EP0687880A1 - Tube with a plurality of spiral ribs and method of manufacturing the same - Google Patents
Tube with a plurality of spiral ribs and method of manufacturing the same Download PDFInfo
- Publication number
- EP0687880A1 EP0687880A1 EP95108495A EP95108495A EP0687880A1 EP 0687880 A1 EP0687880 A1 EP 0687880A1 EP 95108495 A EP95108495 A EP 95108495A EP 95108495 A EP95108495 A EP 95108495A EP 0687880 A1 EP0687880 A1 EP 0687880A1
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- EP
- European Patent Office
- Prior art keywords
- finned tube
- rib
- tube according
- rolling
- finned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 23
- 238000005096 rolling process Methods 0.000 claims description 59
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000011295 pitch Substances 0.000 description 13
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
- F28F13/185—Heat-exchange surfaces provided with microstructures or with porous coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- B21C37/15—Making tubes of special shape; Making tube fittings
- B21C37/20—Making helical or similar guides in or on tubes without removing material, e.g. by drawing same over mandrels, by pushing same through dies ; Making tubes with angled walls, ribbed tubes and tubes with decorated walls
- B21C37/207—Making helical or similar guides in or on tubes without removing material, e.g. by drawing same over mandrels, by pushing same through dies ; Making tubes with angled walls, ribbed tubes and tubes with decorated walls with helical guides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/34—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely
- F28F1/36—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely the means being helically wound fins or wire spirals
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/42—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being both outside and inside the tubular element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/42—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being both outside and inside the tubular element
- F28F1/422—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being both outside and inside the tubular element with outside means integral with the tubular element and inside means integral with the tubular element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/02—Light metals
- F05C2201/021—Aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S165/00—Heat exchange
- Y10S165/51—Heat exchange having heat exchange surface treatment, adjunct or enhancement
- Y10S165/518—Conduit with discrete fin structure
- Y10S165/524—Longitudinally extending
- Y10S165/525—Helical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
- Y10T29/49377—Tube with heat transfer means
- Y10T29/49378—Finned tube
- Y10T29/49382—Helically finned
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/53—Means to assemble or disassemble
- Y10T29/53113—Heat exchanger
- Y10T29/53122—Heat exchanger including deforming means
Definitions
- the invention relates to a metallic finned tube, in particular for heat exchangers or the like; with helical circumferential, multi-start integral ribs on the outside (see, for example, DE-AS 2.110.485).
- Finned tubes with single or multi-start fins running helically on the outside are rolled out of the tube wall by means of rolling tools which have roller disks arranged on tool shafts (cf. US Pat. Nos. 1,865,575 / 3,327,512 and Fig. 1).
- the transferable thermal performance of finned tubes depends, among other things, on the enlargement of the surface achieved by the fins. For this reason, the fin division of finned tubes has decreased continuously in recent years. As a result, the surface enlargement achieved by the ribbing could be increased further and further. With a rib pitch of 0.63 mm (corresponding to 1574 ribs per m), the surface is quadrupled compared to the smooth tube. In applications with phase change, ie in evaporators and condensers, surface forces and capillary-porous effects result in additional intensification of the heat transfer, in particular in the case of Pipes with small fin pitches reached.
- the invention has for its object to improve the heat transfer performance of the known finned tubes, an economical production of the finned tubes must be ensured.
- the object is achieved in that at a rate n ⁇ 4 at least one group is formed which has at least two adjacent starts (A1, A2 or A3, A4 ...) of rib courses.
- groups of two, three or four beginnings of finned passages are formed.
- the invention is particularly suitable for high-performance finned tubes in which the fin tips are compressed on the outside either to form thickened ends, are notched and possibly split after the notching to form cavities and / or are laterally bent and / or compressed.
- the inside has corrugations, which can also be interrupted and whose spacing - viewed in the longitudinal direction of the tube - preferably corresponds to the product of the fin pitch t R and pitch n.
- protrusions are recommended on the inside, which are formed by two intersecting systems of oppositely helical inner trains.
- the invention further relates to a method for producing the finned tube according to the invention.
- the fins were originally rolled on the outside of a finned tube.
- w roll is the rolling speed
- ⁇ is the inclination angle
- D sch is the diameter of the largest rolling disk
- ⁇ is the speed of the tool shafts.
- D sch are geometrical limits; because the maximum diameter results from the condition that the roller disks of adjacent tool shafts must not touch during operation.
- n is the movement rate
- R t is the pitch of the ribs and D core
- the core diameter of the finned tube is. Accordingly, for a given rib geometry (pitch and core diameter), the inclination can only be increased by increasing the pitch.
- the method according to the invention is characterized in that the desired movement n of the existing number N of rolling tools is adapted in such a way that one or more of the rolling tools each more generate as a ribbed duct; d. H. it is always n> N.
- the method according to the invention is based on the fact that at least one rolling tool is used to produce more than one rib gear.
- the ability to roll finned tubes is thus increased considerably beyond what was previously possible.
- the present invention enables the output of rolling devices to be multiplied.
- the maximum limit of the movement is the achievable inclination angles of the devices, apart from the self-locking.
- each rolling tool produces two, three or four rib courses.
- a method according to claim 20 is recommended for producing a finned tube with compressed fin tips, a method according to claim 21 for producing a finned tube with notched finned tips and one according to claim 22 for producing a finned tube with split and / or bent and / or compressed finned tips.
- a profiled rolling mandrel is recommended for producing a finned tube according to the invention with inner fins.
