EP1023424B1 - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- EP1023424B1 EP1023424B1 EP98947649A EP98947649A EP1023424B1 EP 1023424 B1 EP1023424 B1 EP 1023424B1 EP 98947649 A EP98947649 A EP 98947649A EP 98947649 A EP98947649 A EP 98947649A EP 1023424 B1 EP1023424 B1 EP 1023424B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silicone
- ceramide
- detergent composition
- detergent
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Definitions
- This invention relates to a laundry detergent composition which is suitable for laundering fine fabric materials such as wool, silk, nylon, polyester and the like under relatively mild washing conditions.
- Laundry detergent compositions generally employ anionic surfactants as the primary detergent-active compounds, such as alkyl benzene sulphonates, fatty alcohol sulphates or alkyl glycol ether sulphates.
- anionic surfactants damage the fibre structure of sensitive fabrics upon repeated washing.
- Fine fabric wash formulations tend to contain a blend of anionic surfactants with non-ionic or amphoteric surfactants.
- the non-ionic surfactants are intended to increase detergency.
- sensitive woollen fabrics are washed with non-ionics, the fabrics tend to feel comparatively hard and brittle. These effects can be intensified with machine washing.
- amphoteric surfactants do not completely counteract the loss of feel and, although amphoteric surfactants act as fibre-softening agents, some anionic and non-ionic surfactants reduce the softening effect of the amphoteric surfactants. Also, most known softening agents which are incorporated into detergents are detrimental to cleaning performance.
- a laundry detergent composition for washing delicate fabrics comprising:
- the detergent composition comprises:
- the silicone is a silicone fluid, more preferably a silicone emulsion, and most preferably a silicone micro-emulsion
- suitable silicones are polyalkyl or polyaryl silicones.
- Particularly preferred silicones are polydimethylsiloxanes, with organic groups incorporated into the basic silicone backbone, having the following structure: wherein R is an amino, polyether, epoxy, hydroxyl, polyether/amino, polyether/epoxy or cyclohexyl functional group;
- A may be any group suitable for ending the silicone chains, for example a hydrogen, methyl or hydroxyl group; and a and b are integers, preferably between 7 and 5000.
- Suitable silicones are those marketed under the trade names DC 225 (produced by Dow Corning Corporation) and Magnasoft EM 410 (produced by Witco).
- the concentration of silicone in the compositions of the invention suitably lies in the range from 0.05 to 5 wt %, preferably 0.1 to 2 wt % and most preferably the silicone concentration is about 0.5 wt %.
- the ceramide present in the composition of the present invention may be a natural ceramide or a synthetic ceramide, for example an N-acylsphingenine or a derivative thereof.
- the amide-linked fatty acids are generally characterised by a C 16 to C 26 , C 30 /w-OH or C 32 /w-OH chain.
- the long chain amine may be sphingosine or sphinganine or phytosphingosine.
- ceramides are Bis (N-hydroxyethyl cetyl) Malanamide which is marketed under the trade name Questamide H and produced by Quest (this is synthetic "ceramide 2", with ceramide 2 being naturally found in hair) ; myristyl palmitado -serinate which is marketed under the trade name ceramide A2 and produced by Sederma; Palmitadohexadecanediol which is marketed under the trade name Ceramide II and produced by Quest and a glycosphingolipid marketed under the trade name ceramide PG5 and produced by Seporga.
- composition of the present invention may contain only one ceramide, or, alternatively, two or more different ceramides may be present.
- the concentration of ceramide in the compositions of the invention suitably lies in the range from 0.001 to 5 wt %, preferably 0.001 to 2 wt % and most preferably 0.01 to 1 wt %.
- the composition of the present invention further includes detergent-active compounds. Many suitable detergent-active compounds are available and are fully described in the literature.
- the total amount of surfactant present in the composition of the present invention ranges from 2 to 60 wt % by weight of the total fine fabric detergent composition, preferably 5 to 40 wt %, and most preferably 10 to 20 wt %.
- anionic surfactant is not limited and any anionic surfactant suitable for use in a laundry composition may be used.
- suitable anionic surfactants are alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; primary and secondary alkyl sulphates, particularly C 8 - C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates and fatty acid ester sulphonates.
