EP0341420B1 - Yarn and method for making it - Google Patents
Yarn and method for making it Download PDFInfo
- Publication number
- EP0341420B1 EP0341420B1 EP89106097A EP89106097A EP0341420B1 EP 0341420 B1 EP0341420 B1 EP 0341420B1 EP 89106097 A EP89106097 A EP 89106097A EP 89106097 A EP89106097 A EP 89106097A EP 0341420 B1 EP0341420 B1 EP 0341420B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- yarn
- granular particles
- component
- particles
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000002245 particle Substances 0.000 claims abstract description 122
- 238000009958 sewing Methods 0.000 claims abstract description 40
- 239000006185 dispersion Substances 0.000 claims abstract description 31
- 239000012530 fluid Substances 0.000 claims abstract description 27
- 239000000725 suspension Substances 0.000 claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003595 mist Substances 0.000 claims abstract description 10
- 239000000428 dust Substances 0.000 claims abstract description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- 238000007598 dipping method Methods 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012222 talc Nutrition 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 10
- 239000000919 ceramic Substances 0.000 abstract description 6
- 239000011162 core material Substances 0.000 description 12
- 238000012545 processing Methods 0.000 description 9
- 238000009736 wetting Methods 0.000 description 8
- 238000009826 distribution Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007900 aqueous suspension Substances 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
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- 239000003795 chemical substances by application Substances 0.000 description 3
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- 230000006872 improvement Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- -1 alkylaryl sulfates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000011545 laboratory measurement Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010972 statistical evaluation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/16—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
- D02G1/164—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam in the presence of a liquid, e.g. a crimp finish
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/46—Sewing-cottons or the like
Definitions
- the present invention relates to a yarn, in particular a sewing thread, with the features of the preamble of patent claim 1 and two methods for producing the yarn with the features of the preamble of patent claims 11 and 19.
- Swirled yarns which consist of at least two yarn components, one yarn component forming the core, which is also called the core, and the other yarn component forming the sheath, have long been known.
- such intermingled yarns are produced by feeding the core material with a certain advance, for example between about 1% and about 5%, together with the sheath material to a nozzle and swirling it there by an air stream, the sheath material generally being compared to the core material with a much higher lead in the nozzle.
- the air stream hitting the yarn causes the individual filaments of the soul and / or the sheath material, for example with the formation of loops, loops and.
- Swirled and confused so that the resulting finished yarn forms a closed yarn structure due to this swirling or confusion, without a twisting of the two components is necessary for this.
- swirled single yarns which do not have the core-sheath structure described above.
- the multifilament yarn consisting of individual filaments is fed to the nozzle with a certain advance. swirled over an air stream in such a way that the individual filaments are swirled or tangled with themselves, so that a yarn which is closed per se results.
- the mechanical-technological properties are then considerably deteriorated, which can be expressed, for example, in the case of a sewing thread in a reduced strength, a deterioration in the force-elongation ratio and / or in an increase in the frequency of thread breakage during sewing.
- the present invention has for its object to provide a yarn of the type specified, which has a particularly low frequency of yarn breakage during processing.
- the yarn designed according to the invention which is used in particular as a sewing thread, consists of at least one first yarn component designed as a core and at least one second yarn component intermingled with the first yarn component, the second yarn component being arranged predominantly in relation to the finished yarn in the outer region thereof.
- Grain-like particles are arranged in the spaces between the threads and / or on the outside of the thread.
- the grain-like particles have a grain diameter of between approximately 4 ⁇ m and approximately 400 ⁇ m. Your concentration is between about 0.02% by weight and about 20% by weight, each based on the weight of the yarn.
- the mechanical-technological properties and the processing behavior are considerably improved in comparison with a conventionally designed, equivalent yarn which does not have such granular particles.
- This is expressed, for example, in that the yarn strength is improved by approximately 15% compared to the standard yarn described above, while at the same time the elasticity is improved in the yarn according to the invention.
- the thread break frequency of a conventional yarn with the same structure compared to the yarn according to the invention by a factor of between is about 3 and about 8 higher.
- the yarn according to the invention also has a higher interlacing in comparison to a conventional yarn produced under otherwise the same conditions, to which the property improvements previously mentioned are also attributed.
- these particles can contribute to the electrostatic charge reduce synthetic yarns, which in turn improves the processing properties of the yarn according to the invention.
- EP 0 136 727 A discloses a yarn which is used as a filler or sealing material.
- the known yarn which is a single multifilament yarn, has a filament number between 1,000 and 20,000 filaments.
- EP 0 136 727 A suggests swirling the only multifilament starting material, the multifilament starting material being wetted with an aqueous dispersion of granular particles before the swirling.
- the grain-like particles used for this have a grain size that varies predominantly between 0.1 ⁇ m and 1 ⁇ m.
- the known yarn thus differs from the previously described inventive yarn not only in its construction but also decisively in the number of filaments and the size of the grain-like particles.
- a particularly suitable embodiment of the yarn according to the invention has granular particles in a concentration between about 0.2% by weight and about 0.4% by weight.
- a very fine titer i.e. for yarns in a titer range between about 100 dtex and about 300 dtex
- the aforementioned concentration range of granular particles is sufficient to achieve the desired improvement in processing properties, the increase in strength and the increase in elongation behavior. This is particularly true if the grain-like particles are predominantly or exclusively arranged on the surface of the finished yarn and if the diameter of the particles is approximately in a range between 10 ⁇ m and approximately 100 ⁇ m.
- titers i.e.
- Titers in the range between approximately 500 dtex and approximately 800 dtex may require higher concentrations of granular particles, these concentrations usually being in a range between approximately 0.5% by weight and approximately 4% by weight.
- concentrations in the order of magnitude between approximately 5% by weight and approximately 15% by weight may be required in order to achieve the above-mentioned favorable properties, with all of the above-mentioned yarns, the particle concentration for the respective yarn depends on the number of filaments, the distribution of the particles over the yarn cross-section and the particle diameter.
- Such embodiments have particularly good mechanical properties and advantageous processing behavior of the yarn according to the invention, in which the grain-like particles have a grain diameter of between approximately 20 ⁇ m and approximately 100 ⁇ m.
- Such relatively small particles are particularly effective in reducing the friction described above and also have good adhesion to the yarn, so that no unwanted dusting occurs when the yarn is processed.
- both the embodiment of the yarn according to the invention, in which the particles are predominantly or exclusively arranged in the outer region of the yarn, and those embodiments in which the particles are evenly distributed over the yarn cross section are claimed .
- the last-mentioned embodiments are suitable for yarns which have a relatively high number of filaments, i.e. between about 80 filaments and about 200 filaments, have a relatively fine titer, for example between about 100 dtex and about 300 dtex.
- the desired improvement in properties depends crucially on the fact that the friction between the filaments is effectively reduced, which is achieved by embedding the particles in the spaces between the filaments.
- Another advantageous embodiment of the yarn according to the invention provides that the grain-like particles are embedded in a finish applied to the yarn.
- the finish supports the effect of the grain-like particles in reducing friction, while the finish improves the adhesion of the grain-like particles to the yarn or to the individual filaments processed therein.
- the avivage affects The mobility of the particles relative to the individual filaments or the yarn is only slight, so that the previously described positive properties of the particles are additionally reinforced in such an embodiment of the yarn according to the invention.
- the same statements apply as were made above for the distribution of the particles.
- the yarn according to the invention has a core-sheath structure, the core (core) made of a multifilament yarn, for example one with a titer between approximately 100 dtex and approximately 500 dtex, in particular with a titer between approximately 150 dtex and approximately 300 dtex.
- the number of filaments of such a core material can vary between approximately 50 threads and approximately 500 threads, in particular between approximately 100 threads and approximately 300 threads, depending on the particular field of use of the yarn.
- the core sheath yarn described above has one or more multifilament yarns, the titer and number of filaments of which correspond to approximately half the titer and the number of filaments of the core material.
- grain-like particles there are basically those particles that have a certain hardness and resistance exhibit mechanical loads.
- Inorganic particles such as talc, kieselguhr and aluminum oxide are particularly suitable.
- One embodiment of the yarn according to the invention which contains titanium dioxide and / or barium sulfate particles, has particularly good mechanical properties and excellent processing behavior, since these substances have excellent resistance to mechanical stress.
- the yarn according to the invention can be processed wherever a high mechanical load on the yarn occurs during processing and / or high strength and excellent elastic behavior of the yarn is required.
- the use of the yarn according to the invention as a sewing thread brings considerable advantages compared to a suitably designed conventional thread, as will be demonstrated below by the exemplary embodiments.
- Such a sewing thread preferably has the core / sheath structure described above.
- the yarn according to the invention can also have a twist, for example in the range between 1 twist / m and approximately 1000 twists / m, preferably between approximately 100 twists / m and approximately 600 twists / m.
- a twist for example in the range between 1 twist / m and approximately 1000 twists / m, preferably between approximately 100 twists / m and approximately 600 twists / m.
- Such a twisted embodiment is particularly suitable for those uses in which the yarn is exposed to extremely high mechanical loads, as is the case, for example, with yarns used in large-scale manufacturing.
- the rotation also improves the yarn composite, while the particles preferably arranged on the outside of such a twisted yarn considerably reduce the friction occurring during processing, so that the yarn breakage frequency is significantly reduced.
- the present invention is also based on the object of providing a method of the type specified, with which the yarns described above can be produced with special consideration of a uniform yarn titer.
- this object is achieved by a method having the characterizing features of patent claim 11 and by a method having the characterizing features of patent claim 19.
- the first, basic variant of the method according to the invention is based on the basic idea that grain-like particles are added to the water with which the first yarn component is wetted before intermingling, the grain-like particles used here having a specific weight greater than 1 g / cm 3 and one Grain diameter between about 4 microns and about 400 microns, in particular between about 20 microns and about 100 microns.
- this then leads to a turbulent fluid flow acting on the yarn in the nozzle, and there specifically in the swirl chamber, which, in addition to the fluid fed to the nozzle in each case, for example air or steam, has a turbulent particle flow from the defined large one contains grain-like particles, which increases the degree of intermingling of the individual filaments and causes the grain-like particles to be deposited in or on the thread, so that a sewing thread produced in this way has the advantages as described above for the thread according to the invention.
- the process according to the invention has a number of further advantages.
- the core-jacket yarns produced by this process are characterized by a particularly uniform titer, which is attributed to the fact that the flow conditions in the nozzle are optimized and / or by the additional particle flow in the swirl chamber be evened out.
- the particle flow causes any matting of the first yarn component to be loosened, which in turn improves the yarn uniformity.
- the particle flow also prevents the deposit of loosened or lubricated preparations and additives in the nozzle, so that undesired and uncontrollable changes in the dimension of the nozzle due to deposits or lubrication do not occur in the process according to the invention during production, so that on the one hand the flow conditions in the nozzle can also be kept constant over a longer production period and on the other hand undesirable Knot formation and / or capillary or yarn breaks can be prevented.
- This has the effect that the yarns described above can be produced over a longer period of time without interruption and without the need to clean the nozzle, so that in the method according to the invention there is no significant downtime for cleaning the nozzle and / or reinserting it Yarns occur when yarn breaks occur.
- the method according to the invention thus permits the economical production of improved core-sheath yarns, this being evident preferably in improved mechanical-technological properties and in a higher mechanical strength of the yarns during processing.
- Grain-like particles whose specific weight is between approximately 1 g / cm 3 and approximately 6 g / cm 3, in particular between approximately 2 g / cm 3 and approximately 4.5 g / cm 3, are preferably used in the process according to the invention, it being particularly advantageous has proven to vary the specific weight of the granular particles depending on the yarn to be processed.
