EP0073729A1 - Rührer zum Einrühren von Gas bei der Behandlung metallener Bäder - Google Patents
Rührer zum Einrühren von Gas bei der Behandlung metallener Bäder Download PDFInfo
- Publication number
- EP0073729A1 EP0073729A1 EP82420123A EP82420123A EP0073729A1 EP 0073729 A1 EP0073729 A1 EP 0073729A1 EP 82420123 A EP82420123 A EP 82420123A EP 82420123 A EP82420123 A EP 82420123A EP 0073729 A1 EP0073729 A1 EP 0073729A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- bath
- channels
- passage
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 17
- 239000002184 metal Substances 0.000 title claims abstract description 17
- 238000011282 treatment Methods 0.000 title claims abstract description 17
- 238000003756 stirring Methods 0.000 title description 2
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims description 17
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 49
- 239000000203 mixture Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000004581 coalescence Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 210000003462 vein Anatomy 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011369 optimal treatment Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/111—Centrifugal stirrers, i.e. stirrers with radial outlets; Stirrers of the turbine type, e.g. with means to guide the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/81—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis the stirrers having central axial inflow and substantially radial outflow
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/066—Treatment of circulating aluminium, e.g. by filtration
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
- C22B9/055—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ while the metal is circulating, e.g. combined with filtration
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D27/00—Stirring devices for molten material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23311—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a hollow stirrer axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23314—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a hollow stirrer element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2335—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the direction of introduction of the gas relative to the stirrer
- B01F23/23352—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the direction of introduction of the gas relative to the stirrer the gas moving perpendicular to the axis of rotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/115—Stirrers characterised by the configuration of the stirrers comprising discs or disc-like elements essentially perpendicular to the stirrer shaft axis
Definitions
- the present invention relates to a rotary gas dispersion device for the treatment of a bath of liquid metal and, in particular, of aluminum and its alloys.
- the first consists in passing the liquid metal through inert or active filtration media which retain the impurities either mechanically, chemically or by exerting the two effects;
- the second way resorts to the use of inert or reactive gases or their mixtures, which are more or less intensely stirred with the liquid metal, in the presence or not of products such as fluxes.
- gases are injected in the form of small discrete bubbles by means of a device consisting of a rotary shaft secured to a finned rotor, of a fixed sleeve surrounding said shaft and connected at its lower end to a stator with fins: shaft and sleeve are separated by an axial passage in which the gases are transported then introduced at the level of the fins where they are subdivided into small bubbles and brought into contact with the metal stirred by the rotor.
- each gas bubble emitted can be small at the time of its formation, and give rise initially and locally to the formation of a fine dispersion, on the other hand, during its progress in the bath, it grows rapidly by coalescence with other bubbles and then forms a coarse dispersion.
- the liquid-gas exchange is considerably reduced for the parts of the bath which have not been in contact with the gas at its point of emission, hence the random effectiveness of the treatment.
- it is necessary to find a system in which each of the elementary volumes of the liquid constituting the whole of the bath to be treated, can form with the gas this desired fine dispersion in order to obtain optimum efficiency.
- This rotary gas dispersing device for the treatment of a bath of liquid metal contained in a container comprises a cylinder-shaped rotor equipped with vanes plunging into the bath, connected to a hollow drive shaft serving to supply gas, and is characterized in that the rotor is pierced with pairs of channels, each couple comprising a channel which is used for the passage of the liquid and the other, for the passage of the gas, each of these couples opening separately at the same point of the lateral surface of the cylinder so that a fine dispersion of liquid-gas is formed there, which is then distributed in the bath by means of paddles.
- the device according to the invention therefore comprises known elements, namely a cylinder-shaped rotor equipped on its side wall with pallets having any contour, placed symmetrically with respect to the axis of rotation and arranged either vertically or obliquely so as to form a helix with steps up or down.
- This rotor is connected, in its center, and in the direction of its axis, to the lower part of a drive shaft whose upper end is connected, via a speed reducer, with a motor which gives it a rotational movement.
- This shaft is hollow, so as to bring to the rotor a gas admitted at its upper end by means, for example, of a pipe provided with a rotating joint.
