EP1296775A1 - Liquid delivery apparatus - Google Patents
Liquid delivery apparatusInfo
- Publication number
- EP1296775A1 EP1296775A1 EP01943633A EP01943633A EP1296775A1 EP 1296775 A1 EP1296775 A1 EP 1296775A1 EP 01943633 A EP01943633 A EP 01943633A EP 01943633 A EP01943633 A EP 01943633A EP 1296775 A1 EP1296775 A1 EP 1296775A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- vessel
- valve
- liquid
- pressure
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/08—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/02—Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling time, or sequence, of delivery
- B05B12/06—Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling time, or sequence, of delivery for effecting pulsating flow
Definitions
- the present invention relates to a liquid delivery apparatus, such as a liquid delivery apparatus that is to be used for distributing liquid waste over agricultural land.
- valve between the reservoir and the outlet to control passage of liquid from the reservoir to the outlet, said valve having (a) an opening, (b) a closure member adapted to close the opening, and (c) a biasing means, the arrangement of the components of the valve being such that the valve is normally held closed under the force of the biasing means and the pressure of the liquid in the reservoir;
- valve control mechanism for controlling the operation of the valve in response to the pressure of the liquid in the reservoir
- valve control mechanism comprises a moveable element which is capable of being acted on by the pressure of the liquid in the reservoir and transmitting a resultant force to the closure member of the valve in a direction to open the valve, and wherein the respective effective surface areas of the moveable element and the closure member and the force of the biasing means are chosen such that the closure member is openable when the pressure of the liquid in the reservoir reaches a predetermined level.
- the liquid delivery apparatus disclosed in the aforesaid patents includes a housing and an inner moveable wall which sub-divides the housing into first and second chambers which are of variable volume depending upon the position of the inner moveable wall in the housing, the first chamber containing air as a compressible fluid and the second chamber defining the liquid reservoir, and the inner moveable wall being a flexible membrane such as a flexible bag.
- a liquid delivery apparatus comprising
- valve between the vessel and the outlet to control passage of liquid from the vessel to the outlet, said valve having (a) an opening, (b) a closure member adapted to close the opening, and (c) a biasing means, the arrangement of the components of the valve being such that the valve is normally held closed under the force of the biasing means and the pressure of the liquid and air in the vessel;
- valve control mechanism for controlling the operation of the valve in response to the pressure of the liquid and air in the vessel; and (v) a means for transmitting the pressure of the air in the vessel to the valve control mechanism; wherein the valve control mechanism comprises a moveable element which is capable of being acted on by the pressure of the air in the vessel and transmitting a resultant force to the closure member of the valve in a direction to open the valve, and wherein the respective effective surface areas of the moveable element and the closure member and the force of the biasing means are chosen such that the closure member is openable when the pressure of the liquid in the vessel reaches a predetermined level.
- the apparatus according to the first aspect of the invention does not have, or need to have, an inner moveable wall in the housing.
- the apparatus can be provided with a second vessel that includes an inner moveable wall (such as flexible member) .
- a liquid delivery apparatus comprising
- a first vessel into which a liquid may be introduced via an inlet to partially fill the first vessel and to pressurise the liquid that partially fills the first vessel and the air that fills the remainder of the first vessel;
- valve between the first vessel and the outlet to control passage of liquid from the first vessel to the outlet, said valve having (a) an opening,
- a valve control mechanism for controlling the operation of the valve in response to the pressure of the liquid and air in the first vessel;
- valve control mechanism comprises a moveable element which is capable of being acted on by the pressure of the air in the second chamber and transmitting a resultant force to the closure member of the valve in a direction to open the valve, and wherein the respective effective surface areas of the moveable element and the closure member and the force of the biasing means are chosen such that the closure member is opened when the pressure of the liquid and air in the first vessel reaches a predetermined level.
- the vessel into which the liquid is introduced, or the first and/or second vessels, as the case may be, is normally a rigid vessel, but could be a non-rigid vessel (e.g. a flexible or resilient vessel) if it is such that the liquid introduced therein, and the air present therein, can be pressurised therein.
