EP0636549A1 - Assembly for dispensing a liquid or pasty product without air suction, with a deformable membrane - Google Patents
Assembly for dispensing a liquid or pasty product without air suction, with a deformable membrane Download PDFInfo
- Publication number
- EP0636549A1 EP0636549A1 EP94401668A EP94401668A EP0636549A1 EP 0636549 A1 EP0636549 A1 EP 0636549A1 EP 94401668 A EP94401668 A EP 94401668A EP 94401668 A EP94401668 A EP 94401668A EP 0636549 A1 EP0636549 A1 EP 0636549A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dome
- orifice
- membrane
- insert
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 38
- 235000011837 pasties Nutrition 0.000 title claims abstract description 5
- 239000007788 liquid Substances 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000012530 fluid Substances 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 238000009826 distribution Methods 0.000 claims description 20
- 239000012815 thermoplastic material Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000007789 sealing Methods 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000000475 sunscreen effect Effects 0.000 description 2
- 239000000516 sunscreening agent Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D35/00—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
- B65D35/44—Closures
- B65D35/46—Closures with valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D47/00—Closures with filling and discharging, or with discharging, devices
- B65D47/04—Closures with discharging devices other than pumps
- B65D47/20—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
- B65D47/2018—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure
- B65D47/2056—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type
- B65D47/2062—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type in which the deformation raises or lowers the valve stem
- B65D47/2068—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type in which the deformation raises or lowers the valve stem in which the stem is lowered by the pressure of the contents and thereby opening the valve
Definitions
- the present invention relates to a product dispensing assembly of fluid to pasty consistency comprising a container and a dispensing head provided with a dispensing orifice capable of being opened or closed by a spike operated in translation by a deformable membrane.
- This set can be used, in particular for the distribution of cosmetic products, for example sunscreen.
- fluid product means any product in the form of a liquid, cream or paste capable of flowing.
- FR-A-829 056 discloses an assembly comprising a receptacle made of flexible material containing the fluid product to be dispensed and a dispensing head comprising a dome provided with at least one dispensing orifice capable of being closed by a pin mobile carried by an elastically deformable membrane, the orifice being closed by the pin in the absence of any overpressure on said membrane on the side where said pin is located and being released when an overpressure is applied to said membrane on the side where said pin is located pin, the container and the dome constituting a single piece obtained by molding, a rigid insert being placed at the base of the dome and delimiting, between it and the dome, a space, said insert comprising at least one channel, which puts in communicating said space and the container, and carrying, vis-à-vis the orifice, the deformable membrane, the latter giving the pin a bearing force against the edges of the opening, said support force and the contact surface between the pin and the edges of the opening being, in the closed position, sufficient for said closure to prevent any air
- Such an assembly makes it possible to ensure a distribution without air intake by implementing the opening and closing of a dispensing orifice by a spike operated by a membrane. deformable.
- the flexible containers are crushed as and when dispensed, which allows the user to identify the filling state of the container even if the wall is totally opaque.
- the absence of air intake prevents deterioration of the product during distribution by oxidation and also prevents contamination of the product on the bacterial level, which results in a possible reduction in the use of preservatives.
- the present invention therefore relates to a product distribution assembly of fluid to pasty consistency comprising a container made of flexible material containing the fluid product to be dispensed and a dispensing head comprising a dome provided with at least one dispensing orifice capable of being closed.
- the container and the dome constituting a single piece obtained by molding, a rigid insert being placed at the base of the dome and delimiting, between it and the dome, a space, said insert comprising at least one channel, which connects said space and the container, and bearing, vis-à-vis the orifice, the deformable membrane, the latter conferring at the pin a bearing force against the edges of the opening, said bearing force and the contact surface between the pin and the edges of the opening being, in the closed position, sufficient for said closure to prevent any recovery of air after distribution, the insert consisting of a plate through which is (are) formed (s) the channel (channels) and a support element which carries the membrane and is integral with said plate, I ' support element being arranged in the central zone of the plate, characterized in
- the insert is put in place precisely thanks to the redent, and therefore the pin is positioned precisely relative to the orifice.
- the container is preferably constituted by a tube whose cylindrical skirt, of circular or oval section, is molded in one piece with the dome and which is closed by a linear weld in its zone opposite to the dome.
- the support element comprises a cylindrical skirt which fits with a slight tightening in the blind housing and a base constituting the membrane. This limits the dead volume inside the dome.
- the support element is surrounded by a plurality of channels organized in a ring around it.
- the insert is preferably made up of two separate pieces assembled: according to a particular embodiment, the plate comprises, in its central zone, a blind housing inside which the support element is fixed, the latter comprising a cylindrical zone engaged in said housing and a base constituting the membrane.
- This two-piece embodiment makes it possible to obtain an assembly of greater rigidity and to limit the sealing problems between the insert and the wall of the dome, when the wall of the dome deforms; indeed, one can use to mold the support element carrying the elastic membrane a more flexible plastic material than to mold the tray in which is (are) formed (s) the channel (channels).
- the spike and the edges of the orifice preferably have complementary shapes such that the contact surface between the end of the spike and the edge of the opening is large.
- the dispensing orifice advantageously comprises a frustoconical bearing, the pin being shaped at its free end according to a frustoconical bearing substantially of the same angle at the top.
- the assembly advantageously comprises a cap capable of covering the dome; the cap is fixed by fitting, latching or screwing on the base of the dome.
- the cap preferably comprises, internally, a stud arranged in line with the dispensing orifice when the cap is fixed to the dome; according to a preferred embodiment, the dispensing orifice ends, towards the outside of the dome, by a frustoconical bearing and the stud is shaped at its free end according to a frustoconical bearing substantially of the same angle at the top; preferably, the two frustoconical bearing surfaces of the dispensing orifice are separated from each other by a cylindrical zone.
- the cap thus avoids any accidental distribution of the product during storage and the various handling operations, in the event that pressure is exerted on the container.
