EP0426925A1 - Process and installation for the treatment of municipal and industrial wastes - Google Patents
Process and installation for the treatment of municipal and industrial wastes Download PDFInfo
- Publication number
- EP0426925A1 EP0426925A1 EP89403348A EP89403348A EP0426925A1 EP 0426925 A1 EP0426925 A1 EP 0426925A1 EP 89403348 A EP89403348 A EP 89403348A EP 89403348 A EP89403348 A EP 89403348A EP 0426925 A1 EP0426925 A1 EP 0426925A1
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- EP
- European Patent Office
- Prior art keywords
- thermolysis
- waste
- gases
- chamber
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000009434 installation Methods 0.000 title claims description 47
- 239000002440 industrial waste Substances 0.000 title claims description 21
- 238000001149 thermolysis Methods 0.000 claims abstract description 96
- 239000007789 gas Substances 0.000 claims abstract description 74
- 239000002699 waste material Substances 0.000 claims abstract description 56
- 238000001035 drying Methods 0.000 claims abstract description 47
- 238000006243 chemical reaction Methods 0.000 claims abstract description 43
- 239000011269 tar Substances 0.000 claims abstract description 14
- 238000000746 purification Methods 0.000 claims abstract description 8
- 239000002274 desiccant Substances 0.000 claims abstract description 7
- 238000011084 recovery Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 4
- 239000011343 solid material Substances 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 26
- 239000012071 phase Substances 0.000 description 9
- 238000010408 sweeping Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
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- 239000000203 mixture Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000861223 Issus Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
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- 230000001954 sterilising effect Effects 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/32—Other processes in ovens with mechanical conveying means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
Definitions
- the invention relates to a method and an installation for treating urban and / or industrial waste.
- Pyrolysis consists of burning a solid with a certain lack of oxygen. Oxygen is used in this reaction to heat the product and to decompose the materials in combustible gases, smoke and combustible carbonaceous residues, such as charcoal.
- thermolysis reaction is even higher than that of pyrolysis because we are in the presence of a phenomenon of distillation of organic matter. During this reaction, the heat no longer comes from a direct flame but from radiation from a heating chamber.
- thermolysis reaction When a thermolysis reaction is carried out on urban and / or industrial waste, we will somehow carry out a distillation of these to finally obtain carbonaceous solids recoverable and recoverable after sorting of inert, tars recoverable and recoverable in specific petrochemical plants, as well as clean combustible gases that can also be reused. So far, laboratory tests of thermolysis and some Experiments promise an interesting future for the treatment of urban and / or industrial waste, but no process or treatment facility has yet emerged, allowing certain economic industrial development.
- the efficiency of the installation depends on the quality of the products obtained, that is to say the recoverable residual materials.
- the treatment installation must be safe in terms of its operation, i.e. it must not be dangerous for the personnel supervising the operations or polluting the environment with regard to possible clearances. that could happen.
- the object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which a thermolysis reaction is used which is entirely suited to industrial requirements, namely efficiency, economy, pollution.
- One of the aims of the present invention is to propose a method and an installation for treating urban and / or industrial waste, which allow continuous treatment of waste and which allow a lifetime. important installation mechanics, avoiding repetitive thermal shock as much as possible.
- Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which the temperature is obtained by the autothermal combustion of the residues produced during the reaction.
- Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which the different stages are controlled sequentially, the control of each of these stages being carried out from the point of view of the temperatures set works, the atmosphere in which the reaction is carried out, to allow stable operation in temperature and pressure.
- Another object of the present invention is to provide a process which allows the production of installations for treating urban and / or industrial waste, which are modular in their capacity and which can be easily adapted according to such or such uses.
- Another object of the present invention is to provide a method and an installation for destroying urban and / or industrial waste which are advantageous in terms of the recovery of the material which can be stored and then checked before reuse.
- Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste which are particularly advantageous from the ecological point of view and which make it possible to provide a solution to the problem of pollution of incinerators, well known to date.
- the process for treating urban and / or industrial waste, by which the waste is subjected to a thermolysis reaction is characterized in that: - the waste to be treated is previously dehydrated in a closed drying enclosure, - all the gases produced during drying are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step, - Said purified gases are at least partially reinjected into the installation as a drying agent and the non-polluting excess gases are discharged to the outside.
- thermolysis reaction is carried out at low temperature, of the order of 400 to 450 ° C., in a thermolysis chamber, isolated and controlled, then the gaseous products obtained from the thermolysis reaction, in closed circuits relative to the atmosphere, in which the gaseous elements are separated tars in the gaseous state, then the combustible gases are purified with a view to their subsequent re-use in said process.
- the installation allowing the implementation of the method of the invention comprises at least: - a drying chamber for the waste to be treated, consisting of a closed enclosure, means for creating a stream of hot air able to circulate from the inlet to the outlet of said drying enclosure, means for recovering the gaseous fluid resulting from the drying at the outlet of the drying chamber, - Means for purifying said gaseous fluid resulting from drying.
- the installation comprises a controlled and insulated thermolysis chamber, constituted by a double envelope reactor having a primary enclosure, into which the waste is introduced, and a secondary heating enclosure, capable of raising at least the temperature of the primary enclosure for carrying out the thermolysis reaction as well as means for recovering solids and for recovering and treating gaseous products resulting from thermolysis.
- a controlled and insulated thermolysis chamber constituted by a double envelope reactor having a primary enclosure, into which the waste is introduced, and a secondary heating enclosure, capable of raising at least the temperature of the primary enclosure for carrying out the thermolysis reaction as well as means for recovering solids and for recovering and treating gaseous products resulting from thermolysis.
- the invention relates to a method and an installation for treating urban and / or industrial waste, which in particular allow destruction of such waste in a non-polluting and economical manner using a thermolysis reaction.
- thermolysis consist of carbonaceous solids recoverable and recoverable after sorting inert, tars also recoverable and recoverable in specific thermal or petrochemical installations as well as clean gases reusable in the process of the invention after inspection.
- the waste is subjected to a fully controlled thermolysis reaction, in which in particular the creation at high temperature of chlorinated compounds and stable pollutants difficult to remove, such as dioxide, is avoided, and then the products obtained by implementing different stages carried out successively and sequentially, without discharge polluting the atmosphere.
- the waste to be treated Prior to the thermolysis reaction, according to the present invention, the waste to be treated is dehydrated in order to eliminate a large part of the moisture contained in it.
- This prior dehydration is carried out in a closed drying enclosure and this phase is completely controlled since all the gases produced during drying are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step.
- said purified gases are at least partially reinjected into the installation as a drying agent.
- it is necessary to evacuate the excess gases because for example it is necessary to enter the installation of the combustion air.
- this discharge to the outside is carried out in a non-polluting way because the excess gases are not aggressive for the atmosphere.
- thermolysis is advantageously carried out at a temperature below 450 ° C. to avoid the formation of dangerous pollutants such as, for example, dioxide.
- thermolysis reaction is carried out in a thermolysis chamber, isolated and controlled, from which the gaseous products resulting from the thermolysis reaction are recovered, in closed circuits with respect to the atmosphere.
- the recovered gaseous products, resulting from the thermolysis reaction, are then also treated in closed circuits in which the combustible gaseous elements are separated from the tars in the gaseous state, then the combustible gases are purified with a view to their subsequent use in said process, i.e. separating the droplets from the gas before storage.
- thermolysis reaction can be carried out at atmospheric pressure.
- thermolysis reaction under sweeping neutral gas for the reaction, in the thermolysis chamber, at a controlled pressure slightly higher than atmospheric pressure.
- thermolysis gaseous products resulting from thermolysis are continuously removed from the thermolysis chamber and directed to the means for recovering and treating said gaseous products.
- thermolysis chamber In the case where the reaction is carried out under neutral gas sweeping, such a gas is blown into the thermolysis chamber at a pressure slightly higher than atmospheric pressure, for example of the order of 1.6 bar, which continuously flushes out gaseous products from thermolysis.
- thermolysis reaction In the case where the thermolysis reaction is carried out under overpressure, it is the pressure prevailing inside the thermolysis chamber which will drive the gases resulting from the thermolysis out of the enclosure as a function of a calibration pressure. predetermined.
- thermolysis step proper the temperature in the thermolysis chamber is established, indirectly with respect to the waste to be treated, by circulation of high temperature heating gas.
- these heating gases are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step, in the same way as the gases produced during the preliminary drying.
- the purified gases are at least partially reinjected into the installation as a drying agent.
- the purified excess gases therefore non-polluting, can be evacuated outside the installation.
- One of the advantages of the process of the present invention is that it allows continuous treatment of the waste.
- the waste is dehydrated in a drying chamber, in which it is stirred and subjected to a flow of hot air, such that a movement of the waste from the inlet to the outlet of said said is defined. drying chamber.
- thermolysis reaction proper is carried out, as has been specified above.
- thermolysis phase When the waste to be treated has undergone the thermolysis phase, it is then removed by gravity and sequentially solids from thermolysis for recovery.
- FIG. 1 shows an example of an installation for treating urban and / or industrial waste, capable of carrying out a thermolysis reaction and designed particularly for the implementation of the method of the invention which has just been described.
- thermolysis chamber controlled and isolated, waste to be treated
- means for recovering solid materials and gaseous products. from thermolysis.
- the drying chamber (1), the thermolysis chamber (2) and the means (3) for recovering the materials are advantageously arranged successively in series in such a way as to allow a continuous, sequential gravity movement of the waste and the contained materials, from the inlet of the installation (5) to its outlet (6) and that the 'We can keep each chamber (1, 2, 3) stable operation in temperature and / or pressure.
- the first phase of the actual treatment therefore consists of a phase of drying or dehydration of the waste.
- This phase is carried out in the drying chamber (1) in which the waste is stirred and subjected to a flow of hot air.
- an advance movement (7) of the waste is generated from the inlet (5) to the outlet (8) of said drying chamber (1).
- the drying chamber (1) consists of an enclosure (9) closed, having an inlet (5) through which the waste to be treated is introduced and an outlet (8) from which the dehydrated product will drain out.
- a motorized drum (10) Inside the closed enclosure (9) is provided a motorized drum (10) able to contain the waste to be dried and to brew it permanently, and also able to create said advance movement (7) for the waste from the inlet (5) to the outlet (8).
- the installation comprises means (12, 13) for creating a stream of hot air able to circulate in said drying enclosure (9).
- a treatment box (12) which comprises a gas burner (13) and a blowing system (47) placed upstream of the burner (13), and able to direct a gas flow towards the flame of said burner.
