EP0472008A2 - Particle filter regenerable by combustion for exhaust gases of internal combustion engine - Google Patents
Particle filter regenerable by combustion for exhaust gases of internal combustion engine Download PDFInfo
- Publication number
- EP0472008A2 EP0472008A2 EP91112672A EP91112672A EP0472008A2 EP 0472008 A2 EP0472008 A2 EP 0472008A2 EP 91112672 A EP91112672 A EP 91112672A EP 91112672 A EP91112672 A EP 91112672A EP 0472008 A2 EP0472008 A2 EP 0472008A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter
- exhaust gas
- housing
- filter material
- candles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 title claims abstract description 23
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 9
- 239000007789 gas Substances 0.000 title description 36
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000004140 cleaning Methods 0.000 claims abstract description 4
- 230000008929 regeneration Effects 0.000 claims description 11
- 238000011069 regeneration method Methods 0.000 claims description 11
- 239000004071 soot Substances 0.000 description 13
- 238000001802 infusion Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 241000722921 Tulipa gesneriana Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/0212—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters with one or more perforated tubes surrounded by filtering material, e.g. filter candles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0226—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being fibrous
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/10—Fibrous material, e.g. mineral or metallic wool
Definitions
- the invention relates to a particle filter for cleaning the exhaust gas of internal combustion engines with filter cartridges, which are arranged in a housing provided with an inlet chamber and an outlet funnel between holding plates and are formed from a support tube provided with exhaust gas passage openings and covered with filter material, and which also provide heat from a heat source is supplied for regeneration by free burning.
- Particle filters of this type are required for cleaning exhaust gases from internal combustion engines, in particular in vehicles which are operated with diesel fuel, in order to filter out the soot particles, which are harmful to health and represent a high and dangerous environmental impact.
- the exhaust gas is filtered as it flows through a ceramic block (monolith) which has a large number of through channels, of which one channel is closed like a chessboard and one channel is closed on the outlet side, so that the exhaust gas flows into one channel, then through the surrounding monolith section acting as a filter flows into the adjacent channel and leaves it, freed from soot particles.
- a soot filter describes e.g. DE-OS 32 17 357.
- filter cartridges for particle filtering are preferably designed as a wound filter.
- a support tube provided with exhaust gas passage openings wrapped in multiple layers with filter material threads, so that an element comparable to a textile yarn spool is produced.
- Such an arrangement shows, for example, DE-OS 38 15 148 with a special representation of the storage of the filter candles in holding plates.
- the filter candles can also be formed by a hose cover made of filter material via a support tube according to DE-OS 38 23 205.
- the filter candles are flowed through from the outside in, the exhaust gas to be cleaned enters the support tubes through the filter material, which are closed on the inlet side, the soot particles are retained when the wound filter material flows through, and the cleaned exhaust gas flows through the support tubes into the outlet funnel and is released by dissipated there.
- the filter cartridges are arranged on concentric circles in the filter housing and are of a uniform design. Instead of the holding plate on the inlet side provided with exhaust gas passage openings, a holding grille can also be arranged.
- sooting occurs when it flows through the particle filter, ie the filter material becomes increasingly clogged with soot particles and the soot has to be removed after a relatively short period of operation.
- Mechanical removal is practically out of the question because the entire filter would have to be removed and the soot would have to be disposed of. It is therefore necessary to burn off the enriched soot.
- oxidizing agents are added to the exhaust gas from a storage container as additives, so that the collected soot comes into contact with these agents which lower the soot ignition temperature and increase the combustion rate and can be burned off at relatively low exhaust gas temperatures.
- the invention has for its object to provide a particle filter that enables regeneration while driving and in which a high degree of free burning is achieved over the entire length of the filter, so that the re-infusion time is approximately constant and corresponds to the first infusion time.
- the solution to this problem is a generic particle filter in which filter candles of different active lengths are arranged equidistantly distributed over the cross section of the housing.
- Active length is understood to mean the section of the filter candle covered with filter material.
- a different active length can be formed in that the filter material occupancy is different over the length of the filter candle, for example, is stronger at the front when viewed in the direction of flow than in the following area.
- This different occupancy can be different for the individual filter cartridges, so a different occupancy can be selected in the edge area of the filter than in the central (middle) area.
- the strength of the occupancy can be selected according to the flow profile of the exhaust gas to be cleaned.
- a particularly useful continuation is characterized in that the length of the support tubes is covered with filter material to different degrees.
- the filter candles are arranged according to the flow profile of the exhaust gas flowing through, i.e. that the filter cartridges with the shorter active length are arranged radially on the outside in the housing.
- the supporting tubes with a short filter material occupancy are arranged in the outer, radially more distant area of the housing.
- FIG. 1 In the example of the particle filter shown in FIG. 1, two variants are shown. An arrangement is shown in the upper half of FIG. 1, in which the exhaust gas to be cleaned is fed to the filter material above the filter space. The version shown in the upper half represents a preferred arrangement.
- the housing 1 shows a housing 1 with thermal insulation 4, which is necessary in order to maintain the free-burning temperature with the lowest possible energy supply and to protect the components surrounding the filter.
- the housing 1 is subdivided into three chambers by an upstream holding base 3a which is fixedly arranged in the housing 1 and a downstream holding base 3b which is preferably arranged with a sliding seat.
