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EP0017503A3 - Gem-bis (hydroxymethyl) alcohols and mixtures thereof with diols, process for their preparation involving the preparation of formyl alcohols, of hydroxymethyl formyl alcohols and of diols and a process for the preparation of polyurethanes therefrom - Google Patents

Gem-bis (hydroxymethyl) alcohols and mixtures thereof with diols, process for their preparation involving the preparation of formyl alcohols, of hydroxymethyl formyl alcohols and of diols and a process for the preparation of polyurethanes therefrom Download PDF

Info

Publication number
EP0017503A3
EP0017503A3 EP80301101A EP80301101A EP0017503A3 EP 0017503 A3 EP0017503 A3 EP 0017503A3 EP 80301101 A EP80301101 A EP 80301101A EP 80301101 A EP80301101 A EP 80301101A EP 0017503 A3 EP0017503 A3 EP 0017503A3
Authority
EP
European Patent Office
Prior art keywords
preparation
alcohols
diols
hydroxymethyl
formyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80301101A
Other versions
EP0017503A2 (en
EP0017503B1 (en
Inventor
Edgar R. Rogier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/026,858 external-priority patent/US4216343A/en
Priority claimed from US06/026,859 external-priority patent/US4216344A/en
Priority claimed from US06/081,951 external-priority patent/US4304945A/en
Application filed by Henkel Corp filed Critical Henkel Corp
Publication of EP0017503A2 publication Critical patent/EP0017503A2/en
Publication of EP0017503A3 publication Critical patent/EP0017503A3/en
Application granted granted Critical
Publication of EP0017503B1 publication Critical patent/EP0017503B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C08G18/3209—Aliphatic aldehyde condensates and hydrogenation products thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/22—Trihydroxylic alcohols, e.g. glycerol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75—Reactions with formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP19800301101 1979-04-04 1980-04-03 Gem-bis (hydroxymethyl) alcohols and mixtures thereof with diols, process for their preparation and a process for the preparation of polyurethanes therefrom Expired EP0017503B1 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US06/026,858 US4216343A (en) 1979-04-04 1979-04-04 High molecular weight polyhydric alcohols
US26858 1979-04-04
US06/026,859 US4216344A (en) 1979-04-04 1979-04-04 High molecular weight polyol mixtures
US26859 1979-04-04
US8195379A 1979-10-04 1979-10-04
US81951 1979-10-04
US06/081,951 US4304945A (en) 1979-04-04 1979-10-04 High molecular weight products
US81953 2008-07-18

Publications (3)

Publication Number Publication Date
EP0017503A2 EP0017503A2 (en) 1980-10-15
EP0017503A3 true EP0017503A3 (en) 1980-12-10
EP0017503B1 EP0017503B1 (en) 1982-12-29

Family

ID=27487533

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19800301101 Expired EP0017503B1 (en) 1979-04-04 1980-04-03 Gem-bis (hydroxymethyl) alcohols and mixtures thereof with diols, process for their preparation and a process for the preparation of polyurethanes therefrom

Country Status (3)

Country Link
EP (1) EP0017503B1 (en)
CA (1) CA1144573A (en)
DE (1) DE3061482D1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4246376A (en) * 1979-09-10 1981-01-20 Henkel Corporation Curing agents
ATE14212T1 (en) * 1981-04-27 1985-07-15 Henkel Corp POLYHYDRICAL ALCOHOLS.
EP0098335B1 (en) * 1982-06-18 1987-01-14 HENKEL CORPORATION (a Delaware corp.) Cycloaliphatic alcohols
DE19805421C1 (en) * 1998-02-11 1999-06-02 Basf Coatings Ag Scratch-resistant coating material with high reflow

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB808878A (en) * 1956-06-29 1959-02-11 Degussa Process for the production of methyl trimethylol methane
FR1335323A (en) * 1962-09-25 1963-08-16 Shell Int Research Process for preparing polyols
FR1377140A (en) * 1963-12-13 1964-10-31 Tosi Franco Ist Process for preparing 2-methyl-2-secondobutylpropanediol-1, 3
FR1447188A (en) * 1964-02-27 1966-07-29 Unilever Nv Process for preparing cosmetic compositions
FR2009683A1 (en) * 1968-05-30 1970-02-06 Bayer Ag
FR2069018A5 (en) * 1969-11-04 1971-09-03 Bayer Ag
FR2301505A1 (en) * 1975-02-21 1976-09-17 Basf Ag PROCESS FOR PREPARING 2,2-DIMETHYLOLALCANALS
FR2385751A1 (en) * 1977-03-28 1978-10-27 Ppg Industries Inc Polyurethane free from ether linkages - used for glazing or optical lenses, and hard, flexible and resist to weathering
EP0000912A1 (en) * 1977-08-26 1979-03-07 Bayer Ag Process for the preparation of low molecular polyhydroxy compounds

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB808878A (en) * 1956-06-29 1959-02-11 Degussa Process for the production of methyl trimethylol methane
FR1335323A (en) * 1962-09-25 1963-08-16 Shell Int Research Process for preparing polyols
FR1377140A (en) * 1963-12-13 1964-10-31 Tosi Franco Ist Process for preparing 2-methyl-2-secondobutylpropanediol-1, 3
FR1447188A (en) * 1964-02-27 1966-07-29 Unilever Nv Process for preparing cosmetic compositions
FR2009683A1 (en) * 1968-05-30 1970-02-06 Bayer Ag
FR2069018A5 (en) * 1969-11-04 1971-09-03 Bayer Ag
FR2301505A1 (en) * 1975-02-21 1976-09-17 Basf Ag PROCESS FOR PREPARING 2,2-DIMETHYLOLALCANALS
FR2385751A1 (en) * 1977-03-28 1978-10-27 Ppg Industries Inc Polyurethane free from ether linkages - used for glazing or optical lenses, and hard, flexible and resist to weathering
EP0000912A1 (en) * 1977-08-26 1979-03-07 Bayer Ag Process for the preparation of low molecular polyhydroxy compounds

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMIKER ZEITUNG, vol. 101, 1977, no. 7/8, pages 343-350 Heidelberg, DE. B. FELL et al.: "Isomerisierungsfreie Hydroformylierung mit Rhodiumcarbonyl/tert. Phosphin-Komplexkatalysatoren, II. Die Hydro-formylierung von Allylalkoholen" *
THE JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, Vol. 54, No. 11 November 1977, pages 882A-885A Minneapolis, U.S.A. W.R. MILLER et al.: "Geminal hydroxymethyl compounds from 9(10) formyl steoric Acid". *

Also Published As

Publication number Publication date
EP0017503A2 (en) 1980-10-15
EP0017503B1 (en) 1982-12-29
DE3061482D1 (en) 1983-02-03
CA1144573A (en) 1983-04-12

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