EP0433547B1 - Appareil pour gazéifier des combustibles solides - Google Patents
Appareil pour gazéifier des combustibles solides Download PDFInfo
- Publication number
- EP0433547B1 EP0433547B1 EP90115070A EP90115070A EP0433547B1 EP 0433547 B1 EP0433547 B1 EP 0433547B1 EP 90115070 A EP90115070 A EP 90115070A EP 90115070 A EP90115070 A EP 90115070A EP 0433547 B1 EP0433547 B1 EP 0433547B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hereinbefore
- gas producer
- furnace
- combustion
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004449 solid propellant Substances 0.000 title claims abstract description 11
- 238000002309 gasification Methods 0.000 claims abstract description 28
- 239000002699 waste material Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 12
- 238000003763 carbonization Methods 0.000 claims abstract description 10
- 239000003245 coal Substances 0.000 claims abstract description 5
- 238000004939 coking Methods 0.000 claims abstract description 4
- 239000003077 lignite Substances 0.000 claims abstract description 3
- 239000003415 peat Substances 0.000 claims abstract description 3
- 239000002916 wood waste Substances 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 85
- 239000002737 fuel gas Substances 0.000 claims description 27
- 238000001816 cooling Methods 0.000 claims description 7
- 239000002956 ash Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000567 combustion gas Substances 0.000 claims 1
- 239000000289 melt material Substances 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 description 15
- 239000000446 fuel Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000543 intermediate Substances 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 239000003517 fume Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 150000002013 dioxins Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 1
- WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 235000006173 Larrea tridentata Nutrition 0.000 description 1
- 244000073231 Larrea tridentata Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229960002126 creosote Drugs 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000003924 mental process Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/22—Arrangements or dispositions of valves or flues
- C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
- C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/08—Continuous processes with ash-removal in liquid state
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/80—Other features with arrangements for preheating the blast or the water vapour
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Definitions
- This invention concerns an apparatus to gasify solid fuels as set forth in the main claim.
- the invention concerns a gasification apparatus suitable to produce fuel gas by the simultaneous application of a direct flame and of a downward flame to the material to be gasified.
- the apparatus of the invention employs operational methods which do not pollute the outside environment and are more remunerative from the production point of view.
- the apparatus is used in particular for the gasification of solid urban wastes and generally for the gasification of low-cost solid products such as wood waste, wood chips, biomasses in general, tyres, peat, lignite, coal and other materials.
- the state of the art covers a plurality of apparatuses to produce gas from solid fuels; these apparatuses have various types of conformations and working principles.
- the process to produce the gas since the process to produce the gas generates products which are hard to dispose of or detrimental owing to their toxicity; the first of these categories includes the various types of tars, while the second may comprise dioxin; other types of products may have undesirable characteristics; for instance, they may be evil-smelling, such as creosote or the like.
- US-A-4,175,929 discloses a coal gasification process whereby all the pollutants contained in the producer gas are substantially eliminated. To this end the producer gas is passed through stages of water scrubbing and condensation which purify it. Devices are provided for the recovery of energy and for the recirculation of fluids which can be reused in the operation of the the gas producer.
- DE-A-3.523.765 concerns a process and a device to gasify carbonaceous material, whereby the gas distilled at a low temperature is sent to an oxidation zone free of solid materials where it is almost completely burnt.
- FR-A-7.830.787 concerns a process and a device to produce gas from wood, which use the combined principle of production of gas by a gas producer and production of water gas by means of air from steam and tar vapour.
- WO-A-8.002.563 discloses a process for the complete gasification of carbonaceous materials by thorough pyrolysis
- WO-A-8.100.112 discloses a process and plant for the gasification of solid fuels, whereby the gasification is obtained in three separate stages.
- DE-A-3.327.203 concerns a process and apparatus for the gasification of solid wastes, whereby the gas leaving a distillation zone as a gas distilled with steam is returned to the melting zone to be burnt at least partly.
- DE-A-2.747.571 discloses a method for the continuous production of a reduction gas containing carbon monoxide and hydrogen, into which in the upper zone of a reactor there is introduced a solid fuel which contains carbon and is heated in that upper zone and brought to an intermediate zone of the reactor.
