionally include flavourants in addition to tobacco particulates.
- a multi-component filter for a smoking article that, in use, provides improved flavour enhancement, and in particular improved mint and menthol flavour delivery to mainstream smoke as it is drawn from a rod of smokable material through the filter by a consumer. Furthermore, it would be desirable to provide a multi-component filter for a smoking article comprising a flavour release segment that minimises loss of flavour during storage.
- a multi-component filter for a smoking article comprising: a mouth end segment; and a flavour release segment upstream of the mouth end segment.
- the flavour release segment comprises a plug of fibrous filtration material, peppermint leaf distributed through the fibrous filtration material and a filter plasticiser applied to the fibrous filtration material.
- the amount of filter plasticiser in the flavour release segment is up to 5% by weight of the fibrous filtration material.
- a smoking article comprising a wrapped rod of smokable material and a multi-component filter according to the present invention attached to the rod of smokable material, preferably by tipping paper.
- the smoking article is a filter cigarette.
- upstream and downstream are used to describe the relative positions of segments of the multi-component filter of the invention in relation to the direction of the mainstream smoke drawn from a rod of smokable material through the multi-component filter during use.
- the flavour release segment is upstream of the mouth end segment, which means that mainstream smoke is drawn first through the flavour release segment and then through the mouth end segment.
- filter plasticiser refers to any compound suitable for use as a plasticiser in a conventional fibrous cigarette filter plug.
- the plasticiser is typically a solvent for the fibre material and acts by softening the outer surfaces of the fibres such that they adhere to each other.
- Glycerol triacetate is commonly used as the filter plasticiser for a cellulose acetate tow.
- the filter plasticiser used in the present invention is glycerol triacetate.
- peppermint leaf is used to denote a material consisting of the leaves of a peppermint plant, which have preferably been cut or shredded to provide a particulate material.
- the peppermint leaf is capable of releasing flavour into mainstream smoke drawn through the multi-component filter.
- the flavour released from the peppermint leaf is provided by volatile compounds, such as oils, contained therein, which are volatilised during smoking.
- the mainstream smoke enriched with the volatile oils from the peppermint leaf flows downstream through the mouth end segment of the multi-component filter into the consumer's mouth.
- the volatile oils Prior to smoking, the volatile oils remain trapped within the peppermint leaf. This advantageously ensures that loss of flavour during storage of multi-component filters and smoking articles according to the present invention is minimised, and so maximises flavour release into the mainstream smoke during smoking.
- the peppermint leaf in the flavour release segment is shredded, cut or otherwise reduced in size. More preferably, the peppermint leaf has a cut width of between about 0.25 mm and about 3 mm. Most preferably, the peppermint leaf has a cut width of between about 1 mm and about 2 mm.
- the peppermint leaf is dried to a moisture content of between about 8 % and about 10 %.
- the oil content of the peppermint leaf is at least about 0.6 % by weight.
- the inclusion of peppermint leaf in the flavour release segment of multi-component filters according to the present invention advantageously provides an improved way of imparting mint and menthol flavours to the mainstream smoke of a smoking article.
- Smoking articles according to the present invention advantageously provide enhanced mint and menthol flavours compared to conventional menthol cigarettes.
- the filter plasticiser is glycerol triacetate. It has surprisingly been found that the inclusion of peppermint leaf and glycerol triacetate in the flavour release segment of multi-component filters and smoking articles according to the present invention advantageously enhances the mint and menthol flavour provided by the release of menthol and other volatile oils from the peppermint leaf. This Is illustrated, for example, by the results shown in Table 1, below.
- Table 1 shows the quantities of particular flavour compounds released into the mainstream smoke from peppermint leaf in the flavour release segment of filter cigarettes (Samples 1 and 3) according to the Invention having the general construction shown In Figure 1 .
- the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein.
- Table 1 also shows the quantities of the flavour compounds released from peppermint leaf In the flavour release segment of filter cigarettes (Samples 2 and 4) not according to the Invention having the same construction as Samples 1 and 3, but in which the flavour release segment does not contain glycerol triacetate.
- Each of the samples contains 40 mg of peppermint leaf. Not all of the compounds released from the peppermint leaf are measured.
- Each of the samples is smoked under ISO conditions and the smoke extracts obtained are analysed using a GC-MS single ion monitoring method in order to determine the levels of the volatile compounds in the smoke.
- a full scan analysis with a scan range from 30 to 400 m/z (anion mass to charge ratio) is performed.
- the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the filter cigarettes according to the present invention results in increased levels of flavour compound being released from the peppermint leaf into the mainstream smoke during smoking compared to the filter cigarettes not according to the Invention, in which the flavour release segment does not contain glycerol triacetate.
- acetic acid and glycerine are released in the flavour release segment of the filter as a result of hydrolysis of the glycerol triacetate. Accordingly, the levels of acetic acid released In the filter during smoking are significantly higher than for a smoking article not according to the invention, as illustrated by the results shown in Table 2, below.
- Table 2 gives the dimensions and properties of a filter cigarette (Sample 5) according to the present invention having the general construction shown in Figure 9.
- the mouth end segment of the filter cigarette consists of a plug of cellulose acetate tow and the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein.
- Table 2 also gives the dimensions and properties of a filter cigarette (Sample 6) not according to the present invention having the same construction as Sample 5, but in which the flavour release segment does not contain glycerol triacetate.
- the overall length of smoking articles according to the present invention is between about 70 mm and about 128 mm, more preferably about 84 mm.
- the external diameter of multi-component filters and smoking articles according to the present invention is between about 5 mm and 8.5 mm, more preferably about 7.9 mm.
- the overall length of multi-component filters according to the present invention is between about 18 mm and about 36 mm, more preferably about 27 mm.
- the length of each individual segment of multi-component filters according to the present invention is between about 5 mm and about 22 mm.
- the mouth end segment of multi-component filters according to the present invention may, in some embodiments, advantageously prevent peppermint leaf from the flavour release segment reaching the mouth of the consumer during smoking.
- the mouth end segment comprises filtration material. More preferably, the mouth end segment comprises filtration material that has substantially no particulate phase filtration efficiency or very low particulate phase filtration efficiency.
- the mouth end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration material of low filtration efficiency.
- the length of the mouth end segment is preferably between about 3 mm and about 12 mm, more preferably between about 6 mm and about 8 mm.
- Multi-component filters according to the present invention may further comprise a rod end segment upstream of the flavour release segment.
- the rod end segment comprises fibrous filtration material.
- the rod end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration materials such as paper.
- cellulosic material such as cellulose acetate tow
- fibrous filtration materials such as paper.
- the rod end segment may comprise at least one sorbent capable of removing at least one gas phase constituent from mainstream smoke drawn through the filter.
- the at least one sorbent is selected from the group consisting of activated carbon, active aluminium, zeolites, sepiolites, molecular sieves and silica gel.
- the rod end segment may include one or more flavourants, preferably one or more liquid flavourants, to further enhance flavour delivery to the consumer during smoking.
- the rod end segment may comprise a plug of filtration material including one or more threads impregnated with liquid flavourant.
- the one or more threads may be made from cellulose acetate yarn, rayon, cotton, or any other hydrophilic textile or non-textile material capable of absorbing or adsorbing the liquid flavourant.
- the threads may be coloured, for example, to indicate the type of flavourant impregnated therein. If more than one thread is provided, the threads may be the same or different colours and may be impregnated with the same or different liquid flavourants.
