EP1351775A1 - Electronic micro-pump - Google Patents
Electronic micro-pumpInfo
- Publication number
- EP1351775A1 EP1351775A1 EP01994873A EP01994873A EP1351775A1 EP 1351775 A1 EP1351775 A1 EP 1351775A1 EP 01994873 A EP01994873 A EP 01994873A EP 01994873 A EP01994873 A EP 01994873A EP 1351775 A1 EP1351775 A1 EP 1351775A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- piston
- wall
- chamber
- micropump according
- orifice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007789 sealing Methods 0.000 claims description 16
- 230000002093 peripheral effect Effects 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000000047 product Substances 0.000 description 13
- 239000012263 liquid product Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 230000003071 parasitic effect Effects 0.000 description 2
- 239000004479 aerosol dispenser Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/085—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump
- B05B9/0855—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being motor-driven
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/0005—Components or details
- B05B11/0062—Outlet valves actuated by the pressure of the fluid to be sprayed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1001—Piston pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1042—Components or details
- B05B11/1066—Pump inlet valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1094—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle having inlet or outlet valves not being actuated by pressure or having no inlet or outlet valve
Definitions
- the invention relates to a ⁇ electronic micropump.
- This pump which is associated with a miniature electric actuator is intended for the distribution and / or dosing of liquid products such as perfumes, cosmetics or pharmaceutical compositions.
- the traditional pumps used for these applications generally comprise a cylindrical body enclosing a metering chamber delimited by a piston and communicating, on the one hand, with a reservoir via a supply orifice provided with an inlet valve and, on the other hand, with the outside via an ejection orifice fitted with an exhaust valve.
- These pumps are also provided with a push button covering a nozzle tube connected to the exhaust valve and allowing, by manual pressure, to push the piston into the chamber to evaluate the product under pressure.
- a micropump characterized in that the piston is connected to an external alternating actuator and in that at least one of the valves consists of a sealing element capable of to be driven in translation, by friction contact with said piston, successively in one direction then in the other and whose stroke in the chamber is less than that of said piston.
- said sealing element comprises at least one wall intended to come to seal in a sealed and periodic manner the ejection orifice or the supply orifice.
- said wall is provided with a rod.
- the ejection orifice is formed on the side wall of said body and said sealing element consists of a cylindrical-conical sleeve, the bottom of which forms the intake valve while its upper lateral edge forms the valve. exhaust.
- the lower part of said socket includes at least one through lumen.
- the side wall of said sleeve has guide ribs in contact with the internal wall of the chamber.
- the internal part of the piston is provided with a lateral grooving and an upper lip ensuring the sealing and the upper stop of the stroke.
- the bottom and / or the upper edge of the bushing comprise a peripheral ring coming into tight abutment respectively downwards or upwards against the wall of the chamber.
- the ejection orifice opens axially into said chamber and said element closing the exhaust valve consists of a rod engaged on the one hand, with friction in a bore of the piston and provided with: on the other hand, a head carrying a transverse wall capable of coming into leaktight support against the axial ejection orifice.
- said head is housed inside a cavity whose transverse walls form end-of-travel stops.
- the supply orifice is formed on the side wall of said body and the shutter element of the intake valve consists of a jacket in which is engaged with friction contact the internal part piston.
- said jacket cooperates with an annular shoulder formed on the internal side wall of the body to limit its travel.
- the micropump of the invention offers great flexibility of use by allowing a continuous and regular distribution of the product. thanks to the high operating frequencies of the actuator (of the order of 30 to 150 Hz).
- the friction connection can be obtained, for example, by making a slight radial tightening between the piston and the sealing element.
- FIG. 1 represents a schematic sectional view of a first embodiment of the micropump of the invention
- FIG. 2 represents a sectional view of a first variant of the micropump of FIG. 1,
- FIG. 3 represents two half-views in section of a second variant of the micropump of FIG. 1 in two distinct phases
- FIG. 4 represents a schematic sectional view of a second embodiment of the micropump of the invention
- FIG. 5 represents a sectional view of a first variant of the micropump of FIG. 4,
- FIG. 6 represents a sectional view of a second variant of the micropump of FIG. 4.
- the micropump shown in the figures is provided with a cylindrical body 1 enclosing a metering chamber 10.