- a combustion-supporting gas is fed selectively into the intermediate zone at points distant from each other so as to gasify the fuel and to maintain a gasification temperature sufficient to free volatile hydrocarbons through cracking of the fuel and to oxidize partly the carbon in the fuel.
- steam is fed selectively into the intermediate zone at points distant from each other so as to keep the gasification temperature below the melting point of the solid fuel containing carbon and to allow the steam to react with the carbon of the fuel so as to form carbon monoxide and hydrogen.
- the partly oxidized fuel, from which the volatile components are expelled is brought to a lower zone of the reactor.
- a combustion-supporting gas and steam are fed into the lower zone so as to generate carbon monoxide and hydrogen by reaction with the carbon contained in the fuel, while the ash is removed from the lower zone.
- the reduction gas produced in the intermediate and lower zones is discharged to the exterior.
- This method can be used only by starting with a good quality solid fuel containing carbon and cannot be employed by using low cost products or wastes.
- US 4,530,720 provides for the gasification of biomasses and can be applied also to solid fuel products of a low cost. It teaches a crude, elementary technology, and its teaching cannot be combined with others except with a complex and articulated mental process that leads to a new view of the concept of gasification of low grade products.
- the present applicant has designed, tested and embodied a gasification apparatus able to overcome the problems of the state of the art.
- the gasification apparatus according to the invention is a gas producer in which two types of flame, a direct flame and a downward flame, are employed in the furnace. There may be a plurality of flames of each type.
- the zone of aspiration of the fuel gases produced or of emission of combustion supporting air is located advantageously in an intermediate portion of the furnace between the positions of the two types of flame.
- a device to melt the non-fuel parts of the wastes such as glass, metallic slags, etc. may be provided at the bottom of the gas producer, especially in the case of gasification of solid urban waste.
- a normal zone for collection and discharge of the ashes produced in the gasification may also be provided.
- the fuel gases produced by gasification of the material inside the gas producer include gas from pyrolysis and products of distillation, which can be condensed and returned to the combustion zone of the furnace of the gas producer, where they are burned.
- combustion zone may also be sent the volatile polluting products still present in the fuel gases leaving the gas producer or in the gases leaving an apparatus connected to the gas producer, such as a vapour condenser, for instance.
- the gasification apparatus of the invention may be connected advantageously to energy production plants, heating plants, motor transport stations and many other users.
- a gas producer 10 consists substantially of a pre-charging and drying silo 11, a carbonisation and gasification silo 12 and a furnace 13.
- the pre-charging silo 11 contains a stock of fuel material and is equipped advantageously with equipment to dry the excess water in the stock.
- the drying can be carried out by using heat recovered from the gas producer 10 or, as in this case, by using discharged gases arriving, for instance, along a duct 14 from a motor 15 that drives a generator 16.
- the discharged gases are brought into the pre-charging silo 11 through grills 21 and leave through a conduit 22 in the top of the silo after being cooled and impregnated with moisture removed from the fuel material.
- the excess fraction of the discharged gases leaves through an outlet 23 and may undergo thereafter a possible condensation to recover water which can be used for the gas producer 10 and for recovery of energy.
- the reusable fraction of these gases is aspirated by the fan 19 through the valve 17 so as to be mixed with hot discharge gases arriving through the duct 14, and in this way a condition of temperature at the thermostat 18 is restored which is suitable for the drying treatment in the pre-charging silo 11.
- the solid fuels pass from the carbonisation or coking and gasification silo 12 into the furnace 13 so as to undergo combustion.
- air for the downward burning flame 28 namely the downward flame fed with combustion-supporting air, is brought into the furnace 13 by means of a duct 27 and manifold 29.
- This combustion-supporting air reaches the gas producer 10 through a delivery conduit 30, at the inlet of which the air is suitably moistened, for instance, by a water sprayer 31.
- a valve 48 to regulate the flow of air for the direct flame 26 and the downward flame 28 is positioned at the end of the delivery conduit 30.
- the fuel gases leaving the furnace 13 in the direction of the arrow 32 pass into a transfer chamber 33, which has also decantation functions for solid particles in the flow of the gases.
- This transfer chamber 33 is limited at its lower end by a grating 34 that has the functions of containing uniformly the carbonised material in the furnace 13 and of providing a uniform flow of the gases leaving the furnace 13.