- the threads are between about 0.6 mm and about 2.0 mm in diameter, more preferably about 0.8 mm in diameter.
- Filter plugs comprising flavourant bearing threads suitable for use in rod end segments of multi-component filters according to the present invention, and methods and apparatuses for producing such plugs, are described in US Patents Nos- 4,281,671 and 7,074,170 and are available from the American Filtrona Company, Richmond, Virginia, USA.
- the rod end segment may Include a plurality of beads impregnated with liquid flavourant.
- the beads may be formed from, for example, a cellulosic material bonded with a polyvinyl acetate binder, or from tobacco powder bonded with microcrystalline cellulose.
- Beads suitable for use In rod end segments of multi-component filters according to the present invention are manufactured and sold under the brand Viscopearls® by Rengo Co. Ltd., Japan. Methods and apparatuses for producing such beads are also described in Japanese Patent Application No. 10182842 .
- the beads may be of the same or different diameters and colours.
- the colour of the beads may, for example, indicate the type of flavourant with which they are impregnated.
- the beads are between about 0.2 mm and about 2 mm in diameter.
- Liquid flavourants for use in the rod end segments of multi-component filters according to the present invention may include one or more flavour ingredients to create a certain flavour type and may be natural extracts, synthetic flavours, or a combination thereof.
- Liquid flavourants and flavour types that may be included in the rod end segment of multi-component filters according to the present invention include, but are not limited to, menthol, peppermint, spearmint, coffee, tea, spices (such as cinnamon, clove and ginger), cocoa, vanilla and fruit flavourants.
- the multi-component filter comprises a liquid menthol flavourant.
- the provision of a menthol flavourant in the rod end segment advantageously enhances the flavour released into mainstream smoke drawn through the filter during smoking and compliments the menthol and mint flavours released downstream into the mainstream smoke by the peppermint leaf In the flavour release segment.
- the mouth end segment may comprise at least one flavourant, such as those previously described above for the rod end segment.
- a flavourant such as those previously described above for the rod end segment.
- the mouth end segment includes one or more threads impregnated with liquid flavourant.
- Multi-component filters according to the present Invention may include mouth end segments comprising at least one flavourant or rod end segments comprising at least one flavourant or mouth end segments comprising at least one flavourant and rod end segments comprising at least one flavourent.
- the mouth end segment and the rod end segment comprise at least one flavourant
- the at least one flavourant in the mouth end segment may be the same as or different to the at least one flavourant in the rod end segment.
- flavour is released into the mainstream smoke from the peppermint leaf in the flavour release segment.
- flavour is also released upstream of the flavour release segment as previously described above.
- flavour is also released downstream of the flavour release segment.
- Multi-component filters according to the present invention may, therefore, provide dual or triple flavour enhancement to mainstream smoke drawn through the filter during smoking,
- Multi-component filters according to the present invention may be produced by forming separate continuous rods comprising multiple units of each individual segment of the multi-component filter and then combining these separate rods in a known manner in one or more stages to form a continuous filter rod comprising multiple units of the multi-component filter.
- the continuous filter rod may then be subsequently severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters according to the invention.
- smoking articles according to the present invention comprise a wrapped rod of tobacco cut filler.
- smoking articles according to the present invention have a total nicotine free dry particulate matter (NFDPM) or "tar" delivery of up to about 10 mg. More preferably, the "tar delivery” is between 1 mg and 10 mg and more preferably about 6 mg.
- NFDPM nicotine free dry particulate matter
- Smoking articles according to the present invention may be packaged in containers, for example in soft packs or hinge-lid packs, with an inner liner coated with one or more flavourants.
- the peppermint leaf in the flavour release segment is distributed through a plug of fibrous filtration material, preferably a cellulose acetate tow.
- the filter plasticiser Is applied to the fibrous filtration material in a conventional manner, by spraying it onto the separated fibres, preferably before applying the peppermint leaf to the filtration material.
- the peppermint leaf is substantially evenly distributed along the length the plug of fibrous filtration material.
- the loading of peppermint leaf in the flavour release segment is preferably between about 1 mg and about 4 mg per mm of the flavour release segment for a multi-component filter having a diameter of between about 7.5 mm and about 7.8 mm.
- the amount of filter plasticiser may be between 1% and 9% by weight of the plug of fibrous filter material, preferably 5% or less by weight of the plug of fibrous filter material. If glycerol triacetate is used as the filter plasticiser, the amount of glycerol triacetate is preferably about 5% by weight of the cellulose acetate tow or other fibrous filtration material. This level of glycerol triacetate has been found to provide an acceptable rigidity of the plug of fibrous filtration material of the flavour release segment without obstructing the release of flavour from the peppermint leaf. It is notably lower than the amount of glycerol triacetate in conventional cellulose acetate tow filter plugs, which is typically about 7% by weight.
- the flavour segment is preferably between about 5 mm and about 22 mm in length, more preferably between about and 10 mm about 15 mm in length, most preferably about 12 mm in length.
- the mouth end segment may comprise a hollow tube or recess.
- the hollow tube or recess may be formed when the multi-component filter is attached to a rod of smokable material by, for example, tipping paper to form a smoking article according to the present invention.
- the downstream end of the flavour release segment is visible at the mouth end of the multi-component filter through the hollow tube or recess, allowing the consumer to see the peppermint leaf distributed in the plug of fibrous filtration material.
- the length of the mouth end segment is preferably between about 3 mm and about 4 mm.
- Multi-component filters according to the present invention may further comprise a second flavour release segment between the mouth end segment and the flavour release segment previously described.
- the inclusion of a second flavour release segment further enhances flavour delivery to the consumer during smoking.
- the second flavour release segment comprises tobacco leaf.
- the tobacco leaf may be shredded, cut, or otherwise reduced in size.
- the tobacco leaf is finely cut and more preferably, the tobacco leaf has a cut width of about 0.4 mm.
- the tobacco leaf in the second flavour release segment is dried.
- the moisture content of the tobacco leaf is about 15% or less by weight.
- the length of the second flavour release segment is between about 6 mm and about 12 mm, more preferably between about 6 mm and about 10 mm.
- the second flavour release segment may include tobacco leaf to which casing comprising, for example, sugars or humectants has been applied.
- the filter cigarettes shown in Figures 1 to 8 have several components in common and these components have been given the same reference numerals. In each of the side views, portions have been broken away to illustrate interior details of the multi-component filter.
- Each filter cigarette generally comprises an elongate, cylindrical wrapped tobacco rod 2 attached at one end to an axially aligned, elongate, cylindrical, multi-component filter 4.
- the wrapped tobacco rod 2 and the multi-component filter 4 are joined in a conventional manner by tipping paper 6, which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrapped tobacco rod 2.
- tipping paper 6 which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrapped tobacco rod 2.
- a plurality of annular perforations 8 are provided through the tipping paper 6 at a location along the multi-component filter 4.
- the multi-component filter 4 of the filter cigarette 10 includes two segments in abutting end-to-end relationship: a mouth end segment 12, distant from the wrapped tobacco rod 2; and a flavour release segment 14, located upstream of the mouth end segment 12 and adjacent to and abutting the wrapped tobacco rod 2.
- the mouth end segment 12 comprises a plug of cellulose acetate tow of low filtration efficiency plasticised with glycerol triacetate.
