EP1337362A1 - A method of producing steel strip - Google Patents
A method of producing steel stripInfo
- Publication number
- EP1337362A1 EP1337362A1 EP01971503A EP01971503A EP1337362A1 EP 1337362 A1 EP1337362 A1 EP 1337362A1 EP 01971503 A EP01971503 A EP 01971503A EP 01971503 A EP01971503 A EP 01971503A EP 1337362 A1 EP1337362 A1 EP 1337362A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- steel
- cast
- microstructure
- residuals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/16—Controlling or regulating processes or operations
- B22D11/22—Controlling or regulating processes or operations for cooling cast stock or mould
- B22D11/225—Controlling or regulating processes or operations for cooling cast stock or mould for secondary cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/021—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
- C21D8/0215—Rapid solidification; Thin strip casting
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/573—Continuous furnaces for strip or wire with cooling
Definitions
- the present invention relates to a method of producing steel strip and the cast strip produced according to the method.
- the present invention relates to producing steel strip in a continuous strip caster.
- strip as used in the specification is to be understood to mean a product of 5mm thickness or less.
- casting steel strip continuously in a twin roll caster involves introducing molten steel between a pair of contra-rotated horizontal casting rolls which are internally water cooled so that metal shells solidify on the moving rolls surfaces and are brought together at the nip between them to produce a solidified strip delivered downwardly from the nip between the rolls, the term "nip" being used to refer to the general region at which the rolls are closest together.
- the molten metal may be poured from a ladle into a smaller vessel from which it flows through a metal delivery nozzle located above the nip so as to direct it into the nip between the rolls, so forming a casting pool of molten metal supported on the casting surfaces of the rolls immediately above the nip and extending along the length of the nip.
- This casting pool is usually confined between side plates or dams held in sliding engagement with end surfaces of the rolls so as to dam the two ends of the casting pool against outflow, although alternative means such as electromagnetic barriers have also been proposed.
- the casting of steel strip in twin roll casters of this kind is for example described in United States Patents 5,184,668, 5,277,243 and 5,934,359.
- the concentration of residuals in the steel composition can have a significant effect on the finished microstructure, and in turn affect yield strength properties of cast strip.
- higher concentrations of residuals make it possible to use lower cooling rates to transform the strip from austenite to ferrite in a temperature range between 850°C and 400°C to produce microstructures in cast strip that provide high yield strengths - It is understood that the transformation temperature range is within the range between 850°C and
- the continuous caster may be a twin roll caster.
- residuals covers levels of elements, such as copper, tin, zinc, nickel, chromium, and molybdenum, that are included in relatively small amounts, and are usually as a consequence of standard steel making.
- the elements may be present as a result of using scrap steel to produce steel.
- the total amount of the residuals is 1.2 wt°6 or less. These residuals may be up to 2.0 wt% where harder steel strip is desired with yield strengths up to and in excess of 700 MPa. This weight percent is the total weight percent in the steel strip including the residuals from scrap steel and steel processing.
- the cast strip produced in step (a) may have a thickness of no more than 2mm.
- the cast strip produced in step (a) may include austenite grains that are columnar.
- the steel may be low carbon steel.
- low carbon steel is understood to be mean steel of the following composition, in wt%:
- Mn 1 .0 or less ; residuals: 1.2 or less; and Fe: balance.
- the low carbon steel may be silicon/manganese killed and may have the following composition by weight:
- the low carbon steel may be aluminum killed and may have the following composition by weight:
- the aluminum killed steel may be calcium treated.
- the method may further include the step of inline hot rolling the cast strip after step (a) and prior to step (b) .
- Step (b) may include cooling the strip to transform the strip from the austenite to ferrite at a selected cooling rate of at least 0.01°C/sec, and usually at least 0.1 °C/sec, to produce a microstru ⁇ ture that provides required yield strength properties of the cast strip, the microstru ⁇ ture being selected from a group that includes microstructures that are:
- microstructures of types (ii) and (iii) will have microstructures of types (ii) and (iii) .
- low temperature transformation products includes idmanstatten ferrite, acicular ferrite, bainite, and martensite.