- this shaft is composed of two different materials: one, for the part which plunges into the bath and which is generally graphite, the other, for the emerging part and which can be a corrosion-resistant metal alloy when the treatment gas contains chlorine for example.
- This part of the shaft can be provided with cooling fins to avoid any excessive rise in temperature, which would adversely affect the performance of the equipment relating to the gas supply, and to the drive mechanism.
- the particularity of the device lies in the presence, at the inside of the rotor, most often made of graphite, of pairs of gas circulation channels and metal circulation channels drilled in the mass and arranged in an original manner.
- liquid metal circulation channels they generally have an oblique direction relative to the axis of the rotor and pass through the latter from side to side, originating either on its lower face or on its upper face, and opening onto the lateral face, at the precise place where the gas circulation pipes open. This direction is generally tilted between 10 and 60 degrees from the horizontal.
- Their section, generally circular, is greater than that of the gas channels, and also varies according to the flow rate of metal which it is desired to treat, but a diameter of between 0.5 and 1.5 cm is perfectly suitable.
- each gas channel is associated a liquid channel, from where a set of pairs of channels having a common point of emergence in the bath.
- the liquid metal moves in the channels which are intended for it. This movement takes place from bottom to top or from top to bottom depending on whether the liquid channels arise on the lower or upper face of the rotor.
- the flow rate obtained is a function of the speed of rotation of the rotor, the number of channels, their section, their inclination relative to the vertical, the difference in level between their ends and the distance between where they take birth and the center of the rotor.
- the mixture thus produced appearing on the lateral surface of the rotor is distributed immediately by means of paddles throughout the bath where the exchange reactions continue, and before coalescence occurs, the magnification of the gas bubbles and their bursting at the bath surface.
- the liquid flow rate Due to the numerous parameters which influence the liquid flow rate, it is always possible to adjust these to certain values so as to obtain a complete treatment of all the flow rate of the metal to be treated. Likewise, the gas flow rate can be adjusted to values commonly accepted for the treatment of a given quantity of metal. Thanks to these possibilities of adjusting the geometric parameters indicated above, it is possible to limit oneself to low rotational speeds, which has the advantage of simplifying the technology of the drive mechanism and thus improving the resistance in the material time.
- Such a device according to the invention can be placed in any container whose content is to be treated, whether it is a ladle, a holding or processing oven operating continuously or not, whether or not it is equipped with intermediate partitions, whether it involves flows or not, whether the gases used are nitrogen, argon, chlorine, or their mixtures, or vapors of halogenated derivatives, or any other gaseous product capable of having a favorable action on the purification of the metal.
- the flow to be treated the desired duration of the treatment, several devices can be used, whether they are placed on a single or several containers placed in series or in parallel.
- FIG. 1 there is a hollow drive shaft (1) by which the gas (2) is brought to the level of the rotor (3) by means of a chamber (4) provided at its periphery with channels ( 5) which open at (6) at the precise location where the channels (7) which originated in this case on the underside of the rotor terminate and supplying the liquid so as to form the fine liquid-gas dispersion which is then dispersed in the bath by the paddles (8).
- FIG 3 there is shown a ladle (9) closed by a cover (10), divided into an upstream compartment (11) and a downstream compartment (12) by a partition (13) supplied with liquid by the chute 'inlet (14) and drained by the outlet chute (15).
- the liquid is subjected to the action of the device according to the invention, on which we can distinguish the rotor (3) provided with its channels (5) and (7) opening into the bath at (6) and pallets (8), connected via the chamber (4) to the hollow shaft composed of a graphite part (1), sleeved at its upper part on a metal shaft (16) equipped with cooling fins (17) driven by a reduction gear (18) controlled by a motor (19) and connected to a pipe (20) by means of a rotary joint (21) in order to be able to admit gas (2) from an external source.
- the liquid enters the channels (7) in the directions (22), rises to (6) where it meets the gases admitted into the chamber (4) in the directions (23 ) which escape through the channels (5) to form a fine dispersion which is distributed in the bath by the pallets (8) in the direction (24).
- the present invention is illustrated by the following application example: a pocket 60 cm in diameter and 1 m high has been fitted with a graphite rotor having a diameter of 20 cm and a height of 8 cm.