- the drying circuit also includes means (48) for recovering the gaseous fluid resulting from the drying of the drying chamber (9) as well as means for purifying said gaseous fluid resulting from drying.
- the hot dry air (11) introduced into the dryer absorbs, on contact with the stirred waste, the moisture contained in it and thus leaves charged with moisture in (16).
- This moist air (16) recovered by the means (48) then passes through a condenser exchanger (17) in order to be dehumidified and before being recycled to the means (12, 13) to create said stream of hot air, at the inlet (15) of the air treatment box (12) so that it is purified.
- said means for creating the stream of hot air and for purifying the gaseous fluid consist essentially of the burner (13) and the blowing system (47).
- a burner will be provided, the flame of which advantageously reaches at least 850 ° C. and a blowing system, the speeds of which will be such that the said gases will pass through the flame and will be maintained at this temperature for at least two seconds.
- a sterilization of the gases will be obtained which will therefore be purified and the aromatic essences which they contained will be burned.
- a valve (50), installed on the discharge of high temperature excess gases (19), before the recovery battery (18), will allow the adjustment of the volume of air entering compared to the volume of air leaving.
- the direction of circulation of the hot air flow (11) is opposite to said advance movement (7) of the waste in the dryer.
- the drum (10) is placed in said stream of hot air and provision is made for its rotation and its arrangement so that the hot air is introduced countercurrently into the dryer.
- said drum (10) is arranged horizontally with its inclined axis of rotation to allow movement (7) of the waste from the inlet (5) to the outlet (8) of the dryer.
- the drum (10) will internally have blades (49) fixed on the latter.
- thermolysis reaction is carried out in the thermolysis chamber (2).
- this thermolysis chamber (2) is constituted by a double jacket reactor having an internal primary enclosure (21), fixed, into which the waste is introduced, and by a secondary external heating enclosure (22), fixed, enveloping said primary enclosure (21).
- a motorized rotor (23) equipped with paddles (24) oriented and fixed on a central axis controlled by a motor (25).
- thermolysis chamber is horizontal; nevertheless, other arrangements could be envisaged, the rotor possibly being oblique, or even vertical. Likewise, a fixed enclosure and a rotating rotor are provided, but of course, one could imagine a reverse system in which the enclosure would turn.
- the waste is heated up in particular by the combustion gases from a burner (28), of the mixed fuel oil - gas type for example, circulating in said secondary enclosure (22) which surrounds the primary enclosure (21).
- This circulation of high temperature gas allows in particular the rise in temperature inside the enclosure (21) of the reactor of the order of 400 to 450 ° C.
- the gases shown diagrammatically at (30) in the figure are reinjected into the drying circuit, as described above, thus participating in energy recovery. These gases are in particular reinjected at the inlet (15) of the box (12).
- thermolysis chamber recovery heating gases which heat the thermolysis chamber, recovery which takes place in a closed circuit with respect to the atmosphere. Then these gases are also subjected to a purification step as it was for the drying gases.
- drying (1) and thermolysis (2) chambers are superimposed, as shown in particular in FIG. 1, so that loading can occur by gravity.
- an airlock (31) capable of connecting the two chambers in a sealed manner, so the waste can be introduced into the chamber thermolysis (2) continuously via said airlock (31) in order on the one hand to balance the pressures between the two enclosures and on the other hand, to authorize a neutralization of the incoming product, in particular by injection of nitrogen or pressure balance before opening the interior door of the airlock, or other.
- thermolysis chamber there is another airlock (32) also sealingly connecting the thermolysis chamber and the means for recovering solid materials (3).
- this second airlock (32) is similar to the first with regard to the evacuation of solids from thermolysis.
- the waste is stirred inside the enclosure (21) of the reactor by the rotor (23-25).
- the blades (24) define an advance movement (26) of the material contained in the chamber (2), from its inlet (8) to its outlet (27).
- thermolysis according to the process of the present invention, the gaseous products resulting from the thermolysis reaction are recovered and treated in closed circuits (33) relative to the atmosphere as particularly illustrated in FIG. 2 .
- the closed circuit (33) substantially constitutes said means (4) for recovering gaseous products resulting from thermolysis and are capable of separating the fuel elements from the tars in the gaseous state, by washing the combustible gases, with a view to their subsequent use. in said method.
- these means (4) consist of a closed circuit (33) comprising at least one device for circulating said gaseous products such as a mechanical extraction device (34), a separator (35) "gaseous element fuel - tar in gaseous state ", of sprayer type, a gas purification circuit (36) in which the gas droplets are separated before its storage, as well as a circuit (37) for treating liquid effluents .
- a closed circuit (33) comprising at least one device for circulating said gaseous products such as a mechanical extraction device (34), a separator (35) "gaseous element fuel - tar in gaseous state ", of sprayer type, a gas purification circuit (36) in which the gas droplets are separated before its storage, as well as a circuit (37) for treating liquid effluents .
- thermolysis reactor (2) taking into account the temperature at which the reaction is carried out, there is a mixture of the combustible gaseous elements and of the tars in the gaseous state. These gases are removed under pressure or by sweeping the gas. In addition, certain powdery solid elements can also be entrained.
- the principle of separation of combustible gases and tars leaving the reactor is carried out by the wet method using the separator (35) of the sprayer type generally known under the name of "quench at the water”.
- the gaseous elements produced by the thermolysis reaction escape through the top (39) of the separator, the extraction device (34) making it possible to overcome the pressure drops in the circuit.
- These gases are combustible and are then purified and stored in pressure tanks before being reused by the installation's burners.
- This decantation is carried out in the treatment circuit (37) in which the light phase is continuously recovered by an oleophilic drum, then detached from the drum using a scraper which sends it in a small buffer capacity (40) , heated by an internal coil, in order to lower the viscosity of the organic mixture.
- This mixture is then taken up by a gear then stored in a tar storage tank (41) before being redirected or treated.
- the heavy aqueous phase is taken up at the bottom of the settling tank (37) by a centrifugal pump (42) then clarified on filters (43) intended to remove solid particles such as dust.
- the decantation purge is then purified of any organic compound by passage over active carbon (44) and then discharged into the wastewater basin.
- the washing liquid, used in the separator (35) of the sprayer type is recycled, kept at low temperature on the loop.
- the on-line neutralization of the chlorine contained in the gas circuit is done by injection of soda (45) in the water of the "Quench".
- the circuit is purged regularly to be sent to the settling tanks (37).
- the solids resulting from thermolysis are removed by gravity and sequentially. This evacuation is, let us recall, carried out by means of the airlock (32) which makes it possible to maintain a controlled atmosphere inside the reactor (2).
- thermolysis chamber (2) and the recovery means (3) are superimposed, the latter being in particular constituted by a container (46) adapted under said airlock (32).
- a container (46) adapted under said airlock (32) it could also be possible to place them side by side with a lifting conveyor between them.
- thermolysis solid residues from thermolysis, such as coals or inert materials, these being recovered from below the reactor (2) via the airlock (32), in particular neutralized by nitrogen injection.
- a mobile, sealed, double-envelope container (46) is used, in which cold water is circulated in order to accelerate the cooling of the product.
- a handling device with a magnetic drum to remove ferrous materials and a vibrating screen to isolate the inert parts of the carbon. All of this equipment will be provided in particular under a sealed hood in order to limit carbon dust and its expansion in the atmosphere.
- urban waste is supplied in a main pit with an autonomy of several days of operation, but without however being exaggerated so as to minimize the release of odors.
- the air volume located above the repository is maintained in depression by a mechanical ventilation assembly.
- the waste thus prepared is then conveyed on a crusher allowing the ultimate physical transformation of the raw product before treatment.
- the grinding will shred household waste into sufficiently small elements so as to facilitate the drying technique described above.
- a belt conveyor assembly takes up the waste thus treated from the mill outlet to store it in a hopper with a capacity such that it can continuously supply the drying chamber (1) of the present invention.
- thermolysis reaction The means for treating the gaseous products resulting from thermolysis which have just been described will in particular be adapted as a function of the conditions under which the thermolysis reaction is carried out, namely under atmospheric pressure or under CO 2 sweeping or under overpressure particularly to allow in the different processing circuits the circulation of the different products.
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- Oil, Petroleum & Natural Gas (AREA)
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- Processing Of Solid Wastes (AREA)
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Abstract
Description
L'invention est relative à un procédé et une installation de traitement de déchets urbains et/ou industriels.The invention relates to a method and an installation for treating urban and / or industrial waste.
Elle trouvera notamment son application dans le domaine de l'élimination des déchets urbains et/ou industriels ainsi que dans le domaine de la valorisation de ces déchets.It will find its application in particular in the field of urban and / or industrial waste disposal as well as in the field of recovery of this waste.
Dans le domaine du traitement des déchets urbains et/ou industriels, différentes techniques sont connues à ce jour, allant de la plus simple qui consiste en un dépôt des ordures et des déchets dans des décharges ouvertes jusqu'aux solutions les plus sophistiquées utilisant les réactions de pyrolyse ou de thermolyse.In the field of treatment of urban and / or industrial waste, various techniques are known to date, ranging from the simplest which consists of depositing garbage and waste in open landfills to the most sophisticated solutions using the reactions pyrolysis or thermolysis.
La pyrolyse consiste à faire brûler un solide avec un certain manque d'oxygène. On utilise l'oxygène dans cette réaction pour chauffer le produit et réaliser une décomposition des matières dans des gaz combustibles, de la fumée et des résidus carbonés combustibles, tels que charbon de bois.Pyrolysis consists of burning a solid with a certain lack of oxygen. Oxygen is used in this reaction to heat the product and to decompose the materials in combustible gases, smoke and combustible carbonaceous residues, such as charcoal.
La réaction de thermolyse est encore supérieure à celle de la pyrolyse car on est en présence d'un phénomène de distillation de la matière organique. Pendant cette réaction, la chaleur ne vient plus d'une flamme directe mais par rayonnement depuis une chambre de chauffage.The thermolysis reaction is even higher than that of pyrolysis because we are in the presence of a phenomenon of distillation of organic matter. During this reaction, the heat no longer comes from a direct flame but from radiation from a heating chamber.
