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EP2147870B1 - Film package - Google Patents

Film package Download PDF

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Publication number
EP2147870B1
EP2147870B1 EP09164270A EP09164270A EP2147870B1 EP 2147870 B1 EP2147870 B1 EP 2147870B1 EP 09164270 A EP09164270 A EP 09164270A EP 09164270 A EP09164270 A EP 09164270A EP 2147870 B1 EP2147870 B1 EP 2147870B1
Authority
EP
European Patent Office
Prior art keywords
foil
component
bag
foil bag
weakening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09164270A
Other languages
German (de)
French (fr)
Other versions
EP2147870A1 (en
Inventor
Ralf Willner
Josef Glogger
Armin Bässler
Frank Thiemann
Thomas Bürgel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hilti AG
Original Assignee
Hilti AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hilti AG filed Critical Hilti AG
Priority to EP11152157A priority Critical patent/EP2322449B1/en
Priority to PL09164270T priority patent/PL2147870T3/en
Publication of EP2147870A1 publication Critical patent/EP2147870A1/en
Application granted granted Critical
Publication of EP2147870B1 publication Critical patent/EP2147870B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B65D81/325Containers having parallel or coaxial compartments, provided with a piston or a movable bottom for discharging contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00553Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with means allowing the stock of material to consist of at least two different components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00553Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with means allowing the stock of material to consist of at least two different components
    • B05C17/00559Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with means allowing the stock of material to consist of at least two different components the different components being stored in coaxial chambers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00583Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes the container for the material to be dispensed being deformable