- the rotor is provided with eight channels for the passage of metal with a diameter of 1 cm, with a length of 7 cm, inclined with respect to the vertical of 45 ° and with eight channels for the passage of gas, drilled horizontally, and with a diameter of 0.1 cm.
- the alloy was very gaseous, and presented in the vacuum test under a pressure of 2 Torr, a hydrogen content of 0.85 cc / 100 g; at the outlet, by subjecting this alloy to the same test, there was only a content of 0.14 cc / 100 g and no appearance of bubbles, which shows the effectiveness of the treatment obtained by means of the claimed device.
- the present invention finds its application whenever a good dispersion in two-phase liquid-gas mixtures is sought: this is the case in the treatment of liquid metals and, in particular, aluminum or its alloys with a view to '' remove hydrogen and non-metallic impurities.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treating Waste Gases (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Coating Apparatus (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Radiation-Therapy Devices (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Chemically Coating (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82420123T ATE12311T1 (de) | 1981-08-28 | 1982-08-25 | Ruehrer zum einruehren von gas bei der behandlung metallener baeder. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8116735 | 1981-08-28 | ||
FR8116735A FR2512067B1 (fr) | 1981-08-28 | 1981-08-28 | Dispositif rotatif de dispersion de gaz pour le traitement d'un bain de metal liquide |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0073729A1 true EP0073729A1 (de) | 1983-03-09 |
EP0073729B1 EP0073729B1 (de) | 1985-03-20 |
Family
ID=9261862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82420123A Expired EP0073729B1 (de) | 1981-08-28 | 1982-08-25 | Rührer zum Einrühren von Gas bei der Behandlung metallener Bäder |
Country Status (28)
Country | Link |
---|---|
US (1) | US4426068A (de) |
EP (1) | EP0073729B1 (de) |
JP (1) | JPS6049700B2 (de) |
KR (1) | KR870000508B1 (de) |
AT (1) | ATE12311T1 (de) |
AU (1) | AU546831B2 (de) |
BG (1) | BG41825A3 (de) |
BR (1) | BR8205026A (de) |
CA (1) | CA1184381A (de) |
CS (1) | CS229943B2 (de) |
DD (1) | DD202453A5 (de) |
DE (1) | DE3262681D1 (de) |
DK (1) | DK158325C (de) |
EG (1) | EG15395A (de) |
ES (1) | ES8307914A1 (de) |
FR (1) | FR2512067B1 (de) |
GR (1) | GR77611B (de) |
HK (1) | HK27686A (de) |
HU (1) | HU186110B (de) |
IE (1) | IE53805B1 (de) |
IN (1) | IN156351B (de) |
NO (1) | NO160527C (de) |
PL (1) | PL131793B1 (de) |
RO (1) | RO85137B (de) |
SU (1) | SU1233807A3 (de) |
TR (1) | TR21856A (de) |
YU (1) | YU42045B (de) |
ZA (1) | ZA826254B (de) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2562449A1 (fr) * | 1984-04-06 | 1985-10-11 | Servimetal | Dispositif de traitement de l'acier, avant coulee continue, par injection de gaz |
EP0183402A2 (de) * | 1984-11-29 | 1986-06-04 | Foseco International Limited | Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen |
FR2604099A1 (fr) * | 1986-09-22 | 1988-03-25 | Pechiney Aluminium | Dispositif rotatif a pels de mise en solution d'elements d'alliage et de dispersion de gaz dans un bain d'aluminium |
WO1990001985A1 (de) * | 1988-08-16 | 1990-03-08 | Dieter Gabor | Vorrichtung zur aufbereitung flüssiger bis dünnbreiiger medien |
EP0365013A2 (de) * | 1988-10-21 | 1990-04-25 | Showa Aluminum Kabushiki Kaisha | Vorrichtungzur Erzeugung und Verteilung von Blasen in einer Flüssigkeit |