- a method according to claim 24 is proposed for finned tube with inner corrugations (cf. also EPS 0.102.407).
- a corrugated washer is not used in all rolling tools.
- FIG. 1 schematically shows an integral finned tube 1 according to the invention, on the outside of which fins 2 run helically, between which a groove 3 is formed.
- the ribs 2 have a height h R ; the rib division (distance from center of rib to center of rib) is denoted by t R.
- the finned tube 1 according to the invention is produced by a rolling process (cf. US Pat. Nos. 1,865,575 / 3,327,512) using the device shown in FIGS. 1 and 2b.
- the tool holder 4 can be adjusted radially. They are in turn arranged in a stationary roller head (not shown) (according to another variant, the tube is only advanced axially when the roller head is rotating).
- the smooth pipe 1 'entering the device in the direction of the arrow is set in rotation by the driven rolling tools 5 arranged on the circumference, the shafts 6 of the rolling tools 5 running obliquely to the pipe axis.
- the rolling tools 5 consist, in a manner known per se, of a plurality of rolling disks 7 arranged side by side on the shafts 6, the diameter of which increases in the direction of the arrow.
- the centrally arranged rolling tools 5 form the helically surrounding ribs 2 from the tube wall of the smooth tube 1 ', the smooth tube 1' being supported here by a profiled rolling mandrel 8.
- the ribs which are denoted by the number 9, are formed on the inside of the tube 1 in the form of a spiral.
- FIG. 3 shows schematically the difference between the inventive and conventional rolling method using the example of six-speed rolling.
- Fig. 3a three groups of two adjacent beginnings A1, A2 or A3, A4 or A5, A6 (the latter not shown) of fins are distributed evenly over the circumference of the tube, while according to Fig. 3b six individual beginnings A1, A2, A3, A4, A5, A6 (A4 - A6 not shown) are arranged on the pipe circumference. (For the rest, the previous reference numbers, some of which are provided with indices, are used in FIGS. 3a, 3b.)
- finned tubes 1 with a fin pitch t R ⁇ 0.53 mm were produced on a device with four rolling tools 5 in eight threads.
- the fin height h R 0.95 mm.
- Another implementation is based on the eight-thread rolling of a finned tube 1 with a pitch t R ⁇ 0.64 mm with a similar internal structure as described above.
- FIG. 4 shows, in addition to FIG. 1, a rolling device in which a swaging disk 10 is additionally integrated in the tool holder 4 for upsetting into T-shaped rib tips 2 '.
- FIG. 5 shows a partial section perpendicular to the tube axis, in which the sizes rib diameter D, inner diameter D i , rib height h i , average flank spacing W and the apex angle ⁇ of the inner ribs 9 are entered.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Geometry (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Bending Of Plates, Rods, And Pipes (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Abstract
Die Erfindung betrifft ein metallisches Rippenrohr (1), insbesondere für Wärmetauscher oder dgl., mit auf der Außenseite schraubenlinienförmig umlaufenden, mehrgängigen integralen Rippen (2), wobei die n Rippengänge am Rohranfang - gleichmäßig über den Rohrumfang verteilt - beginnen. Das Rippenrohr (1) ist dadurch gekennzeichnet, daß bei einer Gängigkeit n >= 4 mindestens eine Gruppe gebildet ist, die mindestens zwei nebeneinanderliegende Anfänge (A1, A2 bzw. A3, A4 ...) von Rippengängen aufweist. Durch das erfindungsgemäße Verfahren wird eine wirtschaftliche Herstellung des erfindungsgemäßen Rippenrohres (1) gewährleistet. <IMAGE>The invention relates to a metallic finned tube (1), in particular for heat exchangers or the like, with multi-start integral fins (2) that run around the outside in a helical manner, the n finned passages beginning at the beginning of the tube - evenly distributed over the circumference of the tube. The finned tube (1) is characterized in that at a rate n> = 4 at least one group is formed which has at least two adjacent starts (A1, A2 or A3, A4 ...) of finned passages. The method according to the invention ensures economical production of the finned tube (1) according to the invention. <IMAGE>
Description
Die Erfindung betrifft ein metallisches Rippenrohr, insbesondere für Wärmeaustauscher oder dgl.; mit auf der Außenseite schraubenlinienförmig umlaufenden, mehrgängigen integralen Rippen (vgl. beispielsweise DE-AS 2.110.485).The invention relates to a metallic finned tube, in particular for heat exchangers or the like; with helical circumferential, multi-start integral ribs on the outside (see, for example, DE-AS 2.110.485).
Rippenrohre mit auf der Außenseite schraubenlinienförmig umlaufenden, ein- oder mehrgängigen Rippen werden mittels Walzwerkzeugen, die auf Werkzeugwellen angeordnete Walzscheiben aufweisen, aus der Rohrwandung herausgewalzt (vgl. US-PSen 1.865.575/3.327.512 und Fig. 1).Finned tubes with single or multi-start fins running helically on the outside are rolled out of the tube wall by means of rolling tools which have roller disks arranged on tool shafts (cf. US Pat. Nos. 1,865,575 / 3,327,512 and Fig. 1).
Während beim Gewindewalzen auf Stangen bzw. dickwandigen Rohren häufig Vorrichtungen mit zwei gegenüber angeordneten Walzwerkzeugen Verwendung finden, werden zum Walzen von Rippenrohren Vorrichtungen mit drei oder vier gleichmäßig am Rohrumfang verteilten Walzwerkzeugen verwendet (vgl. Fig.2).While thread rolling on bars or thick-walled pipes often uses devices with two rolling tools arranged opposite one another, devices with three or four rolling tools evenly distributed around the pipe circumference are used for rolling finned pipes (see Fig. 2).
