EP0242253B1 - Disposable dispenser pump for liquid and pasty products - Google Patents
Disposable dispenser pump for liquid and pasty products Download PDFInfo
- Publication number
- EP0242253B1 EP0242253B1 EP87400613A EP87400613A EP0242253B1 EP 0242253 B1 EP0242253 B1 EP 0242253B1 EP 87400613 A EP87400613 A EP 87400613A EP 87400613 A EP87400613 A EP 87400613A EP 0242253 B1 EP0242253 B1 EP 0242253B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- skirt
- product
- liquid
- nozzle
- tubular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 title claims description 9
- 235000011837 pasties Nutrition 0.000 title description 2
- 239000000047 product Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 8
- 238000007789 sealing Methods 0.000 claims description 5
- 239000012263 liquid product Substances 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 238000004500 asepsis Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 208000031968 Cadaver Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K5/00—Holders or dispensers for soap, toothpaste, or the like
- A47K5/06—Dispensers for soap
- A47K5/12—Dispensers for soap for liquid or pasty soap
- A47K5/1202—Dispensers for soap for liquid or pasty soap dispensing dosed volume
- A47K5/1208—Dispensers for soap for liquid or pasty soap dispensing dosed volume by means of a flexible dispensing chamber
- A47K5/1209—Dispensers for soap for liquid or pasty soap dispensing dosed volume by means of a flexible dispensing chamber with chamber in the form of a cylindrical tube
Definitions
- the present invention aims to achieve a simple and inexpensive dispensing pump, the discharge valve is nevertheless designed so as to obtain a perfect seal both in the waiting position and after completion of an operation of distribution.
- the design of this pump is such that it can be produced in a disposable form, so that it can be manufactured at the same time as the cartridge of the product to be dispensed in order to be disposed of at the same time as it.
- the invention relates to a dispensing pump intended to be placed under the lower flow opening of a container which contains a liquid product to be dispensed, comprising a tubular body of flexible material equipped at its lower part with a discharge valve and at its upper part of an intake valve being in the form of a tubular mouthpiece.
- flexible material the downstream end of which is flattened to define a transverse slot located between two lips which keep it elastically closed when the valve is at rest, while they move apart when a pressure gradient occurs within the liquid to be dispensed.
- This pump is characterized in that the discharge valve comprises on the one hand a nozzle provided, at mid-height, with a projecting annular lip and on the other hand a obturator tube comprising a deformable tubular skirt engaged inside this nozzle and pressing against the annular lip thereof in the sealing position, this skirt being closed at its upper part by a transverse bottom around which there are provided passages for the passage of the product to be expelled between the tubular skirt and the discharge nozzle, so that when the tubular body is crushed, the downward thrust of the liquid on the outside of the skirt pushes this skirt inward to move it away from the annular lip so as to leak towards the down a dose of product.
- the upper end of the deformable skirt of the discharge valve comprises an external collar in which are formed lights constituting passages for the product to be expelled, this collar being arranged in an annular internal housing of the external nozzle.
- the present pump can be incorporated into the lower opening of a rigid and deformable bottle with which it forms an assembly which is discarded after use.
- FIG. 1 There is shown in the drawings a container or cartridge 1 which contains the liquid 2 to be dispensed.
- This container has at its bottom an open flow ture 3 under which the distributor pump 4 according to the invention is adapted.
- the adaptation can be carried out by any known means, for example by welding, or by screwing, of a threaded sleeve 5 as was assumed in Figures 1 to 3.
- the pump 4 comprises a tubular body 6 terminated at its top by a flange 7 on which an intake valve 8 is supported, and at its lower part by a discharge nozzle 9.
- the nozzle 9 has an opening 10 for the ejection of a dose 11 of the product 2.
- annular internal housing 13 designed to receive the flange 14 fitted to the top of a shutter tube 15.
- the body 6 of the pump is made of a flexible molded material, which the user can crush between his fingers, as symbolized in FIG. 2 by the arrows 16.
