EP0377882B1 - Flexible packaging for liquid produce - Google Patents
Flexible packaging for liquid produce Download PDFInfo
- Publication number
- EP0377882B1 EP0377882B1 EP19890123727 EP89123727A EP0377882B1 EP 0377882 B1 EP0377882 B1 EP 0377882B1 EP 19890123727 EP19890123727 EP 19890123727 EP 89123727 A EP89123727 A EP 89123727A EP 0377882 B1 EP0377882 B1 EP 0377882B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- packaging
- clip
- channel
- intended
- jaws
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009459 flexible packaging Methods 0.000 title claims description 14
- 239000007788 liquid Substances 0.000 title description 9
- 238000004806 packaging method and process Methods 0.000 claims description 58
- 239000012263 liquid product Substances 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000003351 stiffener Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000021056 liquid food Nutrition 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011104 metalized film Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G23/00—Other table equipment
- A47G23/02—Glass or bottle holders
- A47G23/0258—Glass or bottle holders for cartons or plastic bags
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D75/5816—Opening or contents-removing devices added or incorporated during package manufacture for tearing a corner or other small portion next to the edge, e.g. a U-shaped portion
- B65D75/5822—Opening or contents-removing devices added or incorporated during package manufacture for tearing a corner or other small portion next to the edge, e.g. a U-shaped portion and defining, after tearing, a small dispensing spout, a small orifice or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/3261—Flexible containers having several compartments
- B65D81/3266—Flexible containers having several compartments separated by a common rupturable seal, a clip or other removable fastening device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2575/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes or webs of flexible sheet material, e.g. in folded wrappers
- B65D2575/52—Details
- B65D2575/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D2575/586—Opening or contents-removing devices added or incorporated during package manufacture with means for reclosing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/40—Packages formed by enclosing successive articles, or increments of material, in webs, e.g. folded or tubular webs, or by subdividing tubes filled with liquid, semi-liquid, or plastic materials
- B65D75/44—Individual packages cut from webs or tubes
- B65D75/48—Individual packages cut from webs or tubes containing liquids, semiliquids, or pastes, e.g. cushion-shaped packages
Definitions
- the subject of the present invention is an assembly comprising a flexible packaging for liquid product and means for withdrawing the packaged product, in which the packaging has a bottom, a wall, and a closed upper end intended to be opened, and the means for racking form in the packaging a channel adjacent to its wall and extended from an open lower end close to the bottom of the packaging to the closed upper end thereof.
- the flexible packaging has, substantially like the recovered glass bottle, the lowest charges for environment, considered in its simplest form, that is to say in the form of a sealed bag to be torn or cut to extract the product contained therein, and then to be discarded.
- these wineskins are generally equipped with a suspension means constituted by a strap of rope or leather.
- a flexible packaging is described, provided internally with a channel adjacent to its wall and with an elastic core.
- the channel is produced by wall welding and extends from an open end close to the bottom of the packaging to the closed upper end of the latter which is intended to be open to withdraw the packaged product.
- the elastic core acts as a pump for the ejection of the product and, above all, for its aspiration when the pressure is released after a withdrawal in order to close the lips of the upper opening of the channel by sucking the liquid it contains .
- the liquid is reintroduced in the mass of liquid remaining in the packaging at each racking.
- the invention aims to improve the shelf life of a liquid food product in a flexible package, after opening the latter, and to facilitate the racking operation, while retaining the economic and ecological advantages that this type of packaging presents.
- the section of the channel formed by the clamp being necessarily reduced compared to that of the packaging, it is easy for the consumer, after removal of the desired quantity of liquid product, to close its upper end, by example using a clothespin or paperclip, and place the packaging in an upright position in any container.
- the product remaining in the packaging is not in contact with air and only a very small quantity of this product, corresponding substantially to the cross section of the channel, was brought into contact with air during sampling.
- the clamp it can be put in place at the packaging or by the user himself. In the latter case, it is obvious that the assistant clamp, once in the possession of the user, can be kept by him for later uses with other packaging of the same type. And this makes this clip, which already allows simple manufacturing of the packaging, hardly accounts for environmental packaging costs.
- the packaging of the first embodiment shown in Figures 1 and 2 is in the form of a substantially polyhedral bag with developable walls, obtained by folding and heat-bonding the junction edges 2 and 3 of a sheet of material.
- flexible synthetic such as for example a low density polyethylene or a sandwich of plastics and aluminum, depending on the consumable liquid product to be packaged. It can be produced in the usual way, for example by shaping and tubular welding from one or more coils.
- the packaging has a channel 14 adjacent to a wall 6 which here forms one side of the packaging, and which is extended vertically from a first end 7 located in and near the bottom of the packaging to a second end 8 located at the top and out of the packaging.
- the channel 14 is formed and limited along its extent by a pinch line 9 produced by the action of a clamp 13, joining at the top the junction edge 2 of the walls of the package and leaving a small passage below. 10 communicating with compartment 4.
- the upper end of channel 14 is thus closed and the packaged liquid fills compartment 4 and channel 14, these two elements communicating through passage 10.
- the closed top of the channel 14 which is intended to be opened to allow the withdrawal of the packaged liquid product, for example by cutting using a pair of scissors along a cutting line 11 indicated by a sign affixed to it which, at the same time, serves as an element of distinction between the top and the bottom of the packaging.
