EP1273230A1

EP1273230A1 - Wetting agent composition for agricultural chemicals

Info

Publication number: EP1273230A1
Application number: EP01919839A
Authority: EP
Inventors: K. Kao Corporation ResearchLabs. YAMAGUCHI; K. Kao Corporation Research Labs. KURITA; M. Kao Corporation HAYASHI
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2000-04-10
Filing date: 2001-04-09
Publication date: 2003-01-08
Anticipated expiration: 2021-04-09
Also published as: JP4083366B2; DE60136346D1; EP1273230B1; WO2001076365A1; US20030125212A1; EP1273230A4; JP2001288006A

Abstract

The present invention provides an agrochemical spreader composition having excellent low-temperature stability. Specifically, the present invention provides an agrochemical spreader composition comprising a surfactant (A) having a melting point of 20 to 60°C, a surfactant (B) having a melting point of not more than 0°C and water in a specific ratio.

Description

Field of the Invention

The present invention relates to an agrochemical spreader composition.

Background Art

Agricultural chemicals such as insecticides, fungicides, plant-growth hormones or herbicides can produce their effects only after they are absorbed in plants or animals such as pest insects. However, wax-lipoids are secreted, feathery fibers grow thick or fine irregularities are present on the surfaces of many plants and on the other hand, the same layer as a keratin is present on the surface of a pest insect. All these materials have such qualities as to repel aqueous solutions of agricultural chemicals. The problem that no intended effect can be obtained even in the case of spraying agricultural chemicals therefore arises.
In light of this, in order to compensate this drawback, agrochemical spreaders including emulsifiable concentrates and water-dispersible powders are widely used in agricultural fields with the intention of improving the wet spreading ability (wettability and extendibility) of agricultural chemicals. The agrochemical spreader is used to obtain the aforementioned wet spreading ability by lowering surface tension by using a surfactant as its major component and is also an important auxiliary controlling physicochemical characteristics such as emulsification, dispersion, penetration, fixation, suspension or defoaming abilities in practical use.
As the agrochemical spreader, nonionic surfactants such as polyoxyethylene sorbitan ester, polyoxyethylene alkyl (or aryl) ether or polyoxyethylene fatty acid ester, anionic surfactants such as straight-chain alkylbenzene sulfonate, dialkylsulfosuccinate, lignin sulfonate or polynaphthyl sulfonate and high molecular compounds such as polyacrylates are conventionally known.
In order to improve the effect of the agrochemical spreader, it is considered to alter the material quality and composition of a surfactant which is a major component of the spreader. Alkylene oxide addition type nonionic surfactants in particular are considered to be effective for this purpose because the material qualities of these surfactants can be changed with ease by controlling the number of the addition mols of alkylene oxide and the like. There are descriptions that a specific alkylene oxide addition type nonionic surfactant is used for the agrochemical spreader in, for example, JP-A-6-329503, JP-A-9-278605 and JP-A-10-231202. Also, an agrochemical spreader composition comprising sorbitan fatty acid ester, polyoxyethylene alkyl ether and polyether modified silicone in a specific ratio is disclosed in JP-A-2000-1404.
Generally, because nonionic surfactants used for the agrochemical spreader have a relatively low melting point, many agrochemical spreaders using these nonionic surfactants are liquid materials. However, there is the case where nonuniformity and solidification of formulations are caused by the type and compounding amount of nonionic surfactant. Many agrochemical spreaders are compounded in agricultural formulations (liquid materials in general) and therefore, when such a solidification problem as aforementioned arises, a lot of time and labor are needed for heating and the workability is impaired.