Die übertragbare thermische Leistung von Rippenrohren hängt u. a. von der durch die Berippung erreichten Vergrößerung der Oberfläche ab. Deshalb hat die Rippenteilung von berippten Rohren in den letzten Jahren immer weiter abgenommen. Hierdurch konnte die durch die Berippung erreichte Oberflächenvergrößerung immer weiter gesteigert werden. Bei einer Rippenteilung von 0,63 mm (entsprechend 1574 Rippen je m) wird etwa eine Vervierfachung der Oberfläche gegenüber dem glatten Rohr erreicht. Bei Anwendungen mit Phasenwechsel, d. h. in Verdampfern und Kondensatoren, wird durch Oberflächenkräfte und kapillarporöse Effekte eine zusätzliche Intensivierung des Wärmeübergangs, insbesondere bei Rohren mit geringen Rippenteilungen, erreicht.The transferable thermal performance of finned tubes depends, among other things, on the enlargement of the surface achieved by the fins. For this reason, the fin division of finned tubes has decreased continuously in recent years. As a result, the surface enlargement achieved by the ribbing could be increased further and further. With a rib pitch of 0.63 mm (corresponding to 1574 ribs per m), the surface is quadrupled compared to the smooth tube. In applications with phase change, ie in evaporators and condensers, surface forces and capillary-porous effects result in additional intensification of the heat transfer, in particular in the case of Pipes with small fin pitches reached.
Der Erfindung liegt die Aufgabe zugrunde, die Wärmeübertragungsleistung der bekannten Rippenrohre zu verbessern, wobei eine wirtschaftliche Herstellung der Rippenrohre gewährleistet sein muß.The invention has for its object to improve the heat transfer performance of the known finned tubes, an economical production of the finned tubes must be ensured.
Die Aufgabe wird erfindungsgemäß dadurch gelöst, daß bei einer Gängigkeit n ≧ 4 mindestens eine Gruppe gebildet ist, die mindestens zwei nebeneinanderliegende Anfänge (A₁, A₂ bzw. A₃, A₄ ...) von Rippengängen aufweist.The object is achieved in that at a rate n ≧ 4 at least one group is formed which has at least two adjacent starts (A₁, A₂ or A₃, A₄ ...) of rib courses.
Die wirtschaftliche Herstellung des erfindungsgemäßen Rippenrohres wird im Zusammenhang mit dem erfindungsgemäßen Verfahren erläutert.The economical production of the finned tube according to the invention is explained in connection with the method according to the invention.
Nach bevorzugten Ausführungsformen des erfindungsgemäßen Rippenrohres sind jeweils Gruppen von zwei, drei oder vier Anfängen von Rippengängen gebildet.According to preferred embodiments of the finned tube according to the invention, groups of two, three or four beginnings of finned passages are formed.
Beispielsweise ergeben sich bei einer Vorrichtung mit drei Walzwerkzeugen und sechsgängiger Walzweise drei Gruppen von jeweils zwei nebeneinanderliegenden Anfängen von Rippengängen, wie in Fig. 3a gezeigt. Im Gegensatz dazu würden sich bei einer Vorrichtung mit sechs Walzwerkzeugen bei sechsgängiger Walzweise sechs Anfänge von Rippengängen ergeben (Fig. 3b).For example, in the case of a device with three rolling tools and a six-course rolling method, there are three groups, each with two adjacent starts of rib passes, as shown in FIG. 3a. In contrast to this, in the case of a device with six rolling tools, with six-course rolling, there would be six starts of rib courses (FIG. 3b).
Die Erfindung eignet sich insbesondere für Hochleistungsrippenrohre, bei denen die Rippenspitzen auf der Außenseite entweder unter Ausbildung verdickter Enden gestaucht sind, eingekerbt sind und eventuell nach dem Kerben unter Ausbildung von Hohlräumen gespalten und/oder seitlich umgebogen und/oder gestaucht sind.The invention is particularly suitable for high-performance finned tubes in which the fin tips are compressed on the outside either to form thickened ends, are notched and possibly split after the notching to form cavities and / or are laterally bent and / or compressed.
Bei den erfindungsgemäßen Rippenrohren beträgt die Rippenteilung vorzugsweise tR = 0,25 - 1,50 mm und die Rippenhöhe hR ≦ 1,60 mm.In the finned tubes according to the invention, the fin pitch is preferably t R = 0.25-1.50 mm and the fin height h R ≦ 1.60 mm.
Zur Intensivierung des Wärmeübergangs kann die erfindungsgemäß ausgebildete Außenseite der Rippenrohre mit unterschiedlichen Strukturen auf der Rohrinnenseite kombiniert werden. Dabei wird vorzugsweise vorgeschlagen, daß die Innenseite schraubenlinienförmig umlaufende Innenrippen aufweist, deren Teilung - senkrecht zu den Innenrippen gemessen - ti = 0,5 - 3 mm, deren Höhe hi = 0,2 - 0,5 mm und deren Steigungswinkel ϑ = 25 - 70° beträgt.To intensify the heat transfer, the outside of the finned tubes designed according to the invention can be combined with different structures on the inside of the tube. It is preferably proposed that the inside has helical circumferential inner ribs, the division - measured perpendicular to the inner ribs - t i = 0.5 - 3 mm, their height h i = 0.2 - 0.5 mm and their pitch angle ϑ = 25 - 70 °.
