EP1508007A1 - Freezer comprising a defrost function and operating method therefor - Google Patents
Freezer comprising a defrost function and operating method thereforInfo
- Publication number
- EP1508007A1 EP1508007A1 EP03752736A EP03752736A EP1508007A1 EP 1508007 A1 EP1508007 A1 EP 1508007A1 EP 03752736 A EP03752736 A EP 03752736A EP 03752736 A EP03752736 A EP 03752736A EP 1508007 A1 EP1508007 A1 EP 1508007A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- freezer
- time interval
- heating device
- timer
- operating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/002—Defroster control
- F25D21/008—Defroster control by timer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D17/00—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
- F25D17/04—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
- F25D17/06—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation
- F25D17/062—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation in household refrigerators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/06—Removing frost
- F25D21/08—Removing frost by electric heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2700/00—Means for sensing or measuring; Sensors therefor
- F25D2700/02—Sensors detecting door opening
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2700/00—Means for sensing or measuring; Sensors therefor
- F25D2700/10—Sensors measuring the temperature of the evaporator
Definitions
- the present invention relates to a freezer with a cooling surface, on which an ice layer can form during the operation of the freezer, and a heating device for heating the cooling surface and thereby defrosting such an ice layer.
- Conventional freezers of this type also known as frost-free devices, have a control device for controlling the operation of the heating device, which automatically puts the heating device into operation when a running time of the device or a compressor of the device, recorded with the aid of a timer, is one exceeds the predetermined limit. In this way it is ensured that the cooling surface is defrosted from time to time even without the active intervention of a user, so that no layer of ice can form on it that significantly impairs the energy efficiency of the device.
- a problem with this technology is that it is unable to take into account whether refrigerated goods may have been freshly stored in the freezer just before the defrosting process is initiated. If this is the case, such refrigerated goods should be frozen as quickly as possible, which requires a high cooling capacity.
- automatic defrosting of the cooling surface at such a time means that freezing takes a long time, and under unfavorable circumstances it could even result in the refrigerated goods already stored in the freezer being heated so much by the newly stored goods, that this stock is thawing.
- Another disadvantage of this technique is that it is associated with relatively high energy costs because the freezer's increased power requirement associated with defrosting can occur at any time of the day.
- the object of the present invention is to provide a freezer and an operating method therefor, which ensure that frozen goods are quickly frozen at any time. ten and which also make it possible to minimize the energy costs associated with the operation of such a device.
- the object is achieved on the one hand by a freezer with an icable cooling surface, a heating device for heating the cooling surface and a control circuit for controlling the operation of the heating device as a function of a timer in which the control circuit is set up, the operation of the heating device during a lock time interval set by the timer.
- this freezer need not necessarily be an automatic defrost freezer;
- the timer does not necessarily serve to trigger a defrosting process after a certain time, as in the conventional frost-free devices, but, on the contrary, to prevent this at certain, unfavorable times.
- the times at which a defrosting process is considered necessary can be determined both automatically and by a user, as will be explained in more detail below.
- the time interval defined by the timer is a time interval, and preferably one that lasts from 9:00 a.m. to 10:00 p.m., preferably at least from 1:00 a.m. to 5:00 a.m.
- This determination of the time interval is based on the assumption that at night, especially between 9:00 a.m. and 10:00 p.m., there is little likelihood that refrigerated goods will be reloaded into the freezer because most users do shopping earlier in the day.
- the extension of the time interval in which the operation of the heating device is blocked to 5:00 a.m. on one day until 1:00 a.m. the next day has the additional advantage that inexpensive night-time electricity is then available in the time still available for defrosting can be used for defrosting.
- the freezer according to the invention preferably also uses inexpensive night-time electricity in that, provided that no defrosting takes place, it operates the cooling surface with a higher cooling capacity in the time allowed for defrosting than during the blocked time interval. This means that energy is also given to the freezer during normal operation. if necessary, shifted from the blocked time interval to the period in which defrosting is permitted and in which the costs for electrical energy are lower than in the blocked time interval.
- the timer is coupled to a sensor for detecting the opening of a door of the freezer, and the time interval specified by the timer is a time interval from when the door is opened.
- the effect of this configuration is comparable to that described above.
- the timer for the control circuit can be constructed differently. First, it can be an autonomous timer that does not receive any control signals from outside. Such a timer can in particular comprise an oscillator, especially a quartz oscillator for high accuracy at low costs.