- the upstream inlet chamber 4, which is designed as a mixing chamber, is followed downstream by the filter chamber 5 between the holding plates 3a, 3b and the subsequent outlet chamber 6, which is provided with an outlet funnel 7 and to which an exhaust gas outlet connection 8 is connected.
- the radial or tangential supply of the exhaust gas to be cleaned takes place via at least one exhaust gas inlet connection 9 in the inlet chamber 4.
- the required external heat supply also takes place via the connection 10, which in this exemplary embodiment also represents a suitable burner as it is is known for example from DE-OS 34 10 716.9.
- a DE-OS 35 45 437.7 shows an example of an external heat supply at 10.
- the filter candles 11 are arranged between the holding bases 3a, 3b. These consist of a support tube 12 which is provided with filter material 13 in the form of, for example, a ceramic ring winding.
- the support tubes 12 have a perforation 14 for the passage of the exhaust gas, at least in the area covered by filter material 13.
- the support tubes 12 are fixedly mounted in the holding plate 3a.
- the other end of the support tubes 12 is also fixedly mounted in the holding plate 3b if the holding plate 3b is arranged with a sliding seat in the housing 1 or is mounted in the holding plate 3b with a sliding seat if the holding plate 3b is also arranged firmly in the housing 1.
- This one-sided movable storage is required to accommodate the thermal change in length of the support tubes 12 during the free burning process.
- the exhaust gas to be cleaned is supplied via the exhaust gas inlet connection 9 into the inlet chamber 4, in which an additional heating takes place via the external heat supply at 10.
- the preferred "flow from outside to inside" of the filter candles 11 is shown.
- the exhaust gas to be cleaned loaded with soot particles, enters the filter chamber 5 from the inlet chamber 4 via inflow openings 15 arranged in the holding plate 3a. This is closed downstream by the holding plate 3b, so that the exhaust gas through filter material 13 enters through the perforation 14 in the support tube 12 and leaves this downstream open support tube 12 cleaned in the outlet chamber 6 and is discharged via the exhaust outlet port 8.
- the holding base 3a on the downstream side is designed to be closed, while the holding base 3b on the downstream side has outflow openings 16 and the support tubes 12 which are open on the outlet side are closed in the other embodiment, so that the exhaust gas flowing into the support tubes 12 which are open on the inlet side is closed flows out through the filter material 13 into the filter chamber 5 and is discharged via the outflow openings 16.
- the support tubes 12, which are open on the inlet side can have an integrally formed inlet tulip 17 in order to improve the inflow of the exhaust gas.
- FIG. 3 A variant of a filter candle 11 is shown in FIG. 3.
- the different active length of the filter candle 11 is achieved in that on the support tube 12, in the example with an integrally formed inlet tulip 17, an occupancy of filter material 13 of different lengths over the length of the support tube 12 is made.
- the support tube 12 is provided with the largest filter material occupancy in the downstream first section, in the second section there is a harmonious transition to a low filter material occupancy in the last section.
- Such filter cartridges 11 are preferably used in particle filters for vehicles with load conditions with a low exhaust gas mass flow or with a strongly changing mass flow.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Filtering Materials (AREA)
Abstract
Description
Die Erfindung betrifft einen Partikelfilter für die Reinigung des Abgases von Brennkraftmaschinen mit Filterkerzen, die in einem mit einer Eintrittskammer und einem Austrittstrichter versehenen Gehäuse zwischen Halteplatten angeordnet sind und aus einem mit Abgasdurchtrittsöffnungen versehenen, mit Filtermaterial belegten Tragrohr gebildet sind und denen aus einer Wärmequelle zusätzlich Wärme für die Regeneration durch Freibrennen zugeführt wird.The invention relates to a particle filter for cleaning the exhaust gas of internal combustion engines with filter cartridges, which are arranged in a housing provided with an inlet chamber and an outlet funnel between holding plates and are formed from a support tube provided with exhaust gas passage openings and covered with filter material, and which also provide heat from a heat source is supplied for regeneration by free burning.
Derartige Partikelfilter werden für die Reinigung von Abgasen aus Brennkraftmaschinen, insbesondere bei Fahrzeugen, die mit Dieselkraftstoff betrieben werden, benötigt, um die Rußpartikel, die gesundheitsschädlich sind und eine hohe und gefährliche Umweltbelastung darstellen, herauszufiltern. Diese Partikelfilter sind in mehreren Ausführungen bekannt. Bei der einen Ausführung erfolgt die Filterung des Abgases beim Durchströmen eines Keramikblockes (Monolithen), der eine Vielzahl von Durchgangskanälen aufweist, von denen schachbrettartig jeweils ein Kanal eintrittsseitig und ein Kanal austrittsseitig verschlossen ist, so daß das Abgas in den einen Kanal einströmt, sodann durch den als Filter wirkenden umgebenden Monolithabschnitt in den benachbarten Kanal einströmt und diesen, von Rußpartikel befreit, verläßt. Einen solchen Rußfilter beschreibt z.B. die DE-OS 32 17 357.Particle filters of this type are required for cleaning exhaust gases from internal combustion engines, in particular in vehicles which are operated with diesel fuel, in order to filter out the soot particles, which are harmful to health and represent a high and dangerous environmental impact. Several versions of these particle filters are known. In one embodiment, the exhaust gas is filtered as it flows through a ceramic block (monolith) which has a large number of through channels, of which one channel is closed like a chessboard and one channel is closed on the outlet side, so that the exhaust gas flows into one channel, then through the surrounding monolith section acting as a filter flows into the adjacent channel and leaves it, freed from soot particles. Such a soot filter describes e.g. DE-OS 32 17 357.
