EP1587963A2 - Acier lamine a chaud a tres haute resistance et procede de fabrication de bandes - Google Patents
Acier lamine a chaud a tres haute resistance et procede de fabrication de bandesInfo
- Publication number
- EP1587963A2 EP1587963A2 EP04701978A EP04701978A EP1587963A2 EP 1587963 A2 EP1587963 A2 EP 1587963A2 EP 04701978 A EP04701978 A EP 04701978A EP 04701978 A EP04701978 A EP 04701978A EP 1587963 A2 EP1587963 A2 EP 1587963A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- equal
- hot rolled
- iron
- ferrite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 42
- 239000010959 steel Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 13
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 10
- 238000004804 winding Methods 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910001563 bainite Inorganic materials 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims 1
- 239000011572 manganese Substances 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 239000011651 chromium Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000922 High-strength low-alloy steel Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
Definitions
- the present invention relates to hot rolled steel with very high resistance, and to a method of manufacturing strips of this steel, the structure of which is bainito-martensitic and can contain up to 5% of ferrite.
- Very high strength steels have been developed in recent years, in particular to meet the specific needs of the automotive industry, which are in particular the reduction of the weight and therefore of the thickness of the parts, and the improvement of safety. which involves increasing the resistance to fatigue and the impact resistance of the parts. These improvements must not further deteriorate the formability of the sheets used for the manufacture of the parts.
- a second family of very high strength steels is made up of so-called dual phase steels, with a structure comprising around 10% ferrite and 90% martensite. These steels have very good formability, but resistance levels not exceeding 800 MPa.
- the steel according to the invention can also include the following characteristics, alone or in combination:
- the method according to the invention consists first of all in hot rolling a slab of specific composition, in order to obtain a homogeneous structure.
- the rolling temperature is less than 950 ° C, and preferably less than 900 ° C.
- the strip thus obtained is cooled to a temperature less than or equal to 400 ° C, maintaining a cooling rate greater than 50 ° C / s between 800 and 700 ° C.
- This rapid cooling is carried out so that less than 5% of ferrite is formed, the presence of which is not desired, since the titanium would preferentially precipitate in this phase.
- This cooling rate is preferably between 50 ° C / s and 200 ° C / s.
- the method then consists in winding the strip at a winding temperature less than or equal to 250 ° C. We limit the temperature of this step in order to avoid causing an income from martensite, which would decrease the mechanical strength and raise the elastic limit, resulting in a poor E / Rm ratio.
- the composition also includes chromium at a content of between 0.50% and 1.0%. A minimum content of 0.50% promotes the appearance of bainite in the microstructure. Its content is however limited to 1.0% since a high chromium content would favor the increase in the amount of ferrite formed beyond 5%, due to its alphagenic character.
- the composition also includes silicon at a content of between 0.05% and 0.3%. It greatly improves the yield strength of steel while slightly reducing its ductility and deteriorating its coatability, which explains why its content is limited.
- the composition also comprises titanium at a content of between 0.05 and 0.1%. This element makes it possible to significantly increase the mechanical characteristics by a phenomenon of precipitation during rolling and cooling. It does not increase hot hardness due to its moderate content. Its content is limited to 0.1% to avoid degrading the impact resistance properties, the hardness when hot, as well as the ability to fold.
- the composition may also include phosphorus at a content of less than 0.05%, since beyond it could cause problems of segregation during continuous casting.
- the microstructure of test 1, according to the invention is bainitomartensitic, while the microstructure of tests 2 and 3 is ferrito-martensitic. It is found that a cooling rate between 800 and 700C of less than 50 ° C / s, induces the presence of ferrite in a proportion greater than 5%. The titanium will then precipitate in this ferrite, which no longer makes it possible to obtain the level of mechanical characteristics sought, in particular a high Rm. Furthermore, a winding temperature above 250 ° C, associated with a cooling rate between 800 and 700 ° C below 50 ° C / s, increases the elastic limit without increasing the mechanical strength. The E / Rm ratio is therefore too high.