- the various elements of the assembly can be molded using the same thermoplastic material: in this case, polyethylene is used, which has the advantage of being recyclable; it is nevertheless possible to choose polyethylenes of different elasticities; for example, a more rigid polyethylene may be used for the insert tray than for the support element.
- the container-dome assembly be molded from a different thermoplastic material, in particular from a heat-sealable multilayer material, this type of material having the advantage of being highly impermeable to air.
- the assembly according to the invention is simple to manufacture.
- the different parts are molded separately: the part formed by the wall of the unclosed container and the dome, the two parts forming the insert and, optionally, the cap.
- the two pieces forming the insert are assembled and then the insert is pushed into the container until it is in place at the base of the dome.
- the product to be dispensed is then introduced through the open bottom of the container and the open end of the container is closed, in particular by heat sealing.
- a linear weld is preferably carried out substantially perpendicular to the axis of the tube.
- the assembly according to the invention operates as follows: during use, the user removes the cap to release the orifice provided on the dome; he then compresses the walls side of the flexible container with his fingers. Under the pressure produced, the product contained in the container passes through the channels provided in the insert, and enters the space between the insert and the dome. The pressure exerted on the product by the user's fingers deforms the elastic membrane carrying the spike; this pin, which initially closed the dispensing orifice, moves in translation and releases the dispensing orifice; the product then leaves through the dispensing orifice and can be applied. Simultaneously the container, which is flexible, crashes. When the user stops pressing on the container, the pressure exerted by the product on the membrane ceases and the membrane returns by elasticity to its initial position, the pin again closing the dispensing orifice.
- the membrane returning very quickly to its initial position and the pin cooperating in a sealed manner with the edge of the orifice, there is no air intake; consequently, the deterioration of the product to be dispensed by air oxidation and its contamination by air microorganisms is avoided; we can therefore reduce the use of preservatives in the product to be distributed.
- the tube remains, after dispensing, in its partially crushed form: the user can thus easily assess the quantity of product remaining in the tube, even if the latter is opaque.
- the space between the inserted part and the dome can be proportionally very small compared to the volume of the container; the internal volume of the channels is also very small compared to the volume of the container; under these conditions, the dead volume is low, the quantity of non-expellable product that it contains is low and the rate of return of the product to be distributed is therefore high.
- the distribution assembly 1 shown in FIGS. 1 to 4 consists of a container formed by a tube 2 containing the product to be distributed and of a distribution head constituted by a dome 3 molded with the tube 2 and by an insert 5 in which channels 23 are formed, said insert carrying an elastic membrane 6 provided with a spike 7.
- the insert 5 is disposed at the base of the dome 3.
- an orifice 4 In the dome 3 is formed an orifice 4.
- the dome 3 is covered by a cap 8.
- the tube 2 is formed of a cylindrical skirt 9 pinched at its end opposite to the dome 3 by a linear weld 10.
- the dome 3 is coaxial with the tube 2; it consists, on the one hand, of a cylindrical skirt 11 of smaller diameter than the cylindrical skirt 9 of the tube 2, the skirt 11 being connected to the skirt 9 by a circular shoulder 12, and, on the other hand, a dome 13, the convexity of which faces outwards.
- a cusp 3a is provided within the dome 3 to the junction between the skirt 11 and the dome 13.
- a hole 4 is provided at the center of the dome 13; the side walls of said orifice 4 (see FIG. 4) have the shape of two frustoconical bearing surfaces 4 a , 4 b separated from one another by a cylindrical zone.
- the insert 5 consists of two parts assembled by fitting: a plate 14, in which are formed four channels 23 and a support element 15 carrying the membrane 6 provided with the pin 7.
- the plate 14 comprises, in its part turned towards the tube 2, a circular plate 16, which is provided with four openings forming the inlet of the channels 23 and whose central area is full. This circular plate has an equal diameter. apart from the necessary clearance, the internal diameter of the cylindrical skirt 11 of the dome 3.
- the circular plate 16 is molded in one piece with an annular element 17 which forms, with the plate 16, a blind housing 14 a cylindrical.
- the annular element 17 carries, at its upper part, a flange 19 of external diameter equal, apart from the necessary clearance, to the diameter of the dome 3 below the redent 3 a , the flange 19 coming to bear against the redent 3 a .
- the channels 23 are regularly arranged at the periphery of the annular element 17 and open on one side into the plate 16 and on the other into the flange 19.
- the support element 15 is constituted by the membrane 6 carrying in its center the pin 7, which constitutes a circular transverse base, and by a cylindrical skirt 20, which has an external diameter equal to the internal diameter of the annular element 17 and which has the same height so as to be able to fit with a slight interference in the blind recess 14 limited by the annular element 17 and the plate 16.
- the pin 7 is arranged to the right of the orifice 4 provided in the axis of the dome 3 and the precision of the positioning of the insert 5 in the dome 3 thanks to the redent 3 a makes it possible to define the bearing force of the pin 7 against the edges of the orifice 4.
- the pin 7 is circular and its end has a frustoconical bearing 7 a complementary to the frustoconical bearing 4 a of the orifice 4 so as to obtain a contact surface between the pin 7 and the orifice 4 sufficient for the closure to be watertight 'air.
- the cap 8 consists of a side skirt 21, the free edge of which bears on the shoulder 12, fitting into place with a slight tightening on the base of the dome 3 at the level where the insert 5 is located.
- skirt 21 is connected to a transverse circular base 22 carrying in its center, on its internal face, a stud 24 arranged in line with the orifice 4 when the cap is fitted onto the base of the dome 3; the stud 24 is shaped at its free end along a frustoconical surface 24 has substantially the same angle at the top as the frustoconical surface 4 b of the orifice 4.
- the assembly according to the invention is manufactured in the manner described below: four parts are prepared separately by molding: the assembly formed by the cylindrical skirt 9 of the tube 2 and the dome 3, the two elements of the insert 5 (the plate 14 and the support element 15), and the cap 8.