- Sodium salts are generally preferred.
- Particularly preferred anionic surfactants are sodium lauryl ether sulphate, which is available under the trade name EMPICOL ESC3 from Albright & Wilson; sodium lauryl sulphate, which is available under the trade name EMPICOL LX from Albright & Wilson; ⁇ -olefine sulphonate, which is available under the trade name RHODACAL A 246 L from Rhône-Poulenc and disodium lauryl sulphonsuccinate, which is available under the trade name REWOPOL 5B F12 from Witco.
- the anionic surfactants are desirably present in amounts of 2 to 30 wt %, preferably 5 to 20 wt %, and most suitably the anionic surfactant concentration is about 10 wt %.
- non-ionic surfactant is also not limited and any non-ionic surfactant suitable for use in a laundry composition may be used.
- suitable non-ionic surfactants are primary and secondary alcohol ethoxylates, especially the C 8 - C 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and most particularly the C 10 - C 15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
- Non-ethoxylated non-ionic surfactants include alkyl polyglycosides, glycerol monoethers, alkanol amides and polyhdroxyamides (glucamide).
- non-ionic surfactants are Coceth-6 (PEG ether of coconut alcohol); Coceth-10(PEG ether of coconut alcohol); Laureth-6 (PEG ether of lauryl alcohol); Lauramide DEA, which is availble under the trade name EMPILAN 26224 from Albright & Wilson; and lauryl polyglucoside, which is available under the trade name PLANTEREN 1200CS/UP from Henkel.
- the non-ionic surfactants are desirably present in amount of 0 to 20 wt %, preferably 0.5 to 10 wt %, and most suitably about 1 to 2 wt %.
- amphoteric surfactants are cocoamidopropylbetaine, such as that available under the trace name EMPIGEN from Albright & Wilson and amine oxides, such as lauramine oxide, which is available under the trade name TEGAMINE OXIDE W from Goldsch.
- amphoteric surfactants are desirably present in amounts of 0.5 to 2C wt % and preferably 0.5 to 10 wt %.
- compositions of the present invention can optionally contain relatively minor amounts of the usual types of non-surfactant auxiliary ingredients as are commonly employed in conventional laundry detergents, for example inorganic salts such as sodium carbonate, sodium sulphate or sodium silicate (where the composition is a powder) ; anti-redeposition agents such as cellulosic polymers; preservatives; optical brighteners; pearlescing agents; colourants; viscosifying agents such as sodium chloride and pH regulators such as citric acid.
- inorganic salts such as sodium carbonate, sodium sulphate or sodium silicate (where the composition is a powder)
- anti-redeposition agents such as cellulosic polymers
- preservatives such as cellulosic polymers
- optical brighteners such as pearlescing agents
- colourants such as sodium chloride and pH regulators such as citric acid.
- Detergent compositions of the invention may be of any suitable form, for example powders or granules, liquids or gels.
- the manner in which the detergent compositions are prepared or formulated is not particularly critical and such may be prepared by methods well known to those skilled in the art.
- the detergent compositions of the present invention are especially well suited and beneficial for the laundering under relatively mild washing conditions (e.g. mild or gentle machine agitation or hand washing and at low or cold wash water temperature) of fine fabric materials such as knitted fabrics of wool and silk, nylon and polyester.
- relatively mild washing conditions e.g. mild or gentle machine agitation or hand washing and at low or cold wash water temperature
- fine fabric materials such as knitted fabrics of wool and silk, nylon and polyester.
- these fabrics do not become hard, but instead retain their natural softness, not only with hand washing but also with machine washing.
- a fine fabric wash detergent composition was prepared from the following ingredients: Component wt% Nature Trade name ⁇ -olefine Sulphonate 5.2 Anionic surfactant RHODACAL A 246 L (RP) Sodium Lauryl Sulphate 8.3 Anionic surfactant EMPICOL LX (A&W) Lauyl Polyglucoside 1.0 Non-ionic Surfactant PLANTEREN 1200CS/UP (HENKEL) Lauramide DEA 0.75 Non-ionic Surfactant EMIPLAN 26224 (A&W) Cocoamidopropyl betaine 2.5 Amphoteric surfactant EMPIGEN (A&W) Amino-functional silicone emulsion 1.1 silicone MAGNASOFT Em.
