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EP1436481B1 - Insulating glazing and the production method thereof - Google Patents

Insulating glazing and the production method thereof Download PDF

Info

Publication number
EP1436481B1
EP1436481B1 EP02790517A EP02790517A EP1436481B1 EP 1436481 B1 EP1436481 B1 EP 1436481B1 EP 02790517 A EP02790517 A EP 02790517A EP 02790517 A EP02790517 A EP 02790517A EP 1436481 B1 EP1436481 B1 EP 1436481B1
Authority
EP
European Patent Office
Prior art keywords
glazing unit
substantially flat
glazing
insulating glazing
glass sheets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02790517A
Other languages
German (de)
French (fr)
Other versions
EP1436481A1 (en
Inventor
Yves Demars
Jean-Pierre Douche
Jean-Christophe Elluin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of EP1436481A1 publication Critical patent/EP1436481A1/en
Application granted granted Critical
Publication of EP1436481B1 publication Critical patent/EP1436481B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C15/00Details
    • F24C15/02Doors specially adapted for stoves or ranges
    • F24C15/04Doors specially adapted for stoves or ranges with transparent panels
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/67Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/6621Units comprising two or more parallel glass or like panes permanently secured together with special provisions for fitting in window frames or to adjacent units; Separate edge protecting strips
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67326Assembling spacer elements with the panes
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67304Preparing rigid spacer members before assembly
    • E06B3/67321Covering spacer elements, e.g. with sealants
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67339Working the edges of already assembled units
    • E06B3/67356Covering the edges with bands or profiles

Definitions

  • the subject of the invention is an insulating glazing unit and its method of manufacture.
  • a well-known type of insulating glazing unit comprises two sheets of glass which are spaced apart by a gas strip such as air and which are spaced apart and joined together by means of a spacer frame consisting of hollow metal profiles folded or assembled by corner pieces.
  • the profiles are filled with a molecular sieve which has the role of absorbing the water molecules trapped in the air gap at the time of manufacture of the glazing and which would be likely to condense in cold weather, causing the appearance of mist.
  • the spacer frame is bonded to the glass sheets by a butyl rubber elastomer bead applied directly to the profiles by extrusion through a nozzle. Each corner of the spacer frame is also packed at the corner piece with butyl rubber.
  • the elastomeric sealing bead plays a role in temporarily holding the glass sheets.
  • a crosslinkable sealant of the polysulfide or polyurethane type which completes the mechanical assembly of the glass sheets.
  • Butyl rubber mainly has the role of sealing the interior of the glazing with water vapor, while the sealant provides a seal with liquid water or solvents.
  • a disadvantage posed by such manufacture is that of the storage of materials. In order to be operational for any new order placed for insulating glazing, many lots of each material must be available, which does not participate in a simple and fast management as to supply and storage of these materials.
  • the object of the invention is thus to obviate these drawbacks by proposing an insulating glazing whose choice of materials makes it possible to facilitate the management of their manufacturing flow, to simplify assembly operations and to restore the glazing without destroying it, in particular by replacement of the granular molecular sieve and / or reintroduction of gas.
  • the insulating glazing unit which comprises at least two glass sheets spaced by a gas blade, an interlayer for spacing the two glass sheets and having an inner face facing the gas blade and an opposite outer face , as well as sealing means vis-à-vis the interior of said glazing, is characterized in that the interlayer comprises a substantially flat profile that surrounds a first portion of the perimeter of the glazing, this portion may be the entire around, being plated by its inner face against the slices of the glass sheets, and held fixed by securing means, and another non-essentially flat profile which surrounds a second portion of the perimeter of the glazing, this second part not being the entire periphery.
  • This type of profile and its arrangement on the slices of the glazing have the particular advantage of increasing the visibility through the glazing in the parts of its periphery having as a spacer that the substantially flat profile.
  • the major advantage of the invention lies in the advantage of the extreme ease of bonding and takeoff of the substantially flat profile, particularly in order to access the interior of the hollow profile to replace the desiccant molecular sieve it contains; this accessibility is optimal when the hollow section occupies part, but not the entire periphery of the glazing: for example the lower horizontal side, or a fraction only of any rectilinear side. Re-bonding the flat profile after it has been peeled off does not pose a problem with many common material choices.
  • profile in the sense of the invention is meant a non-substantially flat profile, hollow or solid, square section, rectangular or more complex, for example having a lengthwise side substantially corresponding to the thickness of the gas strip.
  • the glazing unit of the invention comprises at least two sheets of glass, including three or more, spaced from each other, each designating both a monolithic glass sheet and a laminated sheet of glass and plastic.
  • the other section comprises at least a portion located outside the space defined by the glass sheets and shaped to fit and / or fixing the glazing in the bay for which it is intended. It is thus conceivable that this outer portion of the other profile forms a tongue along the entire length of the profile, and that this tongue can fit tightly into a groove formed in the frame of the bay, which makes unnecessary subsequent fixation by nailing - or equivalent process - a rod, called pareclose, on this part of the perimeter of the glazing.
  • the interlayer has gas and dust-tightness properties, and liquid water.
  • the sealing means of the substantially flat profile are arranged at least on the outer face, or at least on the inner face of the insert.
  • the outer face of the substantially flat profile advantageously has irregularities capable of ensuring the installation and / or centering and / or fixing of the glazing in the bay for which it is intended. These irregularities may consist of longitudinal striations as obtained by extrusion of thermoplastic or similar process.
  • irregularities may consist of longitudinal striations as obtained by extrusion of thermoplastic or similar process.
  • Figures 7 and 8 stepped ridges with one inclined side and the other right, arranged on inclined ramps and designed to fix the glazing in its frame, with simultaneous centering, by simple pressure. Streaks of this type are well within the present embodiment.
  • the sealing means of the substantially flat profile may consist of a metal coating, preferably of stainless steel or aluminum, which has a thickness of between 2 and 50 microns.
  • the substantially flat profile may be entirely metallic.
  • the substantially flat profile is based on thermoplastic material with or without reinforcing fibers such as cut or continuous glass fibers.
  • This coating can be both on the outside and on the inside of the side of the gas blade. There are advantages to having it preferably on the inside: a lesser thickness will be necessary since it will not need to withstand external shocks or scratches, the thermal bridge at the periphery of the glazing will be reduced, its bonding particularly it is aluminum is perfectly controlled on the glass regardless of the plastic of the profile used, it can finally promote the electrical connection with electrical elements provided inside the glazing.
  • the interlayer has a linear resistance to buckling of at least 400 N / m.
  • the flat profile must have a thickness of at least 0.1 mm when it is entirely made of stainless steel, at least 0.15 mm when it is entirely made of aluminum, and at least 0.25 mm when it is made of thermoplastic material reinforced with reinforcing fibers.
  • the securing means of the interlayer against the glazing are impermeable to water, they are constituted by a glue-type adhesive which withstands stripping stresses of at least 0.45 MPa.
  • the free ends of the substantially flat profile are assembled to surround all or part of the glazing so that one end covers the other, or one end of said other profile, complementary sealing means being intended to seal lateral sections made open by the covering.
  • the free ends of the substantially flat profile have complementary shapes adapted to cooperate mutually to achieve their assembly according to an abutment.
  • Adhesive tape or gas and steam-tight glue will preferably be applied to the abutment area.
  • the insulating glazing may have a complex shape, particularly with curved parts, to which the flat interlayer is perfectly adapted because it can by its flexibility easily marry the curves of the glazing.
  • one and / or the other face of the spacer has formally structured, or integrally attached, functional elements.
  • the studs may in particular serve as retaining elements for fixing braces installed in the gas strip, these braces having a decorative function.
  • these pads are arranged towards the inside of the glazing and according to at least two parallel strips, they can serve as guiding and wedging elements of at least one additional glass sheet for the manufacture of a triple or quadruple glazing. But they can also serve as holding elements of a glass sheet which, thus resting on these elements, allows communication between the different air blades of the glazing.
  • These elements if they have a function towards the outside of the glazing, can also favor the assembly by interlocking, the wedging, the blocking or the assembly of the glazing in the rabbet of the window or with neighboring windows or walls, or still these elements can constitute a way of cooperation with a rail for a sliding door.
  • the spacer may have cavities, double walls may constitute or house features, for example breathing tubes (tubes allowing the balancing of pressures between the inside and outside of the glazing without convection) .
  • the interlayer has at least one hole in order to be able for example to attach a desiccant cartridge, or a gas cartridge so as to fill the space between the glass sheets with gas, also to be able to achieve an equilibrium pressure when the glazing has been manufactured in a place where the atmospheric pressure is different from that of the delivery location, or the hole or holes may allow controlled air circulation between the glass sheets so as to constitute a breathable glazing very useful for example for an oven door.
  • This hole can be made in the substantially flat profile, or in the other profile, or in both, the two holes being advantageously, in the latter case, vis-à-vis one of the other.
  • the hole may be in direct communication with the gas strip, or not (for example when it is a hollow section end section, the sealing is provided by overlapping with a substantially flat profile).
  • the hole can be through or not; thus it can result only from the local absence of the waterproof layer, aluminum or other, but not the underlying layer, possibly permeable to gases.
  • This hole can be obtained by any suitable means of drilling or by an element attached to the profile provided with a punch by drilling at the indicated location, for example by a previously shaped impression on the profile, or by the positioning exact of the reported element thanks to locating bosses previously shaped on the profile as explained above.
  • the piercing footprint may for example be of the type of that arranged in commercial aluminum drink cans; once the drilling is done, the portion of repoussée material remains attached to the profile.
  • the hole has been made for the insertion of the gas, it is then necessary to close it in a sealed manner, for example by a gas-tight strip, which is mechanically fixed against the profile by various means such as using a suitable adhesive and sealing.
  • the tape can be glued by one of its faces against the face of the strip intended to be applied against the perforated profile.
  • the ribbon has on its opposite side a non-stick protective film which allows the application of the strip against the profile to change the position of said strip so as to arrange it correctly on the desired location.
  • a tab is provided laterally to the ribbon, it can be pulled to remove the protective film to discover the adhesive that will ensure the bonding of the strip against the profile.
  • the invention also encompasses a particular glazing unit, in which the edges of said two glass sheets are at least partly offset with respect to each other. It is conceivable that only one side of one of the two sheets protrudes from the corresponding side of the other of the two sheets, the gap space being occupied by said other profile, over the entire length of the side. It is also possible for one of said two sheets of glass to be a laminate whose sheet oriented towards the outside of the glazing is of larger dimensions than the other constituents of the laminate, on the edge of which, on the one hand, as well as on that of the other of said two sheets of glass on the other hand, a substantially flat profile is glued.
  • Another particular insulating glazing according to the invention is distinguished by the fact that at least one of said two sheets of glass has a through-hole, that the edges of this hole are considered to be part of said first part of the periphery of the glazing. , a substantially flat profile being pressed against and sealingly adhered to these edges. If the through hole is a disk, the flat section is shaped as a tube in which, if necessary, the glazing attachment means to a building structure or the like.
  • the interlayer is arranged on the slices of the glass sheets leaves free the inner peripheral surface of the glass sheets close to the slices, while in the prior art, this surface is occupied by the interlayer. It is thus possible to use this free surface to fix elements for example by gluing, such as decorative braces.
  • the fixing is invisible because it is at the level of the rabbet of the window, outside the clear view.
  • the substantially flat profile is present before its introduction in the form of a wound tape which is intended to be unwound, stretched and cut to the desired length, while the glue-type fastening means are deposited on the ribbon stretching by injection means.
  • the desiccant is deposited on the stretching tape during the application of the securing means.
  • the establishment of the substantially flat profile is effected by applying it by compression to a priming point and against the slices of a first side of the glazing, the belting being effected from this point priming and positioning of the ribbon on the corners of the glazing being made for a substantially flat profile based on thermoplastic material by heating its outer face beforehand to help its folding around the corners and marry perfectly their outline .
  • the initiation point is located in a side of the glazing side so as to apply and compress the substantially flat profile simultaneously in two opposite directions, which saves manufacturing time.
  • the priming point may be located rather at an angle of the glazing.
  • the establishment of the substantially flat profile is effected by applying two ribbons by compression at two points of initiation using means of distribution and compression, and the belting s' performs from these points of initiation by translational movements of the glazing and / or distribution means.
  • all glazing manufacturing operations can be performed in a chamber filled with the gas to be contained in the glazing.
  • a gas supply device which is inserted between the two glass sheets to deliver gas while the glazing surround is performed, and which is removed just before the end of the belting.
  • FIG. 1a illustrates a single insulating glazing unit 1 obtained by a manufacturing method which will be described later with regard to its device visible in FIG. 2.
  • the glazing 1 comprises two sheets of glass 10 and 11 spaced apart by a gas strip 12, an insert 2 which serves to space the two sheets of glass and has the role of ensuring the mechanical maintenance of the entire glazing, as well as sealing means 3 for sealing the glazing with liquid water, solvents and water vapor.
  • the insert 2 is in the form of a substantially flat profile approximately 1 mm thick and of substantially parallelepiped section.
  • This profile advantageously has a low mechanical inertia, that is to say that it can be easily wound by having a small winding radius of 10 cm for example.
  • the profile surrounds the perimeter of the glazing. It is arranged in the manner of a ribbon on the slices 10a and 11a of the glass sheets and guarantees the mechanical assembly of the glazing through securing means 4 which ensure its total adhesion to the glass.
  • the profile is rigid enough to perform the mechanical holding function of the two spaced glass sheets. Its rigidity is defined by the very nature of its constituent material, whose linear buckling resistance must be at least 400 N / m.
  • the nature of the material of said profile is also chosen so that during the glass manufacturing process, the profile may have sufficient flexibility for the operation of belting the glass slices, in particular during the curling angles.
  • the spacer is entirely metallic, the material chosen being preferably stainless steel or aluminum. During the process, the edges are bent by means of machines well known to those skilled in the art of processing metal materials.
  • the interlayer In order to guarantee a minimum linear resistance to buckling of 400N / m, the interlayer must have a thickness of at least 0.1 mm for stainless steel and 0.15 mm for aluminum.
  • the interlayer 2 is based on plastic material with or without reinforcement fibers cut or continuous.
  • a material may be styrene acrylonitrile (SAN) associated with cut glass fibers, sold for example under the name LURAN® by BASF, or polypropylene reinforced with continuous glass fibers, sold under the name TWINTEX® by the company VETROTEX.
  • SAN styrene acrylonitrile
  • the interlayer from a combination of materials such as plastic and metal to form for example a spacer with a thickness of plastic material secured to a metal thickness.
  • the desiccant may be a molecular sieve such as zeolite powder, which may be up to 20% by weight or about 10% by volume.
  • the amount of desiccant is a function of the lifetime that we want to assign to the glazing.
  • the plastic material being much less heat-conducting than the metal, the thermal insulation of the entire glazing is only better when the glazing is for example exposed to strong sunlight.
  • the spacer 2 has a thickness of at least 0.2 mm when it is made of thermoplastic material and reinforcing fibers.
  • the width of the spacer 2 is adapted to the total thickness of the glazing which can be multiple by including several glass sheets spaced by gas strips.
  • the interlayer of the invention only requires knowledge of the total width of the glazing and not the separation distances of the glass sheets.
  • the separation distances for a multiple glazing may vary, which necessarily entails in the case of the use of spacers according to those of the state of the art to have available for the manufacture of glazing several interleaves for the different separations, and different widths of inserts according to separation distances.
  • the glazing of the invention with its interlayer disposed on the edges of the glass sheets does not lose rigidity, but on the contrary it is further improved in comparison with a conventional glazing of the prior art presenting its interlayer disposed between the inner faces of the glass sheets.
  • the ratio of the arrows of the glazing of the invention and respectively of a conventional glazing as a function of the thickness has been calculated. of the air knife. For this purpose, is applied to each glazing a given force, is then measured the maximum deflection of each glazing and is then calculated the ratio of the arrows.
  • This ratio equal to the deflection of the usual glazing divided by the deflection of the glazing unit of the invention is always greater than 1, reflecting a better resistance to bending and therefore a better rigidity of the glazing unit of the invention.
  • FIG. 6 illustrates this ratio as a function of the air gap, the spacer considered for the insulating glazing unit of the invention being an aluminum profile of 0.5 mm. We see that the ratio is always greater than 1, and is for example 1.5 for a 12 mm air gap.
  • the insert or profile 2 comprises an inner face 20 and an opposite outer face 21, the inner face 20 being intended to be plated, and maintained, by its edges in the case of a single insulating glazing unit, against the slices 10a and 11a glass sheets through the securing means 4.
  • the inner face 20 of the profile has in its central portion 22 and facing the gas blade 12 the properties of those of a desiccant which aims to absorb the water molecules that can be trapped in the gas blade .
  • These desiccant properties can result from the nature of the interlayer material, whose composition itself incorporates a molecular sieve.
  • the desiccant element will rather be obtained by a deposit of molecular sieve on the central portion 22 before the introduction of the spacer on the slices of the glazing, as we will see in the following description.
  • the edges of the inner face 20 are covered with an adhesive which constitutes the securing means 4.
  • the adhesive is of the glue type; it is impervious to gases, water vapor. Tests carried out in accordance with ASTM 96-63T standard on 1.5 mm thick adhesive samples showed that an adhesive with a water vapor permeability coefficient of 35 g / 24h.m 2 such as silicone is suitable. Of course, an adhesive having a permeability coefficient of 4 g / 24h.m 2, such as polyurethane, or even lower, is more suitable because the seal being further improved, a lesser amount of desiccant is then expected.
  • the adhesive must also withstand the take-off by liquid water, ultraviolet light as well as traction that can be exerted perpendicularly to the faces of the glazing and commonly called shear stresses, and by the pulls exerted parallel to the force of the weight of the glazing .
  • a satisfactory adhesive must withstand stripping stresses of at least 0.45 MPa.
  • the adhesive must for example have a temperature resistance sufficient for the application of glazing to a door of an electric household oven.
  • the adhesive has fast gluing properties, of the order of a few seconds; it is an adhesive which is taken by chemical reaction, whether or not activated by heat or pressure, or is carried out by cooling if the adhesive consists of a hot-melt material of the type hot melt, for example based on polyurethane crosslinkable with the humidity of the air.
  • the outer face 21 of the interlayer made of reinforced plastic material is covered with a metallic protective coating 21a of the type of aluminum or stainless steel strip having a thickness of, for example, between 2 and 50 ⁇ m, this coating constituting the means for sealing 3.
  • a metallic protective coating 21a of the type of aluminum or stainless steel strip having a thickness of, for example, between 2 and 50 ⁇ m, this coating constituting the means for sealing 3.
  • the strip particularly when made of stainless steel, effectively protects the profile against abrasion, for example during its handling or transport. Finally, it promotes the exchange of heat with the thermoplastic material when it comes to soften the latter during the manufacturing process.
  • the metal coating 21a could be large enough to cover the outer face 21 and be folded over the edges of the inner face 20.
  • the hollow section 30 is bonded by the securing means 5 to the slices of the glass sheets 10 and 11.
  • the inner face 20 of the spacer is a delimitation of the gas strip 12, so that the desiccant molecular sieve contained in the hollow profile and not shown is active vis-à-vis the gas blade, through communications 31 -housing, porosity, ...- formed in the inner face 20. If necessary, these communications 31 with the gas strip are released by local removal of a possible sealing layer which would be provided with the profile 30.
  • the communications 31 are smaller than those of the desiccant, frequently in the form of granules, so to retain them in the hollow section 30.
  • the securing means 5 ensure the required seal between the gas strip 12 and the outside atmosphere.
  • the hollow section is disposed on all or part of a rectilinear side of the insulating glazing, in a single section or in several sections of a length indicative of 10 to 15 cm.
  • the hollow section is optionally sealed with a hot-melt material with low moisture transmission, such as polyurethane.
  • a substantially flat profile not shown in Figure 1b is bonded to each of the two end sections of the hollow profile 30, which it thus sealingly closes, possibly in combination with the hot melt material low moisture transmission aforementioned.
  • the flat profile 2 (see FIG. 1a) comprises sealing means, constituted as described above, of an aluminum foil 3, which may be oriented towards the inside of the glazing, the glue 4 being chosen to bond the aluminum to the hollow profile 30 but also to the slices of the glass sheets.
  • This orientation of the sealing means 3 has the advantage of making it possible to conform the external face of the flat profile 2, for example made of plastic, with grooves for fixing the glazing as described in the application EP-745 750 A1 , especially by extrusion.
  • a substantially flat profile 2 provided with its sealing means 3 facing outward surrounds all the periphery of the insulating glass, being adhered to the slices of the glass sheets by the glue 4.
  • the flat profile 2 presents a hole 6 which, for example, could be cut after securing the flat profile to the glass sheets, and possibly after a certain period of use of the glazing resulting therefrom.
  • a hollow profile 30 has therefore here been subsequently bonded to the flat profile 2 by the glue 5.
  • the molecular sieve contained in the hollow of the profile 30 is active vis-à-vis the gas plate 12, with which it communicates through the pores or holes 31 formed in the inner wall 20 of the profile 30 and through the hole 6.
  • the hollow profile 30 can here also be plugged at its ends with a hot melt material with low moisture transmission. Additional sealing means not shown are conveniently used between the flat profile 2 and the hollow profile 30: adhesive tape, injection of materials suitable for closing open side cover sections (see above). These additional means are removable, so that the regeneration of the molecular sieve of the profile 30, possibly after a long period of use of several years, is particularly simplified by the measures of the invention.
  • Figure 1d is shown a variant in which a hollow section 30 is installed integrally in the space defined by two sheets of glass 10 and 11 of an insulating glass, by bonding with a material 5 'able to provide the required seal between the gas slide and the outside atmosphere but on a only part of the periphery of the glazing, preferably on part or all of a rectilinear side of the glazing.
  • a substantially flat non-visible profile covers and is bonded at least on each of the two end sections of the hollow profile 30, so as to ensure or at least contribute to the required seal between the cavity of the hollow profile 30 and the external atmosphere . It suffices to take off a sufficient portion of the flat profile 2 to clear one end of the hollow section 30 to replace the used desiccant it contains, then to re-stick.
  • the glass sheets 10 and 11 are conveyed edge by usual means to a chamber that can enclose the gas to be introduced into the glazing.
  • the glass sheets 10 and 11 are held at the desired spacing by means of suction pads disposed on the outer faces of the glazing and controlled by pneumatic cylinders.
  • Figure 2 schematically illustrates the manufacturing device of the glazing enclosed in the chamber C.
  • a coil 50 constitutes the store of the section 2 which is unwound and stretched, using a non-visible stretching device, in the form of a ribbon which is cut to a length equivalent to the perimeter of the glazing, the width of the ribbon corresponding to the total thickness of the glazing.
  • the adhesive 4 is deposited using injection means 51, such as a nozzle, on the internal face 20 of the ribbon intended to be applied to the edge of the glazing.
  • the ribbon comprises the desiccant inherently on its inner side, the desiccant having been incorporated as a powder or granules to the reinforced thermoplastic material during the manufacture of the profile.
  • the desiccant and the adhesive when it comes to adding the desiccant subsequently to the manufacture of the profile, it is preferable to set up the desiccant and the adhesive during a single operation with the aid of three injection nozzles two lateral nozzles aiming at the edges of the tape for the deposition of the adhesive in order to be facing the slices of the glazing and a central nozzle injecting the desiccant on the central portion 22 of the tape in order to be vis-à-vis -vis the gas blade.
  • At least one pressure roller 54 controlled by a not shown articulated arm performs the application and compression of the ribbon 2 against the edge of the glazing 1 over its entire perimeter. To save time in the operation of belting, it will preferably be provided two rollers 54 which will be driven in two opposite directions and will simultaneously flank two halves of the perimeter.
  • Heating means 55 such as two heating wire resistors are provided for heating the profile before folding and its application at the corners of the glazing.
  • the operation of the device is as follows.
  • the two sheets of glass 10, 11 kept apart are positioned fixed in the center of the chamber C.
  • the two pressure rollers 54 are brought into contact with the tape to apply it to a midpoint of the lower horizontal side of the glazing. Once the ribbon pressed against the wafer of the glazing, the curling is initiated at this midpoint which thus ensures the power of the ribbon.
  • rollers 54 then progress in opposite directions to the lower left 13 and right 14 corners of the glazing.
  • the pressure rollers 54 are again put into operation to fold the profile and properly border the corners 13 and 14 of the glazing. Then the pebbles continue to run around the glazing to the upper corners 15 and 16 of the glazing where the heating operation of the profile is reiterated by means of the heating wires 55.
  • the pinch rollers 54 end to border the last side of the glazing.
  • one of the rollers is stopped while the other roller continues to crush the section until the free end 23 of the profile associated with the roller in operation covers the other end 24 of the profiled section (FIG. 4).
  • the belting operation is then completed, the pressure rollers 54 are released from the glazing.
  • complementary sealing means such as glue are injected so as to close off said sections 25.
  • An unillustrated assembly variant of the two ends of the ribbon may consist not in covering them but in abutting them to one another when they comprise complementary shapes adapted to cooperate mutually, in the manner of a tenon and of a mortise.
  • glue or water and vapor-tight adhesive tape such as stainless steel tape, will be added to the butting area.
  • junction of the two ends of the ribbon is performed on one side of the glazing, it is also possible to alternatively make this junction at an angle of the glazing.
  • the glazing entered in the chamber C which is not illustrated here, is disposed between the position 1 corresponding to the front of the glazing and the position 2 corresponding to the rear of the glazing.
  • the movable head 56b starts at a lower angle of the glazing corresponding to the position 1, and is actuated upwards to follow the vertical front side of the glazing.
  • the head 56b rotates 90 ° and is immobilized, the two heads being then vis-à-vis.
  • the glazing is then translated from left to right, that is to say that the rear of the glazing goes from the position 2 to the position 1, so as simultaneously perform the belting of the horizontal sides of the glazing by respectively each of the heads ( Figure 5b).
  • This combination of translational movement of the glazing and at least one ribbon dispensing head saves time to surround the glazing.
  • a gas supply device such as a pipe which is inserted between the two glasses and which delivers gas as the edges of the glazing are girdled and sealed. The device is removed just before closing the last side of the glazing.
  • the profile of the invention has a generally flat and parallelepipedal shape, nevertheless alternative embodiments are possible. It may for example be envisaged to provide the inner face 20 of the profile opposite to that comprising the metal coating, centering and positioning means such as longitudinal projections or lugs regularly distributed along two longitudinal lines spaced by a width equivalent to the separation of the two glass sheets so as to guide and properly position the profile against the edge of the glazing, the projections or lugs inserting inside the glazing and being pressed against the inner walls.

