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EP0637419B1 - Durch mikrowellen aufheizbarer spender für schmelzbare klebemittel - Google Patents

Durch mikrowellen aufheizbarer spender für schmelzbare klebemittel Download PDF

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Publication number
EP0637419B1
EP0637419B1 EP94909720A EP94909720A EP0637419B1 EP 0637419 B1 EP0637419 B1 EP 0637419B1 EP 94909720 A EP94909720 A EP 94909720A EP 94909720 A EP94909720 A EP 94909720A EP 0637419 B1 EP0637419 B1 EP 0637419B1
Authority
EP
European Patent Office
Prior art keywords
container
heat
microwave
dispenser
susceptor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94909720A
Other languages
English (en)
French (fr)
Other versions
EP0637419A1 (de
EP0637419A4 (de
Inventor
Hans E. Haas
Bernard M. Malofsky
Richard T. Thompson
Cynthia R. Jaros
John R. Nottingham
John Spirk
Craig M. Saunders
Paul E. Brokaw
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nottingham Spirk Design Associates Inc
Henkel Loctite Corp
Original Assignee
Nottingham Spirk Design Associates Inc
Henkel Loctite Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nottingham Spirk Design Associates Inc, Henkel Loctite Corp filed Critical Nottingham Spirk Design Associates Inc
Publication of EP0637419A1 publication Critical patent/EP0637419A1/de
Publication of EP0637419A4 publication Critical patent/EP0637419A4/de
Application granted granted Critical
Publication of EP0637419B1 publication Critical patent/EP0637419B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00—Heating by electric, magnetic or electromagnetic fields
    • H05B6/64—Heating using microwaves
    • H05B6/647—Aspects related to microwave heating combined with other heating techniques
    • H05B6/6491—Aspects related to microwave heating combined with other heating techniques combined with the use of susceptors
    • H05B6/6494—Aspects related to microwave heating combined with other heating techniques combined with the use of susceptors for cooking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00523—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes provided with means to heat the material
    • B05C17/00546—Details of the heating means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/24—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices
    • B65D35/28—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices for expelling contents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
    • B65D81/3446—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
    • B65D81/3461—Flexible containers, e.g. bags, pouches, envelopes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3439—Means for affecting the heating or cooking properties
    • B65D2581/3451—Microwave reactive fibres, i.e. microwave reactive material in the form of fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3472—Aluminium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3477—Iron or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3477—Iron or compounds thereof
    • B65D2581/3478—Stainless steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3482—Ceramic compositions, e.g. vermiculite, bentonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3483—Carbon, carbon black, or graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3486—Dielectric characteristics of microwave reactive packaging
    • B65D2581/3494—Microwave susceptor

Definitions

  • the present invention relates to improvements in the design and construction of apparatus for dispensing microwaveable hot melt adhesives and other heat sensitive materials.
  • the apparatus comprises a dispenser which is heated by microwaves and then used to dispense a material therefrom.
  • the dispenser is specifically designed to convert microwave energy into heat and to transfer the heat to the material to be dispensed in a more efficient and/or safe manner.
  • the dispenser is particularly useful for heating and dispensing a material (e.g. a hot melt adhesive) which is capable of changing from a solid state or a state of high viscosity to a state of low viscosity when heated above a predetermined threshold temperature, thereby enabling the material to be dispensed when in the state of low viscosity.
  • a material e.g. a hot melt adhesive
  • glue guns hot melt adhesive applicators
  • glue guns were designed to be connected to a wall socket by an electrical cord and plug for continuously applying electrical power to the glue gun, thereby melting the adhesive in the glue gun. This meant that the range over which the glue gun could physically operate was determined by the length of the electrical cord coupling the glue gun to the wall socket. Moreover, the cord at times presented a physical obstacle for the user to maneuver around when using the glue gun.
  • a cordless glue gun is a glue gun that can be detached from its source of electricity so that it can operate without an electrical cord.
  • the support structure must conveniently support the glue gun and enable the glue gun to be electrically energized (heated) while it is on the support structure.
  • the support structure and the glue gun need to be designed to enable convenient release of the glue gun from the support structure and from the source of electricity when it is desired to use the glue gun.
  • the support structure includes a socket for transmitting electrical energy to the glue gun and a release mechanism enabling the glue gun to be disconnected from the socket when it is released from the support structure.
  • a cordless glue gun still has drawbacks.
  • the cordless glue gun does not require continuous electrical power, it must be initially electrically heated while on the support structure and may require intermittent electrical heating to maintain the hot melt adhesive in a state of low viscosity.
  • both the conventional glue gun and the cordless glue gun require hot melt adhesive sticks or other forms of bulk adhesive to be inserted into the glue gun. This requires the purchase of the hot melt adhesive separate from the purchase of the glue gun itself and the handling of the hot melt adhesive before each use of the glue gun.
  • both the conventional glue gun and the cordless glue gun are bulky, relatively expensive to purchase, need a relatively long preheating time before glue can be dispensed, and a relatively long cool down period before being stored away.
  • US-A-5,188,256 discloses a dispenser for heat sensitive materials comprising a first material which changes from a solid state or a state of high viscosity to a state of low viscosity when heated above a predetermined temperature, a second material which is adapted to be heated above a predetermined temperature when subjected to microwave energy for at least a predetermined time, a container enclosing the first and second materials, and an outlet through which the first material can be dispensed from the container when in the state of low viscosity.
  • a hot melt adhesive is encased within a container, the inner surface of which has been coated with a microwave susceptor material.
  • the present invention is directed to novel improvements and refinements of the hot melt adhesive dispenser of US-A-5,188,256.
