EP0392589A1 - Process for the treatment of heavy chlorination residues - Google Patents

Abstract

A process for the treatment of heavy residues originating from the manufacture of chlorinated products in which a chemical compound chosen from certain fatty compounds is added to the heavy residues in order to form fluid and stable liquid suspensions. <IMAGE>

Description

The present invention relates to a process for the treatment of heavy residues resulting from the manufacture of chlorinated products in which a chemical compound chosen from certain fatty compounds is added to the heavy residues in order to form fluid and stable liquid suspensions.

The chlorination processes and more particularly the chlorination processes of C₁ to C₄ hydrocarbons; often performed at high temperature, generate the formation of heavy residual by-products containing chlorinated hydrocarbons such as hexachloroethane, hexachlorobutadiene and hexachlorobenzene.

Such heavy residues pose various technical and ecological problems such as:
- the need to recover and separate the recoverable organic products still embedded in the residues,
- the disposal in an ecologically acceptable manner of products which cannot be reused industrially.

These various problems, resolved in a more or less fragmentary manner in existing industrial installations, require continuous monitoring from an industrial point of view in order to increase the yields of recovery of recoverable products on the one hand and on the other hand. '' from an ecological point of view in order to make discharges into the surrounding environment harmless and in accordance with increasingly critical ecological requirements.

One solution, recently proposed in United States patent 4,540,837, consists in dissolving the heavy chlorination residues at temperatures between 100 ° and 180 ° C. in tarry hydrocarbons obtained as by-products of the pyrolysis of 1, 2-dichloroethane and / or in hydrocarbons having a low content of aromatic products with a boiling point between 160 ° and 300 ° C and finally incinerate the solutions thus obtained.

This process, which makes it possible, by the incineration stage, to eliminate the current need for underground storage of products such as hexachlorobenzene, however still has a certain number of drawbacks. Thus, for proper operation, it requires very high dilutions, otherwise it does not prevent the settling of certain products, such as hexachlorobenzene, described above as non-recoverable. Furthermore, when it is carried out under ideal conditions, i.e. with perfect solutions, it requires quantities of diluent such that it finally becomes necessary to burn up to ten times the quantity of residues used. However, it is clear that such an operation results in the loss of products which may still be recoverable and, although it is coupled with recovery of hydrochloric acid, causes an excess of other non-gaseous gases to be released into the atmosphere. desired in direct relation to the quantities of materials incinerated.

We have now found a process for treating chlorination residues which no longer has the drawbacks of the aforementioned process in which the residues are dissolved in an excess of diluent and which makes the elimination of the residues by incineration usable in practice. This process makes it possible to incinerate the chlorination residues without the need to resort to intolerable excess of materials to be incinerated and without unnecessary loss of raw materials.

The present invention relates for this purpose to a process for treating heavy residues resulting from the manufacture of chlorinated hydrocarbons according to which one or more chemical compounds chosen from fatty acids, fatty alcohols or fatty esters are added to the heavy residues.

Heavy residues resulting from the production of chlorinated hydrocarbons are understood to mean any residue of chlorinated hydrocarbons containing heavy impurities such as hexachlorobenzene, having below 100 to 120 ° C a settling phenomenon due to the formation of crystals of these heavy impurities.

Usually the process of the invention is carried out with heavy residues of chlorinated hydrocarbons of which at least 5% by weight of the total composition consists of hexachlorobenzene. Generally one operates on residues of which at least 10% by weight of the total composition consists of hexachlorobenzene.

Preferably, the heavy residues treated contain other residual products, such as hexachlorobutadiene and / or hexachlorethane; in this case, the operation is usually carried out with heavy residues of chlorinated hydrocarbons of which at least 20% and preferably 30% by weight of the total composition consist of hexachlorobenzene and hexachlorobutadiene. The good results observed with the process of the invention are illustrated in Example 1 with a composition of heavy residues of chlorinated hydrocarbons containing 50% by weight of perchlorethylene, 25% by weight of hexachlorobutadiene and 25% by weight of hexachlorobenzene.