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  • Securing Of Glass Panes Or The Like (AREA)
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Abstract

An insulating glazing unit including at least two glass sheets spaced apart by a gas-filled cavity, an insert that serves to keep the two glass sheets apart and that has an internal face facing the gas-filled cavity and an opposed external face, and a sealing with respect to the inside of the glazing unit. The insert includes a substantially flat strip that surrounds a first part of the perimeter of the glazing unit, being pressed by its internal face against the edges of the glass sheets and kept fastened by a fastener, and another strip that surrounds a second part of the perimeter of the glazing unit.

Description

L'invention a pour objet un vitrage isolant et son procédé de fabrication.The subject of the invention is an insulating glazing unit and its method of manufacture.

Un type de vitrage isolant bien connu comporte deux feuilles de verre qui sont espacées par une lame de gaz tel que de l'air et, qui sont écartées et réunies au moyen d'un cadre entretoise constitué par des profilés métalliques creux pliés ou assemblés par des pièces d'angle. Les profilés sont garnis d'un tamis moléculaire qui a notamment pour rôle d'absorber les molécules d'eau emprisonnées dans la lame d'air intercalaire au moment de la fabrication du vitrage et qui seraient susceptibles de se condenser par temps froid, entraînant l'apparition de buée.A well-known type of insulating glazing unit comprises two sheets of glass which are spaced apart by a gas strip such as air and which are spaced apart and joined together by means of a spacer frame consisting of hollow metal profiles folded or assembled by corner pieces. The profiles are filled with a molecular sieve which has the role of absorbing the water molecules trapped in the air gap at the time of manufacture of the glazing and which would be likely to condense in cold weather, causing the appearance of mist.

Pour assurer l'étanchéité du vitrage, le cadre entretoise est collé aux feuilles de verre par un cordon élastomère du type caoutchouc butyl appliqué directement sur les profilés par extrusion au travers d'une buse. Chaque coin du cadre entretoise est également garni au niveau de la pièce d'angle par du caoutchouc butyl. Une fois le vitrage assemblé, le cordon élastomère d'étanchéité joue un rôle de maintien mécanique provisoire des feuilles de verre. Enfin, on injecte dans la gorge périphérique délimitée par les deux feuilles de verre et le cadre entretoise un mastic d'étanchéité réticulable du type polysulfure ou polyuréthane qui termine l'assemblage mécanique des feuilles de verre. Le caoutchouc butyl a principalement comme rôle de rendre étanche l'intérieur du vitrage à la vapeur d'eau, tandis que le mastic assure une étanchéité à l'eau liquide ou aux solvants.To ensure the tightness of the glazing, the spacer frame is bonded to the glass sheets by a butyl rubber elastomer bead applied directly to the profiles by extrusion through a nozzle. Each corner of the spacer frame is also packed at the corner piece with butyl rubber. Once the glazing is assembled, the elastomeric sealing bead plays a role in temporarily holding the glass sheets. Finally, is injected into the peripheral groove defined by the two glass sheets and the spacer frame a crosslinkable sealant of the polysulfide or polyurethane type which completes the mechanical assembly of the glass sheets. Butyl rubber mainly has the role of sealing the interior of the glazing with water vapor, while the sealant provides a seal with liquid water or solvents.

La fabrication de ce vitrage nécessite plusieurs matériaux distincts dont les profilés, les pièces d'angle, le tamis moléculaire, les joints organiques d'étanchéité, ces matériaux n'étant pas assemblés en une seule et même opération.The manufacture of this glazing requires several different materials including profiles, corner pieces, molecular sieve, organic seals, these materials are not assembled in one and the same operation.

