EP0882811A1 - Method of carburizing metallic workpieces in a vacuum furnace - Google Patents
Method of carburizing metallic workpieces in a vacuum furnace Download PDFInfo
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- EP0882811A1 EP0882811A1 EP97108860A EP97108860A EP0882811A1 EP 0882811 A1 EP0882811 A1 EP 0882811A1 EP 97108860 A EP97108860 A EP 97108860A EP 97108860 A EP97108860 A EP 97108860A EP 0882811 A1 EP0882811 A1 EP 0882811A1
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- carbon
- carbon carrier
- carburizing
- partial pressure
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/36—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding
- C23C8/38—Treatment of ferrous surfaces
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
- C23C8/22—Carburising of ferrous surfaces
Definitions
- the invention relates to a method for carburizing metallic workpieces in a vacuum furnace, the furnace atmosphere being a carbon carrier contains, under the process conditions of carburization with the release of pure carbon is split.
- thermochemical case hardening treatments metallic workpieces have been in addition to the conventional gas carburizing is increasingly the carburizing processes in Vacuum systems enforced, because only with these procedures Carburization free of edge oxidation is feasible.
- these Carburizing processes in vacuum plants are the vacuum and plasma carburizing. Since in these carburizing processes without oxygen-containing reaction gases is working, no C level control respectively; the key parameter for the carbon transition is at this method the carbon mass flow density, which as The amount of carbon is defined per unit of time and area in the Material passes over.
- This carbon required for carburization is from a carbon carrier in the furnace atmosphere - usually one Hydrocarbon - provided at the given Process conditions with the release of pure carbon is split.
- propane C 3 H 8
- propane C 3 H 8
- propane C 3 H 8
- propane pyrolysis methane (CH 4 ) is mostly used as the carbon carrier, which is obtained by methane pyrolysis according to the equation CH 4 ⁇ C + 2H 2 is split.
- propane instead of methane.
- methane or propane as a carbon carrier is in each case associated with various advantages and disadvantages.
- propane due to its larger number of carbon atoms - 3 carbon atoms for propane versus 1 carbon atom for methane - a more effective carbon carrier as methane.
- propane has the disadvantage that it is already thermally split in the temperature range above 600 ° C, which leads to Sooting of the oven and tar formation in the oven can result.
- methane only has one carbon atom, but it is the methane molecule so stable that it is not already necessary Carburizing temperature is split. Rather, the split takes place only in Plasma and therefore really only on the workpiece surface. Since the Carbon mass flow density is low when splitting methane, For large batches, large quantities of process gas must be sent to the furnace be fed.
- Partial pressure of the carbon carrier pulsates towards higher partial pressures vary so that the increasing the carbon mass flow density Partial pressure of the carbon carrier only briefly to increase the Carburizing effect is available, but then decreases again, so that the soot formation can be kept within limits. Because of the partial high partial pressure of the carbon carrier of up to 100 mbar however, even in this method operated with pressure pulses gradual sooting of the furnace so that it still closes Cleaning purposes must be switched off.
- the invention has for its object to provide a method for carburizing metallic workpieces in a vacuum furnace, which ensures a constant carburization with a high carbon mass flow density, without the risk of sooting the furnace .
- the carbon carrier is a hydrocarbon with a carbon-hydrogen ratio of 1: 1 is used, preferably acetylene.
- a partial pressure of the carbon carrier of less than 20 mbar, preferably 10 mbar, observed in order to achieve a high without soot formation Carbon mass flow density or carbon transfer rate achieve.
- Carburizing the partial pressure of the carbon carrier pulsating can be varied, the partial pressure of the carbon carrier values from to reached to 50 mbar.
- the furnace atmosphere can also contain other gases, in particular Contain hydrogen and / or argon, which additionally as the inert gases Prevent oxidation of the workpieces.
- the Splitting of the carbon carrier can be supported by a plasma.
- Vacuum carburization with the carbon carriers propane and ethane took place at 860 ° C and with a partial pressure of the carbon carrier of 10 mbar.
- the vacuum carburization with the carbon carrier acetylene was carried out at 930 ° C and a partial pressure of the carbon carrier of 10 mbar a carburizing and diffusion phase period of 260 min.