- Figure 1 illustrates a strip casting installation incorporating an in-line hot rolling mill and coiler
- Figure 2 illustrates details of the twin roll strip caster
- Figure 3 illustrates the effect of residuals on yield strength of cast strip.
- twin roll casters The following description is in the context of continuous casting steel strip using a twin roll caster.
- the present invention is not limited to the use of twin roll casters and extends to other types of continuous strip casters.
- Figure 1 illustrates successive parts of a production line whereby steel strip can be produced in accordance with the present invention.
- Figures 1 and 2 illustrate a twin roll caster denoted generally as 11 which produces a cast steel strip 12 that passes in a transit path 10 across a guide table 13 to a pinch roll stand 14 comprising pinch rolls 14A.
- the strip passes into a hot rolling mill 16 comprising a pair of reduction rolls 16A and backing rolls 16B by in which it is hot rolled to reduce its thickness .
- the rolled strip passes onto a runout table 17 on which it may be force cooled by water jets 18 and through a pinch roll stand 20 comprising a pair of pinch rolls 20A, and thence to a coiler 19.
- twin roll caster 11 comprises a main machine frame 21 which supports a pair of parallel casting rolls 22 having a casting surfaces 22A.
- Molten metal is supplied during a casting operation from a ladle (not shown) to a tundish 23, through a refractory shroud 24 to a distributor 25 and thence through a metal delivery nozzle 26 into the nip 27 between the casting rolls 22.
- Molten metal thus delivered to the nip 27 forms a pool 30 above the nip and this pool is confined at the ends of the rolls by a pair of side closure dams or plates 28 which are applied to the ends of the rolls by a pair of thrusters (not shown) comprising hydraulic cylinder units connected to the side plate holders.
- the upper surface of pool 30 (generally referred to as the "meniscus" level) may rise above the lower end of the delivery nozzle so that the lower end of the delivery nozzle is immersed within this pool .
- Casting rolls 22 are water cooled so that shells solidify on the moving roll surfaces and are brought together at the nip 27 between them to produce the solidified strip 12 which is delivered downwardly from the nip between the rolls.
- twin roll caster may be of the kind which is illustrated and described in some detail in United States Patents 5,184,668 and 5,277,243 or United States Patent 5,488,988 and reference may be made to those patents for appropriate constructional details which form no part of the present invention.
- the cooling rate in transforming the strip from austenite to ferrite in a temperature range between 850°C and 400°C is selected to be at least 0.01°C/sec, preferably at least 0.1°C/sec, and may be in excess of 100°C/sec. With such cooling rates for low carbon steel it is possible to produce cast strip having microstructures including:
- the concentration of residuals in the steel is selected having regard to the finished microstructure of the cast strip that is required to provide required mechanical properties for the strip.
- the present disclosure is based on experimental work that has found the presence of a high amount of residuals (0.2%Cr, 0.2%Ni, 0.2%Mo, 0.4%Cu, 0.2%Sn) has produced a strip with improved microstructure.
- the experimental findings include that the austenite microstructure of strip cast at 75 m/min was similar to the microstructure of strip without residuals. However, when the cast strip with residuals was subjected to a standard cooling rate of 10-15°C/sec, the resultant finished microstructure was very different from that of the cast strip without residuals cooled at the same rate.
- the observed microstructure of cooled cast strip with residuals was predominantly bainitic with only a thin band of grain boundary ferrite appearing along the prior austenite grain boundaries, indicating a severely suppressed ferrite transformation caused by the presence of residuals.