Un inconvénient posé par une telle fabrication est celui du stockage des matériaux. Afin d'être opérationnel pour toute nouvelle commande passée pour des vitrage isolants, de nombreux lots de chaque matériaux doivent être à disposition, ce qui ne participe pas à une gestion simple et rapide quant à l'approvisionnement et au stockage de ces matériaux.A disadvantage posed by such manufacture is that of the storage of materials. In order to be operational for any new order placed for insulating glazing, many lots of each material must be available, which does not participate in a simple and fast management as to supply and storage of these materials.

En outre, le nombre actuel de matériaux à assembler engendre plusieurs opérations de montage qui, bien qu'automatisées, sont réalisées les unes après les autres ce qui pénalise notablement le temps de fabrication. Certaines de ces opérations imposent aussi des interruptions dans la chaîne de fabrication, pouvant par ces courts temps morts gêner davantage la cadence de production.In addition, the current number of materials to assemble causes several assembly operations which, although automated, are performed one after the other which significantly penalizes the manufacturing time. Some of these operations also impose interruptions in the production line, which may, in these short dead times, further hamper the production rate.

De plus, la régénération du tamis moléculaire garnissant l'intérieur des profilés creux est impossible avec les vitrages isolants connus à l'heure actuelle car elle implique leur destruction.In addition, the regeneration of the molecular sieve lining the interior of the hollow profiles is impossible with insulating glass currently known because it involves their destruction.

L'invention a donc pour objet d'obvier à ces inconvénients en proposant un vitrage isolant dont le choix des matériaux permet de faciliter la gestion de leur flux de fabrication, de simplifier les opérations de montage et restaurer le vitrage sans le détruire, notamment par remplacement du tamis moléculaire granuleux et/ou réintroduction de gaz.The object of the invention is thus to obviate these drawbacks by proposing an insulating glazing whose choice of materials makes it possible to facilitate the management of their manufacturing flow, to simplify assembly operations and to restore the glazing without destroying it, in particular by replacement of the granular molecular sieve and / or reintroduction of gas.

Selon l'invention, le vitrage isolant qui comporte au moins deux feuilles de verre espacées par une lame de gaz, un intercalaire servant à espacer les deux feuilles de verre et présentant une face interne en regard de la lame de gaz et une face externe opposée, ainsi que des moyens d'étanchéité vis-à-vis de l'intérieur dudit vitrage, est caractérisé en ce que l'intercalaire comprend un profilé sensiblement plat qui ceinture une première partie du pourtour du vitrage, cette partie pouvant être la totalité du pourtour, en étant plaqué par sa face interne contre les tranches des feuilles de verre, et maintenu fixé par des moyens de solidarisation, et un autre profilé non essentiellement plat qui ceinture une seconde partie du pourtour du vitrage, cette seconde partie n'étant pas la totalité du pourtour.According to the invention, the insulating glazing unit which comprises at least two glass sheets spaced by a gas blade, an interlayer for spacing the two glass sheets and having an inner face facing the gas blade and an opposite outer face , as well as sealing means vis-à-vis the interior of said glazing, is characterized in that the interlayer comprises a substantially flat profile that surrounds a first portion of the perimeter of the glazing, this portion may be the entire around, being plated by its inner face against the slices of the glass sheets, and held fixed by securing means, and another non-essentially flat profile which surrounds a second portion of the perimeter of the glazing, this second part not being the entire periphery.

Ce type de profilé et sa disposition sur les tranches du vitrage présentent notamment l'avantage d'augmenter la visibilité au travers du vitrage dans les parties de sa périphérie ne comportant en tant qu'intercalaire que le profilé sensiblement plat.This type of profile and its arrangement on the slices of the glazing have the particular advantage of increasing the visibility through the glazing in the parts of its periphery having as a spacer that the substantially flat profile.

Il peut y avoir recouvrement partiel ou même total desdites première et seconde parties du pourtour du vitrage, à condition que les fonctions classiques d'entretoisement et d'étanchéité de l'intercalaire soient remplies. La seconde partie du pourtour occupée par ledit autre profilé ne représente pas la totalité du pourtour. En effet, dans le cas où l'autre profilé est creux, l'intérêt majeur de l'invention réside dans la mise à profit de l'extrême facilité de collage et décollage du profilé sensiblement plat, notamment de manière à pouvoir accéder à l'intérieur du profilé creux pour remplacer le tamis moléculaire desséchant qu'il contient ; or cette accessibilité est optimale lorsque le profilé creux occupe une partie, mais non la totalité du pourtour du vitrage : par exemple le côté horizontal inférieur, ou une fraction seulement d'un côté rectiligne quelconque. Le recollage du profilé plat après qu'il a été décollé ne pose pas de problème avec de nombreux choix de matériaux usuels.There may be partial or even total recovery of said first and second parts of the perimeter of the glazing, provided that the conventional bracing and sealing functions of the interlayer are met. The second portion of the periphery occupied by said other profile does not represent the entire periphery. Indeed, in the case where the other profile is hollow, the major advantage of the invention lies in the advantage of the extreme ease of bonding and takeoff of the substantially flat profile, particularly in order to access the interior of the hollow profile to replace the desiccant molecular sieve it contains; this accessibility is optimal when the hollow section occupies part, but not the entire periphery of the glazing: for example the lower horizontal side, or a fraction only of any rectilinear side. Re-bonding the flat profile after it has been peeled off does not pose a problem with many common material choices.

Par autre profilé au sens de l'invention, on entend un profilé non essentiellement plat, creux ou plein, de section carrée, rectangulaire ou plus complexe, ayant par exemple un côté de longueur correspondant sensiblement à l'épaisseur de la lame de gaz.For another profile in the sense of the invention is meant a non-substantially flat profile, hollow or solid, square section, rectangular or more complex, for example having a lengthwise side substantially corresponding to the thickness of the gas strip.

Le vitrage de l'invention comporte au moins deux feuilles de verre, y compris trois ou plus, espacées les unes des autres, chacune désignant aussi bien une feuille de verre monolithique qu'un feuilleté de feuilles de verre et de matière plastique.The glazing unit of the invention comprises at least two sheets of glass, including three or more, spaced from each other, each designating both a monolithic glass sheet and a laminated sheet of glass and plastic.

Conformément à deux variantes qui ne s'excluent pas mutuellement :

  • ledit autre profilé est plaqué par sa face interne contre les tranches des feuilles de verre, soit directement soit avec interposition, par exemple, dudit profilé sensiblement plat ;
  • ledit autre profilé est au moins en partie situé entre les feuilles de verre.
According to two variants which are not mutually exclusive:
  • said other section is plated by its inner face against the slices of the glass sheets, either directly or with interposition, for example, said substantially flat profile;
  • said other profile is at least partly located between the glass sheets.

Dans les deux cas, l'autre profilé peut être collé aux feuilles de verre, que ce soit sur leurs tranches ou sur leurs surfaces internes. Cependant il est également possible qu'un tel collage ne soit pas effectué, par exemple dans des configurations telles que :

  • autre profilé plaqué sur les tranches des feuilles de verre et totalement enveloppé par le profilé plat lui-même collé au verre ;
  • autre profilé totalement entre les feuilles de verre, sur le côté horizontal inférieur, en appui par gravité sur la face interne du profilé plat, ou avec serrage entre les deux feuilles.
In both cases, the other section can be glued to the glass sheets, either on their slices or on their internal surfaces. However it is also possible that such a bonding is not performed, for example in such configurations as:
  • other profile plated on the slices of the glass sheets and completely wrapped by the flat profile itself glued to the glass;
  • another profile completely between the glass sheets, on the lower horizontal side, supported by gravity on the inner face of the flat profile, or with clamping between the two sheets.

Avantageusement, l'autre profilé comprend une partie au moins située en dehors de l'espace délimité par les feuilles de verre et de forme adaptée au calage et/ou à la fixation du vitrage dans la baie à laquelle il est destiné. Il est ainsi concevable que cette partie extérieure de l'autre profilé forme une languette sur toute la longueur du profilé, et que cette languette puisse s'emboîter étroitement dans une rainure formée dans le cadre de la baie, ce qui rend superflue la fixation ultérieure par clouage - ou procédé équivalent - d'une baguette, appelée pareclose, sur cette partie de pourtour du vitrage.Advantageously, the other section comprises at least a portion located outside the space defined by the glass sheets and shaped to fit and / or fixing the glazing in the bay for which it is intended. It is thus conceivable that this outer portion of the other profile forms a tongue along the entire length of the profile, and that this tongue can fit tightly into a groove formed in the frame of the bay, which makes unnecessary subsequent fixation by nailing - or equivalent process - a rod, called pareclose, on this part of the perimeter of the glazing.

De préférence, l'intercalaire présente des propriétés d'étanchéité aux gaz et poussières, et à l'eau liquide.Preferably, the interlayer has gas and dust-tightness properties, and liquid water.

Les moyens d'étanchéité du profilé sensiblement plat sont disposés au moins sur la face externe, ou au moins sur la face interne de l'intercalaire. Dans ce dernier cas, la face externe du profilé sensiblement plat présente avantageusement des irrégularités aptes à assurer la pose et/ou le centrage et/ou la fixation du vitrage dans la baie à laquelle il est destiné. Ces irrégularités peuvent consister en stries longitudinales telles qu'obtenues par extrusion de thermoplastique ou procédé similaire. A cet égard référence est faite à la demande EP-0 745 750 A1 décrivant (figures 7 et 8) des stries en gradins avec un côté incliné et l'autre droit, disposées sur des rampes inclinées et conçues pour fixer le vitrage dans son cadre, avec centrage simultané, par simple pression. Des stries de ce type entrent parfaitement dans le présent mode de réalisation.The sealing means of the substantially flat profile are arranged at least on the outer face, or at least on the inner face of the insert. In the latter case, the outer face of the substantially flat profile advantageously has irregularities capable of ensuring the installation and / or centering and / or fixing of the glazing in the bay for which it is intended. These irregularities may consist of longitudinal striations as obtained by extrusion of thermoplastic or similar process. In this respect reference is made to the request EP-0 745 750 A1 describing (Figures 7 and 8) stepped ridges with one inclined side and the other right, arranged on inclined ramps and designed to fix the glazing in its frame, with simultaneous centering, by simple pressure. Streaks of this type are well within the present embodiment.

Les moyens d'étanchéité du profilé sensiblement plat peuvent être constitués par un revêtement métallique, de préférence en inox ou en aluminium, qui présente une épaisseur comprise entre 2 et 50 µm.The sealing means of the substantially flat profile may consist of a metal coating, preferably of stainless steel or aluminum, which has a thickness of between 2 and 50 microns.

Le profilé sensiblement plat peut être entièrement métallique.The substantially flat profile may be entirely metallic.

Cependant, selon un mode de réalisation préférentiel de l'intercalaire, le profilé sensiblement plat est à base de matière thermoplastique armée ou non de fibres de renforcement telles que des fibres de verre coupées ou continues.However, according to a preferred embodiment of the interlayer, the substantially flat profile is based on thermoplastic material with or without reinforcing fibers such as cut or continuous glass fibers.

Lorsque le profilé est en matière plastique, il est prévu un revêtement métallique pour constituer les moyens d'étanchéité aux gaz et à la vapeur d'eau comme indiqué ci-dessus.When the profile is made of plastic, there is provided a metal coating to form the sealing means for gas and water vapor as indicated above.

Ce revêtement peut aussi bien être sur la face extérieure que sur la face intérieure du côté de la lame de gaz. On trouve des avantages à le disposer de préférence sur la face intérieure : une épaisseur moindre sera nécessaire puisqu'il n'aura pas besoin de résister aux chocs ou éraflures externes, le pont thermique en périphérie de vitrage sera amoindri, son collage notamment s'il est en aluminium est parfaitement maîtrisé sur le verre quelle que soit la matière plastique du profilé utilisée, il peut enfin favoriser la liaison électrique avec des éléments électriques prévus à l'intérieur du vitrage.This coating can be both on the outside and on the inside of the side of the gas blade. There are advantages to having it preferably on the inside: a lesser thickness will be necessary since it will not need to withstand external shocks or scratches, the thermal bridge at the periphery of the glazing will be reduced, its bonding particularly it is aluminum is perfectly controlled on the glass regardless of the plastic of the profile used, it can finally promote the electrical connection with electrical elements provided inside the glazing.

Selon une caractéristique, l'intercalaire présente une résistance linéique au flambage d'au moins 400 N/m. Afin d'assurer cette résistance, le profilé plat doit présenter une épaisseur d'au moins 0,1 mm lorsqu'il est constitué entièrement d'inox, d'au moins 0,15 mm lorsqu'il est entièrement en aluminium, et d'au moins 0,25 mm lorsqu'il est en matière thermoplastique armé de fibres de renforcement.According to one characteristic, the interlayer has a linear resistance to buckling of at least 400 N / m. In order to ensure this resistance, the flat profile must have a thickness of at least 0.1 mm when it is entirely made of stainless steel, at least 0.15 mm when it is entirely made of aluminum, and at least 0.25 mm when it is made of thermoplastic material reinforced with reinforcing fibers.

Avantageusement, les moyens de solidarisation de l'intercalaire contre le vitrage sont imperméables à l'eau, ils sont constitués par un adhésif du type colle qui résiste à des contraintes à l'arrachement d'au moins 0,45 Mpa.Advantageously, the securing means of the interlayer against the glazing are impermeable to water, they are constituted by a glue-type adhesive which withstands stripping stresses of at least 0.45 MPa.

Selon une autre caractéristique, les extrémités libres du profilé sensiblement plat sont assemblées pour ceinturer la totalité ou une partie du vitrage de façon que l'une des extrémités recouvre l'autre, ou une extrémité dudit autre profilé, des moyens d'étanchéité complémentaires étant prévus pour obturer des sections latérales rendues ouvertes par le recouvrement.According to another characteristic, the free ends of the substantially flat profile are assembled to surround all or part of the glazing so that one end covers the other, or one end of said other profile, complementary sealing means being intended to seal lateral sections made open by the covering.

En variante, afin de ceinturer la totalité du vitrage, les extrémités libres du profilé sensiblement plat présentent des formes complémentaires adaptées à coopérer mutuellement pour réaliser leur assemblage selon un aboutement. Un ruban adhésif ou de la colle étanche aux gaz et à la vapeur d'eau sera de préférence appliqué sur la zone d'aboutement.Alternatively, in order to surround the entire glazing, the free ends of the substantially flat profile have complementary shapes adapted to cooperate mutually to achieve their assembly according to an abutment. Adhesive tape or gas and steam-tight glue will preferably be applied to the abutment area.

Le vitrage isolant peut présenter une forme complexe, en particulier avec des parties courbes, auxquelles l'intercalaire plat est parfaitement adapté car il peut par sa flexibilité aisément épouser les courbes du vitrage.The insulating glazing may have a complex shape, particularly with curved parts, to which the flat interlayer is perfectly adapted because it can by its flexibility easily marry the curves of the glazing.