FR2645456A1 (fr) * | 1989-04-11 | 1990-10-12 | Air Liquide | Procede et installation de traitement d'un liquide avec un gaz |
EP0408165A1 (de) * | 1989-07-10 | 1991-01-16 | The Carborundum Company | Gasverteilung in Metallschmelzen |
FR2656001A1 (fr) * | 1989-12-18 | 1991-06-21 | Pechiney Recherche | Procede et dispositif d'elaboration de produits composites a matrice metallique. |
EP0665198A1 (de) * | 1994-01-27 | 1995-08-02 | Foseco International Limited | Schlagfeste oxidationsbeständige Beschichtung für Graphitteile |
WO1995021273A1 (en) * | 1994-02-04 | 1995-08-10 | Alcan International Limited | Gas treatment of molten metals |
WO1997011034A1 (en) * | 1995-09-22 | 1997-03-27 | Bernhard Van Dyk | Submersible mixing impeller |
US5660614A (en) * | 1994-02-04 | 1997-08-26 | Alcan International Limited | Gas treatment of molten metals |
WO1998005915A1 (fr) * | 1996-08-02 | 1998-02-12 | Pechiney Rhenalu | Dispositif rotatif de dispersion de gaz pour le traitement d'un bain d'aluminium liquide |
WO1999034024A1 (en) * | 1997-12-24 | 1999-07-08 | Alcan International Limited | Injector for gas treatment of molten metals |
CN111102850A (zh) * | 2019-12-26 | 2020-05-05 | 河北工业职业技术学院 | 金属冶炼用自动匀料器 |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO155447C (no) * | 1984-01-25 | 1987-04-01 | Ardal Og Sunndal Verk | Anordning ved anlegg for behandling av en vaeske, f.eks. en aluminiumssmelte. |
FR2568267B1 (fr) * | 1984-07-27 | 1987-01-23 | Pechiney Aluminium | Poche de chloruration d'alliages d'aluminium destinee a eliminer le magnesium |
JPS62205235A (ja) * | 1986-03-05 | 1987-09-09 | Showa Alum Corp | 溶融金属の処理装置 |
JPH01271059A (ja) * | 1988-04-21 | 1989-10-30 | Honda Kinzoku Gijutsu Kk | 金属連続溶解保持炉 |
CA1305609C (en) * | 1988-06-14 | 1992-07-28 | Peter D. Waite | Treatment of molten light metals |
GB2294209B (en) * | 1991-09-26 | 1996-07-03 | Charles Edward Eckert | Method for treating a molten metal with a gas |
US5160693A (en) * | 1991-09-26 | 1992-11-03 | Eckert Charles E | Impeller for treating molten metals |
JPH07122106B2 (ja) * | 1991-12-02 | 1995-12-25 | 福岡アルミ工業株式会社 | 溶融軽金属の精製処理方法及び軽金属鋳塊または鋳物の製造方法 |
CA2097648C (en) * | 1992-06-12 | 1998-04-28 | Ronald E. Gilbert | Molton metal pump with vaned impeller and flow directing pumping chamber |
US5634770A (en) * | 1992-06-12 | 1997-06-03 | Metaullics Systems Co., L.P. | Molten metal pump with vaned impeller |
FR2702159B1 (fr) * | 1993-03-05 | 1995-04-28 | Raymond Berchotteau | Appareil pour introduire et diffuser de l'air ou un gaz dans un liquide. |
US5597289A (en) * | 1995-03-07 | 1997-01-28 | Thut; Bruno H. | Dynamically balanced pump impeller |
DE19539621C1 (de) * | 1995-10-16 | 1997-06-05 | Bayer Ag | Begasungsrührer für Leichtmetallschmelzen |
US6254340B1 (en) * | 1997-04-23 | 2001-07-03 | Metaullics Systems Co., L.P. | Molten metal impeller |
FR2763079B1 (fr) * | 1997-05-07 | 1999-07-30 | Graphitech | Rotor et installation pour le traitement d'un bain de metal liquide |
US6019576A (en) * | 1997-09-22 | 2000-02-01 | Thut; Bruno H. | Pumps for pumping molten metal with a stirring action |
US6109449A (en) * | 1998-11-04 | 2000-08-29 | General Signal Corporation | Mixing system for separation of materials by flotation |
US6199836B1 (en) | 1998-11-24 | 2001-03-13 | Blasch Precision Ceramics, Inc. | Monolithic ceramic gas diffuser for injecting gas into a molten metal bath |
US6457940B1 (en) | 1999-07-23 | 2002-10-01 | Dale T. Lehman | Molten metal pump |