Eine andere Ausführungsart verwendet zur Partikelfilterung Filterkerzen. Diese Filterkerzen sind vorzugsweise als Wickelfilter ausgebildet. Dabei wird ein mit Abgasdurchtrittsöffnungen versehenes Tragrohr mehrlagig mit Filtermaterialfäden umwickelt, so daß ein mit einer Textilgarnspule vergleichbares Element entsteht. Eine derartige Anordnung zeigt z.B. die DE-OS 38 15 148 mit besonderer Darstellung der Lagerung der Filterkerzen in Halteplatten. Die Filterkerzen können auch durch einen Schlauchüberzug aus Filtermaterial über ein Tragrohr entsprechend der DE-OS 38 23 205 gebildet sein. Die Filterkerzen werden von außen nach innen durchströmt, das zu reinigende Abgas tritt durch das Filtermaterial in die Tragrohre, die eintrittsseitig verschlossen sind ein, die Rußpartikel werden beim Durchströmen des gewickelten Filtermaterials zurückgehalten und das gereinigte Abgas strömt durch die Tragrohre in den Austrittstrichter und wird von dort abgeführt. Die Filterkerzen sind dabei auf konzentrischen Kreisen im Filtergehäuse angeordnet und sind von einheitlicher Bauform. Anstelle der mit Abgasdurchtrittsöffnungen versehenen eintrittsseitigen Halteplatte kann auch ein Haltegitter angeordnet sein.Another embodiment uses filter cartridges for particle filtering. These filter cartridges are preferably designed as a wound filter. Here, a support tube provided with exhaust gas passage openings wrapped in multiple layers with filter material threads, so that an element comparable to a textile yarn spool is produced. Such an arrangement shows, for example, DE-OS 38 15 148 with a special representation of the storage of the filter candles in holding plates. The filter candles can also be formed by a hose cover made of filter material via a support tube according to DE-OS 38 23 205. The filter candles are flowed through from the outside in, the exhaust gas to be cleaned enters the support tubes through the filter material, which are closed on the inlet side, the soot particles are retained when the wound filter material flows through, and the cleaned exhaust gas flows through the support tubes into the outlet funnel and is released by dissipated there. The filter cartridges are arranged on concentric circles in the filter housing and are of a uniform design. Instead of the holding plate on the inlet side provided with exhaust gas passage openings, a holding grille can also be arranged.
Während des Betriebes der Brennkraftmaschine erfolgt beim Durchströmen des Partikelfilters eine Aufrußung, d.h. das Filtermaterial setzt sich zunehmend mit Rußpartikel zu, und der Ruß muß nach einer relativ geringen Betriebsdauer entfernt werden. Eine mechanische Entfernung scheidet praktisch aus, da hierzu der gesamte Filter ausgebaut werden und der Ruß entsorgt werden müßte. Man ist daher auf ein Freibrennen des angereicherten Rußes angewiesen. Hierzu werden dem Abgas aus einem Vorratsbehälter Oxidationsmittel als Additive zugesetzt, so daß der gesammelte Ruß mit diesen die Rußzündtemperatur herabsetzenden und die Verbrennungsgeschwindigkeit erhöhenden Mitteln in Kontakt kommt und bei relativ niedrigen Abgastemperaturen abgebrannt werden kann. Diese Art des Freibrennens des angesammelten Rußes hat jedoch den Nachteil, daß die Additive chemische Verbindungen sind, die leicht entflammbar sind und das Abgas mit unerwünschten Bestandteilen anreichert, deren Umweltverträglichkeit noch nicht erwiesen ist. Man hat daher bereits versucht, einen Dieselbrenner als externe Wärmequelle anzuschließen, konnte mit der bekannten Anordnung aber nicht im Fahrbetrieb des Fahrzeuges die Filter regenerieren. Daher ist man bei dieser Lösung auf sehr große Filter angewiesen, um eine Speicherkapazität zu erhalten, die einen längeren Fahrbetrieb zwischen den Regenerationsphasen zuläßt. Diese Ruhepausenregeneration ist bei Fahrzeugen möglich, die im Intervallbetrieb arbeiten, z.B. Busse im innerstädtischen Betrieb. Für andere Fahrzeuge muß die Regeneration während des Fahrbetriebes erfolgen. Hierfür hat man z.B. zwei Filter parallel zueinander angeordnet und regeneriert jeweils einen der beiden Filter.During operation of the internal combustion engine, sooting occurs when it flows through the particle filter, ie the filter material becomes increasingly clogged with soot particles and the soot has to be removed after a relatively short period of operation. Mechanical removal is practically out of the question because the entire filter would have to be removed and the soot would have to be disposed of. It is therefore necessary to burn off the enriched soot. For this purpose, oxidizing agents are added to the exhaust gas from a storage container as additives, so that the collected soot comes into contact with these agents which lower the soot ignition temperature and increase the combustion rate and can be burned off at relatively low exhaust gas temperatures. However, this type of burning the accumulated soot has the disadvantage that the additives are chemical compounds that are easily flammable and enrich the exhaust gas with undesirable components, the environmental compatibility of which has not yet been proven. Attempts have therefore already been made to connect a diesel burner as an external heat source, but the known arrangement has not been able to regenerate the filters while the vehicle is in operation. Therefore one is on this solution very large filters instructed to obtain a storage capacity that allows longer driving between the regeneration phases. This regeneration regeneration is possible for vehicles that work in intervals, for example buses in inner-city operation. For other vehicles, regeneration must take place while driving. For this purpose, two filters have been arranged parallel to each other and one of the two filters has been regenerated.