- the location of the cutting line 11 is provided so that only the channel 14 is open, without being able to communicate with the compartment 4, and the cross section of the channel 14 is provided sufficiently reduced, depending on the degree of fluidity of the packaged liquid product. , to avoid too much withdrawal rate, and also to allow it to be closed, after each withdrawal of product, using a simple means accessible to all consumers, such as for example a clothespin or a paper clip.
- the shape of the packaging is asymmetrical here thanks to two retracted corners forming two bellows 12 on the side opposite to the channel 14, which gives the latter two projecting ends.
- the upper projection forms a practical pouring spout for the consumer and the lower projection a receptacle making it possible to take up almost all of the liquid product contained in the packaging without it being brought into contact with air, exception, however, of a very small quantity corresponding to the cross section of channel 14.
- the channel 14 acts as a siphon preventing any entry of air into the compartment 4, the product necessarily having to pass through the passage 10, at the bottom of this channel, while the volume of this compartment decreases accordingly, under the effect of atmospheric pressure.
- the consumer can place the packaging in any container, preferably in a vertical position, or else suspend it by its upper border 2, without having to empty it of its content.
- the consumable liquid product remaining in the packaging is thus unvented and non-oxidized, its taste and aromas are preserved and its shelf life extended.
- the channel 14 is formed by the clamp 13 independent of the packaging, intended to be associated with it at least by the consumer at the time of use, if not sold with him.
- the clamp 13 is constituted by a tube split over its entire length and the channel 14 is formed by bringing together and pinching two parts remote from the wall constituting the side of the packaging opposite the bellows 12 by the action of this clamp 13, as it is threaded around and along this side.
- the upper end 15 of the tube forming the clamp 13 is cut in a miter to facilitate the opening by cutting of the upper end of the channel 14 after its installation, and the length of this tube is provided to leave a communication passage between the channel and the compartment thus formed, as the passage 10 shown in FIG. 1.
- the essential function of the clamp 13, which consists of simply and advantageously forming the packaging channel, can be extended to other subsidiary functions which are beneficial to the consumer, by developing its structure.
- Figure 3 shows a second embodiment in which the clamp is intended to be associated with a packaging 25 of the same kind as that of Figure 2 to form its channel, but whose structure is developed to at the same time constitute a support to hang or hang.
- This clamp which is particularly suitable for flexible packages of small capacity, is composed of a pair of vertical jaws 26 extended over the height of the package 25 and articulated at their upper and lower parts by a horizontal articulation 27 integrating a spring clamp, not visible, above and below this package, like a pair of scissors.
- each jaw 26 is connected beyond the articulation 27, by a hoop 28 surrounding the side of the bellows 12 opposite to the side enclosed by the two jaws 26.
- the active clamping parts of the two jaws 26 are extended and shaped so that they can pinch the channel 14, in the same way so that by the clamp 13 of the first embodiment.
- each arch 28 has a lower projection 29 intended to compensate for the additional thickness formed by the articulation 27.
- the package 25 carries, marked along its side intended to form the channel 14, lines for locating the area to be pinched, as well as the cut line 11.
- the packaging 25 is introduced between the two arches 28, the two jaws 26 are spread by manual pressure on these arches 28 and released for tightening on the aforementioned locating lines, to form channel 14.
- the second embodiment comprises a clamp shown in the open position in FIG. 4 and in the closed service position in FIG. 5, preferably suitable for flexible packaging of medium to large capacity, the general shape of which has been shown to be identical to that of the packaging already shown in Figures 1 and 2 in a spirit of simplification.
- This clamp is composed of two parts 30 and 31 hinged together by a hinge 32 joining their bases 33 forming two support feet, and which each have a side cheek 34 and a front cheek 35, the latter defining a clamping jaw 36 intended to form the channel 14 of a package 37 of the aforementioned kind to meet the corresponding jaw of the other part, when this clamp is closed.
- the upper parts of the lateral cheeks 34 of the two parts 30 and 31 form two gripping plates 38 and 39 comprising force interpenetration means constituted on one side by pins 40 integral with the plate 38 and on the other side by corresponding holes 41 drilled in the plate 39.
- the plate 39 carries a stiffener 42 in a cap, curved downward, on the side opposite to the jaws 36, to constitute a handling handle 43.
- the gripping plate 38, respectively 39 and the jaw 36 of each of the two parts 30 and 31 are inscribed substantially in a plane containing the longitudinal axis of the hinge 32, so that when the clamp is closed these gripping plates and these jaws apply well both against the upper edge 12 of the packaging and the two walls on its side intended to form the channel 14.
- the upper edge 2 of the packaging 37 includes notches 44 in the form of a U intended to be crossed by the pins 40 of the plate 38 when the packaging is placed between the two parts of the clamp.
- two marking lines 45 can advantageously be provided on the packaging to facilitate positioning precise jaws 36, given its flexibility.
- the stiffener 42 facilitates the manual forcing of the pins 40 of the plate 38 through the notches 44 of the packaging and in the holes 41 of the plate 39.
- This assembly placed on its feet 33 is stable and ensures good retention of the flexible packaging which is thus suspended by the upper edge 2 between the two gripping plates 38 and 39. It is also well retained between the cheeks 34 and 35 and the jaws 36 during the pouring of the liquid product, and this pouring is facilitated by the use of the handle 43.
- pliers can be constituted in a simple, light and economical manner by two plastic shells. It can constitute for the consumer, as well as the tongs shown in FIG. 3, a usual kitchen object that he can keep and reuse. It can also be made of all kinds of materials since it will in principle never get dirty, not coming into contact with the contents of the packaging, which represents a clear advantage compared to other kitchen utensils.