Definitions

  • the invention relates to a foil container for storing multi-component masses and for insertion into a receptacle of a squeezing device with a first foil bag and a second foil bag arranged next to the first foil bag for separately mounted components of a multi-component mass and with a head part on which at least two receiving sections for each an end of a foil bag are provided.
  • Multi-component materials such as, for example, mortar, foam and sealing compounds, are made available to the user as multicomponent materials in cartridges and film packs.
  • Foil packs have proven themselves as packaging for such masses and are characterized in particular by their compared to cartridges low material content, which must be disposed of after dispensing the mass.
  • foil packs are easy and inexpensive to produce.
  • the film container is in a receptacle of a squeezing device, such.
  • a dispenser inserted or introduced into this.
  • the components are simultaneously squeezed out through an outlet opening on the head part, usually passed through a mixer housing with a mixer element, in which the individual components are mixed to the desired mass, and applied to an application site.
  • a disadvantage of the known solution is that stored in this film pack only two-component masses and in a recording of a squeezing Can be inserted. If three-component masses or masses with even more components are used, until now special extrusion devices and containers are required, which are complicated to build and therefore expensive to manufacture.
  • a film bag with a head piece wherein the film bag is provided with a material weakening at the head end facing in the film, which serves as a predetermined breaking point and opens with increasing internal pressure of the film bag, is from the EP 0 910 995 A2 known.
  • the object of the invention is to provide a foil container for storage and for insertion into a receptacle of a squeezing device for masses with more than two components, which can be brought out with squeezing devices for two-component masses.
  • the first film bag contains at least one component of the multicomponent mass and the second film bag at least two components of the multicomponent mass, wherein a first part (A1) of the first component in the first film bag and a second part (A2) of the first component and a second component different from the first component are proposed in separate foil chambers of the second foil pouch.
  • the dimensions of the film bundle essentially correspond to the dimensions of a film bundle for two-component masses, with which the film bundle according to the invention can be dispensed with conventional dispensing devices already on the market.
  • the components can be provided in the corresponding ratio to one another in the film container. It can also be stored in the film package of more than three components and deployed after insertion into a recording of a squeezing with this.
  • the at least two components of the multicomponent mass are provided in separate foil bag chambers of the second foil bag, whereby a reaction of the at least two components in the second foil bag is prevented.
  • a dividing wall is advantageously provided in the second foil bag, which prevents direct contact of the at least two components during storage in the second foil bag and thus a reaction in the contact area with one another.
  • a first part of a first component of the multicomponent mass in a first film bag and a second part of the first component and a second component of the multicomponent mass different from the first component are provided in separate film chambers of the second film bag.
  • the larger component of the multicomponent mass is divided into two equal or dissimilar parts, whereby different mixing ratios of the components are possible with a constant outer dimension of the film package. For example, this can be done at one In the external dimensions corresponding conventional 3: 1 container realize a different mixing ratio of 5: 1.
  • a film container must be labeled depends on the content of substances subject to labeling, for example the content of peroxide and / or sensitizing methacrylates.
  • Peroxides for example peresters, perketals, hydro- or diacyl peroxides, in particular butyl perbenzoate, cumyl hydroperoxide, dibenzoyl peroxide or lauroyl peroxide
  • the performance of the curable, multicomponent mass is significantly reduced.
  • the performance of the curable, multicomponent mass can in such an arrangement by changing the mixing ratio z. B. from 3: 1 to 5: 1 can not be increased, as this would reduce the available total concentration of the peroxide further.
  • peroxide contents in a chamber of the second film bag of the film package can be realized, which can be greater than 1%, the peroxide content relative to the components in the second film bag with the two film chambers at mixing ratios of 1: 1 to 10: 1 is less than 1%.
  • a powerful injection mortar can be realized, which is free of labeling and thus without special precautions manageable.
  • the ratio of the second part of the first component to the second component is in the range of 0.5: 1 to 7: 1, preferably in the range of 2: 1 to 5: 1, and the ratio of the entire first component to the second component in the range from 1: 1 to 10: 1, preferably in the range of 2: 1 to 7: 1.
  • the abovementioned ratios of the components or the parts of the components to one another ensure the provision of different high-performance curable compositions which require no special labeling.
  • the film bag are fixed inextricably with their corresponding ends on the head part and thus captively connected thereto.
  • the entire film pack is easy in the recording of Auspressilless insert and removable from this.
  • the film bags are glued to the headboard.
  • At least one of the film bag is provided at the end facing the receiving portion partially with a weakening openable under pressure, which when pressurized with pressure z. B. by means of an extrusion piston of Auspressilless the film of the film bag in the weakening tear and this film bag can be easily opened.
  • the weakening of the film bag is advantageously carried out by means of a laser with which a part of the layers of the usually multilayer film of the film bag is removed. If the multilayer film has a barrier layer, it is advantageous for the outer layer or layers to be removed in regions up to this barrier layer.
  • the weakening extends in regions spaced from a closure means of the film bag.
  • the film bag is usually gathered at the ends and closed with a closure means, for example with a clip.
  • the weakening is advantageously provided in a region between the closure means and the outer periphery of the corresponding foil bag.
  • the weakening advantageously extends over a certain section of the film bag over a radially encircling or linear area.
  • the weakening can be continuous or discontinuous.
  • two passageways are provided in the head part for connecting a respective receiving portion with an outlet opening provided on the head part, wherein the at least one foil bag is arranged with the weakening in the receiving portion, that the center of the surface area of the weakening twisted to the corresponding passage opening is arranged.
  • the center of the surface area of the weakening is arranged rotated through an angle of -135 ° to + 135 ° to the corresponding passage opening, whereby the after opening during the Auspressvorgang exiting or exiting components substantially directly on the way into the passage opening and the outlet opening at the head part enter.
  • the rotation is in an angular range of -45 ° to + 45 ° to the corresponding passage opening.
  • foil container 11 for storing and inserting into a receptacle of a Auspressvorraum not shown here according to the prior Tecknik has a first foil bag 12 with a first component 16 and a next to the first foil bag 12 arranged second foil bag 22 with a second component 26 and a third Component 27 for the separate storage of the components 16, 26 and 27 of a three-component mass.
  • the two components 26 and 27 are provided in separate foil bag chambers of the second foil bag 22, which are formed by a common partition wall 28 arranged in the second foil bag 22.
  • the first film bag 12 is gathered at both ends 13 and 14 and each closed with a clip as a closure means 15. Also, the second film bag 22 is gathered at both ends 23 and 24 and each closed with a clip as a closure means 25.
  • the film package 11 further comprises a head portion 31 having a first receiving portion 32 for the end 13 of the first film bag 12 and a second receiving portion 36 for the end 23 of the second film bag 22, wherein the film bag 12 and 22 with their respective ends 13 and 23 are permanently fixed to the head part 31.
  • a first passage 33 is provided, which connects the receiving space formed by the first receiving portion 32 with a first outlet channel 42 of an outlet opening 41.
  • a second passage 37 is further provided which connects the receiving space formed by the second receiving portion 36 with a second outlet channel 46 of the outlet opening 41.
  • an external thread for the connection of a mixer housing not shown here is provided with a mixing element in which the discharged from the foil bags 12 and 22 components 16, 26 and 27 are mixed during the Auspressvorgang to ready-to-use mass.
  • the first film bag 12 is provided at the end 13 facing the first receiving portion 32 in regions with a pressure which can be opened under weakening 17, which extends at a distance from the closure means 15 of the film bag 12 over a surface area.
  • the first foil bag 12 is arranged in the first receiving section 32 such that the center M of the surface area of the weakening 17 is arranged directly above the first passage opening 33.
  • the ends facing away from the head part 31 and 14, respectively, of the film bags 12 and 22 are pressurized.
  • the film of the first film bag 12 ruptures in the region of the weakening 17, so that the component 16 located in the first film bag 12 during the squeezing process passes through the first passage 33 and the first exit channel 42 emerges from the outlet opening 41.
  • the closure means 25 is stripped off at the first end 23 of the second film bag 22, so that during the extrusion process, the components 26 and 27 located in the second film bag 22 pass through the second passage 37 and the second Outlet channel 46 emerge from the outlet opening 41.
  • a flow restrictor 38 is provided when entering the second passage 37.
  • FIG. 3 another arrangement of the film bag 12 and 22 is shown on the head part 31, in which the center M of the surface area of the weakening 17 on the first film bag 12 is rotated by an angle ⁇ of 90 ° to the first passage opening 33 in the first receiving portion 32.
  • FIG. 4 illustrated film bundles 51 according to the invention for storing and inserting into a receptacle of a Auspressvorraum not shown here comprises a first foil bag 52 and a next to the first foil bag 52 arranged second foil bag 62 for the separate storage of the components of a two-component mass.
  • a first part A1 of a non-marking-requiring first component is provided in the first foil bag 52 and a second part A2 of the first component is provided in a foil chamber 63 of the second foil bag 62. Furthermore, the second foil bag 62 has a second foil chamber 64, in which a second component B, different from the first component, of the multicomponent mass is provided.
  • the ratio of the second part A2 of the first component to the second component B is in the range of 0.5: 1 to 7: 1, preferably in the range of 2: 1 to 5: 1.
  • the ratio of the total first component to the second component B is in the range of 1: 1 to 10: 1, preferably in the range of 2: 1 to 7: 1.
  • the second component B has a content of peroxide which is above 1%. However, the total content of peroxide of the curable material arranged in the film bag 62 is less than 1%, with which the film bag 62 and the film container 51 are free of labeling.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Package Specialized In Special Use (AREA)
  • Packages (AREA)
  • Bag Frames (AREA)
  • Containers And Plastic Fillers For Packaging (AREA)

Abstract

The barrel (11) has a foil bag (12, 22) for components (16, 26, 27) of a multi-component mass arranged next to each other, where the components are stored separately from each other. Two supporting sections (32, 36) for ends (13, 23) of the foil bags are provided at a head part (31). The former foil bag includes one of the components (16) of the multi-component mass, and the latter foil bag includes other two components (26, 27) of the multi-component mass. The latter two components of the multi-component mass are provided in separate foil bag chambers of the latter foil bag.