- the above-described uniform carburization on the outer and The inner surface of the test workpiece is also shown in the illustrations 2 to 4, in which the surface hardness and the case hardening depth (HV 1.0) is shown at different measuring points.
- a comparison of the graphics 3 and 4 shows that when using acetylene as a carbon carrier not just an almost constant surface hardness along the inner and outer workpiece surface is achieved, but also the Case hardening depth (HV 1.0) on the inner and outer Workpiece surface coincides almost at all measuring points.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
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Abstract
Description
Die Erfindung betrifft ein Verfahren zur Aufkohlung metallischer Werkstücke in einem Vakuum-Ofen, wobei die Ofenatmosphäre einen Kohlenstoff-Träger enthält, der unter den Prozeßbedingungen der Aufkohlung unter Abgabe von reinem Kohlenstoff gespalten wird.The invention relates to a method for carburizing metallic workpieces in a vacuum furnace, the furnace atmosphere being a carbon carrier contains, under the process conditions of carburization with the release of pure carbon is split.
Unter den thermochemischen Behandlungsverfahren zur Einsatzhärtung metallischer Werkstücke haben sich in den letzten Jahren neben der konventionellen Gasaufkohlung immer mehr die Aufkohlungsprozesse in Vakuumanlagen durchgesetzt, da nur mit diesen Verfahren eine randoxidationsfreie Aufkohlung realisierbar ist. Bei diesen Aufkohlungsprozessen in Vakuumanlagen handelt es sich um die Unterdruck- und die Plasmaaufkohlung. Da bei diesen Aufkohlungsverfahren ohne sauerstoffhaltige Reaktionsgase gearbeitet wird, kann keine C-Pegelregelung erfolgen; die entscheidende Kenngröße für den Kohlenstoffübergang ist bei diesen Verfahren die Kohlenstoff-Massenstromdichte, die als Kohlenstoffmenge definiert ist, die pro Zeit- und Flächeneinheit in den Werkstoff übergeht. Dieser zur Aufkohlung benötigte Kohlenstoff wird von einem in der Ofenatmosphäre befindlichen Kohlenstoff-Träger - meist einem Kohlenwasserstoff - zur Verfügung gestellt, der bei den gegebenen Prozeßbedingungen unter Abgabe von reinem Kohlenstoff gespalten wird.Among thermochemical case hardening treatments metallic workpieces have been in addition to the conventional gas carburizing is increasingly the carburizing processes in Vacuum systems enforced, because only with these procedures Carburization free of edge oxidation is feasible. With these Carburizing processes in vacuum plants are the vacuum and plasma carburizing. Since in these carburizing processes without oxygen-containing reaction gases is working, no C level control respectively; the key parameter for the carbon transition is at this method the carbon mass flow density, which as The amount of carbon is defined per unit of time and area in the Material passes over. This carbon required for carburization is from a carbon carrier in the furnace atmosphere - usually one Hydrocarbon - provided at the given Process conditions with the release of pure carbon is split.
Bei den bekannten Unterdruck-Aufkohlungsverfahren wird als Kohlenstoff-Träger
in der Regel Propan (C3H8) verwendet, welches im Laufe der
sogenannten Propanpyrolyse nach folgenden Reaktionsgleichungen gespalten
wird:
Die Verwendung von Methan oder Propan als Kohlenstoff-Träger ist jeweils mit verschiedenen Vor- und Nachteilen verbunden. So ist beispielsweise Propan aufgrund seiner größeren Anzahl von Kohlenstoffatomen - 3 C-Atome bei Propan gegenüber 1 C-Atom bei Methan - ein wirksamerer Kohlenstoff-Träger als Methan. Andererseits weist Propan jedoch den Nachteil auf, daß es bereits im Temperaturbereich über 600°C thermisch gespalten wird, was zum Verrußen des Ofens sowie zur Teerbildung im Ofen führen kann. Die frühe Dissoziation des Propan schon bei niedrigen Temperaturen hat darüber hinaus zur Folge, daß bei der Behandlung dicht gepackter Chargen sowie von Werkstücken mit schwierig zugängigen Oberflächen, wie beispielsweise Sacklochbohrungen, der dissoziierte Kohlenstoff überwiegend außen an der Charge abgegeben wird, so daß die Aufkohlungswirkung in der Chargenmitte geringer ist. Dasselbe gilt nicht nur für dicht gepackte Chargen, sondern auch für Bohrungen, insbesondere Sacklochbohrungen, bei denen der Kohlenstoff überwiegend an der Bohrungsöffnung abgegeben wird und im Inneren der Bohrung kaum noch eine Aufkohlungswirkung nachzuweisen ist.The use of methane or propane as a carbon carrier is in each case associated with various advantages and disadvantages. For example Propane due to its larger number of carbon atoms - 3 carbon atoms for propane versus 1 carbon atom for methane - a more effective carbon carrier as methane. On the other hand, however, propane has the disadvantage that it is already thermally split in the temperature range above 600 ° C, which leads to Sooting of the oven and tar formation in the oven can result. The early one Dissociation of the propane even at low temperatures has beyond that as a result that in the treatment of tightly packed batches and of Workpieces with difficult to access surfaces, such as Blind holes, the dissociated carbon predominantly on the outside of the Batch is released so that the carburizing effect in the middle of the batch is less. The same applies not only to tightly packed batches, but also for bores, in particular blind holes, in which the carbon is predominantly dispensed at the bore opening and inside the There is hardly any carburizing effect in the bore.