Selon une autre caractéristique, l'une et/ou l'autre face de l'intercalaire présente des éléments fonctionnels structurés par formage, ou rapportés de manière solidaire.According to another characteristic, one and / or the other face of the spacer has formally structured, or integrally attached, functional elements.

Ainsi, il est possible de conformer le profilé selon des formes bien précises. On peut avant sa pose le former par laminage ou autre moyen adapté pour intégrer des éléments variés dans un but fonctionnel. A titre d'exemple, il est possible de structurer sur les faces du profilé des plots, des bossages en creux ou en bosses, ponctuels ou en continu, disposés selon deux bandes parallèles par exemple, ou en quinconce, en prévoyant des arrêts dans les angles tels que des poinçons, stries ou prédécoupes.Thus, it is possible to conform the profile into specific shapes. It can be formed before rolling by rolling or other suitable means to integrate various elements for a functional purpose. For example, it is possible to structure on the faces of the section studs, indentations or bosses, punctually or continuously, arranged in two parallel bands for example, or staggered, providing for stops in the angles such as punches, streaks or pre-cuts.

Les plots peuvent notamment servir d'éléments de retenue pour la fixation de croisillons installés dans la lame de gaz, ces croisillons ayant une fonction décorative.The studs may in particular serve as retaining elements for fixing braces installed in the gas strip, these braces having a decorative function.

Si ces plots sont disposés vers l'intérieur du vitrage et selon au moins deux bandes parallèles, ils peuvent servir d'éléments de guidage et de calage d'au moins une feuille de verre additionnelle pour la fabrication d'un vitrage triple, voire quadruple. Mais ils peuvent également servir d'éléments de maintien d'une feuille de verre qui, ainsi se reposant sur ces éléments, permet une communication entre les différentes lames d'air du vitrage. Ces éléments, s'ils ont une fonctionnalité vers l'extérieur du vitrage, peuvent également favoriser le montage par emboîtement, le calage, le blocage ou l'assemblage du vitrage dans la feuillure de la fenêtre ou avec des vitrages ou parois voisins, ou encore ces éléments peuvent constituer un chemin de coopération avec un rail pour une porte coulissante.If these pads are arranged towards the inside of the glazing and according to at least two parallel strips, they can serve as guiding and wedging elements of at least one additional glass sheet for the manufacture of a triple or quadruple glazing. But they can also serve as holding elements of a glass sheet which, thus resting on these elements, allows communication between the different air blades of the glazing. These elements, if they have a function towards the outside of the glazing, can also favor the assembly by interlocking, the wedging, the blocking or the assembly of the glazing in the rabbet of the window or with neighboring windows or walls, or still these elements can constitute a way of cooperation with a rail for a sliding door.

Bien entendu, on peut envisager l'ajout d'éléments supplémentaires sur le profilé par d'autres moyens selon la nature du matériau du profilé, ainsi par collage, soudage ou rivetage sans pour autant modifier l'intégrité du profilé, quitte à la rétablir si elle est modifiée. Aussi, par le greffage de parties supplémentaires on pourra constituer des inserts améliorant encore la rigidité et l'inertie du profilé assemblant le vitrage, ou bien contribuant à sa mise en oeuvre, notamment son montage dans les feuillures.Of course, it is possible to envisage the addition of additional elements to the profile by other means depending on the nature of the profile material, thus by gluing, welding or riveting without modifying the integrity of the profile, even if it means restoring it. if it is modified. Also, by grafting additional parts can be formed inserts further improving the rigidity and inertia of the profile assembling the glazing, or contributing to its implementation, including its mounting in the rabbets.

Il s'agira également d'apports de matières supplémentaires par des plots de matière plastique, par l'extrusion de rainures ou lèvres profilées d'étanchéité ou de décoration.It will also involve additions of additional materials by plastic pads, by extrusion grooves or contoured sealing lips or decoration.

Outre ces ajouts, il est tout à fait envisageable d'appliquer au préalable sur le profilé un traitement anti-corrosion ou une peinture ou un laquage décoratif, également d'estamper ou d'imprimer tous marquages ou informations en vue par exemple de fournir une traçabilité du vitrage fabriqué.In addition to these additions, it is quite possible to apply beforehand on the profile anti-corrosion treatment or paint or decorative lacquering, also to stamp or print any markings or information for example to provide a traceability of the glazing manufactured.

L'intercalaire, de forme sensiblement plate, peut présenter des cavités, des doubles parois pouvant constituer ou loger des fonctionnalités, par exemple des breathing tubes (tubes autorisant l'équilibrage des pressions entre l'intérieur et l'extérieur du vitrage sans convection).The spacer, of substantially flat shape, may have cavities, double walls may constitute or house features, for example breathing tubes (tubes allowing the balancing of pressures between the inside and outside of the glazing without convection) .

L'intercalaire de l'invention comporte avantageusement une ou plusieurs des fonctionnalités suivantes :

  • il contient du desséchant, notamment dans une cavité intégrée dans la forme de l'intercalaire ou rapportée sur l'intercalaire ;
  • il comprend des moyens de commande, de transmission mécanique, de connexion électrique (fils électriques, éléments conducteurs de chauffage des bords du vitrage, circuits imprimés), la sortie des conducteurs s'effectuant par exemple au niveau de la zone d'aboutement ;
  • il intègre un store vénitien installé dans la lame de gaz ;
  • il intègre un moyen de mesure du taux d'humidité dans la lame de gaz, afin de prévoir le moment où la restauration du vitrage par démontage, lavage, remontage, régénération du desséchant, est nécessaire.
The interlayer of the invention advantageously comprises one or more of the following functionalities:
  • it contains desiccant, especially in a cavity integrated in the form of the interlayer or reported on the insert;
  • it comprises control means, mechanical transmission, electrical connection (electrical wires, conductive heating elements, edges of the glazing, printed circuits), the output of the conductors taking place for example at the abutment area;
  • it incorporates a venetian blind installed in the gas blade;
  • it incorporates a means of measuring the moisture content in the gas strip, to predict the moment when the restoration of the glazing by disassembly, washing, reassembly, regeneration of the desiccant is necessary.

Il est particulièrement avantageux, grâce à l'invention, d'associer undit profilé sensiblement plat à trois des quatre côtés du vitrage, d'installer l'une des fonctionnalités précitées par le côté libre du vitrage, puis de coller sur celui-ci undit profilé sensiblement plat.It is particularly advantageous, thanks to the invention, to associate undit substantially flat profile to three of the four sides of the glazing, to install one of the aforementioned functionalities by the free side of the glazing, then to stick on it. substantially flat profile.

Dans un mode de réalisation, l'intercalaire comporte au moins un trou afin de pouvoir par exemple accoler une cartouche de desséchant, ou une cartouche de gaz de manière à remplir de gaz l'espace entre les feuilles de verre, également pouvoir réaliser un équilibre de pression lorsque le vitrage a été fabriqué dans un endroit où la pression atmosphérique est différente de celle de l'endroit de livraison, ou encore le ou les trous peuvent permettre une circulation d'air contrôlée entre les feuilles de verre de manière à constituer un vitrage respirant bien utile par exemple pour une porte de four. Ce trou peut être réalisé dans le profilé sensiblement plat, ou dans l'autre profilé, ou dans les deux, les deux trous étant avantageusement, dans ce dernier cas, en vis-à-vis l'un de l'autre. Le trou peut être en communication directe avec la lame de gaz, ou non (par exemple lorsqu'il s'agit d'une section d'extrémité de profilé creux, dont l'étanchéité est assurée par recouvrement avec un profilé sensiblement plat). Le trou peut être traversant ou non ; ainsi il peut ne résulter que de l'absence locale de la couche étanche, aluminium ou autre, mais non de la couche sous-jacente, éventuellement perméable aux gaz.In one embodiment, the interlayer has at least one hole in order to be able for example to attach a desiccant cartridge, or a gas cartridge so as to fill the space between the glass sheets with gas, also to be able to achieve an equilibrium pressure when the glazing has been manufactured in a place where the atmospheric pressure is different from that of the delivery location, or the hole or holes may allow controlled air circulation between the glass sheets so as to constitute a breathable glazing very useful for example for an oven door. This hole can be made in the substantially flat profile, or in the other profile, or in both, the two holes being advantageously, in the latter case, vis-à-vis one of the other. The hole may be in direct communication with the gas strip, or not (for example when it is a hollow section end section, the sealing is provided by overlapping with a substantially flat profile). The hole can be through or not; thus it can result only from the local absence of the waterproof layer, aluminum or other, but not the underlying layer, possibly permeable to gases.

Ce trou peut être obtenu par tout moyen adapté de perçage ou par un élément rapporté sur le profilé pourvu d'un poinçon en effectuant un perçage à l'endroit indiqué, soit par exemple par une empreinte conformée préalablement sur le profilé, soit par le positionnement exact de l'élément rapporté grâce à des bossages de repérage conformés préalablement sur le profilé comme expliqué précédemment. L'empreinte de perçage peut par exemple être du type de celle aménagée dans les canettes en aluminium de boisson du commerce; une fois le perçage effectué, la portion de matière repoussée reste attachée au profilé.This hole can be obtained by any suitable means of drilling or by an element attached to the profile provided with a punch by drilling at the indicated location, for example by a previously shaped impression on the profile, or by the positioning exact of the reported element thanks to locating bosses previously shaped on the profile as explained above. The piercing footprint may for example be of the type of that arranged in commercial aluminum drink cans; once the drilling is done, the portion of repoussée material remains attached to the profile.

Si le trou a été réalisé pour l'insertion du gaz, il convient ensuite de le refermer de manière étanche, par exemple par un feuillard étanche au gaz, qu'on fixe mécaniquement contre le profilé par divers moyens tels qu'à l'aide d'un adhésif adapté et assurant l'étanchéité.If the hole has been made for the insertion of the gas, it is then necessary to close it in a sealed manner, for example by a gas-tight strip, which is mechanically fixed against the profile by various means such as using a suitable adhesive and sealing.

Ainsi, le ruban peut être collé par l'une de ses faces contre la face du feuillard destinée à être appliquée contre le profilé troué. Le ruban comporte sur sa face opposée un film protecteur anti-adhérent qui permet lors de l'application du feuillard contre le profilé de modifier la position dudit feuillard de façon à l'agencer correctement sur l'endroit souhaité. Une languette est prévue latéralement au ruban, elle peut être tirée afin d'ôter le film protecteur pour découvrir l'adhésif qui assurera le collage du feuillard contre le profilé.Thus, the tape can be glued by one of its faces against the face of the strip intended to be applied against the perforated profile. The ribbon has on its opposite side a non-stick protective film which allows the application of the strip against the profile to change the position of said strip so as to arrange it correctly on the desired location. A tab is provided laterally to the ribbon, it can be pulled to remove the protective film to discover the adhesive that will ensure the bonding of the strip against the profile.

L'invention englobe également un vitrage particulier, dans lequel les bords desdites deux feuilles de verre sont au moins en partie décalés l'un par rapport à l'autre. Il est envisageable qu'un seul côté d'une des deux feuilles dépasse du côté correspondant de l'autre des deux feuilles, l'espace du décalage étant occupé par ledit autre profilé, sur toute la longueur du côté. Il est également possible que l'une desdites deux feuilles de verre soit un feuilleté dont la feuille orientée vers l'extérieur du vitrage soit de plus grandes dimensions que les autres constituants du feuilleté, sur la tranche desquels d'une part, ainsi que sur celle de l'autre desdites deux feuilles de verre d'autre part, undit profilé sensiblement plat est collé.The invention also encompasses a particular glazing unit, in which the edges of said two glass sheets are at least partly offset with respect to each other. It is conceivable that only one side of one of the two sheets protrudes from the corresponding side of the other of the two sheets, the gap space being occupied by said other profile, over the entire length of the side. It is also possible for one of said two sheets of glass to be a laminate whose sheet oriented towards the outside of the glazing is of larger dimensions than the other constituents of the laminate, on the edge of which, on the one hand, as well as on that of the other of said two sheets of glass on the other hand, a substantially flat profile is glued.

Un autre vitrage isolant particulier conforme à l'invention se distingue par le fait que l'une au moins desdites deux feuilles de verre comporte un trou traversant, que les bords de ce trou sont considérés comme faisant partie de ladite première partie du pourtour du vitrage, un profilé sensiblement plat étant plaqué contre et collé de manière étanche à ces bords. Si le trou traversant est un disque, le profilé plat est conformé en un tube dans lequel prennent place, le cas échéant, des moyens de fixation du vitrage à une structure de bâtiment ou autre.Another particular insulating glazing according to the invention is distinguished by the fact that at least one of said two sheets of glass has a through-hole, that the edges of this hole are considered to be part of said first part of the periphery of the glazing. , a substantially flat profile being pressed against and sealingly adhered to these edges. If the through hole is a disk, the flat section is shaped as a tube in which, if necessary, the glazing attachment means to a building structure or the like.

Enfin, le fait que l'intercalaire soit disposé sur les tranches des feuilles de verre laisse libre la surface périphérique interne des feuilles de verre proche des tranches, alors que dans l'art antérieur, cette surface est occupée par l'intercalaire. Il est ainsi possible d'utiliser cette surface libre pour fixer des éléments par exemple par collage, tels que des croisillons décoratifs. Lorsque le vitrage est incorporé à un cadre de fenêtre, la fixation est invisible du fait qu'elle se trouve au niveau de la feuillure de la fenêtre, en dehors du clair de vue.Finally, the fact that the interlayer is arranged on the slices of the glass sheets leaves free the inner peripheral surface of the glass sheets close to the slices, while in the prior art, this surface is occupied by the interlayer. It is thus possible to use this free surface to fix elements for example by gluing, such as decorative braces. When the glazing is incorporated in a window frame, the fixing is invisible because it is at the level of the rabbet of the window, outside the clear view.

Un premier procédé de fabrication de l'invention est caractérisé en ce que :

  • on assemble ledit autre profilé pourvu le cas échéant de ses moyens de solidarisation au vitrage et les deux feuilles de verre , maintenues parallèles et espacées ;
  • on met en place la face interne du profilé sensiblement plat pourvu des moyens de solidarisation contre les tranches des feuilles de verre et, le cas échéant, sur la face externe de l'autre profilé ;
  • on applique quasi-instantanément lors de la mise en place du profilé sensiblement plat des moyens de pression sur la face externe de celui-ci de façon à assurer son adhésion avec les tranches des feuilles de verre et, le cas échéant, avec l'autre profilé ; et
  • on assemble solidairement les deux extrémités du profilé sensiblement plat, soit l'une avec l'autre, soit chacune d'elles avec une extrémité de l'autre profilé.
A first manufacturing method of the invention is characterized in that:
  • said other section is provided provided optionally its means of attachment to the glazing and the two glass sheets, kept parallel and spaced apart;
  • the inner face of the substantially flat profile is provided provided with fastening means against the slices of the glass sheets and, where appropriate, on the outer face of the other section;
  • it is applied almost instantaneously when placing the substantially flat profile of the pressure means on the outer face thereof so as to ensure its adhesion with the slices of the glass sheets and, if necessary, with the other shaped; and
  • the two ends of the substantially flat profile are joined together, either with each other or with each end with the other section.