Lorsque l'on mène une réaction de thermolyse sur des déchets urbains et/ou industriels, on va en quelque sorte réaliser une distillation de ceux-ci pour obtenir finalement des solides carbonés récupérables et valorisables après tri des inertes, des goudrons récupérables et valorisables dans des installations pétrochimiques spécifiques, ainsi que des gaz propres combustibles également réutilisables. Jusqu'à présent, des essais en laboratoire de thermolyse et certaines expériences promettent un avenir intéressant pour le traitement des déchets urbains et/ou industriels mais aucun procédé ni installation de traitement n'a encore vu le jour permettant un développement industriel économique certain.When a thermolysis reaction is carried out on urban and / or industrial waste, we will somehow carry out a distillation of these to finally obtain carbonaceous solids recoverable and recoverable after sorting of inert, tars recoverable and recoverable in specific petrochemical plants, as well as clean combustible gases that can also be reused. So far, laboratory tests of thermolysis and some Experiments promise an interesting future for the treatment of urban and / or industrial waste, but no process or treatment facility has yet emerged, allowing certain economic industrial development.
En effet, pour être exploitable, une telle installation de traitement de déchets urbains et/ou industriels doit être efficace, économique, rentable et non polluante pour l'environnement.In order to be usable, such an urban and / or industrial waste treatment installation must be efficient, economical, profitable and environmentally friendly.
De l'efficacité de l'installation dépend la qualité des produits obtenus, c'est-à-dire des matières résiduelles récupérables.The efficiency of the installation depends on the quality of the products obtained, that is to say the recoverable residual materials.
Cette efficacité est liée également au temps de mise en oeuvre d'un traitement et par suite se répercute sur le coût de revient du traitement. En effet, comme il s'agit de traiter des déchets urbains et/ou industriels, il faut que ce traitement soit abordable pour ne pas être dissuasif.This efficiency is also linked to the time for implementing a treatment and consequently has repercussions on the cost price of the treatment. Indeed, since it is a question of treating urban and / or industrial waste, this treatment must be affordable in order not to be dissuasive.
Enfin, l'installation de traitement doit être sûre quant à son fonctionnement, c'est-à-dire qu'il ne faut pas qu'elle soit dangereuse pour le personnel qui surveille les opérations ni polluante pour l'environnement quant aux dégagements éventuels qui pourraient se produire.Finally, the treatment installation must be safe in terms of its operation, i.e. it must not be dangerous for the personnel supervising the operations or polluting the environment with regard to possible clearances. that could happen.
Le but de la présente invention est de proposer un procédé et une installation de traitement des déchets urbains et/ou industriels dans lesquels on met en oeuvre une réaction de thermolyse qui soit tout à fait adaptée aux impératifs industriels à savoir efficacité, économie, pollution.The object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which a thermolysis reaction is used which is entirely suited to industrial requirements, namely efficiency, economy, pollution.
Un des buts de la présente invention est de proposer un procédé et une installation de traitement des déchets urbains et/ou industriels, qui permettent un traitement en continu des déchets et qui autorisent une durée de vie mécanique de l'installation importante en évitant au maximum les chocs thermiques répétitifs.One of the aims of the present invention is to propose a method and an installation for treating urban and / or industrial waste, which allow continuous treatment of waste and which allow a lifetime. important installation mechanics, avoiding repetitive thermal shock as much as possible.
Un autre but de la présente invention est de proposer un procédé et une installation de traitement des déchets urbains et/ou industriels dans lesquels la température est obtenue par la combustion autotherme des résidus produits lors de la réaction.Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which the temperature is obtained by the autothermal combustion of the residues produced during the reaction.
Un autre but de la présente invention est de proposer un procédé et une installation de traitement des déchets urbains et/ou industriels dans lesquels les différentes étapes sont contrôlées séquentiellement, la maîtrise de chacune de ces étapes étant menées au point de vue des températures mises en oeuvres, de l'ambiance dans laquelle est menée la réaction, pour autoriser un fonctionnement stable en température et pression.Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste in which the different stages are controlled sequentially, the control of each of these stages being carried out from the point of view of the temperatures set works, the atmosphere in which the reaction is carried out, to allow stable operation in temperature and pressure.
Un autre but de la présente invention est de proposer un procédé qui permette la réalisation d'installations de traitement des déchets urbains et/ou industriels, qui soient modulables dans leur capacité et qui puissent être adaptées facilement en fonction de telles ou telles utilisations.Another object of the present invention is to provide a process which allows the production of installations for treating urban and / or industrial waste, which are modular in their capacity and which can be easily adapted according to such or such uses.
Un autre but de la présente invention est de proposer un procédé et une installation de destruction de déchets urbains et/ou industriels qui soient intéressants au niveau de la récupération de la matière qui peut être stockée puis contrôlée avant réutilisation.Another object of the present invention is to provide a method and an installation for destroying urban and / or industrial waste which are advantageous in terms of the recovery of the material which can be stored and then checked before reuse.
Un autre but de la présente invention est de proposer un procédé et une installation de traitement des déchets urbains et/ou industriels qui soient particulièrement intéressants sur le plan de l'écologie et qui permettent d'apporter une solution au problème de la pollution des incinérateurs, bien connu à ce jour.Another object of the present invention is to provide a method and an installation for treating urban and / or industrial waste which are particularly advantageous from the ecological point of view and which make it possible to provide a solution to the problem of pollution of incinerators, well known to date.
En effet, grâce à la présente invention, on ne rejette dans l'atmosphère que des gaz ou des produits préalablement épurés, c'est-à-dire dans lesquels on élimine toute trace de pollution pour l'environnement et on évite particulièrement la création à haute température de composés chlorés et de polluants stables, difficiles à éliminer, tels que dioxyde.In fact, thanks to the present invention, only gases or previously purified products are discharged into the atmosphere, that is to say in which all traces of pollution for the environment are eliminated and creation is particularly avoided. at high temperature of chlorinated compounds and stable pollutants, difficult to remove, such as dioxide.
D'autres buts et avantages de la présente invention apparaîtront au cours de la description qui va suivre qui n'est cependant donnée qu'à titre indicatif et qui n'a pas pour but de la limiter.Other objects and advantages of the present invention will appear during the description which follows which is however given only for information and which is not intended to limit it.
Selon la présente invention, le procédé de traitement des déchets urbains et/ou industriels, par lequel on soumet les déchets à une réaction de thermolyse est caractérisé par le fait que :
- on déshydrate préalablement les déchets à traiter dans une enceinte fermée de séchage,
- on récupère tous les gaz produits lors du séchage, en circuit fermé par rapport à l'atmosphère, et on soumet ces gaz à une étape de purification,
- on réinjecte au moins en partie lesdits gaz purifiés dans l'installation comme agent de séchage et on évacue les gaz excédentaires non polluants vers l'extérieur.According to the present invention, the process for treating urban and / or industrial waste, by which the waste is subjected to a thermolysis reaction is characterized in that:
- the waste to be treated is previously dehydrated in a closed drying enclosure,
- all the gases produced during drying are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step,
- Said purified gases are at least partially reinjected into the installation as a drying agent and the non-polluting excess gases are discharged to the outside.
En outre, selon la présente invention, on mène la réaction de thermolyse à basse température, de l'ordre de 400 à 450°C, dans une chambre de thermolyse, isolée et contrôlée, puis on récupère et on traite les produits gazeux issus de la réaction de thermolyse, dans des circuits fermés par rapport à l'atmosphère, dans lesquels on sépare les éléments gazeux combustibles des goudrons à l'état gazeux, puis on épure les gaz combustibles en vue de leur réutilisation ultérieure dans ledit procédé.In addition, according to the present invention, the thermolysis reaction is carried out at low temperature, of the order of 400 to 450 ° C., in a thermolysis chamber, isolated and controlled, then the gaseous products obtained from the thermolysis reaction, in closed circuits relative to the atmosphere, in which the gaseous elements are separated tars in the gaseous state, then the combustible gases are purified with a view to their subsequent re-use in said process.
L'installation permettant la mise en oeuvre du procédé de l'invention comporte au moins :
- une chambre de séchage des déchets à traiter, constituée par une enceinte fermée,
- des moyens pour créer une veine d'air chaud apte à circuler de l'entrée vers la sortie de ladite enceinte de séchage,
- des moyens pour récupérer le fluide gazeux issu du séchage en sortie de l'enceinte de séchage,
- des moyens pour purifier ledit fluide gazeux issu du séchage.The installation allowing the implementation of the method of the invention comprises at least:
- a drying chamber for the waste to be treated, consisting of a closed enclosure,
means for creating a stream of hot air able to circulate from the inlet to the outlet of said drying enclosure,
means for recovering the gaseous fluid resulting from the drying at the outlet of the drying chamber,
- Means for purifying said gaseous fluid resulting from drying.
En outre, l'installation comporte une chambre de thermolyse contrôlée et isolée, constituée par un réacteur double enveloppe présentant une enceinte primaire, dans laquelle sont introduits les déchets, et une enceinte secondaire de chauffage, apte à élever au moins la température de l'enceinte primaire pour mener la réaction de thermolyse ainsi que des moyens de récupération des matières solides et de récupération et de traitement des produits gazeux issus de la thermolyse.In addition, the installation comprises a controlled and insulated thermolysis chamber, constituted by a double envelope reactor having a primary enclosure, into which the waste is introduced, and a secondary heating enclosure, capable of raising at least the temperature of the primary enclosure for carrying out the thermolysis reaction as well as means for recovering solids and for recovering and treating gaseous products resulting from thermolysis.
La présente invention sera mieux comprise à la lecture de la description suivante, accompagnée des dessins en annexe qui en font partie intégrante.
- La figure 1 schématise les différents éléments constituant l'installation de traitement de la présente invention.
- La figure 2 montre en détails les moyens de récupération et de traitement des produits gazeux issus de la thermolyse menée dans l'installation de la figure 1.
- Figure 1 shows schematically the various elements constituting the treatment installation of the present invention.
- FIG. 2 shows in detail the means of recovery and treatment of the gaseous products resulting from the thermolysis carried out in the installation of FIG. 1.
L'invention concerne un procédé et une installation de traitement des déchets urbains et/ou industriels, qui permettent notamment une destruction de tels déchets de façon non polluante et économique en utilisant une réaction de thermolyse.The invention relates to a method and an installation for treating urban and / or industrial waste, which in particular allow destruction of such waste in a non-polluting and economical manner using a thermolysis reaction.
Pour ce qui est de la pollution, il est à noter que le système mis au point permet un traitement dans des circuits fermés évitant toute communication avec l'extérieur.Regarding pollution, it should be noted that the system developed allows treatment in closed circuits avoiding any communication with the outside.
