EP0000619A1 - Liquid dielectric composition - Google Patents
Liquid dielectric composition Download PDFInfo
- Publication number
- EP0000619A1 EP0000619A1 EP78300086A EP78300086A EP0000619A1 EP 0000619 A1 EP0000619 A1 EP 0000619A1 EP 78300086 A EP78300086 A EP 78300086A EP 78300086 A EP78300086 A EP 78300086A EP 0000619 A1 EP0000619 A1 EP 0000619A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- benzene
- ethylbenzene
- alkylation
- liquid dielectric
- diphenylethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/20—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils
- H01B3/22—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils hydrocarbons
Definitions
- the invention defined herein relates to a liquid dielectric composition obtained as a result of a process which comprises reacing berzana with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely un- roacted benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane and heavier products, separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temperature range of about 275° to about 420°C. , preferably about 280° to about 400°C., (including any portion thereof) as said liquid dielectric composition.
- a liquid dielectric composition can be obtained from a process which comprises reacting benzene with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely unreacted benzene, ethylbenzene, polyethylbenzenes, 1,1-diphenylethane and heavier products separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temperature range of about 275° to about 420°C. , preferably about 280 0 to about 400°C. , as said liquid dielectric composition.
- the process employed in obtaining the new liquid dielectric compositions defined and claimed herein comprises reacting benzene with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely unreacted benzene, ethylbenzene, polyethylbenzenes, 1, 1-diphenylethane and heavier, still higher-boiling, products, separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temerature range of about 275° to about 420°C., preferably about 280° to about 400°C., as said liquid dielectric composition.
- the alkylation of benzene with ethylene that can be employed to obtain the new liquid dielectric compositions claimed herein can be any of the processes known in the art for producing a product containing ethylbenzene, for example, either liquid phase alkylation or vapour phase alkylation.
- the molar ratios of benzene to ethylene employed can be, for example, in the range of about 25:1 to about 2:1, preferably about 10:1 to about 3:1.
- an alkylation catalyst for example a Friedel Crafts catalyst, such as aluminium chloride or aluminium bromide or some other organo-aluminium halide; Lewis acids, such as promoted ZnCl 2 , FeCl 3 and BF 3 ; and Bronsted acids, including sulfuric acid, sulfonic acid and p-toluenesulfonic acid, hydrofluoric acid, etc., in an amount corresponding to about 0. 002 to about 0. 050 parts, preferably about 0. 005 to about 0.
- an alkylation catalyst for example a Friedel Crafts catalyst, such as aluminium chloride or aluminium bromide or some other organo-aluminium halide
- Lewis acids such as promoted ZnCl 2 , FeCl 3 and BF 3
- Bronsted acids including sulfuric acid, sulfonic acid and p-toluenesulfonic acid, hydrofluoric acid, etc.
- 030 parts, relative to ethylbenzene produced are reacted in a temperature range of about 20° to about 175°C. , preferably about 90° to about 150°C, , and a pressure in the range of about atmospheric to about 250 pounds per square inch gauge (about atmospheric to about 17. 6 kilograms per square centimeter), preferably about seven to about 200 pounds per square inch gauge (about 0. 5 to about 14 kilograms per square centimeter), for about ten minutes to about 10 hours, preferanls for about 20 minutes to about three hours.
- the reactants can be passed over a suitable alkylation catalyst bed containing alkylation catalysts, such as phosphoric acid on kieselguhr, silica or alumina, aluminium silicates, etc. , at a convenient hourly space velocity in a temperature range of about 250° to about 450°C. , preferably about 300° to about 400°C. , and a pressure of about 400 to about 1200 pounds per square inch gauge (about 28 to about 85 kilograms per square centimeter), preferably about 600 to about 1000 pounds per square inch gauge (about 42 to about 70 kilograms per square centimeter).
- alkylation catalysts such as phosphoric acid on kieselguhr, silica or alumina, aluminium silicates, etc.
- an alkylation product is obtained containing unreacted benzene, the desired ethylbenzene, polyethylbenzenes, such as diethylbenzens and triethylbenzene, 11-diphenylethane and higher-boiling products.
- the alkylation product can be treated in any conventional manner to remove any alkylation catalyst present therein.
- the alkylation product can be sent to a settler wherein the aluminium chloride complex is removed and recycled to the reaction zone and the remaining product can then be water washed and neutralized.