- the steel according to the invention has a good ability to be coated by immersion in a bath of molten metal, such as zinc or a zinc alloy, or only aluminum or one of its alloys.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0300371A FR2849864B1 (fr) | 2003-01-15 | 2003-01-15 | Acier lamine a chaud a tres haute resistance et procede de fabrication de bandes |
FR0300371 | 2003-01-15 | ||
PCT/FR2004/000058 WO2004070064A2 (fr) | 2003-01-15 | 2004-01-14 | Acier lamine a chaud a tres haute resistance et procede de fabrication de bandes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1587963A2 true EP1587963A2 (fr) | 2005-10-26 |
EP1587963B1 EP1587963B1 (fr) | 2011-10-12 |
Family
ID=32524914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04701978A Expired - Lifetime EP1587963B1 (fr) | 2003-01-15 | 2004-01-14 | Acier laminé à chaud à très haute résistance et procédé de fabrication de bandes |
Country Status (16)
Country | Link |
---|---|
US (1) | US7699947B2 (fr) |
EP (1) | EP1587963B1 (fr) |
JP (1) | JP4505055B2 (fr) |
KR (1) | KR101065781B1 (fr) |
CN (1) | CN100366759C (fr) |
AT (1) | ATE528414T1 (fr) |
BR (1) | BRPI0406731B1 (fr) |
CA (1) | CA2513096C (fr) |
ES (1) | ES2374188T3 (fr) |
FR (1) | FR2849864B1 (fr) |
MX (1) | MXPA05007580A (fr) |
PL (1) | PL209154B1 (fr) |
RU (1) | RU2333284C2 (fr) |
UA (1) | UA79531C2 (fr) |
WO (1) | WO2004070064A2 (fr) |
ZA (1) | ZA200505161B (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2631314T3 (pl) * | 2010-10-18 | 2020-03-31 | Nippon Steel Corporation | Blacha stalowa cienka walcowana na gorąco, walcowana na zimno i powlekana galwanicznie o zwiększonej jednorodnej i miejscowej ciągliwości przy dużej szybkości odkształcenia |
WO2012153009A1 (fr) * | 2011-05-12 | 2012-11-15 | Arcelormittal Investigación Y Desarrollo Sl | Procede de fabrication d'acier martensitique a tres haute resistance et tole ainsi obtenue |
WO2012153008A1 (fr) * | 2011-05-12 | 2012-11-15 | Arcelormittal Investigación Y Desarrollo Sl | Procede de fabrication d'acier martensitique a tres haute resistance et tole ou piece ainsi obtenue |
CN102560272B (zh) * | 2011-11-25 | 2014-01-22 | 宝山钢铁股份有限公司 | 一种超高强度耐磨钢板及其制造方法 |
US10053757B2 (en) | 2012-08-03 | 2018-08-21 | Tata Steel Ijmuiden Bv | Process for producing hot-rolled steel strip |
CN103695762B (zh) * | 2013-12-13 | 2016-06-08 | 安徽工业大学 | 一种抗拉强度560~590MPa热轧轮辋用钢及其制造方法 |
US10837079B2 (en) * | 2014-01-24 | 2020-11-17 | Rautaruukki Oyj | Hot-rolled ultrahigh strength steel strip product |
DE102017130237A1 (de) | 2017-12-15 | 2019-06-19 | Salzgitter Flachstahl Gmbh | Hochfestes, warmgewalztes Stahlflachprodukt mit hohem Kantenrisswiderstand und gleichzeitig hohem Bake-Hardening Potential, ein Verfahren zur Herstellung eines solchen Stahlflachprodukts |
KR102020435B1 (ko) | 2017-12-22 | 2019-09-10 | 주식회사 포스코 | 굽힘성 및 저온인성이 우수한 고강도 열연강판 및 이의 제조방법 |
CN115386783B (zh) * | 2022-08-29 | 2023-10-03 | 东北大学 | 一种屈服强度1000MPa级超高强钢板及其制备方法 |
CN115354237B (zh) * | 2022-08-29 | 2023-11-14 | 东北大学 | 抗拉强度1000MPa级热轧超高强钢板及其制备方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2133744B2 (de) * | 1971-07-07 | 1973-07-12 | August Thyssen-Hütte AG, 4100 Duisburg | Die verwendung eines vollberuhigten stahles fuer gegenstaende aus warmgewalztem band |
JPS56150135A (en) * | 1980-01-18 | 1981-11-20 | British Steel Corp | Binary steel |
US4388122A (en) * | 1980-08-11 | 1983-06-14 | Kabushiki Kaisha Kobe Seiko Sho | Method of making high strength hot rolled steel sheet having excellent flash butt weldability, fatigue characteristic and formability |