- the hardness of the particle particles used is also important for the desired effects.
- the granular particles should not be so soft that they are destroyed during the swirling and on the other hand they should still have a certain softness in order not to cause undesired capillary injuries and / or undesirable damage to the nozzle.
- Grain-like particles are usually used which have a hardness on the Mohs hardness scale of between approximately 1 and approximately 7, in particular between approximately 4 and approximately 6 1/2, but also the hardness, as already explained above for the density of the grain-like particles, depends on the yarn used and its number of filaments.
- the grain size of the particles used can also vary in a range between approximately 4 ⁇ m and approximately 400 ⁇ m, in particular for the production of yarns with an average titer between approximately 300 dtex and approximately 600 dtex Grain diameters between about 20 microns and about 100 microns can be used.
- the finer titers of the individual filaments and / or the finished yarn particles with a grain size of between approximately 20 ⁇ m and approximately 50 ⁇ m are preferred, and in the case of the coarser titers of the individual filaments or of the finished yarn preferably also larger grain-like particles, for example, those in a range between approximately 150 ⁇ m and approximately 250 ⁇ m can be used.
- the concentration of the granular particles in the aqueous suspension or dispersion depends on the type of wetting of the first yarn component. If the first yarn component is wetted by immersion in an aqueous suspension or dispersion of the granular particles, the concentration is usually in a range between approximately 45 g granular particles / l and approximately 150 g particles / l, preferably a concentration range between approximately 30 g Particle / l and about 60 g particle / l is selected.
- particle concentrations between about 10 g / l and about 200 g / l, preferably between about 50 g / l and about 150 g / l, are preferably used .
- surfactants and / or dispersing agents or suspending agents are added to the aqueous suspension or dispersion of the granular particles.
- the surfactants or dispersing and suspending agents known per se from textile chemistry can be used here, preference being given to using low-foaming products and / or the known antifoaming agents, for example based on organosilicon compounds.
- anionic surfactants or dispersing and / or suspending agents based on organic sulfates and sulfonates for example alkyl sulfates, alkyl sulfonates and / or alkylaryl sulfates or sulfonates, the concentration of the above products preferably being in a range between 1 g / l and about 4 g / l.
- the dispersion or suspension is constantly moved. This can be done, for example, by stirring the dispersion or suspension or by irradiating it with ultrasound waves.
- a particularly good distribution and a stable dispersion or suspension are obtained by generating a turbulent flow in the dispersion or suspension, which can be achieved very well, for example, by blowing in air.
- the yarn components are usually intermingled at a fluid pressure between approximately 6 bar and approximately 15 bar, preferably between approximately 8 bar and approximately 10 bar. Either steam or air can be used as the fluid, the latter leading to particularly good results.
- a fluid pressure between approximately 6 bar and approximately 15 bar, preferably between approximately 8 bar and approximately 10 bar.
- Either steam or air can be used as the fluid, the latter leading to particularly good results.
- the yarn components of the starting material are fed to a nozzle and there through the turbulent fluid flow swirls, the fluid flow additionally having, for example, air and / or steam, also granular particles.
- the fluid flow that is fed to the nozzle is either a mist consisting of finely divided water droplets with a diameter between approximately 40 ⁇ m and approximately 600 ⁇ m with granular particles dispersed or suspended therein, and / or one Dust of the granular particles alone is added, the granular particles having a grain size between approximately 4 ⁇ m and approximately 400 ⁇ m and in particular between 20 ⁇ m and 100 ⁇ m.
- the granular particles are not supplied directly by the first yarn component, but rather by the fluid flows supplied to the nozzle, which leads to a further intensification of the intermingling of the yarns.
- the first yarn component is wetted with the particle-containing dispersion or suspension
- the particles adhering to the yarn during the air or steam flow during the relatively short stay of the yarn in the nozzle does not have to be accelerated there, but instead granular particles are already supplied to the nozzle as accelerated particles.
- the fluid flow is supplied with a mist which is produced from an aqueous dispersion or suspension of the granular particles, the concentration of the granular particles preferably being between approximately 30 g / l and approximately 300 g / l between about 60 g / l and about 200 g / l.
- concentration of the granular particles preferably being between approximately 30 g / l and approximately 300 g / l between about 60 g / l and about 200 g / l.
- the supply of a mist in which the particles are dispersed or suspended has the advantage that the mechanical stress on the yarn and the nozzle is reduced by the lubricating or sliding action caused by the water is, so that the supply of a dust to the fluid flow is preferably used when using particularly soft particles, when using special nozzles, which will be described below, and / or with relatively coarse-titer yarns.
- the fluid flow between about 0.1 m3 / h and about 5 m3 / h, in particular between about 0.5 m3 / h and about 2 m3 / h, fog or dust of the composition described above, with such Processes of fluid flow (air or steam) in a range between about 4 m3 / h and about 15 m3 / h, preferably between about 5 m3 / h and about 8 m3 / h.
- surfactants if a mist in which the granular particles are suspended or dispersed is fed to the fluid flow, it is also possible to add surfactants and / or To use dispersing or suspending agents, the surfactants or dispersing or. Suspension agents preferably have the chemical structure described above.
- the nozzle used to carry out the method according to the invention has at least a first inlet opening for the yarn, a second inlet opening for the fluid flow, an outlet opening for the swirled yarn and a swirl chamber, at least the inner walls of the swirl chamber and the inner walls of the outlet opening being made of ceramic .
- ceramic in particular not only has the required hardness and resistance to the particle flow impinging in the swirl chamber and the outlet opening, but at the same time brings about a constant flow profile in the nozzle due to its closed surface, which leads to a particularly reproducible yarn.
- the aqueous dispersion or suspension of the granular particles can be applied by spraying the thread with the dispersion or suspension or by immersing the thread in the dispersion or suspension.
- a special wetting device for applying the aqueous dispersion or suspension, through which the yarn is passed.
- this wetting device has a wetting head which can be brought into contact with the yarn and via which the dispersion or suspension of the granular particles is applied to the yarn in a kind of popping technique.
- Such wetting devices are known and are widely used and are offered, for example, by the Heberlein company under the system name "HEMA-WET-DÜSE".
- a yarn denoted overall by 1 which consists of a plurality of individual capillaries 2 which are intermingled.
- the individual capillaries are either swirled together in a knot-like manner, as can be seen at the point denoted by 3.
- the yarn also has protruding loops 4 and confused areas 5.
- Grain-like particles 6 are arranged in the spaces between the individual capillaries 2 and are freely movable in a certain area relative to the individual capillaries.
- Particles 7 adhere to the outside of the yarn and, like the particles 6, can be moved within a certain range relative to the individual capillaries 2 or to the yarn 1 as a whole.
- the particles 6 and 7 shown in the figure are titanium dioxide particles with a grain size of 60 ⁇ m. Their concentration is 0.2% by weight, based on the weight of the yarn.
- a sewing thread with a titer of 285 dtex is produced by interlacing a first thread component serving as a soul, which was a polyester multifilament thread with a titer of 180 dtex and an elementary thread count of 40 filaments.
- the first yarn component was interlaced with a second component (effect or sheath component), the titer of the second yarn component being 50 dtex with a number of filaments of 24 filaments.
- a conventionally designed, commercially available nozzle was used as the nozzle, which bore the type designation T341 and is offered by the Heberlein company.
- Air was fed to the nozzle as a fluid stream at a pressure of 10.5 bar, the air throughput being 8 m 3 / h. After intermingling, the yarn was drawn off at a speed of 500 m / min.
- the first thread component of the sewing thread was wetted before immersion by immersing it in water, the immersion distance being about 2 cm.
- the conventionally produced and designated sewing thread No. 1 was dyed and finished according to the known methods and served as a reference material for the subsequent mechanical-technological measurements and for industrial sewing tests.
- a No. 2 sewing thread was prepared under the conditions described above, the No. 2 sewing thread being treated with an aqueous suspension of 30 g / l barium sulfate before intermingling.
- the barium sulfate had a particle size of 80 ⁇ m. Otherwise, the manufacturing conditions corresponded to embodiment 1.
- a sewing thread Mr. 3 was produced in accordance with working example 1, however, in deviation from this, the first yarn component was wetted with a dispersion of 60 g / l titanium dioxide with a particle size of 20 ⁇ m prior to intermingling.
- a sewing thread No. 4 was produced under the conditions described in exemplary embodiment 1, but in deviation from this the first thread component was not wetted with water before the intermingling. Instead, 15% by volume of a mist, which was prepared from an aqueous dispersion of 100 g / l barium sulfate, was added to the air stream.
- the sewing threads 1 to 4 described above were first examined microscopically. It was found that the degree of interlacing of the sewing threads increased steadily from sewing thread No. 1 to sewing thread No. 4.
- the frequency of yarn breakage when rubbing sewing thread against sewing thread was determined on a specially developed measuring device.
- one end of the sewing thread was clamped in a clamp, then the sewing thread was placed in a loop, the loop over movable rollers was kept open and then the yarn was moved under a load of 50 g in such a way that a point-like abrasion of yarn on yarn occurred at the loop.
- the scouring tests were carried out until the yarn broke, the number of movement cycles until the break being measured.
- the conventionally produced sewing thread 1 broke after 200 movement cycles. Sewing thread 2 broke at 450 movement cycles, while 3,600 movement cycles were required for sewing thread and 4,750 movement cycles for sewing thread were required to break.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein Garn, insbesondere ein Nähgarn, mit den Merkmalen des Oberbegriffs des Patentanspruchs 1 sowie zwei Verfahren zur Herstellung des Garnes mit den Merkmalen der Oberbegriffe der Patentansprüche 11 und 19.The present invention relates to a yarn, in particular a sewing thread, with the features of the preamble of
Verwirbelte Garne, die aus mindestens zwei Garnkomponenten bestehen, wobei die eine Garnkomponente die Seele, die auch Kern genannt wird, und die andere Garnkomponente den Mantel bilden, sind seit langem bekannt.Swirled yarns, which consist of at least two yarn components, one yarn component forming the core, which is also called the core, and the other yarn component forming the sheath, have long been known.
Üblicherweise werden derartige verwirbelte Garne dadurch hergestellt, daß man das Kernmaterial mit einer bestimmten Voreilung, beispielsweise zwischen etwa 1 % und etwa 5 %, zusammen mit dem Mantelmaterial einer Düse zuführt und dort durch einen Luftstrom miteinander verwirbelt, wobei das Mantelmaterial in der Regel im Vergleich zum Kernmaterial mit einer wesentlich höheren Voreilung in die Düse eingebracht wird. In der Düse bewirkt der auf das Garn auftreffende Luftstrom, daß die Einzelfilamente des Seelen- und/oder des Mantelmaterials, beispielsweise unter Ausbildung von Schlaufen, Schlingen u. dgl., verwirbelt und verwirrt werden, so daß das resultierende fertige Garn aufgrund dieser Verwirbelung bzw. Verwirrung einen geschlossenen Garnverband bildet, ohne daß hierfür zwangsläufig eine Zwirnung der beiden Komponenten notwendig ist.Typically, such intermingled yarns are produced by feeding the core material with a certain advance, for example between about 1% and about 5%, together with the sheath material to a nozzle and swirling it there by an air stream, the sheath material generally being compared to the core material with a much higher lead in the nozzle. In the nozzle, the air stream hitting the yarn causes the individual filaments of the soul and / or the sheath material, for example with the formation of loops, loops and. Like., Swirled and confused, so that the resulting finished yarn forms a closed yarn structure due to this swirling or confusion, without a twisting of the two components is necessary for this.