- the recovery of the fuel gases in the direction 32 takes place substantially in an intermediate position in the furnace 13 between the direct flame 26 and downward flame 28.
- the departing fuel gases contact a wall 35 of the gasification silo 12, thus providing a supply of heat towards the inside of the silo 12, this heat being useful for the purposes of pyrolysis, distillation and carbonisation or coking of the fuel products contained therein.
- the fuel gases leaving the transfer chamber 33 pass advantageously into a heat exchanger 36, in which they yield heat to the combustion-supporting air entering the gas producer 10; this air therefore is pre-heated when it reaches the furnace 13.
- the condensation products collected by the heat exchanger 36 are sent by a pump 37 to the inlet 38 of the manifold 29, where they are re-evaporated by the pre-heated combustion-supporting air coming from the duct 27.
- Fig.1 references generically with 39 an opening for ignition and control of the flame and with 40 a hole for the actual ignition.
- the fuel gases pass from the heat exchanger 36 advantageously to a cooling battery 41, consisting, for instance, of a set of cyclones outwardly cooled by an interpsace containing a recirculation of water, where a further separation takes place by a possibly fractional condensation of different substances.
- the condensation products are also collected by a pump 42 and sent through the inlet 38 into the manifold 29.
- condensation products can be collected in several separate stages; as an example, a first stage may collect the denser tars and dioxins, while a second stage collects the acetic acid, water and intermediate products and a third stage gathers the benzol, methanol and the like.
- a final cooling 44 with water so as to get the gas temperature conditions required by the successive gas usage means. If this usage means is an internal combustion engine 15, the fuel gases pass on to a mixer 45, which mixes the gases suitably with incoming air 46 before sending them to the engine 15.
- the gases discharged by the engine or motor 15 are sent advantageously through the duct 14 to the pre-charging and drying silo 11.
- Discharge means 49 a worm for instance, are included at the bottom of the gas producer 10 to remove the ashes produced in the furnace 13 and may advantageously provide a free entry of air.
- Fig.2 shows another embodiment of the invention, in which the gas producer 110 provides again combustion with a downward flame or flames 28 and a direct flame or flames 26.
- This gas producer 110 is especially suitable for fuels of a solid urban waste type and includes at its base a cupola-furnace type device to provide final melting of the materials which cannot be gasified, such as slags of various metals, glass, etc.
- the cupola furnace consists of a crucible 50 with a casting channel 51 that cooperates advantageously with a plurality of ingot moulds 52 arranged in series to collect the various molten materials separately according to their relative densities.
- the gas producer 110 includes, in the zone of charging the material to be gasified and carbonised, a plurality of suitably inclined and staggered sectors 53 so as to obtain a re-mixing of the material during its descent within the gas producer 110.
- a partial support for that material is obtained at the same time so as not to burden too greatly the combustion zones of the furnace 13.
- a central duct 54 to deliver air to the downward flame or flames 28 comprises at its inlet a regulating valve 55 to control the gasification conditions.
- This central duct 54 may be lined advantageously within with Perkins-type steam tubes so as to remove excessive heat in its lower end portion and to transfer that heat to the incoming air and towards the less hot upper zones.
- Supplementary inlets 61 and 62 for combustion-supporting air are included respectively in the zone of the downward flame 28 and in the zone of the direct flame 26 to provide for the severest operational conditions in the production of fuel gases.
- a supplementary silo 81 controlled by a valve 82 is included and can store stocks of materials, such as coal or wooden scrap, to be introduced into the furnace 13 when extra calories are required to integrate the calories produced from the wastes so as to obtain final melting.
- the required flow of combustion-supporting air through an inlet 60 to the crucible 50 is regulated by a regulation valve 59.
- the air inlet 60 may equally well have independent means to aspirate and control the combustion-supporting air.
- a path 63 is used by steam leaving a boiler 58 and passing towards a battery of steam turbines 64 connected to a battery of alternators 65.
- the fumes leaving the boiler 58 according to the arrow 66 pass advantageously over a means 67 to preheat air being sent to the crucible 50 and can then be sent to a first drier 68 that dries solid urban wastes.
- the solid urban wastes are delivered according to the arrow 69 to the first drier 68, which is advantageously a rotary cylinder and in which the wastes receive heat from the fumes of the boiler 58; at the same time the dioxins and tars still present in those fumes are condensed on the wastes.