- the tube 2 and the dome 3 are made of multilayer heat-sealable plastic material, and the other parts are made of polyethylene.
- the plate 14 and the support element 15 are assembled with each other by inserting the skirt 20 in the blind housing 14 a , which is thus closed by the elastic membrane 6.
- the insert 5 thus assembled is introduced by the open end of the tube 2 and it is pushed in until the flange 19 abuts against the redent 3 has formed in the internal wall of the dome 3; the redent 3 a allows precise positioning of the insert and, consequently, precise positioning of the pin 7 relative to the orifice 4.
- the insert 5 stiffens the cylindrical skirt 11 of the dome and, therefore, the convex dome 13; in this way, the dispensing head is substantially rigid.
- Tube 2 is then filled using product P, which is, for example, sunscreen, and linear welding 10 is performed by heat-sealing after pinching the walls of skirt 9.
- the tube 2 is filled under vacuum. so as to avoid any air pollution during filling.
- the user When he wishes to use the product P, the user removes the cap 8. He then presses the tube 2 with his fingers. The product P contained in the tube 2 then passes through the channels 23 in the space 25 between the insert 5 and the dome 3. The pressure exerted by the product deforms the elastic membrane 6 which, initially planar (see FIG. 1) , becomes concave (see figure 3). The pin 7 fixed on the elastic membrane 6, which closed the orifice 4 (see FIG. 1) then moves in translation and releases the orifice 4 from the dome 3 (see FIG. 3): the product P is distributed by the orifice 4. When the user ceases to exert pressure on the tube 2, the elastic membrane 6 resumes by elasticity its flat shape and the pin 7 returns to close the orifice 4: the distribution of the product ceases.
- the elastic membrane 6 quickly regaining its shape, there is no air intake; in addition, the valve formed by the pin 7 and the orifice 4 is perfectly airtight. Under these conditions, the tube 2 cannot resiliently return to its initial volume and remains crushed: it is therefore easy for the user to assess the quantity of product P remaining in the tube 2. In addition, since there is no there is no return air, there is no risk of product pollution by air.
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- Engineering & Computer Science (AREA)
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- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
Abstract
Description
La présente invention concerne un ensemble de distribution de produit de consistance fluide à pâteuse comportant un récipient et une tête de distribution munie d'un orifice de distribution susceptible d'être ouvert ou obturé par un picot manoeuvré en translation par une membrane déformable. Cet ensemble est utilisable, notamment pour la distribution de produits cosmétiques, par exemple de crème solaire.The present invention relates to a product dispensing assembly of fluid to pasty consistency comprising a container and a dispensing head provided with a dispensing orifice capable of being opened or closed by a spike operated in translation by a deformable membrane. This set can be used, in particular for the distribution of cosmetic products, for example sunscreen.
Dans la présente description et dans les revendications, on entend par "produit fluide", tout produit sous forme de liquide, de crème ou de pâte susceptible de s'écouler.In the present description and in the claims, the term "fluid product" means any product in the form of a liquid, cream or paste capable of flowing.
On connaît, par FR-A-829 056, un ensemble comportant un récipient en matériau souple contenant le produit fluide à distribuer et une tête de distribution comportant un dôme munie d'au moins un orifice de distribution susceptible d'être fermé par un picot mobile porté par une membrane élastiquement déformable, l'orifice étant obturé par le picot en l'absence de toute surpression sur ladite membrane du côté où se trouve ledit picot et étant libéré quand on applique une surpression sur ladite membrane du côté où se trouve ledit picot, le récipient et le dôme constituant une seule pièce obtenue par moulage, un insert rigide étant mis en place à la base du dôme et délimitant, entre lui et le dôme, un espace, ledit insert comportant au moins un canal, qui met en communication ledit espace et le récipient, et portant, en vis-à-vis de l'orifice, la membrane déformable, cette dernière conférant au picot une force d'appui contre les bords de l'ouverture, ladite force d'appui et la surface de contact entre le picot et les bords de l'ouverture étant, en position de fermeture, suffisantes pour que ladite fermeture empêche toute reprise d'air après distribution, l'insert étant constitué d'un plateau au travers duquel est (sont) ménagé(s) le canal (les canaux) et d'un élément support qui porte la membrane et est solidaire dudit plateau, l'élément support étant disposé dans la zone centrale du plateau.FR-A-829 056 discloses an assembly comprising a receptacle made of flexible material containing the fluid product to be dispensed and a dispensing head comprising a dome provided with at least one dispensing orifice capable of being closed by a pin mobile carried by an elastically deformable membrane, the orifice being closed by the pin in the absence of any overpressure on said membrane on the side where said pin is located and being released when an overpressure is applied to said membrane on the side where said pin is located pin, the container and the dome constituting a single piece obtained by molding, a rigid insert being placed at the base of the dome and delimiting, between it and the dome, a space, said insert comprising at least one channel, which puts in communicating said space and the container, and carrying, vis-à-vis the orifice, the deformable membrane, the latter giving the pin a bearing force against the edges of the opening, said support force and the contact surface between the pin and the edges of the opening being, in the closed position, sufficient for said closure to prevent any air recovery after distribution, the insert being made up of a plate at the through which is (are) formed (s) the channel (s) and a support element which carries the membrane and is integral with said plate, the support element being arranged in the central zone of the plate.