Description

Die Erfindung betrifft ein Foliengebinde zum Aufbewahren von Mehrkomponentenmassen und zum Einlegen in eine Aufnahme einer Auspressvorrichtung mit einem ersten Folienbeutel und einem neben dem ersten Folienbeutel angeordneten zweiten Folienbeutel für voneinander getrennt gelagerten Komponenten einer mehrkomponentigen Masse und mit einem Kopfteil, an dem zumindest zwei Aufnahmeabschnitte für jeweils ein Ende eines Folienbeutels vorgesehen sind.The invention relates to a foil container for storing multi-component masses and for insertion into a receptacle of a squeezing device with a first foil bag and a second foil bag arranged next to the first foil bag for separately mounted components of a multi-component mass and with a head part on which at least two receiving sections for each an end of a foil bag are provided.

Mehrkomponentenmassen, wie beispielsweise Mörtel-, Schaum- und Dichtmassen, werden dem Anwender als Mehrkomponentenmassen in Kartuschen und Foliengebinden zur Verfügung gestellt. Foliengebinde haben sich als Verpackung für derartige Massen bewährt und zeichnen sich insbesondere durch ihren gegenüber Kartuschen geringen Materialanteil aus, der nach dem Ausbringen der Masse entsorgt werden muss. Zudem sind Foliengebinde einfach und kostengünstig herstellbar.Multi-component materials, such as, for example, mortar, foam and sealing compounds, are made available to the user as multicomponent materials in cartridges and film packs. Foil packs have proven themselves as packaging for such masses and are characterized in particular by their compared to cartridges low material content, which must be disposed of after dispensing the mass. In addition, foil packs are easy and inexpensive to produce.

Das Foliengebinde wird in eine Aufnahme einer Auspressvorrichtung, wie z. B. eines Dispensers, eingelegt beziehungsweise in diese eingeführt. Über einen Auspressmechanismus werden die Komponenten gleichzeitig durch eine Austrittsöffnung am Kopfteil ausgepresst, üblicherweise durch ein Mischergehäuse mit einem Mischerelement hindurchgeführt, in dem die einzelnen Komponenten zu der gewünschten Masse gemischt werden, und an einem Applikationsort ausgebracht.The film container is in a receptacle of a squeezing device, such. As a dispenser, inserted or introduced into this. Via an extrusion mechanism, the components are simultaneously squeezed out through an outlet opening on the head part, usually passed through a mixer housing with a mixer element, in which the individual components are mixed to the desired mass, and applied to an application site.

Aus der EP 0 914 069 B1 ist ein gattungsgemässes Foliengebinde mit zwei nebeneinander angeordneten Folienbeuteln bekannt, die jeweils eine Komponente einer zweikomponentigen Masse aufweisen. Diese Anordnung der Folienbeutel wird auch als Side-by-Side-Anordnung bezeichnet.From the EP 0 914 069 B1 a generic film package with two juxtaposed foil bags is known, each having a component of a two-component mass. This arrangement of the film bag is also referred to as a side-by-side arrangement.

Nachteilig an der bekannten Lösung ist, dass in diesem Foliengebinde nur zweikomponentige Massen aufbewahrt und in eine Aufnahme einer Auspressvorrichtung eingelegt werden Können. Kommen dreikomponentige Massen oder Massen mit noch mehr Komponenten zum Einsatz, sind bis anhin spezielle Auspressgeräte und Gebinde erforderlich, die kompliziert im Aufbau und somit kostenintensiv in der Fertigung sind.A disadvantage of the known solution is that stored in this film pack only two-component masses and in a recording of a squeezing Can be inserted. If three-component masses or masses with even more components are used, until now special extrusion devices and containers are required, which are complicated to build and therefore expensive to manufacture.

Aus der EP 0319 666 A1 ist eine Schlauchbeutel-Packung für pastöse Mehr- oder Ein-Komponenten-Systeme bekannt, die aus biegsamen Schlauchmaterial mit einer beliebigen Anzahl Kammern aus mindestens einem Schlauch-Mantel besteht, wobei die Kammern dicht und in sich parallel in axialer Richtung geschlossen sind.From the EP 0319 666 A1 is a tubular bag package for pasty multi-component or one-component systems is known, which consists of flexible tubing with any number of chambers of at least one hose jacket, the chambers are closed tightly and in parallel in the axial direction.

Aus der DE 29501255 U1 ist eine Folienpackung bestehend aus wenigstens einem Folienbeutel mit Bodenteil bekannt, welche eine einwandfreie und problemlose nicht zu Verschmutzungen führende Verarbeitung der eingefüllten Massen ermöglicht.From the DE 29501255 U1 is a foil package consisting of at least one foil bag with bottom part known, which allows a flawless and easy non-polluting processing of the filled masses.

Ein Folienbeutel mit einem Kopfstück, wobei der Folienbeutel mit einer Materialschwächung an dem dem Kopfstück zugewandten Ende in der Folie versehen ist, die als Sollbruchstelle dient und sich mit steigendem Innendruck des Folienbeutels öffnet, ist aus der EP 0 910 995 A2 bekannt.A film bag with a head piece, wherein the film bag is provided with a material weakening at the head end facing in the film, which serves as a predetermined breaking point and opens with increasing internal pressure of the film bag, is from the EP 0 910 995 A2 known.

Aufgabe der Erfindung ist es, ein Foliengebinde zum Aufbewahren und zum Einlegen in eine Aufnahme einer Auspressvorrichtung für Massen mit mehr als zwei Komponenten zu schaffen, die mit Auspressvorrichtungen für zweikomponentige Massen ausbringbar sind.The object of the invention is to provide a foil container for storage and for insertion into a receptacle of a squeezing device for masses with more than two components, which can be brought out with squeezing devices for two-component masses.