- the wastes may be sent according to the arrow 70 to a second drier 71, in which they are further dried with a reduction of excess moisture and are advantageously re-mixed and heated by contact on chutes 83 made hot by suitable interspaces by means of the steam discharged according to the arrow 72 from the turbines 64.
- the solid urban wastes go from the second drier 71 according to the arrow 73 to feed the gas producer 110, care being taken to prevent more air entering with the wastes than the amount useful for facilitating the distribution and subsequent carbonisation of the wastes.
- the fumes leaving the first drier 68 according to the arrow 74 are aspirated by an aspirator means 75, a centrifugal fan for instance, in quantities corresponding to the actual requrement of the boiler 58.
- This fan 75 arranges to keep the whole plant under negative pressure and at the same time aspirates into the gas producer 110 the quantity of combustion-supporting air needed for the production of the required fuel gases.
- Cooled fumes leaving the fan 75 according to the arrow 76 are discharged into a stack 77, into which is also discharged according to the arrow 78 the hot, moist exchange air from an outer recycling circuit 79 of the second drier 71.
- the reference 80 indicates a condenser of the discharged steam from the turbines 64 which has not been used in the second drier 71.
- Fig.3 shows a variant of the invention in which the gas producer 210, while having many parts in common with the gas producer 10 of Fig.1, is different therefrom in that it has a zone 92 of immission of combustion-supporting air at a position in the furnace 13 between the position of the direct flame 26 and that of the downward flame 28.
- the recovery of the fuel gases is located at two different positions in the gas producer 210, one position 132 in the lower part of the furnace 13 and the other 232 in the upper part of the carbonisation silo 12.
- the direct flame 26 enhances the carbonisation action and the gaseous production of distillates and achieves also some cracking effect; this is an outcome of the fact that the heat of the fuel gas is used at the end of the direct flame 26 when the reducing action too is finishing and the distillates therefore cannot burn.
- the fuel gases are aspirated from the gasification silo 12 by means of a duct 88 with a regulation valve 85 actuated by a thermostat 84 and are sent by means of a valve 86 to the usage means 15 or to another pre-selected usage means.
- the gases containing distillates may be made to recirculate in the gas producer 210 by the aspirator 87 so that, their quantity being regulated suitably so as to obtain an adequate resulting cracking action, they are mixed with the combustion-supporting air and burn in a pre-combustion chamber 89 with a definitely oxidising combustion.
- a Venturi tube may also be comprised instead of the aspirator 87 and will use combustion-supporting air entering from the conduit 92 and pre-heated in the heat exchanger 36, which employs hot gases in the discharge pipe 93.
- This type of recirculation, with direct flame, of gases rich of distillates can be brought about advantageously in the gas producer 110 too of Fig.2 by placing recovery intakes below the inclined sectors 53.
- the action of distillation and carbonisation in the high zone of the gas producer 110 is enhanced in this way, particularly so if air is not allowed to enter together with the combustible scrap and waste from the inlets of the gas producer.
- the aspirated gases can be put back into circulation either by modulating the cracking at the air inlets 61 and also 62 or, in particular, if this is actuated instead of the addition of fuel material held in the supplementary silo 81.
- the combustion-supporting air can be moistened by the sprayer 31 actuated by the thermostat 47 positioned in the discharge pipe 93.
- the mixture of fuel gases in the pre-combustion chamber 89 is aspirated into the furnace 13, thus determining the direct flame 26 and the downward flame 28.
- This mixture undergoes firstly a combustion and cracking action and thereafter a reducing action owing to the sudden scantiness or lack of oxygen.
- the fuel gases intended for a usage means can be recovered from below the grill of the ashes and will exit only in the direction 132 with the methods cited earlier.
