EP0005376A1 - Method for making decorative emblems - Google Patents
Method for making decorative emblems Download PDFInfo
- Publication number
- EP0005376A1 EP0005376A1 EP19790300786 EP79300786A EP0005376A1 EP 0005376 A1 EP0005376 A1 EP 0005376A1 EP 19790300786 EP19790300786 EP 19790300786 EP 79300786 A EP79300786 A EP 79300786A EP 0005376 A1 EP0005376 A1 EP 0005376A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- aluminium foil
- top surface
- plastic
- inch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000000758 substrate Substances 0.000 claims abstract description 83
- 229920003023 plastic Polymers 0.000 claims abstract description 59
- 239000004033 plastic Substances 0.000 claims abstract description 59
- 238000000576 coating method Methods 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 239000011888 foil Substances 0.000 claims description 31
- 229920002635 polyurethane Polymers 0.000 claims description 21
- 239000004814 polyurethane Substances 0.000 claims description 21
- 239000005030 aluminium foil Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 16
- 230000002093 peripheral effect Effects 0.000 claims description 15
- 238000005520 cutting process Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000009740 moulding (composite fabrication) Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000004049 embossing Methods 0.000 claims description 4
- 238000009966 trimming Methods 0.000 claims description 4
- 238000007650 screen-printing Methods 0.000 claims description 3
- 238000005034 decoration Methods 0.000 claims 1
- 238000013007 heat curing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 12
- 238000005266 casting Methods 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 239000000203 mixture Substances 0.000 description 8
- 230000005855 radiation Effects 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 6
- 150000003077 polyols Chemical class 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920005906 polyester polyol Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000003570 air Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000003796 beauty Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 230000005499 meniscus Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 229920002176 Pluracol® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical group C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000004886 head movement Effects 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- DSSXKBBEJCDMBT-UHFFFAOYSA-M lead(2+);octanoate Chemical compound [Pb+2].CCCCCCCC([O-])=O DSSXKBBEJCDMBT-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000037 vitreous enamel Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/30—Processes for applying liquids or other fluent materials performed by gravity only, i.e. flow coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/20—Applying plastic materials and superficially modelling the surface of these materials
Definitions
- the present invention relates to a method for making decorative emblems, plaques, panels, etc., which have a cured plastic layer over a decorative surface and, more particularly, it relates to a method for flow coating a fluent plastic material onto a decorative substrate to give a uniform thickness coated substrate from which emblems, plaques, or panels are formed.
- Decorative plaques and emblems are widely used throughout a number of industries, including the automotive and appliance fields.
- a colored vitreous frit was flowed into a bronze substrate and fired at 1250°F.
- the glass-like vitreous enamel served to beautify the product and protect the decorative substrate from weathering should the plaque or emblem - be exposed to the environment.
- Another problem is that the foil shapes are cast individually and the manufacturing process can as a result be too cumbersome and costly for some purposes. Accordingly, the need exists for yet another improved process for producing decorative emblems which is less expensive, more efficient and which yields a product which can be formed to different three-dimensional shapes if desired.
- the present invention meets that need by utilizing a flow coating process to apply a clear plastic material to a decorative substrate from which individual emblems and plaques may then be stamped and shaped.
- flow coating per se is known in a number of areas.
- U. S. Patents No. 3,875,893 to Riley and 3,431,889 to Fraatz both disclose flow-coating processes using multiple orifices to lay down a thin film onto a flat surface. But Fraatz and Riley do not relate to emblem or plaque manufacturing processes where a clear plastic is applied to a decorative substrate.
- the present invention utilizes such a flow coating process to produce decorative emblems in a manner more conducive to mass production than the process of my copending application Serial No. 702,194.
- the depth and beauty of the lens effect achieved by the process of that copending application is not duplicated with the present one. Still, it does have a number of other advantages. Principal among these is the economical and efficient means of production and the ability to apply a smooth coating to a decorated and embossed substrate which may be formed for application to non-planar surfaces.
- the substrate upon which the fluent plastic is coated may be a plastic or metal foil, preferably an aluminium foil 0.003 to .020 inch (.0762 to .508 mm) thick.
- the foil substrate is decorated with an appropriate design or series of designs. For example, if a foil sheet or a substantial part of it is to be used as a panel with a minimum amount of trimming after being coated, a single design might be used. More commonly, a series of designs in the form of individual emblems or plaque shapes will be applied to the foil sheet. With a metal foil, the series of designs is preferably applied by silk screen or lithographic printing then the design is enhanced by embossing select areas; although, other means for forming the decorative designs may also be used.
- any suitable primer may be used such as a silane primer.
- the decorated-primed substrate is then placed upon a vacuum mat which is situated upon a horizontal vacuum table such as that shown in U.S. Patent No. 4,034,708, and assigned to the assignee of this invention. Vacuum is drawn against the bottom surface of the foil through the mat to hold the substrate flat and horizontal.
- the substrate be held flat and horizontal during flow coating because of the fact that the flow characteristics of the fluent plastic and the liquid wettability of the substrate are used to control the spread of the plastic so that it is contiguous with predetermined areas of the foil as well as being uniformly thick. Another important factor in controlling'this is the existence of sharply defined peripheral sides for the substrate or define areas of the substrate.
- the flow coating is a path- wise disposition. That is, a multiple orifice nozzle (nor nozzles) is passed over the decorated-primed surface of the foil at a steady speed as the substrate is held stationary.
- the number of orifices used may vary depending on the width of the path to be laid down. As an example, a 2.1 inch (53. 34 mm) wide nozzle having 22 orifices of a .022 inch (.5588 mm) I.D. and with a 0.10 inch (2.54 mm) spacing between the orifices, can be used to lay down a path of 2.4 to 2.5 inches (60.96 to 63. 5 mm) in width.
- the thickness sought is between approximately .020 to .030 inch (.508 to .762 mm).
- the plastic is preferably a fluent polyurethane of two component parts (polyol and isocyanate) which are mixed immediately prior to coating and cure upon heating.
- a polyurethane of this type is disclosed in my copending application Serial No. 702,194.
- the polyurethane may be compounded from among the componentslisted in the copending application as is known to give a more flexible cured plastic.