Die Aufgabe ist durch die Merkmale des unabhängigen Anspruchs gelöst. Vorteilhafte Weiterbildungen sind in den Unteransprüchen dargelegt.The object is solved by the features of the independent claim. Advantageous developments are set forth in the subclaims.

Gemäss der Erfindung enthält der erste Folienbeutel zumindest eine Komponente der mehrkomponentigen Masse und der zweite Folienbeutel zumindest zwei Komponenten der mehrkomponentigen Masse, wobei ein ersten Teil (A1) des ersten Komponente in dem ersten Folienbeutel und ein zweiten Teil (A2) der ersten Komponente sowie eine zweite von der ersten Komponente unterschiedliche Komponente in separaten Folienkammern des zweiten Folienbeutels vorgeschen sind.According to the invention, the first film bag contains at least one component of the multicomponent mass and the second film bag at least two components of the multicomponent mass, wherein a first part (A1) of the first component in the first film bag and a second part (A2) of the first component and a second component different from the first component are proposed in separate foil chambers of the second foil pouch.

Die Abmessungen des Foliengebindes entsprechen im Wesentlichen den Abmessungen eines Foliengebindes für zweikomponentige Massen, womit das erfindungsgemässe Foliengebinde mit herkömmlichen, bereits auf dem Markt befindlichen Auspressgeräten ausbringbar ist. Je nach Art und Erfordernisse der im Foliengebinde eingelagerten Masse können die Komponenten im entsprechenden Verhältnis zueinander im Foliengebinde vorgesehen werden. Dabei können im Foliengebinde auch von mehr als drei Komponenten aufbewahrt und nach dem Einlegen in eine Aufnahme einer Auspressvorrichtung mit dieser ausgebracht werden.The dimensions of the film bundle essentially correspond to the dimensions of a film bundle for two-component masses, with which the film bundle according to the invention can be dispensed with conventional dispensing devices already on the market. Depending on the nature and requirements of the mass stored in the film container, the components can be provided in the corresponding ratio to one another in the film container. It can also be stored in the film package of more than three components and deployed after insertion into a recording of a squeezing with this.

Vorzugsweise sind die zumindest zwei Komponenten der mehrkomponentigen Masse in separaten Folienbeutelkammern des zweiten Folienbeutels vorgesehen, womit eine Reaktion der zumindest zwei Komponenten im zweiten Folienbeutel verhindert ist. Zur Ausbildung der separaten Folienbeutelkammern des zweiten Folienbeutels wird vorteilhaft eine Trennwand im zweiten Folienbeutel vorgesehen, welche einen direkten Kontakt der zumindest zwei Komponenten während der Lagerung im zweiten Folienbeutel und somit eine Reaktion in Kontaktbereich miteinander verhindert.Preferably, the at least two components of the multicomponent mass are provided in separate foil bag chambers of the second foil bag, whereby a reaction of the at least two components in the second foil bag is prevented. To form the separate foil bag chambers of the second foil bag, a dividing wall is advantageously provided in the second foil bag, which prevents direct contact of the at least two components during storage in the second foil bag and thus a reaction in the contact area with one another.

Erfindungsgemäß sind ein erster Teil einer ersten Komponente der mehrkomponentigen Masse in einem ersten Folienbeutel und ein zweiter Teil der ersten Komponente sowie eine zweite von der ersten Komponente unterschiedliche Komponente der mehrkomponentigen Masse in separaten Folienkammern des zweiten Folienbeutels vorgesehen. Die grössere Komponente der mehrkomponentigen Masse wird in zwei gleiche oder ungleiche Teile aufgeteilt, wodurch verschiedene Mischungsverhältnisse der Komponenten bei konstanter Aussenabmessung des Foliengebindes möglich sind. Beispielsweise lässt sich so bei einem in den Aussenabmessungen entsprechendem herkömmlichen 3:1-Gebinde ein davon abweichendes Mischungsverhältnis von 5:1 realisieren.According to the invention, a first part of a first component of the multicomponent mass in a first film bag and a second part of the first component and a second component of the multicomponent mass different from the first component are provided in separate film chambers of the second film bag. The larger component of the multicomponent mass is divided into two equal or dissimilar parts, whereby different mixing ratios of the components are possible with a constant outer dimension of the film package. For example, this can be done at one In the external dimensions corresponding conventional 3: 1 container realize a different mixing ratio of 5: 1.

Des Weiteren lassen sich mit dieser Ausgestaltung des Folienbeutels kennzeichnungsfreie Injektionsmörtel realisieren, die eine hohe Leistungsfähigkeit aufweisen, jedoch nicht besonders gekennzeichnet werden müssen. Ob ein Foliengebinde gekennzeichnet werden muss, hängt von dem Gehalt an kennzeichnungspflichtigen Stoffen, beispielsweise vom Gehalt an Peroxid und/oder sensibilisierenden Methacrylaten ab. Peroxide (z. B. Perester, Perketale, Hydro- oder Diacylperoxide, insbesondere Butylperbenzoat, Cumylhydroperoxid, Dibenzoylperoxid oder Lauroylperoxid) werden oftmals als Härter z. B. für Mörtel zur chemischen Verankerung von Befestigungselementen eingesetzt. Wird der Peroxid-Gehalt bei einer herkömmlichen Side-by-Side-Anordnung der Folienbeutel unter die kennzeichnungsfreie Grenze von 1% reduziert, verringert sich die Leistungsfähigkeit der aushärtbaren, mehrkomponentigen Masse massgeblich. Die Leistungsfähigkeit der aushärtbaren, mehrkomponentigen Masse kann bei solch einer Anordnung durch Änderung des Mischungsverhältnisses z. B. von 3:1 auf 5:1 nicht gesteigert werden, da dadurch die verfügbare Gesamtkonzentration des Peroxids weiter abgesenkt werden würde.Furthermore, with this embodiment of the film bag, it is possible to realize marking-free injection mortars which have a high performance but do not need to be specially marked. Whether a film container must be labeled depends on the content of substances subject to labeling, for example the content of peroxide and / or sensitizing methacrylates. Peroxides (for example peresters, perketals, hydro- or diacyl peroxides, in particular butyl perbenzoate, cumyl hydroperoxide, dibenzoyl peroxide or lauroyl peroxide) are often used as hardeners, for example. B. used for mortar for the chemical anchoring of fasteners. If the peroxide content is reduced below the label-free limit of 1% in a conventional side-by-side arrangement of the film pouches, the performance of the curable, multicomponent mass is significantly reduced. The performance of the curable, multicomponent mass can in such an arrangement by changing the mixing ratio z. B. from 3: 1 to 5: 1 can not be increased, as this would reduce the available total concentration of the peroxide further.