Methan hingegen weist zwar nur ein C-Atom auf, jedoch ist das Methan-Molekül so stabil, daß es nicht bereits bei der notwendigen Aufkohlungstemperatur gespalten wird. Die Spaltung erfolgt vielmehr erst im Plasma und somit wirklich nur an der Werkstückoberfläche. Da die Kohlenstoff-Massenstromdichte bei der Spaltung von Methan gering ist, müssen bei großflächigen Chargen große Mengen an Prozeßgas dem Ofen zugeführt werden.In contrast, methane only has one carbon atom, but it is the methane molecule so stable that it is not already necessary Carburizing temperature is split. Rather, the split takes place only in Plasma and therefore really only on the workpiece surface. Since the Carbon mass flow density is low when splitting methane, For large batches, large quantities of process gas must be sent to the furnace be fed.
Wie bereits voranstehend angedeutet, liegt ein weiteres Problem bei den aus dem Stand der Technik bekannten Aufkohlungsverfahren darin, daß mit zunehmendem Kohlenstoff-Wasserstoff-Verhältnis (C/H) des Kohlenstoff-Trägers die Rußbildung im Ofen zunimmt. Bei Methan, CH4 (C/H = 0,25), ist der Rußanfall gering, bei Ethan, C2H6 (C/H = 0,33), ist der Rußanfall mittelgroß, bei Propan, C3H8 (C/H = 0,375) groß und bei Butan, C4H10 (C/H = 0,4) sehr hoch. Somit stehen sich bei der Optimierung der Aufkohlungsverfahren in Vakuum-Öfen zwei widerstreitende Forderungen bzw. Prozesse gegenüber, nämlich einerseits die Forderung nach einer Erhöhung des Kohlenstoff-Wasserstoff-Verhältnisses beim Kohlenstoff-Träger zur Erhöhung der Kohlenstoff-Massenstromdichte zur Erzielung einer besseren Aufkohlungswirkung und andererseits die zunehmende Rußbildung bei der Erhöhung des Kohlenstoff-Wasserstoff-Verhältnisses beim Kohlenstoff-Träger. Eine zur Erhöhung der Kohlenstoff-Massenstromdichte angestrebte Erhöhung des Partialdruckes des Kohlenstoff-Trägers erhöht dabei zusätzlich die Rußbildung im Ofen.As already indicated above, a further problem with the carburizing processes known from the prior art is that with increasing carbon-hydrogen ratio (C / H) of the carbon carrier, the soot formation in the furnace increases. With methane, CH 4 (C / H = 0.25), the soot accumulation is low, with ethane, C 2 H 6 (C / H = 0.33), the soot accumulation is medium, with propane, C 3 H 8 ( C / H = 0.375) large and very high for butane, C 4 H 10 (C / H = 0.4). Thus, when optimizing the carburizing processes in vacuum furnaces, there are two conflicting demands or processes, namely on the one hand the demand for an increase in the carbon-hydrogen ratio in the carbon carrier to increase the carbon mass flow density to achieve a better carburizing effect and on the other hand the increasing soot formation with the increase in the carbon-hydrogen ratio in the carbon carrier. An increase in the partial pressure of the carbon support aimed at increasing the carbon mass flow density additionally increases the soot formation in the furnace.