Nach einer weiteren Ausführungsform der Erfindung beträgt der Steigungswinkel der Innenrippen (9) ϑ = 5 - 25°, das Verhältnis der Höhe der Innenrippen (9) zum Innendurchmesser des Rohres hi/Di = 0,02 - 0,03, der mittlere Flankenabstand der Innenrippen (9) W = 0,15 - 40 mm und der Scheitelwinkel der Innenrippen γ = 30 - 60° (W und γ werden in einer Schnittebene senkrecht zur Rohrachse gemessen).According to a further embodiment of the invention, the pitch angle of the inner fins (9) ϑ = 5 - 25 °, the ratio of the height of the inner fins (9) to the inner diameter of the tube h i / D i = 0.02 - 0.03, the middle Flank distance of the inner fins (9) W = 0.15 - 40 mm and the apex angle of the inner fins γ = 30 - 60 ° (W and γ are measured in a section plane perpendicular to the pipe axis).
Nach einer anderen Alternative weist die Innenseite Wellungen auf, die auch unterbrochen sein können und deren Abstand - in Rohrlängsrichtung gesehen - vorzugsweise dem Produkt aus Rippenteilung tR und Gängigkeit n entspricht.According to another alternative, the inside has corrugations, which can also be interrupted and whose spacing - viewed in the longitudinal direction of the tube - preferably corresponds to the product of the fin pitch t R and pitch n.
Weiterhin sind auf der Innenseite Vorsprünge empfehlenswert, die durch zwei einander kreuzende Systeme gegensinnig schraubenlinienförmiger Innenzüge gebildet sind.Furthermore, protrusions are recommended on the inside, which are formed by two intersecting systems of oppositely helical inner trains.
Gegenstand der Erfindung ist weiterhin ein Verfahren zur Herstellung des erfindungsgemäßen Rippenrohres.The invention further relates to a method for producing the finned tube according to the invention.
Ursprünglich wurden die Rippen auf der Rohraußenseite eines Rippenrohres eingängig gewalzt. Zur Erhöhung der Ausbringung einer Walzvorrichtung bietet sich eine Betrachtung der Beziehung für die Walzgeschwindigkeit wwalz an. Die Walzgeschwindigkeit berechnet sich aus:
Der Erhöhung der Drehzahl ω sind dabei technische Grenzen gesetzt. Dsch sind geometrische Grenzen gesetzt; denn der maximale Durchmesser ergibt sich aus der Bedingung, daß sich die Walzscheiben benachbarter Werkzeugwellen im Betrieb nicht berühren dürfen.There are technical limits to increasing the speed ω. D sch are geometrical limits; because the maximum diameter results from the condition that the roller disks of adjacent tool shafts must not touch during operation.
Eine Erhöhung von wwalz läßt sich daher nur über den Schrägstellungswinkel α erreichen. Für tan α gilt der Zusammenhang:
wobei n die Gängigkeit, tR die Rippenteilung und DKern der Kerndurchmesser des Rippenrohres ist. Demnach läßt sich bei vorgegebener Rippengeometrie (Teilung und Kerndurchmesser) die Schrägstellung nur durch Erhöhung der Gängigkeit vergrößern.An increase in w roll can therefore only be achieved via the inclination angle α. The following applies to tan α:
where n is the movement rate, R t is the pitch of the ribs and D core, the core diameter of the finned tube is. Accordingly, for a given rib geometry (pitch and core diameter), the inclination can only be increased by increasing the pitch.
Zunächst wurden auf Walzvorrichtungen mit drei Walzwerkzeugen zweigängige Rippenrohre gewalzt (vgl. US-PS 3.383.893).First, two-start finned tubes were rolled on rolling devices with three rolling tools (see US Pat. No. 3,383,893).
Später wurde auf solchen Vorrichtungen dreigängig gewalzt (vgl. US-PS 3.481.394). In dieser Patentschrift wird auch die Möglichkeit erwähnt, sechsgängig zu walzen bei Verwendung von Vorrichtungen mit sechs Walzwerkzeugen. Kennzeichnend für den Stand der Technik ist, daß entweder alle Walzwerkzeuge in einem gemeinsamen Rippengang laufen (ein- und zweigängiges Walzen) oder im Grenzfall jedes Walzwerkzeug einen eigenen Rippengang formt (drei- bzw. viergängiges Walzen). Damit war eine Grenze erreicht, da davon ausgegangen wurde, daß jedes Walzwerkzeug maximal einen Rippengang erzeugen kann.Later, three-speed rolling was carried out on such devices (cf. US Pat. No. 3,481,394). This patent also mentions the possibility of rolling with six threads when using devices with six rolling tools. It is characteristic of the prior art that either all the rolling tools run in a common rib gear (single and double-start rolling) or, in the limit case, each rolling tool forms its own rib gear (three- or four-gear rolling). A limit was reached because of that it was assumed that each rolling tool can produce a maximum of one rib gear.
Ausgehend von einem Verfahren gemäß dem Oberbegriff des Anspruchs 16 (vgl. DE-AS 2.110.485) ist das erfindungsgemäße Verfahren dadurch gekennzeichnet, daß die gewünschte Gängigkeit n der vorhandenen Anzahl N der Walzwerkzeuge derart angepaßt wird, daß ein oder mehrere der Walzwerkzeuge jeweils mehr als einen Rippengang erzeugen; d. h. es ist stets n > N.Starting from a method according to the preamble of claim 16 (cf. DE-AS 2.110.485), the method according to the invention is characterized in that the desired movement n of the existing number N of rolling tools is adapted in such a way that one or more of the rolling tools each more generate as a ribbed duct; d. H. it is always n> N.