- a radio receiver for receiving a radio time standard is particularly suitable as a non-autonomous timer.
- the interface to such a network can of course also serve to receive a time signal transmitted or queried on the network and to make it available to the control circuit.
- a preferred application of the invention are devices such as the frost-free devices already mentioned, in which the control circuit is designed to record at least one operating parameter of the freezer correlated with the degree of icing of the cooling surface and to close the heating device outside the specified time interval take if the at least one monitored operating parameter has exceeded a limit value.
- Preferred examples of such operating parameters are the total time that has elapsed since the last operating phase of the heating device or the operating time that has passed since then of a compressor of the freezer.
- a parameter that, unlike the two above, does not require cumulative detection, is the ratio of the operating time to the operating time of a freezer compressor.
- Another suitable parameter is the number of door openings counted since the last operating phase of the heating device.
- the control circuit is assigned an operating element for entering a command for starting up the heating device.
- This control element enables the user to enter a command to start up the heating device at any time if he determines that defrosting is useful, especially if he has opened the door and thus recognized the need for defrosting.
- the lock according to the invention prevents the defrosting process from being carried out at an unfavorable time.
- Such an operating element can of course also be provided on a freezer with automatic defrost.
- the object is further achieved by a method for controlling a freezer with an icable cooling surface and a heating device for heating the cooling surface, with the following steps:
- Figure 1 is a schematic section through a freezer to which the present invention is applicable.
- FIG. 2 shows a block diagram of a first embodiment of a control arrangement for the box device
- FIG. 3 shows a flowchart of an operating method for the control arrangement from FIG. 2;
- FIG. 5 shows a flow diagram of an operating method for the control arrangement from FIG. 4;
- FIG. 6 shows a modification of the control method from FIG. 5;
- FIG. 7 shows a third embodiment of a control arrangement according to the invention.
- FIG. 8 shows a flowchart of a working method for the control arrangement from FIG. 7.
- the structure of the refrigeration device shown in FIG. 1 is essentially known and is therefore only to be outlined briefly.
- a heat-insulating housing 1 and a door 2 of this type delimit a freezer compartment 3 in the interior of the housing 1.
- a wall 4 separates a chamber 5 from the freezer compartment 3, on the rear wall of which an evaporator 6 serving as a cooling surface is arranged.
- the evaporator 6 is part of a refrigerant circuit, together with a compressor 7 and a condenser 8.
- a fan 9 is arranged in a through opening in the partition 4. arranged to cause air circulation between the freezer compartment 3 and the chamber 5.
- the evaporator 6 Under normal operating conditions, the evaporator 6 is at temperatures below zero degrees Celsius. Moisture from air circulated from the freezer compartment 3 into the chamber 5 condenses on the surface of the evaporator 6 and forms an ice layer thereon after prolonged operation. In order to be able to defrost this layer of ice, a heating device 10 is arranged in the chamber 5.
- the invention can of course also be applied to freezers in which the evaporator 6 is not housed in its own chamber, but is in direct thermal contact with the freezer compartment 3.
- Fig. 2 shows a first embodiment of a control arrangement for the refrigerator of Fig. 1.
- the control arrangement comprises a control circuit 11, e.g. a microprocessor or microcontroller connected to an operating element 12, e.g. an electrical button attached to the housing 1, a temperature sensor 13 arranged on the evaporator 6 and a timer 14 are connected.
- the timer 14 is preferably implemented in the form of a quartz clock or a radio clock and periodically delivers a quantitative signal representative of the time.
- the timer 14 can also be the interface to such a network, since in such networks time signals are periodically transmitted or requested by the interface 14 from another terminal can.
- step S1 the time delivered by the timer 14 in the next step S2. If this is between 5:00 a.m. and 1:00 a.m., the control circuit 11 first ignores the user's command and waits in step S3 until 1:00 a.m. The time interval from 5:00 a.m. to 1:00 a.m.
- the control circuit 11 switches on the power supply to the heating device 10 and, at the same time, switches off the compressor 7 and the blower 9 if they were switched on.
- the control circuit 11 waits until the defrosting process is initiated until its operating phase has ended normally.
- the power supply to the heating device 10 is switched off in step S6 and the normal one Cooling operation resumed.
- the user can thus enter a defrost command at any time convenient for him, e.g. if he recognizes that defrosting is necessary when loading or unloading refrigerated goods.