Un tel ensemble permet d'assurer une distribution sans reprise d'air en mettant en oeuvre l'ouverture et la fermeture d'un orifice de distribution par un picot manoeuvré par une membrane déformable. On sait qu'en l'absence de reprise d'air, les récipients souples s'écrasent au fur et à mesure de la distribution, ce qui permet à l'utilisateur de repérer l'état de remplissage du récipient même si la paroi est totalement opaque. Au surplus, l'absence de reprise d'air évite la détérioration du produit en cours de distribution par oxydation et évite également la contamination du produit sur le plan bactérien d'où il résulte une réduction possible de l'emploi des conservateurs.Such an assembly makes it possible to ensure a distribution without air intake by implementing the opening and closing of a dispensing orifice by a spike operated by a membrane. deformable. We know that in the absence of air intake, the flexible containers are crushed as and when dispensed, which allows the user to identify the filling state of the container even if the wall is totally opaque. In addition, the absence of air intake prevents deterioration of the product during distribution by oxidation and also prevents contamination of the product on the bacterial level, which results in a possible reduction in the use of preservatives.
Toutefois, un tel ensemble connu nécessite, pour fonctionner correctement, un positionnement précis du picot par rapport à l'orifice ; malheureusement, rien n'est prévu dans l'ensemble selon FR-A-829 056 pour faciliter ce positionnement, et la présente invention a pour but de pallier cet inconvénient.However, such a known assembly requires, to function properly, precise positioning of the pin relative to the orifice; unfortunately, nothing is provided in the assembly according to FR-A-829,056 to facilitate this positioning, and the present invention aims to overcome this drawback.
La présente invention concerne donc un ensemble de distribution de produit de consistance fluide à pâteuse comportant un récipient en matériau souple contenant le produit fluide à distribuer et une tête de distribution comportant un dôme muni d'au moins un orifice de distribution susceptible d'être fermé par un picot mobile porté par une membrane élastiquement déformable, l'orifice étant obturé par le picot en l'absence de toute surpression sur ladite membrane du côté où se trouve ledit picot et étant libéré quand on applique une surpression sur ladite membrane du côté où se trouve ledit picot, le récipient et le dôme constituant une seule pièce obtenue par moulage, un insert rigide étant mis en place à la base du dôme et délimitant, entre lui et le dôme, un espace, ledit insert comportant au moins un canal, qui met en communication ledit espace et le récipient, et portant, en vis-à-vis de l'orifice, la membrane déformable, cette dernière conférant au picot une force d'appui contre les bords de l'ouverture, ladite force d'appui et la surface de contact entre le picot et les bords de l'ouverture étant, en position de fermeture, suffisantes pour que ladite fermeture empêche toute reprise d'air après distribution, l'insert étant constitué d'un plateau au travers duquel est (sont) ménagé(s) le canal (les canaux) et d'un élément support qui porte la membrane et est solidaire dudit plateau, I'élément support étant disposé dans la zone centrale du plateau, caractérisé par le fait que le plateau comporte, dans sa partie tournée vers le tube, une plaque circulaire dont la zone centrale est pleine et qui est moulée d'une seule pièce avec un élément annulaire qui forme avec la plaque un logement borgne cylindrique à l'intérieur duquel est fixé l'élément support, I'élément annulaire portant, à sa partie supérieure, une collerette venant en appui contre un redent prévu à l'intérieur du dôme à la jonction entre la jupe et la coupole.The present invention therefore relates to a product distribution assembly of fluid to pasty consistency comprising a container made of flexible material containing the fluid product to be dispensed and a dispensing head comprising a dome provided with at least one dispensing orifice capable of being closed. by a mobile pin carried by an elastically deformable membrane, the orifice being closed by the pin in the absence of any overpressure on said membrane on the side where said pin is located and being released when an overpressure is applied to said membrane on the side where there is said pin, the container and the dome constituting a single piece obtained by molding, a rigid insert being placed at the base of the dome and delimiting, between it and the dome, a space, said insert comprising at least one channel, which connects said space and the container, and bearing, vis-à-vis the orifice, the deformable membrane, the latter conferring at the pin a bearing force against the edges of the opening, said bearing force and the contact surface between the pin and the edges of the opening being, in the closed position, sufficient for said closure to prevent any recovery of air after distribution, the insert consisting of a plate through which is (are) formed (s) the channel (channels) and a support element which carries the membrane and is integral with said plate, I ' support element being arranged in the central zone of the plate, characterized in that the plate comprises, in its part turned towards the tube, a circular plate whose central zone is full and which is molded in one piece with an annular element which forms with the plate a cylindrical blind housing inside which is fixed the support element, the annular element carrying, at its upper part, a flange coming to bear against a recess provided inside the dome at the junction between the skirt and the dome.
Ainsi, grâce à cette disposition, l'insert est mis en place de façon précise grâce au redent, et donc le picot est positionné de manière précise relativement à l'orifice.Thus, thanks to this arrangement, the insert is put in place precisely thanks to the redent, and therefore the pin is positioned precisely relative to the orifice.
Le récipient est, de préférence, constitué par un tube dont la jupe cylindrique, de section circulaire ou ovale, est moulée d'une pièce avec le dôme et qui est fermé par une soudure linéaire dans sa zone opposée au dôme.The container is preferably constituted by a tube whose cylindrical skirt, of circular or oval section, is molded in one piece with the dome and which is closed by a linear weld in its zone opposite to the dome.
Avantageusement, I'élément support comprend une jupe cylindrique qui s'emboîte avec un léger serrage dans le logement borgne et une base constituant la membrane. Ceci permet de limiter le volume mort à l'intérieur du dôme.Advantageously, the support element comprises a cylindrical skirt which fits with a slight tightening in the blind housing and a base constituting the membrane. This limits the dead volume inside the dome.