Pour ce qui est de la rentabilité de l'installation, il est à remarquer que les produits obtenus par la mise en oeuvre de la thermolyse sont constitués par des solides carbonés récupérables et valorisables après tri des inertes, des goudrons également récupérables et valorisables dans des installations thermique ou pétrochimiques spécifiques ainsi que des gaz propres réutilisables dans le procédé de l'invention après contrôle.With regard to the profitability of the installation, it should be noted that the products obtained by the implementation of thermolysis consist of carbonaceous solids recoverable and recoverable after sorting inert, tars also recoverable and recoverable in specific thermal or petrochemical installations as well as clean gases reusable in the process of the invention after inspection.
Cette valorisation permet de réduire sensiblement les frais du traitement des déchets, et la récupération de certains gaz permet une économie sensible d'énergie.This recovery significantly reduces the costs of waste treatment, and the recovery of certain gases allows significant energy savings.
Ainsi, par le procédé de la présente invention, on soumet les déchets une réaction de thermolyse totalement contrôlée, dans laquelle on évite notamment la création à haute température de composés chlorés et de polluants stables difficiles à éliminer, tels que dioxyde, puis on récupère les produits obtenus en mettant en oeuvre différentes étapes réalisées successivement et séquentiellement, sans rejet polluant pour l'atmosphère.Thus, by the process of the present invention, the waste is subjected to a fully controlled thermolysis reaction, in which in particular the creation at high temperature of chlorinated compounds and stable pollutants difficult to remove, such as dioxide, is avoided, and then the products obtained by implementing different stages carried out successively and sequentially, without discharge polluting the atmosphere.
Préalablement à la réaction de thermolyse, selon la présente invention, on déshydrate les déchets à traiter afin d'éliminer une grande partie d'humidité contenue dans ceux-ci.Prior to the thermolysis reaction, according to the present invention, the waste to be treated is dehydrated in order to eliminate a large part of the moisture contained in it.
Cette déshydratation préalable est menée dans une enceinte fermée de séchage et cette phase est complètement contrôlée car on récupère tous les gaz produits lors du séchage, en circuit fermé par rapport à l'atmosphère, et on soumet ces gaz à une étape de purification.This prior dehydration is carried out in a closed drying enclosure and this phase is completely controlled since all the gases produced during drying are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step.
Il s'agit là d'un point très important sur le plan de la pollution et sur le plan de l'économie.This is a very important point in terms of pollution and in terms of the economy.
Sur le plan de l'économie, selon le procédé de traitement de l'invention, on réinjecte au moins en partie lesdits gaz purifiés dans l'installation comme agent de séchage. Toutefois, il est nécessaire d'évacuer les gaz excédentaires, car par exemple il est nécessaire d'entrer dans l'installation de l'air comburant. Toutefois, ce rejet vers l'extérieur est effectué de façon non polluante car les gaz excédentaires ne sont pas agressifs pour l'atmosphère.In terms of economy, according to the treatment method of the invention, said purified gases are at least partially reinjected into the installation as a drying agent. However, it is necessary to evacuate the excess gases, because for example it is necessary to enter the installation of the combustion air. However, this discharge to the outside is carried out in a non-polluting way because the excess gases are not aggressive for the atmosphere.
En outre, selon le procédé de la présente invention, la thermolyse est avantageusement menée à une température inférieure 450°C pour éviter la formation d'éléments polluants dangereux tels que par exemple la dioxyde.In addition, according to the process of the present invention, the thermolysis is advantageously carried out at a temperature below 450 ° C. to avoid the formation of dangerous pollutants such as, for example, dioxide.
Cette réaction de thermolyse est menée dans une chambre de thermolyse, isolée et contrôlée, de laquelle on récupère les produits gazeux issus de la réaction de thermolyse, dans des circuits fermés par rapport à l'atmosphère.This thermolysis reaction is carried out in a thermolysis chamber, isolated and controlled, from which the gaseous products resulting from the thermolysis reaction are recovered, in closed circuits with respect to the atmosphere.
Les produits gazeux récupérés, issus de la réaction de thermolyse, sont ensuite traités également dans des circuits fermés dans lesquels on sépare les éléments gazeux combustibles des goudrons à l'état gazeux, puis on épure les gaz combustibles en vue de leur utilisation ultérieure dans ledit procédé, c'est-à-dire qu'on sépare les gouttelettes du gaz avant son stockage.The recovered gaseous products, resulting from the thermolysis reaction, are then also treated in closed circuits in which the combustible gaseous elements are separated from the tars in the gaseous state, then the combustible gases are purified with a view to their subsequent use in said process, i.e. separating the droplets from the gas before storage.
Il est à noter que la réaction de thermolyse peut être menée à la pression atmosphérique.It should be noted that the thermolysis reaction can be carried out at atmospheric pressure.
Toutefois, on a noté de très bons résultats en effectuant la réaction de thermolyse sous balayage de gaz neutre pour la réaction, dans la chambre de thermolyse, à une pression contrôlée légèrement supérieure à la pression atmosphérique.However, very good results have been noted in carrying out the thermolysis reaction under sweeping neutral gas for the reaction, in the thermolysis chamber, at a controlled pressure slightly higher than atmospheric pressure.
On a également obtenu de bons résultats en menant la réaction de thermolyse dans une chambre de thermolyse en surpression.Good results have also been obtained by conducting the thermolysis reaction in an overpressure thermolysis chamber.
Les produits gazeux issus de la thermolyse sont prélevés en continu de la chambre de thermolyse et dirigés vers les moyens de récupération et de traitement desdits produits gazeux.The gaseous products resulting from thermolysis are continuously removed from the thermolysis chamber and directed to the means for recovering and treating said gaseous products.
Dans le cas où la réaction est menée sous balayage de gaz neutre, on insuffle dans la chambre de thermolyse un tel gaz à une pression légèrement supérieure à la pression atmosphérique, par exemple de l'ordre de 1,6 bar, ce qui chasse continuellement les produits gazeux issus de la thermolyse.In the case where the reaction is carried out under neutral gas sweeping, such a gas is blown into the thermolysis chamber at a pressure slightly higher than atmospheric pressure, for example of the order of 1.6 bar, which continuously flushes out gaseous products from thermolysis.
Dans le cas où la réaction de thermolyse est menée en surpression, c'est la pression qui règne à l'intérieur de la chambre de thermolyse qui chassera les gaz issus de la thermolyse hors de l'enceinte en fonction d'une pression de tarage prédéterminée.In the case where the thermolysis reaction is carried out under overpressure, it is the pressure prevailing inside the thermolysis chamber which will drive the gases resulting from the thermolysis out of the enclosure as a function of a calibration pressure. predetermined.
A titre d'information, il est à noter que l'on a effectué différentes expérimentations donnant des résultats significatifs en effectuant :
- la thermolyse entre 400 et 450°C sous balayage de gaz carbonique CO2 à une pression intérieure de 1,6 bar,
- la thermolyse entre 400 et 450°C sous une pression absolue jusque 3 bars.For your information, it should be noted that we carried out various experiments giving significant results by performing:
- thermolysis between 400 and 450 ° C under sweeping of carbon dioxide CO2 at an internal pressure of 1.6 bar,
- thermolysis between 400 and 450 ° C under absolute pressure up to 3 bars.
Pour ce qui est de l'étape de thermolyse proprement dite, on établit la température dans la chambre de thermolyse, indirectement par rapport aux déchets à traiter, par circulation de gaz de chauffage haute température.As regards the thermolysis step proper, the temperature in the thermolysis chamber is established, indirectly with respect to the waste to be treated, by circulation of high temperature heating gas.
Selon une caractéristique de la présente invention, on récupère ces gaz de chauffage, en circuit fermé par rapport à l'atmosphère, et on soumet ces gaz à une étape de purification, au même titre que les gaz produits lors du séchage préalable.According to a characteristic of the present invention, these heating gases are recovered, in a closed circuit with respect to the atmosphere, and these gases are subjected to a purification step, in the same way as the gases produced during the preliminary drying.
Egalement, on réinjecte au moins en partie les gaz purifiés dans l'installation comme agent de séchage.Also, the purified gases are at least partially reinjected into the installation as a drying agent.
Les gaz excédentaires purifiés, donc non polluants, peuvent être évacués vers l'extérieur de l'installation.The purified excess gases, therefore non-polluting, can be evacuated outside the installation.
Un des avantages du procédé de la présente invention est de permettre un traitement en continu des déchets.One of the advantages of the process of the present invention is that it allows continuous treatment of the waste.
Pour cela, on déshydrate les déchets dans une chambre de séchage, dans laquelle ils sont brassés et soumis à un flux d'air chaud, tel que l'on définisse un mouvement d'avance des déchets de l'entrée vers la sortie de ladite chambre de séchage.For this, the waste is dehydrated in a drying chamber, in which it is stirred and subjected to a flow of hot air, such that a movement of the waste from the inlet to the outlet of said said is defined. drying chamber.
On introduit ensuite, gravitairement et séquentiellement, les déchets ainsi déshydratés dans ladite chambre de thermolyse, isolée et contrôlée, dans laquelle on mène la réaction de thermolyse proprement dite, tel que cela a été précisé ci-dessus.The waste thus dehydrated is then introduced, gravitatively and sequentially, into said thermolysis chamber, isolated and controlled, in which the thermolysis reaction proper is carried out, as has been specified above.
Lorsque les déchets à traiter ont subi la phase de thermolyse, on évacue alors gravitairement et séquentiellement les matières solides issues de la thermolyse en vue de leur récupération.When the waste to be treated has undergone the thermolysis phase, it is then removed by gravity and sequentially solids from thermolysis for recovery.
A ce sujet, rappelons que les produits gazeux issus de la thermolyse sont prélevés en continu tel qu'il a été précisé ci-dessus.In this regard, it should be recalled that the gaseous products resulting from thermolysis are withdrawn continuously as has been specified above.
La figure 1 montre un exemple d'installation de traitement de déchets urbains et/ou industriels, apte à mettre en oeuvre une réaction de thermolyse et conçue particulièrement pour la mise en oeuvre du procédé de l'invention qui vient d'être décrit.FIG. 1 shows an example of an installation for treating urban and / or industrial waste, capable of carrying out a thermolysis reaction and designed particularly for the implementation of the method of the invention which has just been described.
Elle comporte au moins une chambre de séchage (1), contrôlée et isolée, des déchets à traiter, une chambre de thermolyse (2) contrôlé et isolée, ainsi que des moyens (3, 4) de récupération des matières solides et des produits gazeux issus de la thermolyse.It comprises at least one drying chamber (1), controlled and isolated, waste to be treated, a thermolysis chamber (2) controlled and isolated, as well as means (3, 4) for recovering solid materials and gaseous products. from thermolysis.