Zur Reduzierung der Rußbildung bei steigendem Partialdruck des Kohlenstoff-Trägers ist es beispielsweise aus der US-PS 3 796 615 bekannt, den Partialdruck des Kohlenstoff-Trägers pulsierend auf höhere Partialdrücke zu variieren, so daß der die Kohlenstoff-Massenstromdichte erhöhende Partialdruck des Kohlenstoff-Trägers nur kurzzeitig zur Erhöhung der Aufkohlungswirkung zur Verfügung steht, danach jedoch wieder absinkt, so daß die Rußbildung in Grenzen gehalten werden kann. Aufgrund des teilweise hohen Partialdruckes des Kohlenstoff-Trägers von bis zu 100 mbar liegt jedoch selbst bei diesem mit Druckpulsen betriebenen Verfahren eine allmähliche Verrußung des Ofens vor, so daß dieser immer noch zu Reinigungszwecken abgeschaltet werden muß.To reduce soot formation with increasing partial pressure of the carbon carrier it is known, for example, from US Pat. No. 3,796,615 Partial pressure of the carbon carrier pulsates towards higher partial pressures vary so that the increasing the carbon mass flow density Partial pressure of the carbon carrier only briefly to increase the Carburizing effect is available, but then decreases again, so that the soot formation can be kept within limits. Because of the partial high partial pressure of the carbon carrier of up to 100 mbar however, even in this method operated with pressure pulses gradual sooting of the furnace so that it still closes Cleaning purposes must be switched off.
In Anbetracht des voranstehend geschilderten Standes der Technik liegt der Erfindung die Aufgabe zugrunde, ein Verfahren zur Aufkohlung metallischer Werkstücke in einem Vakuum-Ofen bereitzustellen, das eine gleichbleibende Aufkohlung mit einer hohen Kohlenstoff-Massenstromdichte gewährleistet, ohne daß gleichzeitig die Gefahr der Verrußung des Ofens besteht.In view of the above-described prior art, the invention has for its object to provide a method for carburizing metallic workpieces in a vacuum furnace, which ensures a constant carburization with a high carbon mass flow density, without the risk of sooting the furnace .
Überraschenderweise hat sich herausgestellt, daß diese Aufgabe erfindungsgemäß dadurch gelöst wird, daß als Kohlenstoff-Träger ein Kohlenwasserstoff mit einem Kohlenstoff-Wasserstoff-Verhältnis von 1:1, vorzugsweise Acetylen, verwendet wird.Surprisingly, it has been found that this object is achieved in that as the carbon carrier is a hydrocarbon with a carbon-hydrogen ratio of 1: 1 is used, preferably acetylene.
Überraschend bei der Verwendung von Acetylen als Kohlenstoff-Träger ist nicht nur die sehr gute und gleichmäßige Aufkohlungswirkung auch bei schwierig zugänglichen Werkstücken, sondern insbesondere die Tatsache, daß trotz des hohen Kohlenstoff-Wasserstoff-Verhältnisses von 1:1 so gut wie keine Ruß- und Teerbildung auftritt. Die gute Aufkohlungswirkung bei der Verwendung von Acetylen als Kohlenstoff-Träger läßt sich damit erklären, daß aufgrund des hohen Kohlenstoff-Wasserstoff-Verhältnisses auch schon bei geringen Partialdrücken des Kohlenstoff-Trägers eine ausreichende Kohlenstoff-Massenstromdichte zur Verfügung steht, um eine gleichbleibende und ausreichende Aufkohlung zu erzielen.Is surprising when using acetylene as a carbon carrier not only the very good and even carburizing effect difficult to access workpieces, but especially the fact that despite the high carbon-hydrogen ratio of 1: 1 as good as no soot and tar formation occurs. The good carburizing effect at Use of acetylene as a carbon carrier can be explained by the fact that due to the high carbon-hydrogen ratio low partial pressures of the carbon carrier an adequate Carbon mass flow density is available to a constant and to achieve sufficient carburization.