De préférence, I'élément support est entouré par une pluralité de canaux organisés en couronne autour de lui. L'insert est, de préférence, constitué de deux pièces séparées assemblées : selon un mode de réalisation particulier, le plateau comporte, dans sa zone centrale, un logement borgne à l'intérieur duquel est fixé l'élément support, ce dernier comportant une zone cylindrique engagée dans ledit logement et une base constituant la membrane. Ce mode de réalisation en deux pièces permet d'obtenir un ensemble d'une plus grande rigidité et de limiter les problèmes d'étanchéité entre l'insert et la paroi du dôme, lorsque la paroi du dôme se déforme ; en effet, on peut utiliser pour mouler l'élément support portant la membrane élastique un matériau plastique plus souple que pour mouler le plateau dans lequel est (sont) ménagé(s) le canal (les canaux).Preferably, the support element is surrounded by a plurality of channels organized in a ring around it. The insert is preferably made up of two separate pieces assembled: according to a particular embodiment, the plate comprises, in its central zone, a blind housing inside which the support element is fixed, the latter comprising a cylindrical zone engaged in said housing and a base constituting the membrane. This two-piece embodiment makes it possible to obtain an assembly of greater rigidity and to limit the sealing problems between the insert and the wall of the dome, when the wall of the dome deforms; indeed, one can use to mold the support element carrying the elastic membrane a more flexible plastic material than to mold the tray in which is (are) formed (s) the channel (channels).
Le picot et les bords de l'orifice ont, de préférence, des formes complémentaires telles que la surface de contact entre l'extrémité du picot et le bord de l'ouverture soit importante. L'orifice de distribution comporte, avantageusement, une portée tronconique, le picot étant conformé à son extrémité libre selon une portée tronconique sensiblement de même angle au sommet.The spike and the edges of the orifice preferably have complementary shapes such that the contact surface between the end of the spike and the edge of the opening is large. The dispensing orifice advantageously comprises a frustoconical bearing, the pin being shaped at its free end according to a frustoconical bearing substantially of the same angle at the top.
L'ensemble comporte avantageusement un capuchon susceptible de recouvrir le dôme ; le capuchon est fixé par emboîtage, encliquetage ou vissage sur la base du dôme. Le capuchon comporte, de préférence, intérieurement un téton disposé au droit de l'orifice de distribution quand le capuchon est fixé sur le dôme ; selon un mode de réalisation préféré, l'orifice de distribution se termine, vers l'extérieur du dôme, par une portée tronconique et le téton est conformé à son extrémité libre selon une portée tronconique sensiblement de même angle au sommet ; de préférence, les deux portées tronconiques de l'orifice de distribution sont séparées l'une de l'autre par une zone cylindrique. Le capuchon permet ainsi d'éviter toute distribution accidentelle du produit au cours du stockage et des différentes opérations de manutention, dans le cas où une pression serait exercée sur le récipient.The assembly advantageously comprises a cap capable of covering the dome; the cap is fixed by fitting, latching or screwing on the base of the dome. The cap preferably comprises, internally, a stud arranged in line with the dispensing orifice when the cap is fixed to the dome; according to a preferred embodiment, the dispensing orifice ends, towards the outside of the dome, by a frustoconical bearing and the stud is shaped at its free end according to a frustoconical bearing substantially of the same angle at the top; preferably, the two frustoconical bearing surfaces of the dispensing orifice are separated from each other by a cylindrical zone. The cap thus avoids any accidental distribution of the product during storage and the various handling operations, in the event that pressure is exerted on the container.
Les différents éléments de l'ensemble peuvent être moulés en utilisant un même matériau thermoplastique : dans ce cas, on utilise, plus particulièrement, le polyéthylène qui a l'avantage d'être recyclable ; on peut néanmoins choisir des polyéthylènes d'élasticités différentes ; par exemple, on peut utiliser un polyéthylène plus rigide pour le plateau de l'insert que pour l'élément support. On préfère néanmoins que l'ensemble récipient-dôme soit moulé en un matériau thermoplastique différent, notamment en un matériau multicouche thermosoudable, ce type de matériau ayant l'avantage de présenter une grande imperméabilité à l'air.The various elements of the assembly can be molded using the same thermoplastic material: in this case, polyethylene is used, which has the advantage of being recyclable; it is nevertheless possible to choose polyethylenes of different elasticities; for example, a more rigid polyethylene may be used for the insert tray than for the support element. However, it is preferred that the container-dome assembly be molded from a different thermoplastic material, in particular from a heat-sealable multilayer material, this type of material having the advantage of being highly impermeable to air.
L'ensemble selon l'invention est simple à fabriquer. On moule séparément les différentes pièces : la pièce formée par la paroi du récipient non fermé et le dôme, les deux pièces formant l'insert et, éventuellement, le capuchon. On assemble les deux pièces formant l'insert puis on enfonce l'insert dans le récipient jusqu'à ce qu'il soit en place à la base du dôme. On introduit ensuite le produit à distribuer par le fond ouvert du récipient et on ferme l'extrémité ouverte de ce dernier, notamment par thermosoudage. Dans le cas où le récipient est un tube, on effectue, de préférence, une soudure linéaire sensiblement perpendiculaire à l'axe du tube. Pour finir, on dispose, éventuellement, le capuchon sur le dôme.The assembly according to the invention is simple to manufacture. The different parts are molded separately: the part formed by the wall of the unclosed container and the dome, the two parts forming the insert and, optionally, the cap. The two pieces forming the insert are assembled and then the insert is pushed into the container until it is in place at the base of the dome. The product to be dispensed is then introduced through the open bottom of the container and the open end of the container is closed, in particular by heat sealing. In the case where the container is a tube, a linear weld is preferably carried out substantially perpendicular to the axis of the tube. Finally, we possibly have the cap on the dome.