- the mechanical properties of the resultant product are very desirable, with typical values of 540 MPa yield strength, 650 MPa tensile strength and 15% total elongation. Such values could be achieved in the past by icroalloying which added considerable cost to the production of the cast strip.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Metal Rolling (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPR046000 | 2000-10-02 | ||
AUPR0460A AUPR046000A0 (en) | 2000-10-02 | 2000-10-02 | A method of producing steel strip |
PCT/AU2001/001224 WO2002028569A1 (en) | 2000-10-02 | 2001-09-28 | A method of producing steel strip |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1337362A1 true EP1337362A1 (en) | 2003-08-27 |
EP1337362A4 EP1337362A4 (en) | 2004-11-03 |
Family
ID=3824520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01971503A Ceased EP1337362A4 (en) | 2000-10-02 | 2001-09-28 | A method of producing steel strip |
Country Status (13)
Country | Link |
---|---|
US (1) | US20020043304A1 (en) |
EP (1) | EP1337362A4 (en) |
JP (1) | JP2004509770A (en) |
KR (2) | KR20090011018A (en) |
CN (1) | CN1466503A (en) |
AU (1) | AUPR046000A0 (en) |
BR (1) | BR0114404A (en) |
CA (1) | CA2422133A1 (en) |
MX (1) | MXPA03002806A (en) |
MY (1) | MY134909A (en) |
RU (1) | RU2307002C2 (en) |
TW (1) | TW520307B (en) |
WO (1) | WO2002028569A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPP811399A0 (en) * | 1999-01-12 | 1999-02-04 | Bhp Steel (Jla) Pty Limited | Cold rolled steel |
US7117925B2 (en) * | 2000-09-29 | 2006-10-10 | Nucor Corporation | Production of thin steel strip |
US7485196B2 (en) * | 2001-09-14 | 2009-02-03 | Nucor Corporation | Steel product with a high austenite grain coarsening temperature |
US7404431B2 (en) | 2002-06-04 | 2008-07-29 | Nucor Corporation | Production of thin steel strip |
US7938164B2 (en) | 2002-06-04 | 2011-05-10 | Nucor Corporation | Production of thin steel strip |
JP4197269B2 (en) * | 2002-09-09 | 2008-12-17 | 株式会社キッツ | Nickel elution prevention method for copper alloy piping equipment such as valves and fittings and its copper alloy piping equipment |
WO2007079545A1 (en) * | 2006-01-16 | 2007-07-19 | Nucor Corporation | Thin cast steel strip with reduced microcracking |
US7975754B2 (en) | 2007-08-13 | 2011-07-12 | Nucor Corporation | Thin cast steel strip with reduced microcracking |
HUP1300743A2 (en) | 2013-12-19 | 2015-06-29 | Dunaujvarosi Foeiskola | Technical layout and method for hot rolling of mp and trip steel based on controled heat dissipation |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0641867A1 (en) * | 1993-02-26 | 1995-03-08 | Nippon Steel Corporation | Thin cast piece of ordinary carbon steel containing large quantities of copper and tin, thin steel sheet, and method of production thereof |
EP0706845A1 (en) * | 1994-03-25 | 1996-04-17 | Nippon Steel Corporation | Method of production of thin strip slab |
EP0707908A1 (en) * | 1994-04-04 | 1996-04-24 | Nippon Steel Corporation | Twin-roll type continuous casting method and device |
JPH08290242A (en) * | 1995-04-18 | 1996-11-05 | Nippon Steel Corp | Production of carbon steel thin steel strip of <=500mpa strength from thin cast slab |
WO1998057767A1 (en) * | 1997-06-19 | 1998-12-23 | Acciai Speciali Terni S.P.A. | Continuous casting process for producing low carbon steel strips and strips so obtainable with good as cast mechanical properties |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2768807B2 (en) * | 1990-02-06 | 1998-06-25 | 新日本製鐵株式会社 | Manufacturing method of thin steel sheet |
JPH07118735A (en) * | 1993-10-20 | 1995-05-09 | Nippon Steel Corp | Method for producing thin cast strip and apparatus therefor |
WO1995013155A1 (en) * | 1993-11-08 | 1995-05-18 | Ishikawajima-Harima Heavy Industries Company Limited | In-line heat treatment of continuously cast steel strip |