- the resulting alkylation product is then distilled at atmospheric pressure or under vacuum to recover unreacted benzene (B. P. 80°C.), ethylbenzene (B.P. 136°C.), polyethylbenzenes (B. P. 176°-250°C.) and 1,1-diphenylethane (B. P. 270°C.).
- the heavier product remaining after removal of benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane, as described above, is a dark, viscous, high-boiling material from which the novel liquid dielectric compositions defined and claimed herein are obtained.
- the said heavier product is simply subjected to distillation and those portions recovered having a boiling point at atmospheric pressure (14. 7 pounds per square inch gauge or 760 millimeters of mercury) in the temperature range of about 275° to about 420°C., preferably about 2 80° to about 400°C., constitute the desired and novel liquid dielectric composition.
- the remaining heavier material or residue is a black asphalt-like material solid at ambient temperature believed, in part, to be polynuclear structure having fuel value only.
- a number of liquid dielectric compositions were prepared from the residue, or heavier products, obtained as a result of the production of ethylbenzene.
- This residue was obtained as follows: Benzene and ethylene in a molar ratio of 9:1 were contacted in the liquid phase, while stirring, in a reactor at a temperature of 130°C. and a pressure of 70 pounds per square inch gauge (4. 9 kilograms per square centimeter) in the presence of AlC13 catalyst over a period of one hour, which was sufficient to convert all of the ethylene,
- the AlCl 3 complex catalyst was prepared by dissolving AlCl 3 in a polyethylbenzene cut from a previous run so that after the addition the composition of the catalyst complex was as follows: 31.
- the alkylation product was subjected to distillation to recover unreacted benzene, ethylbenzene, polyalkylated benzenes and 1,1-diphenylethane, and the benzene and polyalkylated benzenes were recycled to the reaction zone.
- the residue remaining was a dark, viscous, high-boiling material, and was produced in an amount corresponding to 0. 012 parts for each part of ethylbenzene produced.
- aged aluminium chloride complex the amount of high-boiling residue formed can be increased substantially.
- compositions defined and claimed herein are useful as liquid dielectric compositions, particularly for use in capacitors.
- compositions can be further treated, if desired, for example, to further improve their properties for a particular purpose, for example, to improve their flash point, interfacial tension, pour point, viscosity, oxidation stability, corrosion resistance, etc.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Insulating Materials (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
- The invention defined herein relates to a liquid dielectric composition obtained as a result of a process which comprises reacing berzana with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely un- roacted benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane and heavier products, separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temperature range of about 275° to about 420°C. , preferably about 280° to about 400°C., (including any portion thereof) as said liquid dielectric composition.
- Polychlorinated biphenyls have been extensively employed commercially in the electrical industry over a long period of time a.3 liquid insulating fluids, but because of environmental and toxicological problems associated therewith, substitutes therefor are raquired.
- We have found that a liquid dielectric composition can be obtained from a process which comprises reacting benzene with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely unreacted benzene, ethylbenzene, polyethylbenzenes, 1,1-diphenylethane and heavier products separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temperature range of about 275° to about 420°C. , preferably about 2800 to about 400°C. , as said liquid dielectric composition.
- In the alkylation of benzene with ethylene an alkylation product is obtained containing largely unreacted benzene , ethylbenzene, polyethylbenzenes and a higher-boiling product. From said alkylation product the unreacted benzene, ethylbenzene and polyethylbenzenes are recovered and said higher-boiling product is said to have only fuel value. In U. S. Patent No. 4, 011, 274, dated March 8, 1977, Masaaki et al recover from said higher-boiling product 1,1-diphenylethane and state that the resulting residue is still available as fuels. In the present application we have found , unexpectedly, that from said resulting residue we can obtain a fraction or fractions useful as liquid dielectric compositions.
- Briefly, the process employed in obtaining the new liquid dielectric compositions defined and claimed herein comprises reacting benzene with ethylene in the presence of an alkylation catalyst to obtain an alkylation product containing largely unreacted benzene, ethylbenzene, polyethylbenzenes, 1, 1-diphenylethane and heavier, still higher-boiling, products, separating benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane from said alkylation product and thereafter recovering from said heavier products a fraction having a boiling point in the temerature range of about 275° to about 420°C., preferably about 280° to about 400°C., as said liquid dielectric composition.