- the inlet includes an upright tube extending upwardly into the vessel or the first vessel .
- the height of the tube in the vessel determines the level of liquid remaining in the vessel after discharge.
- a baffle plate is preferably disposed in the vessel or the first vessel, between the valve opening and the inlet, so as partially to subdivide the interior of the vessel or the first vessel into first and second compartments such that flow of liquid from one compartment to the other is possible.
- the inlet to the vessel or the first vessel may include a non-return valve.
- the moveable element of the valve control mechanism may comprise either a diaphragm in a pressure chamber or a bellows.
- the apparatus preferably includes means for varying the length of the bellows .
- the biassing means comprises a compression spring
- the apparatus includes means for varying the degree of compression of the compression spring.
- the means for transmitting the pressure to the valve control mechanism comprises either (a) a pressure line directly connecting the vessel to the pressure chamber containing the diaphragm or to the bellows, or (b) a first pressure line directly connecting the first vessel to the first chamber of the second vessel and a second pressure line directly connecting the second chamber of the second vessel to the pressure chamber containing the diaphragm or to the bellows.
- a regulating tank is disposed in the pressure line, or in either of both of the first and second pressure lines.
- the closure member of the valve is preferably one that is able to open in two or more stages in which the closure member has different effective surface areas such that the force required to open the valve is less in the second (or subsequent) stage than it is in the first (or previous) stage.
- the diaphragm or the bellows is acted on directly by the pressure of the liquid introduced via the inlet .
- the outlet via which the liquid may be discharged preferably comprises an upright rotatable discharge tube having one or more offset discharge nozzles connected thereto.
- a moveable flap may be mounted at the end of the discharge nozzle, or a moveable ball mounted in the discharge nozzle.
- the rotatable discharge tube has a rope or strap wound around it via which reciprocating movement of the rope or strap can cause or allow rotation of the discharge tube in a stepwise manner.
- the rotatable discharge tube is preferably rotated by a drive mechanism that in turn is driven by a bellows that in turn is driven by pressure change.
- the apparatus may further comprise a pump for pumping air into the vessel or the first vessel.
- Figure 1 is a view of a liquid delivery apparatus as already in use, in accordance with European Patent No. 0548159;
- FIGS 2 (and 2A) and 3 show various improvements, in accordance with the present invention, in the apparatus shown in Figure 1;
- FIGS. 4 (and 4A, 4B and 4C) and 5 show other liquid delivery apparatus in accordance with the present invention
- FIGS 6 and 7 show alternative valves for use in the apparatus shown in Figures 2 to 5;
- FIGs 8, 9 and 10 show regulator valves for use in the apparatus shown in Figures 2 to 5;
- Figure 11 shows a pump for use in the apparatus of Figures 2 to 5;
- Figure 12 shows an apparatus for rotating the nozzle arm of the apparatus of Figures 2 to 5;
- Figure 13 shows a flap that may be fitted at the end of the nozzle,- and
- FIG 14 shows a modification of the nozzle itself.
- an existing liquid delivery apparatus as more fully disclosed in European Patent No. 0548159 (and U.S. Patent No. 5316215) .
- Liquid under pressure is fed via an inlet 1 to a chamber 2 and from there via a filter 3 to the interior of a rubber bag 4 disposed within a cylindrical pressure vessel 5.
- the pressure within the bag 4 compresses the air in the annular space, around the bag, within the vessel 5.
- the annular space is connected via an air line 6 and a diaphragm relief valve 7 to a chamber 8 containing an actuating member, i.e. a diaphragm, of .a poppet valve 9.
- the introduction of liquid under pressure into the bag 4 causes an increase in pressure in the chamber 8 until, at a given pressure, as more fully disclosed in the above patents, the poppet valve 9 opens for a brief period of time to allow liquid under pressure to enter a chamber 10 and from there to be discharged from a nozzle 11.
- FIGS 2 and 3 show a modification of the apparatus of Figure 1.