Finally, the process of the invention is particularly advantageous when it is carried out on compositions containing at least 50% and preferably at least 90 to 95% or even 100% by weight of perchlorinated compounds such as hexachlorethane, hexachlorobutadiene and hexachlorobenzene. Good results observed with such compositions are illustrated in Example 3 with a composition of heavy residues of chlorinated hydrocarbons containing 50% by weight of hexachlorobutadiene and 50% by weight of hexachlorobenzene.

The heavy residues of chlorinated hydrocarbons used in the process of the invention usually come from the chlorination of hydrocarbons containing from 1 to 4 carbon atoms and preferably containing from 1 to 3 carbon atoms; the starting hydrocarbons can be aliphatic or olefinic in nature and optionally already be substituted by halogen atoms such as chlorine. Preferably one implements heavy residues from the manufacture of tetrachloromethane, perchlorethylene, trichlorethylene or chlorinated pyrolysis or not of compounds containing up to 3 carbon atoms.

The chemical compounds chosen from fatty acids, fatty alcohols and fatty esters generally used according to the method of the invention are usually chosen from chemical compounds of these families containing at least 12 to 25 carbon atoms. with fatty acids, such as hydroxy acids with or without side hydrocarbon chains, fatty alcohols and so-called saturated or unsaturated fatty esters containing from 16 to 25 carbon atoms or a mixture of these and very particularly preferred are the technical stearic acid, hydroxyl acids and lanolin esters; the best results have been obtained with technical stearic acid.

In addition to pure chemical compounds, mixtures of fatty compounds as defined above can be used. An advantageous form which can be used in the context of the present invention consists of course in using the fatty compounds in the form of so-called "technical" quality.

The chemical compounds chosen from fatty acids, alcohols and esters are generally used in the present invention in an amount of 2 to 60% by weight of the total composition used. Usually from 5 to 50% by weight of these chemical compounds are used relative to the total composition. Good results have been observed with 10% to 50% by weight of stearic acid in compositions consisting of a 50/50 mixture of hexachlorobutadiene and hexachlorobenzene.

In addition to the chemical compounds chosen from acids, alcohols and fatty esters, it is advantageous to use in the compositions products such as heavy hydrocarbons having a boiling point above 150 ° C. measured under a pressure of one atmosphere. . Examples of such products include kerosene and other light or heavy fuels; of preferably, however, at this level, for obvious ecological reasons, heavy fuel oil preferably free of SO₂ is used.

The method according to the present invention allows the suspension of heavy impurities, such as hexachlorobenzene, present in the heavy residues resulting from the manufacture of chlorinated hydrocarbons and thus causing a fluidization of the heavy residues. This fluidization in the form of a suspension allows an easy circulation of a homogeneous suspension at a relatively low temperature and easy pumping of the suspension in order to bring it at the desired time to the incinerator.

The suspension of heavy residues added with chemical compounds according to the process of the invention can be done by any known means and is usually done using mechanical means such as stirring. Depending on the particular composition of the heavy residues to be treated, the agitation can be more or less violent.

When the composition of heavy residues of chlorinated hydrocarbons consists almost exclusively of non-recoverable heavy products such as hexachloroethane, hexachlorobutadiene and hexachlorobenzene, mechanical suspension must be used for the suspension allowing violent agitation such as 'obtained by violent crushing in devices of the agitator-grinder type. Thus, in the case of a heavy residue containing 50% by weight of hexachlorobutadiene and 50% of hexachlorobenzene, it is necessary for the suspension to resort to mixing for 3 minutes in an agitator-grinder whose propeller rotates at less at 10,000 and preferably at 15,000 rpm. In this specific case, crushing turns out to be an important operation for obtaining stable suspensions at low temperature.

The temperature at which the chemical compound chosen from fatty acids, alcohols and esters is added to the heavy residues consisting only of non-recoverable products, such as hexachlorobutadiene and hexachlorobenzene, also appears to be an important parameter for obtaining good fluid and stable suspensions. Generally this addition is carried out at temperatures between 60 and 200 ° C. The preferred temperatures for this addition are between 65 and 150 ° C. Finally, good results are generally obtained when the addition is carried out around 80 ° C.

The pressure at which the process is carried out is generally between 1 and 50 bars. Good results have been obtained at atmospheric pressure.