- the chamber 10 has a variable volume being delimited by a piston 2 whose end 2a is capable of penetrating inside the bedroom.
- the chamber 10 communicates, on the one hand, with a reservoir (not shown) via a supply orifice 10a connected, if necessary, to a dip tube 4 and, on the other hand, with the outside via an orifice d ejection 10b connected here to a conduit 5.
- the supply orifice 10a is provided with an intake valve while the ejection orifice 10b is provided with an exhaust valve.
- the piston 2 is connected in its external part 2b to an alternative actuator such as an electric micromotor and possibly to a transmission member (not shown) likely to transform a rotational movement into translation and to communicate to the piston an axial reciprocating movement.
- an alternative actuator such as an electric micromotor and possibly to a transmission member (not shown) likely to transform a rotational movement into translation and to communicate to the piston an axial reciprocating movement.
- this movement has the effect, in the direction of withdrawal, of creating a depression in the chamber 10 and thus of sucking the liquid product P from the reservoir and in the other direction (direction of introduction) of compressing the product P via the supply orifice 10a and discharge it outwards into the chamber via the exhaust orifice 10b.
- At least one of the intake and exhaust valves to consist of a sealing element capable of being driven in alternative translation by friction contact with the internal part. 2a of the piston 2 and therefore the stroke inside the chamber 10 is less than that of the piston.
- This sealing element comprises at least one wall intended to come to close in a sealed and periodic manner, the supply orifice 10a or the ejection orifice 10b.
- the supply orifice 10a is formed axially in the bottom of the chamber 10, while the ejection orifice 10b is produced through the side wall of the body 1 in part high.
- the piston 2 is in the form of a solid cylindrical rod, with a bevelled lower edge.
- the shutter element here consists of a cylindrical-conical socket 3, the flat wall of the bottom 3a forms the intake valve and the cylindrical wall of the upper lateral edge 3b, the exhaust valve.
- the lower part of the sleeve 3 comprises at least one through-hole 30 ensuring the filling of the sleeve, with the liquid product P, during admission.
- the internal part 2a of the piston 2 is provided with a lateral grooving 20 and an upper peripheral lip 21 cooperating with a shoulder 11 of the body 1 for sealing and forming the upper stop of the stroke.
- the grooving 20 defines a cylindrical surface which provides friction contact against the inner dynamic side wall of the bush 3.
- the external lateral wall of the sleeve 3 has guide ribs 31 in contact with the internal wall of the chamber 10.
- the base 3a of the socket 3 and also, here, its upper rim 3c, comprise a peripheral ring 33 which comes into sealing abutment respectively downwards against the bottom 13a of the chamber 10 around the orifice 10a or towards the high against a constriction 13b bordering the orifice 10b.
- the distance separating the constriction 13b from the bottom 13a therefore delimits the axial stroke of the sleeve 3 in the chamber 10.
- the stroke of the piston 2 is, in turn, determined by the amplitude of movement of the actuator.
- the piston 2 In the intake phase, the piston 2 is pulled axially outward from the body 1 and here upward, by the actuator by frictionally driving the bushing 3 in the chamber 10 from the bottom 13a.
- This movement which constitutes the first stage of the pump operating cycle, raises the base 3a of the socket and releases the orifice 10a.
- the progressive withdrawal of the lip 21 of the piston 2 increases the free volume of the chamber 10 by creating a depression quickly compensated for by the arrival of the product P via the orifice 10a.
- the ejection orifice 10b Jointly, the ejection orifice 10b is closed by the wall of the upper edge 3b of the sleeve 3 thus preventing any parasitic entry of the product being downstream of the ejection orifice.
- the upper edge 3b of the sleeve 3 remains in sealed contact with the internal wall of the body 1.
- the openings 30 constitute an obligatory passage for the product P in the direction of the orifice 10b.
- the piston 2 is pushed axially towards the inside of the body 1 by the actuator. This movement is accompanied, firstly, by the descent of the sleeve 3 into the chamber 10 due to the friction contact connection.
- the sleeve 3 releases the ejection orifice 10b and opens the exhaust valve. Under the pressure created by the piston 2, the product P then exits through the conduit 5. When the rod 33 of the base 3a reaches the bottom 13a of the chamber, the intake valve closes and prevents any parasitic output of product through port 10a.