Durch die Aufteilung der ersten Komponente in zwei, in separaten Folienbeuteln gelagerte Teile lassen sich Peroxid-Gehalte in einer Kammer des zweiten Folienbeutels des Foliengebindes realisieren, die grösser als 1 % sein können, wobei der Peroxid-Gehalt in Bezug auf die Komponenten im zweiten Folienbeutel mit den beiden Folienkammern bei Mischungsverhältnissen von 1:1 bis 10:1 unter 1 % zu liegen kommt. Somit ist mit dieser Ausführungsform der Erfindung ein leistungsfähiger Injektionsmörtel realisierbar, der kennzeichnungsfrei und somit ohne besondere Vorkehrungen handhabbar ist.By dividing the first component into two parts mounted in separate film bags, peroxide contents in a chamber of the second film bag of the film package can be realized, which can be greater than 1%, the peroxide content relative to the components in the second film bag with the two film chambers at mixing ratios of 1: 1 to 10: 1 is less than 1%. Thus, with this embodiment of the invention, a powerful injection mortar can be realized, which is free of labeling and thus without special precautions manageable.

Vorzugsweise liegt das Verhältnis des zweiten Teils der ersten Komponente zu der zweiten Komponente im Bereich von 0.5:1 bis 7:1, vorzugsweise im Bereich von 2:1 bis 5:1, und das Verhältnis der gesamten ersten Komponente zu der zweiten Komponente im Bereich von 1:1 bis 10:1, vorzugsweise im Bereich von 2:1 bis 7:1. Die vorgenannten Verhältnisse der Komponenten beziehungsweise der Teile der Komponenten zueinander gewährleisten die zur Verfügungstellung von unterschiedlichen leistungsfähigen aushärtbaren Massen, die keine besondere Kennzeichnung bedürfen.Preferably, the ratio of the second part of the first component to the second component is in the range of 0.5: 1 to 7: 1, preferably in the range of 2: 1 to 5: 1, and the ratio of the entire first component to the second component in the range from 1: 1 to 10: 1, preferably in the range of 2: 1 to 7: 1. The abovementioned ratios of the components or the parts of the components to one another ensure the provision of different high-performance curable compositions which require no special labeling.

Bevorzugt sind die Folienbeutel mit ihren entsprechenden Enden an dem Kopfteil unlösbar festgelegt und somit unverlierbar mit diesem verbunden. Damit ist das gesamte Foliengebinde einfach in die Aufnahme des Auspressgerätes einleg- und aus dieser entfernbar. Vorteilhaft sind die Folienbeutel an dem Kopfteil festgeklebt.Preferably, the film bag are fixed inextricably with their corresponding ends on the head part and thus captively connected thereto. Thus, the entire film pack is easy in the recording of Auspressgerätes insert and removable from this. Advantageously, the film bags are glued to the headboard.

Vorzugsweise ist zumindest einer der Folienbeutel an dem dem Aufnahmeabschnitt zugewandten Ende bereichsweise mit einer unter Druck öffnenbaren Schwächung versehen, womit bei Beaufschlagung mit Druck z. B. mittels eines Auspresskolbens des Auspressgerätes die Folie des Folienbeutels im Bereich der Schwächung aufreisst und sich dieser Folienbeutel einfach öffnen lässt. Die Schwächung des Folienbeutels erfolgt vorteilhaft mittels eines Lasers, mit dem ein Teil der Schichten der üblicherweise mehrschichtigen Folie des Folienbeutels entfernt wird. Weist die mehrschichtige Folie eine Sperrschicht auf, so wird vorteilhaft die aussenliegende Schicht oder Schichten bereichsweise bis zu dieser Sperrschicht entfernt.Preferably, at least one of the film bag is provided at the end facing the receiving portion partially with a weakening openable under pressure, which when pressurized with pressure z. B. by means of an extrusion piston of Auspressgerätes the film of the film bag in the weakening tear and this film bag can be easily opened. The weakening of the film bag is advantageously carried out by means of a laser with which a part of the layers of the usually multilayer film of the film bag is removed. If the multilayer film has a barrier layer, it is advantageous for the outer layer or layers to be removed in regions up to this barrier layer.