Bei Anordnungen nur eines Partikelfilters mit mehreren Filterkerzen ist es auch bekannt, zur "Fahrregeneration", sobald sich eine höhere Belegung mit Rußpartikel z.B. über den Abgasgegendruck feststellen läßt, eine externe Wärmequelle zuzuschalten, die das zu reinigende Abgas soweit erhitzt (> 600 °C), daß der Freibrennvorgang erfolgen kann. Dabei hat sich jedoch gezeigt, daß vor allem bei Lastzuständen mit geringem Abgasmassenstrom während der Regeneration die Filterkerzen nicht auf ihrer gesamten Länge freigebrannt werden. Ursache hierfür ist, daß bereits ein Freibrennen der etwa vorderen Hälfte der Filterkerzen für einen ausreichend niedrigen Strömungswiderstand sorgt und damit der hintere Teil bzw. die äußersten Filterkerzen nicht genügend durchströmt werden. Aus dieser unvollkommenen Regeneration ergeben sich immer kürzere Wiederaufrußungszeiten, die im ungünstigsten Fall zum Ausfall des Filters führen können. Versuche haben gezeigt, daß die Aufrußungszeit von z.B. 135 Minuten bei Erstaufrußung auf 15 bis 20 Minuten zurückging.In the case of arrangements of only one particle filter with several filter cartridges, it is also known to "drive regeneration" as soon as there is a higher occupancy with soot particles, e.g. can be determined via the exhaust gas back pressure, connect an external heat source that heats the exhaust gas to be cleaned to such an extent (> 600 ° C) that the free-burning process can take place. It has been shown, however, that the filter candles are not burned free over their entire length, especially in load states with a low exhaust gas mass flow. The reason for this is that already burning free the approximately front half of the filter candles ensures a sufficiently low flow resistance and thus the rear part or the outermost filter candles are not sufficiently flowed through. This imperfect regeneration results in shorter and shorter re-infiltration times, which in the worst case can lead to filter failure. Experiments have shown that the infusion time of e.g. 135 minutes at the first infusion decreased to 15 to 20 minutes.
Um bei der Freibrennregenerierung eine wesentliche Verbesserung zu erzielen, hat man gemäß der nicht vorveröffentlichten deutschen Patentanmeldung P 40 04 861.6 bereits eine Verbesserung des Freibrennens dadurch erreicht, daß in dem Raum zwischen den Filterkerzen sogenannte überströmrohre angeordnet sind, über die das zu reinigende Abgas den Filterkerzen derart zugeführt wird, daß eine gleichmäßige Beaufschlagung über die gesamte Länge der Filterkerzen erreicht wird.In order to achieve a significant improvement in the free-burning regeneration, according to the unpublished German patent application P 40 04 861.6, an improvement in the free-burning has already been achieved in that so-called overflow pipes are arranged in the space between the filter candles, via which the exhaust gas to be cleaned passes the filter candles is fed in such a way that a uniform application is achieved over the entire length of the filter candles.
Es ist ferner aus der DE 38 36 697 A1 bereits eine gattungsgemäße Einrichtung bekannt, bei welcher die Halteplatten samt den Filterkerzen eine drehbewegliche Trommel bilden, so daß immer ein Segment dieser Trommel in einen Bereich geführt werden kann, in dem das Freibrennen erfolgt. Eine derartige Einrichtung ist sehr aufwendig, insbesondere hinsichtlich der Lagerung der drehbeweglichen Trommel und der Abdichtung gegen Umströmen durch ungereinigtes Abgas. Diese Probleme werden in dieser Druckschrift gelöst. Für den Serieneinbau sind solche Einrichtungen mit segmentweisem Freibrennen jedoch nicht geeignet.It is also known from DE 38 36 697 A1 a generic device in which the holding plates together with the filter candles form a rotatable drum, so that a segment of this drum can always be guided into an area in which the free burning takes place. Such a device is very complex, especially with regard to the storage of the rotatable drum and the seal against flow from uncleaned exhaust gas. These problems are solved in this document. However, such devices with segmental free firing are not suitable for series installation.
Ausgehend von diesem Stand der Technik liegt der Erfindung die Aufgabe zugrunde, einen Partikelfilter aufzuzeigen, der eine Regeneration während des Fahrbetriebes ermöglicht und bei dem ein hoher Freibrenngrad über die gesamte beaufschlagte Filterlänge erzielt wird, so daß die Wiederaufrußzeit etwa konstant ist und der Erstaufrußungszeit entspricht.Based on this prior art, the invention has for its object to provide a particle filter that enables regeneration while driving and in which a high degree of free burning is achieved over the entire length of the filter, so that the re-infusion time is approximately constant and corresponds to the first infusion time.