- the obturator tube 15 provided with a flexible cylindrical skirt 17 closed at its top by a transverse bottom 18.
- a transverse bottom 18 Around the latter is arranged the flange 14 in which are cut lights 19 to let the product 2 freely circulate around the skirt 17.
- the obturator tube 15 is held in place by the flange 14 in the housing 13 ( Figure 3), while the skirt 17 is elastically tightened by the sealing lip 12 which surrounds it.
- the inlet valve 8 is made in one piece from a flexible molded material. It has the shape of an annular transverse flange 20 extended downwards by a tubular mouth 23, flattened at its downstream end where it defines a transverse slot 21. This slot is located between two flexible lips 22 which, when the valve 8 is closed, remain tightly pressed against each other ( Figures 2 and 5).
- the pump according to the invention can be manufactured for a very low cost price, so that it can be provided in disposable form.
- it is possible to integrate it into the cartridge 1 containing the product 2.
- the assembly can then be delivered in sterile form, then discarded after use. This is particularly suitable for medical and surgical applications.
- the pump 4 is permanently welded to the single lower opening 3 of a bottle 26.
- the latter has the distinction of being made of a plastic material that is both rigid and deformable.
- the bottle has a well defined initial shape, for example parallelepipedic (FIG. 8), which makes it possible to adapt it to a wall-mounted dispenser.
- FIG. 8 parallelepipedic
- the latter collapses on itself by deformation like another ( Figure 9). It is thus possible to discard the assembly 4 - 26 when the bottle 26 has been emptied.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Closures For Containers (AREA)
- Reciprocating Pumps (AREA)
Description
La présente invention est relative à une pompe distributrice d'un type nouveau, du genre de celles qu'on utilise pour distribuer des produits liquides qui peuvent être très fluides (alcool), crémeux, ou plus ou moins visqueux (savon liquide, crème à raser, etc.).The present invention relates to a dispensing pump of a new type, of the kind used for dispensing liquid products which can be very fluid (alcohol), creamy, or more or less viscous (liquid soap, cream shave, etc.).
On connait des pompes distributrices de ce genre, mais toutes présentent divers inconvénients.Distributor pumps of this kind are known, but all have various drawbacks.
Tout d'abord leur structure souvent complexe conduit à un prix de revient important. Ces pompes doivent donc pouvoir être réutilisées avec plusieurs recharges successives du produit à distribuer. Cela pose des problèmes d'asepsie lorsqu'on souhaite les utiliser par exemple au bloc opératoire dans un hôpital.First of all, their often complex structure leads to a significant cost price. These pumps must therefore be able to be reused with several successive refills of the product to be dispensed. This poses aseptic problems when you want to use them, for example in the operating room in a hospital.
De plus, la plupart des pompes connues laissent remonter l'air extérieur dans le produit après chaque utilisation. Il en résulte qu'elles ont tendance à se boucher par dessication du produit. Par ailleurs les rentrées d'air posent à nouveau un problème d'asepsie pour les utilisations médicales.In addition, most of the known pumps allow the outside air to rise in the product after each use. As a result, they tend to become clogged by drying the product. In addition, the air intake again poses a problem of asepsis for medical uses.
Le brevet US 2 772 817 représente, à la figure 3 des dessins annexés, un dispositif de pompe constitué par un corps creux déformable destiné à recevoir une certaine quantité du produit à distribuer, et qui est équipé d'un clapet d'admission à sa partie supérieure et d'un clapet de refoulement à sa partie inférieure. Ces clapets consistent l'un et l'autre en une embouchure tubulaire en matière souple dont l'extrémité aval est aplatie pour définir une fente transversale. Ainsi les lèvres de chacune de ces fentes maintiennent la fente correspondante élastiquement fermée lorsque le clapet considéré est au repos, tout en permettant un passage de produit lors de l'apparition d'un gradient de pression en amont.US Patent 2,772,817 shows, in Figure 3 of the accompanying drawings, a pump device consisting of a deformable hollow body intended to receive a certain amount of the product to be dispensed, and which is equipped with an inlet valve to its upper part and a discharge valve at its lower part. These valves each consist of a tubular mouthpiece of flexible material whose downstream end is flattened to define a transverse slot. Thus, the lips of each of these slots maintain the corresponding slot elastically closed when the valve considered is at rest, while allowing product to pass when the pressure gradient appears upstream.