Daneben sind noch verwirbelte Einfachgarne (Single-Konstruktionen) bekannt, die nicht die vorstehend beschriebene Kern-Mantelstruktur aufweisen. Hierbei wird das aus Einzelfilamenten bestehende Multifilamentgarn mit einer bestimmten Voreilung der Düse zugeführt und. über einen Luftstrom derartig verwirbelt, daß die Einzelfilamente mit sich selbst verwirbelt bzw. verwirrt werden, so daß ein an sich geschlossenes Garn resultiert.In addition, swirled single yarns (single constructions) are known which do not have the core-sheath structure described above. Here, the multifilament yarn consisting of individual filaments is fed to the nozzle with a certain advance. swirled over an air stream in such a way that the individual filaments are swirled or tangled with themselves, so that a yarn which is closed per se results.
Um bei dem zuvor beschriebenen bekannten Verfahren insbesondere eine gleichmäßige Verwirbelung des Seelen materials mit dem Mantelmaterial und eine konstante Dicke des fertigen Garnes zu erzielen, ist es bei Verwirbelungsverfahren üblich, die die Seele bildende erste Garnkomponente vor dem Verwirbeln mit Wasser zu netzen. Hierdurch soll eine Verschmutzung der Düse durch Präparationen und/oder Avivagen, die vom Wasser gelöst und somit vor der Düse von dem Garn entfernt werden, verhindert werden. Darüberhinaus sollen dabei die Einzelfilamente der ersten Garnkomponente, die ggf. durch die Präparation und Avivagen miteinander verklebt sind, aufgespreizt werden, so daß ein relativ offener Garnverband der Düse zugeführt wird, was die Gleichmäßigkeit und den Verwirbelungseffekt verbessern kann. Das vorstehend beschriebene Netzen der ersten Garnkomponente mit Wasser kann jedoch bei den bekannten Verfahren zu Schwierigkeiten führen. Diese drücken sich beispielsweise dadurch aus, daß die Präparation bzw. Avivagen während des relativ kurzen Netzvorganges nur angelöst bzw. hydratisiert werden, so daß sie bei der anschließenden Verwirbelung in der Düse erhebliche Schwierigkeiten bereiten, die sich beispielsweise in einem Abschmieren bzw. in einer Ablagerung der angelösten bzw. hydratisierten Präparationen und Avivagen an den Innenwandungen der Düse bemerkbar machen. Dies wiederum führt dazu, daß sich die Strömungsverhältnisse der für die Verwirbelung der Garne verantwortlichen Luftströmung in der Düse ständig ändern, was sich in einem unregelmäßig verwirbelten Garn und/oder unerwünschten Titerschwankungen ausdrückt. Bei einem derartigen Garn sind dann die mechanisch-technologischen Eigenschaften erheblich verschlechtert, was sich beispielsweise bei einem Nähgarn in einer verringerten Festigkeit, einer Verschlechterung des Kraft-Dehnungs-Verhältnisses und/oder in einer Erhöhung der Garnbruchhäufigkeit beim Nähen ausdrücken kann.In order to achieve, in particular, a uniform intermingling of the core material with the sheath material and a constant thickness of the finished yarn in the known method described above, it is common in intermingling methods to wet the core-forming first yarn component with water before intermingling. This is to prevent contamination of the nozzle by preparations and / or finishing agents which are detached from the water and thus removed from the yarn in front of the nozzle. In addition, the individual filaments of the first yarn component, which may or may not be glued together by the preparation and finishing agents, are to be spread out, so that a relatively open yarn group is fed to the nozzle, which can improve the uniformity and the swirling effect. However, the previously described wetting of the first yarn component with water can lead to difficulties in the known processes. These are expressed, for example, by the fact that the preparation or finishing agents are only dissolved or hydrated during the relatively short wetting process, so that they are subsequently swirled cause considerable difficulties in the nozzle, which are noticeable, for example, in smearing or in a deposit of the dissolved or hydrated preparations and additives on the inner walls of the nozzle. This in turn leads to the fact that the flow conditions of the air flow in the nozzle responsible for the intermingling of the yarns change constantly, which is expressed in an irregularly intermingled yarn and / or undesirable titre fluctuations. With such a thread, the mechanical-technological properties are then considerably deteriorated, which can be expressed, for example, in the case of a sewing thread in a reduced strength, a deterioration in the force-elongation ratio and / or in an increase in the frequency of thread breakage during sewing.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, ein Garn der angegebenen Art zur Verfügung zu stellen, das eine besonders niedrige Garnbruchhäufigkeit bei der Verarbeitung besitzt.The present invention has for its object to provide a yarn of the type specified, which has a particularly low frequency of yarn breakage during processing.
Diese Aufgabe wird durch ein Garn mit den kennzeichnenden Merkmalen des Patentanspruchs 1 gelöst.This object is achieved by a yarn with the characterizing features of
Das erfindungsgemäß ausgebildete Garn, das insbesondere als Nähgarn verwendet wird, besteht mindestens aus einer als Seele ausgebildeten ersten Garnkomponente und mindestens einer mit der ersten Garnkomponente verwirbelten zweiten Garnkomponente, wobei die zweite Garnkomponente überwiegend in bezug auf das fertige Garn im äußeren Bereich desselben angeordnet ist. In den Garnzwischenräumen und/oder außen am Garn sind kornartige Partikel angeordnet. Hierbei besitzen die kornartigen Partikel einen Korndurchmesser zwischen etwa 4 µm und etwa 400 µm . Ihre Konzentration beträgt zwischen etwa 0,02 Gew. % und etwa 20 Gew. %, jeweils bezogen auf das Garngewicht.The yarn designed according to the invention, which is used in particular as a sewing thread, consists of at least one first yarn component designed as a core and at least one second yarn component intermingled with the first yarn component, the second yarn component being arranged predominantly in relation to the finished yarn in the outer region thereof. Grain-like particles are arranged in the spaces between the threads and / or on the outside of the thread. The grain-like particles have a grain diameter of between approximately 4 μm and approximately 400 μm. Your concentration is between about 0.02% by weight and about 20% by weight, each based on the weight of the yarn.
Überraschenderweise wurde bei dem erfindungsgemäßen Garn festgestellt, daß die mechanisch-technologischen Eigenschaften und das Verarbeitungsverhalten im Vergleich zu einem konventionell ausgebildeten, gleichwertigen Garn, das derartige kornartige Partikel nicht aufweist, erheblich verbessert ist. Dies drückt sich beispielsweise darin aus, daß die Garnfestigkeit um etwa 15 % im Vergleich zu dem vorstehend beschriebenen Standardgarn verbessert ist, während gleichzeitig bei dem erfindungsgemäßen Garn die Elastizität verbessert wird. Bei industriellen Nähversuchen sowie bei vergleichenden Labormessungen bezüglich der Faden-Faden-Reibung gegeneinander, wie diese nachfolgend näher noch bei den Ausführungsbeispielen beschrieben wird, konnte festgestellt werden, daß die Fadenbruchhäufigkeit eines konventionellen Garnes mit gleichem Aufbau im Vergleich zu dem erfindungsgemäßen Garn um einen Faktor zwischen etwa 3 und etwa 8 höher liegt. Dies wird darauf zurückgeführt, daß die kornartigen Partikel, die außen an dem fertigen Garn und/oder in den Garnzwischenräumen eingelagert und relativ zu den Einzelfilamenten des Garnes beweglich angeordnet sind, die Reibung zwischen den einzelnen Filamenten des Garnes und/oder die Reibung der äußeren Garnbereiche an beispielsweise Fadenumlenkorganen, Nähnadeln, anderen Fadensystemen o. dgl. erheblich reduzieren. Dadurch treten eine verringerte mechanische Beanspruchung der Einzelfilamente und/oder des gesamten Garnes und damit verbunden eine geringere Erwärmung des Garnes auf, so daß die deutlich herabgesetzte Neigung zu Fadenbrüchen erklärlich wird. Auch besitzt das erfindungsgemäße Garn eine höhere Verwirbelung im Vergleich zu einem unter sonst gleichen Bedingungen hergestellten herkömmlichen Garn, worauf die zuvor geriannten Eigenschaftsverbesserungen auch zurückgeführt werden. Abhängig von der chemischen Zusammensetzung der kornartigen Partikel sowie ihrer Korndurchmesser und Verteilung im bzw. am Garn können diese Partikel die elektrostatische Aufladung bei synthetischen Garnen verringern, was wiederum die Verarbeitungseigenschaften des erfindungsgemäßen Garnes verbessert.Surprisingly, it was found in the yarn according to the invention that the mechanical-technological properties and the processing behavior are considerably improved in comparison with a conventionally designed, equivalent yarn which does not have such granular particles. This is expressed, for example, in that the yarn strength is improved by approximately 15% compared to the standard yarn described above, while at the same time the elasticity is improved in the yarn according to the invention. In industrial sewing tests and in comparative laboratory measurements with respect to the thread-thread friction against each other, as will be described in more detail below in the exemplary embodiments, it was found that the thread break frequency of a conventional yarn with the same structure compared to the yarn according to the invention by a factor of between is about 3 and about 8 higher. This is attributed to the fact that the grain-like particles which are embedded on the outside of the finished yarn and / or in the yarn spaces and are arranged so as to be movable relative to the individual filaments of the yarn, the friction between the individual filaments of the yarn and / or the friction of the outer yarn regions on thread deflection elements, sewing needles, other thread systems or the like. As a result, the mechanical stress on the individual filaments and / or the entire yarn is reduced and, associated therewith, less heating of the yarn occurs, so that the significantly reduced tendency to thread breaks is explained. The yarn according to the invention also has a higher interlacing in comparison to a conventional yarn produced under otherwise the same conditions, to which the property improvements previously mentioned are also attributed. Depending on the chemical composition of the grain-like particles as well as their grain diameter and distribution in or on the yarn, these particles can contribute to the electrostatic charge reduce synthetic yarns, which in turn improves the processing properties of the yarn according to the invention.
Ergänzend zu dem eingangs dargestellten Stand der Technik ist noch anzumerken, daß aus der EP 0 136 727 A ein Garn bekannt ist, das als Füllstoff bzw. Dichtmaterial eingesetzt wird. Hierbei weist das bekannte Garn, bei dem es sich um ein einziges Multifilamentgarn handelt, eine Filamentzahl zwischen 1.000 und 20.000 Filamenten auf. Um ein derartiges Garn herzustellen, schlägt die EP 0 136 727 A ein Verwirbeln des einzigen multifilen Ausgangsmaterials vor, wobei vor dem Verwirbeln das multifile Ausgangsmaterial mit einer wäßrigen Dispersion von kornartigen Partikeln genetzt wird. Die hierfür eingesetzten kornartigen Partikel weisen jedoch eine Korngröße auf, die überwiegend zwischen 0,1 um bis 1 um variiert. Somit unterscheidet sich das bekannte Garn von dem zuvor beschriebenen erfindungsgemäßen Garn nicht nur in seiner Konstruktion sondern auch entscheidend in der Filamentzahl sowie der Größe der kornartigen Partikel.In addition to the prior art described at the outset, it should also be noted that EP 0 136 727 A discloses a yarn which is used as a filler or sealing material. Here, the known yarn, which is a single multifilament yarn, has a filament number between 1,000 and 20,000 filaments. In order to produce such a yarn, EP 0 136 727 A suggests swirling the only multifilament starting material, the multifilament starting material being wetted with an aqueous dispersion of granular particles before the swirling. The grain-like particles used for this, however, have a grain size that varies predominantly between 0.1 μm and 1 μm. The known yarn thus differs from the previously described inventive yarn not only in its construction but also decisively in the number of filaments and the size of the grain-like particles.
