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EP1731593A3 - Fluorinated greases having a low torque at low temperatures - Google Patents

Fluorinated greases having a low torque at low temperatures Download PDF

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Publication number
EP1731593A3
EP1731593A3 EP06010616A EP06010616A EP1731593A3 EP 1731593 A3 EP1731593 A3 EP 1731593A3 EP 06010616 A EP06010616 A EP 06010616A EP 06010616 A EP06010616 A EP 06010616A EP 1731593 A3 EP1731593 A3 EP 1731593A3
Authority
EP
European Patent Office
Prior art keywords
weight
low
integer
fluorinated greases
torque
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06010616A
Other languages
German (de)
French (fr)
Other versions
EP1731593A2 (en
Inventor
Patrizia Maccone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Specialty Polymers Italy SpA
Original Assignee
Solvay Solexis SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Solexis SpA filed Critical Solvay Solexis SpA
Publication of EP1731593A2 publication Critical patent/EP1731593A2/en
Publication of EP1731593A3 publication Critical patent/EP1731593A3/en
Withdrawn legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/38Lubricating compositions characterised by the base-material being a macromolecular compound containing halogen
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/02Mixtures of base-materials and thickeners
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/061Carbides; Hydrides; Nitrides
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • C10M2201/1026Silicates used as thickening agents
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
    • C10M2201/1056Silica used as thickening agents
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2213/00Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
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    • C10M2213/04Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
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    • C10M2213/00Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06Perfluoro polymers
    • C10M2213/062Polytetrafluoroethylene [PTFE]
    • C10M2213/0626Polytetrafluoroethylene [PTFE] used as thickening agents
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10N2010/12Groups 6 or 16
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    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2040/30Refrigerators lubricants or compressors lubricants

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Fluorinated greases comprising:
(A) from 1% to 50% by weight of a thickener;
(B) from 99% to 50% by weight of a mixture of:
(B1) from 0,1 to 100% by weight of a compound of structure:

         X1-O (CF2O)n (CF2CF2O)m (CF2CF2CF2O)p (CF2CF2CF2CF2O)q-X2     (I)

wherein:
X1, X2 have formula -(CF2)zCF3 wherein z is an integer between 0 and 3; n is an integer between 1 and 200; m is an integer between 0 and 200; p, q are integers between 0 and 10; with the proviso that:
the (p+q)/(p+q+m+n) ≤0.05; m/n ≤0.7; the number average molecular weight of (I) is between 1,000 and 10,000; the kinematic viscosity at 40°C is lower than 20 cSt; and

(B2) from 99.9% to 0% by weight of a perfluoropolyether oil having a kinematic viscosity at 40°C higher than 15 cSt and comprising repeating units of the type (CFXO) wherein X is F or CF3 ; -CF2CF2O-, -C3F6O, -CF(CF3)CF2O-, -CF2CF(CF3)O-, statistically distributed along the chain.
EP06010616A 2005-06-10 2006-05-23 Fluorinated greases having a low torque at low temperatures Withdrawn EP1731593A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT001080A ITMI20051080A1 (en) 2005-06-10 2005-06-10 FLUORURED GREASES HAVING LOW MOMENT TORCENT AT LOW TEMPERATURES

Publications (2)

Publication Number Publication Date
EP1731593A2 EP1731593A2 (en) 2006-12-13
EP1731593A3 true EP1731593A3 (en) 2007-08-29

Family

ID=36955255

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06010616A Withdrawn EP1731593A3 (en) 2005-06-10 2006-05-23 Fluorinated greases having a low torque at low temperatures

Country Status (4)

Country Link
US (1) US20060281641A1 (en)
EP (1) EP1731593A3 (en)
JP (1) JP2006348291A (en)
IT (1) ITMI20051080A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4955321B2 (en) * 2006-07-05 2012-06-20 協同油脂株式会社 Grease composition and bearing
DE112009000197B4 (en) 2008-02-01 2015-07-16 Nok Klueber Co. Ltd. Use of a fluorine-containing diamide compound
DE102011104507A1 (en) * 2011-06-17 2012-12-20 KLüBER LUBRICATION MüNCHEN KG Thickener-free grease
CN103031180B (en) * 2011-09-30 2014-09-03 华樱 Grease
CN103525513A (en) * 2013-10-23 2014-01-22 中国石油化工股份有限公司 High-temperature lubricating grease composition and preparation method
JP6646379B2 (en) 2015-08-10 2020-02-14 Ntn株式会社 Grease composition and grease-filled rolling bearing