Bevorzugt erstreckt sich die Schwächung bereichsweise beabstandet zu einem Verschlussmittel des Folienbeutels. Der Folienbeutel ist üblicherweise an den Enden gerafft und mit einem Verschlussmittel, beispielsweise mit einem Clip verschlossen. Die Schwächung ist vorteilhaft in einem Bereich zwischen dem Verschlussmittel und dem äusseren Umfang des entsprechenden Folienbeutels vorgesehen. Die Schwächung erstreckt sich vorteilhaft über einen gewissen Abschnitt des Folienbeutels über einen radial umlaufenden oder linearen Flächenbereich. Die Schwächung kann kontinuierlich oder diskontinuierlich ausgebildet sein.Preferably, the weakening extends in regions spaced from a closure means of the film bag. The film bag is usually gathered at the ends and closed with a closure means, for example with a clip. The weakening is advantageously provided in a region between the closure means and the outer periphery of the corresponding foil bag. The weakening advantageously extends over a certain section of the film bag over a radially encircling or linear area. The weakening can be continuous or discontinuous.

Vorzugsweise sind zwei Durchtrittskanäle im Kopfteil zum Verbinden jeweils eines Aufnahmeabschnitts mit einer am Kopfteil vorgesehenen Austrittsöffnung vorgesehen, wobei der zumindest eine Folienbeutel mit der Schwächung derart im Aufnahmeabschnitt angeordnet ist, dass der Mittelpunkt des Flächenbereichs der Schwächung verdreht zur entsprechenden Durchtrittsöffnung angeordnet ist.Preferably, two passageways are provided in the head part for connecting a respective receiving portion with an outlet opening provided on the head part, wherein the at least one foil bag is arranged with the weakening in the receiving portion, that the center of the surface area of the weakening twisted to the corresponding passage opening is arranged.

Bevorzugt ist der Mittelpunkt des Flächenbereichs der Schwächung um einen Winkel von -135° bis +135° verdreht zur entsprechenden Durchtrittsöffnung angeordnet, womit die nach dem Öffnen während dem Auspressvorgang austretende beziehungsweise austretenden Komponenten im Wesentlichen auf direktem Weg in die Durchtrittsöffnung und die Austrittsöffnung am Kopfteil eintreten. Besonders vorteilhaft liegt die Verdrehung in einem Winkelbereich von -45° bis +45° zur entsprechenden Durchtrittsöffnung.Preferably, the center of the surface area of the weakening is arranged rotated through an angle of -135 ° to + 135 ° to the corresponding passage opening, whereby the after opening during the Auspressvorgang exiting or exiting components substantially directly on the way into the passage opening and the outlet opening at the head part enter. Particularly advantageously, the rotation is in an angular range of -45 ° to + 45 ° to the corresponding passage opening.

Die Erfindung wird nachstehend anhand von Ausführungsbeispielen näher erläutert. Es zeigen:

Fig. 1
Ein Foliengebinde in einer Seitenansicht mit geschnittenem Kopfteil;
Fig. 2
ein erstes Beispiel einer Folienbeutelanordnung in Aufsicht auf das Kopfteil;
Fig. 3
ein zweites Beispiel einer Folienbeutelanordnung in Aufsicht auf das Kopfteil;
Fig. 4
ein erfindungsgemäßes Ausführungsbeispiel einer Folienbeutelanordung im Querschnitt durch die Folienbeutel.
The invention will be explained in more detail below with reference to embodiments. Show it:
Fig. 1
A film bundle in a side view with cut headboard;
Fig. 2
a first example of a foil bag assembly in a plan view of the head part;
Fig. 3
a second example of a foil bag assembly in a plan view of the head part;
Fig. 4
an inventive embodiment of a Folienbeutelanordung in cross section through the film bag.

Grundsätzlich sind in den Figuren gleiche Teile mit den gleichen Bezugszeichen versehen.Basically, the same parts are provided with the same reference numerals in the figures.

Das in der Figur 1 dargestellte Foliengebinde 11 zum Aufbewahren und zum Einlegen in eine Aufnahme einer hier nicht dargestellten Auspressvorrichtung nach dem Stand der Tecknik weist einen ersten Folienbeutel 12 mit einer ersten Komponente 16 und einen neben dem ersten Folienbeutel 12 angeordneten zweiten Folienbeutel 22 mit einer zweiten Komponente 26 und einer dritten Komponente 27 zur voneinander getrennten Lagerung der Komponenten 16, 26 und 27 einer dreikomponentigen Masse auf. Die zwei Komponenten 26 und 27 sind in separaten Folienbeutelkammern des zweiten Folienbeutels 22 vorgesehen, welche durch eine gemeinsame, im zweiten Folienbeutel 22 angeordnete Trennwand 28 gebildet sind.That in the FIG. 1 shown foil container 11 for storing and inserting into a receptacle of a Auspressvorrichtung not shown here according to the prior Tecknik has a first foil bag 12 with a first component 16 and a next to the first foil bag 12 arranged second foil bag 22 with a second component 26 and a third Component 27 for the separate storage of the components 16, 26 and 27 of a three-component mass. The two components 26 and 27 are provided in separate foil bag chambers of the second foil bag 22, which are formed by a common partition wall 28 arranged in the second foil bag 22.

Der erste Folienbeutel 12 ist an beiden Enden 13 und 14 gerafft und jeweils mit einem Clip als Verschlussmittel 15 verschlossen. Auch der zweite Folienbeutel 22 ist an beiden Enden 23 und 24 gerafft und jeweils mit einem Clip als Verschlussmittel 25 verschlossen.The first film bag 12 is gathered at both ends 13 and 14 and each closed with a clip as a closure means 15. Also, the second film bag 22 is gathered at both ends 23 and 24 and each closed with a clip as a closure means 25.