- the pressure vessel 5 does not contain the rubber bag 4.
- a small slave accumulator 14, containing a diaphragm or bag 15, is disposed in the air line 6.
- the diaphragm 15 does not tend to scuff along the wall of the accumulator 14 (unlike the bag 4 in the vessel 5 of Figure 1) .
- a tube 16 ( Figures 2 and 2A) mounted on a mounting plate or bar 17 extending across the inlet to the pressure vessel 5, between the chamber 2 and the vessel 5, leaving two semicircular gaps between the bar
- the tube 16 and the mounting plate or bar 17 are so dimensioned that a vortex is created to allow excess air to be bled from the vessel 5 into the chamber 2.
- the rate of flow of liquid around the tube 16 has to be less than the rate of flow of liquid in the tube, so that a vortex is created around the top of the tube
- the height of the tube 16 controls the level of liquid in the vessel 5.
- a fixed baffle plate 18, containing a hole is shown in Figure 4.
- V-shaped slot 20 ( Figures 4A and 4B) , can be used to control the water level in the pressure vessel 5.
- the plate 18 (also shown in Figure 5) has a sloping semicircular portion extending from the walls of the vessel 5, and an upright rectangular portion extending downwardly from the sloping portion to leave a gap below it through which liquid can flow.
- the inlet 1 can be in the form of a non-return valve.
- the air line 6 can be connected directly to the chamber 8 containing the poppet valve actuating diaphragm (or a bellows, that can be used in place of the diaphragm) .
- the air line 6 can be connected to the chamber 8 via a small tank 21 ( Figure 4C) .
- a restriction can be placed in the line leading to the chamber 8, or in the line leading to the vessel 5, to control the time for which the poppet valve 9 is open.
- the restriction in the line leading to the chamber 8, and the size of the tank 21 can be varied to vary the speed of the opening and closing of the poppet valve 9 and the time for which it is open.
- Figure 5 shows on an enlarged scale the poppet valve 9 and the mechanism, in the form of a bellows 22, for actuating the poppet valve 9.
- the bellows 22 and the compression spring 13 are held between plates 23 and 24 (the spring 13 itself being held on plate 53) which in turn are mounted on threaded bars 25 (three or four, usually) and held by nuts.
- threaded bars 25 three or four, usually
- the apparatus shown in Figure 1 has proven to be satisfactory in use, but needs to have its performance improved, and needs to be made easier to service and cheaper to build. Also, the rubber bag 5 used as the bladder has a tendency to fail.
- the apparatus shown in Figure 2 is an improvement since the removal of the bag 4 from the vessel 5 increases reliability and the absence of the filter 3 increases flow and allows coarser materials to be handled. It is still necessary to use the diaphragm relief valve 7, the non-return valve 12 and filters as on the apparatus of Figure 1.
- the valve opening pressure is controlled by the diaphragm relief valve 7. If, for instance, the main valve 9 opens at 5 bar without the diaphragm relief valve 7, then, to make the valve 9 run reliably, the diaphragm relief valve 7 needs to be set at 5.5 bar, i.e. at a point which is above the point at which the poppet valve 9 could shimmer.
- the apparatus of Figures 4 and 5 is preferred in that it has no air control gear and no bag 4 or 15, since the opening pressure as well as the closing pressure of the poppet valve 9 are adjusted (or pre- set) on the valve itself.
- valves of the apparatus shown in Figures 1 to 3 have the problem that the valves tend to shimmer on their seats and not to open clearly (if they were to be used without the regulator valve) .
- FIG. 6 there is shown an alternative poppet valve layout that can be used in place of the poppet valve shown in Figures 1 to 3.
- This valve has a closure member 26 mounted on a shaft 27 that is moveable by the action of the compression spring 13 ( Figure 5) and the bellows 22 ( Figure 5) , or of the compression spring 13 and the poppet valve actuating diaphragm.
- the closure member 26 has a first seal 30 and a second seal 31.
- first seal 30 looses contact with its respective seat
- second seal 31 remains in contact with its respective seat.