CA2717264C (en) * | 2000-02-01 | 2014-04-29 | Pyrotek, Inc. | Pump for molten materials with suspended solids |
GB2365513A (en) * | 2000-08-04 | 2002-02-20 | Pyrotek Engineering Materials | Refractory components for use in metal producing processes |
US6524066B2 (en) * | 2001-01-31 | 2003-02-25 | Bruno H. Thut | Impeller for molten metal pump with reduced clogging |
CN100409931C (zh) * | 2003-11-11 | 2008-08-13 | 福州华镁新技术开发有限公司 | 镁合金液搅拌精炼器 |
BRMU8402794U8 (pt) * | 2004-08-27 | 2021-10-26 | Magnesita Insider Refratarios Ltda | Configuração aplicada a dispositivo para injeção de gás e/ou gás e pós em metais líquidos através de lança refratária rotativa |
CA2528757A1 (en) * | 2004-12-02 | 2006-06-02 | Bruno H. Thut | Gas mixing and dispersement in pumps for pumping molten metal |
US7497988B2 (en) * | 2005-01-27 | 2009-03-03 | Thut Bruno H | Vortexer apparatus |
US7507365B2 (en) * | 2005-03-07 | 2009-03-24 | Thut Bruno H | Multi functional pump for pumping molten metal |
US7534284B2 (en) * | 2007-03-27 | 2009-05-19 | Bruno Thut | Flux injection with pump for pumping molten metal |
KR101036321B1 (ko) * | 2008-12-26 | 2011-05-23 | 주식회사 포스코 | 페로망간 탈린 장치 및 탈린 방법 |
US9259780B2 (en) | 2013-03-15 | 2016-02-16 | Esm Group Inc. | Rotational lance drive and rotational lance injection method |
JP6317604B2 (ja) * | 2014-03-20 | 2018-04-25 | 東京窯業株式会社 | 気泡の放出分散装置 |
US10126060B2 (en) | 2015-05-01 | 2018-11-13 | Opta Minerals Inc. | Lance drive system |
US11066713B2 (en) * | 2015-12-09 | 2021-07-20 | Tenova South Africa (Pty) Ltd | Method of operating a top submerged lance furnace |
CN109351141A (zh) * | 2018-10-25 | 2019-02-19 | 南京安伦化工科技有限公司 | 一种旋转式废气净化处理装置 |
PL441774A1 (pl) * | 2022-07-19 | 2024-01-22 | Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie | Rotor do urządzenia rafinującego aluminium |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3227547A (en) * | 1961-11-24 | 1966-01-04 | Union Carbide Corp | Degassing molten metals |
FR1555953A (de) * | 1967-02-09 | 1969-01-31 | ||
DE1758186A1 (de) * | 1968-04-19 | 1971-01-14 | Dr Heinrich Willter | Verfahren und Vorrichtung zur Herstellung dispersionsgeharteter Legierungen aus der Schmelze |
FR2166014A1 (de) * | 1971-12-27 | 1973-08-10 | Union Carbide Corp | |
LU64926A1 (de) * | 1972-03-08 | 1973-09-12 | ||
FR2200364A1 (de) * | 1972-09-18 | 1974-04-19 | Aluminum Co Of America | |
FR2209848A1 (de) * | 1972-12-07 | 1974-07-05 | Leybold Heraeus Verwaltung | |
DE2329807B1 (de) * | 1973-06-12 | 1974-10-03 | Kobe Steel Ltd., Kobe (Japan) | |
DE2728173A1 (de) * | 1977-06-23 | 1979-01-04 | Rudolf Koppatz | Ruehrwerk fuer metallschmelzen |
GB1578570A (en) * | 1976-07-21 | 1980-11-05 | Oestberg J | Stirrer for metallurgical melts |
-
1981
- 1981-08-28 FR FR8116735A patent/FR2512067B1/fr not_active Expired
-
1982
- 1982-06-16 IN IN691/CAL/82A patent/IN156351B/en unknown
- 1982-07-26 US US06/402,158 patent/US4426068A/en not_active Expired - Lifetime
- 1982-08-24 DD DD82242755A patent/DD202453A5/de not_active IP Right Cessation
- 1982-08-24 PL PL1982238022A patent/PL131793B1/pl unknown
- 1982-08-25 DE DE8282420123T patent/DE3262681D1/de not_active Expired
- 1982-08-25 EP EP82420123A patent/EP0073729B1/de not_active Expired
- 1982-08-25 AT AT82420123T patent/ATE12311T1/de not_active IP Right Cessation
- 1982-08-25 EG EG516/82A patent/EG15395A/xx active
- 1982-08-25 JP JP57147508A patent/JPS6049700B2/ja not_active Expired
- 1982-08-26 CA CA000410173A patent/CA1184381A/fr not_active Expired
- 1982-08-26 TR TR21856A patent/TR21856A/xx unknown
- 1982-08-26 ZA ZA826254A patent/ZA826254B/xx unknown