  • the present invention is directed to modifications and refinements in a microwaveable hot melt adhesive dispenser which provides for more efficient and, from a consumer standpoint, safer use.
  • the dispensing apparatus of the present invention is designed to be compact and portable for ease of use. In this respect, it is generally a hand holdable dispenser.
  • larger embodiments are also contemplated for potential use in industrial settings.
  • the dispenser concept of the present invention is particularly useful for transforming materials, particularly holt melt materials, from a solid state or state of high viscosity to a liquid state or state of low viscosity when heated above a predetermined threshold temperature.
  • Hot melt materials that may be employed in the practice of the present invention include, for example, hot melt adhesives, food products (i.e. hard candy, chocolate, etc.), solder, wax, and oil.
  • the present invention may also be used for the dispensing and initiation of reaction of heat sensitive reactive materials. Specifically, such heat sensitive materials include materials which cure or polymerize upon exposure to a predetermined temperature for a set period of time.
  • thermosetting resins selected from the group consisting of epoxies, polyesters, polyurethanes, polybutadienes, cyanate esters, bismaleimides, polyimides, phenolics, alkyds, amino resins and silicones.
  • the invention is especially beneficially used for the dispensing of hot melt adhesives and will, for the most part, be discussed in this context.
  • the present invention provides an apparatus for dispensing heat sensitive materials comprising a container within which a first material is disposed and which may either comprise or contain a second material, and an outlet through which the first material can be dispensed following exposure of the apparatus to microwave energy, the first material being such that upon heating to a predetermined temperature it is either transformed from a solid state or state of high viscosity to a liquid state or state of low viscosity or is activated such that polymerisation or cure of the first material is initiated, and the second material being designed to heat to at least the predetermined temperature when subjected to microwave energy for at least a predetermined period of time and the second material being in a heat transfer relationship with the first material, characterised in that the second material is not dispersed within the first material, and in that the second material comprises a ferromagnetic material having a minimum Curie temperature at least equal to the predetermined temperature and a maximum Curie temperature which is lower than the temperature at which the first material will boil or be adversely affected by the heat generated by the second material and lower
  • the container or at least the inner surface of the container, comprises the second material.
  • this embodiment contemplates a molded elongated container having a longitudinal axis, the container having at least one rib on its interior surface parallel to and extending inwardly towards the longitudinal axis.
  • the container may be molded of a high temperature polymeric material upon which is deposited the second material, either in particulate form or as a film.
  • the container itself may comprise the second material wherein the container is molded from a high temperature polymeric material having dispersed therein a particulate material which is, itself, designed to heat when subjected to microwave energy.
  • the polymeric material must be selected such that it has sufficient heat transfer characteristics so as to transfer the heat generated by the dispersed particle to the first material contained within the container.
  • the second material is not dispersed within the first material, and in that comprises two ribs on opposing interior surfaces of the container. The presence of the ribs extending from the interior surface of the container into the first material accelerates and aids in the heating of the first material.
  • FIG. 1 Another embodiment in accordance with the practice of the present invention employs a heating rod having a longitudinal axis parallel to the longitudinal axis of the container as the second material.
  • This heating rod may be encased or embedded within the first material.
  • the heating rod is of sufficient length and shape so as to provide ample surface area for contact with the first material.
  • the heating rod will extend for almost the full length of the longitudinal axis of the container.
  • the heating rod will extend through at least substantially all of the first material.
  • This embodiment is especially efficient inasmuch as all of the radiant energy from the heating rod is transferred to the first material.
  • the heating rod could also be used in conjunction with a container which is or whose inner surface is comprised of the second material as well. Such an embodiment would provide for very fast heating of the first material inasmuch as heating would occur from both directions in the first material.
  • a still further embodiment in accordance with the practice of the present invention incorporates the use of an insulative jacket which substantially encases or encloses the dispenser.
  • the insulative jacket may comprise a part of the container or it may comprise a reusable sleeve into which the container is inserted and withdrawn.
  • the dispenser is withdrawn from the sleeve and a new dispenser inserted so as to make the sleeve reusable.
  • the insulative jacket comprise at least one layer of an insulating material, preferably at least one layer of a polymeric foam.
  • the insulative jacket may comprise multiple layers including an exterior layer, one of which, but preferably not the exterior layer, is comprised of a fibreglass mat.
  • an insulative jacket provides for a substantially cool to the touch exterior surface which is to be handled by the consumer while allowing for sufficient heating of the first material to transform itself from its solid state or state of high viscosity to its liquid state or state or low viscosity or to achieve that temperature at which polymerization or cure is initiated.
  • the present invention relates, in its broadest concept, to improvements and variations in an apparatus for dispensing a heat sensitive material wherein the apparatus comprises:
  • the second material comprises a ferromagnetic material having a minimum Curie temperature at least equal to the predetermined temperature and a maximum Curie temperature which is lower than the temperature at which the first material will boil or be adversely affected by the heat generated by the second material and lower than the ignition temperature of either the first material or the container.
  • the first material which may be employed in the practice of the present invention may comprise any number of materials which are heat sensitive in that they transform from a solid state or state of high viscosity to a liquid state or state of low viscosity upon being heated to a predetermined temperature or which are activated such that polymerization or cure of the first material is initiated upon heating to a predetermined temperature.
  • Materials meeting the former characteristics are oftentimes characterized as being hot melts. Exemplary of such materials there may be given hot melt adhesives; food products such as hard candy, chocolate, syrups, jams, and the like; solder; wax; and oil.
  • thermosetting resins such as epoxies, polyesters, polyurethanes, polybutadienes, cyanate esters, bismaleimides, polyimides, phenolics, alkyds, amino resins and silicone, as well as other heat curable or heat polymerizable materials.