Selon une caractéristique, le profilé sensiblement plat se présente avant sa mise en place sous la forme d'un ruban bobiné qui est destiné à être déroulé, étiré et coupé à la longueur voulue, tandis que les moyens de solidarisation du type colle sont déposés sur le ruban en étirement par des moyens d'injection.According to one feature, the substantially flat profile is present before its introduction in the form of a wound tape which is intended to be unwound, stretched and cut to the desired length, while the glue-type fastening means are deposited on the ribbon stretching by injection means.

Avantageusement, le desséchant est déposé sur le ruban en étirement lors de l'application des moyens de solidarisation.Advantageously, the desiccant is deposited on the stretching tape during the application of the securing means.

Selon une autre caractéristique, la mise en place du profilé sensiblement plat s'effectue en l'appliquant par compression en un point d'amorçage et contre les tranches d'un premier côté du vitrage, le ceinturage s'effectuant à partir de ce point d'amorçage et la mise en place du ruban sur les angles du vitrage étant réalisée pour un profilé sensiblement plat à base de matière thermoplastique en chauffant préalablement sa face externe afin d'aider à son pliage autour des angles et d'épouser parfaitement leur contour.According to another feature, the establishment of the substantially flat profile is effected by applying it by compression to a priming point and against the slices of a first side of the glazing, the belting being effected from this point priming and positioning of the ribbon on the corners of the glazing being made for a substantially flat profile based on thermoplastic material by heating its outer face beforehand to help its folding around the corners and marry perfectly their outline .

De préférence, le point d'amorçage est situé en un milieu de côté du vitrage de façon à appliquer et comprimer le profilé sensiblement plat simultanément dans deux directions opposées, ce qui permet de gagner en temps de fabrication.Preferably, the initiation point is located in a side of the glazing side so as to apply and compress the substantially flat profile simultaneously in two opposite directions, which saves manufacturing time.

En variante, le point d'amorçage peut être situé plutôt au niveau d'un angle du vitrage.Alternatively, the priming point may be located rather at an angle of the glazing.

Dans une variante de réalisation du ceinturage du vitrage, la mise en place du profilé sensiblement plat s'effectue en appliquant deux rubans par compression en deux points d'amorçage à l'aide de moyens de distribution et de compression, et le ceinturage s'effectue à partir de ces points d'amorçage par des mouvements de translation du vitrage et/ou des moyens de distribution. Cette variante permet très avantageusement, combinée avec le profilé de l'invention, de fournir un vitrage présentant une forme complexe, en particulier avec des parties courbes.In an alternative embodiment of the glazing surround, the establishment of the substantially flat profile is effected by applying two ribbons by compression at two points of initiation using means of distribution and compression, and the belting s' performs from these points of initiation by translational movements of the glazing and / or distribution means. This variant allows very advantageously, combined with the profile of the invention, to provide a glazing having a complex shape, in particular with curved parts.

De manière pratique, toutes les opérations de fabrication du vitrage peuvent être réalisées dans une chambre remplie du gaz devant être contenu dans le vitrage. Toutefois en variante, il est possible d'envisager un dispositif d'alimentation en gaz qui est inséré entre les deux feuilles de verre pour délivrer du gaz tandis que le ceinturage du vitrage est effectué, et qui est retiré juste avant la fin du ceinturage.Conveniently, all glazing manufacturing operations can be performed in a chamber filled with the gas to be contained in the glazing. Alternatively, it is possible to envisage a gas supply device which is inserted between the two glass sheets to deliver gas while the glazing surround is performed, and which is removed just before the end of the belting.

Un second procédé de fabrication de l'invention est caractérisé en ce que :

  • on maintient deux feuilles de verre parallèles et espacées ;
  • on met en place la face interne du profilé sensiblement plat pourvu des moyens de solidarisation au verre contre les tranches des feuilles de verre sur la totalité du pourtour du vitrage ;
  • on applique quasi-instantanément lors de la mise en place du profilé sensiblement plat des moyens de pression sur sa face externe de manière à assurer son adhésion avec les tranches des feuilles de verre ;
  • après ceinturage de la totalité du pourtour du vitrage, on assemble solidairement les deux extrémités du profilé sensiblement plat ;
  • on obture de manière étanche un trou présenté par le profilé sensiblement plat au moyen d'undit autre profilé, le trou étant éventuellement foré par le rapprochement du profilé sensiblement plat et de l'autre profilé conformé à cet effet avec un moyen autoforeur, cette opération requérant la mise en oeuvre de moyens d'adhésion dudit autre profilé au profilé sensiblement plat, tels que ruban adhésif, éventuellement associé à une colle injectée.
A second manufacturing method of the invention is characterized in that:
  • two parallel and spaced sheets of glass are kept;
  • placing the inner face of the substantially flat profile provided with the glass securing means against the slices of the glass sheets on the entire periphery of the glazing;
  • it is applied almost instantaneously when placing the substantially flat profile of the pressure means on its outer face so as to ensure its adhesion with the slices of the glass sheets;
  • after girdling of the entire periphery of the glazing unit, the two ends of the substantially flat profile are joined together;
  • sealing a hole presented by the substantially flat profile by means of said other profile, the hole possibly being drilled by the approximation of the substantially flat profile and the other section formed for this purpose with a self-drilling means, this operation requiring the implementation of adhesion means of said other profile substantially flat profile, such as adhesive tape, optionally associated with an injected glue.

D'autres caractéristiques et avantages de l'invention apparaîtront à la lecture de la description qui suit et en regard des dessins annexés sur lesquels :

  • la figure 1a est une vue en coupe d'un vitrage isolant selon l'invention, sur laquelle le profilé creux n'apparaît pas;
  • la figure 1b est une représentation schématique partielle en coupe d'un vitrage isolant selon l'invention, dans lequel le profilé creux est directement collé sur les tranches des feuilles de verre ;
  • la figure 1c est une représentation schématique partielle en coupe d'un vitrage isolant selon l'invention, dans lequel le profilé creux est collé sur les tranches des feuilles de verre avec interposition d'un profilé sensiblement plat ;
  • la figure 1d est une représentation schématique partielle en coupe d'un vitrage isolant selon l'invention, dans lequel le profilé creux est collé entre les feuilles de verre ;
  • la figure 2 illustre une vue schématique en élévation du dispositif d'association du profilé sensiblement plat aux feuilles de verre ;
  • la figure 3 représente la figure 2 au cours d'une étape du procédé de fabrication ;
  • la figure 4 est une vue agrandie de l'assemblage des deux extrémités libres du profilé plat selon l'invention après ceinturage complet du vitrage ;
  • les figures 5a à 5c illustrent une variante de réalisation du ceinturage du vitrage, dans une configuration dans laquelle le profilé creux est intégralement situé dans l'espace délimité par les feuilles de verre ;
  • la figure 6 montre une courbe traduisant le rapport entre la flèche maximum d'un vitrage usuel de l'art antérieur et la flèche maximum d'un vitrage de l'invention pour une force donnée, en fonction de l'épaisseur de la lame d'air.
Other features and advantages of the invention will appear on reading the description which follows and with reference to the appended drawings in which:
  • Figure 1a is a sectional view of an insulating glazing unit according to the invention, on which the hollow profile does not appear;
  • Figure 1b is a partial schematic sectional representation of an insulating glazing unit according to the invention, wherein the hollow section is directly bonded to the slices of the glass sheets;
  • Figure 1c is a partial schematic sectional representation of an insulating glazing unit according to the invention, wherein the hollow profile is bonded to the edges of the glass sheets with the interposition of a substantially flat profile;
  • Figure 1d is a partial schematic sectional representation of an insulating glazing unit according to the invention, in which the hollow section is bonded between the glass sheets;
  • Figure 2 illustrates a schematic elevational view of the association device of the substantially flat profile to the glass sheets;
  • Figure 3 shows Figure 2 during a step of the manufacturing process;
  • Figure 4 is an enlarged view of the assembly of the two free ends of the flat profile according to the invention after complete surround of the glazing;
  • Figures 5a to 5c illustrate an alternative embodiment of the glazing surround, in a configuration in which the hollow section is integrally located in the space defined by the glass sheets;
  • FIG. 6 shows a curve representing the ratio between the maximum deflection of a conventional glazing of the prior art and the maximum deflection of a glazing unit of the invention for a given force, as a function of the thickness of the glass plate. 'air.

La figure 1a illustre un vitrage isolant simple 1 obtenu par un procédé de fabrication qui sera décrit plus loin en regard de son dispositif visible à la figure 2.FIG. 1a illustrates a single insulating glazing unit 1 obtained by a manufacturing method which will be described later with regard to its device visible in FIG. 2.

Le vitrage 1 comporte deux feuilles de verre 10 et 11 espacées par une lame de gaz 12, un intercalaire 2 qui sert à espacer les deux feuilles de verre et a pour rôle d'assurer le maintien mécanique de l'ensemble du vitrage, ainsi que des moyens d'étanchéité 3 destinés à rendre étanche le vitrage à l'eau liquide, aux solvants et à la vapeur d'eau.The glazing 1 comprises two sheets of glass 10 and 11 spaced apart by a gas strip 12, an insert 2 which serves to space the two sheets of glass and has the role of ensuring the mechanical maintenance of the entire glazing, as well as sealing means 3 for sealing the glazing with liquid water, solvents and water vapor.

L'intercalaire 2 se présente sous la forme d'un profilé sensiblement plat d'environ 1 mm d'épaisseur et de section sensiblement parallélipédique. Ce profilé a avantageusement une faible inertie mécanique, c'est-à-dire qu'il peut être aisément enroulé en présentant un faible rayon d'enroulement de 10 cm par exemple.The insert 2 is in the form of a substantially flat profile approximately 1 mm thick and of substantially parallelepiped section. This profile advantageously has a low mechanical inertia, that is to say that it can be easily wound by having a small winding radius of 10 cm for example.

Le profilé entoure le pourtour du vitrage. Il est disposé à la manière d'un ruban sur les tranches 10a et 11a des feuilles de verre et garantit l'assemblage mécanique du vitrage grâce à des moyens de solidarisation 4 qui assurent sa totale adhésion au verre.The profile surrounds the perimeter of the glazing. It is arranged in the manner of a ribbon on the slices 10a and 11a of the glass sheets and guarantees the mechanical assembly of the glazing through securing means 4 which ensure its total adhesion to the glass.

Le profilé est suffisamment rigide pour réaliser la fonction de maintien mécanique des deux feuilles de verre espacées. Sa rigidité est définie par la nature même de son matériau constitutif, dont la résistance linéique au flambage doit être au moins de 400 N/m.The profile is rigid enough to perform the mechanical holding function of the two spaced glass sheets. Its rigidity is defined by the very nature of its constituent material, whose linear buckling resistance must be at least 400 N / m.

Par ailleurs, la nature du matériau dudit profilé est également choisie de façon qu'au cours du procédé de fabrication du vitrage, le profilé puisse présenter suffisamment de souplesse pour que soit effectué l'opération de ceinturage des tranches de verre, en particulier lors du bordage des angles.Furthermore, the nature of the material of said profile is also chosen so that during the glass manufacturing process, the profile may have sufficient flexibility for the operation of belting the glass slices, in particular during the curling angles.

Dans un premier mode de réalisation, l'intercalaire est entièrement métallique, le matériau choisi étant préférentiellement de l'inox ou bien de l'aluminium. Au cours du procédé, le bordage des angles est effectué par pliage à l'aide de machines bien connues de l'homme de l'art spécialisé dans la transformation de matériaux métalliques.In a first embodiment, the spacer is entirely metallic, the material chosen being preferably stainless steel or aluminum. During the process, the edges are bent by means of machines well known to those skilled in the art of processing metal materials.

De manière à garantir une résistance linéique au flambage minimale de 400N/m, l'intercalaire devra présenter une épaisseur d'au moins 0,1 mm pour de l'inox, et de 0,15 mm pour de l'aluminium.In order to guarantee a minimum linear resistance to buckling of 400N / m, the interlayer must have a thickness of at least 0.1 mm for stainless steel and 0.15 mm for aluminum.

Dans un second mode de réalisation et préférentiel de l'invention, l'intercalaire 2 est à base de matière plastique armée ou non de fibres de renforcement coupées ou continues. Ainsi, un matériau peut être du styrène acrylonitrile (SAN) associé à des fibres de verre coupées, commercialisé par exemple sous le nom LURAN® par la société BASF, ou bien du polypropylène armé de fibres de verre continues, vendu sous le nom TWINTEX® par la société VETROTEX.In a second and preferred embodiment of the invention, the interlayer 2 is based on plastic material with or without reinforcement fibers cut or continuous. Thus, a material may be styrene acrylonitrile (SAN) associated with cut glass fibers, sold for example under the name LURAN® by BASF, or polypropylene reinforced with continuous glass fibers, sold under the name TWINTEX® by the company VETROTEX.

Il est également possible de réaliser l'intercalaire à partir d'une combinaison des matériaux tels que la matière plastique et le métal pour constituer par exemple un intercalaire avec une épaisseur de matière plastique solidarisée avec une épaisseur de métal.It is also possible to make the interlayer from a combination of materials such as plastic and metal to form for example a spacer with a thickness of plastic material secured to a metal thickness.

Notons que dans le cas d'un matériau plastique qui est thermofusible, le bordage des angles du vitrage opéré par pliage après ramollissement de la matière, est effectué plus aisément qu'avec un matériau entièrement métallique.Note that in the case of a plastic material that is hot melt, the edge of the corners of the glazing made by folding after softening of the material, is performed more easily than with a completely metallic material.

Par ailleurs, avec l'utilisation de matière plastique, il peut très avantageusement être prévu d'intégrer intrinsèquement, en partie ou en totalité, le desséchant au profilé, ce qui est impossible avec du métal. Le desséchant peut être un tamis moléculaire tel que de la zéolithe en poudre, dont la proportion peut atteindre jusqu'à 20% en masse ou environ 10% en volume. La quantité du desséchant est fonction de la durée de vie que l'on veut attribuer au vitrage.Moreover, with the use of plastic material, it can very advantageously be provided to integrate intrinsically, in part or in full, the desiccant to the profile, which is impossible with metal. The desiccant may be a molecular sieve such as zeolite powder, which may be up to 20% by weight or about 10% by volume. The amount of desiccant is a function of the lifetime that we want to assign to the glazing.

Enfin, la matière plastique étant bien moins conductrice de chaleur que le métal, l'isolation thermique de l'ensemble du vitrage n'en est que meilleure lorsque le vitrage est par exemple exposé à un fort ensoleillement.Finally, the plastic material being much less heat-conducting than the metal, the thermal insulation of the entire glazing is only better when the glazing is for example exposed to strong sunlight.

Quant à l'addition de fibres de verre à la matière plastique, il en résulte un coefficient de dilatation thermique du matériau qui est bien plus faible que celui d'un plastique pur et qui devient proche du coefficient du verre, ce qui engendre, lors d'une variation thermique de la lame de gaz, une force de cisaillement moindre sur les moyens de solidarisation 4.As for the addition of glass fibers to the plastic, this results in a thermal expansion coefficient of the material which is much lower than that of a pure plastic and which becomes close to the glass coefficient, which generates, when a thermal variation of the gas blade, a lower shear force on the securing means 4.