- the flavour release segment 14 comprises a plug of cellulose acetate tow with dried peppermint leaf having a cut width of between 1 mm and 2 mm substantially evenly distributed through it.
- the plug of cellulose acetate tow includes 5 % by weight of glycerol triacetate plasticiser.
- the mouth end segment 12 of the multi-component filter 4 shown in Figure 1 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
- the multi-component filter 4 of the filter cigarette 20 shown in Figure 2 is of similar construction to the multi-component filter 4 of the filter cigarette 10 shown in Figure 1 and described above.
- the mouth end segment 12 of the filter cigarette 20 shown in Figure 2 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 20.
- the filter cigarette 30 shown in Figure 3 has a multi-component filter 4 that includes three segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a flavour release segment 14 located upstream of the mouth end segment; and a rod end segment 32, located upstream of the flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2.
- the mouth end segment 12 and the flavour release segment 14 are of the same construction as those previously described for the filter cigarette 10 shown in Figure 1 .
- the rod end segment 32 comprises a plug of cellulose acetate tow of medium to high filtration efficiency which, in use, partially filters out particulate phase components of the mainstream smoke.
- the multi-component filter 4 of the filter cigarette 40 shown in Figure 4 is of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
- the mouth end segment 12 of the filter cigarette 40 shown in Figure 4 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 40.
- the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 is also of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
- the rod end segment 32 of the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 comprises a central cotton thread 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 50.
- the multi-component filter 4 of the filter cigarette 60 shown in Figure 6 is once again of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
- both the rod end segment 32 and the mouth end segment 12 of the multi-component filter 4 of the filter cigarette 60 shown in Figure 6 comprise a central cotton thread 22, 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 60.
- the rod end segments 32 of the multi-component filters of the filter cigarettes. 40, 50, 60 shown in Figures 4, 5 and 6 may further comprise at least one sorbent capable of removing gas phase constituents from mainstream smoke drawn through the filters 4.
- the at least one sorbent is, for example, activated carbon, activated aluminium, zeolites or sepiolites provided on the cellulose acetate tow.
- the multi-component filter 4 of the filter cigarette 70 shown in Figure 7 Is of similar construction to the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 and described above.
- the rod end segment 32 of the multi-component filter 4 of the filter cigarette 70 shown in Figure 7 comprises a plurality of Viscopearls® loaded with menthol, in place of the central cotton thread 52.
- the mouth end segments 12 of the multi-component filters 4 of the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
- the filter cigarette 90 shown in Figure 8 has a multi-component filter 4 that includes four segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a first flavour release segment 92 located upstream of the mouth end segment, a second flavour release segment 14 located upstream of the first flavour release segment and a rod end segment 32, located upstream of the second flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2.
- the mouth end segment 12, the second flavour release segment 14 and the rod end segment 32 are of the same construction as the mouth end segment, the flavour release segment and the rod end segment previously described for the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7 .
- the second flavour release segment 92 comprises a plug of densely packed fine cut tobacco.
- the multi-component filters 4 are produced and then joined to the wrapped tobacco rods 2, which are produced in a conventional manner, by the tipping paper 6 using known filter cigarette making equipment
- each multi-component filter 4 separate continuous rods comprising multiple units of each segment 12, 14, 32, 92 of the multi-component filter 4 are produced in a known manner and then combined to form a continuous filter rod comprising multiple units of the multi-component filter 4.
- the continuous filter rod is then severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters.
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Abstract
Description
- The present invention relates to a multi-component filter for a smoking article and to a smoking article comprising such a multi-component filter.
- Filter cigarettes typically comprise a rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter aligned in end-to-end relationship with the wrapped tobacco rod and attached thereto by tipping paper. Ventllation In the form of circumferential perforations is commonly provided at a location along the filter, to mix the mainstream smoke produced during combustion of the wrapped tobacco rod with ambient air.
- In conventional filter cigarettes, the filter usually consists of a plug of cellulose acetate tow wrapped in porous plug wrap. However, filter cigarettes with multi-component filters that comprise two or more segments of filtration material for the removal of particulate and gaseous components of the mainstream smoke are also known. To enhance the flavour of the mainstream smoke, it is known to provide filter cigarettes with filters that include flavourants. In particular, it has been proposed to include flavourants in the form of plant material, such as leaves, seeds or roots, from one or more aromatic plants. In one known example, a filter cigarette is proposed with a multi-component filter having a flavour release segment containing a mixture of plant materials, including liquorice plant material, ginger root and shredded peppermint leaf.
- It is also known to incorporate tobacco plant material into the filter of a smoking article. For example,
WO-A-2006/090290 discloses a filter induding tobacco beads within the filter. The tobacco beads optionally include flavourants in addition to tobacco particulates. - It would be desirable to provide a multi-component filter for a smoking article that, in use, provides improved flavour enhancement, and in particular improved mint and menthol flavour delivery to mainstream smoke as it is drawn from a rod of smokable material through the filter by a consumer. Furthermore, it would be desirable to provide a multi-component filter for a smoking article comprising a flavour release segment that minimises loss of flavour during storage.
- According to the present invention there is provided a multi-component filter for a smoking article comprising: a mouth end segment; and a flavour release segment upstream of the mouth end segment. The flavour release segment comprises a plug of fibrous filtration material, peppermint leaf distributed through the fibrous filtration material and a filter plasticiser applied to the fibrous filtration material. The amount of filter plasticiser in the flavour release segment is up to 5% by weight of the fibrous filtration material.
- According to the invention there is also provided a smoking article comprising a wrapped rod of smokable material and a multi-component filter according to the present invention attached to the rod of smokable material, preferably by tipping paper. Preferably, the smoking article is a filter cigarette.
- Throughout the specification, the terms "upstream" and "downstream" are used to describe the relative positions of segments of the multi-component filter of the invention in relation to the direction of the mainstream smoke drawn from a rod of smokable material through the multi-component filter during use. For example, in the filter of the present invention the flavour release segment is upstream of the mouth end segment, which means that mainstream smoke is drawn first through the flavour release segment and then through the mouth end segment.
- The term "filter plasticiser" refers to any compound suitable for use as a plasticiser in a conventional fibrous cigarette filter plug. In conventional fibrous filter plugs, the role of a filter plasticiser is to bind together the fibres of the plug so that the rigidity of the plug, and therefore its resistance to compression, is increased. The plasticiser is typically a solvent for the fibre material and acts by softening the outer surfaces of the fibres such that they adhere to each other. Glycerol triacetate is commonly used as the filter plasticiser for a cellulose acetate tow.
- Preferably, the filter plasticiser used in the present invention is glycerol triacetate.
- The term "peppermint leaf" is used to denote a material consisting of the leaves of a peppermint plant, which have preferably been cut or shredded to provide a particulate material.
- The peppermint leaf is capable of releasing flavour into mainstream smoke drawn through the multi-component filter. The flavour released from the peppermint leaf is provided by volatile compounds, such as oils, contained therein, which are volatilised during smoking. The mainstream smoke enriched with the volatile oils from the peppermint leaf flows downstream through the mouth end segment of the multi-component filter into the consumer's mouth.
- Prior to smoking, the volatile oils remain trapped within the peppermint leaf. This advantageously ensures that loss of flavour during storage of multi-component filters and smoking articles according to the present invention is minimised, and so maximises flavour release into the mainstream smoke during smoking.
