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EP0466850B1 - Installation for venting the petrol tank of a motor vehicle and process for testing its performance - Google Patents

Installation for venting the petrol tank of a motor vehicle and process for testing its performance Download PDF

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Publication number
EP0466850B1
EP0466850B1 EP91901685A EP91901685A EP0466850B1 EP 0466850 B1 EP0466850 B1 EP 0466850B1 EP 91901685 A EP91901685 A EP 91901685A EP 91901685 A EP91901685 A EP 91901685A EP 0466850 B1 EP0466850 B1 EP 0466850B1
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EP
European Patent Office
Prior art keywords
tank
valve
ventilation
shut
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91901685A
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German (de)
French (fr)
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EP0466850A1 (en
Inventor
Ulrich Steinbrenner
Helmut Denz
Ernst Wild
Wolfgang Wagner
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Robert Bosch GmbH
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Robert Bosch GmbH
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/08Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding fuel vapours drawn from engine fuel reservoir
    • F02M25/0809Judging failure of purge control system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/08Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding fuel vapours drawn from engine fuel reservoir
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/08Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding fuel vapours drawn from engine fuel reservoir
    • F02M25/0809Judging failure of purge control system
    • F02M25/0818Judging failure of purge control system having means for pressurising the evaporative emission space

Definitions

  • the invention relates to a tank ventilation system for a motor vehicle and a method for checking the functionality of such a system.
  • a tank ventilation system generally has a fuel tank and a tank ventilation valve, which is connected to the intake manifold of an internal combustion engine, so that fuel vapors are drawn off with the aid of the negative pressure in the intake manifold.
  • a tank ventilation valve usually an activated carbon filter, is interposed between the tank and the tank ventilation valve. This activated carbon filter adsorbs fuel in those periods in which there is no suction from the intake manifold, e.g. B. when the internal combustion engine is at a standstill or when the tank ventilation valve is kept closed due to the current operating state.
  • tank ventilation systems There is a risk that tank ventilation systems will leak or that the tank ventilation valve will not work properly. Such systems must therefore be repeatedly checked for functionality during the operation of a motor vehicle.
  • the most important method for checking the functionality of a motor vehicle tank ventilation system is based on a proposal from the California environmental agency CARB. According to this method, when the tank ventilation valve is opened, a check is carried out to determine whether a lambda regulator has to correct its manipulated value. This is always the case when air is drawn in with fuel vapor from the tank ventilation system. However, it is now the case that the adsorption filter can be completely regenerated and that the fuel in the tank is completely degassed. Then, when the tank ventilation valve is opened, no fuel is supplied in addition to that which is supplied to the injection valves of the internal combustion engine in accordance with the manipulated variable of the lambda control. In such a case, in which no fuel is supplied by the tank ventilation system, i.e.
  • the lambda regulator does not have to make a correction, it is unclear whether the tank ventilation system is leaking or whether no fuel is being supplied for the reasons mentioned.
  • the signal from the lambda controller is only evaluated in accordance with the known method when a fuel temperature sensor indicates that a predetermined minimum fuel temperature has been exceeded and a tank level sensor indicates that the vehicle has been refueled. It is assumed that fuel vapor should then be present in the system in any case, which is sucked in when the tank ventilation valve is opened and then leads to a correction of the lambda regulator.
  • wrong decisions always occur with this method, namely when there is outgassed fuel in the tank, such fuel is refilled and the adsorption filter is largely regenerated.
  • the shut-off speed of the ventilation line of the adsorption filter enables the method according to the invention specified below to check the functionality of the system.
  • the processes share the idea that they exploit the shut-off facility of the ventilation line of the adsorption filter.
  • the lockability of the ventilation line makes it possible to set sufficiently large overpressures and underpressures for a particularly reliable check of the functionality of the system.
  • the shut-off element advantageously has overpressure and underpressure protection valves.
  • the functionality of the shut-off device can be checked by releasing the ventilation line if there is negative pressure. If the vacuum is then reduced, this is a sign that the shut-off device is working properly.
  • Fig. 1 shows schematically a tank ventilation system with a fuel tank KT, an adsorption filter AF and a tank ventilation valve TEV.
  • the latter lies in a valve line VL, which connects the adsorption filter AF to the intake manifold SR of an internal combustion engine, not shown.
  • the valve line opens air sucked in the flow direction L behind the throttle valve. This makes it possible to achieve a relatively high negative pressure in the valve line in order to effectively rinse the adsorption filter AF. With the throttle valve largely closed and at higher speeds, the negative pressure drops to a few 100 hPa.
  • the adsorption filter AF is in turn connected to the fuel tank KT via a filter line FL. If the fuel is in the fuel tank, the outgassing fuel is adsorbed by activated carbon in the adsorption filter AF.
  • a ventilation line BL also opens into the adsorption filter AF. Air flows through this ventilation line BL when the adsorption filter AF is sucked off via the valve line with the tank ventilation valve TEV. This regenerates the activated carbon. The activated carbon can then absorb fuel again when the engine is at a standstill or in operating phases in which the tank ventilation valve is closed.
  • the tank ventilation system shown in Fig. 1 has a structure due to components to be described, which can be checked particularly reliably for functionality. These additional components are a differential pressure meter DDM, which measures the differential pressure in the tank relative to atmospheric pressure, and a shut-off valve for controllably shutting off the ventilation line BL.
  • the shut-off valve AV can be opened or closed with the aid of a signal which is output by a control unit SG. The criteria according to which signals are output are explained below with reference to FIG. 3.
  • the line of a protective valve arrangement SVA also opens into the ventilation line BL, which protective valve arrangement has an overpressure and a vacuum protection valve.