Eine besonderes geeignete Ausführungsform des erfindungsgemäßen Garnes weist kornartige Partikel in einer Konzentration zwischen etwa 0,2 Gew. % bis etwa 0,4 Gew. % auf. Insbesondere bei Garnen mit einem sehr feinen Titer, d.h. bei Garnen in einem Titerbereich zwischen etwa 100 dtex und etwa 300 dtex, hat sich gezeigt, daß der zuvor genannte Konzentrationsbereich an kornartigen Partikeln ausreichend ist, um die gewünschte Verbesserung der Verarbeitungseigenschaften, die Festigkeitszunahme sowie die Erhöhung des Dehnungsverhaltens zu erreichen. Dies trifft insbesondere dann zu, wenn die kornartigen Partikel vorwiegend oder ausschließlich an der Oberfläche des fertigen Garnes angeordnet werden und wenn der Durchmesser der Partikel etwa in einem Bereich zwischen 10 µm und etwa 100 µm liegt. Bei Garnen mit höheren Titern, d.h. Titern im Bereich zwischen etwa 500 dtex und etwa 800 dtex,können höhere Konzentrationen an kornartigen Partikeln erforderlich sein, wobei diese Konzentrationen üblicherweise in einem Bereich zwischen etwa 0,5 Gew. % und etwa 4 Gew. % liegen. Bei Garnen, die einen relativ großen Titer aufweisen, d.h. einen Titer in einem Bereich zwischen 800 dtex und etwa 1200 dtex, können Partikelkonzentrationen in einer Größenordnung zwischen etwa 5 Gew. % und etwa 15 Gew. % erforderlich sein, um die zuvor genannten günstigen Eigenschaften zu erreichen, wobei bei allen, zuvor genannten Garnen, die Partikelkonzentration für das jeweilige Garn von der Elementarfadenzahl, der Verteilung der Partikel über den Garnquerschnitt und den Partikeldurchmesser abhängig ist.A particularly suitable embodiment of the yarn according to the invention has granular particles in a concentration between about 0.2% by weight and about 0.4% by weight. Especially for yarns with a very fine titer, i.e. for yarns in a titer range between about 100 dtex and about 300 dtex, it has been shown that the aforementioned concentration range of granular particles is sufficient to achieve the desired improvement in processing properties, the increase in strength and the increase in elongation behavior. This is particularly true if the grain-like particles are predominantly or exclusively arranged on the surface of the finished yarn and if the diameter of the particles is approximately in a range between 10 μm and approximately 100 μm. For yarns with higher titers, i.e. Titers in the range between approximately 500 dtex and approximately 800 dtex may require higher concentrations of granular particles, these concentrations usually being in a range between approximately 0.5% by weight and approximately 4% by weight. For yarns that have a relatively large titer, i.e. a titer in a range between 800 dtex and approximately 1200 dtex, particle concentrations in the order of magnitude between approximately 5% by weight and approximately 15% by weight may be required in order to achieve the above-mentioned favorable properties, with all of the above-mentioned yarns, the particle concentration for the respective yarn depends on the number of filaments, the distribution of the particles over the yarn cross-section and the particle diameter.
Besonders gute mechanische Eigenschaften und ein vorteilhaftes Verarbeitungsverhalten weisen solche Ausführungsformen des erfindungsgemäßen Garnes auf, bei denen die kornartigen Partikel einen Korndurchmesser zwischen etwa 20 µm und etwa 100 µm besitzen. Derartige, relativ kleine Partikel reduzieren besonders wirkungsvoll die zuvor beschriebene Reibung und besitzen zudem noch eine gute Haftung zu dem Garn, so daß bei der Verarbeitung des Garnes Kein unerwünschtes Stauben auftritt.Such embodiments have particularly good mechanical properties and advantageous processing behavior of the yarn according to the invention, in which the grain-like particles have a grain diameter of between approximately 20 μm and approximately 100 μm. Such relatively small particles are particularly effective in reducing the friction described above and also have good adhesion to the yarn, so that no unwanted dusting occurs when the yarn is processed.
Bezüglich der Verteilung der kornartigen Partikel über den Garnquerschnitt ist festzuhalten, daß sowohl Ausführungsform des erfindungsgemäßen Garnes, bei denen die Partikel überwiegend oder ausschließlich im Außenbereich des Garnes angeordnet sind,als auch solche Ausführungsformen beansprucht werden, bei denen die Partikel gleichmäßig über den Garnquerschnitt verteilt sind. Insbesondere die zuletzt genannten Ausführungsformen sind für solche Garne geeignet, die bei einer relativ hohen Elementarfadenzahl, d.h. zwischen etwa 80 Elementarfäden und etwa 200 Elementarfäden, einen relativ feinen Titer, beispielsweise zwischen etwa 100 dtex und etwa 300 dtex, aufweisen. Bei derartigen Garnen konnte festgestellt werden, daß die gewünschte Eigenschaftsverbesserung maßgeblich davon abhängt, daß wirksam die Reibung zwischen den Elementarfäden verringert wird, was durch Einlagerung der Partikel in die zwischen den Elementarfäden bestehenden Zwischenräumen erreicht wird.With regard to the distribution of the grain-like particles over the yarn cross section, it should be noted that both the embodiment of the yarn according to the invention, in which the particles are predominantly or exclusively arranged in the outer region of the yarn, and those embodiments in which the particles are evenly distributed over the yarn cross section are claimed . In particular, the last-mentioned embodiments are suitable for yarns which have a relatively high number of filaments, i.e. between about 80 filaments and about 200 filaments, have a relatively fine titer, for example between about 100 dtex and about 300 dtex. In the case of such yarns, it was found that the desired improvement in properties depends crucially on the fact that the friction between the filaments is effectively reduced, which is achieved by embedding the particles in the spaces between the filaments.
Eine weitere vorteilhafte Ausführungsform des erfindungsgemäßen Garnes sieht vor, daß die kornartigen Partikel in einer auf das Garn aufgebrachten Avivage eingebettet sind. Hierbei unterstützt die Avivage die Wirkung der kornartigen Partikel in bezug auf eine Verringerung der Reibung, wobei gleichzeitig die Avivage die Haftung der kornartigen Partikel zum Garn bzw. Zu den darin verarbeiteten Einzelfilamenten verbessert. Darüberhinaus beeinträchtigt die Avivage die Beweglichkeit der Partikel relativ zu den Einzelfilamenten bzw. dem Garn nur geringfügig, so daß die zuvor beschriebenen positiven Eigenschaften der Partikel bei einer derartigen Ausführungsform des erfindungsgemäßen Garnes zusätzlich verstärkt werden. Bezüglich der Verteilung der Avivage gelten die gleichen Ausführungen, wie dies vorstehend für die Verteilung der Partikel gemacht wurden.Another advantageous embodiment of the yarn according to the invention provides that the grain-like particles are embedded in a finish applied to the yarn. The finish supports the effect of the grain-like particles in reducing friction, while the finish improves the adhesion of the grain-like particles to the yarn or to the individual filaments processed therein. In addition, the avivage affects The mobility of the particles relative to the individual filaments or the yarn is only slight, so that the previously described positive properties of the particles are additionally reinforced in such an embodiment of the yarn according to the invention. With regard to the distribution of the finish, the same statements apply as were made above for the distribution of the particles.
Bezüglich der chemischen Zusammensetzung der Avivage ist festzuhalten, daß diese aus den an sich bekannten chemischen Verbindungen bestehen kann. Hier sind insbesondere die Carbonsäurederivate, Phosphorsäureester, Paraffinkohlenwasserstoffe und/oder siliciumorganische Verbindungen zu nennen.Regarding the chemical composition of the finish, it should be noted that this can consist of the chemical compounds known per se. The carboxylic acid derivatives, phosphoric acid esters, paraffin hydrocarbons and / or organosilicon compounds should be mentioned here in particular.
Wie bereits vorstehend erwähnt ist, weist das erfindungsgemäße Garn eine Kern-Mantelstruktur auf, wobei der Kern (Seele) aus einem Multifilamentgarn, beispielsweise einem mit einem Titer zwischen etwa 100 dtex und etwa 500 dtex, insbesondere mit einem Titer zwischen etwa 150 dtex und etwa 300 dtex, besteht. Die Elementarfadenzahl eines derartigen Kernmaterials kann abhängig von dem jeweiligen Einsatzgebiet des Garnes zwischen etwa 50 Fäden und etwa 500 Fäden, insbesondere zwischen etwa 100 Fäden und etwa 300 Fäden, schwanken. Als Mantel besitzt das zuvor beschriebene Kern-Mantelgarn ein oder mehrere Multifilamentgarne, deren Titer und Elementarfadenzahl in etwa der Hälfte des Titers und der Elementarfadenzahl des Seelenmaterials entsprechen. Selbstverständlich ist es jedoch auch möglich, als Mantelmaterial ein in der Feinheit mit den zuvor beschriebenen Multifilamantgarnen vergleichbares Fasergarn zu verwenden.As already mentioned above, the yarn according to the invention has a core-sheath structure, the core (core) made of a multifilament yarn, for example one with a titer between approximately 100 dtex and approximately 500 dtex, in particular with a titer between approximately 150 dtex and approximately 300 dtex. The number of filaments of such a core material can vary between approximately 50 threads and approximately 500 threads, in particular between approximately 100 threads and approximately 300 threads, depending on the particular field of use of the yarn. As a sheath, the core sheath yarn described above has one or more multifilament yarns, the titer and number of filaments of which correspond to approximately half the titer and the number of filaments of the core material. Of course, however, it is also possible to use a fiber yarn that is comparable in fineness to the multifilamant yarns described above.
Bezüglich der kornartigen Partikel kommen grundsätzlich solche Partikel infrage, die eine bestimmte Härte und Widerstandsfähigkeit gegenüber mechanischen Beanspruchungen aufweisen. Insbesondere sind anorganische Partikel, wie beispielsweise Talkum, Kieselgur und Aluminiumoxid geeignet.With regard to the grain-like particles, there are basically those particles that have a certain hardness and resistance exhibit mechanical loads. Inorganic particles such as talc, kieselguhr and aluminum oxide are particularly suitable.
Besonders gute mechanische Eigenschaften und ein ausgezeichnetes Verarbeitungsverhalten weist eine Ausführungsform des erfindungsgemäßen Garnes auf, das Titandioxid- und/oder Bariumsulfatpartikel enthält, da diese Substanzen eine ausgezeichnete Widerstandsfähigkeit gegenüber einer mechanischen Belastung besitzen.One embodiment of the yarn according to the invention, which contains titanium dioxide and / or barium sulfate particles, has particularly good mechanical properties and excellent processing behavior, since these substances have excellent resistance to mechanical stress.
Das erfindungsgemäße Garn kann überall dort verarbeitet werden, wo während der Verarbeitung eine hohe mechanische Belastung des Garnes auftritt und/oder eine hohe Festigkeit sowie ein ausgezeichnetes Elastizitätsverhalten des Garnes erforderlich ist. Insbesondere die Verwendung des erfindungsgemäßen Garnes als Nähgarn bringt erhebliche Vorteile im Vergleich zu einem entsprechend ausgebildeten konventionellen Garn, wie dies nachfolgend noch durch die Ausführungsbeispiele belegt wird. Hierbei weist ein derartiges Nähgarn vorzugsweise die zuvor beschriebene Kern-Mantelstruktur auf.The yarn according to the invention can be processed wherever a high mechanical load on the yarn occurs during processing and / or high strength and excellent elastic behavior of the yarn is required. In particular, the use of the yarn according to the invention as a sewing thread brings considerable advantages compared to a suitably designed conventional thread, as will be demonstrated below by the exemplary embodiments. Such a sewing thread preferably has the core / sheath structure described above.