- Preferably, the peppermint leaf in the flavour release segment is shredded, cut or otherwise reduced in size. More preferably, the peppermint leaf has a cut width of between about 0.25 mm and about 3 mm. Most preferably, the peppermint leaf has a cut width of between about 1 mm and about 2 mm.
- Preferably, the peppermint leaf is dried to a moisture content of between about 8 % and about 10 %.
- Preferably, the oil content of the peppermint leaf is at least about 0.6 % by weight. The inclusion of peppermint leaf in the flavour release segment of multi-component filters according to the present invention advantageously provides an improved way of imparting mint and menthol flavours to the mainstream smoke of a smoking article. Smoking articles according to the present invention advantageously provide enhanced mint and menthol flavours compared to conventional menthol cigarettes.
- In particularly preferred embodiments of the invention, the filter plasticiser is glycerol triacetate. It has surprisingly been found that the inclusion of peppermint leaf and glycerol triacetate in the flavour release segment of multi-component filters and smoking articles according to the present invention advantageously enhances the mint and menthol flavour provided by the release of menthol and other volatile oils from the peppermint leaf. This Is illustrated, for example, by the results shown in Table 1, below.
- Table 1 shows the quantities of particular flavour compounds released into the mainstream smoke from peppermint leaf in the flavour release segment of filter cigarettes (Samples 1 and 3) according to the Invention having the general construction shown In
Figure 1 . The flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein. Table 1 also shows the quantities of the flavour compounds released from peppermint leaf In the flavour release segment of filter cigarettes (Samples 2 and 4) not according to the Invention having the same construction as Samples 1 and 3, but in which the flavour release segment does not contain glycerol triacetate. Each of the samples contains 40 mg of peppermint leaf. Not all of the compounds released from the peppermint leaf are measured. - Each of the samples is smoked under ISO conditions and the smoke extracts obtained are analysed using a GC-MS single ion monitoring method in order to determine the levels of the volatile compounds in the smoke. A full scan analysis with a scan range from 30 to 400 m/z (anion mass to charge ratio) is performed.
- As can be seen from Table 1, the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the filter cigarettes according to the present invention results in increased levels of flavour compound being released from the peppermint leaf into the mainstream smoke during smoking compared to the filter cigarettes not according to the Invention, in which the flavour release segment does not contain glycerol triacetate.
Table 1 Sample 1 Sample 2Sample 3 Sample 4 Tar, mg/cigarette 1 1 6 6 Glycerol triacetate content of flavour release segment, % 5 0 6 0 Amount of menthol released into mainstream smoke during smoking, µg/cigarette 0.70 0.25 3.63 1.79 Amount of menthone released into mainstream smoke during smoking, µg/cigarette 0.45 0.36 1.19 0.87 Amount of menthyl acetate released into mainstream smoke during smoking, µg/cigarette nd nd 0.187 0.052 Amount of neomenthol released Into mainstream smoke during smoking, µh/cigarette 0.050 0.018 0.254 0.124 Amount of α-pinene released into mainstream smoke during smoking, µg/cigarette nd nd 0.032 0.030 Amount of β-pinene released into mainstream smoke during smoking, µg/cigarette nd nd 0.050 0.049 (nd = not determined) - During smoking of a smoking article comprising a multi-component filter according to the invention in which the filter plasticiser is glycerol triacetate, acetic acid and glycerine are released in the flavour release segment of the filter as a result of hydrolysis of the glycerol triacetate. Accordingly, the levels of acetic acid released In the filter during smoking are significantly higher than for a smoking article not according to the invention, as illustrated by the results shown in Table 2, below. Table 2 gives the dimensions and properties of a filter cigarette (Sample 5) according to the present invention having the general construction shown in Figure 9. The mouth end segment of the filter cigarette consists of a plug of cellulose acetate tow and the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein. Table 2 also gives the dimensions and properties of a filter cigarette (Sample 6) not according to the present invention having the same construction as Sample 5, but in which the flavour release segment does not contain glycerol triacetate.
- As can be seen from Table 2, the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the multi-component filter of the filter cigarette according to the present Invention (Sample 5) results in a significantly increased level of acetic acid being released in the filter compared to the filter cigarette not according to the present Invention (Sample 6), in which only the mouth end segment contains glycerol triacetate.
Table 2 Sample 5 Sample 6Tar, mg/cigarette 6.1 6.2 Total RTD, mmH2O 93 92 Ventilation, % 35 36 Length of cigarette, mm 84.0 84.0 Length of mouth end segment, mm 15.0 15.0 Length of flavour release segment, mm 12.0 12.0 Filter RTD, mmH2O 92.7 91.2 Glycerol triacetate content of mouth segment, % 7.0 7.0 Glycerol triacetate content of flavour release segment, % 5.0 0.0 Peppermint leaves content, mg 40.0 40.0 Acetic acid concentration, ppm (based on cigarette weight = 920mg) 221 57 - Preferably, the overall length of smoking articles according to the present invention is between about 70 mm and about 128 mm, more preferably about 84 mm.
- Preferably, the external diameter of multi-component filters and smoking articles according to the present invention is between about 5 mm and 8.5 mm, more preferably about 7.9 mm.
- Preferably, the overall length of multi-component filters according to the present invention is between about 18 mm and about 36 mm, more preferably about 27 mm.
- Preferably, the length of each individual segment of multi-component filters according to the present invention is between about 5 mm and about 22 mm.
- The mouth end segment of multi-component filters according to the present invention may, in some embodiments, advantageously prevent peppermint leaf from the flavour release segment reaching the mouth of the consumer during smoking. Preferably, the mouth end segment comprises filtration material. More preferably, the mouth end segment comprises filtration material that has substantially no particulate phase filtration efficiency or very low particulate phase filtration efficiency. The mouth end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration material of low filtration efficiency.
- Where the mouth end segment comprises filtration material, the length of the mouth end segment is preferably between about 3 mm and about 12 mm, more preferably between about 6 mm and about 8 mm.
- Multi-component filters according to the present invention may further comprise a rod end segment upstream of the flavour release segment. Preferably, the rod end segment comprises fibrous filtration material. The rod end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration materials such as paper. The inclusion of a rod end segment comprising filtration material advantageously provides additional filtration efficiency.
- Alternatively or in addition, the rod end segment may comprise at least one sorbent capable of removing at least one gas phase constituent from mainstream smoke drawn through the filter. Preferably, the at least one sorbent is selected from the group consisting of activated carbon, active aluminium, zeolites, sepiolites, molecular sieves and silica gel.
- The rod end segment may include one or more flavourants, preferably one or more liquid flavourants, to further enhance flavour delivery to the consumer during smoking.