Une telle solution pour la réalisation d'un clapet est tout à fait appropriée en ce qui concerne le clapet d'admission, qui n'a pas besoin de comporter une étanchéité absolue. Par contre il n'en est pas de même pour le clapet de refoulement car ce dernier doit présenter une étanchéité parfaite. En effet lorsque le dispositif est en position d'attente, il est absolument nécessaire d'éviter tout risque de fuite du produit pâteux se trouvant à l'intérieur du corps creux déformable. Par ailleurs à la fin d'une opération d'expulsion d'une dose déterminée de ce produit, il est indispensable d'obtenir immédiatement une étanchéité parfaite pour éviter une entrée d'air à l'intérieur du corps creux déformable et les inconvénients qui en résultent. Or un clapet de refoulement du type de celui prévu dans le brevet US en cause ne peut pas donner satisfaction à ce sujet.Such a solution for the production of a valve is entirely appropriate with regard to the intake valve, which does not need to include an absolute seal. By cons it is not the same for the discharge valve because the latter must have a perfect seal. Indeed, when the device is in the waiting position, it is absolutely necessary to avoid any risk of leakage of the pasty product located inside the deformable hollow body. Furthermore, at the end of an operation for expelling a determined dose of this product, it is essential to immediately obtain a perfect seal in order to avoid an entry of air inside the deformable hollow body and the drawbacks which result. However, a discharge valve of the type provided for in the US patent in question cannot be satisfactory on this subject.
C'est pourquoi la présente invention a pour but de réaliser une pompe distributrice simple et peu coûteuse, dont le clapet de refoulement est néanmoins conçu de façon à obtenir une parfaite étanchéité aussi bien en position d'attente qu'après achèvement d'une opération de distribution. De plus la conception de cette pompe est telle que celle-ci puisse être réalisée sous forme jetable, de façon à pouvoir être fabriquée en même temps que la cartouche du produit à distribuer pour être jetée en même temps qu'elle.This is why the present invention aims to achieve a simple and inexpensive dispensing pump, the discharge valve is nevertheless designed so as to obtain a perfect seal both in the waiting position and after completion of an operation of distribution. In addition, the design of this pump is such that it can be produced in a disposable form, so that it can be manufactured at the same time as the cartridge of the product to be dispensed in order to be disposed of at the same time as it.
A cet effet l'invention a pour objet une pompe distributrice destinée à être placée sous l'ouverture inférieure d'écoulement d'un recipient qui contient un produit liquide à distribuer, comprenant un corps tubulaire en matière souple équipé à sa partie inférieure d'un clapet de refoulement et à sa partie supérieure d'un clapet d'admission se présentant sous la forme d'une embouchure tubulaire en. matière souple dont l'extrémité aval est aplatie pour définir une fente transversale située entre deux lèvres qui la maintiennent élastiquement fermée lorsque le clapet est au repos, alors qu'elles s'écartent à l'apparition d'un gradient de pression au sein du liquide à distribuer. Cette pompe est caractérisée en ce que le clapet de refoulement comprend d'une part une buse pourvue, à mi-hauteur, d'une lèvre annulaire saillante et d'autre part un tube obturateur comportant une jupe tubulaire déformable engagée à l'intérieur de cette buse et s'appliquant contre la lèvre annulaire de celle-ci en position d'étanchéité, cette jupe étant fermée à sa partie supérieure par un fond transversal autour duquel il est prévu des passages pour le passage du produit à expulser entre la jupe tubulaire et la buse de refoulement, de sorte que lorsqu'on écrase le corps tubulaire, la poussée descendante du liquide sur l'extérieur de la jupe repousse cette jupe vers l'intérieur pour l'écarter de la lèvre annulaire afin de laisser fuir vers le bas une dose de produit.To this end the invention relates to a dispensing pump intended to be placed under the lower flow opening of a container which contains a liquid product to be dispensed, comprising a tubular body of flexible material equipped at its lower part with a discharge valve and at its upper part of an intake valve being in the form of a tubular mouthpiece. flexible material, the downstream end of which is flattened to define a transverse slot located between two lips which keep it elastically closed when the valve is at rest, while they move apart when a pressure gradient occurs within the liquid to be dispensed. This pump is characterized in that the discharge valve comprises on the one hand a nozzle provided, at mid-height, with a projecting annular lip and on the other hand a obturator tube comprising a deformable tubular skirt engaged inside this nozzle and pressing against the annular lip thereof in the sealing position, this skirt being closed at its upper part by a transverse bottom around which there are provided passages for the passage of the product to be expelled between the tubular skirt and the discharge nozzle, so that when the tubular body is crushed, the downward thrust of the liquid on the outside of the skirt pushes this skirt inward to move it away from the annular lip so as to leak towards the down a dose of product.