  • thermosetting resins such as epoxies, polyesters, polyurethanes, polybutadienes, cyanate esters, bismaleimides, polyimides, phenolics, alkyds, amino resins and silicone, as well as other heat curable or heat polymerizable materials.
  • the present invention is especially suited for use in the heating and dispensing of hot melt adhesives.
  • the apparatus and methodology of the present invention will be discussed with respect to hot melt adhesives in particular.
  • hot melt adhesive suitable for these purposes is manufactured and sold by the H. B. Fuller Company under the designation, Product No. 2125.
  • other hot melt adhesives may also be used in the practice of the present invention including those based upon or comprising polyvinyl formal, polyvinyl butyral, ethylene vinyl acetate (EVA), polyethylene (PE), polypropylene (PP), polyamide, polyester, polyesteramide, and copolymers and blends of the foregoing.
  • the second material which is in a heat transfer relationship with the first material, is adapted to be heated above a predetermined temperature when subjected to microwave energy for at least a predetermined period of time.
  • these materials are known as susceptors and are comprised of microwave absorbing particles.
  • Exemplary of susceptors which may be used in the practice of the present invention are those known for use in microwave cooking.
  • the susceptors comprise microwave absorbing materials which may be in particulate, atomized or film form, depending upon the particular embodiment or methodology of construction of the apparatus of the present invention.
  • the susceptor materials themselves generally comprise metals such as iron, and stainless steel; metal oxides such as ferrites, spinels, and spinel ferrites. Obviously, those skilled in the art will also readily recognize other susceptor materials which may be used in the practice of the present invention as well.
  • particulate microwave absorbing materials are adhered to or embedded in a high temperature polymeric film substrate.
  • the film being used as a layer in the construction of the apparatus.
  • particles of the microwave absorbing material may be dispersed within a high temperature resistant polymer matrix which may then be coated upon the inner surface of the container or which may comprise one or more layers of the container.
  • the second material may also comprise, be adhered to, or be dispersed within a structure, such as a heating rod, compressible coil, or foam particles, which is, in turn, disposed within at least a substantial portion of the first material.
  • one type of susceptor basically comprises microwave energy absorbing particles adhered to a high temperature polymeric film.
  • Susceptors of this type are normally classified by their optical density.
  • Such susceptors suitable for use in accordance with the practice of the present invention generally have an optical density in the range of 0.05 to 2.0.
  • Such films having optical densities in the high end of this range or higher generally have greater reflective characteristics and less absorptive characteristics such that generation of heat by the susceptor is very slow and, at extremely high optical densities, is impractical for use in the practice of the present invention.
  • film susceptors Preferably, such film susceptors have optical densities of from 0.10 to 0.35.
  • One commercially available susceptor of this type comprises metal particles disposed upon a high temperature polyimide film.
  • Such materials are manufactured and sold by National Metalizing Company of Cranbury, NJ.
  • the underlying polyamide film or substrate is manufactured and sold by E. I. DuPont De Nemours & Company under the trademark "Kaptan.”
  • Other high temperature polyimide films which may be used in the manufacture of such susceptor films include the polyether imides manufactured and sold by General Electric Company of Pittsfield, MA, under the trademark "Ultem.”
  • the susceptor films may be used alone or in conjunction with a second, typically supporting, film.
  • the susceptor film comprises a part of a film composite wherein the polymeric film, having deposited thereon the microwave absorbing particles, is adhered to a higher temperature resistant or more structurally oriented support polymeric film.
  • the supporting film may comprise, for example, polyimide films of the type previously mentioned, as well as other high temperature materials.
  • the susceptor film is adhered to the supporting film by use of high temperature adhesives, for example Avery 1184, manufactured and sold by Avery Products Corporation of San Marino, CA.
  • the backing or support layer provides a stable, high temperature backing for the outer susceptor film.
  • This composite comprises a susceptor film, which is a polyester film having deposited thereon microwave absorbing particles, bonded to a microwave transparent polyimide film using a high temperature adhesive. This embodiment will be discussed further in relation to the figures.
  • the susceptor is found is one in which the microwave absorbing particles are dispersed in a high temperature thermoplastic matrix.
  • suitable thermoplastic matrices include the aforementioned polyesters, polyimides, silicones, and the like.
  • Exemplary of such microwave absorbing particle-filled susceptor materials include ferrite-filled silicone resins, and the like.
  • the amount of particulate microwave absorbing material incorporated into the polymer matrix is that which is sufficient to provide sufficient heat to the first material in a reasonable period of time.
  • the amount of material to be incorporated into the polymer matrix resin may comprise anywhere from between 5 and 50%, preferably between 10 and 40%, by weight, based on the combined weight of the microwave absorbing material and the polymer matrix resin.
  • microwave absorbing material While lower levels of incorporation could be used, such lower levels will result in poor heating or too slow a heating time as to be commercially viable. Concurrently, higher loadings of the microwave absorbing material may be employed, although such high loading may adversely affect the physical characteristics of the polymer matrix resin and may also cause too rapid a rate of heating or enable excessive temperatures to be achieved.
  • the microwave absorbing materials to be employed as or incorporated into the susceptor are ferromagnetic materials which have been selected to have a minimum Curie temperature at least equal to the predetermined temperature at which the first material is either transformed from its solid state or state of high viscosity to its liquid state or state of low viscosity or is activated such that polymerization or cure of the first material is initiated and a maximum Curie temperature which is lower than the temperature at which the first material will boil or be adversely affected by the heat generated by the second material and lower than the ignition temperature of any of the materials used in the construction of the apparatus.