Insbesondere bei gefärbten Garnen kann es vorkommen, daß eine Anreicherung der Partikel im äußeren Bereich des Garnes vorliegt, da üblicherweise das erfindungsgemäße Garn, wie nachstehend beschrieben, hergestellt und danach erst gefärbt wird. Bei der Färbung des erfindungsgemäßen Garnes kann es insbesondere bei sehr offenen Garnen zu einer Anreicherung der Partikel im äußeren Garnbereich kommen, wobei eine derartige Anreicherung jedoch keine unerwünschten Nebeneffekte bewirkt.In the case of dyed yarns in particular, there may be an accumulation of particles in the outer region of the yarn, since the yarn according to the invention is usually produced as described below and only afterwards is colored. When the yarn according to the invention is dyed, particles can accumulate in the outer yarn area, in particular in the case of very open yarns, but such an enrichment does not cause any undesirable side effects.
Auch kann das erfindungsgemäße Garn zusätzlich zur Verwirbelung noch eine Drehung, beispielsweise im Bereich zwischen 1 Drehung / m und etwa 1000 Drehungen/m, vorzugsweise zwischen etwa 100 Drehungen/m und etwa 600 Drehungen/m, aufweisen. Eine derartige, gedrehte Ausführungsform ist insbesondere für solche Einsatzzwecke geeignet, bei denen das Garn extrem hohen mechanischen Belastungen ausgesetzt ist, wie dies beispielsweise auf Garne, die in der großtechnischen Konfektion eingesetzt werden, zutrifft. Hierbei verbessert die Drehung zusätzlich zur Verwirbelung noch den Garnverbund, während die vorzugsweise außen an einem derartig gedrehten Garn angeordneten Partikel erheblich die bei der Verarbeitung auftretende Reibung reduziert, so daß die Garnbruchhäufigkeit deutlich reduziert ist.In addition to the intermingling, the yarn according to the invention can also have a twist, for example in the range between 1 twist / m and approximately 1000 twists / m, preferably between approximately 100 twists / m and approximately 600 twists / m. Such a twisted embodiment is particularly suitable for those uses in which the yarn is exposed to extremely high mechanical loads, as is the case, for example, with yarns used in large-scale manufacturing. In addition to the intermingling, the rotation also improves the yarn composite, while the particles preferably arranged on the outside of such a twisted yarn considerably reduce the friction occurring during processing, so that the yarn breakage frequency is significantly reduced.
Der vorliegenden Erfindung liegt ferner die Aufgabe zugrunde, ein Verfahren der angegebenen Art zur Verfügung zu stellen, mit dem die vorstehend beschriebenen Garne unter besonderer Berücksichtigung eines gleichmäßigen Garntiters herstellbar sind.The present invention is also based on the object of providing a method of the type specified, with which the yarns described above can be produced with special consideration of a uniform yarn titer.
Diese Aufgabe wird erfindungsgemäß durch ein Verfahren mit den kennzeichnenden Merkmalen des Patentanspruchs 11 sowie durch ein Verfahren mit den kennzeichnenden Merkmalen des Patentanspruchs 19 gelöst.According to the invention, this object is achieved by a method having the characterizing features of patent claim 11 and by a method having the characterizing features of patent claim 19.
Die erste, grundsätzliche Variante des erfindungsgemäßen Verfahrens beruht auf dem Grundgedanken, daß man dem Wasser, mit dem die erste Garnkomponente vor dem Verwirbeln benetzt wird, kornartige Partikel zusetzt, wobei die hier eingesetzten kornartigen Partikel ein spezifisches Gewicht größer als 1 g/cm³ und einen Korndurchmesser zwischen etwa 4 µm und etwa 400 µm, insbesondere zwischen etwa 20 µm und etwa 100 µm, aufweisen. Dies führt dann bei dem erfindungsgemäßen Verfahren dazu, daß in der Düse, und dort speziell in der Wirbelkammer, eine turbulente Fluidströmung auf das Garn einwirkt, die neben dem der Düse Jeweils zugeführten Fluid, beispielsweise Luft oder Dampf, eine turbulente Teilchenströmung aus dem definiert großen kornartigen Partikeln enthält, wodurch der Verwirblungsgrad der Einzelfilamente erhöht und die Ein- bzw. Anlagerung der kornartigen Partikel im bzw. am Garn bewirkt werden, so daß ein derartig hergestelltes Nähgarn die Vorteile aufweist, wie diese vorstehend für das erfindungsgemäße Garn beschrieben sind.The first, basic variant of the method according to the invention is based on the basic idea that grain-like particles are added to the water with which the first yarn component is wetted before intermingling, the grain-like particles used here having a specific weight greater than 1 g /
Das erfindungsgemäße Verfahren weist eine Reihe von weiteren Vorteilen auf So zeichen sich die nach diesem Verfahren hergestellten Kern-Mantelgarne durch einen besonders gleichmäßigen Titer aus, was darauf zurückgeführt wird, daß durch die zusätzliche Partikelströmung in der Wirbelkammer die Strömungsverhältnisse in der Düse optimiert und/oder vergleichmäßigt werden. Darüberhinaus bewirkt die Teilchenströmung, daß evtl. vorhandene Verfilzungen der ersten Garnkomponente gelöst werden, was wiederum eine Verbesserung der Garngleichmäßigkeit herbeiführt. Auch verhindert die Partikelströmung die Ablagerung von angelösten bzw. abgeschmierten Präparationen und Avivagen in der Düse, so daß während der Produktion unerwünschte und nicht kontrollierbare Anderungen der Dimension der Düse infolge von Ablagerungen bzw. Abschmierungen bei dem erfindungsgemäßen Verfahren nicht auftreten, wodurch einerseits die Strömungsverhältnisse in der Düse auch über einen längeren Produktionszeitraum hin konstant gehalten werden und andererseits unerwünschte Knotenbildungen und/oder Kapillar- oder Garnbrüche verhindert werden. Dies bewirkt, daß nach dem erfindungsgemäßen Verfahren auch über einen längeren Zeitraum ohne Unterbrechung und ohne notwendige Reinigung der Düse die zuvor beschriebenen Garne hergestellt werden können, so daß bei dem erfindungsgemäßen Verfahren keine nennenswerten Ausfallzeiten für die Reinigung der Düse und/oder das erneute Einführen der Garne bei auftretenden Garnbrüchen anfallen. Somit erlaubt das erfindungsgemäße Verfahren insgesamt gesehen die wirtschaftliche Herstellung von verbesserten Kern-Mantelgarnen, wobei sich dieses vorzugsweise in verbesserten mechanisch-technologischen Eigenschaften und in einer höheren mechanischen Beanspruchbarkeit der Garne beim Verarbeiten bemerkbar macht.The process according to the invention has a number of further advantages. The core-jacket yarns produced by this process are characterized by a particularly uniform titer, which is attributed to the fact that the flow conditions in the nozzle are optimized and / or by the additional particle flow in the swirl chamber be evened out. In addition, the particle flow causes any matting of the first yarn component to be loosened, which in turn improves the yarn uniformity. The particle flow also prevents the deposit of loosened or lubricated preparations and additives in the nozzle, so that undesired and uncontrollable changes in the dimension of the nozzle due to deposits or lubrication do not occur in the process according to the invention during production, so that on the one hand the flow conditions in the nozzle can also be kept constant over a longer production period and on the other hand undesirable Knot formation and / or capillary or yarn breaks can be prevented. This has the effect that the yarns described above can be produced over a longer period of time without interruption and without the need to clean the nozzle, so that in the method according to the invention there is no significant downtime for cleaning the nozzle and / or reinserting it Yarns occur when yarn breaks occur. Overall, the method according to the invention thus permits the economical production of improved core-sheath yarns, this being evident preferably in improved mechanical-technological properties and in a higher mechanical strength of the yarns during processing.
Vorzugsweise werden bei dem erfindungsgemäßen Verfahren kornartige Partikel verwendet, deren spezifisches Gewicht zwischen etwa 1 g/cm³ und etwa 6 g/cm³, insbesondere zwischen etwa 2 g/cm³ und etwa 4,5 g/cm³, liegt, wobei es sich als besonders vorteilhaft erwiesen hat, das spezifische Gewicht der kornartigen Partikel abhängig von dem jeweils zu verarbeitenden Garn zu variieren. Allgemein gilt hierfür, daß mit zunehmender Zahl der Elementarfäden des eingesetzten Garnes und zunehmendem Titer der Einzelkapillaren kornartige Partikel verwendet werden, deren spezifisches Gewicht in einem Bereich zwischen etwa 3 g/cm³ und etwa 4 g/cm³ liegt, während für relativ feinfädige Garne mit einer eher geringeren Elementarfadenzahl kornartige Partikel bevorzugt werden, die ein spezifisches Gewicht zwischen etwa 1 g/cm³ und etwa 3 g/cm³ aufweisen.Grain-like particles whose specific weight is between approximately 1 g /
Ebenso ist die Härte der jeweils verwendeten kornartikel Partikel von Bedeutung für die gewünschten Effekte. Einerseits sollen die kornartigen Partikel nicht so weich sein, daß sie während der Verwirbelung zerstört werden und andererseits sollen sie noch eine gewisse Weichheit aufweisen, um nicht unerwünschte Kapillarverletzungen und/oder unerwünschte Beschädigungen der Düse zu bewirken. Üblicherweise werden kornartige Partikel verwendet, die eine Härte nach der Härteskala von Mohs zwischen etwa 1 und etwa 7, insbesondere zwischen etwa 4 und etwa 6 1/2 besitzen, wobei jedoch auch die Härte, wie bereits vorstehend für die Dichte der kornartigen Partikel dargelegt, von dem jeweils eingesetzten Garn und dessen Elementarfadenzahl abhängt. Insbesondere bei Garnen mit einem gröberen Einzeltiter, d.h. einem Titer der Einzelkapillare im Bereich zwischen etwa 5 dtex und etwa 10 dtex, werden kornartige Partikel verwendet, die einen relativ hohen Wert in der Härteskala nach Mohs aufweisen, d.h. einem Wert im Bereich zwischen etwa 4 und etwa 6 1/2 liegt. Hingegen bei Ausgangsgarnen mit sehr feinen Elementarfäden, bei denen der Titer des Einzelfadens zwischen etwa 1 dtex und etwa 3 dtex liegt, werden eher kornartige Partikel verwendet, deren Härte gemäß der Härteskala nach Mohs in einem Bereich zwischen etwa 1 und etwa 3 1/2 liegt.The hardness of the particle particles used is also important for the desired effects. On the one hand, the granular particles should not be so soft that they are destroyed during the swirling and on the other hand they should still have a certain softness in order not to cause undesired capillary injuries and / or undesirable damage to the nozzle. Grain-like particles are usually used which have a hardness on the Mohs hardness scale of between approximately 1 and approximately 7, in particular between approximately 4 and approximately 6 1/2, but also the hardness, as already explained above for the density of the grain-like particles, depends on the yarn used and its number of filaments. Particularly in the case of yarns with a coarser single titer, ie a titer of the single capillary in the range between approximately 5 dtex and approximately 10 dtex, granular particles are used which have a relatively high value on the Mohs hardness scale, ie a value in the range between approximately 4 and is about 6 1/2. In contrast, in the case of starting yarns with very fine elementary threads, in which the titer of the single thread is between approximately 1 dtex and approximately 3 dtex, grain-like particles are used, the hardness of which, according to the Mohs hardness scale, lies in a range between approximately 1 and approximately 3 1/2 .