L'ensemble selon l'invention fonctionne de la façon suivante : lors de l'utilisation, l'utilisateur enlève le capuchon pour dégager l'orifice ménagé sur le dôme ; il comprime ensuite les parois latérales du récipient souple avec ses doigts. Sous la pression produite, le produit contenu dans le récipient passe par les canaux ménagés dans l'insert, et pénètre dans l'espace compris entre l'insert et le dôme. La pression exercée sur le produit par les doigts de l'utilisateur déforme la membrane élastique portant le picot ; ce picot, qui initialement fermait l'orifice de distribution, se déplace en translation et libère l'orifice de distribution ; le produit sort alors par l'orifice de distribution et peut être appliqué. Simultanément le récipient, qui est souple, s'écrase. Lorsque l'utilisateur cesse d'appuyer sur le récipient, la pression exercée par le produit sur la membrane cesse et la membrane revient par élasticité dans sa position première, le picot fermant à nouveau l'orifice de distribution.The assembly according to the invention operates as follows: during use, the user removes the cap to release the orifice provided on the dome; he then compresses the walls side of the flexible container with his fingers. Under the pressure produced, the product contained in the container passes through the channels provided in the insert, and enters the space between the insert and the dome. The pressure exerted on the product by the user's fingers deforms the elastic membrane carrying the spike; this pin, which initially closed the dispensing orifice, moves in translation and releases the dispensing orifice; the product then leaves through the dispensing orifice and can be applied. Simultaneously the container, which is flexible, crashes. When the user stops pressing on the container, the pressure exerted by the product on the membrane ceases and the membrane returns by elasticity to its initial position, the pin again closing the dispensing orifice.
La membrane reprenant très rapidement sa position première et le picot coopérant de façon étanche avec le bord de l'orifice, il n'y a pas de reprise d'air ; par conséquent, on évite la détérioration du produit à distribuer par oxydation à l'air et sa contamination par les microorganismes de l'air ; on peut donc réduire l'utilisation d'agents conservateurs dans le produit à distribuer. De plus, le tube reste, après distribution, sous sa forme partiellement écrasée : l'utilisateur peut ainsi facilement évaluer la quantité de produit restant dans le tube, même si celui-ci est opaque.The membrane returning very quickly to its initial position and the pin cooperating in a sealed manner with the edge of the orifice, there is no air intake; consequently, the deterioration of the product to be dispensed by air oxidation and its contamination by air microorganisms is avoided; we can therefore reduce the use of preservatives in the product to be distributed. In addition, the tube remains, after dispensing, in its partially crushed form: the user can thus easily assess the quantity of product remaining in the tube, even if the latter is opaque.
Par ailleurs, il faut noter que l'espace compris entre la pièce insérée et le dôme peut être proportionnellement très faible par rapport au volume du récipient ; le volume intérieur des canaux est également très faible par rapport au volume du récipient ; dans ces conditions, le volume mort est faible, la quantité de produit non expulsable qu'il contient est faible et le taux de restitution du produit à distribuer est donc élevé.Furthermore, it should be noted that the space between the inserted part and the dome can be proportionally very small compared to the volume of the container; the internal volume of the channels is also very small compared to the volume of the container; under these conditions, the dead volume is low, the quantity of non-expellable product that it contains is low and the rate of return of the product to be distributed is therefore high.
Pour mieux faire comprendre l'objet de l'invention, on va en décrire, ci-après, à titre d'exemple purement illustratif et non limitatif, un mode de réalisation représenté sur le dessin annexé.To better understand the object of the invention, there will be described below, by way of purely illustrative and non-limiting example, an embodiment shown in the accompanying drawing.
Sur ce dessin :
- la figure 1 est une vue en élévation en coupe partielle d'un ensemble selon l'invention comportant son capuchon, avec arrachement en coupe ;
- la figure 2 est une vue partielle en coupe axiale de l'ensemble de distribution de la figure 1 avant distribution, le capuchon étant dégagé du dôme ;
- la figure 3 est une vue partielle en coupe axiale de l'ensemble de distribution de la figure 1 pendant la distribution, le capuchon étant enlevé ;
- la figure 4 représente, à grande échelle, la zone L de la figure 1 ;
- la figure 5 représente, en perspective, le plateau de l'insert ;
- la figure 6 représente, en perspective, l'élément-support de l'insert.
- Figure 1 is an elevational view in partial section of an assembly according to the invention comprising its cap, with cutaway;
- Figure 2 is a partial view in axial section of the dispensing assembly of Figure 1 before dispensing, the cap being released from the dome;
- Figure 3 is a partial view in axial section of the dispensing assembly of Figure 1 during dispensing, the cap being removed;
- FIG. 4 represents, on a large scale, the zone L of FIG. 1;
- Figure 5 shows, in perspective, the tray of the insert;
- FIG. 6 represents, in perspective, the support element of the insert.