  • the pressures in the protective valve arrangement are set in such a way that there is no risk of damage to the tank ventilation system because the pressures are too high or too low.
  • Fig. 2 shows an adsorption filter AF.2, which is equipped with a check valve arrangement.
  • a tank shut-off valve TSV ensures that fuel gas only reaches the adsorption filter AF when a certain excess pressure in the fuel tank KT is exceeded, e.g. B. 30 hPa. Since this tank shut-off valve TSV prevents the tank from being vented under negative pressure, a tank ventilation valve TBV is also available. B. opens at a vacuum of 30 hPa in the tank.
  • a filter shut-off valve FSV is present, which only opens the way into the valve line VL when the vacuum drops below a certain level, e.g. . B. with a pressure drop to less than 50 hPa.
  • FIG. 3 explains how the functionality of the tank ventilation system according to FIG. 1 can be checked.
  • the method also makes it possible to find faults in an absorption filter AF.2 according to FIG. 2, that is to say with check valves.
  • the ventilation line BL is shut off in a step s1, which is done by correspondingly actuating the shutoff valve AV.
  • This process step of shutting off the ventilation valve is a decisive step for all the process variants explained below.
  • a query is made as to whether a test with negative pressure should be carried out in steps s3 to s9.
  • a test can e.g. B. at fixed time intervals. If no vacuum test is to be carried out, step s2 is followed by process steps s10 to s16, which use overpressure in the system. The test with the help of overpressure can also take place at fixed time intervals, or after a test with underpressure.
  • step s3 the tank ventilation valve TEV is opened. Since the ventilation line BL is closed, negative pressure must now build up in the tank ventilation system if it is tight.
  • the pressure measured by the differential pressure meter DDM is first queried in a step s4. It is determined in a step s5 that no negative pressure with an absolute value above a predetermined threshold value (eg 50 hPa (negative pressure)) is obtained, an error message is output in step s6.
  • a predetermined threshold value eg 50 hPa (negative pressure)
  • an evaluation can be excluded, e.g. B. full load, since then there is almost atmospheric pressure in the intake manifold and thus no significant negative pressure can build up in the tank ventilation system.
  • step s6 After the error message has been output in step s6, the end of the method is reached. Otherwise, a step s7 follows in which the ventilation line is released again by opening the shut-off valve AV. In a step s8 it is checked whether the value of the negative pressure measured by the differential pressure meter DDM falls. If this is the case, the end of the procedure is reached. Otherwise, an error message is output in a step s9, which indicates that the shut-off valve AV no longer opens properly. A leakage and thus malfunction of the system can already be fully checked through steps s1-s9.
  • step s2 If, in step s2, after the described check with negative pressure has been switched over to the lambda correction check with positive pressure, the tank ventilation valve is closed in step s10 and the ventilation line BL is blocked by closing the shut-off valve AV.
  • step s11 the differential pressure for the fuel tank KT detected by the differential pressure meter DDM is queried. It is then checked (step s12) whether there is an overpressure that lies above a predetermined threshold, e.g. B. at more than 30 hPa. If this is not the case, steps s11 and s12 are repeated until an overpressure above the specified threshold is reached, or until a step s13 between steps s12 and s11 is determined that an end of test condition has occurred. This can be, for.
  • test B. can be the expiration of a period of time since the start of the check for reaching the predetermined positive pressure.
  • the test end condition can also consist in reaching predetermined operating states. If the test end condition occurs, the end of the Procedure reached. Since an overpressure never builds up under certain circumstances (e.g. with outgassed fuel), it may happen that the pressure threshold is never reached. The following test steps therefore only provide additional information on the vacuum test and are not sufficient as the sole error criterion.
  • step s12 shows that the predetermined overpressure has been exceeded
  • the tank ventilation valve TEV is opened in step s14.
  • fuel is suddenly supplied to the internal combustion engine in addition to that which is injected anyway.
  • the lambda control must then reduce the amount of fuel to be injected.
  • step s15 it is checked whether a lean correction in the lambda control is required when the tank ventilation valve is opened in step s14. If this is the case, it is confirmed again that the tank ventilation system has delivered fuel in the expected manner. The end of the procedure is then reached. Otherwise, an error message is output in step s16. If the previous vacuum test already showed an error, it has now been proven that the connection pipe between the intake manifold and the tank ventilation valve is interrupted.
  • a negative pressure builds up in the tank ventilation system.
  • the realizable negative pressure is usually sufficient to vaporize fuel in the fuel tank KT and thus to deliver fuel through the valve line VL into the intake manifold SR.
  • the vacuum must not fall below a few 10 hPa, otherwise there is a risk of implosion for the KT fuel tank.
  • the negative pressure is accordingly limited by the protective valve arrangement SVA.
  • the test is only carried out if there was previously overpressure in the tank. However, as already mentioned above, this overpressure cannot be guaranteed in all cases despite the blocked ventilation line BL.
  • step s5 the expected negative pressure builds up, this is a sign that the valves TSV and FSV are consistent. If the expected vacuum is not reached, either one of these two valves is blocked or the dance vent valve TEV or the system is leaking. If the pressure in the tank KT rises above a permissible value with the ventilation line BL open, the check valve TSV is clogged. If the pressure in the tank drops when the ventilation line BL is open, this indicates that the tank ventilation valve TBV is clogged. In a corresponding manner, a functional test of the protective valve arrangement SVA is also possible; no negative pressures or overpressures may occur, the absolute values of which exceed the values of the protective pressures.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Supplying Secondary Fuel Or The Like To Fuel, Air Or Fuel-Air Mixtures (AREA)
  • Cooling, Air Intake And Gas Exhaust, And Fuel Tank Arrangements In Propulsion Units (AREA)

Abstract

An installation for venting the petrol tank of a motor vehicle has an adsorption filter (AF) with an aeration line (BL) which can be closed by a controllable shutoff valve (AV). The closable aeration line makes it possible to set specific negative or excess pressures in the installation in order to test its performance. The performance data so obtained are particularly reliable.

Description

Die Erfindung betrifft eine Tankentlüftungsanlage für ein Kraftfahrzeug und Verfahren zum Überprüfen der Funktionstüchtigkeit einer solchen Anlage.The invention relates to a tank ventilation system for a motor vehicle and a method for checking the functionality of such a system.