Selon une autre caractéristique de la présente pompe, l'extrémité supérieure de la jupe déformable du clapet de refoulement comporte une collerette externe dans laquelle sont ménagées des lumières constituant des passages pour le produit à expulser, cette collerette étant disposée dans uns logement interne annulaire de la buse externe.According to another characteristic of the present pump, the upper end of the deformable skirt of the discharge valve comprises an external collar in which are formed lights constituting passages for the product to be expelled, this collar being arranged in an annular internal housing of the external nozzle.
Selon une autre caractéristique de la présente pompe, celle-ci peut être incorporée à l'ouverture inférieure d'un flacon rigide et déformable avec lequel elle forme un ensemble qu'on jette après usage.According to another characteristic of the present pump, it can be incorporated into the lower opening of a rigid and deformable bottle with which it forms an assembly which is discarded after use.
Le dessin annexé, donné à titre d'exemple non limitatif, permettra de mieux comprendre les caractéristiques de l'invention.
- - la figure 1 est une coupe longitudinale d'une pompe distributrice selon l'invention lorsqu'elle est au repos,
- - les figures 2 et 3 illustrent deux phases de son fonctionnement,
- - la figure 4 montre l'utilisation d'un distributeur mural équipé de la pompe selon l'invention,
- - les figures 5 et 6 sont des vues en perspective montrant le clapet d'admission, respectivement fermé, puis ouvert,
- - la figure 7 montre le tube obturateur qui constitue le clapet de refoulement,
- - les figures 8 et 9 montrent une variante où la pompe forme avec son flacon rigide déformable, un ensemble unique et jetable après usage.
- FIG. 1 is a longitudinal section of a dispensing pump according to the invention when it is at rest,
- - Figures 2 and 3 illustrate two phases of its operation,
- FIG. 4 shows the use of a wall-mounted distributor equipped with the pump according to the invention,
- FIGS. 5 and 6 are perspective views showing the inlet valve, respectively closed, then open,
- FIG. 7 shows the obturator tube which constitutes the discharge valve,
- - Figures 8 and 9 show a variant where the pump forms with its rigid deformable bottle, a single set and disposable after use.