- the reference 90 is borne by a vibratory grill employed to drop the ashes onto the discharge means 49, which is provided with a seal engagement to prevent the entry of air from the exterior,the seal in this case being a level of water 91.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing Of Solid Wastes (AREA)
- Gasification And Melting Of Waste (AREA)
- Telephone Function (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Catalysts (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Control Of The Air-Fuel Ratio Of Carburetors (AREA)
Claims (22)
- Appareil pour gazéifier des combustibles solides qui gazéifie des produits de bas de gamme tels que des déchets de bois et des copeaux, des biomasses solides en général, des pneus, de la tourbe, de la lignite, du charbon et d'autres matières ainsi que des déchets urbains solides et qui comprend un gazogène (10-110-210) comprenant, dans l'ordre et de haut en bas, un silo de préchargement (11), un silo de carbonisation ou de cokéfaction et de gazéification (12) et un four (13) et est caractérisé en ce qu'une flamme directe 26 et une flamme dirigée vers le bas (28) sont prévues dans le four (13) du gazogène (10-110-210) et sont associées à une seule source et à une seule entrée d'air (89), et en ce que sont prévues une première zone d'aspiration (32-132-56) des gaz combustibles qui est associée à la flamme dirigée vers le bas (28) et une seconde zone d'aspiration (232) des gaz combustibles qui est associée à la flamme directe (26) et en ce que la première zone d'aspiration (32-132-56) coopère avec une chambre de transfert (33), le silo de préchargement (11) étant associé à un espace intermédiaire (20) pour la circulation de gaz de séchage.
- Appareil suivant la revendication 1, dans lequel le gazogène (10-110-210) comprend, à sa base, des moyens (50) pour faire fondre des matières qui ne peuvent pas être gazéifiées.
- Appareil suivant la revendication 1 ou 2, dans lequel des moyens statiques (53) pour remélanger la matière descendante sont inclus dans le gazogène (10-110-210).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel les moyens de remélange (53) sont installés, inclinés et décalés en quinconce les uns par rapport aux autres, dans le gazogène (10-110-210).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens (31) pour humidifier l'air comburant pénétrant dans le gazogène (10-110-210).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel des moyens échangeurs de chaleur (36) destinés à transmettre de la chaleur des gaz combustibles sortant du gazogène (10-110-210) à l'air comburant entrant dans le gazogène (10-110-210) sont prévus au moins à la sortie de la chambre de transfert (33).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel la chambre de transfert (33), que les gaz combustibles s'échappant (32) du four (13) traversent, comprend au moins une paroi d'échange de chaleur (35) commune au silo de gazéification (12).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel des grilles (34) sont installées sur la sortie (32-132-56) des gaz combustibles du four (13).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens (37) pour recueillir et envoyer vers la zone du four (13) les produits condensés dans l'échangeur de chaleur (36).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel des moyens (38-27) destinés à envoyer des produits condensés vers de l'air comburant préchauffé et à les mélanger avec celui-ci sont prévus.
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens (41-44) pour refroidir les gaz combustibles s'échappant-du gazogène (10-210).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens (42) pour recueillir et envoyer dans la zone du four (13) les produits condensés par les moyens de refroidissement (41-44).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel des moyens de fusion (50) du gazogène (110) sont raccordés à des lingotières (52).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend également des moyens (54) pour fournir de l'air comburant qui sont garnis de tubes de vapeur.
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens supplémentaires (61-62) pour l'introduction de l'air comburant.
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens de stockage supplémentaires (81-82).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend un ventilateur (57) relié aux moyens de fusion (50) et à un dispositif (67) qui utilise la chaleur des gaz de combustion sortant d'une chaudière (58).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel le gazogène 110 est raccordé à des moyens extérieurs (68-71) qui sèchent les déchets urbains solides.
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel les sécheurs (68-71) utilisent des fluides s'échappant (66-72) des dispositifs (58-64) qui utilisent les gaz combustibles sortant du gazogène (110).
- Appareil suivant l'une quelconque des revendications précédentes, dans lequel les sécheurs (71) sont équipés de goulottes (83) pour remélanger et chauffer les déchets par contact, les goulottes (83) étant chauffées par des espaces intermédiaires alimentés de vapeur d'eau s'échappant dans le sens de la flèche (72) de turbines (64).
- Appareil suivant l'une quelconque des revendications précédentes, caractérisé en ce que les moyens (49) qui évacuent les cendres comprennent une garde étanche (91) pour empêcher toute entrée d'air de l'extérieur dans le gazogène (210).