Auch die Korngröße der verwendeten Partikel kann, wie bereits vorstehend erwähnt ist,in einem Bereich zwischen etwa 4 µm und etwa 400 µm variieren, wobei insbesondere für die Herstellung von Garnen mit einem mittleren Titer zwischen etwa 300 dtex und etwa 600 dtex kornartige Partikel mit einem Korndurchmesser zwischen etwa 20 µm und etwa 100 µm verwendet werden. Allgemein gilt auch hierbei, daß bei den feineren Titern der Einzelfilamente und/oder des fertigen Garnes eher Partikel mit einer Korngröße zwischen etwa 20 µm und etwa 50 µm und bei den gröberen Titern der Einzelfilamente bzw. des fertigen Garns bevorzugt auch entsprechend größere kornartige Partikel, beispielsweise solche in einem Bereich zwischen etwa 150 µm und etwa 250 µm , verwendet werden.As already mentioned above, the grain size of the particles used can also vary in a range between approximately 4 μm and approximately 400 μm, in particular for the production of yarns with an average titer between approximately 300 dtex and approximately 600 dtex Grain diameters between about 20 microns and about 100 microns can be used. In general, it also applies here that in the case of the finer titers of the individual filaments and / or the finished yarn, particles with a grain size of between approximately 20 μm and approximately 50 μm are preferred, and in the case of the coarser titers of the individual filaments or of the finished yarn preferably also larger grain-like particles, for example, those in a range between approximately 150 μm and approximately 250 μm can be used.
Die Konzentration der kornartigen Partikel in der wäßrigen Suspension bzw. Dispersion hängt von der Art der Benetzung der ersten Garnkomponente ab. Wird die erste Garnkomponente durch Eintauchen in eine wäßrige Suspension bzw. Dispersion der kornartigen Partikel benetzt, so liegt üblicherweise die Konzentration in einem Bereich zwischen etwa 45 g kornartiger Partikel/l und etwa 150 g Partikel/l, wobei vorzugsweise ein Konzentrationsbereich zwischen etwa 30 g Partikel/l und etwa 60 g Partikel/l ausgewählt wird.The concentration of the granular particles in the aqueous suspension or dispersion depends on the type of wetting of the first yarn component. If the first yarn component is wetted by immersion in an aqueous suspension or dispersion of the granular particles, the concentration is usually in a range between approximately 45 g granular particles / l and approximately 150 g particles / l, preferably a concentration range between approximately 30 g Particle / l and about 60 g particle / l is selected.
Sprüht man hingegen die wäßrige Dispersion bzw. Suspension der kornartigen Partikel auf die erste Garnkomponente auf, so wendet man vorzugsweise Partikelkonzentrationen zwischen etwa 10 g/l und etwa 200 g/l, vorzugsweise zwischen etwa 50 g/l und etwa 150 g/l aus.If, on the other hand, the aqueous dispersion or suspension of the granular particles is sprayed onto the first yarn component, then particle concentrations between about 10 g / l and about 200 g / l, preferably between about 50 g / l and about 150 g / l, are preferably used .
Eine weitere Ausführungsform des erfindungsgemäßen Verfahrens sieht vor, daß man der wäßrigen Suspension bzw. Dispersion der kornartigen Partikel noch Tenside und/oder Dispersionsmittel bzw. Suspensionsmittel zusetzt. Hierbei können die an sich aus der Textilchemie bekannten Tenside bzw. Dispersions- und Suspensionsmittel eingesetzt werden, wobei vorzugsweise schaumarme Produkte und/oder die bekannten Schaumverhinderungsmittel, beispielsweise auf Basis von siliciumorganischen Verbindungen, eingesetzt werden. Besonders gute Ergebnisse können mit anionischen Tensiden bzw. Dispersions- und/oder Suspensionsmitteln auf Basis von organischen Sulfaten und Sulfonaten, z.B. Alkylsulfaten, Alkylsulfonaten und/oder Alkylarylsulfaten bzw. -sulfonaten, erzielt werden, wobei die Konzentration der vorstehenden Produkte vorzugsweise in einem Bereich zwischen 1 g/l und etwa 4 g/l liegt.Another embodiment of the process according to the invention provides that surfactants and / or dispersing agents or suspending agents are added to the aqueous suspension or dispersion of the granular particles. The surfactants or dispersing and suspending agents known per se from textile chemistry can be used here, preference being given to using low-foaming products and / or the known antifoaming agents, for example based on organosilicon compounds. Particularly good results can be achieved with anionic surfactants or dispersing and / or suspending agents based on organic sulfates and sulfonates, for example alkyl sulfates, alkyl sulfonates and / or alkylaryl sulfates or sulfonates, the concentration of the above products preferably being in a range between 1 g / l and about 4 g / l.
Um ein unerwünschtes Absetzen der kornartigen Partikel in der wäßrigen Suspension bzw. Dispersion zu verhindern, wird die Dispersion bzw. Suspension ständig bewegt. Dies kann beispielsweise dadurch geschehen, daß man die Dispersion bzw. Suspension rührt oder mit Ultraschallwellen bestrahlt. Eine besonders gute Verteilung und eine stabile Dispersion bzw. Suspension erhält man dadurch, daß man in der Dispersion bzw. Suspension eine turbulente Strömung erzeugt, wobei dies beispielsweise sehr gut durch Einblasen von Luft erreichbar ist.In order to prevent undesired settling of the granular particles in the aqueous suspension or dispersion, the dispersion or suspension is constantly moved. This can be done, for example, by stirring the dispersion or suspension or by irradiating it with ultrasound waves. A particularly good distribution and a stable dispersion or suspension are obtained by generating a turbulent flow in the dispersion or suspension, which can be achieved very well, for example, by blowing in air.
Üblicherweise werden bei dem erfindungsgemäßen Verfahren die Garnkomponenten bei einem Fluiddruck zwischen etwa 6 bar und etwa 15 bar, vorzugsweise zwischen etwa 8 bar und etwa 10 bar, miteinander verwirbelt. Als Fluid kann wahlweise Dampf oder Luft angesetzt werden, wobei letzteres zu besonders guten Ergebnissen führt. Durch die Anwendung der aus den kornartigen Partikeln bestehenden Teilchenströmung ist es bei dem erfindungsgemäßen Verfahren im Vergleich zu dem konventionellen Verfahren, das lediglich ein Netzen der ersten Garnkomponente mit Wasser vorsieht, möglich, den Fluiddruck um etwa 20 % bis etwa 40 % zu reduzieren, um beim gleichen Ausgangsmaterial den gleichen Verwirbelungsgrad zu erzielen. Dies führt bei dem erfindungsgemäßen Verfahren zu einer erheblichen Kostensenkung, da die Produktionskosten entscheidend von der eingesetzten Luftmenge abhängen, die entsprechend der vorstehenden Ausführung auch demnach in der gleichen Größenordnung (etwa 20 % bis etwa 40 %) reduziert wird.In the method according to the invention, the yarn components are usually intermingled at a fluid pressure between approximately 6 bar and approximately 15 bar, preferably between approximately 8 bar and approximately 10 bar. Either steam or air can be used as the fluid, the latter leading to particularly good results. By using the particle flow consisting of the granular particles, it is possible in the method according to the invention in comparison to the conventional method, which only provides for wetting the first yarn component with water, to reduce the fluid pressure by about 20% to about 40% in order to to achieve the same degree of swirling with the same starting material. In the method according to the invention, this leads to a considerable reduction in costs, since the production costs depend crucially on the amount of air used, which is accordingly reduced in the same order of magnitude (approximately 20% to approximately 40%) in accordance with the above embodiment.
Bei einer weiteren, besonders vorteilhaften Ausführungsform des erfindungsgemäßen Verfahrens zur Herstellung des eingangs beschriebenen Kern-Mantelgarnes werden die Garnkomponenten des Ausgangsmaterials einer Düse zugeführt und dort durch die turbulente Fluidströmung verwirbelt, wobei die Fluidströmung neben beispielsweise Luft und/oder Dampf zusätzlich noch kornartige Partikel aufweist. Hierbei kann derart verfahren werden, daß man der Fluidströmung, die der Düse zugeführt wird, entweder einen Nebel, der aus feinverteilten Wassertröpfchen mit einem Durchmesser zwischen etwa 40 µm und etwa 600 µm mit darin dispergierten bzw. suspendierten kornartigen Partikeln besteht, und/oder einen Staub der kornartigen Partikel allein zusetzt, wobei die kornartigen Partikel eine Korngröße zwischen etwa 4 µm und etwa 400 µm und insbesondere zwischen 20 µm und 100 µm aufweisen. Somit werden bei dieser Ausführungsform des erfindungsgemäßen Verfahrens die kornartigen Partikel nicht durch die erste Garnkomponente, sondern durch die der Düse zugeführten Fluidströmungen direkt geliefert, was zu einer weiteren Intensivierung der Verwirbelung der Garne führt. Als Erklärung hierfür wird angenommen, daß bei dieser Ausführungsform des erfindungsgemäßen Verfahrens im Vergleich zu den vorstehend beschriebenen Ausführungsformen, bei dem die erste Garnkomponente mit der partikelhaltigen Dispersion bzw. Suspension benetzt werden, die an dem Garn anhaftenden Partikel durch den Luft- bzw. Dampfstrom während des relativ kurzen Aufenthaltes des Garnes in der Düse nicht erst dort beschleunigt werden müssen, sondern statt dessen bereits als beschleunigte Teilchen kornartige Partikel der Düse zugeführt werden. Dies wiederum führt dazu, daß der Druck der Fluidströmung und damit der Fluiddurchsatz pro Zeiteinheit bei einem gleichbleibenden Verwirbelungsgrad noch weiter reduziert werden kann. Bei vergleichenden Messungen konnte festgestellt werden, daß bei einem derartigen Verfahren im Vergleich zu einem konventionellen Verfahren, bei dem keine kornartigen Partikel eingesetzt werden, der Verbrauch an Luft um etwa 40 % bis etwa 60 % gesenkt werden konnte.In a further, particularly advantageous embodiment of the method according to the invention for producing the core-sheath yarn described above, the yarn components of the starting material are fed to a nozzle and there through the turbulent fluid flow swirls, the fluid flow additionally having, for example, air and / or steam, also granular particles. This can be done in such a way that the fluid flow that is fed to the nozzle is either a mist consisting of finely divided water droplets with a diameter between approximately 40 μm and approximately 600 μm with granular particles dispersed or suspended therein, and / or one Dust of the granular particles alone is added, the granular particles having a grain size between approximately 4 μm and approximately 400 μm and in particular between 20 μm and 100 μm. Thus, in this embodiment of the method according to the invention, the granular particles are not supplied directly by the first yarn component, but rather by the fluid flows supplied to the nozzle, which leads to a further intensification of the intermingling of the yarns. As an explanation for this, it is assumed that in this embodiment of the method according to the invention, in comparison with the embodiments described above, in which the first yarn component is wetted with the particle-containing dispersion or suspension, the particles adhering to the yarn during the air or steam flow during the relatively short stay of the yarn in the nozzle does not have to be accelerated there, but instead granular particles are already supplied to the nozzle as accelerated particles. This in turn means that the pressure of the fluid flow and thus the fluid throughput per unit time can be reduced even further with a constant degree of swirling. In comparative measurements, it was found that in the case of such a method, in comparison with a conventional method in which no granular particles are used, the consumption of air could be reduced by about 40% to about 60%.