On a représenté sur les dessins un récipient ou cartouche 1 qui contient le liquide 2 à distribuer. Ce récipient possède à sa partie inférieure une ouverture d'écoulement 3 sous laquelle on adapte la pompe distributrice 4 selon l'invention. L'adaptation peut s'effectuer par tout moyen connu, par exemple par soudage, ou par vissage, d'un manchon fileté 5 comme on l'a supposé sur les Figures 1 à 3.There is shown in the drawings a container or cartridge 1 which contains the
La pompe 4 comprend un corps tubulaire 6 terminé, à son sommet, par une collerette 7 sur laquelle prend appui un clapet d'admission 8, et à sa partie inférieure par une buse de refoulement 9.The
A sa partie inférieure, la buse 9 possède une ouverture 10 pour l'éjection d'une dose 11 du produit 2.At its lower part, the
A mi-hauteur, elle est pourvue d'une lèvre annulaire 12 faisant saillie dans son espace intérieur.Halfway up, it is provided with an
A sa partie supérieure, elle possède un logement interne annulaire 13, prévu pour recevoir la collerette 14 équipant le sommet d'un tube obturateur 15.At its upper part, it has an annular
Le corps 6 de la pompe est réalisé en une matière moulée souple, que l'utilisateur peut écraser entre ses doigts, comme symbolisé en Figure 2 par les flèches 16.The
Le tube obturateur 15 pourvu d'une jupe cylindrique souple 17 fermée à son sommet par un fond transversal 18. Autour de celui-ci est disposée la collerette 14 dans laquelle sont découpées des lumières 19 pour laisser le produit 2 librement circuler autour de la jupe 17.The
Au repos, après montage, le tube obturateur 15 est maintenu en place par la collerette 14 dans le logement 13 (Figure 3), cependant que la jupe 17 est serrée élastiquement par la lèvre d'étanchéité 12 qui l'entoure.At rest, after assembly, the
Le clapet d'admission 8 est réalisé d'une pièce en une matière moulée souple. Il a la forme d'une collerette transversale annulaire 20 prolongée vers le bas par une embouchure tubulaire 23, aplatie à son extrémité aval où elle définit une fente transversale 21. Cette fente est située entre deux lèvres souples 22 qui, lorsque le clapet 8 est fermé, restent appliquées l'une contre l'autre de façon étanche (Figures 2 et 5).The
Lorsqu'au contraire un gradient de pression apparaît de l'amont vers l'aval au sein du produit 2, les lèvres 22 s'écartent et ouvrent la fente 21 qui laisse passer le produit 2 (Figures 3 et 6, flèche 24).When, on the contrary, a pressure gradient appears from upstream to downstream within the
Le fonctionnement est le suivant :
- Lorsque l'appareil 1,4 est au repos, les
clapets 8 et 9,15 sont tous deux fermés (Figure 1) et lapompe 4 est pleine duproduit 2 dans tout l'espace situé au-dessus de la lèvre d'étanchéité 12 de labuse 9. L'air ne peut donc pas pénétrer dans la pompe, ce qui garantit l'asepsie duproduit 2 et empêche son éventuelle dessication. - Lorsque l'utilisateur écrase la paroi tubulaire du corps 6 (Figure 2, flèche 16), le clapet d'admission 8 reste hermétiquement fermé sous la poussée ascendante qui tend à refermer encore davantage les
lèvres 22 l'une contre l'autre. Par contre, la poussée descendante exercée sur l'extérieur de lajupe 17 du tube obturateur 15 déforme vers l'intérieur cettejupe 17 qui s'écarte localement de la lèvre annulaire 12 et laisse fuir vers le bas ladose 11 deproduit 2.
- When the
device 1,4 is at rest, the 8 and 9,15 are both closed (Figure 1) and thevalves pump 4 is full of theproduct 2 in all the space located above thesealing lip 12 of thenozzle 9. The air cannot therefore enter the pump, which guarantees the asepsis of theproduct 2 and prevents its possible drying out. - When the user crushes the tubular wall of the body 6 (FIG. 2, arrow 16), the
intake valve 8 remains hermetically closed under the upward thrust which tends to close thelips 22 even more one against the other. On the other hand, the downward thrust exerted on the outside of theskirt 17 of theobturator tube 15 deforms inward thisskirt 17 which deviates locally from theannular lip 12 and lets thedose 11 ofproduct 2 leak downwards.