ES2224283T3 (en) * | 1996-12-19 | 2005-03-01 | Corus Staal Bv | PROCEDURE TO PRODUCE A STEEL BAND OR BLADE. |
IT1290743B1 (en) * | 1997-04-10 | 1998-12-10 | Danieli Off Mecc | LAMINATION PROCESS FOR FLAT PRODUCTS WITH THIN THICKNESSES AND RELATED ROLLING LINE |
GB9803409D0 (en) * | 1998-02-19 | 1998-04-15 | Kvaerner Metals Davy Ltd | Method and apparatus for the manufacture of light gauge steel strip |
JPH11269600A (en) * | 1998-03-25 | 1999-10-05 | Daido Steel Co Ltd | High toughness non-refining steel for hot forging |
FR2798871B1 (en) * | 1999-09-24 | 2001-11-02 | Usinor | PROCESS FOR PRODUCING CARBON STEEL STRIPS, ESPECIALLY STEEL FOR PACKAGING, AND STRIPS THUS PRODUCED |
-
2000
- 2000-10-02 AU AUPR0460A patent/AUPR046000A0/en not_active Abandoned
-
2001
- 2001-09-28 US US09/967,105 patent/US20020043304A1/en not_active Abandoned
- 2001-09-28 KR KR1020087030076A patent/KR20090011018A/en not_active Application Discontinuation
- 2001-09-28 TW TW090124082A patent/TW520307B/en not_active IP Right Cessation
- 2001-09-28 RU RU2003112631/02A patent/RU2307002C2/en not_active IP Right Cessation
- 2001-09-28 MX MXPA03002806A patent/MXPA03002806A/en not_active Application Discontinuation
- 2001-09-28 WO PCT/AU2001/001224 patent/WO2002028569A1/en active Application Filing
- 2001-09-28 JP JP2002532385A patent/JP2004509770A/en active Pending
- 2001-09-28 BR BR0114404-9A patent/BR0114404A/en not_active Application Discontinuation
- 2001-09-28 KR KR10-2003-7004607A patent/KR20030064762A/en not_active Application Discontinuation
- 2001-09-28 EP EP01971503A patent/EP1337362A4/en not_active Ceased
- 2001-09-28 CA CA002422133A patent/CA2422133A1/en not_active Abandoned
- 2001-09-28 CN CNA018163068A patent/CN1466503A/en active Pending
- 2001-10-01 MY MYPI20014580A patent/MY134909A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0641867A1 (en) * | 1993-02-26 | 1995-03-08 | Nippon Steel Corporation | Thin cast piece of ordinary carbon steel containing large quantities of copper and tin, thin steel sheet, and method of production thereof |
EP0706845A1 (en) * | 1994-03-25 | 1996-04-17 | Nippon Steel Corporation | Method of production of thin strip slab |
EP0707908A1 (en) * | 1994-04-04 | 1996-04-24 | Nippon Steel Corporation | Twin-roll type continuous casting method and device |
JPH08290242A (en) * | 1995-04-18 | 1996-11-05 | Nippon Steel Corp | Production of carbon steel thin steel strip of <=500mpa strength from thin cast slab |
WO1998057767A1 (en) * | 1997-06-19 | 1998-12-23 | Acciai Speciali Terni S.P.A. | Continuous casting process for producing low carbon steel strips and strips so obtainable with good as cast mechanical properties |
Non-Patent Citations (3)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 03, 31 March 1997 (1997-03-31) -& JP 08 290242 A (NIPPON STEEL CORP), 5 November 1996 (1996-11-05) * |
SACHS K: "Residuals in engineering steels" METALS TECHNOLOGY, METALS SOCIETY, LONDON, GB, January 1979 (1979-01), pages 33-37, XP002278883 ISSN: 0307-1693 * |
See also references of WO0228569A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1466503A (en) | 2004-01-07 |
TW520307B (en) | 2003-02-11 |
KR20090011018A (en) | 2009-01-30 |
WO2002028569A1 (en) | 2002-04-11 |
MY134909A (en) | 2007-12-31 |
MXPA03002806A (en) | 2004-09-10 |
RU2307002C2 (en) | 2007-09-27 |
AUPR046000A0 (en) | 2000-10-26 |
US20020043304A1 (en) | 2002-04-18 |
BR0114404A (en) | 2003-07-29 |
EP1337362A4 (en) | 2004-11-03 |
CA2422133A1 (en) | 2002-04-11 |
KR20030064762A (en) | 2003-08-02 |
JP2004509770A (en) | 2004-04-02 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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A4 | Supplementary search report drawn up and despatched |
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Effective date: 20081022 |