- the piston 2 continues its stroke and compresses the residue of product P still in the chamber 10 which flows through the slots 30 and the ribs 20 towards the orifice 10b, until the end of the travel of the piston 2.
- the four-stage cycle is completed and the new intake phase for the next cycle can begin immediately.
- the feed port 10a is formed through the side wall of the chamber 10 like the ejection port 10b but in the lower part and, here, diametrically opposite.
- the light 30 is produced, centrally, through the base 3a of the socket 3.
- This configuration which is simpler to manufacture, can also prove to be particularly advantageous from the point of view of the overall size of the pump in the packaging device.
- the body is produced in two parts 1a, 1b respectively lower and upper, secured to one another by means of snap-fastening members 14.
- the half-view on the left represents this variant in the final position of the delivery phase while the half-view on the right represents it in the final position of the intake phase.
- the internal part of the piston 2 is produced here in the form of a coupling sleeve 22 intended to frictionally cover a cylindrical central hub 32 carried by the sleeve 3.
- the piston 2 also comprises, in the upper part, a peripheral rib 23 in sealed sliding contact with the internal wall of the chamber 10.
- the upper edge of the sleeve 22 is connected via a flange 24 to its external part 2b ensuring the connection to the actuator.
- the side wall 25 of the sleeve 22 provides an intermediate space with the side wall 34 of the sleeve 3.
- the intake valve consists of the base 3a of the bushing provided with a peripheral ring 33 intended to surround the supply orifice 10a in a coaxial and sealed manner.
- the slots 30 are produced through the base 3a and outside the rod 33 radially.
- the sealing wall 3b of the exhaust valve is made in radial offset on the side wall 34 of the socket 3.
- the outside diameter of the socket 3 is slightly greater than the inside diameter of the chamber 10 and due to the flexibility of its wall lateral, the sleeve 3 is housed under elastic stresses in the upper part 1b of the body.
- the ejection orifice 10b opens axially and in the upper part into the chamber 10, while the supply orifice 10a is lateral.
- the closing element of the exhaust valve here consists of a rod 6 engaged on the one hand, with friction, in a central bore 26 of the piston 2 and provided, on the other hand, with a head 61 carrying a wall frustoconical 6b likely to come into support during the admission phase tight against the ejection orifice 10b, also frustoconical in profile, forming a valve.
- the head 61 of the valve comes into contact with the internal shoulder 10e by means of ribs or grooves 6c formed on the top of the head 61. These ribs or grooves 6c thus allow the passage of the product. forced out.
- the largest diameter of the head 61 is greater than that of the cylindrical body 6a of the rod 6.
- the head 61 is trapped with freedom of translation inside a cavity 10c, the transverse walls of which therefore form two end-of-travel stops and which communicate with the chamber 10 by a cylindrical conduit 10d.
- the profile of the upstream transverse wall of the cavity 10c, forming the valve seat and delimiting the ejection orifice 10b, is adapted to the frustoconical geometry of the wall 6b of the head 61.
- the shutter element of the intake valve consists of the side wall 25 of the piston 2 provided, where appropriate, with peripheral seals 27.
- the closing element of the intake valve consists of a jacket 7 in which is engaged, coaxially and with friction contact, the internal part 2a of the piston 2.
- the jacket 7 is produced with two different diameters so as to cooperate with an annular peripheral shoulder 17 formed on the internal lateral wall of the body 1 to limit its travel.
- the position of the shoulder 17 is determined in particular as a function of the height of the jacket 7, so that in the delivery phase, the free edge 7a of the external wall of the jacket 7 can come to seal supply port 10a.
- the piston 2 is therefore here in friction contact with two independent sealing elements, the respective strokes of which can be optimally adjusted.
- the ejection conduit 10d defines, at the intersection with the upstream wall of the cavity 10c, a wedge 10f ensuring in contact with the wall 6b a circular sealing line in the closed position of the valve exhaust.
- the pump comprises a cover 8 removably fixed (by screwing or snap-fastening) on the upper part of the body 1.
- the head 61 is here produced in cylindrical form with a ring 66 ensuring closing the ejection orifice 10b by sealed contact on a circular line with the inclined wall opposite.