Quand l'utilisateur relâche la pompe 4 (Figure 3), son corps 6 revient élastiquement à sa position initiale (flèches 25), et la jupe 17 vient se refermer contre la lèvre d'étanchéité 12. Toute remontée d'air à travers la buse 9 se trouve ainsi empêchée.When the user releases the pump 4 (FIG. 3), his
Par contre, le gradient de pression apparaissant entre l'amont et l'aval du clapet d'admission 8 écarte les lèvres 22 (Figures 3 et 6) pour laisser le produit 2 du récipient 1 pénétrer dans le corps 6 de la pompe 4 (flèche 24) qui se trouve ainsi rechargée, prête à un nouvel emploi.On the other hand, the pressure gradient appearing between the upstream and downstream of the
On voit que la pompe selon l'invention peut être fabriquée pour un prix de revient très bas, si bien qu'on peut la prévoir sous forme jetable. En particulier, en fabrication, il est possible de l'intégrer à la cartouche 1 contenant le produit 2. L'ensemble peut alors être livré sous forme stérile, puis jeté après usage. Cela convient particulièrement bien pour les applications médicales et chirurgicales.It is seen that the pump according to the invention can be manufactured for a very low cost price, so that it can be provided in disposable form. In particular, during manufacturing, it is possible to integrate it into the cartridge 1 containing the
Dans la variante illustrée sur les Figures 8 et 9, la pompe 4 est soudée définitivement à l'unique ouverture inférieure 3 d'un flacon 26. Ce dernier présente la particularité d'être réalisé en une matière plastique à la fois rigide et déformable. Ainsi, lorsqu'il est neuf et rempli du liquide 2, le flacon a une forme initiale bien définie, par exemple paralléle- pipédique (Figure 8), qui permet de l'adapter sur un distributeur mural. Par contre, au fur et à mesure que le liquide 2 est soutiré sans que l'air ne pénètre dans le flacon 26, celui-ci s'affaisse sur lui même par déformation à la façon d'une autre (Figure 9). On peut ainsi jeter l'ensemble 4 - 26 quand le flacon 26 a été vidé.In the variant illustrated in Figures 8 and 9, the
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8605982 | 1986-04-16 | ||
FR8605982A FR2597551B1 (en) | 1986-04-16 | 1986-04-16 | DISPOSABLE DISPENSING PUMP FOR LIQUID OR PASTY PRODUCTS |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0242253A1 EP0242253A1 (en) | 1987-10-21 |
EP0242253B1 true EP0242253B1 (en) | 1989-06-28 |
Family
ID=9334599
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87400613A Expired EP0242253B1 (en) | 1986-04-16 | 1987-03-19 | Disposable dispenser pump for liquid and pasty products |
Country Status (7)
Country | Link |
---|---|
US (1) | US4776495A (en) |
EP (1) | EP0242253B1 (en) |
JP (1) | JPH0825569B2 (en) |
CA (1) | CA1274810A (en) |
DE (1) | DE3760269D1 (en) |
ES (1) | ES2010214B3 (en) |
FR (1) | FR2597551B1 (en) |
Families Citing this family (81)
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-
1986
- 1986-04-16 FR FR8605982A patent/FR2597551B1/en not_active Expired - Lifetime
- 1986-12-19 CA CA000525925A patent/CA1274810A/en not_active Expired - Lifetime
-
1987
- 1987-03-19 EP EP87400613A patent/EP0242253B1/en not_active Expired
- 1987-03-19 DE DE8787400613T patent/DE3760269D1/en not_active Expired
- 1987-03-19 ES ES87400613T patent/ES2010214B3/en not_active Expired
- 1987-04-01 US US07/032,688 patent/US4776495A/en not_active Expired - Lifetime
- 1987-04-15 JP JP62092938A patent/JPH0825569B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2010214B3 (en) | 1989-11-01 |
DE3760269D1 (en) | 1989-08-03 |
CA1274810A (en) | 1990-10-02 |
JPH0825569B2 (en) | 1996-03-13 |
JPS62260669A (en) | 1987-11-12 |
FR2597551B1 (en) | 1993-11-12 |
US4776495A (en) | 1988-10-11 |
EP0242253A1 (en) | 1987-10-21 |
FR2597551A1 (en) | 1987-10-23 |
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