  • these ferromagnetic materials shall have a maximum Curie temperature of no more than 10°C above the recommended safe-use/safe-exposure temperatures for the container.
  • Such ferromagnetic materials are desirable in that, depending upon the heating characteristics of the same, they typically will not exceed their Curie temperature.
  • Such ferromagnetic materials include, preferably, ferrites, spinels, spinel ferrites.
  • Especially preferred ferromagnetic materials are those which have predominantly magnetic heating characteristics.
  • Especially preferred are those which have substantially no electric or resistive heating characteristics, most preferably those which are essentially free of electric or resistive heating characteristics. In this latter respect, saturation magnetism and Curie temperature are, essentially, simultaneously achieved such that the material becomes microwave transitive and heating stops.
  • electric or resistive heating has no shut-off point and, therefore, depending upon the level of electric or resistive heating characteristic in the selected ferromagnetic material, heating may continue, although at a much slower pace.
  • a non-quantified assessment of the level of electric or resistive heating characteristics of such ferromagnetic materials may, in part, be ascertained from the electrical interaction or impedance of the ferromagnetic material at the frequency of the microwave energy to be used.
  • the electrical interaction or impedance the higher the impedance, the more preferred the material.
  • ferromagnetic materials are especially desirable in applications where the materials used in the construction of the dispensing apparatus, particularly in the container and the insulative jacket, as discussed below, have ignition points not substantially or markedly higher than the Curie temperature. It is also desired to use such ferromagnetic materials where the first material is adversely affected by higher temperatures or is subject to boiling at such higher temperatures. Where a hot melt material is to be employed as the first material, it is only desirable to heat the hot melt to a temperature at which the liquid state or state of low viscosity is achieved. Concurrently, where a heat reactive material is the first material, it is similarly desired to avoid heating the first material to a temperature substantially above the reaction temperature.
  • the first material is disposed within a container which may comprise the second material or in which the second material as well may be disposed.
  • the container provides the structural definition and integrity to the dispensing apparatus of the present invention.
  • the container itself may comprise one or more layers of materials, depending upon the desired construction and materials to be dispensed.
  • the second material may be coated on the interior surface of the container, may comprise an interlayer which is sandwiched between two non-susceptor layers, all of which comprises the container, or it may comprise the second material altogether.
  • the container comprises at least one high temperature resistant material immediately adjacent the second material or, where the second material is contained within the first material, on the inner surface of the container itself.
  • high temperature resistant materials must be microwave transparent so as to enable the microwave energy to reach the second material.
  • the container comprises multiple layers, including an interlayer comprising the second material, then the outer layer immediately adjacent the second material must be a microwave transparent, high temperature resistant material and is preferably non-heat transmissive.
  • the inner layer i.e., that layer between the second material and the first material
  • the inner layer must be a a high temperature resistant, heat transmissive material so as to enable transfer of the heat from the second material to the first material and is preferably microwave transparent so that there is no impediment to the movement of microwaves through the dispensing apparatus.
  • the container must be manufactured from a high temperature resistant, microwave transparent, heat transmissive material.
  • Exemplary of the materials that may be used in the manufacture of the container include polyimides, high-temperature polyesters, modified polyphenylene oxide resins, silicones and other thermoplastic polymers having the desired aforementioned characteristics. Selection of a particular material for use in manufacturing the container will depend, in part, upon the temperature needed to effect the transformation and/or cure of the first material, as well as the likely temperatures to be attained by the second material during the period of time in which the apparatus is to be or is likely to be subject to microwave energies.
  • a suitable high-temperature material for use in the manufacture of the container may be one which has a melting point of 180°C.
  • a high temperature hot melt one having a melt temperature of 250°C
  • a correspondingly higher temperature attaining second material will be used in conjunction with an even higher temperature resistant polymer for the container.
  • selection of the material is dependent upon the proximity of the second material to the container and the maximum temperatures which this second material is likely to attain when subjected to microwave energies for a period of time in excess of that which is recommended. This latter stipulation will allow for those instances where the consumer is likely to leave the apparatus in a microwave oven longer than the time specified on any directions and will compensate for excessive heating even when the recommended heating period is followed as may be caused by hot spots in the microwave oven.
  • the outlet through which the first material is to be dispensed is preferably in the form of a nozzle.
  • the second material is also found in the nozzle or outlet.
  • the nozzle which may be unitary with the container or an independent component attached to the container, may comprise a polymeric material in which the susceptor material is dispersed.
  • the nozzle may be coated with the susceptor material or with a film susceptor. The purpose of incorporating the susceptor into the nozzle is to prevent heat loss in the first material as it is being dispensed through the nozzle. Otherwise, such heat loss may result in the solidification and blockage of the outlet.
  • the dispensing apparatus in use, is placed in the microwave oven or subject to a source of microwave energy for a sufficient, predetermined period of time, given the frequency of the microwave energy, to effect the transformation of the first material from a solid state or state of high viscosity to a liquid state or a state of low viscosity or to activate the reactive constituents comprising the first material so as to initiate polymerization or cure thereof.
  • This dispensing apparatus is suitable for use in conventional home microwave ovens having a wattage of from 400 watts to 800 watts, and higher, and a frequency of approximately 2.5 GH z .
  • the dispenser could also be used in commercial or industrial-style microwave ovens which typically have wattage in excess of 900 watts and a frequency of from about 10 KH z to 100 GH z , with the same results but in less time.
  • the dispenser is then removed from the oven and materials dispensed therefrom onto the desired place of application.
  • Dispensing is usually effected by squeezing or compressing the container so as to force the first material out through the outlet.