- For example, the rod end segment may comprise a plug of filtration material including one or more threads impregnated with liquid flavourant. The one or more threads may be made from cellulose acetate yarn, rayon, cotton, or any other hydrophilic textile or non-textile material capable of absorbing or adsorbing the liquid flavourant. The threads may be coloured, for example, to indicate the type of flavourant impregnated therein. If more than one thread is provided, the threads may be the same or different colours and may be impregnated with the same or different liquid flavourants. Preferably, the threads are between about 0.6 mm and about 2.0 mm in diameter, more preferably about 0.8 mm in diameter. Filter plugs comprising flavourant bearing threads suitable for use in rod end segments of multi-component filters according to the present invention, and methods and apparatuses for producing such plugs, are described in
US Patents Nos- 4,281,671 and7,074,170 and are available from the American Filtrona Company, Richmond, Virginia, USA. - Alternatively, the rod end segment may Include a plurality of beads impregnated with liquid flavourant. The beads may be formed from, for example, a cellulosic material bonded with a polyvinyl acetate binder, or from tobacco powder bonded with microcrystalline cellulose. Beads suitable for use In rod end segments of multi-component filters according to the present invention are manufactured and sold under the brand Viscopearls® by Rengo Co. Ltd., Japan. Methods and apparatuses for producing such beads are also described in
Japanese Patent Application No. 10182842 - Liquid flavourants for use in the rod end segments of multi-component filters according to the present invention may include one or more flavour ingredients to create a certain flavour type and may be natural extracts, synthetic flavours, or a combination thereof. Liquid flavourants and flavour types that may be included in the rod end segment of multi-component filters according to the present invention include, but are not limited to, menthol, peppermint, spearmint, coffee, tea, spices (such as cinnamon, clove and ginger), cocoa, vanilla and fruit flavourants. In preferred embodiments of the present invention, the multi-component filter comprises a liquid menthol flavourant. In such embodiments, the provision of a menthol flavourant in the rod end segment advantageously enhances the flavour released into mainstream smoke drawn through the filter during smoking and compliments the menthol and mint flavours released downstream into the mainstream smoke by the peppermint leaf In the flavour release segment.
- The mouth end segment may comprise at least one flavourant, such as those previously described above for the rod end segment. Preferably, if a flavourant is provided, the mouth end segment includes one or more threads impregnated with liquid flavourant.
- Multi-component filters according to the present Invention may include mouth end segments comprising at least one flavourant or rod end segments comprising at least one flavourant or mouth end segments comprising at least one flavourant and rod end segments comprising at least one flavourent. Where the mouth end segment and the rod end segment comprise at least one flavourant, the at least one flavourant in the mouth end segment may be the same as or different to the at least one flavourant in the rod end segment.
- In use, as mainstream smoke is drawn from a rod of smokable material through the multi-component filter, flavour is released into the mainstream smoke from the peppermint leaf in the flavour release segment. In embodiments of the present invention in which at least one flavourant is provided in the rod end segment, flavour is also released upstream of the flavour release segment as previously described above. In embodiments of the present invention in which at least one flavourant is alternatively or additionally provided in the mouth end segment, flavour is also released downstream of the flavour release segment. Multi-component filters according to the present invention may, therefore, provide dual or triple flavour enhancement to mainstream smoke drawn through the filter during smoking,
- Multi-component filters according to the present invention may be produced by forming separate continuous rods comprising multiple units of each individual segment of the multi-component filter and then combining these separate rods in a known manner in one or more stages to form a continuous filter rod comprising multiple units of the multi-component filter. The continuous filter rod may then be subsequently severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters according to the invention.
- Preferably, smoking articles according to the present invention comprise a wrapped rod of tobacco cut filler.
- Preferably, smoking articles according to the present invention have a total nicotine free dry particulate matter (NFDPM) or "tar" delivery of up to about 10 mg. More preferably, the "tar delivery" is between 1 mg and 10 mg and more preferably about 6 mg.
- Smoking articles according to the present invention may be packaged in containers, for example in soft packs or hinge-lid packs, with an inner liner coated with one or more flavourants.
- In the filter of the present invention, the peppermint leaf in the flavour release segment is distributed through a plug of fibrous filtration material, preferably a cellulose acetate tow. The filter plasticiser Is applied to the fibrous filtration material in a conventional manner, by spraying it onto the separated fibres, preferably before applying the peppermint leaf to the filtration material.
- Preferably, the peppermint leaf is substantially evenly distributed along the length the plug of fibrous filtration material. The loading of peppermint leaf in the flavour release segment is preferably between about 1 mg and about 4 mg per mm of the flavour release segment for a multi-component filter having a diameter of between about 7.5 mm and about 7.8 mm.
- The amount of filter plasticiser may be between 1% and 9% by weight of the plug of fibrous filter material, preferably 5% or less by weight of the plug of fibrous filter material. If glycerol triacetate is used as the filter plasticiser, the amount of glycerol triacetate is preferably about 5% by weight of the cellulose acetate tow or other fibrous filtration material. This level of glycerol triacetate has been found to provide an acceptable rigidity of the plug of fibrous filtration material of the flavour release segment without obstructing the release of flavour from the peppermint leaf. It is notably lower than the amount of glycerol triacetate in conventional cellulose acetate tow filter plugs, which is typically about 7% by weight.
- In smoking articles according to the invention, the flavour segment is preferably between about 5 mm and about 22 mm in length, more preferably between about and 10 mm about 15 mm in length, most preferably about 12 mm in length.
- In smoking articles according to the invention, the mouth end segment may comprise a hollow tube or recess. The hollow tube or recess may be formed when the multi-component filter is attached to a rod of smokable material by, for example, tipping paper to form a smoking article according to the present invention. In such smoking articles, the downstream end of the flavour release segment is visible at the mouth end of the multi-component filter through the hollow tube or recess, allowing the consumer to see the peppermint leaf distributed in the plug of fibrous filtration material. Where the mouth end segment comprises a hollow tube or recess, the length of the mouth end segment is preferably between about 3 mm and about 4 mm.
- Multi-component filters according to the present invention may further comprise a second flavour release segment between the mouth end segment and the flavour release segment previously described. The inclusion of a second flavour release segment further enhances flavour delivery to the consumer during smoking.
- Preferably, the second flavour release segment comprises tobacco leaf. The tobacco leaf may be shredded, cut, or otherwise reduced in size. Preferably, the tobacco leaf is finely cut and more preferably, the tobacco leaf has a cut width of about 0.4 mm.
- Preferably the tobacco leaf in the second flavour release segment is dried. Preferably the moisture content of the tobacco leaf is about 15% or less by weight.
- Preferably, the length of the second flavour release segment is between about 6 mm and about 12 mm, more preferably between about 6 mm and about 10 mm.
- The second flavour release segment may include tobacco leaf to which casing comprising, for example, sugars or humectants has been applied.