L'ensemble 1 de distribution représenté sur les figures 1 à 4 est constitué d'un récipient formé par un tube 2 contenant le produit à distribuer et d'une tête de distribution constituée par un dôme 3 venu de moulage avec le tube 2 et par un insert 5 dans lequel sont ménagés des canaux 23, ledit insert portant une membrane élastique 6 munie d'un picot 7. L'insert 5 est disposé à la base du dôme 3. Dans le dôme 3 est ménagé un orifice 4. Le dôme 3 est recouvert par un capuchon 8.The distribution assembly 1 shown in FIGS. 1 to 4 consists of a container formed by a tube 2 containing the product to be distributed and of a distribution head constituted by a
Le tube 2 est formé d'une jupe cylindrique 9 pincée à son extrémité opposée au dôme 3 par une soudure linéaire 10. Le dôme 3 est coaxial avec le tube 2 ; il est constitué, d'une part, d'une jupe cylindrique 11 de plus faible diamètre que la jupe cylindrique 9 du tube 2, la jupe 11 étant reliée à la jupe 9 par un épaulement circulaire 12, et, d'autre part, d'une coupole 13, dont la convexité est tournée vers l'extérieur. Un redent 3a est prévu à l'intérieur du dôme 3 à la jonction entre la jupe 11 et la coupole 13. Un orifice 4 est ménagé au centre de la coupole 13 ; les parois latérales dudit orifice 4 (voir figure 4) ont la forme de deux portées tronconiques 4a, 4b séparées l'une de l'autre par une zone cylindrique.The tube 2 is formed of a cylindrical skirt 9 pinched at its end opposite to the
L'insert 5 est constitué de deux pièces assemblées par emboîtage : un plateau 14, dans lequel sont ménagés quatre canaux 23 et un élément-support 15 portant la membrane 6 munie du picot 7. Le plateau 14 comporte, dans sa partie tournée vers le tube 2, une plaque circulaire 16, qui est munie de quatre ouvertures formant l'entrée des canaux 23 et dont la zone centrale est pleine. Cette plaque circulaire a un diamètre égal. au jeu nécessaire près, au diamètre interne de la jupe cylindrique 11 du dôme 3. La plaque circulaire 16 est moulée d'une pièce avec un élément annulaire 17 qui forme avec la plaque 16 un logement borgne 14a cylindrique. L'élément annulaire 17 porte, à sa partie supérieure, une collerette 19 de diamètre externe égal, au jeu nécessaire près, au diamètre du dôme 3 au-dessous du redent 3a, la collerette 19 venant en appui contre le redent 3a. Les canaux 23 sont régulièrement disposés à la périphérie de l'élément annulaire 17 et débouchent d'un côté dans la plaque 16 et de l'autre dans la collerette 19.The
L'élément-support 15 est constitué par la membrane 6 portant en son centre le picot 7, qui constitue une base transversale circulaire, et par une jupe cylindrique 20, qui a un diamètre externe égal au diamètre interne de l'élément annulaire 17 et qui a la même hauteur, de façon à pouvoir s'emboîter avec un léger serrage dans le logement borgne 14a limité par l'élément annulaire 17 et la plaque 16. Le picot 7 est disposé au droit de l'orifice 4 prévu dans l'axe du dôme 3 et la précision de la mise en place de l'insert 5 dans le dôme 3 grâce au redent 3a permet de définir la force d'appui du picot 7 contre les bordures de l'orifice 4. Le picot 7 est circulaire et son extrémité a une portée tronconique 7a complémentaire de la portée tronconique 4a de l'orifice 4 de façon à obtenir une surface de contact entre le picot 7 et l'orifice 4 suffisante pour que la fermeture puisse être étanche à l'air.The
Le capuchon 8 est constitué d'une jupe latérale 21, dont le bord libre vient en appui sur l'épaulement 12, en s'emboîtant avec un léger serrage sur la base du dôme 3 au niveau où se trouve l'insert 5. La jupe 21 est reliée à une base circulaire 22 transversale portant en son centre, sur sa face interne, un téton 24 disposé au droit de l'orifice 4 quand le capuchon est emboîté sur la base du dôme 3 ; le téton 24 est conformé à son extrémité libre selon une portée tronconique 24a sensiblement de même angle au sommet que la portée tronconique 4b de l'orifice 4.The
L'ensemble selon l'invention est fabriqué de la façon décrite ci-après : on prépare séparément par moulage quatre pièces : l'ensemble formé par la jupe cylindrique 9 du tube 2 et le dôme 3, les deux éléments de l'insert 5 (le plateau 14 et l'élément-support 15), et le capuchon 8. Le tube 2 et le dôme 3 sont en matériau plastique multicouche thermosoudable, et les autres pièces en polyéthylène. On assemble l'un avec l'autre le plateau 14 et l'élément-support 15 en insérant la jupe 20 dans le logement borgne 14a, qui est ainsi fermé par la membrane élastique 6. On introduit l'insert 5 ainsi assemblé par l'extrémité ouverte du tube 2 et on l'enfonce jusqu'à ce que la collerette 19 vienne en butée contre le redent 3a ménagé dans la paroi interne du dôme 3 ; le redent 3a permet une mise en place précise de l'insert et, par conséquent, un positionnement précis du picot 7 par rapport à l'orifice 4. De plus, l'insert 5 vient rigidifier la jupe cylindrique 11 du dôme et, par conséquent, la coupole convexe 13 ; de cette façon, la tête de distribution est sensiblement rigide. On remplit ensuite le tube 2 à l'aide du produit P qui est, par exemple, une crème solaire et on effectue par thermosoudage la soudure linéaire 10 après pincement des parois de la jupe 9. Le remplissage du tube 2 est effectué sous vide de façon à éviter toute pollution par l'air au cours du remplissage.The assembly according to the invention is manufactured in the manner described below: four parts are prepared separately by molding: the assembly formed by the cylindrical skirt 9 of the tube 2 and the