Die Formulierung "und/oder" im Oberbegriff des Anspruchs 16 bezieht sich darauf, ob sich das Rohr bei der axialen Vorschubbewegung gleichzeitig drehen soll oder nicht.The wording "and / or" in the preamble of claim 16 relates to whether the tube should rotate at the same time as the axial feed movement or not.
Das erfindungsgemäße Verfahren beruht darauf, daß zumindest mit einem Walzwerkzeug mehr als ein Rippengang erzeugt wird. Die Gängigkeit beim Walzen von Rippenrohren wird damit beträchtlich über das bisher mögliche Niveau hinaus erhöht. Die vorliegende Erfindung ermöglicht die Vervielfachung der Ausbringung von Walzvorrichtungen. Die maximale Grenze der Gängigkeit liegt bei den erreichbaren Schrägstellungswinkeln der Vorrichtungen, abgesehen von der Selbsthemmung. Nach besonderen Ausführungsformen des erfindungsgemäßen Verfahrens erzeugt jedes Walzwerkzeug jeweils zwei, drei oder vier Rippengänge.The method according to the invention is based on the fact that at least one rolling tool is used to produce more than one rib gear. The ability to roll finned tubes is thus increased considerably beyond what was previously possible. The present invention enables the output of rolling devices to be multiplied. The maximum limit of the movement is the achievable inclination angles of the devices, apart from the self-locking. According to special embodiments of the method according to the invention, each rolling tool produces two, three or four rib courses.
Zur Herstellung eines Rippenrohres mit gestauchten Rippenspitzen empfiehlt sich ein Verfahren nach Anspruch 20, zur Herstellung eines Rippenrohres mit gekerbten Rippenspitzen ein Verfahren nach Anspruch 21 und zur Herstellung eines Rippenrohres mit gespaltenen und/oder umgebogenen und/oder gestauchten Rippenspitzen ein solches nach Anspruch 22.A method according to claim 20 is recommended for producing a finned tube with compressed fin tips, a method according to claim 21 for producing a finned tube with notched finned tips and one according to claim 22 for producing a finned tube with split and / or bent and / or compressed finned tips.
Zur Herstellung eines erfindungsgemäßen Rippenrohres mit Innenrippen wird die Verwendung eines profilierten Walzdorns empfohlen. Zur Herstellung eines erfindungsgemäßen Rippenrohres mit inneren Wellungen wird ein Verfahren nach Anspruch 24 vorgeschlagen (vgl. auch EPS 0.102.407). Um zu vermeiden, daß bei den feinen Rippenteilungen die benachbarten Wellungen auf der Rohrinnenseite zu dicht beieinander liegen, wird empfohlen, daß nicht in allen Walzwerkzeugen eine Wellscheibe zu verwenden ist.The use of a profiled rolling mandrel is recommended for producing a finned tube according to the invention with inner fins. To produce an inventive A method according to claim 24 is proposed for finned tube with inner corrugations (cf. also EPS 0.102.407). In order to prevent the adjacent corrugations on the inside of the tube from being too close together in the case of the fine fin divisions, it is recommended that a corrugated washer is not used in all rolling tools.
Die Erfindung wird an Hand der folgenden Ausführungsbeispiele näher erläutert.The invention is explained in more detail using the following exemplary embodiments.
Fig. 1 zeigt schematisch ein erfindungsgemäßes, integrales Rippenrohr 1, auf dessen Außenseite Rippen 2 schraubenlinienförmig umlaufen, zwischen denen eine Nut 3 gebildet ist. Die Rippen 2 weisen eine Höhe hR auf; die Rippenteilung (Abstand von Rippenmitte zu Rippenmitte) ist mit tR bezeichnet.1 schematically shows an integral
Die Herstellung des erfindungsgemäßen Rippenrohres 1 erfolgt durch einen Walzvorgang (vgl. US-PSen 1.865.575/3.327.512) mittels der in Fig. 1 und 2b dargestellten Vorrichtung.The
Es wird eine Vorrichtung verwendet, die aus N = 4 Werkzeughaltern 4 (4₁/4₂/4₃/4₄) besteht, in die jeweils ein Walzwerkzeug 5 integriert ist (in Fig. 1 ist nur ein Werkzeughalter 4 dargestellt. Es können aber beispielsweise drei oder mehr als vier Werkzeughalter 4 verwendet werden). Die Werkzeughalter 4 sind jeweils um β = 360°/N versetzt am Umfang des Rippenrohres 1 angeordnet. Die Werkzeughalter 4 sind radial zustellbar. Sie sind ihrerseits in einem ortsfesten (nicht dargestellten) Walzkopf angeordnet (nach einer anderen Variante wird das Rohr bei sich drehendem Walzkopf lediglich axial vorgeschoben).A device is used which consists of N = 4 tool holders 4 (4₁ / 4₂ / 4₃ / 4₄), in each of which a