- The invention will be further described, by way of example only, with reference to the accompanying drawings, in which:
-
Figures 1 to 3 show side views of three filter cigarettes comprising multi-component filters according to first, second and third embodiments, respectively, of the first aspect of the present invention; -
Figures 4 to 7 show schematic longitudinal cross sections of four filter cigarettes comprising multi-component filters according to fourth to seventh embodiments, respectively, of the present invention; and -
Figure 8 shows a side view of a filter cigarette comprising a multi-component filter according to an alternative embodiment of the present invention. - The filter cigarettes shown in
Figures 1 to 8 have several components in common and these components have been given the same reference numerals. In each of the side views, portions have been broken away to illustrate interior details of the multi-component filter. - Each filter cigarette generally comprises an elongate, cylindrical wrapped
tobacco rod 2 attached at one end to an axially aligned, elongate, cylindrical, multi-component filter 4. The wrappedtobacco rod 2 and the multi-component filter 4 are joined in a conventional manner by tippingpaper 6, which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrappedtobacco rod 2. To ventilate mainstream smoke produced during combustion of the wrapped tobacco rod 4 with ambient air, a plurality ofannular perforations 8 are provided through the tippingpaper 6 at a location along the multi-component filter 4. - The multi-component filter 4 of the
filter cigarette 10 according to the first embodiment of the invention shown InFigure 1 includes two segments in abutting end-to-end relationship: amouth end segment 12, distant from the wrappedtobacco rod 2; and aflavour release segment 14, located upstream of themouth end segment 12 and adjacent to and abutting the wrappedtobacco rod 2. Themouth end segment 12 comprises a plug of cellulose acetate tow of low filtration efficiency plasticised with glycerol triacetate. Theflavour release segment 14 comprises a plug of cellulose acetate tow with dried peppermint leaf having a cut width of between 1 mm and 2 mm substantially evenly distributed through it. The plug of cellulose acetate tow includes 5 % by weight of glycerol triacetate plasticiser. - In an alternative embodiment of the present invention (not shown), the
mouth end segment 12 of the multi-component filter 4 shown inFigure 1 is replaced by a recess, which has substantially no filtration efficiency, formed by the tippingpaper 6. - The multi-component filter 4 of the
filter cigarette 20 shown inFigure 2 is of similar construction to the multi-component filter 4 of thefilter cigarette 10 shown inFigure 1 and described above. However, themouth end segment 12 of thefilter cigarette 20 shown inFigure 2 further comprises acentral cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of thefilter cigarette 20. - The
filter cigarette 30 shown inFigure 3 has a multi-component filter 4 that includes three segments in abutting end-to-end relationship: amouth end segment 12, distant from thetobacco rod 2; aflavour release segment 14 located upstream of the mouth end segment; and arod end segment 32, located upstream of theflavour release segment 14 and adjacent to and abutting the wrappedtobacco rod 2. Themouth end segment 12 and theflavour release segment 14 are of the same construction as those previously described for thefilter cigarette 10 shown inFigure 1 . - The
rod end segment 32 comprises a plug of cellulose acetate tow of medium to high filtration efficiency which, in use, partially filters out particulate phase components of the mainstream smoke. - The multi-component filter 4 of the
filter cigarette 40 shown inFigure 4 is of similar construction to the multi-component filter 4 of thefilter cigarette 30 shown inFigure 3 and described above. However, themouth end segment 12 of thefilter cigarette 40 shown inFigure 4 further comprises acentral cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of thefilter cigarette 40. - The multi-component filter 4 of the
filter cigarette 50 shown inFigure 5 is also of similar construction to the multi-component filter 4 of thefilter cigarette 30 shown inFigure 3 and described above. However, therod end segment 32 of the multi-component filter 4 of thefilter cigarette 50 shown inFigure 5 comprises acentral cotton thread 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of thefilter cigarette 50. - The multi-component filter 4 of the
filter cigarette 60 shown inFigure 6 is once again of similar construction to the multi-component filter 4 of thefilter cigarette 30 shown inFigure 3 and described above. However, both therod end segment 32 and themouth end segment 12 of the multi-component filter 4 of thefilter cigarette 60 shown inFigure 6 comprise acentral cotton thread filter cigarette 60. - In alternative embodiments of the present invention (not shown), the
rod end segments 32 of the multi-component filters of the filter cigarettes. 40, 50, 60 shown inFigures 4, 5 and 6 may further comprise at least one sorbent capable of removing gas phase constituents from mainstream smoke drawn through the filters 4. The at least one sorbent is, for example, activated carbon, activated aluminium, zeolites or sepiolites provided on the cellulose acetate tow. - The multi-component filter 4 of the
filter cigarette 70 shown inFigure 7 Is of similar construction to the multi-component filter 4 of thefilter cigarette 50 shown inFigure 5 and described above. However, therod end segment 32 of the multi-component filter 4 of thefilter cigarette 70 shown inFigure 7 comprises a plurality of Viscopearls® loaded with menthol, in place of thecentral cotton thread 52. - In alternative embodiments of the present invention (not shown), the
mouth end segments 12 of the multi-component filters 4 of thefilter cigarettes Figures 3 to 7 is replaced by a recess, which has substantially no filtration efficiency, formed by the tippingpaper 6. - The
filter cigarette 90 shown inFigure 8 has a multi-component filter 4 that includes four segments in abutting end-to-end relationship: amouth end segment 12, distant from thetobacco rod 2; a firstflavour release segment 92 located upstream of the mouth end segment, a secondflavour release segment 14 located upstream of the first flavour release segment and arod end segment 32, located upstream of the secondflavour release segment 14 and adjacent to and abutting the wrappedtobacco rod 2. Themouth end segment 12, the secondflavour release segment 14 and therod end segment 32 are of the same construction as the mouth end segment, the flavour release segment and the rod end segment previously described for thefilter cigarettes Figures 3 to 7 . The secondflavour release segment 92 comprises a plug of densely packed fine cut tobacco. - To form the
filter cigarettes Figures 1 to 8 , the multi-component filters 4 are produced and then joined to the wrappedtobacco rods 2, which are produced in a conventional manner, by the tippingpaper 6 using known filter cigarette making equipment - To produce each multi-component filter 4, separate continuous rods comprising multiple units of each
segment
Claims (10)
- A multi-component filter (4) for a smoking article comprising:a mouth end segment (12); anda flavour release segment (14) upstream of the mouth end segment (12),wherein the flavour release segment (14) comprises a plug of fibrous filtration material, peppermint leaf distributed through the fibrous filtration material and a filter plasticiser applied to the fibrous filtration material, wherein the amount of filter plasticiser in the flavour release segment is up to 5% by weight of the fibrous filtration material.
- A multi-component filter (4) according to claim 1 wherein the filter plasticiser is glycerol triacetate.
- A multi-component filter (4) according to claim 2 wherein the amount of glycerol triacetate Is between 0.5 % and 1.5 % by weight of the peppermint leaf.
- A multi-component filter (4) according to claim 1, 2 or 3 wherein the flavour release segment (14) comprises a plug of cellulose acetate tow with the peppermint leaf distributed therein.
- A multi-component filter (4) according to any preceding claim further comprising a rod end segment (32) upstream of the flavour release segment (14),
- A multi-component filter according to any preceding claim further comprising a second flavour release segment between the mouth end segment and the flavour release segment.
- A multi-component filter (4) according to any preceding claim wherein the mouth end segment (12) comprises filtration material.
- A multi-component filter (4) according to any preceding claim wherein the mouth end segment (12) comprises at least one liquid flavourant.
- A smoking article (10)(20)(30)(40)(50)(60)(70)(80) comprising:a wrapped rod of smokable material (2); anda multi-component filter (4) according to any preceding claim attached to the rod of smokable material (2) by tipping paper (6).