  • such materials are of a resilient nature in that once the compressing forces are removed from the surface of the container, the container returns to its original or substantially original configuration and shape. Such a resiliency characteristic will enable the first material in the nozzle portion to be sucked back into the main body of the container.
  • the dispensing apparatus of the present invention also comprises an insulative jacket substantially encasing the dispensing apparatus as described above.
  • This insulative jacket is microwave transparent and comprises at least one layer of an insulating material.
  • insulative jackets comprising two or more layers, at least one of which is an insulating material.
  • the insulative jacket may comprise one or more layers having insulating characteristics and an exterior layer having non-insulating properties.
  • the outer layer may be composed of any suitable polymeric material, paper or paper board, and the like, upon which the desired labeling, package coloration, and the like, may be affixed or printed.
  • Suitable insulating layers comprise, for example, a foamed or expanded polymeric material such as polyethylene foam, polypropylene foam, modified polyphenylene oxide foam, polystyrene foam, and so forth.
  • suitable insulating materials include, for example, fiberglass, fiberglass mat, injection molded high-temperature fiberglass filled plastic, low heat transmissive silicones, and the like.
  • the heat insulative jacket comprises multiple layers, it is contemplated, and preferred, that the jacket include at least one intermediate insulating layer formed from a material such as non-woven fiberglass, fiberglass mat, or a foamed polymer.
  • the insulative layer be manufactured from flexible, resilient materials capable of withstanding high temperatures, for example approximately 260°C (500°F), for that period of time for which the dispensing apparatus is contemplated to be heated in the microwave oven.
  • the insulative jacket provides a cool-to-the-touch surface so that the consumer can readily remove the dispensing apparatus from the microwave oven by hand without concern for burning one's hand. Additionally, because the insulative jacket is essentially heat non-transmissive, the insulative jacket serves to retain the heat generated by the second material within the container and, thus, the first material. Consequently, the use of such insulative sleeves provides for much longer use times following removal of the dispensing apparatus from the microwave energy source. In one embodiment, it is preferred that the insulative jacket encase all of the dispensing apparatus but for the extreme tip of the outlet or dispensing nozzle. This will also serve to retain heat within the nozzle portion as well.
  • the insutative jacket may be adhered to or comprise the outer layers of the container for the dispenser.
  • the insulative jacket comprises a sleeve into which the dispensing apparatus as described above is inserted for use and withdrawn and discarded after the first material has been fully dispensed. This embodiment allows for the reusability of the sleeve, minimizing costs and waste of raw materials.
  • the insulative jacket be microwave transparent and constructed of sufficiently flexible and resilient materials as not to interfere with the dispensing of the first material following exposure of the dispensing apparatus to microwave energy.
  • FIG. 1 illustrates a perspective view of a dispensing unit 10 in accordance with one embodiment of the practice of the present invention.
  • the dispensing unit 10 includes a dispenser 12 and a cover 14 therefor.
  • the cover 14 serves as both a cool-to-the-touch dispensing aid as well as a stand for the dispenser and comprises a pair of side members 30 and 32 and a central member 34 therebetween.
  • the side members 30 and 32 and the central member 34 are integrally formed and have an integrally formed hinge structure 36 between each side member and the central member.
  • the cover 14 comprises an opening 38 extending through the central member 34, each hinge structure 36, and through the top portion of each of the side members 30 and 32.
  • the opening 38 is dimensioned to allow the nozzle 24 of the dispenser 12 to fit therethrough.
  • the cover 14 is preferably formed from a relatively rigid, heat insulating composite material.
  • a relatively rigid, heat insulating composite material Exemplary of a appropriate material for a cover is a composite formed by laminating 1.59 to 2.38 mm (1/16 to 3/32 of an inch) of polypropylene foam and/or polyethylene foam to a bleached hardwood craft paper having a thickness of .25 to .51 mm (0.01 to 0.02 inches).
  • the cover enables the dispenser to be maintained in an upright orientation when the cover is supported on a surface in an inverted "V" shaped position.
  • the hinge structure 36 enables the side members 30 and 32 to be subject to opposing forces, and, thus squeezed, compressing the dispenser 12 so as to dispense the first material contained within the dispenser through outlet 24.
  • Figures 2 and 3 provide cross-sectional views of two alternative embodiments of the dispenser wherein the first material 18, the material to be dispensed, is contained within the container 22 whose inner surface is coated with a layer of the second material 20.
  • the second material 20 comprises a susceptor film comprising, for example, a high temperature polyimide film having deposed thereon metal particles. It is generally preferable to maintain an air space 25 above the first material 18 so as to allow for expansion of the first material upon heating. This is particularly important in the event the dispensing unit is subjected to microwave energy for too long a period of time and the first material begins to boil.
  • Figure 3 illustrates a similar embodiment wherein the container 22 is formed of a multilayer composite comprising an exterior layer 23, an intermediate second material layer 20, and an interior layer 40.
  • the second material or susceptor film is sandwiched between the exterior layer 23 which is microwave transparent and an interior layer 40 which is heat transmissive and preferably microwave transparent.
  • the second material may comprise a polyimide film having deposited thereon metal particles.
  • the exterior layer 23 and interior layer 40 may be composed of the same material, for example, high-temperature thermoplastics such as polyimides, polyesters, silicones, and the like.
  • Multilayer configurations are particularly desirable where the first material 18 is a food product which, for health reasons, may not come in contact with material contained within the susceptor layer 20 or the exterior layer 23.
  • the use of the inner layer 40 may also be important where the first material 18 is a reactive material which is adversely affected by constituents contained within the susceptor layer 20 or the exterior layer 23.
  • Figure 4 illustrates a cross-section of the dispenser 12 shown in Figure 2 taken along the line A-A. Again, this embodiment shows the container 22 encasing both the susceptor layer 20 and the first material 18.