Disclosure of the Invention

It is an object of the present invention to provide an agrochemical spreader composition which has an excellent low-temperature stability and may be easily handled with maintaining the performance as an agrochemical spreader.
The present invention resides in the agrochemical spreader composition comprising a surfactant (A) having a melting point of 20 to 60°C and a surfactant (B) having a melting point of not more than 0°C in a total amount of not less than 50% by weight and water in an amount of 10 to 45% by weight.
At least one of the surfactants (A) and (B) is preferably a nonionic surfactant. The nonionic surfactant is preferably one type selected from the group consisting of a polyoxyalkylene alkyl ether, a polyoxyalkylene alkylphenyl ether, a polyoxyalkylene polyhydric alcohol fatty acid ester, a polyhydric alcohol fatty acid ester, a polyoxyalkylene alkylamine, an alkyl polyglycoside and a glycidyl ether.
As preferable examples, (A) is a polyoxyalkylene alkyl ether. Also, (B) is a polyoxyalkylene alkylamine. It is more preferably that (A) be a polyoxyalkylene alkyl ether and (B) be a polyoxyalkylene alkylamine.
(A) or (B) is preferably a compound which is positively electrified.
The ratio by weight of the surfactant (A) to the surfactant (B), (A)/(B), is preferably 2/1 to 1/2. The surfactant (A) may be contained in an amount of 30 to 50% by weight.
The present invention also provides a use of the above composition as an agrochemical spreader. Further, the present invention provides a method of spreading an agricultural chemical, the method comprising adding the above composition to an agricultural chemical and bringing the agricultural chemical into contact with a subject. The present invention resides in an agrochemical composition comprising the above spreader composition and an agricultural chemical.
The spreader composition of the present invention may be used efficiently to spread an agricultural chemical on subjects such as plants, animals such as pest insects and plant disease fungi such as bacteria or fungi. The spreading of an agricultural chemical can improve the spreading ability (wettability and extendibility) and penetrability of the agricultural chemical.
When the composition contains particularly a compound, such as polyoxyalkylene alkylamine, which is positively electrified, the permeability through a cell membrane is also improved. Thus, the effect of an agricultural chemical is improved whereby the agricultural chemical can be made to act more efficiently.