- the side cheeks 34 of this clamp can be fitted, in a variant not shown, with two horizontal pins intended to rest in the vertical forks with a suitable support. In this way, the consumer can use it by simply tilting the packaging.
- a hinge is no longer provided at the bottom of the side walls 34 but above the gripping plates 38 and 39.
- a snap-fit retainer located between the feet 33 is planned.
- the gripping means 40-41 can be replaced by horizontal striations, which avoids the need for the notches 44 of the upper edge 2 of the packaging 37.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Packages (AREA)
- Bag Frames (AREA)
Description
La présente invention a pour objet un ensemble comprenant un emballage souple pour produit liquide et des moyens de soutirage du produit emballé, dans lequel l'emballage comporte un fond, une paroi, et une extrémité supérieure obturée destinée à être ouverte, et les moyens de soutirage forment dans l'emballage un canal adjacent à sa paroi et étendu depuis une extrémité inférieure ouverte proche du fond de l'emballage jusqu'à l'extrémité supérieure obturée de celui-ci.The subject of the present invention is an assembly comprising a flexible packaging for liquid product and means for withdrawing the packaged product, in which the packaging has a bottom, a wall, and a closed upper end intended to be opened, and the means for racking form in the packaging a channel adjacent to its wall and extended from an open lower end close to the bottom of the packaging to the closed upper end thereof.
Dans l'ensemble des emballages utilisés pour les produits liquides tels que les boissons, le lait, les sauces et crèmes alimentaires, l'emballage souple présente, sensiblement au même titre que la bouteille de verre reprise, les charges les plus faibles pour l'environnement, considéré dans sa forme la plus simple, c'est-à-dire sous la forme d'un sac scellé à déchirer ou à couper pour en soutirer le produit contenu, et à jeter ensuite.In all of the packaging used for liquid products such as beverages, milk, sauces and edible creams, the flexible packaging has, substantially like the recovered glass bottle, the lowest charges for environment, considered in its simplest form, that is to say in the form of a sealed bag to be torn or cut to extract the product contained therein, and then to be discarded.
Cet avantage particulier ressort d'un bilan écologique des matériaux d'emballage publié par l'Office Fédéral de la protection de l'environnement en 1984.This particular advantage emerges from an ecological assessment of packaging materials published by the Federal Office for Environmental Protection in 1984.
On peut encore ajouter à cet avantage celui de gain économique à la production et celui de l'inviolabilité, ce dernier avantage ressortant du fait qu'une simple piqûre d'aiguille suffit à le vider de son contenu.We can also add to this advantage that of economic gain in production and that of inviolability, this latter advantage arising from the fact that a simple needle prick is enough to empty it of its content.
En contrepartie et au niveau du consommateur, l'emballage souple présente l'inconvénient, une fois ouvert, de nécessiter le transvasement immédiat du produit liquide qu'il contient dans un récipient, opération malaisée source d'éclaboussures ou de perte de produit, car il n'est pas d'une rigidité suffisante pour assurer son propre maintien.In return and at the consumer level, flexible packaging has the disadvantage, once opened, of requiring immediate decanting of the liquid product which it contains into a container, an awkward operation which is a source of splashes or loss of product, because it is not of sufficient rigidity to ensure its own maintenance.
De ce fait, le produit liquide est entièrement soutiré de son emballage et la partie non utilisée dans l'immédiat est soumise à la pollution de l'air, ce qui réduit considérablement sa durée de conservation.Therefore, the liquid product is completely withdrawn from its packaging and the part not used immediately is subject to air pollution, which considerably reduces its shelf life.
Considéré en soi, l'emballage souple n'est cependant pas d'utilisation récente pour contenir et protéger un produit liquide. Dans les pays de la Méditerranée et du Proche-Orient, et depuis des temps anciens, on utilise des outres en peau de bouc cousue en forme de sac, et certaines de ces outres, utilisées en particulier par les bergers, comportent un moyen de soutirage du liquide contenu constitué par une tétine ou un chalumeau obturé en bout par un bouchon amovible retenu par un lien.Considered in itself, flexible packaging has not been used recently to contain and protect a liquid product. In the countries of the Mediterranean and the Near East, and since ancient times, goatskin goatskin sewn in the shape of a bag has been used, and some of these goatskins, used in particular by shepherds, have a means of racking contained liquid constituted by a teat or a blowtorch closed at the end by a removable stopper retained by a link.
Ce moyen de soutirage permet de ne retirer de l'outre que la quantité de liquide désirée à chaque utilisation, et de protéger le liquide restant en prenant la précaution de refermer la tétine ou le chalumeau avec le bouchon après avoir chassé l'air qui aurait éventuellement pénétré pendant le soutirage, par simple pression.This withdrawal means that only the quantity of liquid desired can be removed from the bottle each time it is used, and the remaining liquid is protected by taking the precaution of closing the teat or the torch with the cap after expelling the air which would have possibly penetrated during racking, by simple pressure.
Pour faciliter leur transport et leur rangement, ces outres sont généralement équipées d'un moyen de suspension constitué par une bandoulière de corde ou de cuir.To facilitate their transport and storage, these wineskins are generally equipped with a suspension means constituted by a strap of rope or leather.
Le principe astucieux de ces outres, qui permet de parer pour une grande part aux inconvénients précités des emballages souples au niveau du consommateur, a été repris récememnt dans une application commerciale pour "emballer" le vin, connue sous le nom de "caisse-outre".The clever principle of these bottles, which overcomes for the most part the aforementioned drawbacks of flexible packaging at the consumer level, was recently taken up in a commercial application for "packaging" wine, known as "box-addition ".