  • FIGS 5 and 6 illustrate a further embodiment of a dispensing unit 50 constructed in accordance with the practice of the present invention.
  • the dispensing unit 50 includes a dispenser 52 and an insulative jacket 54 therefor.
  • the dispenser 52 includes a first material 58 to be dispensed, a second material 60 in a heat transfer relationship with the first material 58, and an outlet 61 through which the first material 58 can be dispensed.
  • the second material 60 comprises a susceptor which is adapted to be heated above a predetermined temperature when subjected to microwaves for at least a predetermined period of time.
  • the susceptor comprises microwave absorbing particles deposited on a thin (48 guage) microwave transparent polymeric film, for example polyester film.
  • the susceptor 60 is adhered, using a high temperature adhesive (e.g., Avery 1184), to a second microwave transparent inner sheet 62 of, for example, polyimide film.
  • This inner sheet 62 provides a stable, high temperature backing for the outer susceptor film 60.
  • the composite film comprising the susceptor 60 and the inner microwave transparent sheet 62 is then spirally wound together around the first material 58 to form a container, for example a tube, with the susceptor 60 located on the outer surface of the tube.
  • the inner microwave transparent sheet 62 can be first spirally wound around the first material 58 and then the susceptor 60 can be wound or folded, widthwise, around the entire length of the inner microwave transparent sheet to form a container.
  • the susceptor does not overlap along the edges and thus the formation of "hot spots" are prevented from occurring along the length of the dispenser.
  • the susceptor particles can be deposited directly onto the outer surface of the outer microwave transparent sheet 62 and this single sheet can then be spirally wound into a tube around the first material 58 to form a container.
  • a high temperature adhesive is applied to bond the susceptor film 60 to the inner microwave transparent sheet 62.
  • this high temperature adhesive is also applied between such overlapping edges to adhesively secure the sheets together.
  • the so formed dispenser 52 is then encased within an insulative jacket 54 which comprises one or more layers of heat insulating material which permits a user to grasp the dispensing unit 50 and remove it from the microwave oven.
  • the insulative jacket 54 comprises an outer insulating sheath 70, an intermediate insulating layer 72, and an inner insulating layer 74.
  • the outer insulating sheath 70 can include serrations or grooves (not shown) to facilitate heat dissipation and grasping by a user, and is preferably formed of a flexible, heat insulating material such as a polyethylene, polypropylene, polyimide, or polystyrene foam.
  • the inner insulating layer 74 and the intermediate insulating layer 72 may also be formed from flexible, resilient, heat insulating materials.
  • the inner insulating material 74 may be formed in the shape of a tube from fiberglass mat, fiberglass filled high-temperature injected molded thermoplastic, or molded silicone.
  • the intermediate insulating 72 can likewise be formed from material such as non-woven fiberglass and other insulative materials.
  • any one or more of the layers of the insulative jacket may comprise a non-insulative material so long as at least one layer comprises an insulating material.
  • the dispensing unit 50 also comprises nozzle 52 having an outlet 61 through which the first material 58 may be dispensed, as well as a base 76 which maintains the dispensing unit 50 in an upright orientation (nozzle pointed upward) while the dispenser is being heated in the microwave oven or is not being used.
  • the base 76 may be molded separately from other heat-resistant materials, for example polypropylene.
  • the base 76 can be removeably attached to the insulative jacket 54, such as by a hinge or a threaded connection (not shown), to allow replacement dispensers 52 to be inserted into the bottom of the insulative jacket 54 for reuse.
  • the hot melt adhesive it is believed important to leave the nozzle 61 uncovered so that the hot melt adhesive can be readily applied to an object after the adhesive is heated and to avoid buildup of pressure with the dispenser 52. Maintaining the dispenser 52 in an upright orientation prevents hot melt adhesive from dripping from the dispenser during the heating process.
  • the outer insulating layer 70 can also be formed slightly higher than the intermediate insulating layer 72, such that any dripping of the hot melt adhesive from the nozzle 61 is contained within the intermediate insulating layer and prevented from dripping down the outer surface of the cover.
  • the dispensing unit 50 comprises an insulative jacket 54 in which is contained the dispensing unit 52.
  • the insulative jacket 54 may comprise a plurality of insulating layers 70 and 72.
  • the dispenser 52 comprises a container 63 in which is enclosed the first material 58 and an end plug 81.
  • the inner surface of the container 63 may be coated with a susceptor material 65.
  • the container 63 comprises a high temperature thermoplastic resin in which is dispersed the second material.
  • an interlayer 65 comprising a high-temperature, heat transmissive polymeric film 65, may act as a chemical barrier between the container 63 and the first material 58. Alternatively, no such interlayer may be used.
  • Figure 9 shows a cross-section of the dispensing unit 50 of Figure 8 taken along the line 16-16.
  • this drawing illustrates the first material 58 contained within the container 63 which, in itself, is contained within an inner insulative layer 72 and an outer insulative layer 70.
  • the container 63 for the dispenser 52 manufactured in accordance with this embodiment of the present invention is preferably a resilient, flexible, thermoplastic or silicone rubber. Where the container 63 also comprises the susceptor for the hot melt dispenser 52, the microwave absorbing particles are dispersed within the polymer matrix making up the container 63. Exemplary of materials suitable for this purpose include ferrite filled silicone.
  • Figure 10 shows a cross-section of a dispensing unit 50, similar to that shown in Figure 8, except that it comprises two ribs 64 extending from the inner surface of the container 63 and running along the inside of the container in a direction parallel to the longitudinal axis of the container.