Bei der Lösung dieser Aufgabe wird von der Erkenntnis ausgegangen, daß das Abgas den Filter in einem bestimmten Strömungsprofil durchströmt und daß die Aufrußung des Filters diesem Strömungsprofil entspricht.In solving this task, it is assumed that the exhaust gas flows through the filter in a certain flow profile and that the sooting of the filter corresponds to this flow profile.
Die Lösung dieser Aufgabe ist ein gattungsgemäßes Partikelfilter, bei welchem über den Querschnitt des Gehäuses äquidistant verteilt Filterkerzen unterschiedlicher aktiver Länge angeordnet sind. Dabei ist unter "aktiver Länge" der mit Filtermaterial belegte Abschnitt der Filterkerze verstanden. Eine unterschiedliche aktive Länge kann dadurch gebildet werden, daß die Filtermaterialbelegung über die Länge der Filterkerze unterschiedlich ist, z.B. in Strömungsrichtung gesehen vorne stärker ist als im folgenden Bereich. Diese unterschiedlich starke Belegung kann bei den einzelnen Filterkerzen verschieden sein, so kann im Randbereich des Filters eine andere Belegung gewählt werden als im zentralen (Mitten-) Bereich. Die Stärke der Belegung kann dabei entsprechend des Strömungsprofiles des zu reinigenden Abgases gewählt werden.The solution to this problem is a generic particle filter in which filter candles of different active lengths are arranged equidistantly distributed over the cross section of the housing. "Active length" is understood to mean the section of the filter candle covered with filter material. A different active length can be formed in that the filter material occupancy is different over the length of the filter candle, for example, is stronger at the front when viewed in the direction of flow than in the following area. This different occupancy can be different for the individual filter cartridges, so a different occupancy can be selected in the edge area of the filter than in the central (middle) area. The strength of the occupancy can be selected according to the flow profile of the exhaust gas to be cleaned.
Eine besonders zweckmäßige Weiterführung ist dadurch gekennzeichnet, daß die Tragrohre in ihrer Längserstreckung unterschiedlich weit mit Filtermaterial belegt sind. Mit dieser Anordnung wird erreicht, daß die als Wickelfilter ausgebildeten Filterkerzen in einem einfachen und bewährten Verfahren in jeweils gleicher Weise hergestellt werden können und sich die Filterkerzen durch die jeweils identische Länge der Tragrohre in ebene Halteplatten in dem Filtergehäuse einsetzen lassen. Dabei erfolgt gemäß einer weiteren Ausgestaltung die Anordnung der Filterkerzen entsprechend dem Strömungsprofil des durchströmenden Abgases, d.h. daß die Filterkerzen mit der kürzeren aktiven Länge radial außen im Gehäuse angeordnet sind. Bei einer bevorzugten Anordnung nach dem Anspruch 2 mit unterschiedlich weit belegtem Tragrohr sind die Tragrohre mit kurzer Filtermaterialbelegung im äußeren, radial ferneren Bereich des Gehäuses angeordnet. Hiermit wird eine Anpassung der inneren Filtergeometrie an das tatsächlich vorhandene Stromlinienfeld im Filter erreicht und damit, daß die Regeneration des Abgases durch Freibrennen der im Filter angesammelten Partikel gleichmäßig über dem genannten Filterbereich erfolgt bei reduziertem Aufwand an Filtermaterial. Zum Freibrennen der Partikel wird dabei zumindest zeitweise extern erzeugte Wärme zugeführt, z.B. über einen an dem Filtergehäuse angeordneten Brenner, wie er z.B. aus sogenannten Fahrzeugstand- oder Zusatzheizungen bekannt ist.A particularly useful continuation is characterized in that the length of the support tubes is covered with filter material to different degrees. With this arrangement it is achieved that the filter cartridges designed as a wound filter can be manufactured in a simple and proven method in the same way and the filter cartridges can be inserted into flat holding plates in the filter housing due to the identical length of the support tubes. According to a further embodiment, the filter candles are arranged according to the flow profile of the exhaust gas flowing through, i.e. that the filter cartridges with the shorter active length are arranged radially on the outside in the housing. In a preferred arrangement according to claim 2 with a differently occupied supporting tube, the supporting tubes with a short filter material occupancy are arranged in the outer, radially more distant area of the housing. This achieves an adaptation of the inner filter geometry to the actually existing streamline field in the filter and thus that the regeneration of the exhaust gas by burning off the particles accumulated in the filter takes place uniformly over the filter area mentioned, with a reduced expenditure of filter material. To burn off the particles, externally generated heat is supplied at least temporarily, e.g. via a burner arranged on the filter housing, e.g. is known from so-called vehicle parking or additional heaters.
Diese in den Unteransprüchen aufgezeigten vorteilhafte und zweckmäßige weitere Ausgestaltungen der Erfindung weisen zumindest teilweise alleine oder in Kombination selbständige erfinderische Merkmale auf.These advantageous and expedient further refinements of the invention shown in the subclaims have, at least in part, independent or inventive features.