- the cover 8 is provided with a spray orifice 80 and an upstream network of swirl channels (not shown) formed on its internal wall.
- the rod 6 of the closing element of the exhaust valve extends, beyond the head 61, by a core 60 capable of closing the vortex channels in its high position, in the discharge phase.
- the core 60 is made in one piece with the rod 6 and in the extension of the head 61.
- This cover 8 when the pump is stopped, is actuated by screwing or latching by applying pressure to the core 60 which forces the wall 6b of the rod head into contact with the wall of the orifice 10b. This positive contact ensures the overall tightness of the system, regardless of the stop position of the electric actuator. But when the actuator stops, the piston 2 is blocked in a random position.
Landscapes
- Reciprocating Pumps (AREA)
- Details Of Reciprocating Pumps (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Saccharide Compounds (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0016127 | 2000-12-12 | ||
FR0016127A FR2817848B1 (en) | 2000-12-12 | 2000-12-12 | ELECTRONIC MICROPUMP |
PCT/FR2001/003917 WO2002047826A1 (en) | 2000-12-12 | 2001-12-11 | Electronic micro-pump |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1351775A1 true EP1351775A1 (en) | 2003-10-15 |
EP1351775B1 EP1351775B1 (en) | 2010-02-10 |
Family
ID=8857527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01994873A Expired - Lifetime EP1351775B1 (en) | 2000-12-12 | 2001-12-11 | Electronic micro-pump |
Country Status (12)
Country | Link |
---|---|
US (1) | US7029249B2 (en) |
EP (1) | EP1351775B1 (en) |
JP (1) | JP4166570B2 (en) |
CN (1) | CN1250336C (en) |
AT (1) | ATE457204T1 (en) |
AU (1) | AU2002225077A1 (en) |
BR (1) | BR0116512A (en) |
CA (1) | CA2431169A1 (en) |
DE (1) | DE60141293D1 (en) |
FR (1) | FR2817848B1 (en) |
MX (1) | MXPA03005210A (en) |
WO (1) | WO2002047826A1 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8241228B1 (en) * | 2003-09-24 | 2012-08-14 | Microfabrica Inc. | Micro-scale and meso-scale hydraulic and pneumatic tools, methods for using, and methods for making |
US20050238506A1 (en) * | 2002-06-21 | 2005-10-27 | The Charles Stark Draper Laboratory, Inc. | Electromagnetically-actuated microfluidic flow regulators and related applications |
US7867193B2 (en) * | 2004-01-29 | 2011-01-11 | The Charles Stark Draper Laboratory, Inc. | Drug delivery apparatus |
US7867194B2 (en) | 2004-01-29 | 2011-01-11 | The Charles Stark Draper Laboratory, Inc. | Drug delivery apparatus |
KR100769980B1 (en) * | 2006-09-01 | 2007-10-25 | 한국전자통신연구원 | Sensory information in/output electronic pen and method for outputting smell information using the same |
US9046192B2 (en) | 2007-01-31 | 2015-06-02 | The Charles Stark Draper Laboratory, Inc. | Membrane-based fluid control in microfluidic devices |
US9475607B2 (en) * | 2008-10-01 | 2016-10-25 | Rehrig Pacific Company | Plastic beer keg |
CA2752830C (en) | 2009-04-20 | 2018-01-02 | Rehrig Pacific Company | Plastic beer keg |
US8017409B2 (en) | 2009-05-29 | 2011-09-13 | Ecolab Usa Inc. | Microflow analytical system |
US8967407B2 (en) * | 2009-07-27 | 2015-03-03 | Rehrig Pacific Company | Plastic beer keg |
US9434505B2 (en) * | 2010-01-26 | 2016-09-06 | Rehrig Pacific Company | Plastic beer keg |
ES2451394T3 (en) | 2010-11-09 | 2014-03-26 | Rehrig Pacific Company | Plastic beer barrel |