- 1982-08-26 GR GR69129A patent/GR77611B/el unknown
- 1982-08-26 SU SU823482205A patent/SU1233807A3/ru active
- 1982-08-26 BG BG057830A patent/BG41825A3/xx unknown
- 1982-08-27 ES ES515297A patent/ES8307914A1/es not_active Expired
- 1982-08-27 YU YU1929/82A patent/YU42045B/xx unknown
- 1982-08-27 IE IE2077/82A patent/IE53805B1/en unknown
- 1982-08-27 DK DK384082A patent/DK158325C/da not_active IP Right Cessation
- 1982-08-27 HU HU822771A patent/HU186110B/hu not_active IP Right Cessation
- 1982-08-27 CS CS826269A patent/CS229943B2/cs unknown
- 1982-08-27 RO RO108530A patent/RO85137B/ro unknown
- 1982-08-27 BR BR8205026A patent/BR8205026A/pt not_active IP Right Cessation
- 1982-08-27 AU AU87793/82A patent/AU546831B2/en not_active Expired
- 1982-08-27 NO NO822913A patent/NO160527C/no not_active IP Right Cessation
- 1982-08-28 KR KR8203887A patent/KR870000508B1/ko not_active IP Right Cessation
-
1986
- 1986-04-17 HK HK276/86A patent/HK27686A/xx not_active IP Right Cessation
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3227547A (en) * | 1961-11-24 | 1966-01-04 | Union Carbide Corp | Degassing molten metals |
FR1555953A (de) * | 1967-02-09 | 1969-01-31 | ||
US3792848A (en) * | 1967-02-09 | 1974-02-19 | J Ostberg | Device for improving reactions between two components of a metallurgical melt |
DE1758186A1 (de) * | 1968-04-19 | 1971-01-14 | Dr Heinrich Willter | Verfahren und Vorrichtung zur Herstellung dispersionsgeharteter Legierungen aus der Schmelze |
FR2166014A1 (de) * | 1971-12-27 | 1973-08-10 | Union Carbide Corp | |
LU64926A1 (de) * | 1972-03-08 | 1973-09-12 | ||
FR2200364A1 (de) * | 1972-09-18 | 1974-04-19 | Aluminum Co Of America | |
FR2209848A1 (de) * | 1972-12-07 | 1974-07-05 | Leybold Heraeus Verwaltung | |
DE2329807B1 (de) * | 1973-06-12 | 1974-10-03 | Kobe Steel Ltd., Kobe (Japan) | |
GB1578570A (en) * | 1976-07-21 | 1980-11-05 | Oestberg J | Stirrer for metallurgical melts |
DE2728173A1 (de) * | 1977-06-23 | 1979-01-04 | Rudolf Koppatz | Ruehrwerk fuer metallschmelzen |
Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0162789A1 (de) * | 1984-04-06 | 1985-11-27 | Servimetal | Vorrichtung zur Stahlbehandlung vor Beginn des Stranggiessens durch Einblasen von Gas |
FR2562449A1 (fr) * | 1984-04-06 | 1985-10-11 | Servimetal | Dispositif de traitement de l'acier, avant coulee continue, par injection de gaz |
EP0183402A2 (de) * | 1984-11-29 | 1986-06-04 | Foseco International Limited | Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen |
EP0183402A3 (en) * | 1984-11-29 | 1986-09-03 | Foseco International Limited | Rotary device, apparatus and method for treating molten metal |
FR2604099A1 (fr) * | 1986-09-22 | 1988-03-25 | Pechiney Aluminium | Dispositif rotatif a pels de mise en solution d'elements d'alliage et de dispersion de gaz dans un bain d'aluminium |
EP0262058A1 (de) * | 1986-09-22 | 1988-03-30 | Aluminium Pechiney | Mit Blättern versehene, drehende Vorrichtung zum Auflösen von Legierungselementen und zur Dispersion von Gas in einem Aluminiumbad |
WO1990001985A1 (de) * | 1988-08-16 | 1990-03-08 | Dieter Gabor | Vorrichtung zur aufbereitung flüssiger bis dünnbreiiger medien |
US5292194A (en) * | 1988-08-16 | 1994-03-08 | Dieter Gabor | Device for preparing liquid to thin pulpy media |
EP0365013A3 (de) * | 1988-10-21 | 1991-10-23 | Showa Aluminum Kabushiki Kaisha | Vorrichtungzur Erzeugung und Verteilung von Blasen in einer Flüssigkeit |