Stand der TechnikState of the art

Eine Tankentlüftungsanlage weist generell einen Kraftstofftank und ein Tankentlüftungsventil auf, das mit dem Saugrohr einer Brennkraftmaschine verbunden ist, damit mit Hilfe des Unterdrucks im Saugrohr Kraftstoffdämpfe abgesaugt werden. Üblicherweise wird nicht unmittelbar das über dem Kraftstoff befindliche Volumen im Tank abgesaugt, sondern zwischen den Tank und das Tankentlüftungsventil ist ein Adsorptionsfilter, üblicherweise ein Aktivkohlefilter, zwischengeschaltet. Dieses Aktivkohlefilter adsorbiert Kraftstoff in denjenigen Zeiträumen, in denen kein Absaugen vom Saugrohr her erfolgt, z. B. beim Stillstand der Brennkraftmaschine oder dann, wenn aufgrund des aktuellen Betriebszustandes das Tankentlüftungsventil geschlossen gehalten wird.A tank ventilation system generally has a fuel tank and a tank ventilation valve, which is connected to the intake manifold of an internal combustion engine, so that fuel vapors are drawn off with the aid of the negative pressure in the intake manifold. Usually, the volume in the tank above the fuel is not sucked off directly, but an adsorption filter, usually an activated carbon filter, is interposed between the tank and the tank ventilation valve. This activated carbon filter adsorbs fuel in those periods in which there is no suction from the intake manifold, e.g. B. when the internal combustion engine is at a standstill or when the tank ventilation valve is kept closed due to the current operating state.

Es besteht die Gefahr, daß Tankentlüftungsanlagen undicht werden oder daß das Tankentlüftungsventil nicht ordnungsgemäß arbeitet. Derartige Anlagen sind daher während des Betriebs eines Kraftfahrzeugs wiederholt auf Funktionstüchtigkeit zu überprüfen.There is a risk that tank ventilation systems will leak or that the tank ventilation valve will not work properly. Such systems must therefore be repeatedly checked for functionality during the operation of a motor vehicle.

Das wichtigste Verfahren zum Überprüfen der Funktionstüchtigkeit einer Kraftfahrzeug-Tankentlüftungsanlage beruht auf einem Vorschlag der kalifornischen Umweltbehörde CARB. Nach diesem Verfahren wird beim Öffnen des Tankentlüftungsventiles überprüft, ob ein Lambdaregler eine Korrektur in seinem Stellwert vornehmen muß. Dies ist immer dann der Fall, wenn aus der Tankentlüftungsanlage Luft mit Kraftstoffdampf angesaugt wird. Nun ist es jedoch so, daß das Adsorptionsfilter ganz regeneriert sein kann und daß der Kraftstoff im Tank völlig entgast ist. Dann wird beim Öffnen des Tankentlüftungsventils kein Kraftstoff zusätzlich zu demjenigen geliefert, der gemäß dem Stellwert der Lambdaregelung an die Einspritzventile der Brennkraftmaschine geliefert wird. In einem solchen Fall, in dem also kein Kraftstoff von der Tankentlüftungsanlage geliefert wird, also der Lambdaregler keine Korrektur vornehmen muß, ist unklar, ob die Tankentlüftungsanlage undicht ist oder ob aus den genannten Gründen kein Kraftstoff geliefert wird. Um diese Frage entscheiden zu können, erfolgt gemäß dem bekannten Verfahren eine Auswertung des Signals vom Lambdaregler nur dann, wenn ein Kraftstofftemperaturfühler das Überschreiten einer vorgegebenen Kraftstoffmindesttemperatur anzeigt und ein Tankfüllstandssensor anzeigt, daß das Fahrzeug betankt wurde. Es wird davon ausgegangen, daß dann auf jeden Fall Kraftstoffdampf in der Anlage vorhanden sein müßte, der beim Öffnen des Tankentlüftungsventils angesaugt wird und dann zu einer Korrektur des Lambdareglers führt. Jedoch treten bei diesem Verfahren immer wieder Fehlentscheidungen auf, wenn sich nämlich ausgegaster Kraftstoff im Tank befindet, ebensolcher Kraftstoff nachgetankt wird und das Adsorptionsfilter weitgehend regeneriert ist.The most important method for checking the functionality of a motor vehicle tank ventilation system is based on a proposal from the California environmental agency CARB. According to this method, when the tank ventilation valve is opened, a check is carried out to determine whether a lambda regulator has to correct its manipulated value. This is always the case when air is drawn in with fuel vapor from the tank ventilation system. However, it is now the case that the adsorption filter can be completely regenerated and that the fuel in the tank is completely degassed. Then, when the tank ventilation valve is opened, no fuel is supplied in addition to that which is supplied to the injection valves of the internal combustion engine in accordance with the manipulated variable of the lambda control. In such a case, in which no fuel is supplied by the tank ventilation system, i.e. the lambda regulator does not have to make a correction, it is unclear whether the tank ventilation system is leaking or whether no fuel is being supplied for the reasons mentioned. In order to be able to decide this question, the signal from the lambda controller is only evaluated in accordance with the known method when a fuel temperature sensor indicates that a predetermined minimum fuel temperature has been exceeded and a tank level sensor indicates that the vehicle has been refueled. It is assumed that fuel vapor should then be present in the system in any case, which is sucked in when the tank ventilation valve is opened and then leads to a correction of the lambda regulator. However, wrong decisions always occur with this method, namely when there is outgassed fuel in the tank, such fuel is refilled and the adsorption filter is largely regenerated.

Demgemäß bestand weiterhin das Problem, ein Verfahren zum Überprüfen der Funktionstüchtigkeit einer Kraftfahrzeug-Tankentlüftungsanlage anzugeben, das möglichst wenig unberechtigte Fehlermeldungen ausgibt. Außerdem bestand das Problem, eine Tankentlüftungsanlage anzugeben, deren Funktionstüchtigkeit sich besonders zuverlässig überprüfen läßt.Accordingly, there was still the problem of specifying a method for checking the functionality of a motor vehicle tank ventilation system that outputs as few unauthorized error messages as possible. There was also the problem of specifying a tank ventilation system, the functionality of which can be checked particularly reliably.