Gemäß einer ersten bevorzugten erfindungsgemäßen Verfahrensweise wird mit Vorteil ein Partialdruck des Kohlenstoff-Trägers von unter 20 mbar, vorzugsweise 10 mbar, eingehalten, um ohne Rußbildung eine hohe Kohlenstoff-Massenstromdichte bzw. Kohlenstoff-Übertragungsrate zu erzielen. Dabei kann gemäß einer Verfahrensvariante des erfindungsgemäßen Aufkohlungsverfahrens der Partialdruck des Kohlenstoff-Trägers pulsierend variiert werden, wobei der Partialdruck des Kohlenstoff-Trägers Werte von bis zu 50 mbar erreicht.According to a first preferred procedure according to the invention advantageously a partial pressure of the carbon carrier of less than 20 mbar, preferably 10 mbar, observed in order to achieve a high without soot formation Carbon mass flow density or carbon transfer rate achieve. According to a variant of the method according to the invention Carburizing the partial pressure of the carbon carrier pulsating can be varied, the partial pressure of the carbon carrier values from to reached to 50 mbar.
Neben dem Kohlenwasserstoff mit einem Kohlenstoff-Wasserstoff-Verhältnis von 1:1 kann die Ofenatmosphäre zusätzlich noch weitere Gase, insbesondere Wasserstoff und/oder Argon enthalten, welche als Inertgase zusätzlich die Oxydation der Werkstücke verhindern sollen.In addition to the hydrocarbon with a carbon-hydrogen ratio 1: 1, the furnace atmosphere can also contain other gases, in particular Contain hydrogen and / or argon, which additionally as the inert gases Prevent oxidation of the workpieces.
Bei einer erfindungsgemäßen Weiterbildung des Verfahrens kann die Aufspaltung des Kohlenstoff-Trägers durch ein Plasma unterstützt werden. In a further development of the method according to the invention, the Splitting of the carbon carrier can be supported by a plasma.
Weitere Merkmale und Vorteile des erfindungsgemäßen Verfahrens ergeben sich aus den nachfolgenden Erläuterungen, die auf die beigefügten Zeichnungen Bezug nehmen. In der Zeichnung zeigt:
- Fig. 1
- einen schematischen Längsschnitt durch ein Probewerkstück mit zugehörigem Tabellenwerk, die Oberflächenhärtewerte auf der Innenseite des Probewerkstücks bei verschiedenen Kohlenstoff-Trägern wiedergebend;
- Fig. 2
- eine Seitenansicht des Probewerkstücks gemäß Fig. 1 mit der Angabe verschiedener Meßpunkte für den Härteverlauf an der Außen- und Innenseite des Probewerkstücks;
- Fig. 3
- eine graphische Darstellung des Härteverlaufs an den Meßpunkten A, C und E gemäß Fig. 2 an der Außenseite des Probewerkstücks nach der Einsatzhärtung mit Acetylen und
- Fig. 4
- eine graphische Darstellung des Härteverlaufs an den Meßpunkten B, D, F und H gemäß Fig. 2 an der Innenseite des Probewerkstück nach der Einsatzhärtung mit Acetylen.
- Fig. 1
- a schematic longitudinal section through a test workpiece with associated tables, showing the surface hardness values on the inside of the test workpiece with different carbon carriers;
- Fig. 2
- a side view of the sample workpiece according to FIG 1 with the specification of various measuring points for the hardness curve on the outside and inside of the sample workpiece.
- Fig. 3
- a graphical representation of the hardness curve at the measuring points A, C and E according to FIG. 2 on the outside of the test workpiece after case hardening with acetylene and
- Fig. 4
- a graphical representation of the hardness curve at the measuring points B, D, F and H according to FIG. 2 on the inside of the test workpiece after case hardening with acetylene.
In der Zeichnung mit dem zugehörigen Tabellenwerk ist für ein Rohr aus dem
Werkstoff 16 MnCr 5 mit einer abgestuften Durchgangsbohrung der Verlauf
der Oberflächenhärte auf der Innenseite des Rohres nach dem
Unterdruckaufkohlen mit den Kohlenstoff-Trägern Acetylen, Propan und Ethan
vergleichend dargestellt.In the drawing with the associated tables is for a pipe from the
Die Unterdruckaufkohlung mit den Kohlenstoff-Trägern Propan und Ethan erfolgte bei 860°C und mit einem Partialdruck des Kohlenstoff-Trägers von 10 mbar. Die Unterdruckaufkohlung mit dem Kohlenstoff-Träger Acetylen erfolgte bei 930°C und einem Partialdruck des Kohlenstoff-Trägers von 10 mbar über einen Zeitraum für die Aufkohlungs- und Diffusionsphase von 260 min.Vacuum carburization with the carbon carriers propane and ethane took place at 860 ° C and with a partial pressure of the carbon carrier of 10 mbar. The vacuum carburization with the carbon carrier acetylene was carried out at 930 ° C and a partial pressure of the carbon carrier of 10 mbar a carburizing and diffusion phase period of 260 min.