En outre, pour autoriser un traitement en continu des déchets et pour permettre la mise en oeuvre des différentes étapes du procédé séquentiellement, la chambre de séchage (1), la chambre de thermolyse (2) et les moyens (3) de récupération des matières solides sont disposés avantageusement successivement en série de telle façon que l'on autorise un mouvement en continu, gravitaire séquentiel, des déchets et des matières contenues, de l'entrée de l'installation (5) vers sa sortie (6) et que l'on puisse conserver à chaque chambre (1, 2, 3) un fonctionnement stable en température et/ou en pression.In addition, to allow continuous processing of the waste and to allow the implementation of the different stages of the process sequentially, the drying chamber (1), the thermolysis chamber (2) and the means (3) for recovering the materials. solids are advantageously arranged successively in series in such a way as to allow a continuous, sequential gravity movement of the waste and the contained materials, from the inlet of the installation (5) to its outlet (6) and that the 'We can keep each chamber (1, 2, 3) stable operation in temperature and / or pressure.
Grâce à cette succession de chambres, on permet une alimentation en continu de l'installation et en séparant les différentes fonctions des chambres, on évite les chocs thermiques et les problèmes d'étanchéité par un fonctionnement stable de chacune des chambres.Thanks to this succession of chambers, a continuous supply of the installation is allowed and by separating the different functions of the chambers, thermal shocks and sealing problems are avoided by stable operation of each of the chambers.
La première phase du traitement proprement dit consiste donc en une phase de séchage ou de déshydratation des déchets.The first phase of the actual treatment therefore consists of a phase of drying or dehydration of the waste.
Cette phase est menée dans la chambre de séchage (1) dans laquelle les déchets sont brassés et soumis à un flux d'air chaud. En outre, on engendre un mouvement d'avance (7) des déchets de l'entrée (5) vers la sortie (8) de ladite chambre de séchage (1).This phase is carried out in the drying chamber (1) in which the waste is stirred and subjected to a flow of hot air. In addition, an advance movement (7) of the waste is generated from the inlet (5) to the outlet (8) of said drying chamber (1).
Dans un mode de réalisation de la présente invention, la chambre de séchage (1) est constituée par une enceinte (9) fermée, présentant une entrée (5) par laquelle on introduit les déchets à traiter et une sortie (8) de laquelle le produit déshydraté s'évacuera.In one embodiment of the present invention, the drying chamber (1) consists of an enclosure (9) closed, having an inlet (5) through which the waste to be treated is introduced and an outlet (8) from which the dehydrated product will drain out.
A l'intérieur de l'enceinte fermée (9) est prévu un tambour motorisé (10) apte à contenir les déchets à sécher et à les brasser en permanence, et également apte à créer ledit mouvement d'avance (7) pour les déchets de l'entrée (5) vers la sortie (8).Inside the closed enclosure (9) is provided a motorized drum (10) able to contain the waste to be dried and to brew it permanently, and also able to create said advance movement (7) for the waste from the inlet (5) to the outlet (8).
Pour obtenir la déshydratation des déchets, on les soumet à un flux d'air chaud, schématisé en (11) sur la figure. Aussi, selon l'invention, l'installation comporte des moyens (12, 13) pour créer une veine d'air chaud apte à circuler dans ladite enceinte de séchage (9).To obtain the dehydration of the waste, it is subjected to a flow of hot air, shown diagrammatically in (11) in the figure. Also, according to the invention, the installation comprises means (12, 13) for creating a stream of hot air able to circulate in said drying enclosure (9).
Comme le montre particulièrement la figure, la préparation de cet air chaud s'effectue dans un caisson de traitement (12) qui comporte un brûleur à gaz (13) et un système de soufflage (47) placé en amont du brûleur (13), et apte à diriger un flux gazeux vers la flamme dudit brûleur.As the figure particularly shows, the preparation of this hot air is carried out in a treatment box (12) which comprises a gas burner (13) and a blowing system (47) placed upstream of the burner (13), and able to direct a gas flow towards the flame of said burner.
Le circuit de séchage comporte également des moyens (48) pour récupérer le fluide gazeux issu du séchage de l'enceinte de séchage (9) ainsi que des moyens pour purifier ledit fluide gazeux issu du séchage.The drying circuit also includes means (48) for recovering the gaseous fluid resulting from the drying of the drying chamber (9) as well as means for purifying said gaseous fluid resulting from drying.
Ainsi, l'air chaud sec (11) introduit dans le sécheur absorbe, au contact des déchets brassés, l'humidité contenue dans ceux-ci et sort ainsi chargé d'humidité en (16).Thus, the hot dry air (11) introduced into the dryer absorbs, on contact with the stirred waste, the moisture contained in it and thus leaves charged with moisture in (16).
Cet air humide (16) récupéré par les moyens (48), traverse ensuite un échangeur condenseur (17) afin d'être déshumidifié et avant d'être recyclé vers les moyens (12, 13) pour créer ladite veine d'air chaud, au niveau de l'entrée (15) du caisson de traitement d'air (12) afin qu'il soit épuré.This moist air (16) recovered by the means (48) then passes through a condenser exchanger (17) in order to be dehumidified and before being recycled to the means (12, 13) to create said stream of hot air, at the inlet (15) of the air treatment box (12) so that it is purified.
En particulier, selon la présente invention, lesdits moyens pour créer la veine d'air chaud et pour purifier le fluide gazeux sont constitués substantiellement par le brûleur (13) et le système de soufflage (47).In particular, according to the present invention, said means for creating the stream of hot air and for purifying the gaseous fluid consist essentially of the burner (13) and the blowing system (47).
On prévoira un brûleur dont la flamme atteint avantageusement au moins 850°C et un système de soufflage dont les vitesses seront telles que lesdits gaz traverseront la flamme et seront maintenus à cette température pendant au moins deux secondes. Ainsi, on obtiendra une stérilisation des gaz qui seront donc épurés et les essences aromatiques qu'ils contenaient seront brûlées.A burner will be provided, the flame of which advantageously reaches at least 850 ° C. and a blowing system, the speeds of which will be such that the said gases will pass through the flame and will be maintained at this temperature for at least two seconds. Thus, a sterilization of the gases will be obtained which will therefore be purified and the aromatic essences which they contained will be burned.
Il est à noter que pour autoriser la combustion du brûleur à gaz (13), on prévoit une amenée d'air (14) provenant de l'extérieur. Aussi, étant donné que les gaz de sortie de séchoir sont recyclés vers le caisson (12), par l'intermédiaire d'une amenée des gaz (15) en amont du brûleur, il sera nécessaire d'évacuer une partie des gaz recyclés purifiés vers l'extérieur. Ces gaz excédentaires sont non polluants pour l'atmosphère.It should be noted that to allow the combustion of the gas burner (13), an air supply (14) from the outside is provided. Also, since the dryer outlet gases are recycled to the box (12), via a gas supply (15) upstream of the burner, it will be necessary to evacuate part of the purified recycled gases outwards. These excess gases are non-polluting for the atmosphere.
A ce sujet, il est à noter que l'on prévoira avantageusement un jeu de batteries de récupération (18) installées sur l'évacuation des gaz excédentaires haute température (19) et l'amenée d'air extérieur (20) afin de permettre de réchauffer cet air avant aspiration par le brûleur (13). Ceci permettra en outre une récupération d'énergie appréciable.In this regard, it should be noted that there will advantageously be a set of recovery batteries (18) installed on the discharge of high temperature excess gases (19) and the supply of outside air (20) in order to allow to heat this air before suction by the burner (13). This will also allow significant energy recovery.
Un clapet (50), installé sur l'évacuation des gaz excédentaires haute température (19), avant la batterie de récupération (18), permettra le réglage du volume d'air en entrée par rapport au volume d'air en sortie.A valve (50), installed on the discharge of high temperature excess gases (19), before the recovery battery (18), will allow the adjustment of the volume of air entering compared to the volume of air leaving.
En outre, pour favoriser le séchage, selon la présente invention, le sens de circulation du flux d'air chaud (11) est contraire audit mouvement d'avance (7) des déchets dans le sécheur. Pour ce, on place le tambour (10) dans ladite veine d'air chaud et l'on prévoit sa rotation et sa disposition afin que l'air chaud soit introduit à contrecourant dans le sécheur.In addition, to promote drying, according to the present invention, the direction of circulation of the hot air flow (11) is opposite to said advance movement (7) of the waste in the dryer. For this, the drum (10) is placed in said stream of hot air and provision is made for its rotation and its arrangement so that the hot air is introduced countercurrently into the dryer.
Plus précisément, ledit tambour (10) est disposé horizontalement avec son axe de rotation incliné pour permettre un déplacement (7) des déchets de l'entrée (5) vers la sortie (8) du sécheur. En outre, pour favoriser ce mouvement, le tambour (10) comportera intérieurement des pales (49) fixées sur ce dernier.More specifically, said drum (10) is arranged horizontally with its inclined axis of rotation to allow movement (7) of the waste from the inlet (5) to the outlet (8) of the dryer. In addition, to promote this movement, the drum (10) will internally have blades (49) fixed on the latter.
Cela étant, à la suite de cette phase de séchage, selon la présente invetnion, on mène la réaction de thermolyse proprement dite dans la chambre de thermolyse (2).However, following this drying phase, according to the present invention, the actual thermolysis reaction is carried out in the thermolysis chamber (2).
Selon le mode de réalisation illustré, cette chambre de thermolyse (2) est constituée par un réacteur double enveloppe présentant une enceinte primaire (21) intérieure, fixe, dans laquelle sont introduits les déchets, et par une enceinte secondaire de chauffage (22) extérieure, fixe, enveloppant ladite enceinte primaire (21).According to the illustrated embodiment, this thermolysis chamber (2) is constituted by a double jacket reactor having an internal primary enclosure (21), fixed, into which the waste is introduced, and by a secondary external heating enclosure (22), fixed, enveloping said primary enclosure (21).
A l'intérieur du réacteur (2) est prévu un rotor (23) motorisé équipé de palettes (24) orientées et fixées sur un axe central commandé par un moteur (25).Inside the reactor (2) is provided a motorized rotor (23) equipped with paddles (24) oriented and fixed on a central axis controlled by a motor (25).
La disposition des palettes ainsi que la rotation de celles-ci engendrent un déplacement des déchets ou des matières solides, schématisé par la flèche (26) de l'entrée (8) de la chambre de thermolyse (2) vers sa sortie (27).The arrangement of the pallets as well as the rotation of these generate a displacement of waste or solid matter, shown diagrammatically by the arrow (26) from the inlet (8) of the thermolysis chamber (2) towards its outlet (27) .