Darstellung der ErfindungPresentation of the invention

Die für das erfindungsgemäße Verfahren verwendete Tankentlüftungsanlage für ein Kraftfahrzeug weist folgende Teile auf, wie zum Beispiel aus der US-4 862 856 bekannt:

  • einen Kraftstofftank,
  • ein Adsorptionsfilter, das mit dem Kraftstofftank über eine Filterleitung verbunden ist und das eine Belüftungsleitung mit einem steuerbaren Absperrventil aufweist,
  • und ein Tankentlüftungsventil, das über eine Ventilleitung das Adsorptionsfilter mit dem Saugrohr einer Brennkraftmaschine verbindet.
The tank ventilation system for a motor vehicle used for the method according to the invention has the following parts, as is known, for example, from US Pat. No. 4,862,856:
  • a fuel tank,
  • an adsorption filter which is connected to the fuel tank via a filter line and which has a ventilation line with a controllable shut-off valve,
  • and a tank ventilation valve, which connects the adsorption filter to the intake manifold of an internal combustion engine via a valve line.

Die Absperrbark Keit der Belüftungsleitung des Adsorptionsfilters ermöglicht die im folgenden angegebenen erfindungsgemäßen Verfahren zum Überprüfen der Funktionstüchtigkeit der Anlage. Den Verfahren ist die Idee gemeinsam, daß sie die Absperrbarkeit der Belüftungsleitung des Adsorptionsfilters ausnutzen.The shut-off speed of the ventilation line of the adsorption filter enables the method according to the invention specified below to check the functionality of the system. The processes share the idea that they exploit the shut-off facility of the ventilation line of the adsorption filter.

Das erfindungsgemäße Verfahren zum Überprüfen der Funktionstüchtigkeit einer Kraftfahrzeug-Tankentlüftungsänlage arbeitet so, daß

  • die Belüftungsleitung des Adsorptionsfilters der Anlage abgesperrt wird,
  • das Tankentlüftungsventil der Anlage geöffnet wird,
  • und gemessen wird, ob sich im Tank Unterdruck aufbaut und, falls dies der Fall ist, auf Funktionstüchtigkeit der Anlage geschlossen wird.
The method according to the invention for checking the functionality of a motor vehicle tank ventilation system works in such a way that
  • the ventilation line of the system's adsorption filter is shut off,
  • the system tank vent valve is opened,
  • and it is measured whether vacuum builds up in the tank and, if this is the case, it is concluded that the system is functioning properly.

Um nicht nur die Dichtheit der Anlage und die Unterdruck-Funktionsfähigkeit verschiedener Ventile, sondern die volle Funktionsfähigkeit aller Ventile überprüfen zu können, wird vorteilhafterweise zusätzlich so verfahren, daß

  • die Belüftungsleitung des Adsorptionsfilters der Anlage abgesperrt wird,
  • das Tankentlüftungsventil der Anlage erst geöffnet wird, wenn sich im Tank ein Mindestüberdruck aufgebaut hat und die Brennkraftmaschine, an die die Anlage angeschlossen ist, mit kleinen Luftdurchsätzen arbeitet,
  • und überprüft wird, ob eine Lambdaregelung beim Öffnen des Tankentlüftungsventils eine Korrektur in Richtung Abmagerung ausführen muß und, falls dies der Fall ist, auf die Funktionstüchtigkeit der Anlage geschlossen wird.
In order to be able to check not only the tightness of the system and the vacuum functionality of various valves, but also the full functionality of all valves, the procedure is advantageously also such that
  • the ventilation line of the system's adsorption filter is shut off,
  • the tank ventilation valve of the system is only opened when a minimum overpressure has built up in the tank and the internal combustion engine to which the system is connected operates with low air flow rates,
  • and it is checked whether a lambda control has to make a correction in the direction of leanness when the tank ventilation valve is opened and, if this is the case, it is concluded that the system is functioning properly.

Die Absperrbarkeit der Belüftungsleitung ermöglicht es, ausreichend große Über- und Unterdrücke für ein besonders zuverlässiges Überprüfen der Funktionstüchtigkeit der Anlage einzustellen.The lockability of the ventilation line makes it possible to set sufficiently large overpressures and underpressures for a particularly reliable check of the functionality of the system.

Damit sich im Falle eines Fehlers des Absperrorgans für die Belüftungsleitung keine zu großen Drücke aufbauen, weist das Absperrorgan vorteilhafterweise Überdruck- und Unterdruck-Schutzventile auf. Die Funktionstüchtigkeit des Absperrorgans läßt sich dadurch überprüfen, daß beim Vorliegen von Unterdruck die Belüftungsleitung wieder freigegeben wird. Baut sich daraufhin der Unterdruck ab, ist dies ein Zeichen dafür, daß das Absperrorgan ordnungsgemäß arbeitet.In order that, in the event of a fault in the shut-off element for the ventilation line, excessive pressures are not built up, the shut-off element advantageously has overpressure and underpressure protection valves. The functionality of the shut-off device can be checked by releasing the ventilation line if there is negative pressure. If the vacuum is then reduced, this is a sign that the shut-off device is working properly.

Zeichnungdrawing

Fig. 1Fig. 1
schematische Darstellung einer Tankentlüftungsanlage mit einem Adsorptionsfilter mit absperrbarer Belüftungsleitung;schematic representation of a tank ventilation system with an adsorption filter with lockable ventilation line;
Fig. 2Fig. 2
schematische Darstellung eines bekannten Adsorptionsfilters mit Rückschlagventilen, zum Erläutern, wie die Funktionstüchtigkeit der Rückschlagventile des Filters überprüft werden kann; undschematic representation of a known adsorption filter with check valves to explain how the functionality of the filter check valves can be checked; and
Fig. 3Fig. 3
Flußdiagramm zum Erläutern eines Verfahrens zum Überprüfen der Funktionstüchtigkeit einer Kraftfahrzeug-Tankentlüftungsanlage, das sowohl mit einer Prüfung bei Unterdruck wie auch einer solchen bei Überdruck arbeitet.Flow diagram for explaining a method for checking the functionality of a motor vehicle tank ventilation system, which works with both a test for negative pressure and one for positive pressure.
Beschreibung von AusführungsbeispielenDescription of exemplary embodiments