- A smoking article (10)(20)(30)(40)(50)(60)(70)(80) according to claim 9 wherein the mouth end segment (12) of the multi-component filter (4) is a hollow tube or recess.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12168428.6A EP2494877B2 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
PL08827853T PL2175749T3 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
SI200830681T SI2175749T1 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
EP08827853A EP2175749B1 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07253246A EP2025251A1 (en) | 2007-08-17 | 2007-08-17 | Multi-component filter for a smoking article |
PCT/IB2008/002887 WO2009024866A2 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
EP08827853A EP2175749B1 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12168428.6A Division EP2494877B2 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
EP12168428.6 Division-Into | 2012-05-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2175749A2 EP2175749A2 (en) | 2010-04-21 |
EP2175749B1 true EP2175749B1 (en) | 2012-06-27 |
Family
ID=38922805
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07253246A Ceased EP2025251A1 (en) | 2007-08-17 | 2007-08-17 | Multi-component filter for a smoking article |
EP08827853A Active EP2175749B1 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
EP12168428.6A Active EP2494877B2 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07253246A Ceased EP2025251A1 (en) | 2007-08-17 | 2007-08-17 | Multi-component filter for a smoking article |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12168428.6A Active EP2494877B2 (en) | 2007-08-17 | 2008-08-14 | Multi-component filter for a smoking article |
Country Status (24)
Country | Link |
---|---|
US (1) | US20090044817A1 (en) |
EP (3) | EP2025251A1 (en) |
JP (2) | JP5356386B2 (en) |
KR (1) | KR101514095B1 (en) |
CN (2) | CN105495685A (en) |
AR (1) | AR067942A1 (en) |
AU (1) | AU2008290277B2 (en) |
BR (1) | BRPI0813791B1 (en) |
CO (1) | CO6251217A2 (en) |
DK (1) | DK2175749T3 (en) |
EA (2) | EA016920B1 (en) |
ES (2) | ES2504098T5 (en) |
HK (2) | HK1138158A1 (en) |
MX (1) | MX2009013969A (en) |
MY (1) | MY165545A (en) |
NZ (1) | NZ582088A (en) |
PL (1) | PL2175749T3 (en) |
PT (1) | PT2175749E (en) |
RS (1) | RS52406B (en) |
SG (1) | SG183002A1 (en) |
SI (1) | SI2175749T1 (en) |
TW (1) | TWI446877B (en) |
UA (1) | UA98664C2 (en) |
WO (1) | WO2009024866A2 (en) |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0820229D0 (en) * | 2008-11-05 | 2008-12-10 | British American Tobacco Co | Filter for a smoking article |
GB0911181D0 (en) * | 2009-06-29 | 2009-08-12 | British American Tobacco Co | A filter for a smoking article |
EP2324722A1 (en) * | 2009-11-23 | 2011-05-25 | Philip Morris Products S.A. | Novel filter segment comprising a substrate loaded with a smoke-modifying agent |
KR101320501B1 (en) * | 2009-11-23 | 2013-10-23 | 엘지디스플레이 주식회사 | Flexible display device and manufacturing method thereof |
GB0922253D0 (en) * | 2009-12-21 | 2010-02-03 | British American Tobacco Co | Sheet filter materials with additives |
GB201004976D0 (en) * | 2010-03-24 | 2010-05-12 | Filtrona Int Ltd | Tobacco smoke filter |
GB201007946D0 (en) * | 2010-05-12 | 2010-06-30 | British American Tobacco Co | Filter additive |
EP2401929A1 (en) * | 2010-06-30 | 2012-01-04 | Philip Morris Products S.A. | Filter for a smoking article |
JP5766934B2 (en) * | 2010-11-01 | 2015-08-19 | 株式会社ダイセル | Tobacco filter, method for producing the same, and tobacco |
EP2462822A1 (en) * | 2010-12-13 | 2012-06-13 | Philip Morris Products S.A. | Smoking article including flavour granules |
WO2012105453A1 (en) * | 2011-02-03 | 2012-08-09 | 日本たばこ産業株式会社 | Filter for cigarette and cigarette with filter |
GB201104788D0 (en) * | 2011-03-22 | 2011-05-04 | British American Tobacco Co | Smoking article |
CN102302220A (en) * | 2011-08-28 | 2012-01-04 | 云南烟草科学研究院 | Application of lemon balm to binary composite filter tips |
CN102423133A (en) * | 2011-08-28 | 2012-04-25 | 云南烟草科学研究院 | Application of mint leaves in binary composite filter tip |
UA112328C2 (en) | 2011-11-07 | 2016-08-25 | Філіп Морріс Продактс С.А. | MENTAL CONTINUOUS SMOKING PRODUCTS |
WO2013098957A1 (en) * | 2011-12-27 | 2013-07-04 | 日本たばこ産業株式会社 | Filter assembly for cigarette, and cigarette |
AR089602A1 (en) | 2011-12-30 | 2014-09-03 | Philip Morris Products Sa | AEROSOL GENERATOR ARTICLE FOR USE WITH AN AEROSOL GENERATOR DEVICE |
JP6227555B2 (en) * | 2011-12-30 | 2017-11-08 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking article with front plug and method thereof |
RU2620491C2 (en) | 2011-12-30 | 2017-05-25 | Филип Моррис Продактс С.А. | Smoking product with front plug and aerosol-forming substrate and method of its use |
EP2625975A1 (en) | 2012-02-13 | 2013-08-14 | Philip Morris Products S.A. | Aerosol-generating article having an aerosol-cooling element |
KR102157508B1 (en) | 2012-05-31 | 2020-09-21 | 필립모리스 프로덕츠 에스.에이. | Flavoured rods for use in aerosol-generating articles |
AR091509A1 (en) | 2012-06-21 | 2015-02-11 | Philip Morris Products Sa | ARTICLE TO SMOKE TO BE USED WITH AN INTERNAL HEATING ELEMENT |
EP2879528B1 (en) | 2012-08-06 | 2018-05-23 | Philip Morris Products S.a.s. | Method of forming smoking articles with mouth end cavities |
EP2712510B1 (en) * | 2012-09-28 | 2016-03-02 | Reemtsma Cigarettenfabriken GmbH | Smoking article |
EP2932860B1 (en) * | 2012-12-13 | 2019-11-20 | Japan Tobacco Inc. | Cigarette |
US20140261486A1 (en) * | 2013-03-12 | 2014-09-18 | R.J. Reynolds Tobacco Company | Electronic smoking article having a vapor-enhancing apparatus and associated method |
LT2978327T (en) * | 2013-03-28 | 2019-02-11 | Philip Morris Products S.A. | Smoking article including a flavour delivery member |
WO2015181949A1 (en) * | 2014-05-30 | 2015-12-03 | 日本たばこ産業株式会社 | Smoking article having filter attached thereto |
GB201421799D0 (en) * | 2014-12-08 | 2015-01-21 | British American Tobacco Co | A Smoking article , a smoking article filtersection and method of manufacturing a smoking article |
TW201635927A (en) | 2015-03-27 | 2016-10-16 | 菲利浦莫里斯製品股份有限公司 | Smoking article with a mouth end cavity and ventilation |
WO2017032784A1 (en) * | 2015-08-24 | 2017-03-02 | Philip Morris Products S.A. | A method for manufacturing multi-component aerosol forming articles |
WO2017187628A1 (en) * | 2016-04-28 | 2017-11-02 | 日本たばこ産業株式会社 | Cigarette with filter |
GB2549803A (en) * | 2016-04-29 | 2017-11-01 | British American Tobacco Investments Ltd | A filter tube for a smoking article |