Dans le mode de réalisation proposé, la chambre de thermolyse est horizontale ; néanmoins, d'autres dispositions pourraient être envisagées, le rotor pouvant être en oblique, voire même vertical. De même, on a prévu une enceinte fixe et un rotor tournant mais bien entendu, on pourrait imaginer un système inverse dans lequel ce serait l'enceinte qui tournerait.In the proposed embodiment, the thermolysis chamber is horizontal; nevertheless, other arrangements could be envisaged, the rotor possibly being oblique, or even vertical. Likewise, a fixed enclosure and a rotating rotor are provided, but of course, one could imagine a reverse system in which the enclosure would turn.
La mise en température des déchets est notamment assurée par les gaz de combustion d'un brûleur (28), de type mixte fioul - gaz par exemple, circulant dans ladite enceinte secondaire (22) qui entoure l'enceinte primaire (21).The waste is heated up in particular by the combustion gases from a burner (28), of the mixed fuel oil - gas type for example, circulating in said secondary enclosure (22) which surrounds the primary enclosure (21).
Cette circulation de gaz haute température autorise notamment l'élévation de température à l'intérieur de l'enceinte (21) du réacteur de l'ordre de 400 à 450°C.This circulation of high temperature gas allows in particular the rise in temperature inside the enclosure (21) of the reactor of the order of 400 to 450 ° C.
A la sortie (29) de l'enceinte secondaire (22), les gaz schématisés en (30) sur la figure sont réinjectés dans le circuit de séchage, tel que décrit ci-dessus, participant ainsi à la récupération d'énergie. Ces gaz sont notamment réinjectés à l'entrée (15) du caisson (12).At the outlet (29) of the secondary enclosure (22), the gases shown diagrammatically at (30) in the figure are reinjected into the drying circuit, as described above, thus participating in energy recovery. These gases are in particular reinjected at the inlet (15) of the box (12).
Aussi, une telle disposition permet la récupération des gaz de chauffage mettant en température la chambre de thermolyse, récupération qui s'effectue en circuit fermé par rapport à l'atmosphère. Ensuite ces gaz sont également soumis à une étape de purification comme cela l'était pour les gaz de séchage.Also, such an arrangement allows recovery heating gases which heat the thermolysis chamber, recovery which takes place in a closed circuit with respect to the atmosphere. Then these gases are also subjected to a purification step as it was for the drying gases.
Une partie de ces gaz purifiés est réinjectée dans l'installation, comme agent de séchage, et on évacue les gaz excédentaires non polluants vers l'extérieur.Part of these purified gases is reinjected into the installation, as a drying agent, and the non-polluting excess gases are discharged to the outside.
En outre, selon l'invention, les chambres de séchage (1) et de thermolyse (2) sont superposées, comme le montre notamment la figure 1, de façon à ce que le chargement puisse se produire gravitairement. Néanmoins, on pourrait envisager de placer les chambres (1) et (2) côte à côte et effectuer le chargement au moyen de convoyeurs élévateurs.In addition, according to the invention, the drying (1) and thermolysis (2) chambers are superimposed, as shown in particular in FIG. 1, so that loading can occur by gravity. However, one could consider placing the chambers (1) and (2) side by side and carry out the loading by means of elevating conveyors.
Entre la sortie de la chambre de séchage (1) et l'entrée de la chambre de thermolyse (2), on dispose un sas (31) apte à relier les deux chambres de façon étanche, ainsi on pourra introduire les déchets dans la chambre de thermolyse (2) en continu par l'intermédiaire dudit sas (31) afin d'une part d'équilibrer les pressions entre les deux enceintes et d'autre part, d'autoriser une neutralisation du produit entrant, notamment par injection d'azote ou mise en équilibre de pression préalable avant ouverture de la porte intérieure du sas, ou autre.Between the outlet of the drying chamber (1) and the inlet of the thermolysis chamber (2), there is an airlock (31) capable of connecting the two chambers in a sealed manner, so the waste can be introduced into the chamber thermolysis (2) continuously via said airlock (31) in order on the one hand to balance the pressures between the two enclosures and on the other hand, to authorize a neutralization of the incoming product, in particular by injection of nitrogen or pressure balance before opening the interior door of the airlock, or other.
De même, au niveau de la sortie (27) de la chambre de thermolyse, on dispose un autre sas (32) reliant également de façon étanche la chambre de thermolyse et les moyens de récupération des matières solides (3).Similarly, at the outlet (27) of the thermolysis chamber, there is another airlock (32) also sealingly connecting the thermolysis chamber and the means for recovering solid materials (3).
Le but de ce second sas (32) est similaire au premier pour ce qui concerne l'évacuation des matières solides issues de la thermolyse.The purpose of this second airlock (32) is similar to the first with regard to the evacuation of solids from thermolysis.
Cela étant, pendant la phase de thermolyse, les déchets sont brassés à l'intérieur de l'enceinte (21) du réacteur par le rotor (23-25). On définit en outre, grâce aux pales (24), un mouvement d'avance (26) de la matière contenue dans la chambre (2), de son entrée (8) vers sa sortie (27).However, during the thermolysis phase, the waste is stirred inside the enclosure (21) of the reactor by the rotor (23-25). In addition, the blades (24) define an advance movement (26) of the material contained in the chamber (2), from its inlet (8) to its outlet (27).
Tout au long de la thermolyse, selon le procédé de la présente invention, on récupère et on traite les produits gazeux issus de la réaction de thermolyse dans des circuits fermés (33) par rapport à l'atmosphère tels que notamment illustrés à la figure 2.Throughout the thermolysis, according to the process of the present invention, the gaseous products resulting from the thermolysis reaction are recovered and treated in closed circuits (33) relative to the atmosphere as particularly illustrated in FIG. 2 .
Le circuit fermé (33) constitue substantiellement lesdits moyens (4) de récupération des produits gazeux issus de la thermolyse et sont aptes à séparer les éléments combustibles des goudrons à l'état gazeux, par lavage des gaz combustibles, en vue de leur utilisation ultérieure dans ledit procédé.The closed circuit (33) substantially constitutes said means (4) for recovering gaseous products resulting from thermolysis and are capable of separating the fuel elements from the tars in the gaseous state, by washing the combustible gases, with a view to their subsequent use. in said method.
Plus précisément, ces moyens (4) sont constitués par un circuit fermé (33) comprenant au moins un dispositif de mise en circulation desdits produits gazeux tel qu'un dispositif d'extraction mécanique (34), un séparateur (35) "élément gazeux combustible - goudron à l'état gazeux", de type pulvérisateur, un circuit (36) d'épuration des gaz, dans lequel on sépare les gouttelettes du gaz avant son stockage, ainsi qu'un circuit (37) de traitement des effluents liquides.More precisely, these means (4) consist of a closed circuit (33) comprising at least one device for circulating said gaseous products such as a mechanical extraction device (34), a separator (35) "gaseous element fuel - tar in gaseous state ", of sprayer type, a gas purification circuit (36) in which the gas droplets are separated before its storage, as well as a circuit (37) for treating liquid effluents .
En sortie du réacteur de thermolyse (2), compte tenu de la température à laquelle est menée la réaction, il se produit un mélange des éléments gazeux combustibles et des goudrons à l'état gazeux. Ces gaz sont évacués sous pression ou par balayage du gaz. En outre, certains éléments solides pulvérulents peuvent être aussi entraînés.At the outlet of the thermolysis reactor (2), taking into account the temperature at which the reaction is carried out, there is a mixture of the combustible gaseous elements and of the tars in the gaseous state. These gases are removed under pressure or by sweeping the gas. In addition, certain powdery solid elements can also be entrained.
Tel que le montre la figure 2, le principe de séparation des gaz combustibles et des goudrons en sortie de réacteur s'effectue par voie humide à l'aide du séparateur (35) de type pulvérisateur généralement connu sous l'appellation de "quench à l'eau".As shown in FIG. 2, the principle of separation of combustible gases and tars leaving the reactor is carried out by the wet method using the separator (35) of the sprayer type generally known under the name of "quench at the water".
Dans ce séparateur, sous l'effet de la pulvérisation à basse température et à contre-courant, on sépare la partie gazeuse et on condense les goudrons dans la partie basse (38) du séparateur.In this separator, under the effect of spraying at low temperature and against the current, the gaseous part is separated and the tars are condensed in the lower part (38) of the separator.
Par contre, les éléments gazeux, produits par la réaction de thermolyse, s'échappent par le haut (39) du séparateur, le dispositif d'extraction (34) permettant de vaincre les pertes de charge du circuit. Ces gaz sont combustibles et sont ensuite épurés et stockés dans des réservoirs sous pression avant d'être réutilisés par les brûleurs de l'installation.On the other hand, the gaseous elements produced by the thermolysis reaction escape through the top (39) of the separator, the extraction device (34) making it possible to overcome the pressure drops in the circuit. These gases are combustible and are then purified and stored in pressure tanks before being reused by the installation's burners.
En ce qui concerne le traitement des effluents liquides, condensés à la partie inférieure (38) du séparateur (35), il se présente sous deux composants, à savoir une phase aqueuse et des goudrons proprement dits.As regards the treatment of liquid effluents, condensed at the lower part (38) of the separator (35), it comes in two components, namely an aqueous phase and tars themselves.
Pour séparer ces deux éléments, on opère par décantation étant donné leur densité très différente, par exemple respectivement 0,99 et 0,77.To separate these two elements, one operates by decantation given their very different density, for example 0.99 and 0.77 respectively.
Cette décantation est menée dans le circuit de traitement (37) dans lequel la phase légère est récupérée en continu par un tambour oléophile, puis détachée du tambour à l'aide d'un racleur qui l'envoie dans une petite capacité tampon (40), chauffée par un serpentin interne, afin d'abaisser la viscosité du mélange organique.This decantation is carried out in the treatment circuit (37) in which the light phase is continuously recovered by an oleophilic drum, then detached from the drum using a scraper which sends it in a small buffer capacity (40) , heated by an internal coil, in order to lower the viscosity of the organic mixture.
Ce mélange est ensuite repris par une pompe à engrenage puis stocké dans un bac de stockage des goudrons (41) avant d'être réexpédié ou traité.This mixture is then taken up by a gear then stored in a tar storage tank (41) before being redirected or treated.