- the second seal 31 looses contact with its respective seat.
- FIG 7 there is shown an alternative poppet valve layout that can be used in place of the poppet valve shown in Figures 1 to 3.
- This valve has a closure member 26 mounted on a shaft 27 that is moveable by the activation of a diaphragm 28 against the action of a compression spring 29.
- the closure member 26, like that of Figure 6, has a two stage opening area, i.e. a first seal 30 and a second seal 31, the first seal 30 being of larger diameter than the second seal 31 and the first seal 30 opening before the second seal 31 (as already described with reference to Figure 6) .
- This again overcomes the problem of the valve shown in Figures 1 to 3, namely the problem that the valve tends to shimmer on its seat and not to open cleanly.
- the valve seals 30 and 31 are preferably made of flexible rubber.
- the valve of Figure 7 is driven by the pressure of the liquid under pressure that enters the inlet of the valve. This (increasing) pressure acts on the diaphragm 28 until the pressure is sufficient to overcome the force exerted on the diaphragm by the spring 29 and on the closure member 26 by the liquid.
- the valve then opens in two stages for a short period of time (by movement of the closure member 26 to the right) , until the pressure falls to allow the diaphragm 28, and the closure member 26, to return to their original positions.
- the valve can alternatively be driven by a separate supply of air under pressure.
- One or more shims 32 can be located as shown to vary the pressure exerted by the spring 29 on the diaphragm 28.
- the diaphragm 28 can be replaced by a bellows.
- the shaft 27 and the diaphragm 28 (or bellows) can be replaced by a plunger, with the spring 29 being located within the plunger.
- the stoke of the bellows can be adjustable so as to vary the pressure at which the valve is activated, i.e. opens.
- the reciprocal movement of the shaft 27 ( Figures 6 and 7) can be used to do work, for example to rotate the nozzle.
- the shaft 27 can also be used to mechanically hold the valve open or closed.
- valves of Figures 6 and 7 The purpose of the valves of Figures 6 and 7 is to provide poppet valves that do not shimmer on their seats but rather open cleanly. Since there is no bag 4 in the tank 5, any regulator valve in the air line 6 has to be able to deal with dirt . These regulator valves are described below with reference to Figures 8, 9 and 10.
- seal 30 opens but seal 31 remains closed (since it runs parallel to the valve shaft) , and the pressure applied to surface 33 after seal 30 has opened makes sure that seal 31 opens.
- the effective areas of the two seals 30 and 31 are different, and seal 31 is well past its balance point by the time it is asked to open.
- the two-seal valves shown in Figures 6 and 7 overcome the problem of valve shimmering. However, this can be overcome by other means such as single rubber assembly. In its simplest form this can be a flexible part 70 able to flex so as to allow point 71 to open before point 72.
- a flap 75 can be fitted on the end of the nozzle 11 ( Figure 1) , as shown in Figure 13, which also shows a pivot point 76, a rubber seal 77 and a weight 78.
- any flap or steel ball mounted in the discharge tube could replace the two seal valve shown in Figures 6 and 7.
- Figures 8, 9 and 10 show regulator valves for use in regulating the apparatus of Figures 1 and 2.
- valves each having a diaphragm 34 on which impinges a jet of air from a nozzle 35, the valves being adjustable by rotation of a threaded shaft 36 that varies the pressure applied on the diaphragm 34 by a coil spring 37.
- FIGs 8, 9 and 10 replace the pressure valve 50 (consisting of diaphragm 52 and spring 54) of Figure 3 of European Patent No. 0548159 (i.e. to replace valve 7 of Figure 1 herein) .
- Figure 8 shows more detail of a first air regulation system. Part 51 is mounted so that face 52 comes into contact with plate 53 ( Figure 5) . When the main valve 9 closes, a gap forms at point 56 allowing spring 37 to close the regulator valve. Nozzle 35 is joined to air line 6 ( Figure 5) , and tube 54 is joined to the main tank 5 ( Figure 4) .
- the mode of operation of the regulator valve is as follows.