- a fine fabric wash detergent composition was prepared from the following ingredients: Component wt% Nature Trade name Sodium Lauryl Ether Sulphate 3.5 Anionic surfactant EMPICOL ESC3 (A&W) Sodium Lauryl Sulphate 4.3 Anionic surfactant EMPICOL LX (A&W) Coceth-6 1.6 Non-ionic surfactant REWOPAL LA 6 (Witco) Lauramide DEA 0.5 Non-ionic surfactant EMIPLAN 26224 (A&W) Lauramine oxide 2.5 Amphoteric surfactant TEGAMINE OXIDE W (Goldsch.) Amino-functional silicone emulsion 0.6 silicone MAGNASOFT Em.
- a fine fabric wash detergent composition was prepared from the following ingredients: Component wt% Nature Trade name Disoduium Lauryl sulphosuccinate 4.2 Anionic surfactant REWOPOL SB F12 (Witco) Sodium Lauryl Sulphate 6.6 Anionic surfactant EMPICOL LX (A&W) Coceth-10 1.4 Non-ionic surfactant REWOPAL LA 10 (Witco) Cocamidopropyl betaine 2.9 Amphoteric surfactant EMPIGEN (A&W) Cyclohexylamino-functional silicone emulsion 1.5 silicone FINISH CT1 10 (Wacker) Palmitadohexadenediol 1.0 Ceramide CERAMIDES II (Quest) Palmitamido serinate de myristyl 0.5 Ceramide CERAMIDE A2 (Seporga) Citric Acid 0.05 pH regulator Preservative 0.05 Dye 0.01 Fragrance 0.2 Deionised Water qsp 100
- a fine fabric wash detergent composition was prepared from the following ingredients: Component wt% Nature Trade name Sodium Alkyl Benzene sulphonate 8.2 Anionic surfactant REWOPOL SB F12 (Witco) Sodium Lauryl Ether Sulphate 8.6 Anionic surfactant EMPICOL LX (A&W) Lauryl Polyglucoside 2.6 Non-ionic Surfactant PLANTEREN 1200CS UP (HENKEL) Lauramide DEA 0.75 Non-ionic Surfactant EMIPLAN 26224 (A&W) Lauramine oxide 2.3 Amphoteric surfactant TEGAMINE OXIDE W (Goldsch.) Amino-functional silicone emulsion 4.5 silicone DC 225 (Witco) Bishydroxyethyl biscetyl Malonamide 2.25 Ceramide QUESTAMIDE H (Quest) Glycosphingolipids 2.5 Ceramide CERAMIDE PG5 (Seporga) Citric Acid 0.05 pH regulator Preservative 0.05 Dye 0.01 Fragrance
- a fine fabric wash detergent composition was prepared from the following ingredients: Component wt% Nature Trade name Sodium Alkyl Benzene sulphonate 15.5 Anionic surfactant REWOPOL SB F12 (Witco) Coceth-6 5.0 Non-ionic surfactant REWOPAL LA 6 (Witco) Sodium Cocoate 3.0 Soap NORFOX COCO POWDER (Norman) Sodium silicoaluminate (Zeolite) 23.0 Builder WESSALITH S (Degussa) Sodium silicate 3.0 Builder Sodium carbonate 5.0 Builder Sodium bicarbonate 15.0 Builder Sodium sulphate 15.0 Filler Cychlohexylamino-functional silicone emulsion 1.5 Silicone FINISH CT110 (Wacker) Glycosphingolipids 2.5 Ceramide CERAMIDE PG5 (Seporga) Sodium citrate 10.0 Fragrance 0.2 Water qsp 100
- Wool fibres of diameter 0.1 - 0.14 mm were evaluated for elasticity using a Rheometrics RSA 2 Solids analyser fitted with a monofilament geometry to give a sample length of 24 mm.
- the test used was a steady strain rate test using a constant strain rate of 0.0001 s -1 with the temperature controlled at 20°C. This allowed measurement of Youngs modulus for a strain between 2 and 3% in the elastic region of the wool fibre which is equal to the elastic modules G 1 . Values of G 1 are given in the table below: Elasticity.