Bei einer bevorzugten Ausführungsform des zuvor beschriebenen Verfahrens führt man der Fluidströmung einen Nebel zu, der aus einer wäßrigen Dispersion bzw. Suspension der kornartigen Partikel hergestellt ist, wobei die Konzentration der kornartigen Partikel zwischen etwa 30 g/l und etwa 300 g/l, vorzugsweise zwischen etwa 60 g/l und etwa 200 g/l, beträgt. Bezüglich der Teilchengröße und der Härte der Partikel gilt das gleiche, wie dies vorstehend für die Ausführungsform des erfindungsgemäßen Verfahrens beschrieben ist, bei der die erste Garnkomponente mit der wäßrigen Dispersion bzw. Suspension benetzt wird.In a preferred embodiment of the method described above, the fluid flow is supplied with a mist which is produced from an aqueous dispersion or suspension of the granular particles, the concentration of the granular particles preferably being between approximately 30 g / l and approximately 300 g / l between about 60 g / l and about 200 g / l. With regard to the particle size and the hardness of the particles, the same applies as described above for the embodiment of the method according to the invention, in which the first yarn component is wetted with the aqueous dispersion or suspension.
Im Vergleich zu der Zuführung eines Staubes zu der Fluidströmung weist die Zuführung eines Nebels, in dem die Teilchen dispergiert bzw. suspendiert sind, den Vorteil auf, daß die mechanische Beanspruchung des Garnes und der Düse durch die vom Wasser hervorgerufene Schmier- bzw. Gleitwirkung reduziert ist, so daß die Zuführung eines Staubes zur Fluidströmung bevorzugt bei Verwendung von besonders weichen Partikeln, beim Einsatz von speziellen Düsen, die noch nachfolgend beschrieben werden, und/oder bei relativ grobtitrigen Garnen angewendet wird.Compared to the supply of a dust to the fluid flow, the supply of a mist in which the particles are dispersed or suspended has the advantage that the mechanical stress on the yarn and the nozzle is reduced by the lubricating or sliding action caused by the water is, so that the supply of a dust to the fluid flow is preferably used when using particularly soft particles, when using special nozzles, which will be described below, and / or with relatively coarse-titer yarns.
Üblicherweise führt man dem Fluidstrom zwischen etwa 0,1 m³/h und etwa 5 m³/h, insbesondere zwischen etwa 0,5 m³/h und etwa 2 m³/h, Nebel bzw. Staub der zuvor beschriebenen Zusammensetzung zu, wobei bei einem derartigen Verfahren der Fluiddurchsatz (Luft oder Dampf) in einem Bereich zwischen etwa 4 m³/h und etwa 15 m³/h, vorzugsweise zwischen etwa 5 m³/h und etwa 8 m³/h, beträgt.Usually, the fluid flow between about 0.1 m³ / h and about 5 m³ / h, in particular between about 0.5 m³ / h and about 2 m³ / h, fog or dust of the composition described above, with such Processes of fluid flow (air or steam) in a range between about 4 m³ / h and about 15 m³ / h, preferably between about 5 m³ / h and about 8 m³ / h.
Selbstverständlich ist es bei Zuführung eines Nebels, in dem die kornartigen Partikel suspendiert bzw. dispergiert sind, zum Fluidstrom auch möglich, zusätzlich noch Tenside und/oder Dispersions- bzw. Suspensionsmittel einzusetzen, wobei die Tenside bzw. Dispersions-bzw. Suspensionsmittel bevorzugt den vorstehend beschriebenen chemischen Aufbau besitzen.Of course, if a mist in which the granular particles are suspended or dispersed is fed to the fluid flow, it is also possible to add surfactants and / or To use dispersing or suspending agents, the surfactants or dispersing or. Suspension agents preferably have the chemical structure described above.
Die zur Durchführung der erfindungsgemaßen Verfahren eingesetzte Düse weist mindestens eine erste Einlaßöffnung für das Garn, eine zweite Einlaßöffnung für die Fluidströmung, eine Auslaßöffnung für das verwirbelte Garn und eine Wirbelkammer auf, wobei mindestens die Innenwände der Wirbelkammer sowie die Innenwände der Auslaßöffnung aus Keramik angefertigt sind.The nozzle used to carry out the method according to the invention has at least a first inlet opening for the yarn, a second inlet opening for the fluid flow, an outlet opening for the swirled yarn and a swirl chamber, at least the inner walls of the swirl chamber and the inner walls of the outlet opening being made of ceramic .
Wie festgestellt worden ist, weist gerade Keramik nicht nur die erforderliche Härte und Resistenz gegenüber der in der Wirbelungskammer und der Auslaßöffnung auftreffenden Partikelströmung auf, sondern bewirkt gleichzeitig wegen seiner geschlossenen Oberfläche ein konstantes Strömungsprofil in der Düse, was zu einem besonders reproduzierbaren Garn führt. Selbstverständlich ist es möglich, auch die Düse insgesamt aus Keramik anzufertigen, was die Herstellung einer derartigen Düse Vereinfacht oder die entsprechenden Düsenteile mit einer Keramikoberfläche zu versehen.As has been found, ceramic in particular not only has the required hardness and resistance to the particle flow impinging in the swirl chamber and the outlet opening, but at the same time brings about a constant flow profile in the nozzle due to its closed surface, which leads to a particularly reproducible yarn. Of course, it is also possible to manufacture the nozzle as a whole from ceramic, which simplifies the manufacture of such a nozzle or to provide the corresponding nozzle parts with a ceramic surface.
Bei den zuvor beschriebenen Verfahren zur Herstellung des erfindungsgemäßen Nähgarn ist unter anderem beschrieben, daß die wäßrige Dispersion bzw. Suspension der kornartigen Partikel durch Besprühen des Garnes mit der Dispersion bzw. Suspension oder durch Eintauchen des Garnes in die Dispersion bzw. Suspension appliziert werden kann. Selbstverständlich ist es auch möglich, zur Applikation der wäßrigen Dispersion bzw. Suspension eine spezielle Benetzungsvorrichtung zu verwenden, über die das Garn geführt wird. Hierbei besitzt diese Benetzungsvorrichtung einen Benetzungskopf, der in Kontakt mit dem Garn bringbar ist und über den die Dispersion bzw. Suspension der kornartigen Partikel in einer Art Pflatschtechnik auf das Garn aufgebracht wird. Derartige Benetzungsvorrichtungen sind bekannt und werden vielfach verwendet und beispielsweise von der Firma Heberlein unter der Systembezeichnung "HEMA-WET-DÜSE" angeboten.In the previously described methods for producing the sewing thread according to the invention, it is described, inter alia, that the aqueous dispersion or suspension of the granular particles can be applied by spraying the thread with the dispersion or suspension or by immersing the thread in the dispersion or suspension. Of course, it is also possible to use a special wetting device for applying the aqueous dispersion or suspension, through which the yarn is passed. In this case, this wetting device has a wetting head which can be brought into contact with the yarn and via which the dispersion or suspension of the granular particles is applied to the yarn in a kind of popping technique. Such wetting devices are known and are widely used and are offered, for example, by the Heberlein company under the system name "HEMA-WET-DÜSE".
Vorteilhafte Weiterbildungen des erfindungsgemäßen Garnes sowie der erfindungsgemäßen Verfahren sind in den Unteransprüchen angegeben.Advantageous developments of the yarn according to the invention and of the method according to the invention are specified in the subclaims.
Die Erfindung wird nachfolgend anhand einer Ausführungsform in Verbindung mit der Zeichnung erläutert. Hierbei zeigt die einzige Figur der Zeichnung schematisch das erfindungsgemäße Garn.The invention is explained below using an embodiment in conjunction with the drawing. The single figure of the drawing shows schematically the yarn according to the invention.
In der Figur ist ein insgesamt mit 1 bezeichnetes Garn abgebildet, das aus einer Vielzahl von miteinander verwirbelten Einzelkapillaren 2 besteht. Hierbei sind die Einzelkapillaren entweder knotenartig miteinander verwirbelt, wie dies an der mit 3 bezeichneten Stelle zu entnehmen ist. Ebenso weist das Garn abstehende Schlaufen 4 sowie verwirrte Bereiche 5 auf. In den Zwischenräumen zwischen den Einzelkapillaren 2 sind kornartige Partikel 6 angeordnet, die relativ zu den Einzelkapillaren in einem gewissen Bereich frei beweglich sind. Außen am Garn haften Partikel 7, die ebenfalls wie die Partikel 6 relativ zu den Einzelkapillaren 2 bzw. zu dem Garn 1 insgesamt in einem gewissen Rahmen bewegbar sind. Bei den in der Figur gezeigten Partikeln 6 und 7 handelt es sich um Titandioxid-Partikel mit einer Korngröße von 60 µm . Ihre Konzentration beträgt 0,2 Gew. %, bezogen auf das Garngewicht.Shown in the figure is a yarn denoted overall by 1, which consists of a plurality of
Ein Nähgarn mit einem Titer von 285 dtex wird durch Verwirbelung einer ersten, als Seele dienenden Garnkomponente hergestellt, bei der es sich um ein Polyester-Multifilamentgarn mit einem Titer von 180 dtex und einer Elementarfadenzahl von 40 Filamenten handelte. Die erste Garnkomponente wurde mit einer zweiten Komponente (Effekt- oder Mantelkomponente) verwirbelt, wobei der Titer der zweiten Garnkomponente 50 dtex bei einer Filamentzahl von 24 Filamenten betrug. Als Düse wurde eine konventionell ausgebildete, im Handel befindliche Düse verwendet, die die Typenbezeichnung T341 trug und von der Firma Heberlein angeboten wird.A sewing thread with a titer of 285 dtex is produced by interlacing a first thread component serving as a soul, which was a polyester multifilament thread with a titer of 180 dtex and an elementary thread count of 40 filaments. The first yarn component was interlaced with a second component (effect or sheath component), the titer of the second yarn component being 50 dtex with a number of filaments of 24 filaments. A conventionally designed, commercially available nozzle was used as the nozzle, which bore the type designation T341 and is offered by the Heberlein company.
Als Fluidstrom wurde Luft der Düse bei einem Druck von 10,5 bar zugeführt, wobei der Luftdurchsatz 8 m³/h betrug. Nach dem Verwirbeln wurde das Garn mit einer Geschwindigkeit von 500 m/min abgezogen.Air was fed to the nozzle as a fluid stream at a pressure of 10.5 bar, the air throughput being 8
Die erste Garnkomponente des Nähgarnes wurde vor der Verwirbelung durch Eintauchen in Wasser genetzt, wobei der Tauchweg etwa 2 cm betrug.The first thread component of the sewing thread was wetted before immersion by immersing it in water, the immersion distance being about 2 cm.
Nach dem Verwirbeln wurde das konventionell hergestellte und mit Nähgarn Nr. 1 bezeichnete Garn nach den bekannten Verfahren gefärbt und aviviert und diente für die nachfolgenden mechanisch-technologischen Messungen sowie bei industriellen Nähversuchen als Referenzmaterial.After the intermingling, the conventionally produced and designated sewing thread No. 1 was dyed and finished according to the known methods and served as a reference material for the subsequent mechanical-technological measurements and for industrial sewing tests.
Ein Nähgarn Nr. 2 wurde unter den zuvor beschriebenen Bedingungen hergestellt, wobei das Nähgarn Nr. 2 vor der Verwirbelung mit einer wäßrigen Suspension von 30 g/l Bariumsulfat behandelt wurde. Hierbei wies das Bariumsulfat eine Teilchengröße von 80 µm auf. Ansonsten entsprachen die Herstellungsbedingungen dem Ausführungsbeispiel 1.A No. 2 sewing thread was prepared under the conditions described above, the No. 2 sewing thread being treated with an aqueous suspension of 30 g / l barium sulfate before intermingling. The barium sulfate had a particle size of 80 μm. Otherwise, the manufacturing conditions corresponded to
Ein Nähgarn Hr. 3 wurde gemäß dem Ausführungsbeispiel 1 hergestellt, wobei jedoch abweichend hiervon die erste Garnkomponente vor dem Verwirbeln mit einer Dispersion von 60 g/l Titandioxid einer Teilchengröße von 20 µm benetzt wurde.A sewing thread Mr. 3 was produced in accordance with working example 1, however, in deviation from this, the first yarn component was wetted with a dispersion of 60 g / l titanium dioxide with a particle size of 20 μm prior to intermingling.