- the bond to the substrate remains strong, it is desirable in this invention to have a somewhat flexible plastic coat so that the emblem, plaque, or panel may be conformed.
- some decorative automobile panels are applied to a curved surface.
- the present invention it is possible to conform the cured plastic coated panel to that surface.
- curing will be by irradiation with infra-red or ultraviolet light.
- the polyurethane compounds mentioned above are heat curable and, thus, infra-red lamps are used; although, obviously other heat sources may also be used. Still, it is desirable to get a through cure, i.e., heat from both the top and bottom of the coated foil.
- the preferred vacuum table arrangement of U. S. Patent No. 4,034,708 makes this possible because of a capability of heating or cooling it.
- the infra-red lamps themselves as the heat source for both top and bottom heating This may be done by using an I. R. absorptive mat as the vacuum mat. The mat will, then, pick up heat from the infra-red radiation and conduct it back from the bottom through the coated foil.
- the coated substrate is cooled and removed from the vacuum table. It may at this stage be further processed by cutting, trimming and forming.
- individual emblem or plaque shapes are contained on the single sheet, they are stamped out by a cutting die around the particular emblem or plaque shape. It has been found that by die cutting from the bottom surface of the coated foil, it is possible to impart a slightly convex configuration when viewed from the top surface. The convex shape helps give the appearance of a lens effect to the emblem; although, one does not actually exist.
- the appearance of the coated emblem is superior to a non-coated one.
- the luster and beauty of the clear plastic adds considerably to the appearance. It also serves to protect the decorative surface from weathering, chipping, scratching, etc.
- the flow coating process of this invention may be performed with a modified form of the device disclosed in U. S. Patent No. 4,034,708.
- An overall view of that device is shown in Fig. 1. As seen there, a foil substrate 12 having a series of emblem design shapes 82 decorated on its surface is positioned on vacuum table 14.
- the coating operation utilizes a casting head (not shown in Figs. 1-2) in the form of a multiple orifice nozzle or nozzles (see Figs. 3-4) for flow coating measured amounts of a fluent plastic material, such as a fluent polyurethane, to the upper surface of the substrate 12.
- a casting head not shown in Figs. 1-2
- a multiple orifice nozzle or nozzles see Figs. 3-4
- an infrared radiation source means for supplying infrared radiation may be provided to irradiate the polyurethane.
- Such a source is included in member 20 which is shown extended in Fig. 1 in dashed lines.
- the source of radiation is moved rather than moving the substrate; although, the reverse situation can also be used.
- the extended position of the member 20 is shown also in Fig. 2, along with lamps 23 which provide the infrared radiation.
- Member 20 is moved by means of air cylinder 25. It should be understood that an ultraviolet curable plastic may also be cast using the device of the present invention; in such a case, lamps 23 would be ultraviolet radiation sources.
- an exhaust means including blower 29, exhaust duct 30, and associated motor (not shown) are provided in order to insure that the operator of the machine does not inhale fumes unnecessarily.
- ambient air is drawn into the cabinet 31 by fan 29. The air will be drawn over the top of the platen means 35. The air will also be drawn past the lamps 23 preventing fumes from escaping upwardly through member 20 and also cooling lamps 23.
- water inlets 36 and 37 and one or more outlets 38 are provided to receive and discharge water supplied at more than one temperature.
- Vacuum pump 41 is also provided to supply a vacuum platen 35 with a vacuum.
- vacuum pump 41 draws a vacuum through holes 43 in platen 35.
- This serves to hold vacuum mat 45 onto the platen since the holes in vacuum mat 45 are not aligned with those in platen 35.
- the vacuum mat 45 may be a perforated one-fourth inch (6.35 mm) thick silicone rubber mat. Since it is perforated, the vacuum from platen 35 will also be drawn through mat 45 against substrate 12.
- Fig. 3 also shows in detail casting head 47 having two nozzles 49 and 50. Each nozzle is fed a supply of fluent plastic such as a liquid polyurethane.
- fluent plastic such as a liquid polyurethane.
- A polyether polyol component
- B diisocyanate component
- a catalyst such as a lead material is used since it promotes a slow cure at room temperature so as to allow time for full flow of the liquid polyurethane before setting.
- the diisocyanate is Hylene W from E. I. duPont de Nemours and Co.
- the polyether polyol may be one or more of the Pluracol materials (P-410 or TP-440) from BASF Wyandotte. It may also be a polyether-polyester polyol combination, use of the polyester polyol making the cured polyurethane more flexible.
- the ratio of components A:B is preferably 50-60:40-50.
- a polyester polyol or polylactone polyol could be used in place of the polyether polyol.
- Tanks (not shown) store the "A" and "B" material separately prior to mixing, then, feeding to supply lines 51 and 52 for nozzles 49 and 50.
- Nozzles 49 and 50 are mounted on carriage 54 which is slidably mounted on rods 57 and 58 for motion over the surface of substrate 12 as indicated by the arrows in Fig. 4.
- Each nozzle has multiple orifices in the form of tubes 61 and 62. Fittings 63 and 64 connect each of the multiple orifice nozzles 49 and 50 to supply lines 51 and 52.
- the number of tubes 61, 62 and the spacing between the tubes in an individual nozzle will vary in dependence on the width of the portion of the substrate to be coated. It has been found, however, that between 10 and 26 tubes, spaced apart approximately 1/8 to 1/10 inch (3.175 to 2.54 mm), may be used for each nozzle means in the present embodiment.
- the tubes preferaby have .022 inch (.5588 mm) I.D. and a .039 inch (.9906 mm) O.D.
- Spacer bars 71 and 72 hold the tubes 61 and 62 spaced apart at desired distances, preferably 0.10 inch (2.54 mm)
- 22 tubes are used in each nozzle 49 and 50.
- the 22 tubes have a combined width of approximately 2.1 inches (53.34 mm)
- casting head 47 The operation of casting head 47 is better understood with reference to rig. 4.
- Pneumatic or hydraulic controls (not shown) drive casting head along the length of stationary substrate 12 as indicated by the arrows. A return movement, also as indicated, takes place after completion of flow coating onto one decorative substrate and the casting head is in position to repeat the process for another decorative substrate.