- a defrost command By restricting the defrosting period to the time between 1:00 a.m. and 5:00 a.m., it is ensured that, until the defrosting process is initiated, any newly loaded refrigerated goods will be safely frozen through.
- Fig. 4 shows an example of a control arrangement which enables a fully automatic defrost operation. Components of this arrangement which have already been described with reference to FIG. 2 have the same reference numerals and are not described separately.
- the control circuit 11 of FIG. 4 additionally has a signal input 15, to which a control signal generated by a thermostat control circuit 16 for switching the compressor 7 on and off is present.
- FIG. 5 A first example of a working method that can be carried out with this configuration of the control arrangement is shown in FIG. 5.
- the method begins with an operating time counter t being set to zero in step S11 after the freezer has been switched on.
- the control circuit 11 recognizes that the compressor 7 is switched on (S12)
- it saves the current time takt in a buffer b (S13).
- the value in the buffer b is subtracted from the now current time takt and stored again in the buffer b (S15).
- step S16 If the result in step S16 shows that the result is less than zero, the beginning and end of the compressor operating phase belong to different days, and 24 hours must be added to the value in buffer b (S17) in order to obtain the correct duration of the operating phase of the compressor , The duration thus obtained is added to t (S18), and it is checked (S19) whether the result over a total operating time t
- the total operating time of the freezer since the last defrosting process could be measured and branched to step S21 as soon as the total operating time has exceeded a predetermined limit value.
- a further embodiment of an operating method for the control arrangement from FIG. 4 is dealt with on the basis of FIG. 6.
- the ratio between the running time of the compressor and the running time of the freezer is used as a criterion for the need for defrosting.
- This modification has the advantage that no parameters are accumulated over the entire operating time from the last defrosting process, so that the defrosting process can also be triggered correctly if saved parameter values are lost as a result of a power failure or another fault.
- step S31 the method begins with the initialization of a parameter a, which is representative of the relationship between the compressor runtime and the device runtime, to a value a, which in principle can be selected arbitrarily below a predetermined limit value A.
- step S32 is checked whether the compressor 7 is turned on or not. If not, the parameter a is multiplied by a “forgetting factor” 1- ⁇ in step S34; otherwise, it is incremented beforehand in step S33. By repeating these steps frequently, a converges to a value proportional to the desired ratio.
- step S 35 a check is made whether the limit value A has been exceeded, if not, steps S32 to S34 are repeated, otherwise it is determined that a defrosting process is required and steps S21 to S26 follow.
- the signal input 15 of FIG. 4 is replaced by a connection to a switch 17.
- This switch 17 is arranged in a manner known per se on the housing 1 in order to detect the opening and closing of the door 2 and accordingly switch the interior lighting of the freezer compartment 3 on and off.
- the control circuit 11 counts the number of times that the door 2 has been opened since the last defrosting process or, alternatively, the total time that the door 2 has been open since the last defrosting process, and compares the result with a limit value. This process is not illustrated using a flow diagram, since its implementation by generalizing the examples given above should be obvious. As soon as the limit value is determined to be exceeded, steps S21 to S26 are also carried out in this method.
- step S 41 the value of any suitable parameter is recorded, for example the number or duration of the door openings, compressor operating time, total operating time, ratio of compressor operating time to total operating time, etc. If it is determined in step S 42 that door 2 has been opened, then the timer 14 started (S43), which in this embodiment does not serve to supply a time, but rather to indicate the lapse of a predetermined period of time, for example three hours. These steps are repeated cyclically as long as it is not determined in step S44 that the monitored parameter has exceeded the limit value.
- next step (S45) must be checked whether the timer has expired, that is to say whether the specified time has elapsed since the door was last opened. If this is not the case, steps S41 to S44 are looped through until the timer has expired. The expiry of the timer indicates that a defrost process can now be initiated because enough time has passed since the last door was opened to safely freeze any newly stored items.
- the subsequent steps are identical to steps S4 to S7 from FIG. 3 and therefore do not need to be explained again.