- the fabrics were hand-washed with 35 ml of the detergent diluted in 5 litres of water (middle hardness water) at 30°C and then rinsed twice in 5 litres of cold water.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Component | wt% | Nature | Trade name |
α-olefine Sulphonate | 5.2 | Anionic surfactant | RHODACAL A 246 L (RP) |
Sodium Lauryl Sulphate | 8.3 | Anionic surfactant | EMPICOL LX (A&W) |
Lauyl Polyglucoside | 1.0 | Non-ionic Surfactant | PLANTEREN 1200CS/UP (HENKEL) |
Lauramide DEA | 0.75 | Non-ionic Surfactant | EMIPLAN 26224 (A&W) |
Cocoamidopropyl betaine | 2.5 | Amphoteric surfactant | EMPIGEN (A&W) |
Amino-functional silicone emulsion | 1.1 | silicone | MAGNASOFT Em. 410 (Witco) |
Palmitadohexadenediol | 0.9 | Ceramide | CERAMIDES II (Quest) |
Citric Acid | 0.05 | pH regulator | |
Preservative | 0.05 | ||
Dye | 0.01 | ||
Fragrance | 0.20 | ||
Deionised Water | qsp 100 |
Component | wt% | Nature | Trade name |
Sodium Lauryl Ether Sulphate | 3.5 | Anionic surfactant | EMPICOL ESC3 (A&W) |
Sodium Lauryl Sulphate | 4.3 | Anionic surfactant | EMPICOL LX (A&W) |
Coceth-6 | 1.6 | Non-ionic surfactant | REWOPAL LA 6 (Witco) |
Lauramide DEA | 0.5 | Non-ionic surfactant | EMIPLAN 26224 (A&W) |
Lauramine oxide | 2.5 | Amphoteric surfactant | TEGAMINE OXIDE W (Goldsch.) |
Amino-functional silicone emulsion | 0.6 | silicone | MAGNASOFT Em. 410 (Witco) |
Bishydroxyethyl biscetyl malonamide | 0.5 | Ceramide | QUESTAMIDE H (Quest) |
Citric Acid | 0.05 | pH regulator | |
Sodium chloride | 2.0 | ||
Preservative | 0.05 | ||
Dye | 0.01 | ||
Fragrance | 0.2 | ||
Deionised Water | qsp 100 |
Component | wt% | Nature | Trade name |
Disoduium Lauryl sulphosuccinate | 4.2 | Anionic surfactant | REWOPOL SB F12 (Witco) |
Sodium Lauryl Sulphate | 6.6 | Anionic surfactant | EMPICOL LX (A&W) |
Coceth-10 | 1.4 | Non-ionic surfactant | REWOPAL LA 10 (Witco) |
Cocamidopropyl betaine | 2.9 | Amphoteric surfactant | EMPIGEN (A&W) |
Cyclohexylamino-functional silicone emulsion | 1.5 | silicone | FINISH CT1 10 (Wacker) |
Palmitadohexadenediol | 1.0 | Ceramide | CERAMIDES II (Quest) |
Palmitamido serinate de myristyl | 0.5 | Ceramide | CERAMIDE A2 (Seporga) |
Citric Acid | 0.05 | pH regulator | |
Preservative | 0.05 | ||
Dye | 0.01 | ||
Fragrance | 0.2 | ||
Deionised Water | qsp 100 |
Component | wt% | Nature | Trade name |
Sodium Alkyl Benzene sulphonate | 8.2 | Anionic surfactant | REWOPOL SB F12 (Witco) |
Sodium Lauryl Ether Sulphate | 8.6 | Anionic surfactant | EMPICOL LX (A&W) |
Lauryl Polyglucoside | 2.6 | Non-ionic Surfactant | PLANTEREN 1200CS UP (HENKEL) |
Lauramide DEA | 0.75 | Non-ionic Surfactant | EMIPLAN 26224 (A&W) |
Lauramine oxide | 2.3 | Amphoteric surfactant | TEGAMINE OXIDE W (Goldsch.) |
Amino-functional silicone emulsion | 4.5 | silicone | DC 225 (Witco) |
Bishydroxyethyl biscetyl Malonamide | 2.25 | Ceramide | QUESTAMIDE H (Quest) |
Glycosphingolipids | 2.5 | Ceramide | CERAMIDE PG5 (Seporga) |
Citric Acid | 0.05 | pH regulator | |
Preservative | 0.05 | ||
Dye | 0.01 | ||
Fragrance | 0.2 | ||
Deionised Water | qsp 100 |