Lorsqu'il désire utiliser le produit P, l'utilisateur enlève le capuchon 8. Il appuie ensuite sur le tube 2 avec les doigts. Le produit P contenu dans le tube 2 passe alors par les canaux 23 dans l'espace 25 compris entre l'insert 5 et le dôme 3. La pression exercée par le produit déforme la membrane élastique 6 qui, initialement plane (voir figure 1), devient concave (voir figure 3). Le picot 7 fixé sur la membrane élastique 6, qui fermait l'orifice 4 (voir figure 1) se déplace alors en translation et libère l'orifice 4 du dôme 3 (voir figure 3) : le produit P est distribué par l'orifice 4. Lorsque l'utilisateur cesse d'exercer une pression sur le tube 2, la membrane élastique 6 reprend par élasticité sa forme plane et le picot 7 revient fermer l'orifice 4 : la distribution du produit cesse. La membrane élastique 6 reprenant rapidement sa forme, il n'y a pas de reprise d'air ; de plus, la valve constituée par le picot 7 et l'orifice 4 est parfaitement étanche à l'air. Dans ces conditions, le tube 2 ne peut pas reprendre élastiquement son volume initial et reste écrasé : il est, par conséquent, facile pour l'utilisateur d'évaluer la quantité de produit P restant dans le tube 2. De plus, comme il n'y a pas de reprise d'air, il n'y pas de risques de pollution du produit par l'air.When he wishes to use the product P, the user removes the
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9309411A FR2708485B1 (en) | 1993-07-30 | 1993-07-30 | Fluid to pasty product distribution assembly without air intake comprising a deformable membrane. |
FR9309411 | 1993-07-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0636549A1 true EP0636549A1 (en) | 1995-02-01 |
EP0636549B1 EP0636549B1 (en) | 1995-11-02 |
Family
ID=9449799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94401668A Expired - Lifetime EP0636549B1 (en) | 1993-07-30 | 1994-07-20 | Assembly for dispensing a liquid or pasty product without air suction, with a deformable membrane |
Country Status (6)
Country | Link |
---|---|
US (1) | US5454494A (en) |
EP (1) | EP0636549B1 (en) |
CA (1) | CA2129165C (en) |
DE (1) | DE69400030T2 (en) |
ES (1) | ES2079252T3 (en) |
FR (1) | FR2708485B1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0849186A1 (en) * | 1996-12-19 | 1998-06-24 | RPC Bramlage GmbH | Multi-function-tube |
WO1999055594A1 (en) * | 1998-04-29 | 1999-11-04 | Nickels Jean Charles | Sealed fluid dispensing device |
NL2004211C2 (en) * | 2010-02-08 | 2011-08-09 | Vacu Vin Innovations Ltd | Dispensing assembly. |
EP2489600A1 (en) | 2011-02-16 | 2012-08-22 | Albéa Services | Tube head provided with a non-rebreathing grating |
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DE19623030A1 (en) * | 1996-06-08 | 1997-12-11 | Pfeiffer Erich Gmbh & Co Kg | Discharge unit for media |
US5871758A (en) * | 1996-12-11 | 1999-02-16 | E-L Management Corp. | Dual phase cosmetic composition |
FR2767311B1 (en) * | 1997-08-12 | 1999-10-01 | Valois Sa | SHUTTERING SYSTEM AND FLUID PRODUCT DELIVERY DEVICE COMPRISING SUCH A SYSTEM |
AU8553198A (en) * | 1997-08-12 | 1999-03-01 | Veresk Biosystems Limited | Container |
US5971232A (en) * | 1998-06-03 | 1999-10-26 | Aptargroup, Inc. | Dispensing structure which has a pressure-openable valve retained with folding elements |
RU2224702C2 (en) * | 1998-08-03 | 2004-02-27 | Вереск Байосистемз Лимитед | Liquid container |
FR2792552B1 (en) * | 1999-04-20 | 2002-04-19 | Valois Sa | FLUID PRODUCT SPRAY HEAD COMPRISING AN IMPROVED SHUTTER |
IT1310921B1 (en) * | 1999-06-24 | 2002-02-27 | Mrp Medical Res & Promotion Es | PLURIDOSE BOTTLE WITH DOSING SPOUT FOR LIQUIDS, PARTICULARLY PHARMACEUTICAL PRODUCTS. |
US20050087571A1 (en) * | 2002-09-20 | 2005-04-28 | Dark Richard C. | Fluid dispensing valve and method of assembly |
US20070293842A1 (en) * | 2004-07-14 | 2007-12-20 | Acrux Dds Pty Ltd | Cap With Seal Moved By Rotatable Collar And Receptacle With Spreading Surface |
DE102010009102B4 (en) * | 2010-02-24 | 2014-08-28 | Gaplast Gmbh | Double-walled squeeze bottle with valve in the airless system |
DE102011007396A1 (en) | 2011-04-14 | 2012-10-18 | Ing. Erich Pfeiffer Gmbh | Discharge head for a tube and tube with discharge head |
KR101556652B1 (en) * | 2013-04-10 | 2015-10-01 | (주)연우 | Tube vessel with an applicator |
US10392239B2 (en) * | 2016-07-29 | 2019-08-27 | Berry Plastics Corporation | Liquid dispenser |
JP6589158B1 (en) * | 2019-05-23 | 2019-10-16 | 株式会社ベッセル・ジャパン | Air bagless structure |
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- 1994-07-20 ES ES94401668T patent/ES2079252T3/en not_active Expired - Lifetime
- 1994-07-20 DE DE69400030T patent/DE69400030T2/en not_active Expired - Fee Related
- 1994-07-20 EP EP94401668A patent/EP0636549B1/en not_active Expired - Lifetime
- 1994-07-25 US US08/280,119 patent/US5454494A/en not_active Expired - Fee Related
- 1994-07-29 CA CA002129165A patent/CA2129165C/en not_active Expired - Fee Related
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0849186A1 (en) * | 1996-12-19 | 1998-06-24 | RPC Bramlage GmbH | Multi-function-tube |
WO1999055594A1 (en) * | 1998-04-29 | 1999-11-04 | Nickels Jean Charles | Sealed fluid dispensing device |
FR2778173A1 (en) * | 1998-04-29 | 1999-11-05 | Jean Charles Nickels | HERMETIC FLUID DISPENSING DEVICE |
NL2004211C2 (en) * | 2010-02-08 | 2011-08-09 | Vacu Vin Innovations Ltd | Dispensing assembly. |
WO2011096814A1 (en) * | 2010-02-08 | 2011-08-11 | Vacu Vin Innovations Limited | Dispensing assembly |
US9027800B2 (en) | 2010-02-08 | 2015-05-12 | Vacu Vin Innovations Limited | Dispensing assembly |
RU2594858C2 (en) * | 2010-02-08 | 2016-08-20 | Вэкью Вин Инновейшнз Лимитед | Batching device |
EP2489600A1 (en) | 2011-02-16 | 2012-08-22 | Albéa Services | Tube head provided with a non-rebreathing grating |
Also Published As
Publication number | Publication date |
---|---|
CA2129165A1 (en) | 1995-01-31 |
CA2129165C (en) | 1997-11-25 |
ES2079252T3 (en) | 1996-01-01 |
DE69400030T2 (en) | 1996-07-04 |
US5454494A (en) | 1995-10-03 |
EP0636549B1 (en) | 1995-11-02 |
FR2708485A1 (en) | 1995-02-10 |
DE69400030D1 (en) | 1995-12-07 |
FR2708485B1 (en) | 1995-10-20 |
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