Il s'agit là de l'association d'une poche souple munie d'un moyen de soutirage constitué par un robinet situé dans sa partie basse, et d'une caisse de maintien et de protection en carton dans laquelle est placée la poche souple.This is the association of a flexible pocket provided with a withdrawal means constituted by a tap located in its lower part, and a cardboard holding and protection box in which the flexible pocket is placed. .
Au fur et à mesure de la consommation et sensiblement jusqu'à la fin du soutirage du vin contenu dans la poche souple, celle-ci se rétracte en s'affaissant sous l'effet de la pression atmosphérique sans laisser entrer d'air, son maintien étant assuré par la caisse.As consumption and substantially until the end of the racking of wine contained in the flexible pocket, it retracts by collapsing under the effect of atmospheric pressure without letting air in, its maintenance being ensured by the body.
Alliés au matériau utilisé pour la poche souple, qui est un film métallisé faisant écran à l'oxygène, ces caractères assurent, selon le fabricant, une conservation pendant plusieurs mois en cours de stockage et plusieurs semaines pendant la période de consommation.Combined with the material used for the flexible pouch, which is a metallized film screened with oxygen, these characters ensure, according to the manufacturer, conservation for several months during storage and several weeks during the consumption period.
Voici donc un système d'emballage utilisant une poche souple qui est avantageux pour le consommateur.Here is a packaging system using a flexible pouch which is advantageous for the consumer.
Il est par contre nettement moins économique et présente de plus grandes charges pour l'environnement que l'emballage souple considéré en soi, tel qu'il est commercialisé en grandes quantités dans sa forme la plus simple, c'est-à-dire sous la forme d'un sac scellé à déchirer ou à couper et à vider dans un récipient, et ceci par le fait qu'il nécessite pour chaque emballage l'adjonction d'une caisse et d'un moyen de soutirage relativement complexe, l'ensemble de ces éléments étant à jeter après utilisation.On the other hand, it is clearly less economical and presents greater environmental burdens than the flexible packaging considered per se, as it is marketed in large quantities in its simplest form, that is to say under the shape of a sealed bag to tear or cut and empty in a container, and this by the fact that it requires for each package the addition of a box and a relatively complex means of withdrawal, the all of these elements are to be discarded after use.
D'autres solutions ont été proposées. Ainsi, dans le document DE-A-3240108, est décrit un emballage souple pourvu intérieurement d'un canal adjacent à sa paroi et d'un noyau élastique. Le canal est réalisé par soudage de paroi et s'étend depuis une extrémité ouverte proche du fond de l'emballage jusqu'à l'extrémité supérieure obturée de celui-ci qui est destinée à être ouverte pour soutirer le produit emballé. Le noyau élastique fait office de pompe pour l'éjection du produit et, surtout, pour son aspiration quant on relâche la pression après un soutirage dans le but de refermer les lèvres de l'ouverture supérieure du canal en aspirant le liquide qu'il contient. De ce fait, le liquide est réintroduit dans la masse du liquide restant dans l'emballage à chaque soutirage.Other solutions have been proposed. Thus, in document DE-A-3240108, a flexible packaging is described, provided internally with a channel adjacent to its wall and with an elastic core. The channel is produced by wall welding and extends from an open end close to the bottom of the packaging to the closed upper end of the latter which is intended to be open to withdraw the packaged product. The elastic core acts as a pump for the ejection of the product and, above all, for its aspiration when the pressure is released after a withdrawal in order to close the lips of the upper opening of the channel by sucking the liquid it contains . As a result, the liquid is reintroduced in the mass of liquid remaining in the packaging at each racking.
On connait par ailleurs un moyen de fermeture de sachets pour matières pulvérulentes tel que décrit par le document US-A-2021609. Ce moyen est constitué par un profilé tubulaire fendu sur toute sa longueur formant une sorte de pince destinée à fermer le sachet après chaque soutirage de produit, et à quelque niveau du sachet que ce soit, par enfilage le long d'un rabattement de ses parois et pinçage de celles-ci.There is also known a means for closing sachets for pulverulent materials as described by document US-A-2021609. This means is constituted by a tubular section split over its entire length forming a sort of clamp intended to close the bag after each withdrawal of product, and at any level of the bag whatsoever, by threading along a folding down of its walls and pinching them.
Des dispositifs ont également été proposés, décrits dans les documents FR-A-1223703 et FR-A-1290196, pour faciliter le maintien et la préhension d'un emballage souple pour produits liquides. Dans le premier de ces deux documents il s'agit d'une pince à ressort destinée à maintenir par pinçage la partie supérieure d'un emballage souple, cette pince étant nantie d'une poignée de portage et éventuellement d'une semelle de sustentation. Dans le second document, il s'agit de diverses variantes d'un boîtier de maintien d'un emballage souple qui ont la particularité commune de comporter deux parties ouvrables articulées entre elles et comportant des moyens internes de mise en place et de suspension d'un emballage par des moyens d'agrippage de ses parties soudées lors de sa fermeture; les variantes montrent l'adjonction d'un bec verseur, d'une poignée de portage, de moyens de sustentation et de moyens pour maintenir fermé l'orifice de sortie de l'emballage.Devices have also been proposed, described in documents FR-A-1223703 and FR-A-1290196, to facilitate the maintenance and gripping of flexible packaging for liquid products. In the first of these two documents, it is a spring clip intended to hold the upper part of a flexible packaging by pinching, this clamp being provided with a carrying handle and possibly with a lifting sole. In the second document, there are various variants of a case for retaining flexible packaging which have the common feature of comprising two openable parts hinged together and comprising internal means for positioning and suspending packaging by means of gripping of its welded parts when it is closed; the variants show the addition of a pouring spout, a carrying handle, lifting means and means for keeping the outlet opening of the packaging closed.