- Appareil suivant l'une quelconque des revendications précédentes, qui comprend des moyens de recyclage (86) installés dans la partie supérieure du gazogène (10-110-210), et destinés à envoyer vers le four (13) les gaz contenant des distillats.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90115070T ATE92093T1 (de) | 1989-11-29 | 1990-08-06 | Vorrichtung zum vergasen fester brennstoffe. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT8351989 | 1989-11-29 | ||
IT08351989A IT1236318B (it) | 1989-11-29 | 1989-11-29 | Apparecchiatura di gassificazione di combustibili solidi |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0433547A1 EP0433547A1 (fr) | 1991-06-26 |
EP0433547B1 true EP0433547B1 (fr) | 1993-07-28 |
Family
ID=11322793
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90115070A Expired - Lifetime EP0433547B1 (fr) | 1989-11-29 | 1990-08-06 | Appareil pour gazéifier des combustibles solides |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0433547B1 (fr) |
JP (1) | JPH03172389A (fr) |
AT (1) | ATE92093T1 (fr) |
DE (1) | DE69002446T2 (fr) |
ES (1) | ES2043199T3 (fr) |
IT (1) | IT1236318B (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997001617A1 (fr) * | 1995-06-27 | 1997-01-16 | Ver Verwertung Und Entsorgung Von Reststoffen Gmbh | Procede et dispositif permettant de produire du gaz combustible |
IL125137A (en) | 1998-06-29 | 2001-07-24 | Maavar Kb Recycling And Prodouction Of Carbon Ltd | Process for making activated carbon from municipal waste |
DE102005026764B3 (de) * | 2005-06-10 | 2007-04-05 | Ws Reformer Gmbh | Festbettvergaser und Verfahren zur Vergasung von Festbrennstoff |
JP6139522B2 (ja) | 2011-07-27 | 2017-05-31 | サウジ アラビアン オイル カンパニー | ディレードコークス化ユニットからの粒子状コークスを用いた重質残油のガス化プロセス |
ES2436844B1 (es) | 2013-09-23 | 2014-07-07 | Eqtec Iberia, S.L. | Procedimiento para la gasificaci�n de materiales sólidos orgánicos y reactor empleado |
EP4209710A1 (fr) | 2022-01-10 | 2023-07-12 | ICMEA Srl leader of temporary association of companies ICMEA Srl - Tecnomec Engineering Srl - CNR IRSA | Unité de lit fluidisé |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR7706858A (pt) * | 1976-10-26 | 1978-07-04 | Union Steel Corp South Africa | Processo e aparelho para a producao continua de um gas redutor contendo monoxido de carbono e hidrogenio |
DE2738932C2 (de) * | 1977-08-30 | 1986-02-06 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zum kontinuierlichen Schlackeabziehen bei dem Vergasen fester Brennstoffe |
US4530702A (en) * | 1980-08-14 | 1985-07-23 | Pyrenco, Inc. | Method for producing fuel gas from organic material, capable of self-sustaining operation |
SE8201263L (sv) * | 1982-03-01 | 1983-09-02 | Skf Steel Eng Ab | Sett och anleggning for forgasning av kolhaltigt material |
GB2183249A (en) * | 1985-11-04 | 1987-06-03 | James Willis Associates Ltd | Thermal reactor |
-
1989
- 1989-11-29 IT IT08351989A patent/IT1236318B/it active IP Right Grant
-
1990
- 1990-08-06 EP EP90115070A patent/EP0433547B1/fr not_active Expired - Lifetime
- 1990-08-06 ES ES90115070T patent/ES2043199T3/es not_active Expired - Lifetime
- 1990-08-06 AT AT90115070T patent/ATE92093T1/de active
- 1990-08-06 DE DE90115070T patent/DE69002446T2/de not_active Expired - Fee Related
- 1990-08-23 JP JP2220157A patent/JPH03172389A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPH03172389A (ja) | 1991-07-25 |
IT8983519A1 (it) | 1991-05-29 |
EP0433547A1 (fr) | 1991-06-26 |
IT8983519A0 (it) | 1989-11-29 |
DE69002446T2 (de) | 1993-12-02 |
DE69002446D1 (de) | 1993-09-02 |
ATE92093T1 (de) | 1993-08-15 |
IT1236318B (it) | 1993-02-09 |
ES2043199T3 (es) | 1993-12-16 |
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