GB201615603D0 (en) | 2016-09-14 | 2016-10-26 | British American Tobacco Investments Ltd | Receptacle section |
GB201615601D0 (en) | 2016-09-14 | 2016-10-26 | British American Tobacco Investments Ltd | Receptacle section |
GB201615608D0 (en) * | 2016-09-14 | 2016-10-26 | British American Tobacco Investments Ltd | A container |
EP3585188B1 (en) * | 2017-02-27 | 2024-08-14 | Philip Morris Products S.A. | Filter element and method for manufacturing thereof |
JP2017136084A (en) * | 2017-04-05 | 2017-08-10 | 日本たばこ産業株式会社 | cigarette |
GB201717567D0 (en) | 2017-10-25 | 2017-12-06 | British American Tobacco Investments Ltd | A filter for a smoking article or an aerosol generating product |
CN108308704A (en) * | 2017-12-27 | 2018-07-24 | 广东中烟工业有限责任公司 | A kind of composition containing natural extracts and its application in preparing function filter stick plasticizer |
US10555558B2 (en) | 2017-12-29 | 2020-02-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device providing flavor control |
CN109998164A (en) * | 2019-04-03 | 2019-07-12 | 红云红河烟草(集团)有限责任公司 | Cigarette filter stick flavor enhancing particle and cigarette filter stick |
KR102022909B1 (en) * | 2019-06-19 | 2019-09-19 | 주식회사 케이티앤지 | A smoking article with technology modifying sidestream and a smoking article case including the same |
CN111436652A (en) * | 2020-03-13 | 2020-07-24 | 南通烟滤嘴有限责任公司 | Firmware with flow channel corresponding to function and filter stick thereof |
CN112493536B (en) * | 2020-11-13 | 2022-11-04 | 云南养瑞科技集团有限公司 | Heating non-combustion cigarette particle filter stick |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2948282A (en) † | 1954-06-28 | 1960-08-09 | Eastman Kodak Co | Fibrous tobacco smoke filter elements |
GB2020158B (en) | 1978-04-21 | 1982-11-24 | Cigarette Components Ltd | Production of tobacco smoke filters |
ZA804947B (en) | 1979-08-28 | 1981-06-24 | British American Tobacco Co | Smoke filtration |
US4924887A (en) † | 1986-02-03 | 1990-05-15 | R. J. Reynolds Tobacco Company | Tobacco rods and filters |
US4763674A (en) * | 1986-04-16 | 1988-08-16 | Hercules Incorporated | Method and device for controlling hydrogen cyanide and nitric oxide concentrations in cigarette smoke |
GB8722309D0 (en) * | 1987-09-22 | 1987-10-28 | Imp Tobacco Ltd | Smoking articles |
JPH02127194U (en) † | 1989-03-29 | 1990-10-19 | ||
CA2015736A1 (en) * | 1989-05-11 | 1990-11-11 | Diane G. Schmidt | Perfume particles for use in cleaning and conditioning compositions |
US4971078A (en) * | 1989-08-15 | 1990-11-20 | Hoechst Celanese Corporation | Filter for a smoking article containing a flavored hollow fiber |
RU2040190C1 (en) * | 1993-08-17 | 1995-07-25 | Геннадий Николаевич Вакс | Filtering cigarette holder |
JPH08196258A (en) * | 1995-01-25 | 1996-08-06 | Seiichi Kitabayashi | Filter of flavored filter cigarette, flavored filter pipe, etc., and flavored filter cigarette, flavored filter pipe and combined body of flavored filter cigarette or flavored cigarette with filter pipe |
JP3177587B2 (en) * | 1996-12-26 | 2001-06-18 | レンゴー株式会社 | Method for producing cellulose fine particles |
JP4209999B2 (en) | 1998-05-19 | 2009-01-14 | 日本たばこ産業株式会社 | Cigarette filter |
CN2415620Y (en) * | 1999-12-31 | 2001-01-24 | 陈慧刚 | Hollow filter tips for cigarettes |
MY138902A (en) * | 2000-04-20 | 2009-08-28 | Philip Morris Prod | "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials" |
MXPA03007568A (en) * | 2001-02-22 | 2003-12-11 | Philip Morris Prod | Cigarette and filter with downstream flavor addition. |
GEP20043350B (en) † | 2001-11-21 | 2004-01-12 | Telavi State University | Smoking Articles |
US7074170B2 (en) | 2002-03-29 | 2006-07-11 | Philip Morris Usa Inc. | Method and apparatus for making cigarette filters with a centrally located flavored element |
KR200381466Y1 (en) * | 2004-06-24 | 2005-04-14 | 김용호 | Herb eddition tobacco |
US20070000505A1 (en) * | 2005-02-24 | 2007-01-04 | Philip Morris Usa Inc. | Smoking article with tobacco beads |
CN100525662C (en) * | 2005-04-19 | 2009-08-12 | 张鹰 | Delayed releasing mint filter tip for cigarette and its production process |
CN2852725Y (en) * | 2005-12-26 | 2007-01-03 | 张家口卷烟厂 | Cigarette with hollow filter tip |
RS52317B (en) * | 2006-08-04 | 2012-12-31 | Philip Morris Products S.A. | Multi-component filter providing multiple flavour enhancement |
-
2007
- 2007-08-17 EP EP07253246A patent/EP2025251A1/en not_active Ceased
-
2008
- 2008-08-14 WO PCT/IB2008/002887 patent/WO2009024866A2/en active Application Filing
- 2008-08-14 AU AU2008290277A patent/AU2008290277B2/en not_active Ceased
- 2008-08-14 UA UAA201002655A patent/UA98664C2/en unknown
- 2008-08-14 MX MX2009013969A patent/MX2009013969A/en active IP Right Grant
- 2008-08-14 PT PT08827853T patent/PT2175749E/en unknown
- 2008-08-14 EP EP08827853A patent/EP2175749B1/en active Active
- 2008-08-14 EA EA201070284A patent/EA016920B1/en not_active IP Right Cessation
- 2008-08-14 SI SI200830681T patent/SI2175749T1/en unknown
- 2008-08-14 EP EP12168428.6A patent/EP2494877B2/en active Active
- 2008-08-14 ES ES12168428.6T patent/ES2504098T5/en active Active
- 2008-08-14 PL PL08827853T patent/PL2175749T3/en unknown
- 2008-08-14 AR ARP080103555A patent/AR067942A1/en active IP Right Grant
- 2008-08-14 ES ES08827853T patent/ES2386187T3/en active Active
- 2008-08-14 JP JP2010520646A patent/JP5356386B2/en active Active
- 2008-08-14 RS RS20120300A patent/RS52406B/en unknown
- 2008-08-14 SG SG2012049987A patent/SG183002A1/en unknown
- 2008-08-14 CN CN201510956284.6A patent/CN105495685A/en active Pending
- 2008-08-14 CN CN200880100773A patent/CN101790329A/en active Pending
- 2008-08-14 KR KR1020097027362A patent/KR101514095B1/en active IP Right Grant
- 2008-08-14 NZ NZ582088A patent/NZ582088A/en not_active IP Right Cessation
- 2008-08-14 DK DK08827853.6T patent/DK2175749T3/en active
- 2008-08-14 BR BRPI0813791A patent/BRPI0813791B1/en active IP Right Grant
- 2008-08-14 MY MYPI20095564A patent/MY165545A/en unknown
- 2008-08-14 EA EA201200576A patent/EA024076B1/en not_active IP Right Cessation
- 2008-08-15 TW TW097131100A patent/TWI446877B/en not_active IP Right Cessation
- 2008-08-15 US US12/222,788 patent/US20090044817A1/en not_active Abandoned
-
2009
- 2009-12-29 CO CO09148746A patent/CO6251217A2/en active IP Right Grant
-
2010
- 2010-05-19 HK HK10104938.5A patent/HK1138158A1/en not_active IP Right Cessation
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2013
- 2013-01-16 HK HK13100699.9A patent/HK1176244A1/en not_active IP Right Cessation
- 2013-08-28 JP JP2013176767A patent/JP5674885B2/en active Active
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