Afin d'assurer une résistance linéique de 400 N/m, l'intercalaire 2 présente une épaisseur d'au moins 0,2 mm lorsqu'il est constitué de matière thermoplastique et de fibres de renforcement.In order to ensure a linear resistance of 400 N / m, the spacer 2 has a thickness of at least 0.2 mm when it is made of thermoplastic material and reinforcing fibers.

La largeur de l'intercalaire 2 est adaptée à l'épaisseur totale du vitrage qui peut être multiple en comprenant plusieurs feuilles de verre espacées par des lames de gaz. Avantageusement, l'intercalaire de l'invention ne nécessite la connaissance que de la largeur totale du vitrage et non des distances de séparation des feuilles de verre. En effet, les distances de séparation pour un vitrage multiple peuvent varier, ce qui entraîne nécessairement dans le cas de l'utilisation d'intercalaires conformes à ceux de l'état de la technique d'avoir à disposition pour la fabrication du vitrage plusieurs intercalaires pour les différentes séparations, et différentes largeurs d'intercalaires selon les distances de séparation.The width of the spacer 2 is adapted to the total thickness of the glazing which can be multiple by including several glass sheets spaced by gas strips. Advantageously, the interlayer of the invention only requires knowledge of the total width of the glazing and not the separation distances of the glass sheets. Indeed, the separation distances for a multiple glazing may vary, which necessarily entails in the case of the use of spacers according to those of the state of the art to have available for the manufacture of glazing several interleaves for the different separations, and different widths of inserts according to separation distances.

Pour tout vitrage, il convient donc simplement de disposer selon l'invention d'un intercalaire ou profilé d'une seule largeur correspondant à celle totale du vitrage quelles que soient le nombre de séparations isolantes internes de ce vitrage et la largeur de ces séparations.For all glazing, it is therefore simply necessary to have according to the invention a spacer or profile of a single width corresponding to the total glazing regardless of the number of internal insulating separations of the glazing and the width of these separations.

On a mis en évidence que le vitrage de l'invention avec son intercalaire disposé sur les tranches des feuilles de verre ne perd pas en rigidité mais au contraire celle-ci est encore améliorée en comparaison avec un vitrage usuel de l'art antérieur présentant son intercalaire disposé entre les faces internes des feuilles de verre.It has been demonstrated that the glazing of the invention with its interlayer disposed on the edges of the glass sheets does not lose rigidity, but on the contrary it is further improved in comparison with a conventional glazing of the prior art presenting its interlayer disposed between the inner faces of the glass sheets.

Pour une même surface des feuilles de verre, une même épaisseur de verre et une même épaisseur de lame d'air, a été calculé le rapport des flèches du vitrage de l'invention et respectivement d'un vitrage usuel en fonction de l'épaisseur de la lame d'air. A cet effet, est appliquée sur chacun des vitrages une force donnée, est alors mesurée la flèche maximale de chaque vitrage puis est calculé le rapport des flèches. Ce rapport égal à la flèche du vitrage usuel divisée par la flèche du vitrage de l'invention est toujours supérieur à 1, rendant compte d'une meilleure résistance à la flexion et donc d'une meilleure rigidité du vitrage de l'invention.For the same surface of the glass sheets, the same glass thickness and the same thickness of the air gap, the ratio of the arrows of the glazing of the invention and respectively of a conventional glazing as a function of the thickness has been calculated. of the air knife. For this purpose, is applied to each glazing a given force, is then measured the maximum deflection of each glazing and is then calculated the ratio of the arrows. This ratio equal to the deflection of the usual glazing divided by the deflection of the glazing unit of the invention is always greater than 1, reflecting a better resistance to bending and therefore a better rigidity of the glazing unit of the invention.

La figure 6 illustre ce rapport en fonction de la lame d'air, l'intercalaire considéré pour le vitrage isolant de l'invention étant un profilé en aluminium de 0,5 mm. On voit que le rapport est toujours supérieur à 1, et est par exemple de 1,5 pour une lame d'air de 12 mm.FIG. 6 illustrates this ratio as a function of the air gap, the spacer considered for the insulating glazing unit of the invention being an aluminum profile of 0.5 mm. We see that the ratio is always greater than 1, and is for example 1.5 for a 12 mm air gap.

Selon l'invention, l'intercalaire ou le profilé 2 comprend une face interne 20 et une face externe opposée 21, la face interne 20 étant destinée à être plaquée, et maintenue, par ses bords dans le cas d'un vitrage isolant simple, contre les tranches 10a et 11 a des feuilles de verre grâce aux moyens de solidarisation 4.According to the invention, the insert or profile 2 comprises an inner face 20 and an opposite outer face 21, the inner face 20 being intended to be plated, and maintained, by its edges in the case of a single insulating glazing unit, against the slices 10a and 11a glass sheets through the securing means 4.

La face interne 20 du profilé possède dans sa partie centrale 22 et en regard avec la lame de gaz 12 les propriétés de celles d'un desséchant qui a pour but d'absorber les molécules d'eau qui peuvent être emprisonnées dans la lame de gaz. Ces propriétés de desséchant peuvent résulter de la nature du matériau de l'intercalaire, dont la composition même intègre un tamis moléculaire. En variante, l'élément desséchant sera plutôt obtenu par un dépôt de tamis moléculaire sur la partie centrale 22 avant la mise en place de l'intercalaire sur les tranches du vitrage, comme nous le verrons dans la suite de la description.The inner face 20 of the profile has in its central portion 22 and facing the gas blade 12 the properties of those of a desiccant which aims to absorb the water molecules that can be trapped in the gas blade . These desiccant properties can result from the nature of the interlayer material, whose composition itself incorporates a molecular sieve. Alternatively, the desiccant element will rather be obtained by a deposit of molecular sieve on the central portion 22 before the introduction of the spacer on the slices of the glazing, as we will see in the following description.

Les bords de la face interne 20 sont recouverts d'un adhésif qui constitue les moyens de solidarisation 4.The edges of the inner face 20 are covered with an adhesive which constitutes the securing means 4.

L'adhésif est du type colle; il est étanche aux gaz, à la vapeur d'eau. Des essais effectués conformément à la norme américaine ASTM 96-63T sur des échantillons de colle de 1,5 mm d'épaisseur ont montré qu'une colle présentant un coefficient de perméabilité à la vapeur d'eau de 35 g/24h.m2 tel que celui du silicone convient. Bien entendu, une colle ayant un coefficient de perméabilité de 4 g/24h.m2 comme le polyuréthane, ou même inférieur, convient davantage car l'étanchéité étant encore améliorée, une quantité moins importante de desséchant est alors à prévoir.The adhesive is of the glue type; it is impervious to gases, water vapor. Tests carried out in accordance with ASTM 96-63T standard on 1.5 mm thick adhesive samples showed that an adhesive with a water vapor permeability coefficient of 35 g / 24h.m 2 such as silicone is suitable. Of course, an adhesive having a permeability coefficient of 4 g / 24h.m 2, such as polyurethane, or even lower, is more suitable because the seal being further improved, a lesser amount of desiccant is then expected.

L'adhésif doit également résister au décollage par l'eau liquide, par les ultraviolets ainsi que par les tractions pouvant être exercées perpendiculairement aux faces du vitrage et nommées couramment contraintes au cisaillement, et par les tractions exercées parallèlement à la force du poids du vitrage. Une colle satisfaisante doit résister à des contraintes à l'arrachement d'au moins 0,45 MPa.The adhesive must also withstand the take-off by liquid water, ultraviolet light as well as traction that can be exerted perpendicularly to the faces of the glazing and commonly called shear stresses, and by the pulls exerted parallel to the force of the weight of the glazing . A satisfactory adhesive must withstand stripping stresses of at least 0.45 MPa.

Il sera également judicieux d'adapter la nature de l'adhésif aux ambiances d'utilisation du vitrage ; ainsi l'adhésif devra par exemple présenter une tenue en température suffisante pour l'application du vitrage à une porte d'un four électroménager.It will also be judicious to adapt the nature of the adhesive to the environments of use of the glazing; thus the adhesive must for example have a temperature resistance sufficient for the application of glazing to a door of an electric household oven.

De préférence, l'adhésif présente des propriétés de collage rapide, de l'ordre de quelques secondes; il s'agit d'un adhésif dont la prise s'effectue par réaction chimique, activée ou non par de la chaleur ou par une pression, ou bien s'effectue par refroidissement si l'adhésif est constitué d'une matière thermofusible du type hot-melt, par exemple à base de polyuréthane réticulable avec l'humidité de l'air.Preferably, the adhesive has fast gluing properties, of the order of a few seconds; it is an adhesive which is taken by chemical reaction, whether or not activated by heat or pressure, or is carried out by cooling if the adhesive consists of a hot-melt material of the type hot melt, for example based on polyurethane crosslinkable with the humidity of the air.

La face externe 21 de l'intercalaire en matière plastique renforcée est recouverte d'un revêtement de protection métallique 21 a du type feuillard en aluminium ou en inox présentant une épaisseur comprise par exemple entre 2 et 50 µm, ce revêtement constituant les moyens d'étanchéité 3. Outre son rôle d'étanchéité, le feuillard, en particulier lorsqu'il est en inox, protège efficacement le profilé contre l'abrasion, par exemple lors de sa manutention ou de son transport. Enfin, il favorise l'échange de chaleur avec la matière thermoplastique lorsqu'il s'agit de ramollir cette dernière pendant le procédé de fabrication.The outer face 21 of the interlayer made of reinforced plastic material is covered with a metallic protective coating 21a of the type of aluminum or stainless steel strip having a thickness of, for example, between 2 and 50 μm, this coating constituting the means for sealing 3. In addition to its sealing role, the strip, particularly when made of stainless steel, effectively protects the profile against abrasion, for example during its handling or transport. Finally, it promotes the exchange of heat with the thermoplastic material when it comes to soften the latter during the manufacturing process.

En variante, le revêtement métallique 21a pourrait être suffisamment large pour recouvrir la face externe 21 et être rabattu sur les bords de la face interne 20.Alternatively, the metal coating 21a could be large enough to cover the outer face 21 and be folded over the edges of the inner face 20.

Les chiffres donnés plus haut sur l'épaisseur de l'intercalaire selon la nature du matériau ou des matériaux utilisés sont fournis pour une résistance au flambage de 400 N/m linéaire, qui est une valeur classique pour les vitrages de dimensions les plus courants, à savoir 1,20 m par 0,50 m. Toutefois, pour élargir l'utilisation à des vitrages de dimensions plus importantes et/ou vitrages soumis à des conditions extrêmes de sollicitation, on préférera concevoir des vitrages dont l'intercalaire est apte à résister à une force de 5700 N par mètre linéaire. Afin de parvenir à une telle résistance au flambage, nous donnons ci-après un tableau indiquant le coefficient de sécurité établi par rapport à la référence de 5700 N/m en fonction des épaisseurs correspondantes à donner à l'intercalaire de l'invention selon le type de matériau. Coefficient de sécurité Styrène acrylonitrile (SAN) Aluminium Inox 1 0,50 mm 0,25 mm 0,20 mm 3 0,75 mm 0,40 mm 0,30 mm 4,5 0,90 mm 0,45 mm 0,35 mm The figures given above on the thickness of the interlayer according to the nature of the material or materials used are provided for a buckling resistance of 400 N / m linear, which is a classic value for glazing of the most common dimensions, namely 1.20 m by 0.50 m. However, to widen the use to glazing of larger dimensions and / or glazing subjected to extreme conditions of stress, it will be preferable to design glazings whose the interlayer is capable of withstanding a force of 5700 N per linear meter. In order to achieve such a buckling resistance, we give below a table indicating the safety factor established with respect to the reference of 5700 N / m as a function of the corresponding thicknesses to give to the interlayer of the invention according to the type of material. Safety coeficient Acrylonitrile Styrene (SAN) Aluminum Stainless steel 1 0.50 mm 0.25 mm 0.20 mm 3 0.75 mm 0.40 mm 0.30 mm 4.5 0.90 mm 0.45 mm 0.35 mm

L'intégration du profilé creux au vitrage isolant de l'invention est illustrée aux figures 1b à 1d.The integration of the hollow profile insulating glazing of the invention is illustrated in Figures 1b to 1d.

En référence à la figure 1b, le profilé creux 30 est collé par les moyens de solidarisation 5 sur les tranches des feuilles de verre 10 et 11. Ainsi la face interne 20 de l'intercalaire est une délimitation de la lame de gaz 12, de sorte que le tamis moléculaire desséchant contenu dans le profilé creux et non représenté soit actif vis-à-vis de la lame de gaz, par l'intermédiaire de communications 31 -trous, porosités,...- ménagées dans la face interne 20. Au besoin, ces communications 31 avec la lame de gaz sont dégagées par enlèvement local d'une éventuelle couche d'étanchéité dont serait munie le profilé 30. Les communications 31 sont de dimensions inférieures à celles du desséchant, fréquemment sous forme de granulés, afin de les retenir dans le profilé creux 30.With reference to FIG. 1b, the hollow section 30 is bonded by the securing means 5 to the slices of the glass sheets 10 and 11. Thus, the inner face 20 of the spacer is a delimitation of the gas strip 12, so that the desiccant molecular sieve contained in the hollow profile and not shown is active vis-à-vis the gas blade, through communications 31 -housing, porosity, ...- formed in the inner face 20. If necessary, these communications 31 with the gas strip are released by local removal of a possible sealing layer which would be provided with the profile 30. The communications 31 are smaller than those of the desiccant, frequently in the form of granules, so to retain them in the hollow section 30.

Les moyens de solidarisation 5 garantissent l'étanchéité requise entre la lame de gaz 12 et l'atmosphère extérieure.The securing means 5 ensure the required seal between the gas strip 12 and the outside atmosphere.

Le profilé creux est disposé sur la totalité ou une partie d'un côté rectiligne du vitrage isolant, en un tronçon unique ou en plusieurs tronçons d'une longueur indicative de 10 à 15 cm. On bouche éventuellement le profilé creux avec un matériau thermofusible à faible transmission d'humidité, tel que polyuréthane.The hollow section is disposed on all or part of a rectilinear side of the insulating glazing, in a single section or in several sections of a length indicative of 10 to 15 cm. The hollow section is optionally sealed with a hot-melt material with low moisture transmission, such as polyurethane.

Un profilé sensiblement plat non apparent sur la figure 1b est collé sur chacune des deux sections d'extrémité du profilé creux 30, qu'elle bouche ainsi de manière étanche, en association éventuelle avec le matériau thermofusible à faible transmission d'humidité précité.A substantially flat profile not shown in Figure 1b is bonded to each of the two end sections of the hollow profile 30, which it thus sealingly closes, possibly in combination with the hot melt material low moisture transmission aforementioned.