- the liquid polyurethane flows from tubes 61, 62 at a uniform flow rate. Since the movement of casting head 47 over stationary substrate 12 is at a steady speed, there is laid down a uniformly distributed amount of liquid polyurethane.
- That fluent plastic then flows to complete the coverage of the portion of the surface desired.
- a uniform thickness of plastic results.
- the speed of casting head movement and coating rate for the plastic depend upon the area to be covered, the number of tubes used, the viscosity of the fluent plastic, etc. Generally, however, it is possible to easily adjust these variables in order to achieve a coating of the thickness desired.
- the desired thickness is 0.020 to 0.030 inch (.508 to .762 mm).
- an important feature in obtaining a uniform coating in this thickness is that the fluent plastic on the surface of substrate 12 flows up to, but not beyond, the sharply defined peripheral sides which intersect with the planar top surface.
- the wettability characteristics of the fluent plastic are such that it only partially wets the surface of substrate 12 and will flow on the surface of the substrate. Under heating, the viscosity of the polyurethane becomes lower and flow slows. Upon reaching a sharply defined peripheral side, this flow will be halted. If the edge is verticle, the flowing liquid plastic wants to maintain a given contact angle at that edge (specified by the interface properties of the plastic and the foil). As long as the internal pressure (hydrostatic) of the plastic does not exceed the surface tension at that contact angle, the liquid plastic will not overflow the side.
- those emblems are represented by emblem design shapes 82.
- a silane before printing.
- Other known silane primers may also be used. The primers may be pre-applied by spraying, dipping, or roller-coating, followed by drying to remove the solvent.
- the design shapes are decorated onto substrate 12.
- silk-screen printing and embossing are the usual methods.
- an aluminium foil from 0.003 to 0.020 inch (0.0762 to 0.508 mm) thick may be silk-screen printed and embossed in selected areas to provide a series of emblem design shapes as at 82.
- the fluent plastic is then flow coated onto the substrate 12 as described.
- the substrate is heated with infrared lamps 23, also as described, in order to cure the plastic.
- a feature of the present invention is the use of vacuum mat 45 to aid in that curing process. That is, by using an infrared absorptive mat, such as a one-fourth inch (6.35 mm) thick silicone rubber mat, heat is absorbed by the mat and re-radiated back through substrate 12 to give a through cure.
- an infrared absorptive mat such as a one-fourth inch (6.35 mm) thick silicone rubber mat
- plastic layer 84 is adhered to substrate 12 sufficiently to permit further processing.
- panel production that may involve only minor amounts of trimming, cutting and forming.
- a die is used to cut around each emblem design shape 82 to form individual emblems. By die cutting from the bottom (uncoatcd) side 86 of substrate 12, a slight convex shape is given to each emblem.
- the emblems may then be adhesively applied into or onto the intended surface. They may also be placed in a retaining frame which is used to affix the emblem onto the surface. Finally, it is noted that since the fluent plastic may be compounded as described to give a somewhat flexible material when cured, forming other than merely die cutting may be undertaken. The emblem, and more often panels, may be conformed to non-planar surfaces as long as the degree bending for the conformity required is not too severe.
- Another embodiment involves use of a single nozzle of the type shown for coverage of a substrate of varying widths. It is mounted on a carriage of the same width which only tracks back and forth longitudinally over the length of substrate 12. Also, the nozzle is movable laterally on the carriage. After each pass and on the return route, the nozzle moves laterally one nozzle width (plus approximately 0.15 - 0.20 inch (3.81 - 5.08 mm). Another pass begins. This is repeated until the full expanse of the substrate has been coated. In each dase, a timing mechanism is necessary to start and stop flow of the liquid plastic during a single pass. A delay timer is provided to permit the lateral movement of the nozzle after the plastic flow has stopped and prior to the start of plastic flow after the lateral movement of the nozzle is completed.
- a single nozzle having 22 tubes as described was used to flow coat a substrate of approximately 2.5 inch x 24 inch (6.35 x 609.6 mm) in a single pass.
- the substrate was 0.015 inch (0.381 mm) thick aluminium foil which had been cleaned, primed, silk-screen printed and embossed with a series of circular emblem designs approximately 1 1/8 inch (28.575 mm) in diameter.
- the 22 tube nozzle had a width of approximately 2.1 inches (53. 34 mm) and was centered over the 2.5 inches (63.5 mm) wide substrate to leave margins of approximately 0.20 inch (5.08 mm) Starting 0.20 inch (5.08 mm) from one end of the foil, it was passed over the surface of the aluminium foil, which was held flat and horizontal on a vacuum mat as described. A steady speed of 3.2 inches (81.28 mm) per second was used. Clear liquid polyurethane was flowed from the nozzle at the uniform rate of 210 grams per minute.
- the liquid polyurethane was a mixture of "A” and “B” components and had a density of 17.39 grams/cubic inch (441.706 grams per cubic millimetre).
- the "A” component was itself a mixture of polyester polyol and polyether polyol and contained a lead octoate catalyst.
- the "B” component was a mixture of polypropylene glycol and an aliphatic diisocyanate. The ratio of "A" to "B” was 54. 5% to 45.5%.
- the coated foil was heated under four 1600 watt infrared lamps at a distance of 12 inch (304.8 mm) for 10 minutes. This was followed by cooling the vacuum table with 60°F (15.55°C) water for 2 minutes. After cooling, representative ones of the emblem shapes were die cut from the foil by applying a die to the bottom (uncoated) surface of the foil.
- the emblems had a slightly convex shape when viewed from the front surface, and were lustrous in appearance.
- the cured plastic was bound firmly to the decorative substrate and provides a tough, resistant protective coating in addition to beautifying the design.
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Apparatus (AREA)
Abstract
Description
- The present invention relates to a method for making decorative emblems, plaques, panels, etc., which have a cured plastic layer over a decorative surface and, more particularly, it relates to a method for flow coating a fluent plastic material onto a decorative substrate to give a uniform thickness coated substrate from which emblems, plaques, or panels are formed.
- Decorative plaques and emblems are widely used throughout a number of industries, including the automotive and appliance fields. In the past, a colored vitreous frit was flowed into a bronze substrate and fired at 1250°F. The glass-like vitreous enamel served to beautify the product and protect the decorative substrate from weathering should the plaque or emblem - be exposed to the environment.