Fig. 1 zeigt schematisch eine Tankentlüftungsanlage mit einem Kraftstofftank KT, einem Adsorptionsfilter AF und einem Tankentlüftungsventil TEV. Letzteres liegt in einer Ventilleitung VL, die das Adsorptionsfilter AF mit dem Saugrohr SR einer nicht dargestellten Brennkraftmaschine verbindet. Die Ventilleitung mündet in Strömungsrichtung L angesaugter Luft hinter der Drosselklappe. Dadurch ist es möglich, einen relativ hohen Unterdruck in der Ventilleitung zu erzielen, um dadurch das Adsorptionsfilter AF wirksam zu spülen. Bei weitgehend geschlossener Drosselklappe und höheren Drehzahlen fällt der Unterdruck bis auf einige wenige 100 hPa.Fig. 1 shows schematically a tank ventilation system with a fuel tank KT, an adsorption filter AF and a tank ventilation valve TEV. The latter lies in a valve line VL, which connects the adsorption filter AF to the intake manifold SR of an internal combustion engine, not shown. The valve line opens air sucked in the flow direction L behind the throttle valve. This makes it possible to achieve a relatively high negative pressure in the valve line in order to effectively rinse the adsorption filter AF. With the throttle valve largely closed and at higher speeds, the negative pressure drops to a few 100 hPa.

Das Adsorptionsfilter AF wiederum ist mit dem Kraftstofftank KT über eine Filterleitung FL verbunden. Gast der Kraftstoff im Kraftstofftank, wird der ausgasende Kraftstoff von Aktivkohle im Adsorptionsfilter AF adsorbiert. Außer der eben genannten Filterleitung FL und der Ventilleitung VL mündet noch eine Belüftungsleitung BL in das Adsorptionsfilter AF. Durch diese Belüftungsleitung BL strömt Luft, wenn das Adsorptionsfilter AF über die Ventilleitung mit dem Tankentlüftungsventil TEV abgesaugt wird. Dadurch wird die Aktivkohle regeneriert. In Stillstandsphasen des Motors oder in Betriebsphasen, in denen das Tankentlüftungsventil geschlossen ist, kann die Aktivkohle dann wieder Kraftstoff aufnehmen.The adsorption filter AF is in turn connected to the fuel tank KT via a filter line FL. If the fuel is in the fuel tank, the outgassing fuel is adsorbed by activated carbon in the adsorption filter AF. In addition to the filter line FL just mentioned and the valve line VL, a ventilation line BL also opens into the adsorption filter AF. Air flows through this ventilation line BL when the adsorption filter AF is sucked off via the valve line with the tank ventilation valve TEV. This regenerates the activated carbon. The activated carbon can then absorb fuel again when the engine is at a standstill or in operating phases in which the tank ventilation valve is closed.

Die in Fig. 1 dargestellte Tankentlüftungsanlage weist aufgrund noch zu beschreibender Bauteile einen Aufbau auf, der sich besonders sicher auf Funktionstüchtigkeit überprüfen läßt. Diese zusätzlichen Bauteile sind ein Differenzdruckmesser DDM, der den Differenzdruck im Tank gegenüber dem Atmosphärendruck mißt, und ein Absperrventll zum steuerbaren Absperren der Belüftungsleitung BL. Das Absperrventil AV läßt sich mit Hilfe eines Signals öffnen oder schließen, das von einem Steuergerät SG ausgegeben wird. Nach welchen Gesichtspunkten Signale ausgegeben werden, wird weiter unten anhand von Fig. 3 erläutert.The tank ventilation system shown in Fig. 1 has a structure due to components to be described, which can be checked particularly reliably for functionality. These additional components are a differential pressure meter DDM, which measures the differential pressure in the tank relative to atmospheric pressure, and a shut-off valve for controllably shutting off the ventilation line BL. The shut-off valve AV can be opened or closed with the aid of a signal which is output by a control unit SG. The criteria according to which signals are output are explained below with reference to FIG. 3.

Damit sich in der Tankentlüftungsanlage kein zu hoher oder kein zu tiefer Druck aufbauen kann, wenn das Absperrventil AV nicht ordnungsgemäß arbeitet, mündet noch die Leitung einer Schutzventilanordnung SVA in die Belüftungsleitung BL, welche Schutzventilanordnung ein Überdruck- und ein Unterdruck-Schutzventil aufweist. Die Drücke in der Schutzventilanordnung sind so eingestellt, daß keine Beschädigungsgefahr für die Tankentlüftungsanlage wegen zu hoher oder zu niedriger Drücke entsteht.So that no too high or no too low pressure can build up in the tank ventilation system if the shut-off valve AV does not work properly, the line of a protective valve arrangement SVA also opens into the ventilation line BL, which protective valve arrangement has an overpressure and a vacuum protection valve. The pressures in the protective valve arrangement are set in such a way that there is no risk of damage to the tank ventilation system because the pressures are too high or too low.

Fig. 2 zeigt ein Adsorptionsfilter AF.2, das mit einer Rückschlagventilanordnung ausgestattet ist. Ein Tanksperrventil TSV sorgt dafür, daß Kraftstoffgas nur dann ins Adsorptionsfilter AF gelangt, wenn ein bestimmter Überdruck im Kraftstofftank KT überschritten wird, z. B. 30 hPa. Da dieses Tanksperrventil TSV das Belüften des Tanks bei Unterdruck verhindert, ist zusätzlich ein Tankbelüftungsventil TBV vorhanden, das z. B. bei einem Unterdruck von 30 hPa im Tank öffnet. Um zu verhindern, daß Kraftstoffdampf aus dem Adsorptionsfilter AF in das Saugrohr SR ausdampfen kann, was insbesondere für Heißstarts einer Brennkraftmaschine nachteilig wäre, ist ein Filtersperrventil FSV vorhanden, das den Weg in die Ventilleitung VL erst bei Unterschreiten eines gewissen Unterdrucks in dieser freigibt, z. B. bei einem Druckabfall auf weniger als 50 hPa.Fig. 2 shows an adsorption filter AF.2, which is equipped with a check valve arrangement. A tank shut-off valve TSV ensures that fuel gas only reaches the adsorption filter AF when a certain excess pressure in the fuel tank KT is exceeded, e.g. B. 30 hPa. Since this tank shut-off valve TSV prevents the tank from being vented under negative pressure, a tank ventilation valve TBV is also available. B. opens at a vacuum of 30 hPa in the tank. In order to prevent fuel vapor from evaporating from the adsorption filter AF into the intake manifold SR, which would be disadvantageous in particular for hot starts of an internal combustion engine, a filter shut-off valve FSV is present, which only opens the way into the valve line VL when the vacuum drops below a certain level, e.g. . B. with a pressure drop to less than 50 hPa.