Das in Pfeilrichtung in die Vorrichtung einlaufende Glattrohr 1' wird durch die am Umfang angeordneten, angetriebenen Walzwerkzeuge 5 in Drehung versetzt, wobei die Wellen 6 der Walzwerkzeuge 5 schräg zur Rohrachse verlaufen. Der Schrägstellungswinkel α der Wellen 6 wird entsprechend der gewünschten Gängigkeit n gemäß Gl. (2) eingestellt. Die Walzwerkzeuge 5 bestehen in an sich bekannter Weise aus mehreren nebeneinander auf den Wellen 6 angeordneten Walzscheiben 7, deren Durchmesser in Pfeilrichtung ansteigt. Die zentrisch angeordneten Walzwerkzeuge 5 formen die schraubenlinienförmig umlaufenden Rippen 2 aus der Rohrwandung des Glattrohres 1', wobei das Glattrohr 1' hier durch einen profilierten Walzdorn 8 unterstützt wird. Hierdurch entstehen gleichzeitig die mit Ziffer 9 bezeichneten, schraubenlinienförmig umlaufenden Rippen auf der Innenseite des Rohres 1.The smooth pipe 1 'entering the device in the direction of the arrow is set in rotation by the driven
Das Walzverfahren ist am Rohranfang bzw. an den Übergangsstücken zwischen berippten und unberippten Rohrabschnitten eindeutig zu erkennen, da der Walzscheibeneingriff beim Eintauchen in die Rohrwandung in Gruppen erfolgt. Fig. 3 zeigt schematisch den Unterschied zwischen erfindungsgemäßer und konventioneller Walzweise am Beispiel des sechsgängigen Walzens. Gemäß Fig. 3a sind drei Gruppen von jeweils zwei nebeneinanderliegenden Anfängen A₁, A₂ bzw. A₃, A₄ bzw. A₅, A₆ (letztere nicht dargestellt) von Rippengängen gleichmäßig über den Rohrumfang verteilt, wärhend gemäß Fig. 3b sechs einzelne Anfänge A₁, A₂, A₃, A₄, A₅, A₆ (A₄ - A₆ nicht dargestellt) am Rohrumfang angeordnet sind. (Im übrigen werden in Fig. 3a, 3b die bisherigen Bezugsziffern, z. T. mit Indizes versehen, verwendet.)The rolling process can be clearly identified at the start of the pipe or at the transition pieces between finned and non-finned pipe sections, since the rolling disc is engaged in groups when immersed in the pipe wall. Fig. 3 shows schematically the difference between the inventive and conventional rolling method using the example of six-speed rolling. According to Fig. 3a, three groups of two adjacent beginnings A₁, A₂ or A₃, A₄ or A₅, A₆ (the latter not shown) of fins are distributed evenly over the circumference of the tube, while according to Fig. 3b six individual beginnings A₁, A₂, A₃, A₄, A₅, A₆ (A₄ - A₆ not shown) are arranged on the pipe circumference. (For the rest, the previous reference numbers, some of which are provided with indices, are used in FIGS. 3a, 3b.)
Nach dem beschriebenen Verfahren wurden Rippenrohre 1 mit einer Rippenteilung tR ≈ 0,53 mm auf einer Vorrichtung mit vier Walzwerkzeugen 5 achtgängig hergestellt. Der Rippendurchmesser beträgt bei diesem Rohrtyp D = 19 mm, die Rippenhöhe hR = 0,95 mm. Auf der Innenseite des Rippenrohres wurde im gleichen Arbeitsgang eine schraubenlinienförmige Innenrippenstruktur erzeugt mit ca 40 Innenrippen 9, die unter einem Steigungswinkel ϑ = 45° zur Rohrachse verlaufen.According to the described method,
Eine andere Realisierung beruht auf dem achtgängigen Walzen eines Rippenrohres 1 mit einer Teilung tR ≈ 0,64 mm mit einer ähnlichen Innenstruktur wie vorstehend beschrieben.Another implementation is based on the eight-thread rolling of a
Fig. 4 zeigt ergänzend zu Fig. 1 eine Walzvorrichtung, bei der zum Stauchen zu T-förmigen Rippenspitzen 2' jeweils zusätzlich eine Stauchscheibe 10 in den Werkzeughalter 4 integriert ist.FIG. 4 shows, in addition to FIG. 1, a rolling device in which a
Zur Erläuterung der Innenstruktur des Rohres 1 zeigt Fig. 5 einen Teilschnitt senkrecht zur Rohrachse, in den die Größen Rippendurchmesser D, Innendurchmesser Di, Rippenhöhe hi, mittlerer Flankenabstand W und der Scheitelwinkel γ der Innenrippen 9 eingetragen sind.To explain the internal structure of the
Claims (25)
dadurch gekennzeichnet,
daß bei einer Gängigkeit n ≧ 4 mindestens eine Gruppe gebildet ist, die mindestens zwei nebeneinanderliegende Anfänge (A₁, A₂ bzw. A₃, A₄ ...) von Rippengängen aufweist.Metallic finned tube (1), in particular for heat exchangers or the like, with on the outside helical circumferential, multi-start integral fins (2), which are described, among other things, by the sizes n, finned pitch t R and fin height h R , the n fins on Start the pipe - evenly distributed over the pipe circumference -
characterized,
that at a rate n ≧ 4 at least one group is formed which has at least two adjacent starts (A₁, A₂ or A₃, A₄ ...) of rib courses.
daß jeweils Gruppen von 2 Anfängen von Rippengängen gebildet sind.Finned tube according to claim 1, characterized in
that groups of 2 beginnings of rib courses are formed.
daß jeweils Gruppen von 3 Anfängen von Rippengängen gebildet sind.Finned tube according to claim 1, characterized in
that groups of 3 beginnings of rib corridors are formed.
daß jeweils Gruppen von 4 Anfängen von Rippengängen gebildet sind.Finned tube according to claim 1, characterized in
that groups of 4 beginnings of rib courses are formed.