- Today, plastics are primarily used for producing such plaques and emblems. For example, in Loew (U. S. Patent No. 3,654,062), there is disclosed a process for injection molding a decorative Mylar facing sheet over a vinyl plastic body. The plaque is coated with a layer of protective varnish on the outer surface of the facing sheet. Gits, U. S. Patent No. 3,246,066, is similar in that male and female molds are used to form a cavity into which a decorative foil is placed and into which a clear plastic material is injected. Prior to injecting a clear plastic material against the front face of the foil, the foil is precoated. Other molding processes, such as compression molding (either one or two shot), are also well known in the art. See for instance, U.S. Patents No. 2,244, 565;2,931,119; 3,075,249; and 3,114,597.
- In my copending application Serial No. 702,194, filed July 2, 1976, there is disclosed an improved process for producing decorative emblems. That process involves casting a plastic material onto decorative foil shapes to form a meniscus which when cured gives a lens effect to the top surface of the foil shape. A problem with that process is that despite an ability to vary the size and shape, it is not practical to later conform the as-cast emblem to non-planar surfaces.
- Another problem is that the foil shapes are cast individually and the manufacturing process can as a result be too cumbersome and costly for some purposes. Accordingly, the need exists for yet another improved process for producing decorative emblems which is less expensive, more efficient and which yields a product which can be formed to different three-dimensional shapes if desired.
- The present invention meets that need by utilizing a flow coating process to apply a clear plastic material to a decorative substrate from which individual emblems and plaques may then be stamped and shaped. Of course, flow coating per se is known in a number of areas. My copending application Serial No. 718,578, filed August 30, 1976, discloses such a process for coating glass containers. As another example, U. S. Patents No. 3,875,893 to Riley and 3,431,889 to Fraatz both disclose flow-coating processes using multiple orifices to lay down a thin film onto a flat surface. But Fraatz and Riley do not relate to emblem or plaque manufacturing processes where a clear plastic is applied to a decorative substrate.
- It should also be noted that Hansen in U.S. Patent No. 3,725,112 Mentions flow coating as one of the possible methods for producing his coated or encapsu- substrates. That patent discloses applying a protective low-glare, uniformly textured, transparent, polymeric coating to a substrate such as wood, steel, hard- board, aluminum and the like. Still, the intent of Hansen is to produce textured films having a low-glare surface and not to produce decorative emblems of the type contemplated by the present invention.
- Therefore, the need still remains for a method for flow coating clear plastic materials onto a decorative substrate to economically and efficiently produce decorative emblems, plaques, panels, etc.
- The present invention utilizes such a flow coating process to produce decorative emblems in a manner more conducive to mass production than the process of my copending application Serial No. 702,194. Of course, the depth and beauty of the lens effect achieved by the process of that copending application is not duplicated with the present one. Still, it does have a number of other advantages. Principal among these is the economical and efficient means of production and the ability to apply a smooth coating to a decorated and embossed substrate which may be formed for application to non-planar surfaces.
- This latter feature is, in fact, possible because a high meniscus and lens effect are not existent here. Rather, the plastic is of a more flexible variety and is applied in a thinner film which will withstand subsequent shaping operations. And yet, because it is possible with the instant flow coating process to deposit the plastic on the decorative substrate uniformly to a thickness of .020 to .030 inches (.508 to .762 mm), an attractive emblem is still produced.
- The substrate upon which the fluent plastic is coated may be a plastic or metal foil, preferably an aluminium foil 0.003 to .020 inch (.0762 to .508 mm) thick. The foil substrate is decorated with an appropriate design or series of designs. For example, if a foil sheet or a substantial part of it is to be used as a panel with a minimum amount of trimming after being coated, a single design might be used. More commonly, a series of designs in the form of individual emblems or plaque shapes will be applied to the foil sheet. With a metal foil, the series of designs is preferably applied by silk screen or lithographic printing then the design is enhanced by embossing select areas; although, other means for forming the decorative designs may also be used.
- Likewise, it is desirable to prime the top surface of the substrate prior to printing. Any suitable primer may be used such as a silane primer. The decorated-primed substrate is then placed upon a vacuum mat which is situated upon a horizontal vacuum table such as that shown in U.S. Patent No. 4,034,708, and assigned to the assignee of this invention. Vacuum is drawn against the bottom surface of the foil through the mat to hold the substrate flat and horizontal.
- It is important that the substrate be held flat and horizontal during flow coating because of the fact that the flow characteristics of the fluent plastic and the liquid wettability of the substrate are used to control the spread of the plastic so that it is contiguous with predetermined areas of the foil as well as being uniformly thick. Another important factor in controlling'this is the existence of sharply defined peripheral sides for the substrate or define areas of the substrate.
- Thus, it is possible to limit the coated areas of a single foil sheet by forming slits, embossed ridges, or other sharp edges in the sheet. When a predetermined amount amount of fluent plastic is flow coated onto that area, then, it will spread only to the sharply defined peripheral side. In this manner, it is possible to avoid waste by coating only the path directly over the designs from which the emblems or plaques are to be formed, and not wastefully on peripheral areas which are to be discarded.
- In the present invention, the flow coating is a path- wise disposition. That is, a multiple orifice nozzle (nor nozzles) is passed over the decorated-primed surface of the foil at a steady speed as the substrate is held stationary. The number of orifices used may vary depending on the width of the path to be laid down. As an example, a 2.1 inch (53. 34 mm) wide nozzle having 22 orifices of a .022 inch (.5588 mm) I.D. and with a 0.10 inch (2.54 mm) spacing between the orifices, can be used to lay down a path of 2.4 to 2.5 inches (60.96 to 63. 5 mm) in width.
- As can be seen from this example, if such a nozzle is to be used to coat a sheet of greater than 2.5 inches (63. 5 mm) width, then either several nozzles tracking across the sheet in parallel paths must be used or the single nozzle must be programmed to track back and forth across the sheet until the surface is covered with a uniform thickness of the fluent plastic.