MX2011011908A (en) * | 2010-11-09 | 2012-05-21 | Rehrig Pacific Co | Plastic beer keg. |
JP6162047B2 (en) | 2011-02-02 | 2017-07-12 | ザ チャールズ スターク ドレイパー ラボラトリー インク | Drug delivery device |
US9670049B2 (en) | 2014-06-23 | 2017-06-06 | Rehrig Pacific Company | Plastic beer keg |
WO2019182745A1 (en) | 2018-03-19 | 2019-09-26 | Bryn Pharma, LLC | Epinephrine spray formulations |
US11174852B2 (en) | 2018-07-20 | 2021-11-16 | Becton, Dickinson And Company | Reciprocating pump |
CN110194364B (en) * | 2019-05-08 | 2021-03-02 | 胡乔生 | Two-stage metering distribution system and control method thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3187960A (en) * | 1964-05-08 | 1965-06-08 | Sterling Drug Inc | Non-metallic pump dispenser |
US3532446A (en) * | 1967-04-04 | 1970-10-06 | Margrete L Stinnes | Sliding seal and valve for reciprocating pump |
FR2403465A2 (en) * | 1977-09-16 | 1979-04-13 | Valois Sa | MANUAL PISTON PUMP FOR DISTRIBUTION OR SPRAYING |
ATE17158T1 (en) * | 1982-04-21 | 1986-01-15 | Kurt Stauffer | PISTON PUMP FOR LIQUIDS. |
US4740141A (en) * | 1982-09-29 | 1988-04-26 | Intevep, S.A. | Plunger with composite retention valve |
US4784584A (en) * | 1987-07-17 | 1988-11-15 | Oil-Rite Corporation | Metering device |
US5192006A (en) * | 1991-05-01 | 1993-03-09 | Risdon Corporation | Low profile pump |
US5188519A (en) * | 1991-07-11 | 1993-02-23 | Cvi Incorporated | Saturated fluid pumping apparatus |
FR2689570B1 (en) * | 1992-04-07 | 1994-05-27 | Serac Group | VOLUMETRIC PUMP. |
SI9600118A (en) * | 1995-04-13 | 1996-10-31 | Monturas Sa | Precompression pump sprayer |
JPH1122594A (en) * | 1997-06-30 | 1999-01-26 | Unisia Jecs Corp | Fuel pressurizng pump for fuel injection device |
-
2000
- 2000-12-12 FR FR0016127A patent/FR2817848B1/en not_active Expired - Fee Related
-
2001
- 2001-12-11 AU AU2002225077A patent/AU2002225077A1/en not_active Abandoned
- 2001-12-11 CA CA002431169A patent/CA2431169A1/en not_active Abandoned
- 2001-12-11 MX MXPA03005210A patent/MXPA03005210A/en active IP Right Grant
- 2001-12-11 US US10/432,637 patent/US7029249B2/en not_active Expired - Fee Related
- 2001-12-11 WO PCT/FR2001/003917 patent/WO2002047826A1/en active Application Filing
- 2001-12-11 CN CN01820476.7A patent/CN1250336C/en not_active Expired - Fee Related
- 2001-12-11 EP EP01994873A patent/EP1351775B1/en not_active Expired - Lifetime
- 2001-12-11 AT AT01994873T patent/ATE457204T1/en not_active IP Right Cessation
- 2001-12-11 BR BR0116512-7A patent/BR0116512A/en active Search and Examination
- 2001-12-11 DE DE60141293T patent/DE60141293D1/en not_active Expired - Lifetime
- 2001-12-11 JP JP2002549388A patent/JP4166570B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO0247826A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE457204T1 (en) | 2010-02-15 |
CA2431169A1 (en) | 2002-06-20 |
JP2004537667A (en) | 2004-12-16 |
CN1479653A (en) | 2004-03-03 |
WO2002047826A1 (en) | 2002-06-20 |
DE60141293D1 (en) | 2010-03-25 |
AU2002225077A1 (en) | 2002-06-24 |
US20040026461A1 (en) | 2004-02-12 |
FR2817848B1 (en) | 2003-03-07 |
JP4166570B2 (en) | 2008-10-15 |
BR0116512A (en) | 2004-01-06 |
MXPA03005210A (en) | 2003-09-25 |
FR2817848A1 (en) | 2002-06-14 |
US7029249B2 (en) | 2006-04-18 |
CN1250336C (en) | 2006-04-12 |
EP1351775B1 (en) | 2010-02-10 |
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Legal Events
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