Bei den Ausführungsbeispielen 2 und 3 wurde ein Verbrauch von 22 l/h an wäßriger Dispersion festgestellt.In Examples 2 and 3, a consumption of 22 l / h of aqueous dispersion was found.
Ein Nähgarn Nr. 4 wurde unter den in Ausführungsbeispiel 1 geschilderten Bedingungen hergestellt, wobei jedoch abweichend hiervon die erste Garnkomponente vor dem Verwirbeln nicht mit Wasser benetzt wurde. Statt dessen wurden dem Luftstrom 15 Vol. % eines Nebels zugesetzt, der aus einer wäßrigen Dispersion von 100 g/l Bariumsulfat hergestellt wurde.A sewing thread No. 4 was produced under the conditions described in
Die zuvor beschriebenen Nähgarne 1 bis 4 wurden zunächst mikroskopisch untersucht. Hierbei stellte man fest, daß der Verwirbelungsgrad der Nähgarne vom Nähgarn Nr. 1 zum Nähgarn Nr. 4 stetig zunahm.The
Vergleichende industrielle Nähversuche ergaben, daß die Garnbruchhäufigkeit beim Nähen der Garne 2 bis 4 im Vergleich zum Garn 1 (konventionell hergestelltes Garn) deutlich geringer war. Eine orientierende, statistische Auswertung der Garnbruchhäufigkeit ergab, daß bezogen auf das Nähgarn Hr. 1 die Garnbruchhäufigkeit beim Nähgarn Nr. 2 20 %, die Garnbruchhäufigkeit beim Nähgarn Nr. 3 30 % und die Garnbruchhäufigkeit beim Nähgarn Nr. 4 um 50 % geringer war.Comparative industrial sewing tests showed that the yarn break frequency when
Gleichzeitig wurde auf einem speziell dafür entwickelten Meßapparat die Garnbruchhäufigkeit bei der Reibung Nähgarn gegen Nähgarn ermittelt. Hierzu wurde ein Ende des Nähgarnes in eine Klemme eingeklemmt, dann das Nähgarn in eine Schlaufe gelegt, wobei die Schlaufe über bewegliche Rollen offengehalten wurde und anschließend das Garn unter einer Belastung von 50 g derart bewegt, daß an der Schlaufe eine punktförmige Scheuerung Garn auf Garn auftrat. Die Scheuerversuche wurden bis zum Bruch des Garnes durchgeführt, wobei die Anzahl der Bewegungszyklen bis zum Bruch gemessen wurde.At the same time, the frequency of yarn breakage when rubbing sewing thread against sewing thread was determined on a specially developed measuring device. For this purpose, one end of the sewing thread was clamped in a clamp, then the sewing thread was placed in a loop, the loop over movable rollers was kept open and then the yarn was moved under a load of 50 g in such a way that a point-like abrasion of yarn on yarn occurred at the loop. The scouring tests were carried out until the yarn broke, the number of movement cycles until the break being measured.
Das konventionell hergestellte Nähgarn 1 brach nach 200 Bewegungszyklen. Das Nähgarn 2 brach bei 450 Bewegungszyklen, während beim Nähgarn 3 600 Bewegungszyklen und beim Nähgarn 4 750 Bewegungszyklen bis zum Bruch erforderlich waren.The conventionally produced
Claims (25)
- A yarn, in particular sewing thread , with at least one core yarn component and at least one second yarn component intermingled with the first yarn component, said second yarn component being mainly present as the jacket of said yarn,
wherein the yarn (1) comprises between about 0,02 % by weight and about 20 % by weight of granular particles (6,7), which are arranged in the yarn gaps and/or at the outside of the yarn (1), and said granular particles (6,7) possess a granule diameter between about 4 µm and about 400 µm. - The yarn according to claim 1, wherein said yarn comprises about 0,2 % by weight to about 0,4 % by weight granular particles (6,7).
- The yarn, according to claim 1 or 2, wherein the granular particles (6,7) possess a granule diameter between about 20 µm and about 100 µm.
- The yarn, according to one of the preceding claims, wherein the granular particles (6,7) are embedded in the yarn gaps and are spread homogeneously over the cross section of the yarn.
- The yarn according to one of the preceding claims, wherein the granular particles are embedded in a spin finish or a preparation.
- The yarn according to one of the preceding claims, wherein the first yarn component is a multifilament yarn and the second yarn component is one multifilament yarn or several multifilament yarns, in particular two to four multifilament yarns.
- The yarn according to one of the preceding claims, wherein the first yarn component is a multifilament yarn with a titre between about 100 dtex and about 1000 dtex, preferably between about 100 dtex and about 600 dtex.
- The yarn according to one of the preceding claims, wherein said yarn comprises a number of elementary filaments between about 40 and about 500, preferably between about 50 and 150.
- The yarn according to one of the preceding claims wherein said yarn contains inorganic granular particles (6,7), in particular talcum, silicon dioxide, aluminium oxide, titanium dioxide and/or barium sulphate,
- The yarn according to one of the preceding claims wherein said yarn provides a twist between about 1 twist /m and about 1000 twists /m, in particular between about 100 twists /m and about 600 twists /m.
- A method for manufacturing the yarn according to one of the preceding claims wherein at least one first core yarn component is intermingled with at least one second yarn component, which is intended as a jacket, in a turbulent fluid stream, said first yarn component being wetted with water before being intermingled, wherein said yarn is a sewing thread and said first yarn component is wetted with an aqueous dispersion or suspension of granular particles, the specific weight of which is larger than 1 g/cm³ and the granule diameter of which is between about 4 µm and about 400 µm, in particular between about 20 µm and about 100 µm.
- The method according to claim 11, wherein the first yarn component is wetted by dipping into the aqueous dispersion or suspension.
- The method according to one of the claims 11 or 12, wherein an aqueous dispersion or suspension is used, which contains the granular particles in a concentration between about 5 g/l and about 150 g/l, preferably between about 30 g/l and about 60 g/l.
- The method according to claim 11, wherein the first yarn component is sprinkled with the aqueous dispersion or suspension of the granular particles.
- The method according to claim 14, wherein an aqueous dispersion or suspension is used, which contains the granular particles in a concentration between about 10 g/l and about 200 g/l, preferably between about 50 g/l and about 150 g/l.
- The method according to claim 14 or 15, wherein between about 1 % by weight and about 50 % by weight, preferably between about 5 % by weight and about 30 % by weight of the aqueous dispersion or suspension is sprinkled onto the first yarn component.
- The method according to one of the claims 11 to 16, wherein a turbulent stream is generated in the aqueous dispersion or suspension .
- the method according to one of the claims 11 to 17, wherein surfactants and/or dispersing agents are added to the aqueous dispersion or suspension.
- The method for manufacturing the yarn according to one of the claims 1 to 10, in which one first core yarn component is intermingled with a second yarn component intended as a jacket in a turbulent fluid stream, wherein said yarn is a sewing thread, and a mist, comprising water droplets with a diameter of between about 40 µm and about 600 µm and granular particles, and/or a dust of granular particles, is supplied to the fluid stream, said granular particles showing a specific weight greater than 1 g/cm³ and a granule diameter between about 4 µm and about 400 µm in particular between about 20 µm and about 100 µm.
- The method according to one of the claims 11 to 19, wherein the granular particles provide a hardness according to Mohs between 1 and 6 1/2, preferably between 3 and 5.
- The method according to one of the claims 11 to 20, wherein the granular particles possess a density between 1,5 g/cm³ and 6 g/cm³, preferably between about 3 g/cm³ and about 5 g/cm³.
- The method according to one of the claims 11 to 21, wherein the yarn components are intermingled with another at an air pressure between about 6 bar and about 15 bar, preferably between about 8 bar and about 10 bar.
- The method according to claim 19, wherein a mist is supplied to the fluid stream, which mist is generated from an aqueous dispersion or suspension of the granular particles, said granular particles being present at a concentration of between about 30 g/l and about 300 g/l, in particular between about 60 g/l and about 200 g/l.
- The method according to claim 19 or 23, wherein the mist is added to the fluid stream at between about 0,1 m³/h, in particular between about 0,5 m³/h and about 2 m³/h.
- The method according to claim 19, wherein a dust is supplied to the fluid stream between about 0,1 volume % and about 15 volume %, in particular between about 0,2 volume % and about 1 volume %.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3816318 | 1988-05-13 | ||
DE3816318A DE3816318C1 (en) | 1988-05-13 | 1988-05-13 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0341420A2 EP0341420A2 (en) | 1989-11-15 |
EP0341420A3 EP0341420A3 (en) | 1990-12-27 |
EP0341420B1 true EP0341420B1 (en) | 1994-06-01 |
Family
ID=6354287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89106097A Expired - Lifetime EP0341420B1 (en) | 1988-05-13 | 1989-04-07 | Yarn and method for making it |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0341420B1 (en) |
AT (1) | ATE106463T1 (en) |
DE (2) | DE3816318C1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102013100613A1 (en) * | 2013-01-22 | 2014-07-24 | Boockmann Gmbh | Textile material strand and method for its production |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1373388A (en) * | 1970-12-24 | 1974-11-13 | Teijin Ltd | Thermoplastic polymer fibres |
DE2140517A1 (en) * | 1971-08-12 | 1973-04-12 | Zwirnerei & Naehfadenfab | Sewing thread - to join textile piece goods with magnetic components carried in the dye pigment |
US3823449A (en) * | 1971-12-27 | 1974-07-16 | Akzona Inc | Apparatus for interlacing yarns |
DE3048650C2 (en) * | 1980-12-23 | 1987-01-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München | Process for preparing sewing threads from synthetic fibres |
DE3202555A1 (en) * | 1982-01-27 | 1983-08-04 | Juan San Cristobal s/n Artes Barcelona Vilanova Grau | Process for producing radiopaque filament material |
DE3341995A1 (en) * | 1982-11-24 | 1984-05-24 | Hasso von 4000 Düsseldorf Blücher | Yarn having specific properties |
ATE28909T1 (en) * | 1983-07-04 | 1987-08-15 | Akzo Nv | POLYAMIDE AROMATIC YARN IMPREGNATED WITH LUBRICANT PARTICLES, PROCESS OF MAKING SUCH YARN AND SEALING MATERIAL OR ROPE CONTAINING THE SAME. |
DE3712863A1 (en) * | 1986-04-16 | 1987-11-26 | Ackermann Goeggingen Ag | Sewing thread |
DE3720237A1 (en) * | 1987-06-15 | 1989-01-05 | Amann & Soehne | METHOD FOR PRODUCING AIR BLOW TEXTURED SEWING THREAD |
-
1988
- 1988-05-13 DE DE3816318A patent/DE3816318C1/de not_active Expired
-
1989
- 1989-04-07 AT AT89106097T patent/ATE106463T1/en not_active IP Right Cessation
- 1989-04-07 EP EP89106097A patent/EP0341420B1/en not_active Expired - Lifetime
- 1989-04-07 DE DE58907737T patent/DE58907737D1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0341420A3 (en) | 1990-12-27 |
DE3816318C1 (en) | 1989-11-30 |
EP0341420A2 (en) | 1989-11-15 |
DE58907737D1 (en) | 1994-07-07 |
ATE106463T1 (en) | 1994-06-15 |
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