Le profilé plat 2 (voir figure 1a) comprend des moyens d'étanchéité, constitués comme décrit ci-dessus, d'une feuille d'aluminium 3, qui peut être orientée vers l'intérieur du vitrage, la colle 4 étant choisie pour coller l'aluminium au profilé creux 30 mais aussi aux tranches des feuilles de verre. Cette orientation des moyens d'étanchéité 3 présente l'avantage de permettre de conformer la face externe du profilé plat 2, par exemple en matière plastique, avec des stries pour la fixation du vitrage comme décrit dans la demande EP-745 750 A1 , notamment par extrusion.The flat profile 2 (see FIG. 1a) comprises sealing means, constituted as described above, of an aluminum foil 3, which may be oriented towards the inside of the glazing, the glue 4 being chosen to bond the aluminum to the hollow profile 30 but also to the slices of the glass sheets. This orientation of the sealing means 3 has the advantage of making it possible to conform the external face of the flat profile 2, for example made of plastic, with grooves for fixing the glazing as described in the application EP-745 750 A1 , especially by extrusion.

La situation du profilé creux 30 au moins en partie à l'extérieur de l'espace délimité par les feuilles de verre permet de l'utiliser dans le montage du vitrage, par insertion dans une rainure formée dans le cadre de baie, sans qu'une étape supplémentaire de fixation d'une pareclose soit nécessaire. Tel est également l'avantage présenté par le mode de réalisation représenté à la figure 1c, à laquelle il est à présent fait référence.The situation of the hollow profile 30 at least partly outside the space delimited by the glass sheets makes it possible to use it in the assembly of the glazing, by insertion into a groove formed in the frame of the bay, without which an additional step of fixing a glazing is necessary. This is also the advantage presented by the embodiment shown in FIG. 1c, to which reference is now made.

Selon ce mode de réalisation, un profilé sensiblement plat 2 muni de ses moyens d'étanchéité 3 orientés vers l'extérieur ceinture tout le pourtour du vitrage isolant, étant collé aux tranches des feuilles de verre par la colle 4. Le profilé plat 2 présente un trou 6 qui, par exemple, a pu être découpé après solidarisation du profilé plat aux feuilles de verre, et éventuellement après une certaine durée d'utilisation du vitrage en résultant. Un profilé creux 30 a donc ici été ultérieurement collé au profilé plat 2 par la colle 5. Le tamis moléculaire contenu dans le creux du profilé 30 est actif vis-à-vis de la lame de gaz 12, avec laquelle il communique par les porosités ou trous 31 ménagés dans la paroi interne 20 du profilé 30 et par le trou 6.According to this embodiment, a substantially flat profile 2 provided with its sealing means 3 facing outward surrounds all the periphery of the insulating glass, being adhered to the slices of the glass sheets by the glue 4. The flat profile 2 presents a hole 6 which, for example, could be cut after securing the flat profile to the glass sheets, and possibly after a certain period of use of the glazing resulting therefrom. A hollow profile 30 has therefore here been subsequently bonded to the flat profile 2 by the glue 5. The molecular sieve contained in the hollow of the profile 30 is active vis-à-vis the gas plate 12, with which it communicates through the pores or holes 31 formed in the inner wall 20 of the profile 30 and through the hole 6.

Le profilé creux 30 peut ici aussi être bouché à ses extrémités avec un matériau thermofusible à faible transmission d'humidité. Des moyens d'étanchéité complémentaires non représentés sont opportunément utilisés entre le profilé plat 2 et le profilé creux 30 : ruban adhésif, injection de matières appropriées pour obturer des sections latérales de recouvrement ouvertes (voir ci-dessus). Ces moyens complémentaires sont amovibles, de sorte que la régénération du tamis moléculaire du profilé 30, éventuellement après une longue durée d'utilisation de plusieurs années, est particulièrement simplifiée par les mesures de l'invention.The hollow profile 30 can here also be plugged at its ends with a hot melt material with low moisture transmission. Additional sealing means not shown are conveniently used between the flat profile 2 and the hollow profile 30: adhesive tape, injection of materials suitable for closing open side cover sections (see above). These additional means are removable, so that the regeneration of the molecular sieve of the profile 30, possibly after a long period of use of several years, is particularly simplified by the measures of the invention.

A la figure 1d est représentée une variante dans laquelle un profilé creux 30 est installé intégralement dans l'espace délimité par deux feuilles de verre 10 et 11 d'un vitrage isolant, par collage avec un matériau 5' apte à procurer l'étanchéité requise entre la lame de gaz et l'atmosphère extérieure, mais sur une partie seulement de la périphérie du vitrage, de préférence sur une partie ou la totalité d'un côté rectiligne du vitrage. Un profilé sensiblement plat non apparent recouvre et est collé au moins sur chacune des deux sections d'extrémité du profilé creux 30, de manière à assurer ou au moins contribuer à l'étanchéité requise entre la cavité du profilé creux 30 et l'atmosphère extérieure. Il suffit ainsi de décoller une partie suffisante du profilé plat 2 pour dégager une extrémité du profilé creux 30 afin de remplacer le desséchant usagé qu'il contient, puis de le recoller.In Figure 1d is shown a variant in which a hollow section 30 is installed integrally in the space defined by two sheets of glass 10 and 11 of an insulating glass, by bonding with a material 5 'able to provide the required seal between the gas slide and the outside atmosphere but on a only part of the periphery of the glazing, preferably on part or all of a rectilinear side of the glazing. A substantially flat non-visible profile covers and is bonded at least on each of the two end sections of the hollow profile 30, so as to ensure or at least contribute to the required seal between the cavity of the hollow profile 30 and the external atmosphere . It suffices to take off a sufficient portion of the flat profile 2 to clear one end of the hollow section 30 to replace the used desiccant it contains, then to re-stick.

Le procédé de fabrication va à présent être décrit en s'attachant au mode de réalisation préférentiel de l'invention utilisant un profilé sensiblement plat à base de matière thermoplastique renforcée. Cette description occulte l'intégration au vitrage isolant du profilé creux, décrite ci-dessus ; cette intégration est antérieure (variantes selon figures 1b et 1d) ou postérieure (variante de la figure 1c) à l'assemblage du profilé plat.The manufacturing method will now be described with reference to the preferred embodiment of the invention using a substantially flat profile based on reinforced thermoplastic material. This description obscures the integration with the insulating glazing of the hollow profile, described above; this integration is anterior (variants according to FIGS. 1b and 1d) or posterior (variant of FIG. 1c) to the assembly of the flat profile.

Les feuilles de verre 10 et 11 sont acheminées sur chant par des moyens usuels jusqu'à une chambre pouvant enfermer le gaz à introduire dans le vitrage.The glass sheets 10 and 11 are conveyed edge by usual means to a chamber that can enclose the gas to be introduced into the glazing.

Les feuilles de verre 10 et 11 sont maintenues à l'écartement désiré au moyen de ventouses disposées sur les faces externes du vitrage et contrôlées par des vérins pneumatiques.The glass sheets 10 and 11 are held at the desired spacing by means of suction pads disposed on the outer faces of the glazing and controlled by pneumatic cylinders.

La figure 2 illustre schématiquement le dispositif de fabrication du vitrage enfermé dans la chambre C.Figure 2 schematically illustrates the manufacturing device of the glazing enclosed in the chamber C.

Une bobine 50 constitue le magasin du profilé 2 qui est déroulé et étiré, à l'aide d'un dispositif d'étirement non visible, sous forme d'un ruban qui est coupé à une longueur équivalente au périmètre du vitrage, la largeur du ruban correspondant à l'épaisseur totale du vitrage.A coil 50 constitutes the store of the section 2 which is unwound and stretched, using a non-visible stretching device, in the form of a ribbon which is cut to a length equivalent to the perimeter of the glazing, the width of the ribbon corresponding to the total thickness of the glazing.

Dès la mise à plat du profilé est déposé l'adhésif 4 à l'aide de moyens d'injection 51, tels qu'une buse, sur la face interne 20 du ruban destinée a être appliquée sur la tranche du vitrage. Dans ce cas, le ruban comprend le desséchant de manière inhérente à sa face interne, le desséchant ayant été incorporé sous forme de poudre ou de granulés à la matière thermoplastique renforcée lors de la fabrication du profilé.As soon as the profile is flattened, the adhesive 4 is deposited using injection means 51, such as a nozzle, on the internal face 20 of the ribbon intended to be applied to the edge of the glazing. In this case, the ribbon comprises the desiccant inherently on its inner side, the desiccant having been incorporated as a powder or granules to the reinforced thermoplastic material during the manufacture of the profile.

Toutefois, lorsqu'il s'agit d'ajouter le desséchant ultérieurement à la fabrication du profilé, on préférera mettre en place le desséchant et l'adhésif au cours d'une seule et même opération à l'aide de trois buses d'injection, deux buses latérales visant les bords du ruban pour le dépôt de l'adhésif dans le but d'être en regard des tranches du vitrage et une buse centrale injectant le desséchant sur la partie centrale 22 du ruban dans le but d'être en vis-à-vis de la lame de gaz.However, when it comes to adding the desiccant subsequently to the manufacture of the profile, it is preferable to set up the desiccant and the adhesive during a single operation with the aid of three injection nozzles two lateral nozzles aiming at the edges of the tape for the deposition of the adhesive in order to be facing the slices of the glazing and a central nozzle injecting the desiccant on the central portion 22 of the tape in order to be vis-à-vis -vis the gas blade.

Il est aussi possible d'envisager un adhésif qui a été déposé lors de la fabrication du profilé et qui est protégé jusqu'à son utilisation, correspondant ici jusqu'à l'application du profilé contre le vitrage.It is also possible to envisage an adhesive which has been deposited during the manufacture of the profile and which is protected until its use, corresponding here until the application of the profile against the glazing.

Au moins un galet presseur 54 contrôlé par un bras articulé non illustré effectue l'application et la compression du ruban 2 contre la tranche du vitrage 1 sur l'ensemble de son périmètre. Pour un gain de temps dans l'opération de ceinturage, il sera de préférence prévu deux galets 54 qui seront entraînés selon deux directions opposées et effectueront simultanément le bordage de deux moitiés du périmètre.At least one pressure roller 54 controlled by a not shown articulated arm performs the application and compression of the ribbon 2 against the edge of the glazing 1 over its entire perimeter. To save time in the operation of belting, it will preferably be provided two rollers 54 which will be driven in two opposite directions and will simultaneously flank two halves of the perimeter.

Des moyens de chauffage 55 tels que deux résistances à fil chauffant sont prévus pour chauffer le profilé avant son pliage et son application au niveau des angles du vitrage.Heating means 55 such as two heating wire resistors are provided for heating the profile before folding and its application at the corners of the glazing.

Le fonctionnement du dispositif est le suivant.The operation of the device is as follows.

Les deux feuilles de verre 10, 11 maintenues écartées sont positionnées fixes au centre de la chambre C.The two sheets of glass 10, 11 kept apart are positioned fixed in the center of the chamber C.

Sous le vitrage est déroulé, étiré et coupé le profilé ou ruban 2 qui comprend le desséchant et les moyens de solidarisation 4.Under the glazing is unrolled, stretched and cut the profile or ribbon 2 which comprises the desiccant and the securing means 4.

Les deux galets presseurs 54 sont amenés au contact du ruban pour appliquer celui-ci en un point milieu du côté horizontal inférieur du vitrage. Une fois le ruban pressé contre la tranche du vitrage, le bordage est amorcé en ce point milieu ce qui assure ainsi la mise sous tension du ruban.The two pressure rollers 54 are brought into contact with the tape to apply it to a midpoint of the lower horizontal side of the glazing. Once the ribbon pressed against the wafer of the glazing, the curling is initiated at this midpoint which thus ensures the power of the ribbon.

Les galets 54 progressent ensuite en des directions opposées vers les coins inférieurs gauche 13 et droit 14 du vitrage.The rollers 54 then progress in opposite directions to the lower left 13 and right 14 corners of the glazing.

Avant d'aborder le tournant des deux angles 13 et 14, les galets 54 sont stoppés momentanément tandis que les fils chauffants 55 sont disposés en aval des galets, proche et en regard du feuillard métallique 21 a du profilé pour chauffer la matière thermoplastique destinée à être appliquée contre les angles (figure 3).Before approaching the turning of the two corners 13 and 14, the rollers 54 are stopped momentarily while the heating son 55 are disposed downstream of the rollers, close and opposite the metal strip 21 has the profile for heating the thermoplastic material intended for be applied against the corners (Figure 3).

Après ramollissement du profilé, les galets presseurs 54 sont à nouveau mis en fonctionnement pour plier le profilé et border correctement les angles 13 et 14 du vitrage. Puis les galets continuent de parcourir le pourtour du vitrage jusqu'aux angles supérieurs 15 et 16 du vitrage où l'opération de chauffage du profilé est réitérée au moyen des fils chauffants 55.After softening the profile, the pressure rollers 54 are again put into operation to fold the profile and properly border the corners 13 and 14 of the glazing. Then the pebbles continue to run around the glazing to the upper corners 15 and 16 of the glazing where the heating operation of the profile is reiterated by means of the heating wires 55.

Une fois les coins supérieurs du vitrage ceinturés, les galets presseurs 54 finissent de border le dernier côté du vitrage. A l'approche du milieu de ce dernier côté, l'un des galets est arrêté tandis que l'autre galet continue d'écraser le profilé jusqu'à ce que l'extrémité libre 23 du profilé associé à ce galet en fonctionnement recouvre l'autre extrémité 24 du profilé mis en place (figure 4). L'opération de ceinturage est alors terminée, les galets presseurs 54 sont dégagés du vitrage.Once the upper corners of the glazing belted, the pinch rollers 54 end to border the last side of the glazing. At the approach of the middle of the latter side, one of the rollers is stopped while the other roller continues to crush the section until the free end 23 of the profile associated with the roller in operation covers the other end 24 of the profiled section (FIG. 4). The belting operation is then completed, the pressure rollers 54 are released from the glazing.

Pour confirmer la solidarisation des deux extrémités 23 et 24 du ruban et surtout étancher les deux sections latérales ouvertes 25 du ruban qui sont dues au recouvrement des extrémités, des moyens complémentaires d'étanchéité tels que de la colle sont injectés de façon à obturer cesdites sections 25.To confirm the fastening of the two ends 23 and 24 of the ribbon and especially to seal the two open lateral sections 25 of the ribbon which are due to the covering of the ends, complementary sealing means such as glue are injected so as to close off said sections 25.

Une variante d'assemblage non illustrée des deux extrémités du ruban peut consister non pas à les recouvrir mais à les abouter l'une à l'autre lorsqu'elles comprennent des formes complémentaires adaptées à coopérer mutuellement, à la manière d'un tenon et d'une mortaise. Pour assurer la totale étanchéité, on ajoutera sur la zone d'aboutage de la colle ou un ruban adhésif étanche aux gaz et à la vapeur d'eau tel qu'un ruban adhésif en inox.An unillustrated assembly variant of the two ends of the ribbon may consist not in covering them but in abutting them to one another when they comprise complementary shapes adapted to cooperate mutually, in the manner of a tenon and of a mortise. To ensure complete watertightness, glue or water and vapor-tight adhesive tape, such as stainless steel tape, will be added to the butting area.