La phase aqueuse lourde est reprise en fond de bassin de décantation (37) par une pompe centrifuge (42) puis clarifiée sur des filtres (43) destinés à éliminer les particules solides telles que poussières. La purge de décantation est ensuite purifiée de tout composé organique par passage sur charbon actif (44) puis rejetée dans le bassin d'eaux résiduaires.The heavy aqueous phase is taken up at the bottom of the settling tank (37) by a centrifugal pump (42) then clarified on filters (43) intended to remove solid particles such as dust. The decantation purge is then purified of any organic compound by passage over active carbon (44) and then discharged into the wastewater basin.
En outre, pendant le traitement des effluents liquides, le liquide de lavage, utilisé dans le séparateur (35) de type pulvérisateur, est recyclé, maintenu à basse température sur la boucle. La neutralisation en ligne du chlore contenu dans le circuit des gaz se fait par injection de soude (45) dans l'eau du "Quench". Le circuit est purgé régulièrement pour être envoyé vers les bassins de décantation (37).In addition, during the treatment of the liquid effluents, the washing liquid, used in the separator (35) of the sprayer type, is recycled, kept at low temperature on the loop. The on-line neutralization of the chlorine contained in the gas circuit is done by injection of soda (45) in the water of the "Quench". The circuit is purged regularly to be sent to the settling tanks (37).
Si les produits gazeux issus de la thermolyse sont prélevés en continu au coeur du réacteur, selon la présente invention, on évacue gravitairement et séquentiellement les matières solides issues de la thermolyse. Cette évacuation est, rappelons-le, effectuée par l'intermédiaire du sas (32) qui permet de maintenir une ambiance contrôlée à l'intérieur du réacteur (2).If the gaseous products resulting from thermolysis are taken continuously from the reactor core, according to the present invention, the solids resulting from thermolysis are removed by gravity and sequentially. This evacuation is, let us recall, carried out by means of the airlock (32) which makes it possible to maintain a controlled atmosphere inside the reactor (2).
Comme le montre notamment la figure 1, dans le cas de l'installation décrite, la chambre de thermolyse (2) et les moyens de récupération (3) sont superposés, ces derniers étant notamment constitués par un conteneur (46) adapté sous ledit sas (32). Néanmoins, il pourrait également être envisageable de les déposer côte à côte avec un convoyeur élévateur entre eux.As shown in particular in Figure 1, in the case of the installation described, the thermolysis chamber (2) and the recovery means (3) are superimposed, the latter being in particular constituted by a container (46) adapted under said airlock (32). However, it could also be possible to place them side by side with a lifting conveyor between them.
Dans ce conteneur (46) sera menée une phase de refroidissement des résidus solides issus de la thermolyse, tels que charbons ou inertes, ceux-ci étant récupérés par le dessous du réacteur (2) via le sas (32), notamment neutralisé par injection d'azote.In this container (46) a phase of cooling of solid residues from thermolysis, such as coals or inert materials, these being recovered from below the reactor (2) via the airlock (32), in particular neutralized by nitrogen injection.
On utilise avantageusement un conteneur (46) mobile, étanche, à double enveloppe, dans laquelle de l'eau froide est mise en circulation afin d'accélérer le refroidissement du produit.Advantageously, a mobile, sealed, double-envelope container (46) is used, in which cold water is circulated in order to accelerate the cooling of the product.
Dès que la température à l'intérieur du conteneur (46) atteint environ 50°C, celui-ci peut alors être ouvert sans risque d'explosion pour récupérer les produits qu'il contient.As soon as the temperature inside the container (46) reaches about 50 ° C, it can then be opened without risk of explosion to recover the products it contains.
On disposera avantageusement d'un dispositif de manutention avec tambour magnétique pour éliminer les matériaux ferreux et un crible à tamis vibrant pour isoler les parties inertes des carbones. L'ensemble de ces équipements sera notamment prévu sous capot étanche afin de limiter les poussières de carbone et leur expansion dans l'atmosphère.Advantageously, there will be a handling device with a magnetic drum to remove ferrous materials and a vibrating screen to isolate the inert parts of the carbon. All of this equipment will be provided in particular under a sealed hood in order to limit carbon dust and its expansion in the atmosphere.
Par ailleurs, pour ce qui est de l'approvisionnement de l'installation de la présente invention, au niveau de l'entrée (5) des déchets, celui-ci s'effectuera par des moyens traditionnels et connus dans le domaine du traitement des déchets urbains et/ou industriels.Furthermore, as regards the supply of the installation of the present invention, at the level of the waste inlet (5), this will be carried out by traditional means and known in the field of treatment of urban and / or industrial waste.
Par exemple, les déchets urbains sont approvisionnés dans une fosse principale ayant une autonomie de plusieurs jours de fonctionnement, mais sans toutefois être exagérée de façon à minimiser les dégagements d'odeurs.For example, urban waste is supplied in a main pit with an autonomy of several days of operation, but without however being exaggerated so as to minimize the release of odors.
En outre, le volume aérien situé au-dessus du stockage est maintenu en dépression par un ensemble de ventilation mécanique.In addition, the air volume located above the repository is maintained in depression by a mechanical ventilation assembly.
On prévoira également un pont roulant équipé d'un grappin pour réaliser le transfert des déchets de la fosse principale vers une trémie depuis laquelle un ensemble de tapis roulants distribuera les déchets vers un ensemble de broyage.There will also be an overhead crane equipped with a grapple to transfer waste from the main pit to a hopper from which a set of conveyor belts will distribute the waste to a grinding set.
Sur cette chaîne de transport, on prévoit par exemple d'une part un tri permettant d'évacuer les objets encombrants et d'autre part un ensemble de déchirage des sacs plastiques, notamment par peigne métallique, situé dans un tunnel assurant un premier éclatement de l'ensemble du produit brut.On this transport chain, for example, provision is made, on the one hand, for sorting for removing bulky objects and, on the other hand, for tearing apart plastic bags, in particular by metal comb, located in a tunnel ensuring a first burst of the whole gross product.
Les déchets ainsi préparés sont acheminés alors sur un broyeur permettant l'ultime transformation physique du produit brut avant traitement. Le broyage permettra de déchiqueter les ordures ménagères en éléments suffisamment petits de façon à faciliter la technique de séchage décrite précédemment.The waste thus prepared is then conveyed on a crusher allowing the ultimate physical transformation of the raw product before treatment. The grinding will shred household waste into sufficiently small elements so as to facilitate the drying technique described above.
Enfin, un ensemble de convoyeur à bande reprend depuis la sortie du broyeur les déchets ainsi traités pour les stocker dans une trémie d'une capacité telle qu'elle puisse alimenter en continu la chambre de séchage (1) de la présente invention.Finally, a belt conveyor assembly takes up the waste thus treated from the mill outlet to store it in a hopper with a capacity such that it can continuously supply the drying chamber (1) of the present invention.
Les moyens de traitement des produits gazeux issus de la thermolyse qui viennent d'être décrits seront notamment adaptés en fonction des conditions dans lesquelles est menée la réaction de thermolyse, à savoir sous pression atmosphérique ou sous balayage de CO2 ou en surpression particulièrement pour autoriser dans les différents circuits de traitement la circulation des différents produits.The means for treating the gaseous products resulting from thermolysis which have just been described will in particular be adapted as a function of the conditions under which the thermolysis reaction is carried out, namely under atmospheric pressure or under CO 2 sweeping or under overpressure particularly to allow in the different processing circuits the circulation of the different products.
Naturellement, d'autres mises en oeuvre de la présente invention, à la portée de l'Homme de l'Art, auraient pu être envisagées sans pour autant sortir du cadre de la présente invention.Naturally, other implementations of the present invention, within the reach of those skilled in the art, could have been envisaged without departing from the scope of the present invention.
Claims (17)
- on déshydrate préalablement les déchets à traiter dans une enceinte fermée de séchage (1),
- on récupère les gaz (16) produits lors du séchage en circuit fermé par rapport à l'atmosphère, et on soumet ces gaz à une étape de purification (17, 12),
- on réinjecte au moins en partie lesdits gaz purifiés (11) dans l'installation comme agents de séchage et on évacue les gaz excédentaires non polluants vers l'extérieur.1. Process for treating urban and / or industrial waste, by which the waste is subjected to a thermolysis reaction, characterized in that:
- the waste to be treated is previously dehydrated in a closed drying enclosure (1),
- the gases (16) produced during drying in a closed circuit with respect to the atmosphere are recovered, and these gases are subjected to a purification step (17, 12),
- Said purified gases (11) are at least partially reinjected into the installation as drying agents and the non-polluting excess gases are discharged to the outside.
- on mène la réaction de thermolyse à basse température, de l'ordre de 400 à 450°C dans une chambre de thermolyse (2) isolée et contrôlée,
- on récupère et on traite les produits gazeux issus de la réaction de thermolyse, dans des circuits fermés (4, 33) par rapport à l'atmosphère, dans lesquels on sépare les éléments gazeux combustibles des goudrons à l'état gazeux, puis on épure les gaz combustibles en vue de leur utilisation ultérieure dans ledit procédé.2. Treatment method according to claim 1, characterized in that:
the thermolysis reaction is carried out at low temperature, of the order of 400 to 450 ° C in a thermolysis chamber (2) isolated and controlled,
- the gaseous products resulting from the thermolysis reaction are recovered and treated, in closed circuits (4, 33) relative to the atmosphere, in which the combustible gaseous elements are separated from the tars in the gaseous state, then purifies the combustible gases with a view to their subsequent use in said process.
- on établit la température dans la chambre de thermolyse (2), indirectement par rapport aux déchets à traiter, par circulation de gaz de chauffage haute température,
- on récupère cesdits gaz de chauffage (30), en circuit fermé par rapport à l'atmosphère, et on soumet ces gaz (30) à une étape de purification,
- on réinjecte au moins en partie lesdits gaz purifiés dans l'installation comme agent de séchage (11) et on évacue les gaz excédentaires non polluants vers l'extérieur.3. Treatment method according to claim 2, characterized in that:
the temperature in the thermolysis chamber (2) is established, indirectly with respect to the waste to be treated, by circulation of high temperature heating gas,
- These heating gases (30) are recovered, in a closed circuit with respect to the atmosphere, and these gases (30) are subjected to a purification stage,
- Said purified gases are at least partially reinjected into the installation as a drying agent (11) and the non-polluting excess gases are discharged to the outside.