daß die Rippenspitzen (2') unter Ausbildung verdickter Enden gestaucht sind.Finned tube according to one or more of claims 1-4, characterized in
that the rib tips (2 ') are compressed to form thickened ends.
daß die Rippenspitzen (2') eingekerbt sind.Finned tube according to one or more of claims 1-4, characterized in
that the rib tips (2 ') are notched.
daß die Rippenspitzen (2') unter Ausbildung von Hohlräumen gespalten und/oder seitlich umgebogen und/oder gestaucht sind.Finned tube according to claim 6, characterized in
that the rib tips (2 ') are split to form cavities and / or laterally bent and / or compressed.
daß die Rippenteilung tR = 0,25 - 1,50 mm und die Rippenhöhe hR ≦ 1,60 mm beträgt.Finned tube according to one or more of claims 1-7, characterized in that
that the rib pitch t R = 0.25 - 1.50 mm and the rib height h R ≦ 1.60 mm.
daß es schraubenlinienförmig verlaufende Innenrippen (9) aufweist.Finned tube according to one or more of claims 1-8, characterized in
that it has helical inner ribs (9).
daß die Teilung der Innenrippen (9) - senkrecht zu den Innenrippen (9) gemessen - ti = 0,5 - 3 mm, die Höhe der Innenrippen (9) hi = 0,2 - 0,5 mm und der Steigungswinkel der Innenrippen (9) ϑ = 25 - 70° beträgt.Finned tube according to claim 9, characterized in
that the division of the inner ribs (9) - measured perpendicular to the inner ribs (9) - t i = 0.5 - 3 mm, the height of the inner ribs (9) h i = 0.2 - 0.5 mm and the pitch angle of the Inner ribs (9) ϑ = 25 - 70 °.
daß der Steigungswinkel der Innenrippen (9) ϑ = 5 - 25°, das Verhältnis der Höhe der Innenrippen (9) zum Innendurchmesser des Rohres hi/Di = 0,02 - 0,03, der mittlere Flankenabstand der Innenrippen (9) W = 0,15 - 0,40 mm und der Scheitelwinkel der Innenrippen γ = 30 - 60° beträgt.Finned tube according to claim 9, characterized in
that the pitch angle of the inner fins (9) ϑ = 5 - 25 °, the ratio of the height of the inner fins (9) to the inner diameter of the tube h i / D i = 0.02 - 0.03, the mean flank spacing of the inner fins (9) W = 0.15 - 0.40 mm and the apex angle of the inner ribs γ = 30 - 60 °.
daß die Innenseite Wellungen aufweist.Finned tube according to one or more of claims 1-8, characterized in
that the inside has corrugations.
daß die Wellungen unterbrochen sind.Finned tube according to claim 12, characterized in
that the corrugations are interrupted.
daß der axiale Abstand der Wellungen dem Produkt aus Rippenteilung tR und Gängigkeit n entspricht.Finned tube according to claim 12 or 13, characterized in that
that the axial spacing of the corrugations corresponds to the product of rib pitch t R and pitch n.
daß es auf der Innenseite Vorsprünge aufweist, die durch zwei einander kreuzende Systeme gegensinnig schraubenlinienförmiger Innenzüge gebildet sind.Finned tube according to one or more of claims 1-8, characterized in
that it has projections on the inside, which are formed by two intersecting systems of oppositely helical inner trains.
gekennzeichnet durch folgenden Verfahrensschritt:
characterized by the following process step:
daß jedes Walzwerkzeug (5) jeweils zwei Rippengänge erzeugt.A method according to claim 16 for producing a finned tube according to claim 2, characterized in that
that each rolling tool (5) produces two rib courses.
daß jedes Walzwerkzeug (5) jeweils drei Rippengänge erzeugt.A method according to claim 16 for producing a finned tube according to claim 3, characterized in that
that each rolling tool (5) produces three rib courses.
Rippenrohres nach Anspruch 4, dadurch gekennzeichnet, daß jedes Walzwerkzeug (5) jeweils vier Rippengänge erzeugt.A method according to claim 16 for producing a
Finned tube according to claim 4, characterized in that each rolling tool (5) produces four fins.
dadurch gekennzeichnet,
daß die Rippenspitzen (2') in mindestens einem Schritt durch radiale Kräfte verformt werden.Method according to one or more of claims 16-19 for producing a finned tube according to claim 5,
characterized,
that the rib tips (2 ') are deformed in at least one step by radial forces.
dadurch gekennzeichnet,
daß Kerben durch mindestens eine Kerbscheibe (10) in die Rippenspitzen (2') eingedrückt werden.Method according to one or more of claims 16-19 for producing a finned tube according to claim 6,
characterized,
that notches are pressed into the rib tips (2 ') by at least one notch disk (10).
daß die Rippenspitzen (2') in Richtung der Rippen (2) gespalten und/oder durch axiale Kräfte umgebogen und/oder durch radiale Kräfte verformt werden.A method according to claim 21 for producing a finned tube according to claim 7, characterized in that
that the rib tips (2 ') split in the direction of the ribs (2) and / or bent by axial forces and / or deformed by radial forces.
daß das Glattrohr (1') durch einen profilierten Walzdorn (8) abgestützt wird.Method according to one or more of claims 16-22 for producing a finned tube according to one or more of claims 9-11, characterized in that
that the smooth tube (1 ') is supported by a profiled rolling mandrel (8).