Si la jonction des deux extrémités du ruban, que ce soit par chevauchement ou par aboutement, est effectuée sur l'un des côtés du vitrage, il est aussi possible de réaliser en variante cette jonction au niveau d'un angle du vitrage.If the junction of the two ends of the ribbon, whether by overlap or abutment, is performed on one side of the glazing, it is also possible to alternatively make this junction at an angle of the glazing.

Par ailleurs, dans une variante de réalisation du procédé, on peut prévoir deux têtes 56a, 56b de distribution du ruban 2, respectivement une fixe et une mobile verticalement, associée chacune à un galet presseur 54, le vitrage étant apte à être translaté horizontalement.Furthermore, in an alternative embodiment of the method, one can provide two heads 56a, 56b distribution ribbon 2, respectively a fixed and a vertically movable, each associated with a pressure roller 54, the glazing being adapted to be translated horizontally.

En référence à la figure 5a, le vitrage entré dans la chambre C qui n'est ici pas illustrée, est disposé entre la position ① correspondant à l'avant du vitrage et la position ② correspondant à l'arrière du vitrage. Au départ, la tête mobile 56b démarre d'un angle inférieur du vitrage correspondant à la position ①, et est actionnée vers le haut pour suivre le côté vertical avant du vitrage. Une fois arrivée à l'angle supérieur, la tête 56b pivote de 90° et est immobilisée, les deux têtes étant alors en vis-à-vis. Le vitrage est ensuite translaté de la gauche vers la droite, c'est-à-dire que l'arrière du vitrage passe de la position ② vers la position ①, de manière à effectuer simultanément le ceinturage des côtés horizontaux du vitrage par respectivement chacune des têtes (figure 5b). Enfin, l'arrière du vitrage est immobilisé en position ①, et le côté vertical est ceinturé par la tête mobile ayant pivoté de 90° au coin supérieur du vitrage pour descendre jusqu'à l'angle inférieur (figure 5c). La solidarisation des deux rubans est alors réalisée dans les angles inférieurs du vitrage par chevauchement ou par aboutement.Referring to Figure 5a, the glazing entered in the chamber C which is not illustrated here, is disposed between the position ① corresponding to the front of the glazing and the position ② corresponding to the rear of the glazing. Initially, the movable head 56b starts at a lower angle of the glazing corresponding to the position ①, and is actuated upwards to follow the vertical front side of the glazing. Once arrived at the upper corner, the head 56b rotates 90 ° and is immobilized, the two heads being then vis-à-vis. The glazing is then translated from left to right, that is to say that the rear of the glazing goes from the position ② to the position ①, so as simultaneously perform the belting of the horizontal sides of the glazing by respectively each of the heads (Figure 5b). Finally, the rear of the glazing is immobilized in position ①, and the vertical side is surrounded by the movable head having rotated 90 ° to the upper corner of the glazing to descend to the lower angle (Figure 5c). The fastening of the two ribbons is then performed in the lower corners of the glazing by overlapping or abutment.

Cette combinaison des mouvements de translation du vitrage et d'au moins une tête de distribution du ruban permet de gagner du temps pour ceinturer le vitrage.This combination of translational movement of the glazing and at least one ribbon dispensing head saves time to surround the glazing.

En outre cette combinaison de mouvements et l'utilisation du profilé de l'invention permet de ceinturer des formes complexes de vitrage qui présentent par exemple des bords courbes à formes concaves et/ou convexes.In addition, this combination of movements and the use of the profile of the invention makes it possible to encircle complex shapes of glazing which have, for example, curved edges with concave and / or convex shapes.

Une autre variante de remplissage du gaz devant être contenu dans le vitrage peut être envisagée. Au lieu de devoir disposer d'une chambre remplie de gaz, il est prévu un dispositif d'alimentation en gaz tel qu'un tuyau qui est inséré entre les deux verres et qui délivre du gaz au fur et à mesure que les bords du vitrage sont ceinturés et étanchés. Le dispositif est retiré juste avant la fermeture du dernier côté du vitrage.Another variant of filling the gas to be contained in the glazing can be envisaged. Instead of having a chamber filled with gas, there is provided a gas supply device such as a pipe which is inserted between the two glasses and which delivers gas as the edges of the glazing are girdled and sealed. The device is removed just before closing the last side of the glazing.

Le profilé de l'invention présente une forme générale plate et parallélépipédique, néanmoins des variantes de réalisation sont possibles. Il peut par exemple être envisagé de munir la face interne 20 du profilé opposée à celle comprenant le revêtement métallique, de moyens de centrage et de positionnement tels que des saillies longitudinales ou des ergots répartis régulièrement selon deux lignes longitudinales écartées d'une largeur équivalente à la séparation des deux feuilles de verre de manière à guider et positionner convenablement le profilé contre la tranche du vitrage, les saillies ou ergots s'insérant à l'intérieur du vitrage et étant plaqués contre les parois internes.The profile of the invention has a generally flat and parallelepipedal shape, nevertheless alternative embodiments are possible. It may for example be envisaged to provide the inner face 20 of the profile opposite to that comprising the metal coating, centering and positioning means such as longitudinal projections or lugs regularly distributed along two longitudinal lines spaced by a width equivalent to the separation of the two glass sheets so as to guide and properly position the profile against the edge of the glazing, the projections or lugs inserting inside the glazing and being pressed against the inner walls.

Claims (32)

  1. An insulating glazing unit, comprising two glass sheets (10, 11) spaced apart by a gas-filled cavity (12), an insert (2) that serves to keep the two glass sheets apart and has an internal face (20) facing the gas-filled cavity and an opposed external face (21), and means (3) for sealing with respect to the inside of the glazing unit, characterized in that the insert (2) comprises a substantially flat strip which surrounds a first part of the perimeter of the glazing unit, this part being able to be the totality of the perimeter, being pressed via its internal face (20) against the edges (10a, 11a) of the glass sheets and kept fastened by fastening means (4), and another non essentially flat strip which surrounds a second part of the perimeter of the glazing unit, this second part being not the totality of the perimeter of the glazing unit.
  2. The insulating glazing unit as claimed in claim 1, characterized in that said other strip is pressed via its internal face (20) against the edges (10a, 11a) of the glass sheets.
  3. The insulating glazing unit as claimed in claim 1, characterized in that said other strip is at least partly located between the glass sheets (10, 11).
  4. The glazing unit as claimed in one of the preceding claims, characterized in that said other strip comprises at least a part which lies outside the space bounded by the glass sheets (10, 11) and has a shape especially suitable for fitting and/or fastening the glazing unit in the opening for which it is intended.
  5. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the insert (2) possesses properties whereby it seals against gases and dust and against liquid water.
  6. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the sealing means (3) of said substantially flat strip are placed at least on the external face (21) of the insert.
  7. The insulating glazing unit according to one of claims 1 to 5, characterized in that the sealing means (3) of said substantially flat strip are placed at least on the internal face (20) of the insert.
  8. The insulating glazing unit as claimed in claim 7, characterized in that the external face (21) of said substantially flat strip has irregularities capable of setting and/or centering and/or fastening the glazing unit in the opening for which it is intended.
  9. The glazing unit as claimed in claim 8, characterized in that said irregularities consist of longitudinal striations such as those obtained by the extrusions of a thermoplastic or a similar process.
  10. The glazing unit as claimed in any one of the preceding claims, characterized in that either or both of the faces (20, 21) of the insert has/have longitudinal elements structured by forming or securely attached.
  11. The glazing unit as claimed in any one of the preceding claims, characterized in that part of the insert has undergone a painting or lacquering anticorrosion treatment or a printing-based marking treatment.
  12. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the sealing means (3) of the substantialy flat strip consists of a metal coating (21a).
  13. The insulating glazing unit as claimed in one of claims 1 to 9, characterized in that said substantially flat strip is made entirely of metal, especially stainless steel with a thickness of at least 0.10 mm, or of aluminum with a thickness of at least 0.15 mm, or is made of a thermoplastic that includes, if necessary, reinforcing fibers, especially continuous or chopped glass fibers, its thickness being in this case at least 0.2 mm.
  14. The insulating glazing unit according to any one of the preceding claims, characterized in that said substantially flat strip has a linear buckling strength of at least 400 N/m.
  15. The insulating glazing unit as claimed in any one of the preceding claims, characterized in that the fastening means (4) are impermeable to water vapor and to gases.
  16. The insulating glazing unit as claimed in any one of the preceding claims, characterized in that the fastening means (4) consist of an adhesive.
  17. The insulating glazing unit as claimed in claim 15, characterized in that the adhesive has a tear strength of at least 0.45 MPa.
  18. The insulating glazing unit as claimed in any one of the preceding claims, characterized in that said substantially flat strip has two free ends (23, 24) which are joined together in order to surround all or part of the glazing unit so that one of the ends overlaps the other, or one end of said other strip, supplementary sealing means being provided in order to seal off lateral sections (25) left open by the overlap.
  19. The insulating glazing unit according to any one of claims 1 to 17, characterized in that said substantially flat strip has two free ends (23, 24) of complementary shapes suitable for mutually cooperating in order to result in their abutment so as to go around the entire glazing unit.
  20. The insulating glazing unit as claimed in claim 19, characterized in that an adhesive tape, or adhesive, impermeable to gases and to water vapor, is applied to the abutment region.
  21. The insulating glazing unit as claimed in any one of the preceding claims, characterized in that it has a complex shape, in particular with curved parts.
  22. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the insert (2) contains a desiccant and/or includes control, electrical-connection and mechanical-transmission means and/or incorporates a venetian blind installed in the gas-filled cavity and/or a means of measuring the moisture content and/or serves for fastening cross members installed in the gas-filled cavity.
  23. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the insert (2) has at least one hole.
  24. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the edges of the said two glass sheets are at least partly offset with respect to each other.
  25. The insulating glazing unit as claimed in one of the preceding claims, characterized in that at least one of said two glass sheets includes a through-hole and in that the edges of this hole are considered as forming part of said first part of the perimeter of the glazing unit, a substantially flat strip being pressed against and adhesively bonded in a leaktight manner to these edges.
  26. A process for manufacturing an insulating glazing unit as claimed in any one of claims 1 to 25, characterized in that:
    - said other strip provided as the case may be with its, means (5; 5') for fastening to the glazing unit is joined to two glass sheets (10, 11), and the kept parallel and spaced apart, are assembled;
    - the internal face (20) of the substantially flat strip provided with the fastening means (4) is placed against the edges (10a, 11a) of the glass sheets and, as the case may be, on the external face (21) of the other strip;
    - during the step of placing the substantially flat strip, pressure means (54) are applied almost instantaneously on the external face (21) of the latter so as to ensure that it adheres to the edges of the glass sheets and, as the case may be, to the other strip; and
    - the two ends (23, 24) of the substantially flat strip are securely joined, either one end to the other, or each of the ends to one end of the other strip.
  27. The process for manufacturing an insulating glazing unit as claimed in claim 26, characterized in that the substantially flat strip before being put into place is in the form of a wound tape (50) intended to be unwound, stretched and cut to the desired length, whereas the adhesive type fastening means (4) are deposited by injection means onto the tape being stretched.
  28. The process for manufacturing an insulating glazing unit as claimed in claim 27, characterized in that desiccant is deposited onto the tape being stretched, during application of the fastening means (4) .
  29. The process for manufacturing an insulating glazing unit as claimed in any one of claims 26 to 28, characterized in that a gas feed device is provided, inserted between the two glass sheets, in order to deliver gas, while the glazing unit is undergoing the surrounding operation, and said device is removed just before the end of the surrounding operation.
  30. The process for manufacturing an insulating glazing unit as claimed in one of claims 1 to 25, characterized in that:
    - the two glass sheets are kept parallel and spaced apart;
    - the internal face (20) of the substantially flat strip, provided with the means (4) for fastening it against the edges (10a, 11a) of the glass sheets, is placed around the entire perimeter of the glazing unit;
    - while the substantially flat strip is being put in place, pressure means (54) are applied almost instantaneously on its external face (21) so as to ensure that it adheres to the edges of the glass sheets;
    - after the entire glazing unit has been surrounded, the two ends (23, 24) of the substantially flat strip are securely joined together;
    - a hole (6) in the substantially flat strip is sealed off by means of a said other strip (30), the hole (6) possibly being drilled by the coming-together of the substantially flat strip and of the other strip shaped for this purpose.
  31. The insulating glazing unit as claimed in one of the preceding claims, characterized in that the substantially flat strip is with an approximately parallelepipedal shape, and possibly has functional elements structured by forming or securely attached.
  32. The insulating glazing unit as claimed in claim 31, characterized in that the strip includes, on one of its main faces (20), means for centering and positioning the insert on the glazing unit.
EP02790517A 2001-10-17 2002-10-16 Insulating glazing and the production method thereof Expired - Lifetime EP1436481B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0113354 2001-10-17
FR0113354A FR2830897B1 (en) 2001-10-17 2001-10-17 INSULATING GLAZING AND METHOD OF MANUFACTURING
PCT/FR2002/003533 WO2003040507A1 (en) 2001-10-17 2002-10-16 Insulating glazing and the production method thereof

Publications (2)

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EP1436481A1 EP1436481A1 (en) 2004-07-14
EP1436481B1 true EP1436481B1 (en) 2008-01-16

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US (1) US7332202B2 (en)
EP (1) EP1436481B1 (en)
JP (1) JP4515764B2 (en)
KR (1) KR20040054714A (en)
CN (1) CN1312374C (en)
AT (1) ATE384188T1 (en)
BR (1) BR0212563B1 (en)
CA (1) CA2463728C (en)
DE (1) DE60224695T2 (en)
DK (1) DK1436481T3 (en)
ES (1) ES2300495T3 (en)
FR (1) FR2830897B1 (en)
HU (1) HU228041B1 (en)
NO (1) NO327704B1 (en)
PL (1) PL209355B1 (en)
PT (1) PT1436481E (en)
RU (1) RU2293168C2 (en)
WO (1) WO2003040507A1 (en)

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JP2005508280A (en) 2005-03-31
DK1436481T3 (en) 2008-07-07
RU2293168C2 (en) 2007-02-10
ATE384188T1 (en) 2008-02-15
RU2004114854A (en) 2005-10-27
PL368239A1 (en) 2005-03-21
HUP0401852A2 (en) 2005-01-28
EP1436481A1 (en) 2004-07-14
ES2300495T3 (en) 2008-06-16
PT1436481E (en) 2008-04-22
KR20040054714A (en) 2004-06-25
US20050003116A1 (en) 2005-01-06
FR2830897B1 (en) 2006-11-17
FR2830897A1 (en) 2003-04-18
BR0212563A (en) 2004-12-28
CN1571876A (en) 2005-01-26
US7332202B2 (en) 2008-02-19
DE60224695T2 (en) 2009-01-15
CN1312374C (en) 2007-04-25
BR0212563B1 (en) 2012-06-26
NO20041967L (en) 2004-05-11
JP4515764B2 (en) 2010-08-04
HU228041B1 (en) 2012-09-28
DE60224695D1 (en) 2008-03-06
CA2463728C (en) 2010-04-13
PL209355B1 (en) 2011-08-31
WO2003040507A1 (en) 2003-05-15
CA2463728A1 (en) 2003-05-15
NO327704B1 (en) 2009-09-14

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