In den Figuren ist ein Ausführungsbeispiel vereinfacht und schematisch dargestellt. An diesem Beispiel wird die Anordnung nachfolgend beschrieben, einschließlich von Weiterführungen. Dabei zeigt:
- Fig. 1
- einen Längsschnitt durch einen Partikelfilter mit in der oberen und der unteren Hälfte dargestellten unterschiedlichen Möglichkeiten der Abgasführung,
- Fig. 2
- einen Querschnitt an der mit A-A angegebenen Stelle
- Fig. 3
- eine Filterkerze mit einer Filtermaterialbelegungsvarianten.
- Fig. 1
- 2 shows a longitudinal section through a particle filter with different exhaust gas routing options shown in the upper and lower half,
- Fig. 2
- a cross section at the point indicated by AA
- Fig. 3
- a filter candle with a filter material allocation variants.
Bei dem in der Fig. 1 dargestellten Partikelfilterbeispiel sind zwei Varianten dargestellt. In der oberen Hälfte der Fig. 1 ist eine Anordnung dargestellt, bei welcher das zu reinigende Abgas dem Filtermaterial über dem Filterraum zugeführt wird, bei der Darstellung in der unteren Hälfte erfolgt die Abgaszuführung über die Tragrohre der Filterkerzen. Dabei stellt die in der oberen Hälfte dargestellte Ausführung eine bevorzugte Anordnung dar.In the example of the particle filter shown in FIG. 1, two variants are shown. An arrangement is shown in the upper half of FIG. 1, in which the exhaust gas to be cleaned is fed to the filter material above the filter space. The version shown in the upper half represents a preferred arrangement.
Die Fig. 1 zeigt ein Gehäuse 1 mit einer Wärmeisolierung 4, die erforderlich ist, um die Freibrenntemperatur mit möglichst geringer Energiezufuhr zu halten und um die das Filter umgebenden Bauteile zu schützen. Durch einen stromaufseitigen Halteboden 3a, der fest in dem Gehäuse 1 angeordnet ist und einen stromabseitigen, vorzugsweise mit Schiebesitz angeordneten Halteboden 3b ist das Gehäuse 1 in drei Kammern unterteilt. Der stromaufseitigen als Mischkammer ausgebildeten Eintrittskammer 4 folgt stromabwärts der Filterraum 5 zwischen den Halteplatten 3a, 3b und die nachfolgende mit einem Auslauftrichter 7 versehene Austrittskammer 6, an die sich ein Abgasaustrittsstutzen 8 anschließt. Die radiale oder auch tangentiale Zufuhr des zu reinigenden Abgases erfolgt über mindestens einen Abgaseintrittsstutzen 9 in die Eintrittskammer 4. In diese Eintrittskammer 4 erfolgt auch die erforderliche externe Wärmezufuhr über den Anschluß 10, der in diesem Ausführungsbeispiel zugleich stellvertretend für einen geeigneten Brenner steht, wie er z.B. aus der DE-OS 34 10 716.9 bekannt ist. Ein Beispiel für eine externe Wärmezufuhr bei 10 zeigt z.B. die DE-OS 35 45 437.7. Zwischen den Halteböden 3a, 3b sind die Filterkerzen 11 angeordnet. Diese bestehen aus einem Tragrohr 12, das mit Filtermaterial 13 in Form z.B. einer Keramikringwicklung versehen ist. Die Tragrohre 12 weisen zumindest im Bereich der Belegung mit Filtermaterial 13 eine Perforation 14 zum Durchtritt des Abgases auf. Die Tragrohre 12 sind in der Halteplatte 3a fest gelagert. Das andere Ende der Tragrohre 12 ist in der Halteplatte 3b ebenfalls fest gelagert, wenn die Halteplatte 3b mit einem Schiebesitz im Gehäuse 1 angeordnet oder in der Halteplatte 3b mit Schiebesitz gelagert, wenn auch die Halteplatte 3b fest im Gehäuse 1 angeordnet ist. Diese einseitig bewegliche Lagerung ist erforderlich, um die thermische Längenänderung der Tragrohre 12 bei dem Freibrennvorgang aufzunehmen.1 shows a housing 1 with thermal insulation 4, which is necessary in order to maintain the free-burning temperature with the lowest possible energy supply and to protect the components surrounding the filter. The housing 1 is subdivided into three chambers by an
Die Zuführung des zu reinigenden Abgases erfolgt über den Abgaseintrittsstutzen 9 in die Eintrittskammer 4, in welche auch eine zusätzliche Aufheizung über die externe Wärmezufuhr bei 10 erfolgt. Für die Zuleitung des Abgases zu dem Filterraum 5 ergeben sich zwei Möglichkeiten. Im oberen Teil der Fig. 1 ist die bevorzugte "von außen nach innen-Durchströmung" der Filterkerzen 11 dargestellt. Hierbei tritt das zu reinigende, mit Rußpartikeln beladene Abgas aus der Eintrittskammer 4 über in der Halteplatte 3a angeordnete Einströmöffnungen 15 in den Filterraum 5 ein. Dieser ist stromab durch die Halteplatte 3b verschlossen, so daß das Abgas durch Filtermaterial 13 über die Perforation 14 in das Tragrohr 12 eintritt und dieses stromab offene Tragrohr 12 in die Austrittskammer 6 gereinigt verläßt und über den Abgasaustrittsstutzen 8 abgeführt wird.The exhaust gas to be cleaned is supplied via the exhaust