  • the surface of the ribs 64, as well as the interior surface of the container 63 may have deposited thereon a susceptor material 65.
  • the container 63 and the ribs 64 may be composed of a second material which comprises a polymer matrix having dispersed therein the microwave absorbing particles.
  • dispensing of the first material 58 from the dispenser 52 through outlet 61 is effected by applying pressure to the outer surface of the insulative cover 54 essentially as shown by the arrows in Figure 10.
  • the use of radially opposed ribs in the construction of this embodiment of the dispenser 52 allows for maximum dispensing of the first material 58.
  • Table 1 shows heat up rates for a dispenser manufactured using the standard tube configuration of Figures 8 and 9 and the ribbed tube configuration of Figure 10 with two different types of ferrite susceptors.
  • Each dispenser was manufactured by injection molding from an injection molding grade silicone rubber, available from Ronsil Rubber, having 40% by weight of the identified ferrite materials incorporated therein.
  • a standard EVA hot melt adhesive was encased within the silicone tube and the tube heat crimped at its end to prevent loss of the hot melt adhesive upon heating. The dispensers were then subjected to microwave energy and the internal temperature of the hot melt adhesive monitored over time using a probe.
  • FIG. 11 A final further embodiment of the apparatus of the present invention is as shown in Figures 11 and 12.
  • this embodiment depicts a dispensing unit 50 in which the second material, or the susceptor, comprises a heating rod 80 embedded or encased within the first material 58.
  • the heating rod 80 may comprise a substrate upon which the second material is coated or the heating rod 80 may comprise the second material in which case the heating rod is produced from a polymeric material having dispersed therein a susceptor material.
  • Figure 12 shows a cross-section of the dispensing unit 50 of Figure 11 taken along line 18-18.
  • the container 63 may be injection molded from a thermoplastic material or silicone rubber which may or may not have dispersed within itself additional amounts of the second material.
  • this embodiment also contemplates that the inner surface of the container 63 may have coated thereon a layer of the second material. Generally, though, the presence of the second material is only necessary in the heating rod 80. When the dispensing unit 50 is in this configuration, heating of the first material 58 occurs from the inside out. This manner of heating further reduces the temperature attained on the exterior surface of the container 63. In this light, it is possible that container 63 may be composed of a microwave transmissive, heat-insulating material. Such an embodiment may eliminate the need for the insulative sleeve 54.
  • the dispensing unit 50 further includes a base 76 which can be removeably attached to the insulative jacket 54.

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  • Food Science & Technology (AREA)
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Claims (29)

  1. Vorrichtung zur Abgabe wärmeempfindlicher Materialien, umfassend einen Behälter (52), in dem sich ein erstes Material (58) befindet und der ein zweites Material (60) entweder umfassen oder enthalten kann, und einen Auslaß (61), durch den das erste Material im Anschluß an das Einwirkenlassen von Mikrowellenenergie auf die Vorrichtung abgegeben werden kann, wobei das erste Material derart ist, daß es beim Erwärmen auf eine vorbestimmte Temperatur entweder von einem festen Zustand oder einem hochviskosen Zustand in einen flüssigen Zustand oder einen niedrigviskosen Zustand überführt wird oder derart aktiviert wird, daß die Polymerisation oder Härtung des ersten Materials initiiert wird, und das zweite Material so gestaltet ist, daß es auf wenigstens die vorbestimmte Temperatur erwärmt wird, wenn es wenigstens eine vorbestimmte Zeit lang Mikrowellenenergie ausgesetzt wird, und das zweite Material mit dem ersten Material in einer Wärmeübertragungsbeziehung steht, dadurch gekennzeichnet, daß das zweite Material (60) nicht innerhalb des ersten Materials (58) dispergiert ist und das zweite Material ein ferromagnetisches Material ist mit einem Curie-Temperaturminimum, das wenigstens gleich der vorbestimmten Temperatur ist, und einem Curie-Temperaturmaximum, das niedriger ist als die Temperatur, bei der das erste Material sieden oder durch die vom zweiten Material erzeugte Wärme nachteilig beeinflußt werden wird, und das niedriger ist als die Entzündungstemperatur entweder des ersten Materials oder des Behälters.
  2. Vorrichtung gemäß Anspruch 1, bei der das erste Material ein Heißschmelzkleber, ein Nahrungsmittelprodukt, ein Lötmittel, ein Wachs oder ein Öl ist.
  3. Vorrichtung gemäß Anspruch 1, bei der das erste Material ein Heißschmelzkleber ist.
  4. Vorrichtung gemäß Anspruch 1, bei der das erste Material eine wärmeaktivierte polymerisierbare Zusammensetzung ist, ausgewählt aus Epoxiden, Polyestern, Polyurethanen, Polybutadienen, Cyanatestern, Bismaleimiden, Polyimiden, Phenolharzen, Alkydharzen, Aminoharzen und Siliconen.
  5. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 4, bei der das zweite Material ein ferromagnetisches mikrowellenabsorbierendes Suszeptor-Material umfaßt, das teilchenförmig, zerstäubt oder in Filmform vorliegen kann.
  6. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 5, bei der das zweite Material einen Hochtemperatur-Polymerfilm umfaßt, auf dem ein ferromagnetisches mikrowellenabsorbierendes Suszeptor-Material abgeschieden ist.
  7. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 5, bei der das zweite Material ein ferromagnetisches mikrowellenabsorbierendes Suszeptor-Material in Form von Teilchen, die innerhalb eines Hochtemperatur-Polymermaterials dispergiert sind, umfaßt.