- spring 37 allows plunger 55 to release diaphragm 34 allowing air to pass from the tank to the bellows on the valve head.
- plate 53 Figure 5
- no spring pressure is exerted on plunger 55 giving free passage of air at point 56.
- gap 54 is reset ready for the next cycle.
- Figure 9 shows more detail of another air regulation system, which is not mechanically connected to main valve 9.
- Tube 35 is joined to the main tank 5 ( Figure 4) .
- Tube 57 is joined to air line 6 ( Figure 5) , and tube 58 is joined to air line 6 (to equalise the pressure in chamber 59) .
- Figure 10 shows more detail of a third air regulation system.
- the lever at point 63 is joined (usually by a spring) to plate 53.
- Tube 64 is joined to air line 6 ( Figure 5)
- tube 65 is joined to the main tank 5 ( Figure 4) .
- this regulator valve is as follows .
- spring 66 allows plunger 67 to release diaphragm 34 allowing air to pass from the tank 5 to the bellows on the valve head.
- the valve opens (because lever 68 is joined to the valve at plate 53) , all the spring pressure is released between plunger 67 and jet 64 allowing free passage of air so as not to restrict debris.
- the regulator is held open by a damper 69 until the main valve has closed.
- Figure 11 shows a diaphragm pump for pumping air into the pressure vessel 5, and consisting of a diaphragm 38, a spring 39, and inlet valve 40, an outlet valve 41, and a non-return valve 42.
- the diaphragm 38 separates the pump into chambers 43 and 44, the latter chamber being in communication with chamber 10 of the apparatus, so that the operation of the poppet valve 9 causes the diaphragm pump to operate to pump air into the pressure vessel 5.
- Figure 12 shows a mechanism for rotating the arm holding the nozzle 11.
- An assembly 45 is arranged to rotate around column 46, and a rope 47 is attached at points 48 to the rotating assembly 45, is wound around the assembly 45, and held tight by a spring 49.
- a diaphragm or bellows unit in communication with chamber 10 of the apparatus provides a reciprocating movement to the assembly 45.
- the drive could also be taken from the tank side of the poppet valve 9, as could the drive for the pump of Figure 11.
- Figure 14 shows another modification, in that the (main) nozzle 11, is provided with a second nozzle 80 at the end of a tube 81 connecting to the tube leading to the nozzle 11.
- the object of the two nozzles is to wet the ground evenly from the furthest range right back to the machine. Although the liquid from the nozzle does fall back as the pressure falls there can be an area in the middle which does not get wet enough.
- the second nozzle 80 is sized to overcome this problem.
Landscapes
- Devices For Dispensing Beverages (AREA)
- Loading And Unloading Of Fuel Tanks Or Ships (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Jet Pumps And Other Pumps (AREA)
- Nozzles (AREA)
- Coating Apparatus (AREA)
- Mechanically-Actuated Valves (AREA)
- Coating By Spraying Or Casting (AREA)
- Soil Working Implements (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0015992.1A GB0015992D0 (en) | 2000-06-29 | 2000-06-29 | Liquid delivery apparatus |
GB0015992 | 2000-06-29 | ||
PCT/GB2001/002830 WO2002002243A1 (en) | 2000-06-29 | 2001-06-26 | Liquid delivery apparatus |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1296775A1 true EP1296775A1 (en) | 2003-04-02 |
EP1296775B1 EP1296775B1 (en) | 2006-08-09 |
Family
ID=9894688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01943633A Expired - Lifetime EP1296775B1 (en) | 2000-06-29 | 2001-06-26 | Liquid delivery apparatus |