daß nach dem Herausformen der Rippen (2) die Nut (3) zwischen den Rippen (2) durchgehend bzw. nur stellenweise durch radiale Kräfte nach innen gedrückt wird, wobei in diesem Bereich keine Abstützung durch einen Innendorn erfolgt, so daß Rohrwandungsmaterial zur Bildung von Wellungen auf die Rohrinnenseite verlagert wird.Method according to one or more of claims 16-22 for producing a finned tube according to claim 12 or 13, characterized in that
that after the formation of the ribs (2), the groove (3) between the ribs (2) is pressed continuously or only in places by radial forces, with no support being provided by an internal mandrel in this area, so that tube wall material to form Corrugations are shifted to the inside of the pipe.
daß nicht allen verwendeten Walzwerkzeugen (5) eine Wellscheibe zugeordnet wird.A method according to claim 24 for producing a finned tube according to claim 15, characterized in that
that not all the rolling tools (5) used are assigned a corrugated washer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4420756A DE4420756C1 (en) | 1994-06-15 | 1994-06-15 | Ribbed heat exchanger tube |
DE4420756 | 1994-06-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0687880A1 true EP0687880A1 (en) | 1995-12-20 |
EP0687880B1 EP0687880B1 (en) | 1998-08-26 |
Family
ID=32932655
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95108495A Expired - Lifetime EP0687880B1 (en) | 1994-06-15 | 1995-06-02 | Tube with a plurality of spiral ribs and method of manufacturing the same |
Country Status (9)
Country | Link |
---|---|
US (2) | US5803164A (en) |
EP (1) | EP0687880B1 (en) |
JP (1) | JP3945785B2 (en) |
KR (1) | KR100365667B1 (en) |
CN (1) | CN1092787C (en) |
CA (1) | CA2150588C (en) |
DE (2) | DE4420756C1 (en) |
MY (1) | MY114272A (en) |
ZA (1) | ZA954310B (en) |
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US4765058A (en) * | 1987-08-05 | 1988-08-23 | Carrier Corporation | Apparatus for manufacturing enhanced heat transfer surface |
-
1994
- 1994-06-15 DE DE4420756A patent/DE4420756C1/en not_active Expired - Fee Related
-
1995
- 1995-05-26 ZA ZA954310A patent/ZA954310B/en unknown
- 1995-05-31 CA CA002150588A patent/CA2150588C/en not_active Expired - Lifetime
- 1995-06-02 EP EP95108495A patent/EP0687880B1/en not_active Expired - Lifetime
- 1995-06-02 DE DE59503311T patent/DE59503311D1/en not_active Expired - Lifetime
- 1995-06-05 JP JP16145395A patent/JP3945785B2/en not_active Expired - Fee Related
- 1995-06-06 US US08/465,758 patent/US5803164A/en not_active Expired - Lifetime
- 1995-06-13 KR KR1019950016124A patent/KR100365667B1/en not_active IP Right Cessation
- 1995-06-13 MY MYPI95001569A patent/MY114272A/en unknown
- 1995-06-15 CN CN95107059A patent/CN1092787C/en not_active Expired - Lifetime
-
1996
- 1996-05-31 US US08/655,981 patent/US5761807A/en not_active Expired - Lifetime
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US1865575A (en) | 1928-11-30 | 1932-07-05 | Wolverine Tube Company | Apparatus for manufacturing integral finned tubing |
US2070539A (en) * | 1935-12-19 | 1937-02-09 | Schutte & Koerting Company | Fin tube |
GB601753A (en) * | 1945-01-17 | 1948-05-12 | Calumet And Hecla Cons Copper | Multiple helical finned tubing and method of manufacturing the same |
US3327512A (en) | 1964-12-28 | 1967-06-27 | Calumet & Hecla | Fine pitch finned tubing and method of producing the same |
US3383893A (en) | 1965-08-16 | 1968-05-21 | Calumet & Hecla | Apparatus for producing integral finned tubing of fine pitch |
US3481394A (en) | 1967-06-26 | 1969-12-02 | Calumet & Hecla Corp | Configuration of heat transfer tubing for vapor condensation on its outer surface |
DE2110485A1 (en) | 1970-03-04 | 1971-09-16 | Trane Co | Device for creating a pipe with helical ribs on the outside |
EP0102407A1 (en) | 1982-09-03 | 1984-03-14 | Wieland-Werke Ag | Finned tube with internal projections and method and apparatus for its manufacture |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112025138A (en) * | 2020-08-10 | 2020-12-04 | 燕山大学 | Online adjusting method and device for opening angle of welding seam of pipeline steel pipe |
CN112025138B (en) * | 2020-08-10 | 2021-04-16 | 燕山大学 | Online adjusting method and device for opening angle of welding seam of pipeline steel pipe |
Also Published As
Publication number | Publication date |
---|---|
CA2150588A1 (en) | 1995-12-16 |
US5761807A (en) | 1998-06-09 |
JP3945785B2 (en) | 2007-07-18 |
US5803164A (en) | 1998-09-08 |
JPH0857535A (en) | 1996-03-05 |
CN1121581A (en) | 1996-05-01 |
KR960001709A (en) | 1996-01-25 |
DE4420756C1 (en) | 1995-11-30 |
KR100365667B1 (en) | 2003-03-04 |
MY114272A (en) | 2002-09-30 |
DE59503311D1 (en) | 1998-10-01 |
EP0687880B1 (en) | 1998-08-26 |
CN1092787C (en) | 2002-10-16 |
ZA954310B (en) | 1996-03-05 |
CA2150588C (en) | 2006-12-19 |
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