EP0365013A2 (de) * | 1988-10-21 | 1990-04-25 | Showa Aluminum Kabushiki Kaisha | Vorrichtungzur Erzeugung und Verteilung von Blasen in einer Flüssigkeit |
US5087292A (en) * | 1989-04-11 | 1992-02-11 | L'Air Liquide, Societe Anonyme pour l'Etude et l Exploitation des Procedes Georges Claude | Process and apparatus for treating a liquid with a gas |
EP0392900A1 (de) * | 1989-04-11 | 1990-10-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Verfahren und Vorrichtung für die Behandlung einer Flüssigkeit mit einem Gas |
FR2645456A1 (fr) * | 1989-04-11 | 1990-10-12 | Air Liquide | Procede et installation de traitement d'un liquide avec un gaz |
EP0408165A1 (de) * | 1989-07-10 | 1991-01-16 | The Carborundum Company | Gasverteilung in Metallschmelzen |
FR2656001A1 (fr) * | 1989-12-18 | 1991-06-21 | Pechiney Recherche | Procede et dispositif d'elaboration de produits composites a matrice metallique. |
EP0438004A1 (de) * | 1989-12-18 | 1991-07-24 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) Immeuble Balzac | Verfahren und Vorrichtung zum Herstellen von Verbundwerkstoff-Körpern mit Metallmatrix |
EP0665198A1 (de) * | 1994-01-27 | 1995-08-02 | Foseco International Limited | Schlagfeste oxidationsbeständige Beschichtung für Graphitteile |
US5656236A (en) * | 1994-02-04 | 1997-08-12 | Alcan International Limited | Apparatus for gas treatment of molten metals |
EP0900853A1 (de) * | 1994-02-04 | 1999-03-10 | Alcan International Limited | Begasungsrührwerk zur Behandlung von Metallschmelzen |
US5593634A (en) * | 1994-02-04 | 1997-01-14 | Alcan International Limited | Gas treatment of molten metals |
US5527381A (en) * | 1994-02-04 | 1996-06-18 | Alcan International Limited | Gas treatment of molten metals |
WO1995021273A1 (en) * | 1994-02-04 | 1995-08-10 | Alcan International Limited | Gas treatment of molten metals |
US5660614A (en) * | 1994-02-04 | 1997-08-26 | Alcan International Limited | Gas treatment of molten metals |
WO1997011034A1 (en) * | 1995-09-22 | 1997-03-27 | Bernhard Van Dyk | Submersible mixing impeller |
AU708143B2 (en) * | 1995-09-22 | 1999-07-29 | Bernhard Van Dyk | Submersible mixing impeller |
US6126150A (en) * | 1995-09-22 | 2000-10-03 | Van Dyk; Bernhard | Submersible mixing impeller |
WO1998005915A1 (fr) * | 1996-08-02 | 1998-02-12 | Pechiney Rhenalu | Dispositif rotatif de dispersion de gaz pour le traitement d'un bain d'aluminium liquide |
US6060013A (en) * | 1996-08-02 | 2000-05-09 | Pechiney Rhenalu | Rotary gas dispersion device for treating a liquid aluminium bath |
WO1999034024A1 (en) * | 1997-12-24 | 1999-07-08 | Alcan International Limited | Injector for gas treatment of molten metals |
US6056803A (en) * | 1997-12-24 | 2000-05-02 | Alcan International Limited | Injector for gas treatment of molten metals |
CN111102850A (zh) * | 2019-12-26 | 2020-05-05 | 河北工业职业技术学院 | 金属冶炼用自动匀料器 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0073729B1 (de) | Rührer zum Einrühren von Gas bei der Behandlung metallener Bäder | |
EP0050578B1 (de) | Vorrichtung zum Behandeln eines geschmolzenen Metallbades durch Gaseinblasen | |
EP0262058B1 (de) | Mit Blättern versehene, drehende Vorrichtung zum Auflösen von Legierungselementen und zur Dispersion von Gas in einem Aluminiumbad | |
EP0170600B1 (de) | Chlorierungspfanne für Aluminiumlegierungen zur Abscheidung von Magnesium | |
CA2148039C (fr) | Procede et installation de traitement d'un ecoulement brut par decantation simple apres lestage au sable fin | |
EP0392900B2 (de) | Verfahren und Vorrichtung für die Behandlung einer Flüssigkeit mit einem Gas | |