- The thickness sought is between approximately .020 to .030 inch (.508 to .762 mm). The plastic is preferably a fluent polyurethane of two component parts (polyol and isocyanate) which are mixed immediately prior to coating and cure upon heating. A polyurethane of this type is disclosed in my copending application Serial No. 702,194. In formulating the particular plastic composition from among those disclosed in the copending application, it is important to use a catalyst which results in a somewhat slow curing time in order to allow the flow coated liquid plastic to flow to its full extent, i.e., to the sharply defined peripheral sides, before curing is accomplished. Otherwise, it may not be possible to obtain a uniform thickness, smooth coating.
- Likewise, the polyurethane may be compounded from among the componentslisted in the copending application as is known to give a more flexible cured plastic. As long as the bond to the substrate remains strong, it is desirable in this invention to have a somewhat flexible plastic coat so that the emblem, plaque, or panel may be conformed. For example, some decorative automobile panels are applied to a curved surface. With the present invention, it is possible to conform the cured plastic coated panel to that surface.
- For most of the types of plastic contemplated, curing will be by irradiation with infra-red or ultraviolet light. The polyurethane compounds mentioned above are heat curable and, thus, infra-red lamps are used; although, obviously other heat sources may also be used. Still, it is desirable to get a through cure, i.e., heat from both the top and bottom of the coated foil. The preferred vacuum table arrangement of U. S. Patent No. 4,034,708 makes this possible because of a capability of heating or cooling it. However, it has been found desirable to use the infra-red lamps themselves as the heat source for both top and bottom heating. This may be done by using an I. R. absorptive mat as the vacuum mat. The mat will, then, pick up heat from the infra-red radiation and conduct it back from the bottom through the coated foil.
- After curing, the coated substrate is cooled and removed from the vacuum table. It may at this stage be further processed by cutting, trimming and forming. When individual emblem or plaque shapes are contained on the single sheet, they are stamped out by a cutting die around the particular emblem or plaque shape. It has been found that by die cutting from the bottom surface of the coated foil, it is possible to impart a slightly convex configuration when viewed from the top surface. The convex shape helps give the appearance of a lens effect to the emblem; although, one does not actually exist.
- Still, the appearance of the coated emblem is superior to a non-coated one. The luster and beauty of the clear plastic adds considerably to the appearance. It also serves to protect the decorative surface from weathering, chipping, scratching, etc.
- Accordingly, it is an object of the present invention to provide a method for making decorative emblems, plaques and panels which have a cured plastic layer over a decorative surface.
- It is another object of the present invention to provide a flow coating process whereby a clear plastic layer may be economically and efficiently laid down to a uniform thickness on a decorative substrate from which the emblems, plaques, and panels may be formed.
- Other objects and advantages of the present invention will be apparent from the following description, the accompanying drawings and the appended claims.
-
- Fig. 1 is a perspective overall view of the preferred apparatus for performing the method of the present invention;
- Fig. 2 is a side view of the device;
- Fig. 3 is a view illustrating the coating nozzle arrangement for performing the method of the present invention;
- -Fig. 4 is a perspective view of the coating arrangement for performing the method of the present invention; and
- Fig. 5 is a cross-sectional view of the coated sheet of Fig. 4.
- The flow coating process of this invention may be performed with a modified form of the device disclosed in U. S. Patent No. 4,034,708. An overall view of that device is shown in Fig. 1. As seen there, a
foil substrate 12 having a series of emblem design shapes 82 decorated on its surface is positioned on vacuum table 14. - The coating operation utilizes a casting head (not shown in Figs. 1-2) in the form of a multiple orifice nozzle or nozzles (see Figs. 3-4) for flow coating measured amounts of a fluent plastic material, such as a fluent polyurethane, to the upper surface of the
substrate 12. - Preferred are approximately 100% solid polyurethane resin systems which are catalyzed by mixing two components just prior to casting. In order to promote a rapid curing of the fluent polyurethane system, an infrared radiation source means for supplying infrared radiation may be provided to irradiate the polyurethane. Such a source is included in
member 20 which is shown extended in Fig. 1 in dashed lines. - In the arrangement illustrated in Figs. 1-2, the source of radiation is moved rather than moving the substrate; although, the reverse situation can also be used. The extended position of the
member 20 is shown also in Fig. 2, along withlamps 23 which provide the infrared radiation.Member 20 is moved by means ofair cylinder 25. It should be understood that an ultraviolet curable plastic may also be cast using the device of the present invention; in such a case,lamps 23 would be ultraviolet radiation sources. - While only very small amounts of volatiles will be given off by the plastic during curing, an exhaust means including
blower 29,exhaust duct 30, and associated motor (not shown) are provided in order to insure that the operator of the machine does not inhale fumes unnecessarily. As illustrated in Fig. 2, ambient air is drawn into thecabinet 31 byfan 29. The air will be drawn over the top of the platen means 35. The air will also be drawn past thelamps 23 preventing fumes from escaping upwardly throughmember 20 and also coolinglamps 23. - It may be desirable to control the temperature of the substrate prior to and during the casting and curing process. Under some circumstances, it may be desirable to maintain the substrate at one temperature during casting and a portion of the curing process, and then to maintain the substrate at a second temperature. Toward this end,
water inlets more outlets 38, are provided to receive and discharge water supplied at more than one temperature. - It may also be desirable to irradiate the substrate prior to the casting process, such that the substrates are heated and the viscosity of the cast plastic reduced as it flows onto the substrates. This reduction in viscosity will cause the plastic to flow more evenly over a larger foil substrate. Since it is desirable to be able to change readily the sequence of steps and the order of these steps, a number of timers and controls shown generally at 39 are provided. Vacuum pump 41 is also provided to supply a
vacuum platen 35 with a vacuum. - The use of a vacuum to hold
substrate 12 flat and horizontal is better shown in Fig. 3. Thus, vacuum pump 41 draws a vacuum throughholes 43 inplaten 35. This serves to holdvacuum mat 45 onto the platen since the holes invacuum mat 45 are not aligned with those inplaten 35. Thevacuum mat 45 may be a perforated one-fourth inch (6.35 mm) thick silicone rubber mat. Since it is perforated, the vacuum fromplaten 35 will also be drawn throughmat 45 againstsubstrate 12. - Fig. 3 also shows in
detail casting head 47 having twonozzles - The mixture of "A" and "B" components of this type cures, through catalytic action, under heat such as produced by infrared radiation. Accordingly, this type of arrangement will be disclosed as the preferred embodiment; although, single component, photocurable, polyurethanes of known types could also be used.