- The alkylation of benzene with ethylene that can be employed to obtain the new liquid dielectric compositions claimed herein can be any of the processes known in the art for producing a product containing ethylbenzene, for example, either liquid phase alkylation or vapour phase alkylation. The molar ratios of benzene to ethylene employed can be, for example, in the range of about 25:1 to about 2:1, preferably about 10:1 to about 3:1. In the liquid phase reaction, for example, the benzene and ethylene, together with an alkylation catalyst, for example a Friedel Crafts catalyst, such as aluminium chloride or aluminium bromide or some other organo-aluminium halide; Lewis acids, such as promoted ZnCl2, FeCl3 and BF3; and Bronsted acids, including sulfuric acid, sulfonic acid and p-toluenesulfonic acid, hydrofluoric acid, etc., in an amount corresponding to about 0. 002 to about 0. 050 parts, preferably about 0. 005 to about 0. 030 parts, relative to ethylbenzene produced, are reacted in a temperature range of about 20° to about 175°C. , preferably about 90° to about 150°C, , and a pressure in the range of about atmospheric to about 250 pounds per square inch gauge (about atmospheric to about 17. 6 kilograms per square centimeter), preferably about seven to about 200 pounds per square inch gauge (about 0. 5 to about 14 kilograms per square centimeter), for about ten minutes to about 10 hours, preferanls for about 20 minutes to about three hours. In the vapour phase, for example, the reactants can be passed over a suitable alkylation catalyst bed containing alkylation catalysts, such as phosphoric acid on kieselguhr, silica or alumina, aluminium silicates, etc. , at a convenient hourly space velocity in a temperature range of about 250° to about 450°C. , preferably about 300° to about 400°C. , and a pressure of about 400 to about 1200 pounds per square inch gauge (about 28 to about 85 kilograms per square centimeter), preferably about 600 to about 1000 pounds per square inch gauge (about 42 to about 70 kilograms per square centimeter).
- As a result of such reactions, an alkylation product is obtained containing unreacted benzene, the desired ethylbenzene, polyethylbenzenes, such as diethylbenzens and triethylbenzene, 11-diphenylethane and higher-boiling products.
- The alkylation product can be treated in any conventional manner to remove any alkylation catalyst present therein. For example, when aluminium chloride is used as catalyst, the alkylation product can be sent to a settler wherein the aluminium chloride complex is removed and recycled to the reaction zone and the remaining product can then be water washed and neutralized.
- The resulting alkylation product is then distilled at atmospheric pressure or under vacuum to recover unreacted benzene (B. P. 80°C.), ethylbenzene (B.P. 136°C.), polyethylbenzenes (B. P. 176°-250°C.) and 1,1-diphenylethane (B. P. 270°C.).
- The heavier product remaining after removal of benzene, ethylbenzene, polyethylbenzenes and 1,1-diphenylethane, as described above, is a dark, viscous, high-boiling material from which the novel liquid dielectric compositions defined and claimed herein are obtained. To obtain the claimed novel liquid dielectric composition, the said heavier product is simply subjected to distillation and those portions recovered having a boiling point at atmospheric pressure (14. 7 pounds per square inch gauge or 760 millimeters of mercury) in the temperature range of about 275° to about 420°C., preferably about 2 80° to about 400°C., constitute the desired and novel liquid dielectric composition. The remaining heavier material or residue is a black asphalt-like material solid at ambient temperature believed, in part, to be polynuclear structure having fuel value only.