In der Tankentlüftungsanlage gemäß Fig. 1 können verschiedene Fehler auftreten. So ist es bei sämtlichen Bauteilen möglich, daß sie undicht werden. Das Tankentlüftungsventil TEV und das Absperrventil AB können darüber hinaus funktionsuntüchtig werden. Beim Adsorptionsfilter AF.2 gemäß Fig. 2 können die Rückschlagventile funktionsunfähig werden.Various errors can occur in the tank ventilation system according to FIG. 1. It is therefore possible for all components to leak. The tank vent valve TEV and the shut-off valve AB can also become inoperative. With the adsorption filter AF.2 according to FIG. 2, the check valves can become inoperative.

Anhand von Fig. 3 wird beispielshaft erläutert, wie die Funktionsfähigkeit der Tankentlüftungsanlage gemäß Fig. 1 überprüft werden kann. Das Verfahren ermöglicht es auch, Fehler in einem Absorptionsfilter AF.2 gemäß Fig. 2, also mit Rückschlagventilen, aufzufinden.3 explains how the functionality of the tank ventilation system according to FIG. 1 can be checked. The method also makes it possible to find faults in an absorption filter AF.2 according to FIG. 2, that is to say with check valves.

Nach dem Start des Verfahrens gemäß Fig. 3 wird in einem Schritt s1 die Belüftungsleitung BL abgesperrt, was durch entsprechendes Ansteuern des Absperrventils AV erfolgt. Dieser Verfahrensschritt des Absperrens des Belüftungsventils ist ein entscheidender Schritt für alle im folgenden erläuterten Verfahrensvarianten.After the start of the method according to FIG. 3, the ventilation line BL is shut off in a step s1, which is done by correspondingly actuating the shutoff valve AV. This process step of shutting off the ventilation valve is a decisive step for all the process variants explained below.

In einem Schritt s2 wird abgefragt, ob eine Prüfung mit Unterdruck in den Schritt s3 bis s9 ausgeführt werden soll. Eine solche Prüfung kann z. B. in festen Zeitabständen erfolgen. Soll keine Prüfung mit Unterdruck erfolgen, schließen sich an Schritt s2 Verfahrensschritte s10 bis s16 an, die Überdruck in der Anlage nutzen. Die Prüfung mit Hilfe von Überdruck kann ebenfalls in festen Zeitabständen erfolgen, oder anschließend an eine Prüfung mit Unterdruck.In a step s2, a query is made as to whether a test with negative pressure should be carried out in steps s3 to s9. Such a test can e.g. B. at fixed time intervals. If no vacuum test is to be carried out, step s2 is followed by process steps s10 to s16, which use overpressure in the system. The test with the help of overpressure can also take place at fixed time intervals, or after a test with underpressure.

Gemäß Schritt s3 wird das Tankentlüftungsventil TEV geöffnet. Da die Belüftungsleitung BL geschlossen ist, muß sich nun Unterdruck in der Tankentlüftungsanlage aufbauen, sofern diese dicht ist. Um dies feststellen zu können, wird zunächst in einem Schritt s4 der vom Differenzdruckmesser DDM gemessene Druck abgefragt. Ergibt sich in einem Schritt s5, daß kein Unterdruck mit einem Absolutwert über einem vorgegebenen Schwellwert (z.B. 50 hPa (Unterdruck)) erhalten wird, wird in einem Schritt s6 eine Fehlermeldung ausgegeben. Bei gewissen Betriebszuständen kann eine Auswertung ausgeschlossen werden, z. B. Vollast, da dann im Saugrohr fast Atmosphärendruck herrscht und sich somit kein wesentlicher Unterdruck in der Tankentlüftungsanlage aufbauen kann.According to step s3, the tank ventilation valve TEV is opened. Since the ventilation line BL is closed, negative pressure must now build up in the tank ventilation system if it is tight. In order to be able to determine this, the pressure measured by the differential pressure meter DDM is first queried in a step s4. It is determined in a step s5 that no negative pressure with an absolute value above a predetermined threshold value (eg 50 hPa (negative pressure)) is obtained, an error message is output in step s6. In certain operating conditions, an evaluation can be excluded, e.g. B. full load, since then there is almost atmospheric pressure in the intake manifold and thus no significant negative pressure can build up in the tank ventilation system.

Nach Ausgeben der Fehlermeldung im Schritt s6 wird das Ende des Verfahrens erreicht. Andernfalls folgt ein Schritt s7, in dem die Belüftungsleitung durch Öffnen des Absperrventils AV wieder freigegeben wird. In einem Schritt s8 wird überprüft, ob der vom Differenzdruckmesser DDM gemessene Wert des Unterdrucks fällt. Ist dies der Fall, wird das Ende des Verfahrens erreicht. Andernfalls wird in einem Schritt s9 eine Fehlermeldung ausgegeben, die anzeigt, daß das Absperrventil AV nicht mehr ordnungsgemäß öffnet. Durch die Schritte s1 - s9 ist eine Undichtheit und somit Fehlfunktion des Systems schon vollständig prüfbar.After the error message has been output in step s6, the end of the method is reached. Otherwise, a step s7 follows in which the ventilation line is released again by opening the shut-off valve AV. In a step s8 it is checked whether the value of the negative pressure measured by the differential pressure meter DDM falls. If this is the case, the end of the procedure is reached. Otherwise, an error message is output in a step s9, which indicates that the shut-off valve AV no longer opens properly. A leakage and thus malfunction of the system can already be fully checked through steps s1-s9.