L'invention a pour but d'améliorer la durée de conservation d'un produit liquide alimentaire d'un emballage souple, après ouverture de ce dernier, et d'en faciliter l'opération de soutirage, tout en conservant les avantages économiques et écologiques que présente ce type d'emballage.The invention aims to improve the shelf life of a liquid food product in a flexible package, after opening the latter, and to facilitate the racking operation, while retaining the economic and ecological advantages that this type of packaging presents.
A cet effet, l'ensemble selon l'invention est tel que défini par la revendication 1.To this end, the assembly according to the invention is as defined by claim 1.
De la sorte, la section du canal formée par la pince étant nécessairement réduite par rapport à celle de l'emballage, il est aisé pour le consommateur, après prélèvement de la quantité de produit liquide désirée, d'en fermer son extrémité supérieure, par exemple à l'aide d'une pince à linge ou d'un trombone, et de placer l'emballage en position verticale dans un récipient quelconque. Le produit restant dans l'emballage n'est pas en contact avec l'air et seule une quantité très réduite de ce produit, correspondant sensiblement à la section droite du canal, a été mise en contact avec l'air pendant le prélèvement. Quant à la pince, elle peut être mise en place au conditionnement ou par l'utilisateur lui-même. Dans ce dernier cas, il est évident que la pince adjointe, une fois en possession de l'utilisateur, peut être conservée par lui pour utilisations ultérieures avec d'autres emballages de même type. Et ceci fait que cette pince, qui permet déjà une fabrication simple de l'emballage, n'entre pratiquement pas pour compte dans les charges de l'emballage pour l'environnement.In this way, the section of the channel formed by the clamp being necessarily reduced compared to that of the packaging, it is easy for the consumer, after removal of the desired quantity of liquid product, to close its upper end, by example using a clothespin or paperclip, and place the packaging in an upright position in any container. The product remaining in the packaging is not in contact with air and only a very small quantity of this product, corresponding substantially to the cross section of the channel, was brought into contact with air during sampling. As for the clamp, it can be put in place at the packaging or by the user himself. In the latter case, it is obvious that the assistant clamp, once in the possession of the user, can be kept by him for later uses with other packaging of the same type. And this makes this clip, which already allows simple manufacturing of the packaging, hardly accounts for environmental packaging costs.
Ces concepts de base de l'invention sont exposés et montrés clairement par la description qui suit et le dessin annexé, ainsi que des développements, notamment en ce qui concerne des structures et des fonctions subsidiaires de la pince associée à l'emballage pour former le canal.These basic concepts of the invention are explained and shown clearly by the following description and the appended drawing, as well as developments, in particular with regard to structures and subsidiary functions of the clamp associated with the packaging to form the channel.
Le dessin annexé représente, à titre d'exemples, trois formes d'exécution de l'objet de l'invention.
- La figure 1 représente l'emballage de la première forme d'exécution et,
- la figure 2 représente ce même emballage en phase de formation de son canal interne.
- La figure 3 est une vue d'ensemble de la seconde forme d'exécution.
- Les figures 4 et 5 sont deux vues d'ensemble de la troisième forme d'exécution montrée respectivement dans deux positions différentes.
- FIG. 1 represents the packaging of the first embodiment and,
- Figure 2 shows the same packaging in the formation phase of its internal channel.
- Figure 3 is an overview of the second embodiment.
- Figures 4 and 5 are two overall views of the third embodiment shown respectively in two different positions.