Das Foliengebinde 11 weist weiter ein Kopfteil 31 mit einem ersten Aufnahmeabschnitt 32 für das Ende 13 des ersten Folienbeutels 12 und mit einem zweiten Aufnahmeabschnitt 36 für das Ende 23 des zweiten Folienbeutels 22 auf, wobei die Folienbeutel 12 und 22 mit ihren entsprechenden Enden 13 bzw. 23 an dem Kopfteil 31 unlösbar festgelegt sind. Im Kopfteil 31 ist ein erster Durchtrittskanal 33 vorgesehen, der den vom ersten Aufnahmeabschnitt 32 gebildeten Aufnahmeraum mit einem ersten Austrittskanal 42 einer Austrittsöffnung 41 verbindet. Im Kopfteil 31 ist weiter ein zweiter Durchtrittskanal 37 vorgesehen, der den vom zweiten Aufnahmeabschnitt 36 gebildeten Aufnahmeraum mit einem zweiten Austrittskanal 46 der Austrittsöffnung 41 verbindet. An der Austrittsöffnung 41 ist ein Aussengewinde für den Anschluss eines hier nicht dargestellten Mischergehäuses mit einem Mischelement vorgesehen, in welchem die aus den Folienbeuteln 12 und 22 ausgebrachten Komponenten 16, 26 und 27 während dem Auspressvorgang zur gebrauchsfertigen Masse gemischt werden.The film package 11 further comprises a head portion 31 having a first receiving portion 32 for the end 13 of the first film bag 12 and a second receiving portion 36 for the end 23 of the second film bag 22, wherein the film bag 12 and 22 with their respective ends 13 and 23 are permanently fixed to the head part 31. In the head part 31, a first passage 33 is provided, which connects the receiving space formed by the first receiving portion 32 with a first outlet channel 42 of an outlet opening 41. In the head part 31, a second passage 37 is further provided which connects the receiving space formed by the second receiving portion 36 with a second outlet channel 46 of the outlet opening 41. At the outlet opening 41 an external thread for the connection of a mixer housing, not shown here is provided with a mixing element in which the discharged from the foil bags 12 and 22 components 16, 26 and 27 are mixed during the Auspressvorgang to ready-to-use mass.

Der erste Folienbeutel 12 ist an dem dem ersten Aufnahmeabschnitt 32 zugewandten Ende 13 bereichsweise mit einer unter Druck öffnenbaren Schwächung 17 versehen, welche sich beabstandet zu dem Verschlussmittel 15 des Folienbeutels 12 über einen Flächenbereich erstreckt. Der erste Folienbeutel 12 ist derart im ersten Aufnahmeabschnitt 32 angeordnet, dass der Mittelpunkt M des Flächenbereichs der Schwächung 17 direkt über der ersten Durchtrittsöffnung 33 angeordnet.The first film bag 12 is provided at the end 13 facing the first receiving portion 32 in regions with a pressure which can be opened under weakening 17, which extends at a distance from the closure means 15 of the film bag 12 over a surface area. The first foil bag 12 is arranged in the first receiving section 32 such that the center M of the surface area of the weakening 17 is arranged directly above the first passage opening 33.

Mittels des Auspressgeräts werden die dem Kopfteil 31 abgewandten Enden 14 bzw. 24 der Folienbeutel 12 und 22 mit Druck beaufschlagt. Wenn der Innendruck im ersten Folienbeutel 12 ein bestimmtes Niveau erreicht hat, reisst die Folie des ersten Folienbeutels 12 im Bereich der Schwächung 17 auf, so dass beim Auspressvorgang die sich im ersten Folienbeutel 12 befindliche Komponente 16 durch den ersten Durchtrittskanal 33 und den ersten Austrittskanal 42 aus der Austrittsöffnung 41 austritt. Wenn der Innendruck im zweiten Folienbeutel 22 ein bestimmtes Niveau erreicht hat, wird das Verschlussmittel 25 am ersten Ende 23 des zweiten Folienbeutels 22 abgestreift, so dass beim Auspressvorgang die sich im zweiten Folienbeutel 22 befindlichen Komponenten 26 und 27 durch den zweiten Durchtrittskanal 37 und den zweiten Austrittskanal 46 aus der Austrittsöffnung 41 austreten. Um das Abstreifen des Verschlussmittels 25 zu vereinfachen sowie den Ausfluss der beiden Komponenten 26 und 27 beim Auspressvorgang im richtigen Verhältnis zueinander sicherzustellen, ist beim Eintritt in den zweiten Durchtrittskanal 37 eine Flussdrossel 38 vorgesehen.By means of the ejection device, the ends facing away from the head part 31 and 14, respectively, of the film bags 12 and 22 are pressurized. When the internal pressure in the first film bag 12 has reached a certain level, the film of the first film bag 12 ruptures in the region of the weakening 17, so that the component 16 located in the first film bag 12 during the squeezing process passes through the first passage 33 and the first exit channel 42 emerges from the outlet opening 41. When the internal pressure in the second film bag 22 has reached a certain level, the closure means 25 is stripped off at the first end 23 of the second film bag 22, so that during the extrusion process, the components 26 and 27 located in the second film bag 22 pass through the second passage 37 and the second Outlet channel 46 emerge from the outlet opening 41. In order to simplify the stripping of the closure means 25 and to ensure the outflow of the two components 26 and 27 during the pressing process in the correct ratio to each other, a flow restrictor 38 is provided when entering the second passage 37.

In der Figur 3 ist eine andere Anordnung der Folienbeutel 12 und 22 am Kopfteil 31 dargestellt, bei welcher der Mittelpunkt M des Flächenbereichs der Schwächung 17 am ersten Folienbeutel 12 um einen Winkel α von 90° verdreht zur ersten Durchtrittsöffnung 33 im ersten Aufnahmeabschnitt 32 angeordnet ist.In the FIG. 3 another arrangement of the film bag 12 and 22 is shown on the head part 31, in which the center M of the surface area of the weakening 17 on the first film bag 12 is rotated by an angle α of 90 ° to the first passage opening 33 in the first receiving portion 32.