Component | wt% | Nature | Trade name |
Sodium Alkyl Benzene sulphonate | 15.5 | Anionic surfactant | REWOPOL SB F12 (Witco) |
Coceth-6 | 5.0 | Non-ionic surfactant | REWOPAL LA 6 (Witco) |
Sodium Cocoate | 3.0 | Soap | NORFOX COCO POWDER (Norman) |
Sodium silicoaluminate (Zeolite) | 23.0 | Builder | WESSALITH S (Degussa) |
Sodium silicate | 3.0 | Builder | |
Sodium carbonate | 5.0 | Builder | |
Sodium bicarbonate | 15.0 | Builder | |
Sodium sulphate | 15.0 | Filler | |
Cychlohexylamino-functional silicone emulsion | 1.5 | Silicone | FINISH CT110 (Wacker) |
Glycosphingolipids | 2.5 | Ceramide | CERAMIDE PG5 (Seporga) |
Sodium citrate | 10.0 | ||
Fragrance | 0.2 | ||
Water | qsp 100 |
Elasticity. | |
Wool without treatment | 9.66 x 107 Pa/% |
Wool washed 3 times with water only | 3.23 x 107 Pa/% |
Wool washed 3 times with detergent formulation containing a ceramide | 3.73 x 107 Pa/% |
Wool washed 3 times with detergent formulation containing a ceramide plus a silicone emulsion | 6.79 x 107 Pa/% |
Fabric | Formulation 1 vs Formulation 2 | Formulation 3 vs Formulation 4 | ||
Formulation 1 | Formulation 2 | Formulation 3 | Formulation 4 | |
Wool | 90% | 10% | 75% | 25% |
Wool/Acrylic | 75% | 25% | 80% | 20% |
Claims (8)
- A laundry detergent composition for washing delicate fabrics comprising:a) one or more anionic, non-ionic or amphoteric surfactants or a mixture of two or more thereof;b) a natural and/or synthetic ceramide;c) a silicone; andd) optionally other detergent ingredients.
- A detergent composition according to Claim 1, wherein the silicone is an amino-functional silicone.
- A detergent composition according to Claim 2, wherein the silicone is a microemulsion of a polydimethylsiloxane.
- A detergent composition according to claim 1, comprising:a) 2 to 60 wt % of one or more anionic, non-ionic or amphoteric surfactants or a mixture of two or more thereof;b) from 0.001 to 5 wt % of one or more ceramides;c) from 0.05 to 5 wt % of a polydimethylsiloxane; andd) optionally other detergent ingredients to 100 wt %.
- A detergent composition according to any of claims 1 to 4, wherein the ceramide is selected from Bis (N-hydoxyethyl cetyl) Malonamide; Palmitadohexadecanediol; Palmitado-serinate de myristyl and glycosphingolipids.
- A process for laundering fabric materials comprising the steps of immersing the material, with at least mild agitation, in a detergent composition comprising:a) one or more anionic, nonionic or amphoteric surfactants or a mixture of two or more thereof;b) a natural and/or synthetic ceramide;c) a silicone; andd) optionally other detergent ingredients.
- A process for laundering fabric materials comprising the steps of immersing the material, with at least mild agitation, in a detergent composition comprising:a) 2 to 60 wt % of one or more anionic, non-ionic or amphoteric surfactants or a mixture of two or more thereof.b) from 0.001 to 5 % of one or more ceramides;c) from 0.05 to 5 wt % of an aminopolydimethyl siloxane; andd) optionally other detergent ingredients to 100 wt %.