L'emballage de la première forme d'exécution représentée figures 1 et 2 se présente sous la forme d'un sac sensiblement polyédrique à parois développables, obtenu par pliage et thermo-collage des bordures de jonction 2 et 3 d'une feuille de matériau synthétique souple, tel que par exemple un polyéthylène de basse densité ou un sandwich de matières plastiques et d'aluminium, suivant le produit liquide consommable à emballer. Il peut être réalisé de manière habituelle, par exemple par conformation et soudage tubulaire à partir d'une ou de plusieurs bobines.The packaging of the first embodiment shown in Figures 1 and 2 is in the form of a substantially polyhedral bag with developable walls, obtained by folding and heat-bonding the
L'emballage présente un canal 14 adjacent à une paroi 6 qui forme ici un côté de l'emballage, et qui est étendu verticalement depuis une première extrémité 7 située dans et proche du fond de l'emballage jusqu'à une seconde extrémité 8 située en haut et hors de l'emballage. Le canal 14 est formé et limité le long de son étendue par une ligne de pincement 9 produite par l'action d'une pince 13, rejoignant en haut la bordure de jonction 2 des parois de l'emballage et laissant en bas un petit passage 10 communiquant avec le compartiment 4. L'extrémité supérieure du canal 14 se trouve ainsi obturée et le liquide emballé remplit le compartiment 4 et le canal 14, ces deux éléments communiquant par le passage 10.The packaging has a
Ainsi conçu, c'est le haut obturé du canal 14 qui est destiné à être ouvert pour permettre le soutirage du produit liquide emballé, par exemple par découpage à l'aide d'une paire de ciseaux selon une ligne de coupe 11 indiquée par un signe apposé sur lui qui, en même temps, sert d'élément de distinction entre le haut et le bas de l'emballage.Thus designed, it is the closed top of the
L'emplacement de la ligne de coupe 11 est prévu pour que seul le canal 14 soit ouvert, sans pouvoir communiquer avec le compartiment 4, et la section droite du canal 14 est prévue suffisamment réduite, en fonction du degré de fluidité du produit liquide emballé, pour éviter un trop grand débit de soutirage, et également pour permettre sa fermeture, après chaque prélèvement de produit, à l'aide d'un moyen simple à la portée de tous les consommateurs, tel que par exemple une pince à linge ou un trombone.The location of the
La forme de l'emballage est ici asymétrique grâce à deux coins rentrés formant deux soufflets 12 du côté opposé au canal 14, ce qui confère à ce dernier deux extrémités en saillie. La saillie supérieure forme un bec verseur pratique pour le consommateur et la saillie inférieure un réceptacle permettant de prélever jusqu'à quasiment la totalité du produit liquide contenu dans l'emballage sans qu'il soit mis en contact avec l'air, à l'exception toutefois d'une très faible quantité correspondant à la section droite du canal 14.The shape of the packaging is asymmetrical here thanks to two retracted corners forming two
En effet, pendant le prélèvement du produit liquide, le canal 14 joue le rôle d'un siphon interdisant toute entrée d'air dans le compartiment 4, le produit devant nécessairement transiter par le passage 10, au bas de ce canal, pendant que le volume de ce compartiment diminue d'autant, sous l'effet de la pression atmosphérique.In fact, during the withdrawal of the liquid product, the
Ainsi, après prélèvement de la quantité désirée de produit liquide, et après fermeture de l'extrémité du canal 14 formant bec verseur, le consommateur peut placer l'emballage dans un récipient quelconque, de préférence en position verticale, ou bien le suspendre par sa bordure supérieure 2, sans devoir le vider de son contenu.Thus, after withdrawing the desired quantity of liquid product, and after closing the end of the
Le produit liquide consommable restant dans l'emballage est ainsi non éventé et non oxydé, son goût et ses arômes sont conservés et sa durée de vie prolongée.The consumable liquid product remaining in the packaging is thus unvented and non-oxidized, its taste and aromas are preserved and its shelf life extended.
Le gain économique et écologique est ici évident et ceci d'autant plus que le consommateur aura moins souvent recours au frigo qu'avec un produit liquide ayant dû être transvasé dans un récipient.The economic and ecological gain is obvious here and all the more so since the consumer will less often have recourse to the fridge than with a liquid product which had to be transferred to a container.
Comme illustré sur les figures 1 et 2, le canal 14 est formé par la pince 13 indépendante de l'emballage, destinée à lui être associée au moins par le consommateur au moment de son emploi, sinon vendue avec lui.As illustrated in Figures 1 and 2, the
La pince 13 est constituée par un tube fendu sur toute sa longueur et le canal 14 est formé par rapprochement et pincement de deux parties distantes de la paroi constituant le côté de l'emballage opposé aux soufflets 12 par l'action de cette pince 13, au fur et à mesure de son enfilage autour et le long de ce côté.The
L'extrémité supérieure 15 du tube formant la pince 13 est coupée en onglet pour faciliter l'ouverture par découpage de l'extrémité supérieure du canal 14 après sa mise en place, et la longueur de ce tube est prévue pour laisser un passage de communication entre le canal et le compartiment ainsi formé, comme le passage 10 montré figure 1.The
Comme il sera montré plus loin, la fonction essentielle de la pince 13, qui consiste à former de façon simple et avantageuse le canal de l'emballage, peut être étendue à d'autres fonctions subsidiaires avantageuses pour le consommateur, par des développements de sa structure.As will be shown below, the essential function of the
La figure 3 montre une seconde forme d'exécution dans laquelle la pince est destinée à être associée à un emballage 25 du même genre que celui de la figure 2 pour former son canal, mais dont la structure est développée pour en même temps constituer un support à poser ou à suspendre.Figure 3 shows a second embodiment in which the clamp is intended to be associated with a
Cette pince, qui convient tout particulièrement pour des emballages souples de petite contenance, est composée d'une paire de mâchoires verticales 26 étendues sur la hauteur de l'emballage 25 et articulées à leurs parties supérieures et inférieures par une articulation horizontale 27 intégrant un ressort de serrage, non visible, au-dessus et au-dessous de cet emballage, à la manière d'une paire de ciseaux.This clamp, which is particularly suitable for flexible packages of small capacity, is composed of a pair of