- Tanks (not shown) store the "A" and "B" material separately prior to mixing, then, feeding to supply
lines nozzles Nozzles carriage 54 which is slidably mounted onrods 57 and 58 for motion over the surface ofsubstrate 12 as indicated by the arrows in Fig. 4. Each nozzle has multiple orifices in the form oftubes Fittings 63 and 64 connect each of themultiple orifice nozzles lines - The number of
tubes tubes nozzle - The operation of casting
head 47 is better understood with reference to rig. 4. Pneumatic or hydraulic controls (not shown) drive casting head along the length ofstationary substrate 12 as indicated by the arrows. A return movement, also as indicated, takes place after completion of flow coating onto one decorative substrate and the casting head is in position to repeat the process for another decorative substrate. As the castinghead 47 begins its initial track oversubstrate 12, starting at approximately 0.15 to 0.20 inch (3. 81 to 5.08 mm) from theedge 75, the liquid polyurethane flows fromtubes head 47 overstationary substrate 12 is at a steady speed, there is laid down a uniformly distributed amount of liquid polyurethane. - That fluent plastic then flows to complete the coverage of the portion of the surface desired. A uniform thickness of plastic results. The speed of casting head movement and coating rate for the plastic depend upon the area to be covered, the number of tubes used, the viscosity of the fluent plastic, etc. Generally, however, it is possible to easily adjust these variables in order to achieve a coating of the thickness desired. The desired thickness is 0.020 to 0.030 inch (.508 to .762 mm).
- As mentioned, an important feature in obtaining a uniform coating in this thickness is that the fluent plastic on the surface of
substrate 12 flows up to, but not beyond, the sharply defined peripheral sides which intersect with the planar top surface. - Thus, the wettability characteristics of the fluent plastic are such that it only partially wets the surface of
substrate 12 and will flow on the surface of the substrate. Under heating, the viscosity of the polyurethane becomes lower and flow slows. Upon reaching a sharply defined peripheral side, this flow will be halted. If the edge is verticle, the flowing liquid plastic wants to maintain a given contact angle at that edge (specified by the interface properties of the plastic and the foil). As long as the internal pressure (hydrostatic) of the plastic does not exceed the surface tension at that contact angle, the liquid plastic will not overflow the side. - Accordingly, it is necessary to form sharply defined peripheral sides intersecting with the top planar surface around each area to be coated. In Fig. 4, there are two paths which are to be uniformly coated, one beneath
nozzle 49 and one beneathnozzle 50. The line between these paths is slit 77 which forms sharpperipheral sides substrate 12, then, complete the formation of the two paths. Of course, other arrangements may be used to form the sharply defined peripheral sides, such as by embossing ridges in the sheet. - It is also possible to coat the whole surface of
substrate 12 since its four edges are sharply verticle. However, it may be advantageous in terms of eliminating excess scrap and waste to form paths in the manner mentioned. Those paths, then, will be over only those areas of the substrate from which emblems or plaques are to be formed. - In Figs. 4-5, those emblems are represented by emblem design shapes 82. It is desirable to prime the substrate with a silane before printing. As an example, a mixture of approximately 2% castor oil (Surfactol from The Baker Castor Oil Co.) and up to approximately 2% silane (Dow 6020, 6040, or 6075 from Dow Corning Corp., which are respectively, 3-(2-amino- ethylamine) propyltrimethoxysilane, glycidoxypropyltrimethoxysilane, and vinyltriacetooxysilane) in a solvent (70% isopropyl alcohol and 30% octane) may be used. Other known silane primers may also be used. The primers may be pre-applied by spraying, dipping, or roller-coating, followed by drying to remove the solvent.
- Next, the design shapes are decorated onto
substrate 12. With a metal foil, silk-screen printing and embossing are the usual methods. Thus, an aluminium foil from 0.003 to 0.020 inch (0.0762 to 0.508 mm) thick may be silk-screen printed and embossed in selected areas to provide a series of emblem design shapes as at 82. - The fluent plastic is then flow coated onto the
substrate 12 as described. Next, the substrate is heated withinfrared lamps 23, also as described, in order to cure the plastic. - A feature of the present invention is the use of
vacuum mat 45 to aid in that curing process. That is, by using an infrared absorptive mat, such as a one-fourth inch (6.35 mm) thick silicone rubber mat, heat is absorbed by the mat and re-radiated back throughsubstrate 12 to give a through cure. - Once the curing is accomplished and the coated substrate cooled,
plastic layer 84 is adhered tosubstrate 12 sufficiently to permit further processing. In the case of panel production, that may involve only minor amounts of trimming, cutting and forming. With emblem production as shown, a die is used to cut around eachemblem design shape 82 to form individual emblems. By die cutting from the bottom (uncoatcd) side 86 ofsubstrate 12, a slight convex shape is given to each emblem. - The emblems may then be adhesively applied into or onto the intended surface. They may also be placed in a retaining frame which is used to affix the emblem onto the surface. Finally, it is noted that since the fluent plastic may be compounded as described to give a somewhat flexible material when cured, forming other than merely die cutting may be undertaken. The emblem, and more often panels, may be conformed to non-planar surfaces as long as the degree bending for the conformity required is not too severe.
- While the preferred embodiment just discussed utilizes a two-nozzle casting head as shown in Pigs. 3-4 which makes a single pass over
substrate 12, it should be emphasized that a single multiple orifice nozzle may be used for a narrower application path or additional nozzles may be added to castinghead 47 to give a wider application path. Likewise, the number of tubes used with each nozzle may be varied to vary the width of the application path. - Another embodiment involves use of a single nozzle of the type shown for coverage of a substrate of varying widths. It is mounted on a carriage of the same width which only tracks back and forth longitudinally over the length of
substrate 12. Also, the nozzle is movable laterally on the carriage. After each pass and on the return route, the nozzle moves laterally one nozzle width (plus approximately 0.15 - 0.20 inch (3.81 - 5.08 mm). Another pass begins. This is repeated until the full expanse of the substrate has been coated. In each dase, a timing mechanism is necessary to start and stop flow of the liquid plastic during a single pass. A delay timer is provided to permit the lateral movement of the nozzle after the plastic flow has stopped and prior to the start of plastic flow after the lateral movement of the nozzle is completed. - In this example, a single nozzle having 22 tubes as described was used to flow coat a substrate of approximately 2.5 inch x 24 inch (6.35 x 609.6 mm) in a single pass. The substrate was 0.015 inch (0.381 mm) thick aluminium foil which had been cleaned, primed, silk-screen printed and embossed with a series of circular emblem designs approximately 1 1/8 inch (28.575 mm) in diameter.