Wird in Schritt s2 nach Ablauf der beschriebenen Überprüfung mit Unterdruck auf die Lambdakorrekturprüfung mit Überdruck umgeschaltet, wird in einem Schritt s10 das Tankentlüftungsventil geschlossen, und die Belüftungsleitung BL wird durch Schließen des Absperrventils AV gesperrt. In einem Schritt s11 wird der vom Differenzdruckmesser DDM erfaßte Differenzdruck für den Kraftstofftank KT abgefragt. Anschließend wird überprüft (Schritt s12), ob ein Überdruck vorhanden ist, der über einer vorgegebenen Schwelle liegt, z. B. bei mehr als 30 hPa. Ist dies nicht der Fall, schließen sich die Schritte s11 und s12 wiederholt so lange an, bis ein Überdruck über der genannten Schwelle erreicht wird, oder bis in einem Schritt s13 zwischen den Schritten s12 und s11 festgestellt wird, daß eine Prüfendebedingung eingetreten ist. Hierbei kann es sich z. B. um das Ablaufen einer Zeitspanne seit dem Start des Überprüfens auf das Erreichen des vorgegebenen Überdrucks handeln. Die Prüfendebedingung kann jedoch auch im Erreichen vorgegebener Betriebszustände bestehen. Tritt die Prüfendebedingung ein, wird unmittelbar das Ende des Verfahrens erreicht. Da unter Umständen (z. B. bei ausgegastem Kraftstoff) sich nie ein Überdruck aufbaut, kann es sein, daß die Druckschwelle nie erreicht wird. Die folgenden Prüfschritte liefern also nur noch zusätzhliche Aussagen zur Unterdruckprüfung und genügen nicht als alleiniges Fehlerkriterium.If, in step s2, after the described check with negative pressure has been switched over to the lambda correction check with positive pressure, the tank ventilation valve is closed in step s10 and the ventilation line BL is blocked by closing the shut-off valve AV. In a step s11, the differential pressure for the fuel tank KT detected by the differential pressure meter DDM is queried. It is then checked (step s12) whether there is an overpressure that lies above a predetermined threshold, e.g. B. at more than 30 hPa. If this is not the case, steps s11 and s12 are repeated until an overpressure above the specified threshold is reached, or until a step s13 between steps s12 and s11 is determined that an end of test condition has occurred. This can be, for. B. can be the expiration of a period of time since the start of the check for reaching the predetermined positive pressure. However, the test end condition can also consist in reaching predetermined operating states. If the test end condition occurs, the end of the Procedure reached. Since an overpressure never builds up under certain circumstances (e.g. with outgassed fuel), it may happen that the pressure threshold is never reached. The following test steps therefore only provide additional information on the vacuum test and are not sufficient as the sole error criterion.

Sobald Schritt s12 ergibt, daß der vorgegebene Überdruck überschritten wurde, wird in einem Schritt s14 das Tankentlüftungsventil TEV geöffnet. Dadurch wird der Brennkraftmaschine plötzlich Kraftstoff zusätzlich zu demjenigen zugeführt, der ohnehin eingespritzt wird. Die Lambdaregelung muß dann die einzuspritzende Kraftstoffmenge verringern. In einem Schritt s15 wird überprüft, ob mit dem Öffnen des Tankentlüftungsventils in Schritt s14 eine Mager-Korrektur in der Lambdaregelung erforderlich wird. Ist dies der Fall, ist nochmals bestätigt, daß die Tankentlüftungsanlage in erwarteter Weise Kraftstoff geliefert hat. Es wird dann das Ende des Verfahrens erreicht. Andernfalls wird in einem Schritt s16 eine Fehlermeldung ausgegeben. Wenn die vorausgehende Unterdruckprüfung schon einen Fehler ergab, ist nun nachgewiesen, daß die Verbindungsleitung Saugrohr - Tankentlüftungsventil unterbrochen ist.As soon as step s12 shows that the predetermined overpressure has been exceeded, the tank ventilation valve TEV is opened in step s14. As a result, fuel is suddenly supplied to the internal combustion engine in addition to that which is injected anyway. The lambda control must then reduce the amount of fuel to be injected. In a step s15, it is checked whether a lean correction in the lambda control is required when the tank ventilation valve is opened in step s14. If this is the case, it is confirmed again that the tank ventilation system has delivered fuel in the expected manner. The end of the procedure is then reached. Otherwise, an error message is output in step s16. If the previous vacuum test already showed an error, it has now been proven that the connection pipe between the intake manifold and the tank ventilation valve is interrupted.

Wenn in Schritt s14 das Tankentlüftungsventil TEV geöffnet wird, baut sich in der Tankentlüftungsanlage ein Unterdruck auf. Der realisierbare Unterdruck reicht in der Regel aus, Kraftstoff im Kraftstofftank KT zum Verdampfen zu bringen und somit Kraftstoff durch die Ventilleitung VL in das Saugrohr SR zu liefern. Es ist jedoch zu beachten, daß der Unterdruck einige 10 hPa nicht unterschreiten darf, da ansonsten Implosionsgefahr für den Kraftstofftank KT besteht. Der Unterdruck ist dementsprechend durch die Schutzventilanordnung SVA begrenzt. Um dennoch sicherzustellen, daß für die Lambdakorrekturprüfung bei funktionstüchtiger Tankentlüftungsanlage auf jeden Fall Kraftstoffdampf zur Verfügung stehen muß, wird die Prüfung nur ausgeführt, wenn zuvor Überdruck im Tank vorlag. Dieser Überdruck läßt sich jedoch, wie schon oben erwähnt, trotz gesperrter Belüftungsleitung BL nicht in allen Fällen gewährleisten.If the tank ventilation valve TEV is opened in step s14, a negative pressure builds up in the tank ventilation system. The realizable negative pressure is usually sufficient to vaporize fuel in the fuel tank KT and thus to deliver fuel through the valve line VL into the intake manifold SR. However, it should be noted that the vacuum must not fall below a few 10 hPa, otherwise there is a risk of implosion for the KT fuel tank. The negative pressure is accordingly limited by the protective valve arrangement SVA. In order to ensure that fuel vapor must be available for the lambda correction test in a functioning tank ventilation system, the test is only carried out if there was previously overpressure in the tank. However, as already mentioned above, this overpressure cannot be guaranteed in all cases despite the blocked ventilation line BL.