In der unteren Hälfte der Fig. 1 ist als Variante die "von innen nach außen Durchströmung" der Filterkerzen 11 dargestellt. Bei sonst gleicher Anordnung ist nach dieser Ausgestaltung der stromaußenseitige Halteboden 3a geschlossen ausgebildet, während der stromabseitige Halteboden 3b Ausströmöffnungen 16 aufweist und die in der anderen Ausführung austrittsseitig offenen Tragrohre 12 verschlossen sind, so daß das in die eintrittsseitig offenen Tragrohre 12 einströmende Abgas durch das Filtermaterial 13 nach außen in den Filterraum 5 strömt und über die Ausströmöffnungen 16 abgeführt wird. Die eintrittsseitig offenen Tragrohre 12 können zur Verbesserung der Einströmung des Abgases eine angeformte Einlaßtulpe 17 aufweisen.In the lower half of FIG. 1, the "flow from the inside out" of the
In Fig. 3 ist eine Variante einer Filterkerze 11 gezeigt. Bei dieser Varianten ist die unterschiedliche aktive Länge der Filterkerze 11 dadurch erreicht, daß auf dem Tragrohr 12, im Beispiel mit einer angeformten Einlaßtulpe 17, eine über der Länge des Tragrohres 12 unterschiedlich starke Belegung mit Filtermaterial 13 vorgenommen ist. In diesem Beispiel ist das Tragrohr 12 im stromab ersten Abschnitt mit der größten Filtermaterialbelegung versehen, im zweiten Abschnitt erfolgt harmonisch der Übergang zu einer geringen Filtermaterialbelegung im letzten Abschnitt. Derartige Filterkerzen 11 werden vorzugsweise bei Partikelfilter für Fahrzeuge mit Lastzuständen mit geringem Abgasmassenstrom eingesetzt oder bei stark wechselndem Massenstrom.A variant of a
Claims (5)
dadurch gekennzeichnet,
daß über den Querschnitt des Gehäuses (1) äquidistant verteilt Filterkerzen (11) unterschiedlicher aktiver Länge angeordnet sind.Particle filters for cleaning the exhaust gas of internal combustion engines with filter candles, which are arranged in a housing provided with an inlet chamber and an outlet funnel between holding plates and are formed in a support tube covered with filter material and provided with exhaust gas openings and to which heat from a heat source is additionally supplied for regeneration by burning free becomes,
characterized,
that over the cross section of the housing (1) equidistantly distributed filter candles (11) of different active lengths are arranged.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4026375 | 1990-08-21 | ||
DE4026375A DE4026375C1 (en) | 1990-08-21 | 1990-08-21 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0472008A2 true EP0472008A2 (en) | 1992-02-26 |
EP0472008A3 EP0472008A3 (en) | 1992-12-02 |
EP0472008B1 EP0472008B1 (en) | 1994-07-06 |
Family
ID=6412600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91112672A Expired - Lifetime EP0472008B1 (en) | 1990-08-21 | 1991-07-27 | Particle filter regenerable by combustion for exhaust gases of internal combustion engine |
Country Status (5)
Country | Link |
---|---|
US (1) | US5138836A (en) |
EP (1) | EP0472008B1 (en) |
AT (1) | ATE108244T1 (en) |
DE (2) | DE4026375C1 (en) |
ES (1) | ES2057680T3 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0549851A1 (en) * | 1992-01-03 | 1993-07-07 | ERNST-APPARATEBAU GmbH & Co. | Soot filter for diesel engines |
EP0583507B1 (en) * | 1992-08-14 | 1996-03-27 | ERNST APPARATEBAU GmbH & Co. | Soot filter with hot gas generator |
EP0854274A1 (en) * | 1997-01-20 | 1998-07-22 | DEUTZ Aktiengesellschaft | Particulate filter |
WO2008118275A1 (en) * | 2007-03-27 | 2008-10-02 | Caterpillar Inc. | Exhaust particulate filter for a machine engine system and assembly method therefor |
EP2146062A1 (en) * | 2008-07-19 | 2010-01-20 | Grywotz Automobiltechnik GmbH Karl-Heinz | Particulate filter for diesel and petrol engines |
US20180345192A1 (en) * | 2016-10-31 | 2018-12-06 | Jonell filtration Products, Inc. | Variable length filter elements, apparatus comprising such filter elements, and methods of making and using such elements and apparatus |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4111029C2 (en) * | 1991-04-05 | 1995-08-31 | Eberspaecher J | Particle filter for the exhaust gases of internal combustion engines that can be regenerated by free burning |
WO1993000503A2 (en) * | 1991-06-27 | 1993-01-07 | Donaldson Company, Inc. | Trap apparatus with tubular filter element |
US5411758A (en) * | 1991-10-09 | 1995-05-02 | Norton Company | Method of making synthetic diamond wear component |