BE1004913A3 (fr) | Appareil distributeur de poudre et procede associe. | |
CH621316A5 (de) | ||
CA2023753C (fr) | Dispositif de traitement au moyen de gaz d'un bain liquide d'al de grande surface maintenu a l'etat stationnaire dans un four | |
US4240618A (en) | Stirrer for metallurgical melts | |
FR2475929A1 (fr) | Element d'installation diffuseur-melangeur, et procede pour realiser et intensifier les processus de transfert de chaleur et/ou de matiere entre des phases liquide-liquide ainsi qu'entre des phases liquide-solide | |
FR2604107A1 (fr) | Dispositif rotatif de mise en solution d'elements d'alliage et de dispersion de gaz dans un bain d'aluminium | |
CH621365A5 (en) | Process for refining magnesium, copper, zinc, tin and lead | |
EP0280689A1 (de) | Verfahren und vorrichtung für die einleitung von gas in flüssigkeit | |
WO1996016193A1 (fr) | Dispositif de degazage et de separation des inclusions dans un bain de metal liquide | |
BE696950A (de) | ||
FR2588571A1 (fr) | Dispositif et procede d'injection continue sous faible pression d'un additif pulverulent dans un courant de metal fondu | |
BE557420A (de) | ||
CH549644A (fr) | Procede pour enlever, en continu, les impuretes non metalliques d'un metal en fusion, appareil pour sa mise en oeuvre et metal ou alliage obtenu. | |
BE492509A (de) | ||
FR2529230A1 (fr) | Procede et appareillage de degazage de bains de fusion metalliques et/ou d'enlevement d'impuretes non metalliques de ces bains | |
BE446203A (de) | ||
BE553659A (de) | ||
BE422878A (de) | ||
BE566844A (de) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE GB IT LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19830318 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ALUMINIUM PECHINEY |
|
ITF | It: translation for a ep patent filed | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE GB IT LI LU NL SE |
|
REF | Corresponds to: |
Ref document number: 12311 Country of ref document: AT Date of ref document: 19850415 Kind code of ref document: T |
|
REF | Corresponds to: |
Ref document number: 3262681 Country of ref document: DE Date of ref document: 19850425 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19850831 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 19890724 Year of fee payment: 8 |
|
ITTA | It: last paid annual fee | ||
EAL | Se: european patent in force in sweden |
Ref document number: 82420123.0 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20010716 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20010724 Year of fee payment: 20 Ref country code: AT Payment date: 20010724 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20010726 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20010727 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20010831 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20010904 Year of fee payment: 20 |
|
BE20 | Be: patent expired |
Free format text: 20020825 *ALUMINIUM PECHINEY |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020824 Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020824 Ref country code: CH Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020824 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020825 Ref country code: AT Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20020825 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 Effective date: 20020824 |
|
EUG | Se: european patent has lapsed |
Ref document number: 82420123.0 |
|
NLV7 | Nl: ceased due to reaching the maximum lifetime of a patent |
Effective date: 20020825 |