Country Status (11)
Country | Link |
---|---|
US (1) | US7048145B2 (en) |
EP (1) | EP1296775B1 (en) |
AT (1) | ATE335547T1 (en) |
AU (2) | AU6617101A (en) |
BR (1) | BR0112077B1 (en) |
CA (1) | CA2413781C (en) |
DE (1) | DE60122150T2 (en) |
ES (1) | ES2269420T3 (en) |
GB (1) | GB0015992D0 (en) |
MX (1) | MXPA02012866A (en) |
WO (1) | WO2002002243A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2661958A1 (en) * | 2012-04-13 | 2013-11-13 | David Mitchell | Liquid delivery apparatus |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011103094A2 (en) | 2010-02-18 | 2011-08-25 | Adco Products, Inc. | Multi-bead applicator |
US9566594B2 (en) | 2010-02-18 | 2017-02-14 | Adco Products, Llc | Adhesive applicator |
US9174234B2 (en) | 2010-02-18 | 2015-11-03 | Adco Products, Llc | Method of applying a polyurethane adhesive to a substrate |
US9089869B2 (en) | 2010-02-18 | 2015-07-28 | Adco Products, Llc | Adhesive bead applicator |
WO2011111037A1 (en) * | 2010-03-07 | 2011-09-15 | Netafim Ltd | A pulsating device |
US9381536B2 (en) | 2011-12-28 | 2016-07-05 | Adco Products, Llc | Multi-bead applicator |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4863101A (en) * | 1982-12-06 | 1989-09-05 | Acb Technology Corporation | Accelerating slugs of liquid |
US4809910A (en) * | 1986-06-06 | 1989-03-07 | Nelson Irrigation Corporation | Apparatus for providing a semiautomatic irrigation system |
WO1992004986A2 (en) | 1990-09-15 | 1992-04-02 | David Mitchell | Liquid delivery apparatus |
US5249745A (en) * | 1991-09-19 | 1993-10-05 | Giacomo Bertolotti | Fluid distribution system |
-
2000
- 2000-06-29 GB GBGB0015992.1A patent/GB0015992D0/en not_active Ceased
-
2001
- 2001-06-26 ES ES01943633T patent/ES2269420T3/en not_active Expired - Lifetime
- 2001-06-26 AU AU6617101A patent/AU6617101A/en active Pending
- 2001-06-26 AT AT01943633T patent/ATE335547T1/en not_active IP Right Cessation
- 2001-06-26 US US10/312,422 patent/US7048145B2/en not_active Expired - Lifetime
- 2001-06-26 AU AU2001266171A patent/AU2001266171B2/en not_active Ceased
- 2001-06-26 MX MXPA02012866A patent/MXPA02012866A/en active IP Right Grant
- 2001-06-26 DE DE60122150T patent/DE60122150T2/en not_active Expired - Lifetime
- 2001-06-26 CA CA2413781A patent/CA2413781C/en not_active Expired - Fee Related
- 2001-06-26 BR BRPI0112077-8A patent/BR0112077B1/en not_active IP Right Cessation
- 2001-06-26 WO PCT/GB2001/002830 patent/WO2002002243A1/en active IP Right Grant
- 2001-06-26 EP EP01943633A patent/EP1296775B1/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO0202243A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2661958A1 (en) * | 2012-04-13 | 2013-11-13 | David Mitchell | Liquid delivery apparatus |
US9381527B2 (en) | 2012-04-13 | 2016-07-05 | David Mitchell | Liquid delivery apparatus |
Also Published As
Publication number | Publication date |
---|---|
ES2269420T3 (en) | 2007-04-01 |
BR0112077B1 (en) | 2010-10-05 |
DE60122150D1 (en) | 2006-09-21 |
AU2001266171B2 (en) | 2005-08-11 |
BR0112077A (en) | 2003-05-06 |
CA2413781A1 (en) | 2002-01-10 |
MXPA02012866A (en) | 2004-07-30 |
AU6617101A (en) | 2002-01-14 |
ATE335547T1 (en) | 2006-09-15 |
GB0015992D0 (en) | 2000-08-23 |
CA2413781C (en) | 2011-08-16 |
US20040025965A1 (en) | 2004-02-12 |
US7048145B2 (en) | 2006-05-23 |
WO2002002243A1 (en) | 2002-01-10 |
DE60122150T2 (en) | 2007-09-13 |
EP1296775B1 (en) | 2006-08-09 |
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