Embodiment of the Invention

As the surfactants (A) and (B) according to the present invention, nonionic surfactants, cationic surfactants, amphoteric surfactants and anionic surfactants may be included. At least one of the surfactants (A) and (B) is preferably a nonionic surfactant. As the nonionic surfactant, one or more types selected from polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenyl ethers, polyoxyalkylene polyhydric alcohol fatty acid esters, polyhydric alcohol fatty acid esters, polyoxyalkylene alkylamines, alkyl polyglycosides and glycidyl ethers are preferable. Examples of polyhydric alcohols constituting a nonionic surfactant include divalent alcohols such as ethyleneglycol, 1,2-propylene glycol, 1,3-propyleneglycol, 1,4-butanediol, 2,3-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol or 2-methyl-1,3-propanediol, trivalent alcohols such as glycerol, trimethylolpropane, trimethylolethane, 1,2,6-hexanetriol or sorbide, tetravalent alcohols such as pentaerythritol, erythritol, sorbitan, diglycerol or ditrimethylolpropane, pentavalent alcohols such as fructose, glucose, galactose, mannose, xylitol or triglycerol, hexavalent alcohols such as sorbitol, mannitol, inositol, tetraglycerol or dipentaerythritol, octavalent alcohols such as sucrose, maltose, lactose or hexaglycerol and dodecavalent alcohols such as decaglycerol or polyglycerols having more hydroxyl groups than these alcohols.
In these compounds, those having a desired melting point can be obtained by changing the structures of components, such as the number of the carbons of an alkyl group, the state as to whether unsaturated bonds or branched structures are present or not and the type and the number of addition mols of alkylene oxide. Examples of the surfactant (A) include:
(A1) polyoxyethylene [number of average addition mols of ethylene oxide (hereinafter referred to as EOp) = 9 to 45] lauryl ether;
(A2) polyoxyethylene (EOp = 5 to 10) stearyl ether;
(A3) polyoxyethylene (EOp = 13 to 33) oleyl ether;
(A4) polyoxyethylene (EOp = 18 to 28) nonylphenyl ether;
(A5) polyoxyethylene (EOp = 40 to 80) hydrogenated caster oil;
(A6) polyoxyethylene (EOp = 15) oleylamine;
(A7) polyoxyethylene (EOp = 2) stearylamine;
(A8) polyoxyethylene (EOp = 61) styrenated phenyl ether;
(A9) oleic acid monoglyceride; and
(A10) polyoxyethylene (Eop = 99) monostearate.
As the surfactant (A), a polyoxyethylene alkyl ether of which the alkyl group has 12 to 18 carbon atoms and which has an EOp of 9 to 13 is desirable.
Also, examples of the surfactant (B) include;
(B1) polyoxyethylene (EOp = 5 to 7) secondary alkyl (11 to 14 carbon atoms) ether;
(B2) polyoxyethylene (EOp = 8 to 9) octylphenyl ether;
(B3) polyoxyethylene (EOp = 3 to 8) nonylphenyl ether;
(B4) polyoxyethylene (EOp = 10 to 20) polyhydric alcohol fatty acid (hydrogenated caster oil composition) ester;
(B5) sorbitan mono-, di- or tri-oleate;
(B6) polyoxyethylene (EOp = 10 to 20) sorbitan monooleate; and
(B7) polyoxyethylene (EOp = 2 to 5) coconut amine.
As the surfactant (B), a polyoxyethylene alkylamine of which the alkyl group has 12 to 14 carbon atoms and which has an EOp of 2 to 5 is desirable.
The agrochemical spreader composition of the present invention contains the surfactants (A) and (B) in a total amount of not less than 50% by weight, more preferably 60 to 80% by weight and still more preferably 70 to 80% by weight. Also, in the present invention, the ratio by weight of the surfactant (A) to the surfactant (B) , (A) / (B) , is 2/1 to 1/2 and particularly 1.5/1 to 1/1.5. Also, it is preferable to contain the surfactant (A) in an amount of preferably 30 to 50% by weight, more preferably 30 to 45% by weight and particularly preferably 35 to 45% by weight.
The agrochemical spreader composition of the present invention contains water in an amount of 10 to 45% by weight, preferably 10 to 40% by weight, more preferably 10 to 30% by weight and particularly preferably 10 to 20% by weight. The above surfactant (A) is a component for improving wettability. It, however, has a high melting point and there is therefore a tendency to impair low-temperature stability when it is used in combination with the surfactant (B). However, if water besides the surfactants (A) and (B) is present in an amount falling in the above range, the low-temperature stability of the composition is improved. It is to be noted that although an agrochemical spreader is occasionally diluted with water and mixed with an agrochemical formulation, the water contained in the composition of the present invention is discriminated from the water used for dilution in use. The agrochemical spreader composition of the present invention like this is a transparent liquid at 15°C. Here, the transparent means that the composition is uniform and has no turbidity found by visual observation.
The agrochemical spreader composition of the present invention may contain a sticking agent such as carboxymethyl cellulose or casein and a dispersing agent such as a naphthalenesulfonic acid formaldehyde condensate or lignin sulfonate.
The agrochemical spreader composition of the present invention may be used for agrochemical formulations containing various agrochemical active components. Examples of the agrochemical active component include herbicides such as a phenoxy type herbicide, diphenyl ether type herbicide, carbamate type herbicide, acid amide type herbicide, urea type herbicide, sulfonylurea type herbicide, triazine type herbicide, diazine type herbicide, diazole type herbicide, bipipyridium type herbicide, dinitroaniline type herbicide, aromatic carboxylic acid type herbicide, fatty acid type herbicide, organic phosphorous type herbicide or amino acid type herbicide; fungicides such as a copper fungicide, inorganic fungicide, organic sulfur fungicide, organic chlorine type fungicide, organic phosphorous type fungicide, benzimidazole type fungicide, acid amide type fungicide, ergosterol biosynthesis inhibitor or antibiotic fungicide; and insecticides such as an organic phosphorous type insecticide, carbamate type insecticide, pyrothroid type insecticide, nereistoxin type insecticide or insect growth control agent, which are all described in "AGROCHEMICAL HANDBOOK, 1994 Edition" (Corporation Japan Plant Protection Association, December 21, 1994). The composition of the present invention is preferably used for, particularly, agrochemical formulations containing an amino acid herbicide as an active component.
The agrochemical spreader composition of the present invention is used for the production of agrochemical formulations containing agrochemical active components. Specifically, the agrochemical spreader composition is subjected to a method of the production of the agrochemical formulations which method has a step of adding the composition of the present invention in any one of production steps. In this case, the composition of the present invention may be compounded (internally added) as one of components constituting the agrochemical formulation in any one of a series of steps for the production of the agrochemical formulation or may be further compounded (externally added) in the agrochemical formulation prepared separately. The internal addition is preferable. In any case, the compound of the present invention is preferably compounded in the agrochemical formulation such that the total amount of the surfactants (A) and (B) in the agrochemical formulation is preferably 10 to 50% by weight, more preferably 20 to 40% by weight and particularly preferably 25 to 35% by weight.