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5202501A (en) * 1985-11-08 1993-04-13 Exfluor Research Corporation Perfluoropolyethers
EP1327673A1 (en) * 2002-01-15 2003-07-16 Minebea Co., Ltd. Low torque grease composition
EP1520906A1 (en) * 2003-10-03 2005-04-06 Solvay Solexis S.p.A. Lubricating greases

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Publication number Priority date Publication date Assignee Title
US3242218A (en) * 1961-03-29 1966-03-22 Du Pont Process for preparing fluorocarbon polyethers
DE1249247B (en) * 1961-04-25 1967-09-07 E. I. Du Pont De Nemours And Company, Wilmington, Del. (V. St. A.) Process for the preparation of perfluoroolefin polyethers
US3715378A (en) * 1967-02-09 1973-02-06 Montedison Spa Fluorinated peroxy polyether copolymers and method for preparing them from tetrafluoroethylene
US3665041A (en) * 1967-04-04 1972-05-23 Montedison Spa Perfluorinated polyethers and process for their preparation
US4523039A (en) * 1980-04-11 1985-06-11 The University Of Texas Method for forming perfluorocarbon ethers
IT1204903B (en) * 1986-06-26 1989-03-10 Ausimont Spa POLYMERIZATION PROCESS IN WATER DISPERSION OF FLORATED MONOMERS
US5032302A (en) * 1986-08-06 1991-07-16 Exfluor Research Corporation Perfluoropolyether solid fillers for lubricants
IT1228655B (en) * 1989-02-09 1991-06-27 Ausimont Srl PERFLUOROPOLIETERI HAVING ANTIRUST PROPERTIES USEFUL AS COMPONENTS OR ADDITIVES OF LUBRICATING OILS AND FATS.
IT1290428B1 (en) * 1997-03-21 1998-12-03 Ausimont Spa FLUORINATED FATS
ITMI981519A1 (en) * 1998-07-02 2000-01-02 Ausimont Spa POLYMERIZATION PROCESS OF TFE
WO2000018210A2 (en) * 1998-09-29 2000-04-06 Loctite Corporation Fluorinated oil-containing compositions
JP5042401B2 (en) * 1998-10-14 2012-10-03 日本精工株式会社 Rolling bearing for automobile fuel injection control
IT1317847B1 (en) * 2000-02-22 2003-07-15 Ausimont Spa PROCESS FOR THE PREPARATION OF WATER DISPERSIONS OF FLUOROPOLYMERS.
US6753301B2 (en) * 2000-07-19 2004-06-22 E. I. Du Pont De Nemours And Company Thermally stable perfluoropolyethers and processes therefor and therewith
ITMI20020281A1 (en) * 2002-02-14 2003-08-14 Ausimont Spa CYCLIC PHOSFAZENIC COMPOUNDS AND THEIR USE AS ADDITIVES OF PERFLUOROPOLYEREAL OILS
ITMI20020804A1 (en) * 2002-04-17 2003-10-17 Ausimont Spa ADDITIVES FOR PERFLUOROPOLYEREAL OILS
ITMI20030992A1 (en) * 2003-05-20 2004-11-21 Solvay Solexis Spa PERFLUOROPOLITEREI ADDITIVES.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5202501A (en) * 1985-11-08 1993-04-13 Exfluor Research Corporation Perfluoropolyethers
EP1327673A1 (en) * 2002-01-15 2003-07-16 Minebea Co., Ltd. Low torque grease composition
EP1520906A1 (en) * 2003-10-03 2005-04-06 Solvay Solexis S.p.A. Lubricating greases

Also Published As

Publication number Publication date
EP1731593A2 (en) 2006-12-13
US20060281641A1 (en) 2006-12-14
ITMI20051080A1 (en) 2006-12-11
JP2006348291A (en) 2006-12-28

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