- A number of liquid dielectric compositions were prepared from the residue, or heavier products, obtained as a result of the production of ethylbenzene. This residue was obtained as follows: Benzene and ethylene in a molar ratio of 9:1 were contacted in the liquid phase, while stirring, in a reactor at a temperature of 130°C. and a pressure of 70 pounds per square inch gauge (4. 9 kilograms per square centimeter) in the presence of AlC13 catalyst over a period of one hour, which was sufficient to convert all of the ethylene, The AlCl3 complex catalyst was prepared by dissolving AlCl3 in a polyethylbenzene cut from a previous run so that after the addition the composition of the catalyst complex was as follows: 31. 5 weignt per cent AlCl3, 7. 0 weight per cent benze ne, 19. 3 weight par cent ethylbenzene, 29. 8 weight per cent polyalkylated benzenes, 3. 4 weight per cent 1,1-diphenylethane and 9. 0 weight per cent higher-boiling components. The amount of AIC13 present in the catalyst mixture amounted to 0. 0034 parts by weight per one part by weight of ethylbenzene produced. Also present in the catalyst was ethyl chloride promoter in an amount corresponding 0. 0034 parts by weight per one part by weight of ethylbenzene produced to maintain a high catalyst efficiency, Analysis of the alkylation product showed the presence of 49. 0 weight per cent benzene, 32. 9 weight per cent ethylbenzene, 17. 5 weight per cent of polyalkylated benzenes (6. 0 weight per cent diethylbenzene, 2. 7 weight per cent triethylbenzenes, 2.1 weight per cent tetraethylbenzenes and 6. 7 weight per cent other alkylbenzenes), 0.1 weight per cent 1,1-diphenylethane and 0. 4 weight per cent residue. The alkylation product was subjected to distillation to recover unreacted benzene, ethylbenzene, polyalkylated benzenes and 1,1-diphenylethane, and the benzene and polyalkylated benzenes were recycled to the reaction zone. The residue remaining was a dark, viscous, high-boiling material, and was produced in an amount corresponding to 0. 012 parts for each part of ethylbenzene produced. By using aged aluminium chloride complex the amount of high-boiling residue formed can be increased substantially.
- The residue obtained above was subjected to distillations at atmospheric pressure and cuts, or combination of cuts, that were recovered were subjected to tests (ASTM-D924) at 25°C to determine their power factors and dielectric constants. In the first series of tests a sample was arbitrarily fractionated into two cuts, one boiling between 2800 and 300°C. and a second boiling between 300° and 405°C. When these cuts were subjected to the above tests the following results were obtained:
-
-
-
- The above values clearly show that the compositions defined and claimed herein are useful as liquid dielectric compositions, particularly for use in capacitors.
- It is understood that the present compositions can be further treated, if desired, for example, to further improve their properties for a particular purpose, for example, to improve their flash point, interfacial tension, pour point, viscosity, oxidation stability, corrosion resistance, etc.
- Obviously, many modifications and variations of the invention, as hereinabove set forth, can be made without departing from the spirit and scope thereof, and therefore only such limitations should be imposed as are indicated in the appended claims.
Claims (5)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/817,695 US4111825A (en) | 1977-07-21 | 1977-07-21 | Liquid dielectric composition based on a fraction derived from the alkylation product of benzene with ethylene |
US817695 | 1977-07-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0000619A1 true EP0000619A1 (en) | 1979-02-07 |
EP0000619B1 EP0000619B1 (en) | 1981-03-11 |
Family
ID=25223668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP78300086A Expired EP0000619B1 (en) | 1977-07-21 | 1978-06-27 | Liquid dielectric composition |
Country Status (6)
Country | Link |
---|---|
US (1) | US4111825A (en) |
EP (1) | EP0000619B1 (en) |
JP (1) | JPS5423088A (en) |
CA (1) | CA1082908A (en) |
DE (1) | DE2860515D1 (en) |
IT (1) | IT1099571B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011104238A1 (en) | 2010-02-23 | 2011-09-01 | B.R.A.H.M.S Gmbh | A method for determining a marker in small volume of a sample of a bodily fluid |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5210543A (en) * | 1975-07-15 | 1977-01-26 | Matsushita Electric Ind Co Ltd | Constant voltage circuit |