Les parties supérieure et inférieure de chaque mâchoire 26 sont reliées au delà de l'articulation 27, par un arceau 28 entourant le côté des soufflets 12 opposé au côté enserré par les deux mâchoires 26.The upper and lower parts of each
Les parties actives de serrage des deux mâchoires 26 sont étendues et conformées de telle sorte qu'elles puissent former par pincement le canal 14, de la même manière que par la pince 13 de la première forme d'exécution.The active clamping parts of the two
Pour assurer la stabilité de cette pince chargée de l'emballage 25, après posage sur une surface horizontale, la partie basse de chaque arceau 28 présente une saillie inférieure 29 destinée à compenser la surépaisseur constituée par l'articulation 27.To ensure the stability of this clamp loaded with the
De préférence, l'emballage 25 porte, inscrit le long de son côté destiné à former le canal 14, des lignes de repérage de la zone à pincer, ainsi que la ligne de coupure 11.Preferably, the
Lors de l'utilisation de cette pince par le consommateur, l'emballage 25 est introduit entre les deux arceaux 28, les deux mâchoires 26 sont écartées par pression manuelle sur ces arceaux 28 et relâchées pour serrage sur les lignes de repérage précitées, pour former le canal 14.When the consumer uses this clamp, the
Après ouverture de ce canal et prélèvement de la quantité de liquide désirée, le consommateur ne doit plus nécessairement refermer le canal à l'aide d'un moyen quelconque à sa portée du fait qu'il peut poser la pince chargée de l'emballage en position verticale, ou bien le suspendre, par exemple par un arceau 28. Seule une très petite surface du produit liquide restant correspondant à la section droite du canal 14, comme déjà dit, est exposée à l'air.After opening this channel and withdrawing the desired quantity of liquid, the consumer no longer necessarily has to close the channel using any means within his reach since he can place the clamp loaded with the packaging in vertical position, or else suspend it, for example by a
La seconde forme d'exécution comporte une pince représentée en position ouverte par la figure 4 et en position fermée de service par la figure 5 appropriée de préférence à un emballage souple de moyenne à grande contenance, dont la forme générale a été représentée identique à celle de l'emballage déjà montré figures 1 et 2 dans un esprit de simplification.The second embodiment comprises a clamp shown in the open position in FIG. 4 and in the closed service position in FIG. 5, preferably suitable for flexible packaging of medium to large capacity, the general shape of which has been shown to be identical to that of the packaging already shown in Figures 1 and 2 in a spirit of simplification.
Cette pince est composée de deux pièces 30 et 31 articulées entre elles par une charnière 32 rejoignant leurs bases 33 formant deux pieds d'appui, et qui présentent chacune une joue latérale 34 et une joue frontale 35, cette dernière définissant une mâchoire de serrage 36 destinée à former le canal 14 d'un emballage 37 du genre précité à la rencontre de la mâchoire correspondante de l'autre pièce, lors de la fermeture de cette pince.This clamp is composed of two
Les parties supérieures des joues latérales 34 des deux pièces 30 et 31 forment deux plaques d'agrippage 38 et 39 comportant des moyens d'interpénétration à force constitués d'un côté par des tétons 40 solidaires de la plaque 38 et de l'autre côté par des trous correspondants 41 percés dans la plaque 39. En outre, l'une de ces deux plaques d'agrippage, la plaque 39, porte un raidisseur 42 en casquette, recourbé vers le bas, du côté opposé aux mâchoires 36, pour constituer une poignée de manutention 43.The upper parts of the
La plaque d'agrippage 38, respectivement 39 et la mâchoire 36 de chacune des deux pièces 30 et 31 sont inscrites sensiblement dans un plan contenant l'axe longitudinal de la charnière 32, de manière à ce qu'à la fermeture de la pince ces plaques d'agrippage et ces mâchoires s'appliquent bien à la fois contre la bordure supérieure 12 de l'emballage et les deux parois de son côté destiné à former le canal 14.The gripping
La bordure supérieure 2 de l'emballage 37 comporte des entailles 44 en forme de U destinées à être traversées par les tétons 40 de la plaque 38 à la mise en place de l'emballage entre les deux pièces de la pince.The
De même deux lignes de repérage 45 peuvent être avantageusement prévues sur l'emballage pour faciliter le positionnement précis des mâchoires 36, compte tenu de sa souplesse.Similarly two marking
Pendant le serrage des plaques d'agrippage 38 et 39 le raidisseur 42 facilite le forcement manuel des tétons 40 de la plaque 38 au travers des entailles 44 de l'emballage et dans les trous 41 de la plaque 39.During the tightening of the
Après fermeture de la pince et après ouverture du canal 14 l'ensemble ainsi constitué de la pince et de l'emballage se présente sous l'aspect de la figure 5.After closing the clamp and after opening the
Cet ensemble, posé sur ses pieds 33 est stable et assure un bon maintien de l'emballage souple qui se trouve ainsi suspendu par la bordure supérieure 2 entre les deux plaques d'agrippage 38 et 39. Il est également bien retenu entre les joues 34 et 35 et les mâchoires 36 pendant le versement du produit liquide, et ce versement est facilité par l'usage de la poignée 43.This assembly, placed on its
Cette pince peut être constituée de manière simple, légère et économique par deux coques en matière plastique. Elle peut constituer pour le consommateur, ainsi que la pince représentée figure 3, un objet de cuisine usuel qu'il pourra garder et réutiliser. Elle pourra également être réalisée en toutes sortes de matériaux puisqu'elle ne se salira en principe jamais, n'entrant pas en contact avec le contenu de l'emballage, ce qui représente un net avantage par rapport aux autres ustensiles de cuisine.These pliers can be constituted in a simple, light and economical manner by two plastic shells. It can constitute for the consumer, as well as the tongs shown in FIG. 3, a usual kitchen object that he can keep and reuse. It can also be made of all kinds of materials since it will in principle never get dirty, not coming into contact with the contents of the packaging, which represents a clear advantage compared to other kitchen utensils.