- The 22 tube nozzle had a width of approximately 2.1 inches (53. 34 mm) and was centered over the 2.5 inches (63.5 mm) wide substrate to leave margins of approximately 0.20 inch (5.08 mm) Starting 0.20 inch (5.08 mm) from one end of the foil, it was passed over the surface of the aluminium foil, which was held flat and horizontal on a vacuum mat as described. A steady speed of 3.2 inches (81.28 mm) per second was used. Clear liquid polyurethane was flowed from the nozzle at the uniform rate of 210 grams per minute.
- The liquid polyurethane was a mixture of "A" and "B" components and had a density of 17.39 grams/cubic inch (441.706 grams per cubic millimetre). The "A" component was itself a mixture of polyester polyol and polyether polyol and contained a lead octoate catalyst. The "B" component was a mixture of polypropylene glycol and an aliphatic diisocyanate. The ratio of "A" to "B" was 54. 5% to 45.5%.
- It took the nozzle 7.43 seconds to transverse the 24 inch (60.96 mm) length of the aluminium foil (stopping 0.20 inch (5.08 mm) from the end). In the process, 26 grams of liquid polyurethane were deposited onto the foil at a uniform thickness of 0.025 inch ± .005 inch (0.635 mm ± 0.127 mm).
- After flow coating, the coated foil was heated under four 1600 watt infrared lamps at a distance of 12 inch (304.8 mm) for 10 minutes. This was followed by cooling the vacuum table with 60°F (15.55°C) water for 2 minutes. After cooling, representative ones of the emblem shapes were die cut from the foil by applying a die to the bottom (uncoated) surface of the foil.
- The emblems had a slightly convex shape when viewed from the front surface, and were lustrous in appearance. The cured plastic was bound firmly to the decorative substrate and provides a tough, resistant protective coating in addition to beautifying the design.
- While the method herein described constitutes a preferred embodiment of the invention, it is to be understood that the invention is not limited to this precise method, and that changes may be made therein without departing from the scope of the invention.
Claims (11)
said substrate having sharply defined peripheral sides which intersect with said top surface,
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90382978A | 1978-05-08 | 1978-05-08 | |
US903829 | 1978-05-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0005376A1 true EP0005376A1 (en) | 1979-11-14 |
EP0005376B1 EP0005376B1 (en) | 1985-08-14 |
Family
ID=25418136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19790300786 Expired EP0005376B1 (en) | 1978-05-08 | 1979-05-08 | Method for making decorative emblems |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0005376B1 (en) |
JP (1) | JPS54146838A (en) |
DE (1) | DE2967497D1 (en) |
IE (1) | IE50566B1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0028903A1 (en) * | 1979-11-09 | 1981-05-20 | The D.L.Auld Company | Method for making decorative emblems having an ultrathin coating of plastic |
EP0030827A1 (en) * | 1979-12-17 | 1981-06-24 | The D.L.Auld Company | Decorative emblem and method of manufacture |
EP0060721A1 (en) * | 1981-03-16 | 1982-09-22 | The D.L.Auld Company | Decorative emblems and method for making same |
US4767647A (en) * | 1979-12-17 | 1988-08-30 | The D. L. Auld Company | Decorative emblem |
US5282111A (en) * | 1989-06-09 | 1994-01-25 | Labinal Components And Systems, Inc. | Thermal transfer plate and integrated circuit chip or other electrical component assemblies including such plate |
US5485351A (en) * | 1989-06-09 | 1996-01-16 | Labinal Components And Systems, Inc. | Socket assembly for integrated circuit chip package |
NL2000357C2 (en) * | 2006-12-06 | 2008-06-09 | Herikon B V | Method and device for manufacturing polyurethane products, in particular day marks for buoys. |
DE102007061056A1 (en) * | 2007-12-18 | 2009-06-25 | Doro Tape Ehlis Gmbh & Co. Kg | Three-dimensional plastic label manufacturing method, involves bringing hardenable plastic in small excess quantity in preheated negative-molds moved with predetermined conveying speed in still free-flowing condition in continuous process |
CN114762846A (en) * | 2021-01-14 | 2022-07-19 | 通用汽车环球科技运作有限责任公司 | Logo installation system and method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4825232B2 (en) * | 2008-03-21 | 2011-11-30 | 中外炉工業株式会社 | Burner |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1549303A (en) * | 1967-09-01 | 1968-12-13 | ||
US3431889A (en) * | 1965-09-27 | 1969-03-11 | Shell Oil Co | Fluid distribution bar |
DE1652329A1 (en) * | 1966-08-01 | 1971-04-08 | Glaverbel Bruessel | Method and device for applying a liquid to a surface |
US3725112A (en) * | 1970-12-04 | 1973-04-03 | L Hansen | Novel display device |
US3875893A (en) * | 1973-11-14 | 1975-04-08 | Neil R Riley | Fluid dispensing system |
DE2506462A1 (en) * | 1975-02-15 | 1976-09-02 | Hoechst Ag | PROCESS FOR EVEN APPLICATION OF TREATMENT LIQUIDS ON TEXTILE FLATS |
US4034708A (en) * | 1976-08-30 | 1977-07-12 | The D. L. Auld Co. | Modular device for production of cast plastic emblems |
US4100010A (en) * | 1974-06-12 | 1978-07-11 | The D. L. Auld Company | Method for making decorative emblems |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49102763A (en) * | 1973-01-12 | 1974-09-27 | ||
JPS5355349A (en) * | 1976-10-29 | 1978-05-19 | Kyowa Electric & Chemical | Apparatus for painting rod |
-
1979
- 1979-05-08 DE DE7979300786T patent/DE2967497D1/en not_active Expired
- 1979-05-08 JP JP5625479A patent/JPS54146838A/en active Pending
- 1979-05-08 EP EP19790300786 patent/EP0005376B1/en not_active Expired