Wie aus der Abbildung sowie dem zugehörigen Tabellenwerk ersichtlich ist, wurden mit den aus dem Stand der Technik bekannten Kohlenstoff-Trägern Propan und Ethan Oberflächenhärten von etwa 60 HRC und mehr nur in den Randbereichen der Bohrungen, das heißt bis zu einer Bohrungstiefe von etwa 50 mm von beiden Bohrungsöffnungen her gesehen, erzielt. Dahingegen lag bei der Verwendung von Propan als Kohlenstoff-Träger der Wert der Oberflächenhärte in der Mitte der Durchgangsbohrung bei einer Bohrtiefe von 110 mm bei nur 36,0 HRC. Hier fand also so gut wie keine Aufkohlung statt. Bei der Verwendung von Ethan als Kohlenstoff-Träger, welches aufgrund seines geringeren Kohlenstoff-Wasserstoff-Verhältnisses bei gleichem Partialdruck des Kohlenstoff-Trägers auch nur eine geringere Kohlenstoff-Massendichte erzielen kann, lag der Wert für die Oberflächenhärte in der Mitte der Durchgangsbohrung sogar bei nur 25,9 HRC.As can be seen from the figure and the associated tables, with the carbon carriers known from the prior art Propane and ethane surface hardness of about 60 HRC and more only in the Edge areas of the holes, that is up to a hole depth of about 50 mm seen from both holes, achieved. In contrast, lay the value of when using propane as a carbon carrier Surface hardness in the middle of the through hole at a drilling depth of 110 mm at only 36.0 HRC. There was practically no carburization here. When using ethane as a carbon carrier, which due to its lower carbon-hydrogen ratio at the same Partial pressure of the carbon carrier also only a lower carbon mass density the surface hardness was in the middle the through hole even at only 25.9 HRC.
Im Vergleich mit diesen bekannten Kohlenstoff-Trägern Propan und Ethan wurde mit dem neuen Kohlenstoff-Träger Acetylen eine nahezu gleichbleibend gute Aufkohlung über die gesamte Durchgangsbohrung erzielt. Wie aus der Tabelle ersichtlich ist, liegt der Wert für die Oberflächenhärte an der inneren Oberfläche der Durchgangsbohrung fast durchgehend bei einem Wert von 60 HRC und mehr.In comparison with these known carbon carriers propane and ethane became almost constant with the new carbon carrier acetylene good carburization achieved over the entire through hole. As from the As can be seen in the table, the value for the surface hardness lies on the inner one Surface of the through hole almost continuously at a value of 60 HRC and more.
Die voranstehend beschriebene gleichmäßige Aufkohlung an der äußeren und inneren Oberfläche des Probewerkstücks verdeutlichen auch die Abbildungen Fig. 2 bis 4, in denen die Oberflächenhärte sowie die Einsatzhärtungstiefe (HV 1,0) an verschiedenen Meßpunkten dargestellt ist. Ein Vergleich der Graphiken in Fig. 3 und 4 zeigt, daß bei der Verwendung von Acetylen als Kohlenstoff-Träger nicht nur eine nahezu gleichbleibende Oberflächenhärte entlang der inneren und äußeren Werkstückoberfläche erzielt wird, sondern auch die Einsatzhärtungstiefe (HV 1,0) an der inneren und äußeren Werkstückoberfläche fast an allen Meßpunkten übereinstimmt.The above-described uniform carburization on the outer and The inner surface of the test workpiece is also shown in the illustrations 2 to 4, in which the surface hardness and the case hardening depth (HV 1.0) is shown at different measuring points. A comparison of the graphics 3 and 4 shows that when using acetylene as a carbon carrier not just an almost constant surface hardness along the inner and outer workpiece surface is achieved, but also the Case hardening depth (HV 1.0) on the inner and outer Workpiece surface coincides almost at all measuring points.