  8. Vorrichtung gemäß Anspruch 6 oder 7, bei der das Hochtemperatur-Polymermaterial ausgewählt ist aus Polyimiden, Hochtemperatur-Polyestern, modifizierten Polyphenylenoxiden und Siliconen.
  9. Vorrichtung gemäß irgendeinem der Ansprüche 5 bis 8, bei der das mikrowellenabsorbierende Suszeptor-Material ausgewählt ist aus Metallen und Metalloxiden.
  10. Vorrichtung gemäß Anspruch 9, bei der das mikrowellenabsorbierende Suszeptor-Material ein Metalloxid in Teilchenform ist, ausgewählt aus Ferriten, Spinellen und Spinellferriten.
  11. Vorrichtung gemäß Anspruch 9 oder 10, bei der das mikrowellenabsorbierende Suszeptor-Material ein ferromagnetisches Material mit vorwiegend magnetischen Erwärmungseigenschaften ist.
  12. Vorrichtung gemäß Anspruch 9, bei der das mikrowellenabsorbierende Suszeptor-Material ein teilchenförmiges Metall ist, ausgewählt aus der Gruppe, bestehend aus Aluminiumteilchen, Eisenteilchen und Edelstahlteilchen.
  13. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 12, bei der das zweite Material in Form eines Heizstabs (80) oder einer kompressiblen Spule vorliegt, der/die in dem ersten Material (58) eingebettet oder eingeschlossen ist.
  14. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 12, bei der das zweite Material den Behälter umfaßt.
  15. Vorrichtung gemäß Anspruch 14, bei der das zweite Material ein Silicon umfaßt, worin ein ferromagnetischer mikrowellenabsorbierender Suszeptor dispergiert ist.
  16. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 12, bei der das zweite Material zwischen dem ersten Material und dem Behälter liegt.
  17. Vorrichtung gemäß Anspruch 16, bei der das zweite Material als eine Beschichtung auf der Innenfläche des Behälters vorliegt.
  18. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 17, bei der der Behälter im wesentlichen röhrenförmig mit einer Längsachse ist und wenigstens eine Rippe (64) auf dessen Innenfläche enthält, die zur Längsachse der Röhre parallel ist und sich nach innen erstreckt.
  19. Vorrichtung gemäß Anspruch 18, bei der der Behälter zwei Rippen hat, wobei sich an den gegenüberliegenden Innenflächen des Behälters jeweils eine Rippe befindet.
  20. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 19, bei der der Auslaß eine Düse enthält und das zweite Material sich auch innerhalb der genannten Düse befindet.
  21. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 20, die darüber hinaus eine Innenschicht (62) aus einem hochtemperaturbeständigen wärmeleitenden Material umfaßt, welche zwischen dem genannten ersten Material und dem genannten zweiten Material liegt.
  22. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 21, die darüber hinaus einen Deckel (14) umfaßt.
  23. Vorrichtung gemäß Anspruch 22, bei der der Deckel ein wärmeisolierendes Material umfaßt und es ermöglicht, daß die Vorrichtung in aufrechter Position stehen bleibt.
  24. Vorrichtung gemäß irgendeinem der Ansprüche 1 bis 21, die darüber hinaus einen mikrowellendurchlässigen Isoliermantel (54) umfaßt, der den Behälter im wesentlichen umhüllt.
  25. Vorrichtung gemäß Anspruch 24, bei der der Isoliermantel wenigstens eine Schicht eines Isoliermaterials umfaßt.
  26. Vorrichtung gemäß Anspruch 25, bei der das Isoliermaterial ein Polymerschaum ist.
  27. Vorrichtung gemäß irgendeinem der Ansprüche 24 bis 26, bei der der Isoliermantel wenigstens zwei Schichten umfaßt, einschließlich einer Außenschicht, wobei eine davon, jedoch nicht die Außenschicht, entweder aus Glasfaser oder Glasfasermatte ist.
  28. Vorrichtung gemäß irgendeinem der Ansprüche 24 bis 27, bei der der Isoliermantel eine wiederverwendbare Hülle bildet, in die bzw. aus der der Behälter hineingesteckt bzw. herausgezogen wird.
  29. Vorrichtung gemäß irgendeinem der Ansprüche 24 bis 28, bei der der Isoliermantel eine nichtisolierende Außenschicht umfaßt.
EP94909720A 1993-02-22 1994-02-18 Durch mikrowellen aufheizbarer spender für schmelzbare klebemittel Expired - Lifetime EP0637419B1 (de)

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US2051193A 1993-02-22 1993-02-22
US20511 1993-02-22
PCT/US1994/001808 WO1994019917A1 (en) 1993-02-22 1994-02-18 Microwaveable hot melt dispenser

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EP0637419A1 EP0637419A1 (de) 1995-02-08
EP0637419A4 EP0637419A4 (de) 1995-07-26
EP0637419B1 true EP0637419B1 (de) 1999-04-21

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JP (1) JP2972340B2 (de)
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EP0696481A1 (de) * 1994-08-10 1996-02-14 Loctite Corporation Durch Mikrowellen aufheizbare Spender für Klebemittel und sein Klebemittelvorrat
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CA2131325A1 (en) 1994-09-01
HK1005162A1 (en) 1998-12-24
AU6245394A (en) 1994-09-14
CA2131325C (en) 1998-08-25
DE69417964T2 (de) 1999-11-11
JP2972340B2 (ja) 1999-11-08
AU666813B2 (en) 1996-02-22
JPH07506295A (ja) 1995-07-13
WO1994019917A1 (en) 1994-09-01
BR9404162A (pt) 1999-06-15
DE69417964D1 (de) 1999-05-27
EP0637419A1 (de) 1995-02-08
EP0637419A4 (de) 1995-07-26

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