Effect of the Invention

According to the present invention, a liquid agrochemical spreader composition having low-temperature stability is obtained.

Examples

Example 1

Agrochemical spreader compositions having percentage compositions shown in Table 1 were prepared. The outward appearance of each composition after stored at 10°C for 5 days was observed according to the following standard. The transparent melting point (according to JIS K 0064) and freezing point (according to JIS K 0065) of the composition were also measured. The results are shown in Table 1.

○: Uniform and transparent.
Δ: Turbid.
×: Separated or solidified.

Example 2

Agrochemical spreader compositions having percentage compositions shown in Table 2 were prepared. The outward appearance of each composition after stored at 10°C for 7 days was evaluated in the same manner as in Example 1. The results are shown in Table 2.

Example 3

Agrochemical spreader compositions having percentage compositions shown in Table 3 were prepared. The outward appearance of each composition after stored at 15°C for one day was evaluated. The results are shown in Table 3.

Claims

An agrochemical spreader composition comprising a surfactant (A) having a melting point of 20 to 60°C and a surfactant (B) having a melting point of not more than 0°C in a total amount of not less than 50% by weight and water in an amount of 10 to 45% by weight.
A composition according to Claim 1, wherein at least any one of the surfactants (A) and (B) is preferably a nonionic surfactant.
A composition according to Claim 2, wherein the nonionic surfactant is one type selected from the group consisting of a polyoxyalkylene alkyl ether, a polyoxyalkylene alkylphenyl ether, a polyoxyalkylene polyhydric alcohol fatty acid ester, a polyhydric alcohol fatty acid ester, a polyoxyalkylene alkylamine, an alkyl polyglycoside and a glycidyl ether.
A composition according to Claim 1, wherein (A) is a polyoxyalkylene alkyl ether.
A composition according to Claim 1, wherein (B) is a polyoxyalkylene alkylamine.
A composition according to Claim 1, wherein (A) is a polyoxyalkylene alkyl ether and (B) is a polyoxyalkylene alkylamine.
A composition according to Claim 1, wherein the ratio by weight of the surfactant (A) to the surfactant (B) , (A)/(B), is 2/1 to 1/2.
A composition according to Claim 1, wherein the surfactant (A) is contained in an amount of 30 to 50% by weight.
A use of the composition according to Claim 1 as an agrochemical spreader.
A method of spreading an agricultural chemical, the method comprising adding the composition according to Claim 1 to an agricultural chemical and bringing the agricultural chemical into contact with a subject.
An agrochemical composition comprising the spreader composition according to Claim 1 and an agricultural chemical.