US4501626A (en) * | 1980-10-17 | 1985-02-26 | Kabushiki Kaisha Kobe Seiko Sho | High strength steel plate and method for manufacturing same |
US4472208A (en) * | 1982-06-28 | 1984-09-18 | Sumitomo Metal Industries, Ltd. | Hot-rolled high tensile titanium steel plates and production thereof |
JP2819344B2 (ja) * | 1990-05-11 | 1998-10-30 | トーア・スチール株式会社 | ばね用鋼線 |
JPH06240356A (ja) * | 1993-02-10 | 1994-08-30 | Sumitomo Metal Ind Ltd | 加工性に優れた高強度熱延鋼板の製造方法 |
JP3425837B2 (ja) * | 1996-03-28 | 2003-07-14 | 株式会社神戸製鋼所 | 耐孔明き腐食性および圧壊特性に優れた高強度熱延鋼板、および高強度亜鉛系めっき鋼板並びにそれらの製造方法 |
EP1025272B1 (fr) * | 1997-07-28 | 2006-06-14 | Exxon Mobil Upstream Research Company | Aciers soudables ultra-resistants avec excellente tenacite aux tres basses temperatures |
JPH11199984A (ja) * | 1998-01-09 | 1999-07-27 | Kobe Steel Ltd | 溶断性に優れた高強度鋼板 |
FR2796966B1 (fr) * | 1999-07-30 | 2001-09-21 | Ugine Sa | Procede de fabrication de bandes minces en acier de type "trip" et bandes minces ainsi obtenues |
CN1107122C (zh) * | 2000-02-29 | 2003-04-30 | 济南济钢设计院 | 奥贝马钢及其制备方法 |
US6364968B1 (en) * | 2000-06-02 | 2002-04-02 | Kawasaki Steel Corporation | High-strength hot-rolled steel sheet having excellent stretch flangeability, and method of producing the same |
JP4608739B2 (ja) * | 2000-06-14 | 2011-01-12 | Jfeスチール株式会社 | 自動車ドア補強用鋼管の製造方法 |
FR2820150B1 (fr) * | 2001-01-26 | 2003-03-28 | Usinor | Acier isotrope a haute resistance, procede de fabrication de toles et toles obtenues |
-
2003
- 2003-01-15 FR FR0300371A patent/FR2849864B1/fr not_active Expired - Lifetime
-
2004
- 2004-01-14 RU RU2005125717/02A patent/RU2333284C2/ru active
- 2004-01-14 UA UAA200508007A patent/UA79531C2/uk unknown
- 2004-01-14 JP JP2006502099A patent/JP4505055B2/ja not_active Expired - Lifetime
- 2004-01-14 BR BRPI0406731-2A patent/BRPI0406731B1/pt active IP Right Grant
- 2004-01-14 KR KR1020057013089A patent/KR101065781B1/ko active IP Right Grant
- 2004-01-14 AT AT04701978T patent/ATE528414T1/de active
- 2004-01-14 EP EP04701978A patent/EP1587963B1/fr not_active Expired - Lifetime
- 2004-01-14 WO PCT/FR2004/000058 patent/WO2004070064A2/fr active Application Filing
- 2004-01-14 PL PL378236A patent/PL209154B1/pl unknown
- 2004-01-14 MX MXPA05007580A patent/MXPA05007580A/es active IP Right Grant
- 2004-01-14 US US10/542,107 patent/US7699947B2/en active Active
- 2004-01-14 ES ES04701978T patent/ES2374188T3/es not_active Expired - Lifetime
- 2004-01-14 CA CA2513096A patent/CA2513096C/fr not_active Expired - Lifetime
- 2004-01-14 CN CNB2004800021197A patent/CN100366759C/zh not_active Expired - Lifetime
-
2005
- 2005-06-24 ZA ZA2005/05161A patent/ZA200505161B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2004070064A2 * |
Also Published As
Publication number | Publication date |
---|---|
PL378236A1 (pl) | 2006-03-20 |
BRPI0406731A (pt) | 2005-12-20 |
EP1587963B1 (fr) | 2011-10-12 |
MXPA05007580A (es) | 2005-09-21 |
ATE528414T1 (de) | 2011-10-15 |
RU2333284C2 (ru) | 2008-09-10 |
UA79531C2 (en) | 2007-06-25 |
ES2374188T3 (es) | 2012-02-14 |
US20060207692A1 (en) | 2006-09-21 |
BRPI0406731B1 (pt) | 2012-11-27 |
CA2513096A1 (fr) | 2004-08-19 |
WO2004070064A3 (fr) | 2004-09-16 |
FR2849864B1 (fr) | 2005-02-18 |
FR2849864A1 (fr) | 2004-07-16 |
WO2004070064A2 (fr) | 2004-08-19 |
CN1735700A (zh) | 2006-02-15 |
ZA200505161B (en) | 2006-12-27 |
JP2006518009A (ja) | 2006-08-03 |
KR101065781B1 (ko) | 2011-09-19 |
RU2005125717A (ru) | 2006-02-10 |
US7699947B2 (en) | 2010-04-20 |
JP4505055B2 (ja) | 2010-07-14 |
CA2513096C (fr) | 2011-03-29 |
CN100366759C (zh) | 2008-02-06 |
KR20050090458A (ko) | 2005-09-13 |
PL209154B1 (pl) | 2011-07-29 |
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