Die vorgenannten Verfahrensabläufe prüfen zugleich die Funktionsfähigkeit eines Adsorptionsfilters AF.2 mit Rückschlagventilen TSV, TBV und FSV gemäß Fig. 2. Stellt sich in Schritt s5 heraus, daß sich der erwartete Unterdruck aufbaut, ist dies ein Zeichen dafür, daß die Ventile TSV und FSV durchgängig sind. Stellt sich der erwartete Unterdruck nicnt ein, ist entweder eines dieser beiden Ventile verstopft oder das Tänkentlüftungsventil TEV oder die Anlage ist undicht. Steigt der Druck im Tank KT bei geöffneter Belüftungsleitung BL über einen zulässigen Wert, ist das Rückschlagventil TSV verstopft. Sinkt der Druck im Tank bei geöffneter Belüftungsleitung BL, zeigt dies an, daß das Tankbelüftungsventil TBV verstopft ist. In entsprechender Weise ist auch eine Funktionsprüfung der Schutzventilanordnung SVA möglich; es dürfen keine Unterdrücke oder Überdrücke auftreten, deren Absolutwerte die Werte der Schutzdrücke überschreiten.The above-mentioned procedures also check the functionality of an adsorption filter AF.2 with check valves TSV, TBV and FSV according to FIG. 2. If it is found in step s5 that the expected negative pressure builds up, this is a sign that the valves TSV and FSV are consistent. If the expected vacuum is not reached, either one of these two valves is blocked or the dance vent valve TEV or the system is leaking. If the pressure in the tank KT rises above a permissible value with the ventilation line BL open, the check valve TSV is clogged. If the pressure in the tank drops when the ventilation line BL is open, this indicates that the tank ventilation valve TBV is clogged. In a corresponding manner, a functional test of the protective valve arrangement SVA is also possible; no negative pressures or overpressures may occur, the absolute values of which exceed the values of the protective pressures.

Abschließend sei nochmals darauf hingewiesen, daß für die beschriebene Tankentlüftungsanlage wesentlich ist, daß sie eine absperrbare Belüftungsleitung aufweist und daß mit Hilfe dieser absperrbaren Belüftungsleitung Verfahren zum Überprüfen der Funktionstüchtigkeit der Anlage möglich sind, die insbesondere mit Unterdruck, und eventuell zusätzlich mit überdruck in der Anlage arbeiten. Von Bedeutung ist, daß nach beiden Seiten ausreichend hohe Drücke eingestellt werden und vor allem, daß steuerbar ist, ob Über- oder Unterdruck herrschen soll. Bei einer Tankentlüftungsanlage mit einem Adsorptionsfilter AF.2 gemäß Fig. 2 mit Rückschlagventilen und ohne Absperrventil AV kann zwar ebenfalls Über- oder Unterdruck in einem Kraftstofftank KT herrschen, jedoch können die Drücke nicht zuverlässig eingestellt werden. Basiert die Prüfung nur auf Kontrolle der Mager-Korrektur der Lambdaregelung bei Überdruck, ist z. B. nicht sicher, ob sich der Überdruck gegebenenfalls wegen einer Undichtheit nicht aufbaut oder ob ausgegaster Kraftstoff im Tank ist.Finally, it should be pointed out again that it is essential for the tank ventilation system described that it has a lockable ventilation line and that with the help of this lockable ventilation line, methods for checking the functionality of the system are possible, particularly with negative pressure and possibly also with excess pressure in the system work. It is important that sufficiently high pressures are set on both sides and, above all, that it is controllable whether overpressure or underpressure should prevail. In a tank ventilation system with an adsorption filter AF.2 according to FIG. 2 with check valves and without a shut-off valve AV, there may also be overpressure or underpressure in a fuel tank KT, but the pressures cannot be set reliably. If the test is based only on checking the lean correction of the lambda control at excess pressure, z. B. not sure whether the excess pressure may not build up due to a leak or whether there is outgassed fuel in the tank.

Claims (3)

  1. Method for testing the operativeness of a motor vehicle tank ventilation system having an adsorption filter with ventilation line, which filter connects a fuel tank to the inlet pipe of an internal combustion engine via a tank ventilation valve, characterised in that
    - the ventilation line of the adsorption filter is shut off,
    - the tank ventilation valve is opened,
    - and it is measured whether underpressure is building up in the tank and, if this is the case, it is concluded that the system is operative.
  2. Method according to Claim 1, characterised in that, when underpressure is present, the ventilation line is released again and whenever the underpressure falls away, it is concluded that the shut-off valve for the ventilation line is operating correctly.
  3. Method according to one of Claims 1 or 2, characterised in that
    - the ventilation line of the adsorption filter is shut off,
    - the tank ventilation valve is not opened until a minimum overpressure has built up in the tank and the internal combustion engine is operating at low rates of airflow,
    - and it is tested whether a lambda controller has to carry out a correction in the direction of leanness when the tank ventilation valve is opened and, if this is the case, it is concluded that the system is operative.
EP91901685A 1990-02-08 1991-01-09 Installation for venting the petrol tank of a motor vehicle and process for testing its performance Expired - Lifetime EP0466850B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4003751 1990-02-08
DE4003751A DE4003751C2 (en) 1990-02-08 1990-02-08 Tank ventilation system for a motor vehicle and method for checking its functionality
PCT/DE1991/000010 WO1991012426A1 (en) 1990-02-08 1991-01-09 Installation for venting the petrol tank of a motor vehicle and process for testing its performance

Publications (2)

Publication Number Publication Date
EP0466850A1 EP0466850A1 (en) 1992-01-22
EP0466850B1 true EP0466850B1 (en) 1996-12-11

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EP (1) EP0466850B1 (en)
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WO (1) WO1991012426A1 (en)

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DE59108403D1 (en) 1997-01-23
EP0466850A1 (en) 1992-01-22
JP3036703B2 (en) 2000-04-24
KR100236136B1 (en) 2000-01-15
KR920701651A (en) 1992-08-12
US5193512A (en) 1993-03-16
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JPH04505491A (en) 1992-09-24
DE4003751A1 (en) 1991-08-14

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