The addition of chemical compounds in the process according to the invention can be carried out at any time before, during or after mechanical crushing of heavy residues but, for practical reasons, is generally done just before the mechanical operation of suspending.

Although the Applicant does not wish to be bound or limited in these claims by any theoretical explanation of the phenomenon of suspending and maintaining stable suspension of heavy residues by the process of the invention, it nevertheless seems to him useful to provide the following explanations apply to residues consisting only of non-recoverable heavy residues as defined above.

Indeed, measurements under the microscope make it possible to distinguish for a heavy residue consisting of hexachlorobutadiene and hexachlorobenzene in a 50/50 ratio that:
on the one hand, the dimensions of the crystals present in the medium are practically identical for a residue:
- after crushing in an agitator-grinder for 3 minutes at 80 ° C and
- after subsequent reheating to 150 ° C and then cooling to 80 ° C when after crushing, 20% stearic acid is added to the heavy starting residue (fig. 1 and 2), and
on the other hand, the dimensions of the crystals present in the medium are very different for the residue:
- after crushing in an agitator-grinder for 3 minutes at 80 ° C and
- after subsequent reheating to 150 ° C then cooling to 80 ° C when no chemical compound is added to the heavy starting residue (fig. 3 and 4). Consequently, the effect of the chemical compounds added seems to be a stabilizing effect on the crystal size, ie an effect inhibiting the growth and agglomeration of the crystals and consequently a stabilizing of the suspensions, which therefore remain fluid when they are maintained above 50 ° C., and this probably due to a coating of the small crystals present in the heavy residues with the particular chemical compounds added.

The suspensions obtained according to the process of the invention remain stable and fluid up to temperatures as low as 50 ° C. In addition, after solidification, they can be resuspended by simple reheating without affecting their stability and fluidity. In addition, the suspensions keep their properties also after being subjected to high temperatures of the order of 250 to 300 ° C (as for example in an incinerator preheater). It follows from the above that the suspensions obtained by the process of the invention are in an ideal form for incineration with intermediate storage of the products to be incinerated. Indeed, the storage and circulation of these products can be carried out at relatively low temperatures without risk of settling and solidification in the apparatus in normal operation. Furthermore, if for any reason the heating of the installation cannot be ensured continuously, the resuspension can be ensured by simple reheating of the installation without any other purging operation, etc.

The process according to the invention can be carried out in any installation making it possible to combine the operating conditions described above. A general diagram of an installation is shown in FIG. 5. This installation comprises a column for the separation or distillation of light products and heavy products 1, a pump 2, a temperature exchanger 3 making it possible to heat the starting product. The hot heavy product from column 1 is brought via a line 4 to a buffer tank 5. The heavy product is withdrawn from this buffer tank 5 by a pipe 6 in which the chemical compound or compounds according to the invention are brought via the pipe 7 which are stored in the tank 31. From there a pipe 8 transfers the heavy product to a grinding pump 9 and via line 10 into a heat exchanger 11. The product is then sent via line 12 into a tank 13 provided with an agitator 14 and a heating system 15. From this tank 13 fitted with a degassing line 16, the heavy product is either recycled through line 17 to the grinding pump 9 or transferred to a buffer tank 19 through line 18. The buffer tank 19 is equipped with an agitator 21 and d a heating system 29. The heavy product is then either recycled via the pump 28 via the line 20 into the tank 19, or transferred via the pump 30 via the line 22. The product is transferred via the line 22 or via the line e 24 to a tank 25 to be stored, either via line 23 to an incinerator 26, the burnt products are transferred via line 27.

The invention is illustrated by the following examples.

Example 1R

1 kg of a mixture originating from the manufacture of trichlorethylene and containing 250 g of hexachlorobenzene, 250 g of hexachlorobutadiene and 500 g of perchlorethylene at 200 ° C. are used at atmospheric pressure.

This mixture is cooled to 80 ° C. and grinding is carried out for 3 minutes in a mixer having a propeller with 3 blades of 50 mm in diameter which rotates at 15,000 rpm.

A very fluid solution is obtained containing fine crystals which decant.

Example 2

1 kg of a mixture identical to that of Example 1R is brought to ambient temperature at atmospheric pressure.