- 1979-08-08 IE IE92579A patent/IE50566B1/en unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3431889A (en) * | 1965-09-27 | 1969-03-11 | Shell Oil Co | Fluid distribution bar |
DE1652329A1 (en) * | 1966-08-01 | 1971-04-08 | Glaverbel Bruessel | Method and device for applying a liquid to a surface |
FR1549303A (en) * | 1967-09-01 | 1968-12-13 | ||
US3725112A (en) * | 1970-12-04 | 1973-04-03 | L Hansen | Novel display device |
US3875893A (en) * | 1973-11-14 | 1975-04-08 | Neil R Riley | Fluid dispensing system |
US4100010A (en) * | 1974-06-12 | 1978-07-11 | The D. L. Auld Company | Method for making decorative emblems |
DE2506462A1 (en) * | 1975-02-15 | 1976-09-02 | Hoechst Ag | PROCESS FOR EVEN APPLICATION OF TREATMENT LIQUIDS ON TEXTILE FLATS |
US4034708A (en) * | 1976-08-30 | 1977-07-12 | The D. L. Auld Co. | Modular device for production of cast plastic emblems |
DE2738749A1 (en) * | 1976-08-30 | 1978-03-02 | Auld D L Co | DEVICE FOR HOLDING A DECAL SHEET WITH SEVERAL PIECES OF SUBSTRATE MATERIAL ATTACHED TO IT |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0028903A1 (en) * | 1979-11-09 | 1981-05-20 | The D.L.Auld Company | Method for making decorative emblems having an ultrathin coating of plastic |
EP0030827A1 (en) * | 1979-12-17 | 1981-06-24 | The D.L.Auld Company | Decorative emblem and method of manufacture |
US4767647A (en) * | 1979-12-17 | 1988-08-30 | The D. L. Auld Company | Decorative emblem |
EP0060721A1 (en) * | 1981-03-16 | 1982-09-22 | The D.L.Auld Company | Decorative emblems and method for making same |
US5282111A (en) * | 1989-06-09 | 1994-01-25 | Labinal Components And Systems, Inc. | Thermal transfer plate and integrated circuit chip or other electrical component assemblies including such plate |
US5485351A (en) * | 1989-06-09 | 1996-01-16 | Labinal Components And Systems, Inc. | Socket assembly for integrated circuit chip package |
NL2000357C2 (en) * | 2006-12-06 | 2008-06-09 | Herikon B V | Method and device for manufacturing polyurethane products, in particular day marks for buoys. |
EP1930144A3 (en) * | 2006-12-06 | 2008-09-10 | Herikon B.V. | Method and device for producing polyurethane products, in particular daymarks for buoys |
DE102007061056A1 (en) * | 2007-12-18 | 2009-06-25 | Doro Tape Ehlis Gmbh & Co. Kg | Three-dimensional plastic label manufacturing method, involves bringing hardenable plastic in small excess quantity in preheated negative-molds moved with predetermined conveying speed in still free-flowing condition in continuous process |
CN114762846A (en) * | 2021-01-14 | 2022-07-19 | 通用汽车环球科技运作有限责任公司 | Logo installation system and method |
US11926491B2 (en) | 2021-01-14 | 2024-03-12 | GM Global Technology Operations LLC | Emblem installation system and method |
CN114762846B (en) * | 2021-01-14 | 2024-09-24 | 通用汽车环球科技运作有限责任公司 | Logo installation system and method |
Also Published As
Publication number | Publication date |
---|---|
IE50566B1 (en) | 1986-05-14 |
JPS54146838A (en) | 1979-11-16 |
EP0005376B1 (en) | 1985-08-14 |
IE790925L (en) | 1979-11-08 |
DE2967497D1 (en) | 1985-09-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4292827A (en) | Method for making decorative emblems | |
EP0030827B1 (en) | Decorative emblem and method of manufacture | |
US4605575A (en) | Decorative emblems | |
US4767647A (en) | Decorative emblem | |
EP0060721B1 (en) | Decorative emblems and method for making same | |
US4332074A (en) | Method for making decorative emblems | |
US4139654A (en) | Medallion-like articles, lamp lenses and method for their manufacture | |
EP0005376B1 (en) | Method for making decorative emblems | |
KR100372183B1 (en) | Fabrication process of decorated, extruded and profiled members | |
CA2035778C (en) | Method for molding fiber-reinforced resin | |
US4225638A (en) | Method and apparatus for flow coating with suck-back control | |
US4259388A (en) | Medallion-like articles, lamp lenses and method for their manufacture | |
US4087570A (en) | Method of making medallion-like articles and lenses | |
EP0012581B1 (en) | Decorative emblems and method for making same | |
US4781952A (en) | Decorative article and process for making | |
KR910007133B1 (en) | Decorative article and process for making | |
EP0028903A1 (en) | Method for making decorative emblems having an ultrathin coating of plastic | |
CN105538869A (en) | Treatment process for surface of automobile trimming part | |
CN115091821B (en) | Composite membrane containing solid layer, preparation method thereof and application thereof in plastic molded product | |
US20050212181A1 (en) | Thermoforming of ink jet printed media for the decoration of soft grained automotive interior components | |
JP4355130B2 (en) | Manufacturing method of resin molding | |
JP2008049545A (en) | Sheet for simultaneous molding and decoration and method for producing decorative molding using the sheet | |
KR101643933B1 (en) | Coating method of the resin sheet and the coating apparatus using the same | |
KR100549278B1 (en) | insert molding methods to control the heat of printing film | |
JP2002103515A (en) | Decorative sheet for molding processing, method for manufacturing the same and molded article using decorative sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): DE FR GB IT |
|
17P | Request for examination filed | ||
ITF | It: translation for a ep patent filed | ||
ITF | It: translation for a ep patent filed | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Designated state(s): DE FR GB IT |
|
REF | Corresponds to: |
Ref document number: 2967497 Country of ref document: DE Date of ref document: 19850919 |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19880129 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19880202 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19881118 |