Mit dem voranstehend dargestellten Verfahren ist es somit möglich, durch die Verwendung eines Kohlenwasserstoffes mit einem Kohlenstoff-Wasserstoff-Verhältnis von 1:1, vorzugsweise Acetylen, als Kohlenstoff-Träger die Aufkohlungswirkung bei der Aufkohlung von metallischen Werkstücken in einem Vakuum-Ofen auch bei Werkstücken mit schwer zugänglichen Oberflächen deutlich zu erhöhen, ohne daß die Gefahr der Verrußung des Ofens besteht.With the method described above, it is thus possible to Use of a hydrocarbon with a carbon-hydrogen ratio of 1: 1, preferably acetylene, as the carbon carrier Carburizing effect when carburizing metallic workpieces in a vacuum oven even for workpieces with difficult to access Surfaces to increase significantly without the risk of sooting the Oven exists.
Claims (7)
dadurch gekennzeichnet,
daß als Kohlenstoff-Träger ein Kohlenwasserstoff mit einem Kohlenstoff-Wasserstoff-Verhältnis von 1:1, vorzugsweise Acetylen, verwendet wird.Process for carburizing metallic workpieces in a vacuum furnace, the furnace atmosphere containing a carbon carrier which is split under the process conditions of carburization with the release of pure carbon,
characterized,
that a hydrocarbon with a carbon-hydrogen ratio of 1: 1, preferably acetylene, is used as the carbon carrier.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE59704123T DE59704123D1 (en) | 1997-06-03 | 1997-06-03 | Process for carburizing metallic workpieces in a vacuum furnace |
EP97108860A EP0882811B2 (en) | 1997-06-03 | 1997-06-03 | Method of carburizing metallic workpieces in a vacuum furnace |
ES97108860T ES2161398T5 (en) | 1997-06-03 | 1997-06-03 | PROCEDURE FOR CARBURATION OF METAL PARTS IN A VACUUM OVEN. |
AT97108860T ATE203572T1 (en) | 1997-06-03 | 1997-06-03 | METHOD FOR CARBURING METAL WORKPIECES IN A VACUUM FURNACE |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97108860A EP0882811B2 (en) | 1997-06-03 | 1997-06-03 | Method of carburizing metallic workpieces in a vacuum furnace |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0882811A1 true EP0882811A1 (en) | 1998-12-09 |
EP0882811B1 EP0882811B1 (en) | 2001-07-25 |
EP0882811B2 EP0882811B2 (en) | 2010-12-15 |
Family
ID=8226864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97108860A Expired - Lifetime EP0882811B2 (en) | 1997-06-03 | 1997-06-03 | Method of carburizing metallic workpieces in a vacuum furnace |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0882811B2 (en) |
AT (1) | ATE203572T1 (en) |
DE (1) | DE59704123D1 (en) |
ES (1) | ES2161398T5 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0818555A1 (en) † | 1995-03-29 | 1998-01-14 | JH Corporation | Method and equipment for vacuum carburization and products of carburization |
FR2821362A1 (en) * | 2001-02-23 | 2002-08-30 | Etudes Const Mecaniques | LOW PRESSURE CEMENTING PROCESS |
WO2003097893A1 (en) * | 2002-05-15 | 2003-11-27 | Linde Aktiengesellschaft | Method and device for heat treatment of metallic work pieces |
EP1391525A1 (en) * | 2002-08-01 | 2004-02-25 | Ipsen International GmbH | Process and apparatus for blackening components |
FR2847591A1 (en) * | 2002-11-25 | 2004-05-28 | Bosch Gmbh Robert | Cementation of hot working steel components by low pressure or vacuum carburation involves fixing the peripheral carbon content by thermodynamic simulation |
US6846366B2 (en) | 2001-01-19 | 2005-01-25 | Oriental Engineering Co., Ltd. | Carburizing method and carburizing apparatus |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10209382B4 (en) * | 2002-03-02 | 2011-04-07 | Robert Bosch Gmbh | Method of carburizing components |
PL204202B1 (en) | 2002-10-21 | 2009-12-31 | Politechnika & Lstrok Odzka | Mixture for negative pressure carburization |