US4228024A (en) * | 1978-10-25 | 1980-10-14 | Gulf Research & Development Company | Insulating oil compositions containing a fraction derived from the alkylation product of benzene with ethylene |
US4347169A (en) * | 1980-06-30 | 1982-08-31 | Nippon Petrochemicals Company, Limited | Electrical insulating oil and oil-filled electrical appliances |
IT1135418B (en) * | 1981-02-11 | 1986-08-20 | Caffaro Spa Ind Chim | DIELECTRIC INSULATING FLUID IN PARTICULAR SUITABLE FOR USE IN ELECTRIC CONDENSERS, AND CONDENSER CONTAINING SUCH FLUID |
US4420791A (en) * | 1981-12-28 | 1983-12-13 | Emhart Industries, Inc. | Dielectric fluid |
JPS6116410A (en) * | 1984-06-29 | 1986-01-24 | 日本石油化学株式会社 | Electrically insulating oil |
JPH088015B2 (en) * | 1986-11-08 | 1996-01-29 | 日本石油化学株式会社 | Improved electrical insulating oil composition |
US4902841A (en) * | 1987-03-11 | 1990-02-20 | Nippon Petrochemicals Company, Ltd. | Method for producing electrical insulating oil composition |
JPH0788319B2 (en) * | 1987-09-09 | 1995-09-27 | 日本石油化学株式会社 | Method for producing m-benzyltoluene |
JPH0810566B2 (en) * | 1988-03-09 | 1996-01-31 | 日本石油化学株式会社 | Electrical insulating oil consisting of improved fractions |
US5003119A (en) * | 1988-05-09 | 1991-03-26 | Lummus Crest, Inc. | Manufacture of alkylbenzenes |
JPH0798946B2 (en) * | 1988-08-13 | 1995-10-25 | 日本石油化学株式会社 | By-product oil treatment method |
US5877362A (en) * | 1996-09-12 | 1999-03-02 | Nippon Petrochemicals Company, Limited | Method for producing diphenylmethane |
US5880322A (en) * | 1996-12-16 | 1999-03-09 | Nippen Petrochemicals Company, Limited | Method for producing diarylmethane |
US6207866B1 (en) | 1997-07-11 | 2001-03-27 | Nippon Petrochemicals Company, Limited | Method for producing diarylmethane or its derivatives |
JP2000016952A (en) | 1998-07-01 | 2000-01-18 | Nippon Petrochem Co Ltd | Production of hydrocarbon |
JP4376367B2 (en) | 1999-09-20 | 2009-12-02 | 新日本石油株式会社 | Hydrocarbon solvent and pressure-sensitive copying material using the same |
US6515235B2 (en) | 2001-05-30 | 2003-02-04 | Ericsson, Inc. | Liquid dielectric tuning of an integrated circuit |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE504293A (en) * | ||||
US2385187A (en) * | 1942-08-22 | 1945-09-18 | Standard Oil Dev Co | Synthesis of ethyl benzene |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2403785A (en) * | 1943-10-07 | 1946-07-09 | Dow Chemical Co | Alkylation method |
US2653979A (en) * | 1948-11-05 | 1953-09-29 | American Cyanamid Co | Preparation of diarylethanes |
GB732900A (en) | 1950-07-12 | 1955-06-29 | Karl Brinkmann | Improvements in the production of electric cables |
DE2014895C3 (en) * | 1969-03-28 | 1974-12-19 | Kureha Kagaku Kogyo K.K., Tokio | Process for the preparation of hydrogenated, alkylated, high temperature cracking residue oils |
JPS5115523B2 (en) * | 1971-10-02 | 1976-05-18 | ||
JPS5427960B2 (en) * | 1972-03-27 | 1979-09-13 | ||
JPS4931652A (en) * | 1972-07-20 | 1974-03-22 | ||
US4011274A (en) * | 1973-01-13 | 1977-03-08 | Asahi-Dow Limited | 1,1-diphenyl ethane process |
US4033854A (en) * | 1974-12-02 | 1977-07-05 | Nippon Oil Company, Ltd. | Electrical insulating oils |
-
1977
- 1977-07-21 US US05/817,695 patent/US4111825A/en not_active Expired - Lifetime
-
1978
- 1978-06-14 CA CA305,491A patent/CA1082908A/en not_active Expired
- 1978-06-27 EP EP78300086A patent/EP0000619B1/en not_active Expired
- 1978-06-27 DE DE7878300086T patent/DE2860515D1/en not_active Expired
- 1978-07-20 IT IT25918/78A patent/IT1099571B/en active
- 1978-07-20 JP JP8779378A patent/JPS5423088A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE504293A (en) * | ||||
US2385187A (en) * | 1942-08-22 | 1945-09-18 | Standard Oil Dev Co | Synthesis of ethyl benzene |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011104238A1 (en) | 2010-02-23 | 2011-09-01 | B.R.A.H.M.S Gmbh | A method for determining a marker in small volume of a sample of a bodily fluid |
Also Published As
Publication number | Publication date |
---|---|
US4111825A (en) | 1978-09-05 |
EP0000619B1 (en) | 1981-03-11 |
IT1099571B (en) | 1985-09-18 |
JPS6319962B2 (en) | 1988-04-26 |
DE2860515D1 (en) | 1981-04-09 |
IT7825918A0 (en) | 1978-07-20 |
JPS5423088A (en) | 1979-02-21 |
CA1082908A (en) | 1980-08-05 |
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