Das in der Figur 4 dargestellte erfindungsgemäße Foliengebinde 51 zum Aufbewahren und zum Einlegen in eine Aufnahme einer hier nicht dargestellten Auspressvorrichtung weist einen ersten Folienbeutel 52 und einen neben dem ersten Folienbeutel 52 angeordneten zweiten Folienbeutel 62 zur voneinander getrennten Lagerung der Komponenten einer zweikomponentigen Masse auf.That in the FIG. 4 illustrated film bundles 51 according to the invention for storing and inserting into a receptacle of a Auspressvorrichtung not shown here comprises a first foil bag 52 and a next to the first foil bag 52 arranged second foil bag 62 for the separate storage of the components of a two-component mass.

Ein erster Teil A1 einer nicht-kennzeichnungspflichtigen, ersten Komponente ist in dem ersten Folienbeutel 52 und ein zweiter Teil A2 der ersten Komponente ist in einer Folienkammer 63 des zweiten Folienbeutels 62 vorgesehen. Weiter weist der zweite Folienbeutel 62 eine zweite Folienkammer 64 auf, in der eine zweite von der ersten Komponente unterschiedliche Komponente B der mehrkomponentigen Masse vorgesehen ist. Das Verhältnis des zweiten Teils A2 der ersten Komponente zu der zweiten Komponente B liegt im Bereich von 0.5:1 bis 7:1, vorzugsweise im Bereich von 2:1 bis 5:1. Das Verhältnis der gesamten ersten Komponente zu der zweiten Komponente B liegt im Bereich von 1:1 bis 10:1, vorzugsweise im Bereich von 2:1 bis 7:1.A first part A1 of a non-marking-requiring first component is provided in the first foil bag 52 and a second part A2 of the first component is provided in a foil chamber 63 of the second foil bag 62. Furthermore, the second foil bag 62 has a second foil chamber 64, in which a second component B, different from the first component, of the multicomponent mass is provided. The ratio of the second part A2 of the first component to the second component B is in the range of 0.5: 1 to 7: 1, preferably in the range of 2: 1 to 5: 1. The ratio of the total first component to the second component B is in the range of 1: 1 to 10: 1, preferably in the range of 2: 1 to 7: 1.

Die zweite Komponente B weist einen Gehalt von Peroxid auf, der über 1 % liegt. Der Gesamtgehalt von Peroxid der in dem Folienbeutel 62 angeordneten aushärtbaren Masse liegt jedoch unter 1%, womit der Folienbeutel 62 als auch das Foliengebinde 51 kennzeichnungsfrei sind.The second component B has a content of peroxide which is above 1%. However, the total content of peroxide of the curable material arranged in the film bag 62 is less than 1%, with which the film bag 62 and the film container 51 are free of labeling.

Claims (8)

  1. Foil container for storage of multi component masses and for insertion into the reception of an extruder device, having a first foil bag (52), and, arranged next to the first foil bag (52), a second foil bag (62), for accommodating components (A1, A2, B) of a multi component mass separately from each other, and having a head member (31) on which are provided at least two receiving sections (32, 36), each for one end (13, 23) of a foil bag, wherein the first foil bag (52) contains at least one component (A1) of the multi component mass, and the second foil bag (62) contains at least two components (A2, B) of the multi component mass provided in separate foil bag chambers of the second foil bag (62), characterised in that a first part (A1) of a first component of the multi component mass is provided in the first foil bag (52), and,
    a second part (A2) of the first component and additionally a second component (B) of the multi component mass different from the first component are provided in separate foil chambers (63, 64) of the second foil bag (62).
  2. Foil container according to claim 1, characterised in that the ratio of the second part (A2) of the first component to the second component (B) lies within the region of 0.5:1 to 7:1 preferably within the region of 2:1 to 5: 1, and
    the ratio of the entirety of the first component to the second component (B) lies within the region of 1:1 to 10:1 preferably within the region 2:1 to 7:1.
  3. Foil container according to claim 1 or 2, characterised in that the foil bags are securely, non detachably, fixed by their respective ends (13, 23) to the head member (31).
  4. Foil container according to one of claims 1 to 3 , characterised in that at least one of the foil bags is provided, in at least one region, with a weakening (17) at the end (13) proximate to the receiving section (32), the weakening (17) being openable under pressure.
  5. Foil container according to claim 4, characterised in that the weakening (17) extends to closure means (15) of the foil bag, at a spacing in at least one region.
  6. Foil container according to claim 4 or 5, characterised in that two through channels (33, 37) are provided in the head member (31) for connecting the respective receiving sections (32, 36) with a discharge opening (41) provided on the head member (31), wherein the at least one foil bag with the weakening (17) is so arranged in the receiving section (32) that the centre (M) of the surface region of the weakening (17) is arranged rotated with respect to the corresponding through opening (33).
  7. Foil container according to claim 6, characterised in that the centre (M) of the surface region of the weakening (17) is arranged rotated by an angle (alpha) of -135° to + 135° with respect to the corresponding through opening (33).
  8. Foil container according to claim 7, characterised in that the centre (M) of the surface region of the weakening (17) is arranged rotated by an angle (alpha) of -45° to + 45° with respect to the corresponding through opening (33).
EP09164270A 2008-07-25 2009-07-01 Film package Active EP2147870B1 (en)

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PL09164270T PL2147870T3 (en) 2008-07-25 2009-07-01 Film package

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DE (1) DE102008040738A1 (en)
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Also Published As

Publication number Publication date
US8313006B2 (en) 2012-11-20
EP2322449B1 (en) 2012-06-20
ES2378128T3 (en) 2012-04-09
ATE541797T1 (en) 2012-02-15
PL2147870T3 (en) 2012-06-29
US20100027918A1 (en) 2010-02-04
EP2147870A1 (en) 2010-01-27
DE102008040738A1 (en) 2010-01-28
EP2322449A1 (en) 2011-05-18

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