- a side result of this control is that the timer will mostly expire at night, because it is therefore most likely that the door will remain closed for so long that the timer can expire. Therefore, with the method of FIG. 8, mainly inexpensive nighttime electricity can be used for the defrosting process.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Defrosting Systems (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Freezing, Cooling And Drying Of Foods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10221904A DE10221904A1 (en) | 2002-05-16 | 2002-05-16 | Freezer with defrost function and operating procedure therefor |
DE10221904 | 2002-05-16 | ||
PCT/EP2003/005004 WO2003098134A1 (en) | 2002-05-16 | 2003-05-13 | Freezer comprising a defrost function and operating method therefor |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1508007A1 true EP1508007A1 (en) | 2005-02-23 |
EP1508007B1 EP1508007B1 (en) | 2010-10-27 |
Family
ID=29413900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03752736A Expired - Lifetime EP1508007B1 (en) | 2002-05-16 | 2003-05-13 | Freezer comprising a defrost function and operating method therefor |
Country Status (10)
Country | Link |
---|---|
US (1) | US7320226B2 (en) |
EP (1) | EP1508007B1 (en) |
CN (1) | CN100374800C (en) |
AT (1) | ATE486256T1 (en) |
BR (1) | BR0309948A (en) |
DE (2) | DE10221904A1 (en) |
ES (1) | ES2353114T3 (en) |
PL (1) | PL202376B1 (en) |
RU (1) | RU2313742C2 (en) |
WO (1) | WO2003098134A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20031395A1 (en) * | 2003-07-09 | 2005-01-10 | Whirlpool Co | TEMPORALLY ADDRESSED AUTOMATIC DEFROST COOLER. |
DE102008054934A1 (en) | 2008-12-18 | 2010-07-01 | BSH Bosch und Siemens Hausgeräte GmbH | Refrigeration device and method for controlling the temperature in a refrigeration device |
WO2011057422A1 (en) * | 2009-11-10 | 2011-05-19 | Unilever Plc | Frost free surfaces and method for manufacturing the same |
DE102010007141A1 (en) * | 2010-02-05 | 2011-08-11 | Aht Cooling Systems Gmbh | freezer |
DE102012213644A1 (en) * | 2012-08-02 | 2014-02-20 | BSH Bosch und Siemens Hausgeräte GmbH | Refrigeration unit with automatic defrost |
DE102012221296A1 (en) * | 2012-11-21 | 2014-05-22 | BSH Bosch und Siemens Hausgeräte GmbH | Refrigerating appliance with a cooling compartment |
US10047969B2 (en) * | 2013-08-30 | 2018-08-14 | James Leych Lau | Energy saving controller |
US10808961B2 (en) | 2013-08-30 | 2020-10-20 | James Leych Lau | Energy saving controller |
CN104880016B (en) * | 2015-05-26 | 2018-02-02 | 青岛海尔股份有限公司 | Refrigerating equipment and its dewing-proof method and anti-condensation system |
US11912104B2 (en) * | 2018-04-13 | 2024-02-27 | Carrier Corporation | Method of defrosting a refrigeration system |
KR20200062698A (en) * | 2018-11-27 | 2020-06-04 | 엘지전자 주식회사 | Refrigerator and method for controlling the same |
US20200173719A1 (en) * | 2018-12-03 | 2020-06-04 | Mikko Lauri Antti Jaakkola | Method and system for cold storage health and content monitoring |
CN114812035B (en) * | 2021-01-29 | 2024-03-15 | 青岛海尔电冰箱有限公司 | Refrigerator and control method thereof |
Family Cites Families (24)
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US1979103A (en) * | 1931-12-19 | 1934-10-30 | Edwin G Gaynor | Automatic control for refrigerators, etc. |
US2703481A (en) * | 1950-09-27 | 1955-03-08 | Cutler Hammer Inc | Circuit controlling device for refrigerating systems and the like |
GB770362A (en) * | 1955-02-15 | 1957-03-20 | Westinghouse Electric Int Co | Improvements in or relating to refrigerating apparatus |
US3164969A (en) * | 1963-08-26 | 1965-01-12 | Lexaire Corp | Heat pump defrost control |
CH626500B (en) * | 1980-01-10 | Suisse Horlogerie | OSCILLATOR WITH DIGITAL TEMPERATURE COMPENSATION. | |