DE10322563B3 (en) * | 2003-05-20 | 2004-11-11 | Ipsen International Gmbh | Vacuum carburizing or vacuum case hardening of steel components at low absolute pressure with addition of hydrogen, nitrogen, or argon |
DE102009041927B4 (en) | 2009-09-17 | 2015-08-06 | Hanomag Härtecenter GmbH | Process for low-pressure carburizing of metallic workpieces |
ES2707585T3 (en) | 2013-12-19 | 2019-04-04 | Groz Beckert Kg | Textile tool and its manufacturing process |
PL422596A1 (en) | 2017-08-21 | 2019-02-25 | Seco/Warwick Spółka Akcyjna | Method for low pressure carburizing (LPC) of elements made from iron and other metals alloys |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU668978A1 (en) * | 1977-06-02 | 1979-06-28 | Предприятие П/Я А-7697 | Method of carburisation of steel articles |
GB2261227A (en) * | 1991-11-08 | 1993-05-12 | Univ Hull | Surface treatment of metals at low pressure |
WO1996030556A1 (en) * | 1995-03-29 | 1996-10-03 | Jh Corporation | Method and equipment for vacuum carburization and products of carburization |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3796615A (en) † | 1971-06-23 | 1974-03-12 | Hayes Inc C I | Method of vacuum carburizing |
-
1997
- 1997-06-03 DE DE59704123T patent/DE59704123D1/en not_active Expired - Lifetime
- 1997-06-03 EP EP97108860A patent/EP0882811B2/en not_active Expired - Lifetime
- 1997-06-03 ES ES97108860T patent/ES2161398T5/en not_active Expired - Lifetime
- 1997-06-03 AT AT97108860T patent/ATE203572T1/en active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU668978A1 (en) * | 1977-06-02 | 1979-06-28 | Предприятие П/Я А-7697 | Method of carburisation of steel articles |
GB2261227A (en) * | 1991-11-08 | 1993-05-12 | Univ Hull | Surface treatment of metals at low pressure |
WO1996030556A1 (en) * | 1995-03-29 | 1996-10-03 | Jh Corporation | Method and equipment for vacuum carburization and products of carburization |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch Week 8010, Derwent World Patents Index; Class M13, AN 80-17823C, XP002046310 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0818555A1 (en) † | 1995-03-29 | 1998-01-14 | JH Corporation | Method and equipment for vacuum carburization and products of carburization |
EP0818555B2 (en) † | 1995-03-29 | 2007-08-15 | JH Corporation | Method for vacuum carburization |
US6846366B2 (en) | 2001-01-19 | 2005-01-25 | Oriental Engineering Co., Ltd. | Carburizing method and carburizing apparatus |
FR2821362A1 (en) * | 2001-02-23 | 2002-08-30 | Etudes Const Mecaniques | LOW PRESSURE CEMENTING PROCESS |
WO2002068707A1 (en) * | 2001-02-23 | 2002-09-06 | Etudes Et Constructions Mecaniques | Low-pressure carburising method |
US7118634B2 (en) | 2001-02-23 | 2006-10-10 | Bnp Parlbas | Low-pressure cementation method |
WO2003097893A1 (en) * | 2002-05-15 | 2003-11-27 | Linde Aktiengesellschaft | Method and device for heat treatment of metallic work pieces |
EP1391525A1 (en) * | 2002-08-01 | 2004-02-25 | Ipsen International GmbH | Process and apparatus for blackening components |
US7160576B2 (en) | 2002-08-01 | 2007-01-09 | Ipsen International Gmbh | Method and device for blacking components |
FR2847591A1 (en) * | 2002-11-25 | 2004-05-28 | Bosch Gmbh Robert | Cementation of hot working steel components by low pressure or vacuum carburation involves fixing the peripheral carbon content by thermodynamic simulation |
Also Published As
Publication number | Publication date |
---|---|
DE59704123D1 (en) | 2001-08-30 |
ATE203572T1 (en) | 2001-08-15 |
ES2161398T5 (en) | 2011-04-05 |
EP0882811B1 (en) | 2001-07-25 |
EP0882811B2 (en) | 2010-12-15 |
ES2161398T3 (en) | 2001-12-01 |
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