Pour un emballage lourd, de grande contenance, les joues latérales 34 de cette pince peuvent être équipées, dans une variante non représentée, de deux tourillons horizontaux destinés à reposer dans les fourches verticales d'un support approprié. De la sorte, le consommateur pourra se servir en faisant simplement basculer l'emballage.For heavy packaging, of large capacity, the
Dans une variante non représentée de cette pince, une charnière est prévue non plus au bas des parois latérales 34 mais au-dessus des plaques d'agrippage 38 et 39. Pour assurer la fermeture de cette variante, une retenue enclenchable, située entre les pieds 33, est prévue.In a variant not shown of this clamp, a hinge is no longer provided at the bottom of the
Dans cette variante les moyens d'agrippage 40-41 peuvent être remplacés par des stries horizontales, ce qui évite la nécessité des entailles 44 de la bordure supérieure 2 de l'emballage 37.In this variant, the gripping means 40-41 can be replaced by horizontal striations, which avoids the need for the
Claims (5)
- A set comprising a flexible packaging for a liquid product and racking means for the packed product, in which the packaging comprises a bottom, a wall, and a sealed upper end intended to be opened, and the racking means form in the packaging a channel adjacent to its wall and extended from a lower open end close to the bottom of the packaging up to the upper sealed end thereof, characterized in that the racking means are formed by an independent clip (13, 26, 36) having two gripping jaws and intended to be associated with the packaging at least upon usage thereof in order to form the inner channel (14) by bringing together and pinching two separate parts of its wall.
- Set according to claim 1, characterized in that the clip is formed by a tube (13) split all over its length and slippable around and along the two distant parts of the packaging intended to form the inner channel (14).
- Set according to claim 2, characterized in that the split tube (13) forming the clip has its upper end (15) mitre cut.
- Set according to claim 1, characterized in that the clip is formed by a pair of vertical jaws (26) articulated over and under the packaging to a horizontal hinge (27) integrating a setting spring, each jaw being extended, beyond that hinge, by a curved part (28) surrounding the side of the packaging opposed to the inner channel (14), the latter being formed by gripping of the two vertical jaws (26).
- Set according to claim 1, characterized in that the clip is formed by two vertical front jaws (36) with lateral maintaining flanges (34) articulated to each other and having at their upper parts two gripping plates (38, 39) intended to assure the holding by suspension therebetween of the packaging (37) upon closure of the clip, the inner channel (14) being simultaneously formed by such closure.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH55/89 | 1989-01-09 | ||
CH5589A CH678614A5 (en) | 1989-01-09 | 1989-01-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0377882A1 EP0377882A1 (en) | 1990-07-18 |
EP0377882B1 true EP0377882B1 (en) | 1993-08-25 |
Family
ID=4178285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19890123727 Expired - Lifetime EP0377882B1 (en) | 1989-01-09 | 1989-12-22 | Flexible packaging for liquid produce |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0377882B1 (en) |
CH (1) | CH678614A5 (en) |
DE (1) | DE68908686T2 (en) |
ES (1) | ES2045374T3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7600360B2 (en) | 2002-04-19 | 2009-10-13 | Lancer Partnership Ltd, Dorothy Linda Schroeder as Trustee for three trusts, and SMJCGF, LLP | Flexible packaging |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1268682B1 (en) * | 1994-10-18 | 1997-03-06 | Giorgio Trani | DISPOSABLE CONTAINER FOR LIQUIDS. |
NL1002505C2 (en) * | 1996-03-01 | 1997-09-03 | Dijk Food Prod Lopik | Bag, as well as a dispenser for dispensing a liquid substance from a bag. |
GB9817578D0 (en) * | 1998-08-12 | 1998-10-07 | Cambridge Consultants | Pack |
DE19927572A1 (en) * | 1999-06-17 | 2000-12-21 | Dentaco Gmbh | Multi-component chamber bag |
US6968669B2 (en) | 2002-11-06 | 2005-11-29 | Lancer Partnership Ltd. | Flexible packaging |
CN112280343B (en) | 2020-11-10 | 2022-07-19 | 山东鲁阳节能材料股份有限公司 | High-temperature nano composite coating, preparation method thereof and small-bag flexible package coating |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2021609A (en) * | 1935-05-21 | 1935-11-19 | Willis J Pippert | Packaged product and closure therefor |
FR1223703A (en) * | 1959-05-05 | 1960-06-20 | Support handle for semi-rigid and flexible packaging | |
FR1290196A (en) * | 1961-02-27 | 1962-04-13 | Device for the rational use of flexible containers or receptacles | |
DE3240108A1 (en) * | 1982-10-29 | 1984-05-03 | Bruno 8039 Puchheim Gruber | Pack made of an enveloping film for receiving flowable or pourable substances |
-
1989
- 1989-01-09 CH CH5589A patent/CH678614A5/fr not_active IP Right Cessation
- 1989-12-22 ES ES89123727T patent/ES2045374T3/en not_active Expired - Lifetime
- 1989-12-22 DE DE1989608686 patent/DE68908686T2/en not_active Expired - Fee Related
- 1989-12-22 EP EP19890123727 patent/EP0377882B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7600360B2 (en) | 2002-04-19 | 2009-10-13 | Lancer Partnership Ltd, Dorothy Linda Schroeder as Trustee for three trusts, and SMJCGF, LLP | Flexible packaging |
Also Published As
Publication number | Publication date |
---|---|
ES2045374T3 (en) | 1994-01-16 |
CH678614A5 (en) | 1991-10-15 |
DE68908686D1 (en) | 1993-09-30 |
EP0377882A1 (en) | 1990-07-18 |
DE68908686T2 (en) | 1994-04-07 |
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