US4392357A (en) * | 1981-04-27 | 1983-07-12 | Emhart Industries, Inc. | Method and means controlling defrost cycles of a cooling unit |
US4581901A (en) * | 1983-01-21 | 1986-04-15 | Emhart Industries, Inc. | Control system for a heat pump system |
US4530218A (en) * | 1984-02-27 | 1985-07-23 | Whirlpool Corporation | Refrigeration apparatus defrost control |
US4787063A (en) * | 1984-10-19 | 1988-11-22 | Francis Muguet | Acquisition and transmission system for a recorder and a computer center |
JP2763568B2 (en) * | 1989-03-06 | 1998-06-11 | 松下冷機株式会社 | Showcase control device |
KR930013649A (en) * | 1991-12-21 | 1993-07-22 | 이헌조 | Defrosting method by learning use pattern of refrigerator |
US5379608A (en) * | 1992-03-24 | 1995-01-10 | Fuji Electric Co., Ltd. | Defrosting control unit for showcases |
US5363669A (en) * | 1992-11-18 | 1994-11-15 | Whirlpool Corporation | Defrost cycle controller |
JPH06249566A (en) * | 1993-02-24 | 1994-09-06 | Sanyo Electric Co Ltd | Defrosting control device for refrigerator |
US5345775A (en) * | 1993-03-03 | 1994-09-13 | Ridenour Ralph Gaylord | Refrigeration system detection assembly |
US5415005A (en) * | 1993-12-09 | 1995-05-16 | Long Island Lighting Company | Defrost control device and method |
US5483804A (en) * | 1994-03-28 | 1996-01-16 | Sanyo Electric Co., Ltd. | Defrost control apparatus for refrigerator |
GB9407098D0 (en) * | 1994-04-09 | 1994-06-01 | Harrison Brothers Steeplejacks | Detection system and method of operating same |
DE4438917C2 (en) * | 1994-11-03 | 1998-01-29 | Danfoss As | Process for defrosting a refrigeration system and control device for carrying out this process |
US5970726A (en) * | 1997-04-08 | 1999-10-26 | Heatcraft Inc. | Defrost control for space cooling system |
US6026651A (en) * | 1998-07-21 | 2000-02-22 | Heat Timer Corporation | Remote controlled defrost sequencer |
JP2001160176A (en) * | 1999-12-03 | 2001-06-12 | Sanden Corp | Automatic vending machine |
US6408634B1 (en) * | 2000-08-17 | 2002-06-25 | Jimex Corporation | Multi-chamber refrigeration system utilizing a single compressor and digital temperature controls |
DE60030971T2 (en) * | 2000-08-18 | 2007-06-14 | Ranco Inc. Of Delaware, Wilmington | Control device and method for controlling defrosting in a refrigerator |
-
2002
- 2002-05-16 DE DE10221904A patent/DE10221904A1/en not_active Ceased
-
2003
- 2003-05-13 DE DE50313221T patent/DE50313221D1/en not_active Expired - Lifetime
- 2003-05-13 RU RU2004133383/11A patent/RU2313742C2/en not_active IP Right Cessation
- 2003-05-13 ES ES03752736T patent/ES2353114T3/en not_active Expired - Lifetime
- 2003-05-13 WO PCT/EP2003/005004 patent/WO2003098134A1/en active Application Filing
- 2003-05-13 CN CNB038111292A patent/CN100374800C/en not_active Expired - Fee Related
- 2003-05-13 EP EP03752736A patent/EP1508007B1/en not_active Expired - Lifetime
- 2003-05-13 BR BR0309948-2A patent/BR0309948A/en not_active Application Discontinuation
- 2003-05-13 PL PL371493A patent/PL202376B1/en not_active IP Right Cessation
- 2003-05-13 AT AT03752736T patent/ATE486256T1/en active
-
2004
- 2004-11-04 US US10/980,968 patent/US7320226B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO03098134A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1653307A (en) | 2005-08-10 |
ES2353114T3 (en) | 2011-02-25 |
PL202376B1 (en) | 2009-06-30 |
RU2004133383A (en) | 2005-07-20 |
ATE486256T1 (en) | 2010-11-15 |
WO2003098134A1 (en) | 2003-11-27 |
RU2313742C2 (en) | 2007-12-27 |
EP1508007B1 (en) | 2010-10-27 |
BR0309948A (en) | 2005-03-01 |
PL371493A1 (en) | 2005-06-27 |
US7320226B2 (en) | 2008-01-22 |
DE10221904A1 (en) | 2003-12-04 |
US20050066667A1 (en) | 2005-03-31 |
CN100374800C (en) | 2008-03-12 |
DE50313221D1 (en) | 2010-12-09 |
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