US5224973A (en) * | 1992-04-20 | 1993-07-06 | Donaldson Company, Inc. | Filter cartridge for trap apparatus |
DE4229723C1 (en) * | 1992-09-05 | 1993-09-16 | Mtu Friedrichshafen Gmbh | Regeneratable filter unit of modular structure - for particle removal from diesel exhaust gas |
US5396764A (en) * | 1994-02-14 | 1995-03-14 | Ford Motor Company | Spark ignition engine exhaust system |
US5771683A (en) * | 1995-08-30 | 1998-06-30 | Southwest Research Institute | Active porous medium aftertreatment control system |
DE19810738C1 (en) * | 1998-03-12 | 1999-04-22 | Hjs Fahrzeugtechnik Gmbh & Co | Cleaning of filter elements in the exhaust of diesel engines |
DE20022035U1 (en) | 2000-12-29 | 2002-02-28 | Thomas Josef Heimbach GmbH, 52353 Düren | filtering device |
JP5284951B2 (en) | 2006-05-03 | 2013-09-11 | サバーテック リミテッド ライアビリティ カンパニー | Emission reduction device and method |
US7981174B2 (en) * | 2007-11-26 | 2011-07-19 | Caterpillar Inc. | Electrically regenerated exhaust particulate filter for an engine system and operating strategy therefor |
US8444729B2 (en) * | 2007-11-26 | 2013-05-21 | Caterpillar Inc. | Electrically regenerated exhaust particulate filter having non-axial regeneration flame propagation |
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US4478618A (en) * | 1983-08-01 | 1984-10-23 | General Motors Corporation | Diesel exhaust particulate trap with plural filter tubes |
DE3836697A1 (en) * | 1988-10-28 | 1990-05-03 | Sueddeutsche Kuehler Behr | Regenerative device for the separation of soot from the exhaust gases of diesel engines |
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DE3217357C2 (en) * | 1982-05-08 | 1987-03-12 | Fa. J. Eberspächer, 7300 Esslingen | Device for reducing the soot content in the exhaust gases of internal combustion engines |
WO1987007324A1 (en) * | 1986-05-30 | 1987-12-03 | Dieter Kuhnert | Exhaust gas cleaning system for diesel engines |
DE3815148A1 (en) * | 1988-05-04 | 1989-11-16 | Eberspaecher J | Arrangement for mounting an exhaust gas filter in a metal housing |
DE3823205A1 (en) * | 1988-07-08 | 1990-01-11 | Eberspaecher J | Soot-filter plug for the purification of exhaust gases and soot-filter arrangement formed from soot-filter plugs |
US5024249A (en) * | 1989-05-17 | 1991-06-18 | Carol Botsolas | Specialized one-piece pipefitting cover for insulated strainer and lateral 45 degree -Y |
US5065574A (en) * | 1990-05-29 | 1991-11-19 | Caterpillar Inc. | Particulate trap regeneration apparatus and method |
-
1990
- 1990-08-21 DE DE4026375A patent/DE4026375C1/de not_active Expired - Lifetime
-
1991
- 1991-07-27 ES ES91112672T patent/ES2057680T3/en not_active Expired - Lifetime
- 1991-07-27 EP EP91112672A patent/EP0472008B1/en not_active Expired - Lifetime
- 1991-07-27 DE DE59102111T patent/DE59102111D1/en not_active Expired - Fee Related
- 1991-07-27 AT AT91112672T patent/ATE108244T1/en not_active IP Right Cessation
- 1991-08-20 US US07/747,664 patent/US5138836A/en not_active Expired - Fee Related
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US4478618A (en) * | 1983-08-01 | 1984-10-23 | General Motors Corporation | Diesel exhaust particulate trap with plural filter tubes |
DE3836697A1 (en) * | 1988-10-28 | 1990-05-03 | Sueddeutsche Kuehler Behr | Regenerative device for the separation of soot from the exhaust gases of diesel engines |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0549851A1 (en) * | 1992-01-03 | 1993-07-07 | ERNST-APPARATEBAU GmbH & Co. | Soot filter for diesel engines |
EP0583507B1 (en) * | 1992-08-14 | 1996-03-27 | ERNST APPARATEBAU GmbH & Co. | Soot filter with hot gas generator |
EP0854274A1 (en) * | 1997-01-20 | 1998-07-22 | DEUTZ Aktiengesellschaft | Particulate filter |
WO2008118275A1 (en) * | 2007-03-27 | 2008-10-02 | Caterpillar Inc. | Exhaust particulate filter for a machine engine system and assembly method therefor |
EP2146062A1 (en) * | 2008-07-19 | 2010-01-20 | Grywotz Automobiltechnik GmbH Karl-Heinz | Particulate filter for diesel and petrol engines |
US20180345192A1 (en) * | 2016-10-31 | 2018-12-06 | Jonell filtration Products, Inc. | Variable length filter elements, apparatus comprising such filter elements, and methods of making and using such elements and apparatus |
Also Published As
Publication number | Publication date |
---|---|
ES2057680T3 (en) | 1994-10-16 |
DE59102111D1 (en) | 1994-08-11 |
US5138836A (en) | 1992-08-18 |
ATE108244T1 (en) | 1994-07-15 |
DE4026375C1 (en) | 1992-01-30 |
EP0472008A3 (en) | 1992-12-02 |
EP0472008B1 (en) | 1994-07-06 |
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