- on introduit gravitairement et séquentiellement les déchets ainsi déshydratés dans une chambre de thermolyse (2), isolée et contrôlée, dans laquelle on mène la réaction de thermolyse à basse température,
- on évacue gravitairement et séquentiellement les matières solides issues de la thermolyse et on prélève en continu les produits gazeux issus de la thermolyse.5. Treatment method according to claim 2, characterized in that:
the waste thus dehydrated is introduced gravitatively and sequentially into a thermolysis chamber (2), isolated and controlled, in which the thermolysis reaction is carried out at low temperature,
- The solid materials from the thermolysis are removed by gravity and sequentially and the gaseous products from the thermolysis are taken continuously.
- une chambre de séchage (1) des déchets à traiter, constituée par une enceinte fermée (9),
- des moyens (12, 13, 47) pour créer une veine d'air chaud apte à circuler dans ladite enceinte de séchage (9),
- des moyens (48) pour récupérer le fluide gazeux issu du séchage de l'enceinte de séchage (9),
- des moyens (17, 13) pour purifier ledit fluide gazeux issu du séchage.9. Installation for treating urban and / or industrial waste, capable of carrying out a thermolysis reaction, designed for implementing the method according to claim 1, characterized in that it comprises at least:
- a drying chamber (1) of the waste to be treated, constituted by a closed enclosure (9),
- means (12, 13, 47) for creating a stream of hot air able to circulate in said drying enclosure (9),
means (48) for recovering the gaseous fluid resulting from the drying of the drying chamber (9),
- Means (17, 13) for purifying said gaseous fluid resulting from drying.
- une chambre de thermolyse (2), contrôlée et isolée, constituée par un réacteur double enveloppe présentant une enceinte primaire (21), dans laquelle sont introduits les déchets, et une enceinte secondaire de chauffage (22), apte à élever au moins la température de l'enceinte primaire (21) pour mener la réaction de thermolyse,
- des moyens (3, 4) de récupération des matières solides et de récupération et de traitement des produits gazeux issus de la thermolyse.12. Treatment installation according to claim 9, characterized in that it comprises:
- a thermolysis chamber (2), controlled and insulated, constituted by a double jacket reactor having a primary enclosure (21), into which the waste is introduced, and a secondary heating enclosure (22), capable of raising at least the temperature of the primary enclosure (21) for carrying out the thermolysis reaction,
- Means (3, 4) for recovering solids and recovering and treating gaseous products from thermolysis.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89403348T ATE93883T1 (en) | 1989-11-07 | 1989-12-04 | PROCESS AND PLANT FOR TREATMENT OF MUNICIPAL AND INDUSTRIAL WASTE. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8915065A FR2654112B1 (en) | 1989-11-07 | 1989-11-07 | METHOD AND PLANT FOR TREATING URBAN AND / OR INDUSTRIAL WASTE. |
FR8915065 | 1989-11-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0426925A1 true EP0426925A1 (en) | 1991-05-15 |
EP0426925B1 EP0426925B1 (en) | 1993-09-01 |
Family
ID=9387471
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89403348A Expired - Lifetime EP0426925B1 (en) | 1989-11-07 | 1989-12-04 | Process and installation for the treatment of municipal and industrial wastes |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0426925B1 (en) |
AT (1) | ATE93883T1 (en) |
DE (2) | DE426925T1 (en) |
ES (1) | ES2027217T3 (en) |
FR (1) | FR2654112B1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0505278A1 (en) * | 1991-03-20 | 1992-09-23 | Societe Francaise De Thermolyse | System for the treatment by thermolyses of solid products whose disposal is damaging to the environment |
EP0522919A1 (en) * | 1991-07-09 | 1993-01-13 | Institut Français du Pétrole | Process and installation for the thermolysis of industrial and/or domestic waste |
FR2679009A1 (en) * | 1991-07-09 | 1993-01-15 | Inst Francais Du Petrole | METHOD AND DEVICE FOR PROCESSING DIRECT CONTACT WASTE. |
WO2000017288A1 (en) * | 1998-09-23 | 2000-03-30 | Hartwig Streitenberger | Method and device for processing waste products and recrements |
WO2001009267A1 (en) | 1999-08-03 | 2001-02-08 | Harald Martin | Method and device for removing recoverable waste products and non-recoverable waste products |
US6735814B2 (en) | 2000-10-05 | 2004-05-18 | Mister Services, Inc. | Apparatus for cleaning hard-to-reach areas |
US7000780B1 (en) | 1999-08-03 | 2006-02-21 | Harald Martin | Method and device for drying, separating, classifying and decomposing recoverable waste products |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010049379A1 (en) | 2010-10-26 | 2012-04-26 | Mioba Mitteldeutscher Industrie-Ofenbau Gmbh & Co. Kg | Device useful for continuous energetic recycling of solid waste, comprises material supply device with sealing device, drying zone, smoldering zone, coke discharge device, incinerating screw and thermal post-combustion device |
DE102012004632B4 (en) * | 2012-03-06 | 2017-09-14 | Ulrich Finger | CUP reactor for the gasification of biomass, for the production of electricity and heat |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2842126A1 (en) * | 1978-09-28 | 1980-04-10 | Anlagen Leasing Service | Refuse pyrolysis reactor drum - with internal spiral ribs of decreasing pitch and adjustable inclination |
DE2855510B1 (en) * | 1978-12-22 | 1980-04-17 | Peter Voelskow | Process and plant for the thermal utilization of waste |
DE2950324A1 (en) * | 1979-12-14 | 1981-07-02 | Rolf Dipl.-Ing. 4005 Büderich Berghoff | Solid fuel prodn. from waste materials - by low-temp. pyrolysis |
DE3018572A1 (en) * | 1980-05-14 | 1981-11-19 | Deutsche Kommunal-Anlagen Miete GmbH, 8000 München | Pyrolysis oven for domestic rubbish - uses burner fed with pyrolysis gases and separately controlled heating chambers |
GB2215716A (en) * | 1988-03-19 | 1989-09-27 | Uk Nii Metallov | Process and apparatus for thermal processing of noncompostable domestic waste. |
-
1989
- 1989-11-07 FR FR8915065A patent/FR2654112B1/en not_active Expired - Lifetime
- 1989-12-04 DE DE198989403348T patent/DE426925T1/en active Pending
- 1989-12-04 AT AT89403348T patent/ATE93883T1/en not_active IP Right Cessation
- 1989-12-04 DE DE89403348T patent/DE68908890T2/en not_active Expired - Lifetime
- 1989-12-04 EP EP89403348A patent/EP0426925B1/en not_active Expired - Lifetime
- 1989-12-04 ES ES89403348T patent/ES2027217T3/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2842126A1 (en) * | 1978-09-28 | 1980-04-10 | Anlagen Leasing Service | Refuse pyrolysis reactor drum - with internal spiral ribs of decreasing pitch and adjustable inclination |
DE2855510B1 (en) * | 1978-12-22 | 1980-04-17 | Peter Voelskow | Process and plant for the thermal utilization of waste |
DE2950324A1 (en) * | 1979-12-14 | 1981-07-02 | Rolf Dipl.-Ing. 4005 Büderich Berghoff | Solid fuel prodn. from waste materials - by low-temp. pyrolysis |
DE3018572A1 (en) * | 1980-05-14 | 1981-11-19 | Deutsche Kommunal-Anlagen Miete GmbH, 8000 München | Pyrolysis oven for domestic rubbish - uses burner fed with pyrolysis gases and separately controlled heating chambers |
GB2215716A (en) * | 1988-03-19 | 1989-09-27 | Uk Nii Metallov | Process and apparatus for thermal processing of noncompostable domestic waste. |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0505278A1 (en) * | 1991-03-20 | 1992-09-23 | Societe Francaise De Thermolyse | System for the treatment by thermolyses of solid products whose disposal is damaging to the environment |
FR2674149A1 (en) * | 1991-03-20 | 1992-09-25 | Chaussonnet Pierre | SYSTEM FOR THE THERMOLYSIS TREATMENT, IN TOTAL ABSENCE OF OXYGEN SOLID PRODUCTS WHICH REJECTION IS PREJUDICABLE TO THE ENVIRONMENT. |
WO1992016599A1 (en) * | 1991-03-20 | 1992-10-01 | Societe Française De Thermolyse | System for the treatment by thermolysis of solid products whose rejection is harmful to the environment |
EP0524847A1 (en) * | 1991-07-09 | 1993-01-27 | Institut Français du Pétrole | Process and apparatus for waste treatment by direct contact |
FR2679009A1 (en) * | 1991-07-09 | 1993-01-15 | Inst Francais Du Petrole | METHOD AND DEVICE FOR PROCESSING DIRECT CONTACT WASTE. |
FR2678850A1 (en) * | 1991-07-09 | 1993-01-15 | Inst Francais Du Petrole | PROCESS AND INSTALLATION OF THERMOLYSIS OF INDUSTRIAL AND / OR HOUSEHOLD WASTE. |
EP0522919A1 (en) * | 1991-07-09 | 1993-01-13 | Institut Français du Pétrole | Process and installation for the thermolysis of industrial and/or domestic waste |
US5505822A (en) * | 1991-07-09 | 1996-04-09 | Institut Francais Du Petrole | Process and device for treating waste by direct contact |
US5616216A (en) * | 1991-07-09 | 1997-04-01 | Institut Francais Du Petrole | Process and device for treating waste by direct contact |
WO2000017288A1 (en) * | 1998-09-23 | 2000-03-30 | Hartwig Streitenberger | Method and device for processing waste products and recrements |
WO2001009267A1 (en) | 1999-08-03 | 2001-02-08 | Harald Martin | Method and device for removing recoverable waste products and non-recoverable waste products |
US7000780B1 (en) | 1999-08-03 | 2006-02-21 | Harald Martin | Method and device for drying, separating, classifying and decomposing recoverable waste products |
US7147681B1 (en) | 1999-08-03 | 2006-12-12 | Harald Martin | Method and device for removing recoverable waste products and non-recoverable waste products |
US6735814B2 (en) | 2000-10-05 | 2004-05-18 | Mister Services, Inc. | Apparatus for cleaning hard-to-reach areas |
Also Published As
Publication number | Publication date |
---|---|
ES2027217T1 (en) | 1992-06-01 |
FR2654112B1 (en) | 1993-12-17 |
ES2027217T3 (en) | 1994-01-16 |
ATE93883T1 (en) | 1993-09-15 |
EP0426925B1 (en) | 1993-09-01 |
DE68908890T2 (en) | 1994-04-28 |
DE426925T1 (en) | 1992-11-26 |
FR2654112A1 (en) | 1991-05-10 |
DE68908890D1 (en) | 1993-10-07 |
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