200 g of technical grade stearic acid are added to this mixture.

It is brought to a boil at 200 ° C., a solution is obtained.

It is cooled to 80 ° C. and grinding is carried out for 3 minutes in a mixer having a 3-blade propeller of 50 mm in diameter which rotates at 15,000 rpm.

A suspension is obtained, which no longer settles, with a kinematic viscosity of 1.6 degrees Engler measured at 80 ° C. (about 6 centistokes, reference standard Afnor NFT 60100).

Examples 3, 4 and 5

1 kg of a composition of heavy residues of chlorinated hydrocarbons containing 50% by weight of hexachlorobutadiene and 50% by weight of hexachlorobenzene is used.

200 g of stearic acid are added to this composition at 80 ° C. for example 3, at 150 ° C. for example 4, at 220 ° C. for example 5.

The mixture is cooled to 80 ° C. with slow stirring and grinding is carried out for 3 minutes in a mixer similar to that described in Example 2.

Pumpable suspensions are obtained which do not settle. The kinematic viscosities obtained measured at 80 ° C are collated in Table 1. Table 1 EXAMPLES KINEMATIC VISCOSITY DEGREES ENGLER CENTISTOKES 3 1.6 6 4 1.6 6 5 1.9 9.5

Examples 6 and 7

1 kg of a composition of heavy residues of chlorinated hydrocarbons containing 50% by weight of hexachlorobutadiene and 50% by weight of hexachlorobenzene is used.

For Example 6, 100 g of heavy oil ^No. 2 at 220 ° C at atmospheric pressure. Then, cool to 80 ° C and add 100 g of stearic acid at this temperature.

Grinding is then carried out for 3 minutes in a mixer having a propeller with 3 blades of 50 mm in diameter which rotates at 15,000 rpm.

For Example 7, the opposite was added stearic acid at 220 ° C and heavy fuel oil ^No. 2 at 80 ° C.

We get suspensions that do not settle. The kinematic viscosities obtained (measured at 80 ° C) are collated in Table 2. Table 2 EXAMPLES KINEMATIC VISCOSITY DEGREES ENGLER CENTISTOKES 6 4.8 35 7 1.8 8.5

Examples 8, 9 and 10

1 kg of a composition of heavy residues of chlorinated hydrocarbons containing 50% by weight of hexachlorobutadiene and 50% by weight of hexachlorobenzene is used.

To this composition 200 g of heavy oil ^No. 2 at 80 ° C for Example 8, 150 ° C for Example 9 and 220 ° C for Example 10 at atmospheric pressure.

The mixture is cooled to 80 ° C. with slow stirring and grinding is carried out for 3 minutes in a mixer similar to that described in Example 2.

Pumpable suspensions are obtained which do not settle.

The kinematic viscosities obtained measured at 80 ° C are collated in Table 3. Table 3 EXAMPLES KINEMATIC VISCOSITY DEGREES ENGLER CENTISTOKES 8 2.9 19 9 3.6 25 10 4.5 32

Claims (8)

1 - Process for the treatment of heavy residues resulting from the manufacture of chlorinated hydrocarbons, characterized in that one or more chemical compounds chosen from fatty acids, fatty alcohols or fatty esters are added to the heavy residues. 2 - Method according to claim 1 characterized in that one operates with heavy residues containing hexachlorobenzene. 3 - Process according to claim 2 characterized in that the content of hexachlorobenzene in the heavy residues is at least 5% by weight. 4 - Process according to any one of claims 1 to 3 characterized in that the heavy residues also contain hexachlorobutadiene. 5 - Process according to claim 4 characterized in that one operates with heavy residues of which at least 20% of the total composition consist of hexachlorobenzene and hexachlorobutadiene. 6 - Process according to any one of claims 1 to 5 characterized in that the compounds chosen from fatty acids, fatty alcohols and fatty esters contain at least 12 carbon atoms. 7 - Process according to claim 6 characterized in that the chemical compound is used in the form of so-called "technical" quality. 8 - Process according to claims 6 and 7 characterized in that the chemical compounds are used in an amount of 2 to 60% by weight of the total composition.

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