- A process according to Claim 6 or 7, wherein the fabric material laundered thereby is a silk,nylon, polyester or wool fabric material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98947649A EP1023424B1 (en) | 1997-10-07 | 1998-10-07 | Detergent composition |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97402358 | 1997-10-07 | ||
EP97402358 | 1997-10-07 | ||
PCT/GB1998/002987 WO1999018177A1 (en) | 1997-10-07 | 1998-10-07 | Detergent composition |
EP98947649A EP1023424B1 (en) | 1997-10-07 | 1998-10-07 | Detergent composition |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1023424A1 EP1023424A1 (en) | 2000-08-02 |
EP1023424B1 true EP1023424B1 (en) | 2002-09-11 |
Family
ID=8229872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98947649A Expired - Lifetime EP1023424B1 (en) | 1997-10-07 | 1998-10-07 | Detergent composition |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1023424B1 (en) |
AU (1) | AU9449198A (en) |
DE (1) | DE69807910T2 (en) |
GB (1) | GB2330148A (en) |
WO (1) | WO1999018177A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4126379A4 (en) * | 2020-04-01 | 2024-05-22 | Energizer Auto, Inc. | Hydrophobic finish car wash compositions and methods of use thereof |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6995124B1 (en) | 1998-10-24 | 2006-02-07 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine |
US6966696B1 (en) | 1998-10-24 | 2005-11-22 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine |
US7185380B2 (en) | 1998-10-24 | 2007-03-06 | The Procter & Gamble Company | Methods for laundering delicate garments in a washing machine comprising a woven acrylic coated polyester garment container |
DE10109845A1 (en) * | 2001-03-01 | 2002-09-05 | Basf Ag | Emulsifiers, in particular based on polyisobutylene amines |
GB2388610A (en) † | 2002-05-17 | 2003-11-19 | Procter & Gamble | Detergent composition containing silicone and fatty acid |
CZ293989B6 (en) * | 2003-02-24 | 2004-09-15 | Universita Karlova V Praze, Farmaceutická Fakulta | Transdermal penetration accelerants |
MX2010010070A (en) * | 2008-03-14 | 2010-10-04 | Procter & Gamble | Low sudsing hand washing liquid laundry detergent. |
CN103484266A (en) * | 2013-09-10 | 2014-01-01 | 无为县荣华鬃刷制品有限公司 | Formula of horsehair cleaning liquor |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4639321A (en) * | 1985-01-22 | 1987-01-27 | The Procter And Gamble Company | Liquid detergent compositions containing organo-functional polysiloxanes |
JPH0248520A (en) * | 1988-08-10 | 1990-02-19 | Pola Chem Ind Inc | Cleaning agent |
FR2648821A1 (en) * | 1989-06-22 | 1990-12-28 | Rhone Poulenc Chimie | |
AU680841B2 (en) * | 1992-11-03 | 1997-08-14 | Quest International B.V. | Method of synthesising phytosphingosine-containing ceramides and cosmetic compositions comprising them |
FR2739284B1 (en) * | 1995-09-29 | 1997-11-07 | Oreal | COMPOSITION FOR THE TREATMENT OF KERATINIC MATERIALS COMPRISING AT LEAST ONE GRAFTED SILICONE POLYMER AND AT LEAST ONE FATTY CHAIN AMIDE AND USES THEREOF |
-
1998
- 1998-10-07 DE DE69807910T patent/DE69807910T2/en not_active Expired - Fee Related
- 1998-10-07 AU AU94491/98A patent/AU9449198A/en not_active Abandoned
- 1998-10-07 GB GB9821813A patent/GB2330148A/en not_active Withdrawn
- 1998-10-07 WO PCT/GB1998/002987 patent/WO1999018177A1/en active IP Right Grant
- 1998-10-07 EP EP98947649A patent/EP1023424B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4126379A4 (en) * | 2020-04-01 | 2024-05-22 | Energizer Auto, Inc. | Hydrophobic finish car wash compositions and methods of use thereof |
Also Published As
Publication number | Publication date |
---|---|
DE69807910D1 (en) | 2002-10-17 |
GB2330148A (en) | 1999-04-14 |
DE69807910T2 (en) | 2003-05-22 |
EP1023424A1 (en) | 2000-08-02 |
AU9449198A (en) | 1999-04-27 |
GB9821813D0 (en) | 1998-12-02 |
WO1999018177A1 (en) | 1999-04-15 |
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